ATE324943T1 - Chirale phosphine, deren komplexe mit übergangsmetallen und deren verwendung in asymmetrischen synthesereaktionen - Google Patents
Chirale phosphine, deren komplexe mit übergangsmetallen und deren verwendung in asymmetrischen synthesereaktionenInfo
- Publication number
- ATE324943T1 ATE324943T1 AT00965136T AT00965136T ATE324943T1 AT E324943 T1 ATE324943 T1 AT E324943T1 AT 00965136 T AT00965136 T AT 00965136T AT 00965136 T AT00965136 T AT 00965136T AT E324943 T1 ATE324943 T1 AT E324943T1
- Authority
- AT
- Austria
- Prior art keywords
- chiral
- ligands
- phosphins
- complexes
- asymmetric
- Prior art date
Links
- 229910052723 transition metal Inorganic materials 0.000 title abstract 3
- 150000003624 transition metals Chemical class 0.000 title abstract 3
- 238000006243 chemical reaction Methods 0.000 title abstract 2
- 238000011914 asymmetric synthesis Methods 0.000 title 1
- 239000003446 ligand Substances 0.000 abstract 5
- 238000006317 isomerization reaction Methods 0.000 abstract 2
- 238000005698 Diels-Alder reaction Methods 0.000 abstract 1
- 238000007341 Heck reaction Methods 0.000 abstract 1
- 238000006845 Michael addition reaction Methods 0.000 abstract 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 abstract 1
- 238000006579 Tsuji-Trost allylation reaction Methods 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 238000005575 aldol reaction Methods 0.000 abstract 1
- 238000009876 asymmetric hydrogenation reaction Methods 0.000 abstract 1
- 238000006555 catalytic reaction Methods 0.000 abstract 1
- 238000005888 cyclopropanation reaction Methods 0.000 abstract 1
- 238000006735 epoxidation reaction Methods 0.000 abstract 1
- 238000007871 hydride transfer reaction Methods 0.000 abstract 1
- 238000006197 hydroboration reaction Methods 0.000 abstract 1
- 238000007037 hydroformylation reaction Methods 0.000 abstract 1
- 238000006459 hydrosilylation reaction Methods 0.000 abstract 1
- 238000006267 hydrovinylation reaction Methods 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 229910052707 ruthenium Inorganic materials 0.000 abstract 1
Classifications
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- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
- B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
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- B01J31/1625—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts immobilised by covalent linkages, i.e. pendant complexes with optional linking groups
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
- B01J2531/96—Water
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Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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US15484599P | 1999-09-20 | 1999-09-20 |
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ATE324943T1 true ATE324943T1 (de) | 2006-06-15 |
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AT00965136T ATE324943T1 (de) | 1999-09-20 | 2000-09-19 | Chirale phosphine, deren komplexe mit übergangsmetallen und deren verwendung in asymmetrischen synthesereaktionen |
Country Status (10)
Country | Link |
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US (1) | US6521769B1 (de) |
EP (1) | EP1214328B1 (de) |
JP (1) | JP4947866B2 (de) |
AT (1) | ATE324943T1 (de) |
AU (1) | AU7590600A (de) |
CA (1) | CA2385421C (de) |
DE (1) | DE60027734T2 (de) |
ES (1) | ES2263487T3 (de) |
HK (1) | HK1046250A1 (de) |
WO (1) | WO2001021625A1 (de) |
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FR2812638B1 (fr) * | 2000-08-03 | 2003-04-25 | Ppg Sipsy | Utilisation de diphosphines chirales comme ligands optiquement actifs pour la preparation de complexes diphosphino-metalliques, les complexes ainsi obtenus et les procedes de catalyse asymetrique les mettant en oeuvre |
US6350819B1 (en) | 2000-10-27 | 2002-02-26 | Union Carbide Chemicals & Plastics Technology Corporation | Dendritic macromolecules for metal-ligand catalyzed processes |
