AT266297B - Verfahren zur Herstellung eines Formgebildes, z.B. eines Fadens - Google Patents
Verfahren zur Herstellung eines Formgebildes, z.B. eines FadensInfo
- Publication number
- AT266297B AT266297B AT471663A AT471663A AT266297B AT 266297 B AT266297 B AT 266297B AT 471663 A AT471663 A AT 471663A AT 471663 A AT471663 A AT 471663A AT 266297 B AT266297 B AT 266297B
- Authority
- AT
- Austria
- Prior art keywords
- cellulose
- solution
- fibers
- spinning
- viscose
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 10
- 238000009987 spinning Methods 0.000 claims description 30
- 229920002678 cellulose Polymers 0.000 claims description 27
- 239000001913 cellulose Substances 0.000 claims description 21
- 150000001875 compounds Chemical class 0.000 claims description 16
- 229920000297 Rayon Polymers 0.000 claims description 13
- 238000004519 manufacturing process Methods 0.000 claims description 11
- 238000007496 glass forming Methods 0.000 claims description 8
- 229920005989 resin Polymers 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 229920003002 synthetic resin Polymers 0.000 claims description 6
- 239000000057 synthetic resin Substances 0.000 claims description 6
- 239000004115 Sodium Silicate Substances 0.000 claims description 5
- -1 sodium silicate Chemical class 0.000 claims description 5
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 5
- 238000001125 extrusion Methods 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000000243 solution Substances 0.000 description 35
- 239000000835 fiber Substances 0.000 description 34
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 13
- 239000004744 fabric Substances 0.000 description 9
- 229920003086 cellulose ether Polymers 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 239000000919 ceramic Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 4
- 229920002301 cellulose acetate Polymers 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 229910052814 silicon oxide Inorganic materials 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 238000000197 pyrolysis Methods 0.000 description 3
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 239000000020 Nitrocellulose Substances 0.000 description 2
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 150000004645 aluminates Chemical class 0.000 description 2
- 229910052810 boron oxide Inorganic materials 0.000 description 2
- 150000001642 boronic acid derivatives Chemical class 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 2
- 238000000578 dry spinning Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920001220 nitrocellulos Polymers 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 2
- 229960001763 zinc sulfate Drugs 0.000 description 2
- 229910000368 zinc sulfate Inorganic materials 0.000 description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 241001085205 Prenanthella exigua Species 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- UGZICOVULPINFH-UHFFFAOYSA-N acetic acid;butanoic acid Chemical class CC(O)=O.CCCC(O)=O UGZICOVULPINFH-UHFFFAOYSA-N 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 239000011260 aqueous acid Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 150000004648 butanoic acid derivatives Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000005007 epoxy-phenolic resin Substances 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000005350 fused silica glass Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000011491 glass wool Substances 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 229910001387 inorganic aluminate Inorganic materials 0.000 description 1
- 229910052909 inorganic silicate Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000011490 mineral wool Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- XJKVPKYVPCWHFO-UHFFFAOYSA-N silicon;hydrate Chemical compound O.[Si] XJKVPKYVPCWHFO-UHFFFAOYSA-N 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
- D01F2/08—Composition of the spinning solution or the bath
- D01F2/10—Addition to the spinning solution or spinning bath of substances which exert their effect equally well in either
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C13/00—Fibre or filament compositions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/62227—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products obtaining fibres
- C04B35/62231—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products obtaining fibres based on oxide ceramics
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/62227—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products obtaining fibres
- C04B35/62231—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products obtaining fibres based on oxide ceramics
- C04B35/6224—Fibres based on silica
