ATE104682T1 - Fester katalysator fuer die olefinpolymerisation und verfahren zu dessen herstellung. - Google Patents
Fester katalysator fuer die olefinpolymerisation und verfahren zu dessen herstellung.Info
- Publication number
- ATE104682T1 ATE104682T1 AT8888900593T AT88900593T ATE104682T1 AT E104682 T1 ATE104682 T1 AT E104682T1 AT 8888900593 T AT8888900593 T AT 8888900593T AT 88900593 T AT88900593 T AT 88900593T AT E104682 T1 ATE104682 T1 AT E104682T1
- Authority
- AT
- Austria
- Prior art keywords
- transition metal
- group
- aluminoxane
- cycloalkadienyl
- compd
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title abstract 2
- 239000011949 solid catalyst Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 title 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 6
- 150000003624 transition metals Chemical class 0.000 abstract 6
- 125000001485 cycloalkadienyl group Chemical group 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 2
- 229910052782 aluminium Inorganic materials 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 2
- 239000010419 fine particle Substances 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 239000002245 particle Substances 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 230000008021 deposition Effects 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 229910052735 hafnium Inorganic materials 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP31128686 | 1986-12-30 | ||
| JP31128786 | 1986-12-30 | ||
| PCT/JP1987/001047 WO1988005058A1 (fr) | 1986-12-30 | 1987-12-28 | Catalyseur a l'etat solide pour la polymerisation d'olefines et procede de preparation |
| EP88900593A EP0295312B1 (de) | 1986-12-30 | 1987-12-28 | Fester katalysator für die olefinpolymerisation und verfahren zu dessen herstellung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE104682T1 true ATE104682T1 (de) | 1994-05-15 |
Family
ID=26566662
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT8888900593T ATE104682T1 (de) | 1986-12-30 | 1988-07-19 | Fester katalysator fuer die olefinpolymerisation und verfahren zu dessen herstellung. |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4921825A (de) |
| EP (1) | EP0295312B1 (de) |
| JP (1) | JP2889205B2 (de) |
| KR (1) | KR910008277B1 (de) |
| AT (1) | ATE104682T1 (de) |
| DE (1) | DE3789666T2 (de) |
| WO (1) | WO1988005058A1 (de) |
Families Citing this family (99)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE81512T1 (de) * | 1986-08-26 | 1992-10-15 | Mitsui Petrochemical Ind | Katalysator zur polymerisierung von alpha-olefin und verfahren. |
| US4794096A (en) * | 1987-04-03 | 1988-12-27 | Fina Technology, Inc. | Hafnium metallocene catalyst for the polymerization of olefins |
| IL87717A0 (en) * | 1987-09-14 | 1989-02-28 | Exxon Chemical Patents Inc | Preparation of an active metallocene-alumoxane catalyst in situ during polymerization |
| IT1237398B (it) * | 1989-01-31 | 1993-06-01 | Ausimont Srl | Catalizzatori per la polimerizzazione di olefine. |
| WO1991009882A1 (en) * | 1990-01-02 | 1991-07-11 | Exxon Chemical Patents Inc. | Supported ionic metallocene catalysts for olefin polymerization |
| US5418200A (en) * | 1991-03-29 | 1995-05-23 | Chevron Chemical Company | Cyclopentadienyl group 6B metal α-olefin polymerization catalysts and process for polymerizing α-olefins |