WO2003042224A2 (en) * | 2001-11-15 | 2003-05-22 | Sasol Technology (Pty) Ltd | Preparation of derivatives of a group 5a element |
JP4176022B2 (ja) | 2002-03-11 | 2008-11-05 | 独立行政法人科学技術振興機構 | 実用的キラルジルコニウム触媒 |
JP4148702B2 (ja) | 2002-06-04 | 2008-09-10 | 高砂香料工業株式会社 | 新規なジホスフィン化合物、その製造中間体、該化合物を配位子とする遷移金属錯体並びに該錯体を含む不斉水素化触媒 |
JP4218261B2 (ja) * | 2002-06-11 | 2009-02-04 | ダイキン工業株式会社 | ポンプユニット |
GB0228018D0 (en) * | 2002-11-30 | 2003-01-08 | Lucite Int Uk Ltd | Carbonylation of ester |
US7485739B2 (en) * | 2002-09-12 | 2009-02-03 | Lucite International Uk Ltd. | Catalyst system |
US6878838B2 (en) | 2003-03-24 | 2005-04-12 | The University Of North Carolina At Chapel Hill | Chiral porous metal phosphonates for heterogeneous asymmetric catalysis |
WO2004084834A2 (en) * | 2003-03-24 | 2004-10-07 | The University Of North Carolina At Chapel Hill | Chiral porous metal phosphonates for heterogeneous asymmetric catalysis |
EP1636243B1 (de) * | 2003-06-13 | 2013-11-06 | Boehringer Ingelheim International GmbH | Chirale liganden zur anwendung in asymmetrischen synthesen |
EP1651587A1 (de) | 2003-07-03 | 2006-05-03 | Lucite International UK Limited | Prozess für die hydroformylierung ethylenisch ungesättigter verbindungen |
US7094725B2 (en) * | 2003-07-11 | 2006-08-22 | The Hong Kong Polytechnic University | Biphenyldiphosphine compounds |
DE10342672A1 (de) | 2003-09-16 | 2005-04-21 | Bayer Chemicals Ag | Chirale Phosphane zur Verwendung in asymmetrischen Synthesen |
GB0403592D0 (en) * | 2004-02-18 | 2004-03-24 | Lucite Int Uk Ltd | A catalyst system |
JP2007533745A (ja) * | 2004-04-20 | 2007-11-22 | アールエヌディー・ファーマシューティカルズ | 脂溶性のシリコン置換シクロオキシゲナーゼ−2選択的非ステロイド性抗炎症薬及び誘導体の医薬組成物及び使用方法 |
GB0411951D0 (en) * | 2004-05-28 | 2004-06-30 | Lucite Int Uk Ltd | Carbonylation of ester |
DE102005030400A1 (de) * | 2005-06-27 | 2006-12-28 | Archimica Gmbh | Verfahren zur Herstellung von Arylaminen, Arylethern und Arylthioethern |
GB0516556D0 (en) * | 2005-08-12 | 2005-09-21 | Lucite Int Uk Ltd | Improved catalyst system |
CA2626107C (en) | 2005-11-17 | 2016-06-21 | Lucite International Uk Limited | Carbonylation of ethylenically unsaturated compounds |
JP4621918B2 (ja) * | 2005-12-09 | 2011-02-02 | 国立大学法人 千葉大学 | 新規不斉イリジウム触媒の製造方法とこれらを用いる光学活性β−ヒドロキシ−α−アミノ酸誘導体の製造方法 |
ZA200804818B (en) * | 2005-12-15 | 2009-11-25 | Penn State Res Found | Tetraphosphorus ligands for catalytic hydroformylation and related reactions |
CN100349880C (zh) * | 2005-12-29 | 2007-11-21 | 上海交通大学 | 2,2’,6,6’-四噁唑啉联苯配体及其制备方法 |
US7754891B2 (en) * | 2005-12-29 | 2010-07-13 | Shanghai Jiaotong University | 5,5′-Position linked 1,1′-biphenyl axial chiral ligand and method for preparing the same |
CN100348597C (zh) * | 2005-12-29 | 2007-11-14 | 上海交通大学 | 5,5’位连接的1, 1’-联苯类轴手性配体的合成方法 |
US8933276B2 (en) * | 2006-01-19 | 2015-01-13 | Agency For Science, Technology And Research | Heterogeneous chiral catalyst |
GB0607494D0 (en) | 2006-04-13 | 2006-05-24 | Lucite Int Uk Ltd | Metal complexes |
KR101464702B1 (ko) * | 2006-12-02 | 2014-11-26 | 루사이트 인터내셔널 유케이 리미티드 | 신규한 카르보닐화 리간드 및 에틸렌성 불포화 화합물의 카르보닐화에서 이들의 용도 |
GB0625518D0 (en) * | 2006-12-21 | 2007-01-31 | Lucite Int Uk Ltd | Carbonylation of conjugated dienes |
RU2010142900A (ru) * | 2008-03-19 | 2012-04-27 | Биал-Портела Энд Ка., С.А. (Pt) | Способ каталитического ассиметрического гидрирования |
GB0812297D0 (en) * | 2008-07-04 | 2008-08-13 | Lucite Int Uk Ltd | Novel carbonylation ligand sand thier use of in the carbonylation of ethylenically unsaturated compounds |
JP5011262B2 (ja) * | 2008-10-31 | 2012-08-29 | 高砂香料工業株式会社 | ホスフィン化合物 |
JP5544756B2 (ja) * | 2009-05-18 | 2014-07-09 | 東ソー株式会社 | ホスフィン化合物及び該ホスフィン化合物と遷移金属化合物からなる触媒 |
FR2952638A1 (fr) | 2009-11-17 | 2011-05-20 | Univ Strasbourg | Procede de phosphination catalytique double ou triple de composes di, tri ou tetrahalobiaryles, intermediaires employes, composes obtenus et leurs utilisations |
GB201000078D0 (en) | 2010-01-05 | 2010-02-17 | Lucite Int Uk Ltd | Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporatng such ligands |
