ES2091509T3 - Procedimiento para la obtencion de derivados de isopreno. - Google Patents

Procedimiento para la obtencion de derivados de isopreno.

Info

Publication number
ES2091509T3
ES2091509T3 ES93105548T ES93105548T ES2091509T3 ES 2091509 T3 ES2091509 T3 ES 2091509T3 ES 93105548 T ES93105548 T ES 93105548T ES 93105548 T ES93105548 T ES 93105548T ES 2091509 T3 ES2091509 T3 ES 2091509T3
Authority
ES
Spain
Prior art keywords
image
procedure
obtaining
isoprene derivatives
asymmetric
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93105548T
Other languages
English (en)
Inventor
Emil Albin Broger
Robert-Karl Muller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
F Hoffmann La Roche AG
Original Assignee
F Hoffmann La Roche AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by F Hoffmann La Roche AG filed Critical F Hoffmann La Roche AG
Application granted granted Critical
Publication of ES2091509T3 publication Critical patent/ES2091509T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
    • C07D317/12—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/172—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with the obtention of a fully saturated alcohol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/125—Monohydroxylic acyclic alcohols containing five to twenty-two carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/48—Preparation of compounds having groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/62—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by hydrogenation of carbon-to-carbon double or triple bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/04—Saturated compounds containing keto groups bound to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

SE DESCRIBE UN PROCEDIMIENTO PARA LA OBTENCION DE DERIVADOS DE ISOPRENO DE FORMULA (I) SE HIDROGENA ASIMETRICAMENTE UN COMPUESTO DE FORMULA (II) EN LA FORMA (E) Y (Z) CON UN COMPLEJO DE RUTENIO DE UNAS DIFOSFINAS OPTICAMENTE ACTIVAS Y NO ISOMERAS GEOMETRICAS. SIENDO; R UN RESTO DE FORMULA (A), (B) O (C); R1 ALQUILO DE BAJO PESO MOLECULAR Y AMBOS R1 ETILENO Y PROPILENO Y N UN NUMERO ENTERO ENTRE 0 Y 2. PRESENTANDO EL CENTRO DE ASIMETRIA LAS CONFIGURACIONES (R) O (S).
ES93105548T 1992-04-16 1993-04-03 Procedimiento para la obtencion de derivados de isopreno. Expired - Lifetime ES2091509T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH127092 1992-04-16

Publications (1)

Publication Number Publication Date
ES2091509T3 true ES2091509T3 (es) 1996-11-01

Family

ID=4206480

Family Applications (1)

Application Number Title Priority Date Filing Date
ES93105548T Expired - Lifetime ES2091509T3 (es) 1992-04-16 1993-04-03 Procedimiento para la obtencion de derivados de isopreno.

Country Status (7)

Country Link
US (1) US5600015A (es)
EP (1) EP0565975B1 (es)
JP (1) JP3310381B2 (es)
AT (1) ATE142191T1 (es)
DE (1) DE59303616D1 (es)
DK (1) DK0565975T3 (es)
ES (1) ES2091509T3 (es)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3214466B2 (ja) * 1998-04-07 2001-10-02 日本電気株式会社 移動通信システム及びその通信制御方法並びにそれに用いる基地局及び移動局
ATE324943T1 (de) * 1999-09-20 2006-06-15 Penn State Res Found Chirale phosphine, deren komplexe mit übergangsmetallen und deren verwendung in asymmetrischen synthesereaktionen
DE10056310A1 (de) * 2000-11-14 2002-05-16 Bayer Ag Verbessertes Verfahren zur Herstellung von enantiomerenreinen(5,5`-Dichlor-6,6`-dimethoxybiphenyl-2,2`-diyl)-bis-(diphenylphosphinoxiden)
US7094725B2 (en) 2003-07-11 2006-08-22 The Hong Kong Polytechnic University Biphenyldiphosphine compounds
ATE520678T1 (de) * 2004-12-22 2011-09-15 Dsm Ip Assets Bv Asymmetrische hydrierung von alkenen mit chiralem iridiumkomplex
US9611200B2 (en) 2012-12-18 2017-04-04 Dsm Ip Assets B.V. (6R,10R)-6,10,14-trimetylpentadecan-2-one prepared from 6,10,14 trimetylpentadeca-5,9,13-trien-2-one or 6,10,14-trimetylpentadeca-5,9-dien-2-one
US10047019B2 (en) * 2012-12-18 2018-08-14 Dsm Ip Assets B.V. Efficient process of asymmetric hydrogenation of unsaturated ketones using additives
EP2935190B1 (en) * 2012-12-18 2018-09-19 DSM IP Assets B.V. (6r,10r)-6,10,14-trimetylpentadecan-2-one prepared from 6,10-dimetylundeca-3,5,9-trien-2-one
CN109970533B (zh) * 2012-12-18 2022-06-14 帝斯曼知识产权资产管理有限公司 由(r)-6，10，14-三甲基十五碳-5-烯-2-酮制备的(6r，10r)-6，10，14-三甲基十五烷-2-酮
EP2935233B1 (en) * 2012-12-18 2019-01-30 DSM IP Assets B.V. Process of asymmetric hydrogenation of ketals and acetals
ES2746749T3 (es) 2012-12-18 2020-03-06 Dsm Ip Assets Bv (6R,10R)-6,10,14-Trimetilpentadecan-2-ona preparada a partir de 6,10-dimetilundec-5-en-2-ona o 6,10-dimetilundeca-5,9-dien-2-ona

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3639439A (en) * 1964-12-10 1972-02-01 Shell Oil Co Rhodium (i) halide complexes
DE3006867C2 (de) * 1980-02-23 1981-11-12 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von höheren gesättigten Ketonen
DE3018388A1 (de) * 1980-05-14 1981-11-19 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von optisch aktiven verbindungen und deren verwendung zur herstellung von vitamin e
EP0258967B2 (en) * 1986-08-27 1996-08-21 Takasago Perfumery Co., Ltd. Process for producing optically active alcohols
EP0295531B1 (en) * 1987-06-16 1993-03-24 F. Hoffmann-La Roche Ag Hydrogenation process
DK0397042T3 (da) * 1989-05-10 1995-10-02 Hoffmann La Roche Fremstilling af isoquinolinderivater
ATE128140T1 (de) * 1989-05-18 1995-10-15 Hoffmann La Roche Phosphorverbindungen.
JPH0753680B2 (ja) * 1989-07-17 1995-06-07 高砂香料工業株式会社 光学活性ケトンの製造法
EP0530336B1 (de) * 1991-03-15 1996-03-06 F. HOFFMANN-LA ROCHE & CO. Aktiengesellschaft Chirale phosphine

Also Published As

Publication number Publication date
US5600015A (en) 1997-02-04
EP0565975A2 (de) 1993-10-20
DE59303616D1 (de) 1996-10-10
JPH0625035A (ja) 1994-02-01
EP0565975A3 (de) 1993-11-03
DK0565975T3 (da) 1996-10-14
JP3310381B2 (ja) 2002-08-05
EP0565975B1 (de) 1996-09-04
ATE142191T1 (de) 1996-09-15

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