| ATE153034T1 (de) * | 1991-03-29 | 1997-05-15 | Chevron Usa Inc | Cyclopentadienylgruppe enthaltende alpha-olefin- polymerisationskatalysatoren auf basis eines metals der 6b-gruppe und verfahren zur polymerisation von alpha-olefinen |
| CA2069995C (en) * | 1991-05-31 | 1996-04-09 | Mitsui Chemicals, Incorporated | Olefin polymerization solid catalyst, olefin polymerization catalyst and olefin polymerization |
| DE4119343A1 (de) * | 1991-06-12 | 1992-12-17 | Basf Ag | Isolierbares, getraegertes katalysatorsystem zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen |
| US5409874A (en) * | 1991-06-20 | 1995-04-25 | Mitsui Petrochemical Industries, Ltd. | Catalyst for olefin polymerization, process for the polymerization of olefin, and transition metal compound employable for the catalyst |
| DE4121368A1 (de) * | 1991-06-28 | 1993-01-07 | Hoechst Ag | Katalysator und verfahren zur herstellung von hochmolekularen polyolefinen |
| US5411925A (en) * | 1993-02-12 | 1995-05-02 | Phillips Petroleum Company | Organo-aluminoxy product and use |
| US5362824A (en) * | 1991-12-13 | 1994-11-08 | Mobil Oil Corporation | Olefin polymerization catalysts |
| US5461017A (en) * | 1991-12-13 | 1995-10-24 | Mobil Oil Corporation | Olefin polymerization catalysts |
| FI112233B (fi) * | 1992-04-01 | 2003-11-14 | Basell Polyolefine Gmbh | Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö |
| US6143854A (en) | 1993-08-06 | 2000-11-07 | Exxon Chemical Patents, Inc. | Polymerization catalysts, their production and use |
| US5332706A (en) * | 1992-12-28 | 1994-07-26 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
| US5602067A (en) * | 1992-12-28 | 1997-02-11 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
| IT1264680B1 (it) | 1993-07-07 | 1996-10-04 | Spherilene Srl | Catalizzatori supportati per la polimerizzazione delle olefine |
| DE4336659A1 (de) * | 1993-10-27 | 1995-05-04 | Witco Gmbh | Verfahren zur Herstellung von Alkylaluminoxanen auf inerten Trägermaterialien |
| US5491207A (en) * | 1993-12-14 | 1996-02-13 | Exxon Chemical Patents Inc. | Process of producing high molecular weight ethylene-α-olefin elastomers with an indenyl metallocene catalyst system |
| US6391817B1 (en) | 1993-12-28 | 2002-05-21 | Exxonmobil Chemical Patents Inc. | Method for producing a prepolymerized catalyst |
| CA2180981A1 (en) * | 1994-01-11 | 1995-07-13 | Terry John Burkhardt | Use of gel-free alumoxane solution |
| AU694765B2 (en) * | 1994-03-01 | 1998-07-30 | Mobil Oil Corporation | Olefin polymerization catalysts |
| EP0750642B1 (de) * | 1994-03-17 | 2000-01-05 | Exxon Chemical Patents Inc. | Sprühgetrockneter emulsionspolymer als katalysatorträger |
| DE4409249A1 (de) * | 1994-03-18 | 1995-09-21 | Witco Gmbh | Verfahren zur Herstellung von Alkylaluminoxan auf inerten Trägermaterialien |
| FR2717816B1 (fr) | 1994-03-23 | 1996-04-26 | Atochem Elf Sa | Composante catalytique pour la polymérisation des oléfines obtenue par impregnation d'un prépolymère par une solution d'une composante catalytique. Prépolymère et polymère obtenus à partir de ladite composante catalytique. |
| US5593931A (en) * | 1995-03-03 | 1997-01-14 | Chevron Chemical Company | Cyclopentadienyl group 6b metal alpha-olefin polymerization catalysts and process for polymerizing alpha-olefins |
| FI105195B (fi) * | 1995-05-02 | 2000-06-30 | Borealis As | Polyeteeni, jolla on hallittu partikkelikoko ja morfologia |
| US6533988B2 (en) | 1995-05-02 | 2003-03-18 | Borealis Technology Oy | Rotational moulding process of ethylene polymers or copolymers having a controlled particle size and morphology |