US8557726B2 (en) * | 2010-03-12 | 2013-10-15 | Council Of Scientific & Industrial Research | Chiral heterogeneous catalyst for assymmetric nitroaldol reaction |
EP2781555A4 (de) | 2011-11-18 | 2015-10-07 | Adeka Corp | Neue verbindung und träger zum stützen dieser neuen verbindung |
CN102592837B (zh) * | 2012-03-12 | 2014-01-15 | 河北师范大学 | 制备超级电容器用四氯合金属季铵盐掺杂聚苯胺电极的方法 |
GB201316410D0 (en) | 2013-09-13 | 2013-10-30 | Bial Portela & Ca Sa | Processes for preparing peripherally-selective inhibitors of dopamine-?-hydroxylase and intermediates for use therein |
CN105985469B (zh) * | 2015-02-11 | 2018-07-10 | 中国石油天然气股份有限公司 | 聚丙烯催化剂及其制备方法 |
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DE59009670D1 (de) * | 1989-05-18 | 1995-10-26 | Hoffmann La Roche | Phosphorverbindungen. |
ES2091509T3 (es) * | 1992-04-16 | 1996-11-01 | Hoffmann La Roche | Procedimiento para la obtencion de derivados de isopreno. |
US5481008A (en) * | 1993-09-13 | 1996-01-02 | Hoffmann-La Roche Inc. | Process for the preparation of optically active compounds |
DE4422672A1 (de) * | 1994-06-30 | 1996-01-04 | Hoechst Ag | Halogenierte Biphenyl-2,2'-diyl-bis-diphenylphosphine, ihre Herstellung und ihre Verwendung |
IT1270082B (it) | 1994-07-12 | 1997-04-28 | Univ Degli Studi Milano | Difosfine eteroaromatiche come leganti chirali, complessi tra dette difosfine e metalli di transizione ed impiego di detti complessi come catalizzatori chirali |
JP3899542B2 (ja) * | 1995-02-24 | 2007-03-28 | 日産化学工業株式会社 | 光学活性二座ホスフィン配位子パラジウム錯体 |
WO1996026210A1 (fr) * | 1995-02-24 | 1996-08-29 | Nissan Chemical Industries, Ltd. | Complexe de palladium/ligand de phosphine de bidentate optiquement actif |
US5624128A (en) | 1995-03-06 | 1997-04-29 | Owens; Jesse L. | Transport system for disabled people |
US5852212A (en) * | 1995-06-21 | 1998-12-22 | Rolic Ag | Process for preparation of optically active α-bromo and α-chlorocarboxylic compounds |
JP3493266B2 (ja) | 1996-08-27 | 2004-02-03 | 高砂香料工業株式会社 | 新規な光学活性ジホスフィン化合物、該化合物を製造す る方法、該化合物を配位子とする遷移金属錯体並びに該 錯体を用いた光学活性体の製造方法 |
CA2290009A1 (en) * | 1998-11-19 | 2000-05-19 | Rhony Niklaus Aufdenblatten | Chiral diphenyldiphosphines and d-8 metal complexes thereof |
ATE297807T1 (de) * | 1999-06-17 | 2005-07-15 | Firmenich & Cie | Stereospezifische isomerierung von allylaminen unter verwendung von immobilisierten chiralen phospho-liganden |
JP2001131192A (ja) * | 1999-10-29 | 2001-05-15 | Takasago Internatl Corp | 新規な光学活性ジホスフィン化合物、その製造中間体、該化合物を配位子とする遷移金属錯体並びに該錯体を含む不斉水素化触媒。 |
-
2000
- 2000-09-19 US US09/665,456 patent/US6521769B1/en not_active Expired - Lifetime
- 2000-09-19 CA CA002385421A patent/CA2385421C/en not_active Expired - Lifetime
- 2000-09-19 JP JP2001525000A patent/JP4947866B2/ja not_active Expired - Lifetime
- 2000-09-19 AT AT00965136T patent/ATE324943T1/de not_active IP Right Cessation
- 2000-09-19 WO PCT/US2000/025635 patent/WO2001021625A1/en active IP Right Grant
- 2000-09-19 ES ES00965136T patent/ES2263487T3/es not_active Expired - Lifetime
- 2000-09-19 DE DE60027734T patent/DE60027734T2/de not_active Expired - Lifetime
- 2000-09-19 EP EP00965136A patent/EP1214328B1/de not_active Expired - Lifetime
- 2000-09-19 AU AU75906/00A patent/AU7590600A/en not_active Abandoned
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2002
- 2002-10-22 HK HK02107646.1A patent/HK1046250A1/zh unknown
Also Published As
Publication number | Publication date |
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ES2263487T3 (es) | 2006-12-16 |
CA2385421C (en) | 2009-12-15 |
JP2003509513A (ja) | 2003-03-11 |
JP4947866B2 (ja) | 2012-06-06 |
US6521769B1 (en) | 2003-02-18 |
CA2385421A1 (en) | 2001-03-29 |
EP1214328A1 (de) | 2002-06-19 |
DE60027734D1 (de) | 2006-06-08 |
AU7590600A (en) | 2001-04-24 |
DE60027734T2 (de) | 2007-04-05 |
WO2001021625A1 (en) | 2001-03-29 |
EP1214328A4 (de) | 2002-11-27 |
HK1046250A1 (zh) | 2003-01-03 |
EP1214328B1 (de) | 2006-05-03 |
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