AR102939A1 - 3-oxo-3-(arilamino)propanoatos, proceso para prepararlos, y su uso para preparar pirrolidinonas - Google Patents
3-oxo-3-(arilamino)propanoatos, proceso para prepararlos, y su uso para preparar pirrolidinonasInfo
- Publication number
- AR102939A1 AR102939A1 ARP150103996A ARP150103996A AR102939A1 AR 102939 A1 AR102939 A1 AR 102939A1 AR P150103996 A ARP150103996 A AR P150103996A AR P150103996 A ARP150103996 A AR P150103996A AR 102939 A1 AR102939 A1 AR 102939A1
- Authority
- AR
- Argentina
- Prior art keywords
- ring
- annular
- independently selected
- atoms
- members
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B31/00—Reduction in general
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C233/00—Carboxylic acid amides
- C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
- C07C233/02—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
- C07C233/04—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with carbon atoms of carboxamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
- C07C233/07—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with carbon atoms of carboxamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C233/00—Carboxylic acid amides
- C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
- C07C233/12—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by halogen atoms or by nitro or nitroso groups
- C07C233/15—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by halogen atoms or by nitro or nitroso groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by a carbon atom of a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/18—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
- C07D207/22—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D207/24—Oxygen or sulfur atoms
- C07D207/26—2-Pyrrolidones
- C07D207/263—2-Pyrrolidones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms
- C07D207/27—2-Pyrrolidones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms with substituted hydrocarbon radicals directly attached to the ring nitrogen atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/18—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
- C07D207/22—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D207/24—Oxygen or sulfur atoms
- C07D207/26—2-Pyrrolidones
- C07D207/273—2-Pyrrolidones with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to other ring carbon atoms
- C07D207/277—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Pyrrole Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
Abstract
Reivindicación 1: Un compuesto seleccionado de la fórmula (1) y sales de estos, en donde: Q¹ es un anillo de fenilo o un sistema anular de naftalenilo; cada anillo o sistema anular esta sustituido, opcionalmente, con hasta 5 sustituyentes seleccionados independientemente de R¹; o un anillo heterocíclico completamente insaturado de 5 a 6 miembros o un sistema anular bicíclico heteroaromático de 8 a 10 miembros, cada anillo o sistema anular contiene miembros anulares seleccionados de átomos de carbono y 1 a 4 heteroátomos seleccionados independientemente de hasta 2 átomos de O, hasta 2 átomos de S y hasta 4 átomos de N, en donde hasta 3 miembros anulares de carbono se seleccionan independientemente de C(=O) y C(=S), y los miembros anulares de átomo de azufre se seleccionan, independientemente, de S(=O)ᵘ(=NR²)ᵛ, cada anillo o sistema anular se sustituye, opcionalmente, con hasta 5 sustituyentes seleccionados independientemente de R¹ en miembros anulares de átomos de carbono y seleccionados de R³ en miembros anulares de átomos de nitrógeno; Q² es un anillo de fenilo o un sistema anular de naftalenilo; cada anillo o sistema anular está sustituido, opcionalmente, con hasta 5 sustituyentes seleccionados independientemente de R⁴; o un anillo heterocíclico completamente insaturado de 5 a 6 miembros o un sistema anular bicíclico heteroaromático de 8 a 10 miembros, cada anillo o sistema anular contiene miembros anulares seleccionados de átomos de carbono y 1 a 4 heteroátomos seleccionados independientemente de hasta 2 átomos de O, hasta 2 átomos de S y hasta 4 átomos de N, en donde hasta 3 miembros anulares de carbono se seleccionan independientemente de C(=O) y C(=S), y los miembros anulares de átomo de azufre se seleccionan independientemente de S(=O)ᵘ(=NR²)ᵛ, cada anillo o sistema anular se sustituye, opcionalmente, con hasta 5 sustituyentes seleccionados independientemente