| US5587439A (en) * | 1995-05-12 | 1996-12-24 | Quantum Chemical Corporation | Polymer supported catalyst for olefin polymerization |
| US5661095A (en) * | 1995-06-06 | 1997-08-26 | Quantum Chemical Corporation | Olefin polymerization catalyst component supported on a copolymer of an olefin and an unsaturated silane |
| CN1047388C (zh) * | 1995-07-14 | 1999-12-15 | 中国石油化工总公司 | 负载型金属茂类化合物/铝氧烷催化剂的制备 |
| CN1045446C (zh) * | 1995-07-14 | 1999-10-06 | 中国石油化工总公司 | 低聚铝氧烷的制备方法 |
| US5610115A (en) * | 1995-07-20 | 1997-03-11 | Samsung General Chemicals Co., Ltd. | Organic carrier supported metallocene catalyst for olefin polymerization |
| DE19527652A1 (de) * | 1995-07-28 | 1997-01-30 | Hoechst Ag | Metallocenverbindung |
| ATE153675T1 (de) * | 1995-09-13 | 1997-06-15 | Witco Gmbh | Verfahren zur herstellung von metallocen- katalysatorsystemen auf inerten trägermaterialien unter verwendung von gasphasenreaktoren |
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| DE19833170A1 (de) | 1998-07-23 | 2000-01-27 | Targor Gmbh | Verfahren zur Herstellung eines metallhaltigen Trägerkatalysators oder einer Trägerkatalysatorkomponente durch Tränkung einer Trägersubstanz |
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| DE19844167A1 (de) * | 1998-09-25 | 2000-04-06 | Ticona Gmbh | Aktivkohlefilter |
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| DE60137638D1 (de) * | 2001-12-19 | 2009-03-26 | Borealis Tech Oy | Herstellung von geträgerten Katalysatoren für die Olefinpolymerisation |
| WO2003062283A1 (en) * | 2002-01-25 | 2003-07-31 | Reliance Industries Limited | An olefin polymerisation titanium catalyst |
| US6884749B2 (en) | 2002-10-17 | 2005-04-26 | Equistar Chemicals L.P. | Supported catalysts which reduce sheeting in olefin polymerization, process for the preparation and the use thereof |
| US7365039B2 (en) | 2003-03-21 | 2008-04-29 | Dow Global Technologies Inc. | Morphology controlled olefin polymerization process |
| US6953764B2 (en) | 2003-05-02 | 2005-10-11 | Dow Global Technologies Inc. | High activity olefin polymerization catalyst and process |
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| EP1847555A1 (de) * | 2006-04-18 | 2007-10-24 | Borealis Technology Oy | Mehrfach verzweigtes Polypropylen |
| EP1939226B1 (de) | 2006-12-28 | 2013-07-17 | Borealis Technology Oy | Verfahren zur Polymerherstellung, Verfahren zur Herstellung eines prepolymerisierten Katalysators, prepolymerisierter Katalysator und seine Verwendung |
| TW200932762A (en) | 2007-10-22 | 2009-08-01 | Univation Tech Llc | Polyethylene compositions having improved properties |
| EP2119732A1 (de) | 2008-05-16 | 2009-11-18 | Borealis Technology Oy | Metallocen-Katalysator-Zusammensetzungen mit verbesserten Eigenschaften, Verfahren zu ihrer Herstellung und ihre Verwendung zur Herstellung von Polyolefin-Homo- oder Copolymeren |
| MX337518B (es) | 2008-09-25 | 2016-03-09 | Basell Polyolefine Gmbh | Composicion de polietileno lineal de baja densidad (lldpe) resistente a impactos y peliculas hechas de la misma. |
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| CN102257017B (zh) | 2008-12-18 | 2014-02-12 | 尤尼威蒂恩技术有限责任公司 | 用于聚合反应种子床处理的方法 |
| WO2010080871A1 (en) | 2009-01-08 | 2010-07-15 | Univation Technologies, Llc | Additive for gas phase polymerization processes |
| KR101698618B1 (ko) | 2009-01-08 | 2017-01-20 | 유니베이션 테크놀로지즈, 엘엘씨 | 폴리올레핀 중합 방법을 위한 첨가제 |
