ATE324943T1 - Chirale phosphine, deren komplexe mit übergangsmetallen und deren verwendung in asymmetrischen synthesereaktionen - Google Patents

Chirale phosphine, deren komplexe mit übergangsmetallen und deren verwendung in asymmetrischen synthesereaktionen

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Publication number
ATE324943T1
ATE324943T1 AT00965136T AT00965136T ATE324943T1 AT E324943 T1 ATE324943 T1 AT E324943T1 AT 00965136 T AT00965136 T AT 00965136T AT 00965136 T AT00965136 T AT 00965136T AT E324943 T1 ATE324943 T1 AT E324943T1
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Austria
Prior art keywords
chiral
ligands
phosphins
complexes
asymmetric
Prior art date
Application number
AT00965136T
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English (en)
Inventor
Xumu Zhang
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Penn State Res Found
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Publication of ATE324943T1 publication Critical patent/ATE324943T1/de

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AT00965136T 1999-09-20 2000-09-19 Chirale phosphine, deren komplexe mit übergangsmetallen und deren verwendung in asymmetrischen synthesereaktionen ATE324943T1 (de)

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Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2812638B1 (fr) * 2000-08-03 2003-04-25 Ppg Sipsy Utilisation de diphosphines chirales comme ligands optiquement actifs pour la preparation de complexes diphosphino-metalliques, les complexes ainsi obtenus et les procedes de catalyse asymetrique les mettant en oeuvre
US6350819B1 (en) 2000-10-27 2002-02-26 Union Carbide Chemicals & Plastics Technology Corporation Dendritic macromolecules for metal-ligand catalyzed processes
WO2003042224A2 (en) * 2001-11-15 2003-05-22 Sasol Technology (Pty) Ltd Preparation of derivatives of a group 5a element
JP4176022B2 (ja) 2002-03-11 2008-11-05 独立行政法人科学技術振興機構 実用的キラルジルコニウム触媒
JP4148702B2 (ja) 2002-06-04 2008-09-10 高砂香料工業株式会社 新規なジホスフィン化合物、その製造中間体、該化合物を配位子とする遷移金属錯体並びに該錯体を含む不斉水素化触媒
JP4218261B2 (ja) * 2002-06-11 2009-02-04 ダイキン工業株式会社 ポンプユニット
GB0228018D0 (en) * 2002-11-30 2003-01-08 Lucite Int Uk Ltd Carbonylation of ester
US7485739B2 (en) * 2002-09-12 2009-02-03 Lucite International Uk Ltd. Catalyst system
US6878838B2 (en) 2003-03-24 2005-04-12 The University Of North Carolina At Chapel Hill Chiral porous metal phosphonates for heterogeneous asymmetric catalysis
WO2004084834A2 (en) * 2003-03-24 2004-10-07 The University Of North Carolina At Chapel Hill Chiral porous metal phosphonates for heterogeneous asymmetric catalysis
EP1636243B1 (de) * 2003-06-13 2013-11-06 Boehringer Ingelheim International GmbH Chirale liganden zur anwendung in asymmetrischen synthesen
EP1651587A1 (de) 2003-07-03 2006-05-03 Lucite International UK Limited Prozess für die hydroformylierung ethylenisch ungesättigter verbindungen
US7094725B2 (en) * 2003-07-11 2006-08-22 The Hong Kong Polytechnic University Biphenyldiphosphine compounds
DE10342672A1 (de) 2003-09-16 2005-04-21 Bayer Chemicals Ag Chirale Phosphane zur Verwendung in asymmetrischen Synthesen
GB0403592D0 (en) * 2004-02-18 2004-03-24 Lucite Int Uk Ltd A catalyst system
JP2007533745A (ja) * 2004-04-20 2007-11-22 アールエヌディー・ファーマシューティカルズ 脂溶性のシリコン置換シクロオキシゲナーゼ−2選択的非ステロイド性抗炎症薬及び誘導体の医薬組成物及び使用方法
GB0411951D0 (en) * 2004-05-28 2004-06-30 Lucite Int Uk Ltd Carbonylation of ester
DE102005030400A1 (de) * 2005-06-27 2006-12-28 Archimica Gmbh Verfahren zur Herstellung von Arylaminen, Arylethern und Arylthioethern
GB0516556D0 (en) * 2005-08-12 2005-09-21 Lucite Int Uk Ltd Improved catalyst system
CA2626107C (en) 2005-11-17 2016-06-21 Lucite International Uk Limited Carbonylation of ethylenically unsaturated compounds
JP4621918B2 (ja) * 2005-12-09 2011-02-02 国立大学法人 千葉大学 新規不斉イリジウム触媒の製造方法とこれらを用いる光学活性β−ヒドロキシ−α−アミノ酸誘導体の製造方法
ZA200804818B (en) * 2005-12-15 2009-11-25 Penn State Res Found Tetraphosphorus ligands for catalytic hydroformylation and related reactions
CN100349880C (zh) * 2005-12-29 2007-11-21 上海交通大学 2,2’,6,6’-四噁唑啉联苯配体及其制备方法
US7754891B2 (en) * 2005-12-29 2010-07-13 Shanghai Jiaotong University 5,5′-Position linked 1,1′-biphenyl axial chiral ligand and method for preparing the same
CN100348597C (zh) * 2005-12-29 2007-11-14 上海交通大学 5,5’位连接的1, 1’-联苯类轴手性配体的合成方法
US8933276B2 (en) * 2006-01-19 2015-01-13 Agency For Science, Technology And Research Heterogeneous chiral catalyst
GB0607494D0 (en) 2006-04-13 2006-05-24 Lucite Int Uk Ltd Metal complexes
KR101464702B1 (ko) * 2006-12-02 2014-11-26 루사이트 인터내셔널 유케이 리미티드 신규한 카르보닐화 리간드 및 에틸렌성 불포화 화합물의 카르보닐화에서 이들의 용도
GB0625518D0 (en) * 2006-12-21 2007-01-31 Lucite Int Uk Ltd Carbonylation of conjugated dienes
RU2010142900A (ru) * 2008-03-19 2012-04-27 Биал-Портела Энд Ка., С.А. (Pt) Способ каталитического ассиметрического гидрирования
GB0812297D0 (en) * 2008-07-04 2008-08-13 Lucite Int Uk Ltd Novel carbonylation ligand sand thier use of in the carbonylation of ethylenically unsaturated compounds
JP5011262B2 (ja) * 2008-10-31 2012-08-29 高砂香料工業株式会社 ホスフィン化合物
JP5544756B2 (ja) * 2009-05-18 2014-07-09 東ソー株式会社 ホスフィン化合物及び該ホスフィン化合物と遷移金属化合物からなる触媒
FR2952638A1 (fr) 2009-11-17 2011-05-20 Univ Strasbourg Procede de phosphination catalytique double ou triple de composes di, tri ou tetrahalobiaryles, intermediaires employes, composes obtenus et leurs utilisations
GB201000078D0 (en) 2010-01-05 2010-02-17 Lucite Int Uk Ltd Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporatng such ligands
US8557726B2 (en) * 2010-03-12 2013-10-15 Council Of Scientific & Industrial Research Chiral heterogeneous catalyst for assymmetric nitroaldol reaction
EP2781555A4 (de) 2011-11-18 2015-10-07 Adeka Corp Neue verbindung und träger zum stützen dieser neuen verbindung
CN102592837B (zh) * 2012-03-12 2014-01-15 河北师范大学 制备超级电容器用四氯合金属季铵盐掺杂聚苯胺电极的方法
GB201316410D0 (en) 2013-09-13 2013-10-30 Bial Portela & Ca Sa Processes for preparing peripherally-selective inhibitors of dopamine-?-hydroxylase and intermediates for use therein
CN105985469B (zh) * 2015-02-11 2018-07-10 中国石油天然气股份有限公司 聚丙烯催化剂及其制备方法