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Structural Engineering (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US21313862A | 1962-07-30 | 1962-07-30 | |
GB4183366A GB1155292A (en) | 1962-07-30 | 1966-09-20 | A Method of Making Sinterable and Sintered Shaped Structures and Structures Made Thereby. |
Publications (1)
Publication Number | Publication Date |
---|---|
AT266297B true AT266297B (de) | 1968-11-11 |
Family
ID=31948078
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT471663A AT266297B (de) | 1962-07-30 | 1963-06-11 | Verfahren zur Herstellung eines Formgebildes, z.B. eines Fadens |
Country Status (6)
Country | Link |
---|---|
AT (1) | AT266297B (en, 2012) |
BE (1) | BE633357A (en, 2012) |
DE (1) | DE1289944B (en, 2012) |
FR (1) | FR1364238A (en, 2012) |
GB (2) | GB1064271A (en, 2012) |
NL (1) | NL293694A (en, 2012) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT384628B (de) * | 1982-05-17 | 1987-12-10 | Chemiefaser Lenzing Ag | Cellulosefasern, insbesondere fuer die herstellung von vliesen und verfahren zur herstellung der fasern |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1287288A (en) * | 1968-12-27 | 1972-08-31 | Universal Oil Prod Co | Refractory inorganic oxide fibers |
JPS5777044A (en) * | 1980-10-30 | 1982-05-14 | Central Glass Co Ltd | Manufacture of glass from metallic alcoholate |
FI91778C (fi) * | 1991-12-31 | 1994-08-10 | Kemira Fibres Oy | Piidioksidia sisältävä tuote ja menetelmä sen valmistamiseksi |
US6344167B1 (en) | 1994-02-18 | 2002-02-05 | Basf Corporation | Process for the production of superconductor containing filaments |
FI97104C (fi) * | 1994-06-03 | 1996-10-25 | Carefibres Oy | Ihon- tai hiustenhoitotuote |
US6248696B1 (en) | 1994-07-15 | 2001-06-19 | Basf Corporation | 7-forming, superconducting filaments through bicomponent dry spinning |
AT401656B (de) * | 1994-11-07 | 1996-11-25 | Chemiefaser Lenzing Ag | Flammfestes nicht gewebtes textiles gebilde |
US5766746A (en) * | 1994-11-07 | 1998-06-16 | Lenzing Aktiengesellschaft | Flame retardant non-woven textile article |
FI97630C (fi) * | 1995-02-23 | 1997-01-27 | Carefibres Oy | Kuitumateriaali ja menetelmä sen valmistamiseksi |
CN100385051C (zh) * | 2003-01-24 | 2008-04-30 | 中国科学院上海硅酸盐研究所 | 注射成型氧化锆制品的制作方法 |
US7229937B2 (en) | 2004-03-23 | 2007-06-12 | E. I. Du Pont De Nemours And Company | Reinforced nonwoven fire blocking fabric, method for making such fabric, and articles fire blocked therewith |
FI119327B (fi) | 2004-06-02 | 2008-10-15 | Sateri Internat Co Ltd | Menetelmä silikaattipitoisen kuidun valmistamiseksi |
US20050284595A1 (en) * | 2004-06-25 | 2005-12-29 | Conley Jill A | Cellulosic and para-aramid pulp and processes of making same |
US7247585B2 (en) | 2004-11-23 | 2007-07-24 | E.I. Du Pont De Nemours And Company | Reinforced nonwoven fire blocking fabric having ridges and grooves and articles fire blocked therewith |
US7226877B2 (en) | 2004-12-27 | 2007-06-05 | E. I. Du Pont De Nemours And Company | Liquid water impermeable reinforced nonwoven fire blocking fabric, method for making such fabric, and articles fire blocked therewith |
CN101248225B (zh) | 2005-08-26 | 2011-02-09 | 大和纺织株式会社 | 防燃性人造丝纤维及其制造方法 |
US7651590B2 (en) | 2006-03-03 | 2010-01-26 | Birla Research Institute For Applied Sciences | Flame retardant and glow resistant zinc free cellulose product |
EP2463412A4 (en) | 2009-12-28 | 2013-11-13 | Daiwabo Holdings Co Ltd | FLAME RETARDANT FIBER, METHOD FOR PRODUCING SAME, AND FIRE RETARDANT FIBER STRUCTURE |
CN108035004B (zh) * | 2017-11-20 | 2021-02-02 | 河北吉藁化纤有限责任公司 | 一种阻燃粘胶纤维及其制备方法 |
CN109537096A (zh) * | 2018-12-09 | 2019-03-29 | 合肥英士博户外用品科技有限公司 | 一种纤维纺丝液 |
CN114369878B (zh) * | 2021-11-19 | 2023-06-02 | 东华大学 | 一种柔性陶瓷纳米纤维规模化连续制造装置 |
CN117585983B (zh) * | 2024-01-19 | 2024-03-26 | 内蒙古农业大学 | 一种纤维状纤维素增强氯化钠耐热盐砖的制备方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT185496B (de) * | 1952-10-21 | 1956-05-11 | Degussa | Verfahren zur Herstellung von künstlichen Faserstoffen |
-
0
- BE BE633357D patent/BE633357A/xx unknown
- NL NL293694D patent/NL293694A/xx unknown
-
1963
- 1963-05-31 FR FR936791A patent/FR1364238A/fr not_active Expired
- 1963-06-08 DE DE1963A0043294 patent/DE1289944B/de active Pending
- 1963-06-11 AT AT471663A patent/AT266297B/de active
- 1963-07-30 GB GB2021763A patent/GB1064271A/en not_active Expired
-
1966
- 1966-09-20 GB GB4183366A patent/GB1155292A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT384628B (de) * | 1982-05-17 | 1987-12-10 | Chemiefaser Lenzing Ag | Cellulosefasern, insbesondere fuer die herstellung von vliesen und verfahren zur herstellung der fasern |
Also Published As
Publication number | Publication date |
---|---|
FR1364238A (fr) | 1964-06-19 |
GB1064271A (en) | 1967-04-05 |
GB1155292A (en) | 1969-06-18 |
BE633357A (en, 2012) | |
DE1289944B (de) | 1969-02-27 |
NL293694A (en, 2012) |
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