| CN102482372B (zh) | 2009-07-23 | 2013-09-04 | 尤尼威蒂恩技术有限公司 | 聚合反应系统 |
| WO2011078923A1 (en) | 2009-12-23 | 2011-06-30 | Univation Technologies, Llc | Methods for producing catalyst systems |
| CN103347905B (zh) | 2010-12-22 | 2015-12-16 | 尤尼威蒂恩技术有限责任公司 | 用于聚烯烃聚合方法的添加剂 |
| BR112015011215B1 (pt) | 2012-11-26 | 2018-11-21 | Braskem S.A. | Catalisador metaloceno suportado em suporte híbrido, processo de obtenção do mesmo, processo de polimerização para obtenção de um homopolímero ou copolímero de etileno com distribuição de massa molar ampla ou bimodal, uso do catalisador de metalocenosuportado e polímero de etileno com distribuição de massa molar ampla ou bimodal |
| US9650453B2 (en) | 2012-12-28 | 2017-05-16 | Univation Technologies, Llc | Methods of integrating aluminoxane production into catalyst production |
| WO2014109832A1 (en) | 2013-01-14 | 2014-07-17 | Univation Technologies, Llc | Methods for preparing catalyst systems with increased productivity |
| GB201420215D0 (en) * | 2014-11-13 | 2014-12-31 | Scg Chemicals Co Ltd | Catalysts |
| JP2017535647A (ja) * | 2014-11-13 | 2017-11-30 | エスシージー ケミカルズ カンパニー,リミテッド | 触媒 |
| WO2016118599A1 (en) | 2015-01-21 | 2016-07-28 | Univation Technologies, Llc | Methods for controlling polymer chain scission |
| WO2016118566A1 (en) | 2015-01-21 | 2016-07-28 | Univation Technologies, Llc | Methods for gel reduction in polyolefins |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4530914A (en) * | 1983-06-06 | 1985-07-23 | Exxon Research & Engineering Co. | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
| JPS60106808A (ja) * | 1983-11-14 | 1985-06-12 | Idemitsu Kosan Co Ltd | ポリエチレン系組成物の製造方法 |
| JPH0788403B2 (ja) * | 1984-11-01 | 1995-09-27 | 昭和電工株式会社 | ポリオレフインの製造方法 |
| CA1268754A (en) * | 1985-06-21 | 1990-05-08 | Howard Curtis Welborn, Jr. | Supported polymerization catalyst |
| US4808561A (en) * | 1985-06-21 | 1989-02-28 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
| US4701432A (en) * | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
| US4752597A (en) * | 1985-12-12 | 1988-06-21 | Exxon Chemical Patents Inc. | New polymerization catalyst |
| US4794096A (en) * | 1987-04-03 | 1988-12-27 | Fina Technology, Inc. | Hafnium metallocene catalyst for the polymerization of olefins |
| JP3098634B2 (ja) * | 1992-10-20 | 2000-10-16 | 株式会社日立メディコ | プリントデータの送信装置及び画像診断装置 |
-
1987
- 1987-12-28 KR KR1019880701044A patent/KR910008277B1/ko not_active Expired
- 1987-12-28 US US07/245,399 patent/US4921825A/en not_active Expired - Fee Related
- 1987-12-28 EP EP88900593A patent/EP0295312B1/de not_active Expired - Lifetime
- 1987-12-28 WO PCT/JP1987/001047 patent/WO1988005058A1/ja not_active Ceased
- 1987-12-28 DE DE3789666T patent/DE3789666T2/de not_active Expired - Fee Related
-
1988
- 1988-07-19 AT AT8888900593T patent/ATE104682T1/de active
-
1997
- 1997-02-10 JP JP9041455A patent/JP2889205B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| KR890700138A (ko) | 1989-03-10 |
| DE3789666D1 (de) | 1994-05-26 |
| EP0295312A1 (de) | 1988-12-21 |
| EP0295312B1 (de) | 1994-04-20 |
| EP0295312A4 (de) | 1989-05-16 |
| WO1988005058A1 (fr) | 1988-07-14 |
| JP2889205B2 (ja) | 1999-05-10 |
| US4921825A (en) | 1990-05-01 |
| JPH0816128B1 (de) | 1996-02-21 |
| JPH09176224A (ja) | 1997-07-08 |
| DE3789666T2 (de) | 1994-08-04 |
| KR910008277B1 (ko) | 1991-10-12 |
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