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE59009670D1 (de) * 1989-05-18 1995-10-26 Hoffmann La Roche Phosphorverbindungen.
ES2091509T3 (es) * 1992-04-16 1996-11-01 Hoffmann La Roche Procedimiento para la obtencion de derivados de isopreno.
US5481008A (en) * 1993-09-13 1996-01-02 Hoffmann-La Roche Inc. Process for the preparation of optically active compounds
DE4422672A1 (de) * 1994-06-30 1996-01-04 Hoechst Ag Halogenierte Biphenyl-2,2'-diyl-bis-diphenylphosphine, ihre Herstellung und ihre Verwendung
IT1270082B (it) 1994-07-12 1997-04-28 Univ Degli Studi Milano Difosfine eteroaromatiche come leganti chirali, complessi tra dette difosfine e metalli di transizione ed impiego di detti complessi come catalizzatori chirali
JP3899542B2 (ja) * 1995-02-24 2007-03-28 日産化学工業株式会社 光学活性二座ホスフィン配位子パラジウム錯体
WO1996026210A1 (fr) * 1995-02-24 1996-08-29 Nissan Chemical Industries, Ltd. Complexe de palladium/ligand de phosphine de bidentate optiquement actif
US5624128A (en) 1995-03-06 1997-04-29 Owens; Jesse L. Transport system for disabled people
US5852212A (en) * 1995-06-21 1998-12-22 Rolic Ag Process for preparation of optically active α-bromo and α-chlorocarboxylic compounds
JP3493266B2 (ja) 1996-08-27 2004-02-03 高砂香料工業株式会社 新規な光学活性ジホスフィン化合物、該化合物を製造す る方法、該化合物を配位子とする遷移金属錯体並びに該 錯体を用いた光学活性体の製造方法
CA2290009A1 (en) * 1998-11-19 2000-05-19 Rhony Niklaus Aufdenblatten Chiral diphenyldiphosphines and d-8 metal complexes thereof
ATE297807T1 (de) * 1999-06-17 2005-07-15 Firmenich & Cie Stereospezifische isomerierung von allylaminen unter verwendung von immobilisierten chiralen phospho-liganden
JP2001131192A (ja) * 1999-10-29 2001-05-15 Takasago Internatl Corp 新規な光学活性ジホスフィン化合物、その製造中間体、該化合物を配位子とする遷移金属錯体並びに該錯体を含む不斉水素化触媒。

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CA2385421C (en) 2009-12-15
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JP4947866B2 (ja) 2012-06-06
US6521769B1 (en) 2003-02-18
CA2385421A1 (en) 2001-03-29
EP1214328A1 (de) 2002-06-19
DE60027734D1 (de) 2006-06-08
AU7590600A (en) 2001-04-24
DE60027734T2 (de) 2007-04-05
WO2001021625A1 (en) 2001-03-29
EP1214328A4 (de) 2002-11-27
HK1046250A1 (zh) 2003-01-03
EP1214328B1 (de) 2006-05-03

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