de R⁴ en miembros anulares de átomos de carbono y seleccionados de R⁵ en miembros anulares de átomos de nitrógeno; R es alquilo o fenilo C₁₋₈; cada R¹ y R⁴ es independientemente halógeno, ciano, nitro, alquilo C₁₋₈, haloalquilo C₁₋₈, nitroalquilo C₁₋₈, alquenilo C₂₋₈, haloalquenilo C₂₋₈, haloalcoxialcoxi C₂₋₈, nitroalquenilo C₂₋₈, alquinilo C₂₋₈, haloalquinilo C₂₋₈, cicloalquilalquilo C₄₋₁₀, halocicloalquilalquilo C₄₋₁₀, alquilcicloalquilalquilo C₅₋₁₂, cicloalquilalquenilo C₅₋₁₂, cicloalquilalquinilo C₅₋₁₂, cicloalquilo C₃₋₈, halocicloalquilo C₃₋₈, alquilcicloalquilo C₄₋₁₀, cicloalquilcicloalquilo C₆₋₁₂, cicloalquenilo C₃₋₈, halocicloalquenilo C₃₋₈, alcoxialquilo C₂₋₈, haloalcoxialquilo C₂₋₈, cicloalcoxialquilo C₄₋₁₀, alcoxialcoxialquilo C₃₋₁₀, alquiltioalquilo C₂₋₈, alquilsulfinilalquilo C₂₋₈, alquilsulfonilalquilo C₂₋₈, alquilaminoalquilo C₂₋₈, haloalquilaminoalquilo C₂₋₈, cicloalquilaminoalquilo C₄₋₁₀, dialquilaminoalquilo C₃₋₁₀, -CHO, alquilcarbonilo C₂₋₈, haloalquilcarbonilo C₂₋₈, cicloalquilcarbonilo C₄₋₁₀, -C(=O)OH, alcoxicarbonilo C₂₋₈, haloalcoxicarbonilo C₂₋₈, cicloalcoxicarbonilo C₄₋₁₀, cicloalquilalcoxicarbonilo C₅₋₁₂, -C(=O)NH₂, alquilaminocarbonilo C₂₋₈, cicloalquilaminocarbonilo C₄₋₁₀, dialquilaminocarbonilo C₃₋₁₀, alcoxi C₁₋₈, haloalcoxi C₁₋₈, alcoxialcoxi C₂₋₈, alqueniloxi C₂₋₈, haloalqueniloxi C₂₋₈, alquiniloxi C₃₋₈, haloalquiniloxi C₃₋₈, cicloalcoxi C₃₋₈, halocicloalcoxi C₃₋₈, cicloalquilalcoxi C₄₋₁₀, alquilcarbonilalcoxi C₃₋₁₀, alquilcarboniloxi C₂₋₈, haloalquilcarboniloxi C₂₋₈, cicloalquilcarboniloxi C₄₋₁₀, alquilsulfoniloxi C₁₋₈, haloalquilsulfoniloxi C₁₋₈, alquiltio C₁₋₈, haloalquiltio C₁₋₈, cicloalquiltio C₃₋₈, alquilsulfinilo C₁₋₈, haloalquilsulfinilo C₁₋₈, alquilsulfonilo C₁₋₈, haloalquilsulfonilo C₁₋₈, cicloalquilsulfonilo C₃₋₈, formilamina, alquilcarbonilamina C₂₋₈, haloalquilcarbonilamina C₂₋₈, alcoxicarbonilamina C₂₋₈, alquilsulfonilamina de C₁₋₆, haloalquilsulfonilamina de C₁₋₆, -SF₅, -SCN, trialquilsililo C₃₋₁₂, trialquilsililalquilo C₄₋₁₂ o trialquilsililalcoxi C₄₋₁₂; cada R² es independientemente H, ciano, alquilcarbonilo C₂₋₃ o haloalquilcarbonilo C₂₋₃; cada R³ y R⁵ es independientemente ciano, alquilo C₁₋₃, alquenilo C₂₋₃, alquinilo C₂₋₃, cicloalquilo C₃₋₆, alcoxialquilo C₂₋₃, alcoxi C₁₋₃, alquilcarbonilo C₂₋₃, alcoxicarbonilo C₂₋₃, alquilaminoalquilo C₂₋₃, dialquilaminoalquilo C₃₋₄ o haloalquilo C₂₋₃; y cada u y v es independientemente 0, 1 ó 2 en cada instancia de S(=O)ᵘ(=NR²)ᵛ, siempre que la suma de u y v sea 0, 1 ó 2. Reivindicación 16: Un método para preparar un compuesto de la fórmula (2) que comprende ciclar reductivamente un compuesto de la fórmula (1) en presencia de un agente reductor.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201462088971P | 2014-12-08 | 2014-12-08 |
Publications (1)
Publication Number | Publication Date |
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AR102939A1 true AR102939A1 (es) | 2017-04-05 |
Family
ID=54782892
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP150103996A AR102939A1 (es) | 2014-12-08 | 2015-12-04 | 3-oxo-3-(arilamino)propanoatos, proceso para prepararlos, y su uso para preparar pirrolidinonas |
Country Status (17)
Country | Link |
---|---|
US (1) | US10227286B2 (es) |
EP (1) | EP3230264B1 (es) |
JP (1) | JP6611816B2 (es) |
KR (1) | KR102542215B1 (es) |
CN (1) | CN107001260B (es) |
AR (1) | AR102939A1 (es) |
AU (1) | AU2015361018B2 (es) |
BR (1) | BR112017009701B1 (es) |
ES (1) | ES2759267T3 (es) |
HU (1) | HUE047582T2 (es) |
IL (1) | IL252637A (es) |
MX (1) | MX2017007087A (es) |
PL (1) | PL3230264T3 (es) |
RU (1) | RU2712831C2 (es) |
SG (1) | SG11201702924WA (es) |
TW (1) | TWI694982B (es) |
WO (1) | WO2016094117A1 (es) |
Families Citing this family (20)
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EA201691156A1 (ru) | 2013-12-03 | 2017-04-28 | Е.И.Дюпон Де Немур Энд Компани | Пирролидиноновые гербициды |
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CN107592862B (zh) | 2015-05-12 | 2021-06-15 | Fmc公司 | 作为除草剂的芳基取代的双环化合物 |
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AR111967A1 (es) | 2017-05-30 | 2019-09-04 | Fmc Corp | Amidas herbicidas |
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BR112021016003A2 (pt) | 2019-02-15 | 2021-11-09 | Syngenta Crop Protection Ag | Composições herbicidas |
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CN110312712B (zh) | 2016-12-21 | 2023-06-23 | Fmc公司 | 硝酮除草剂 |
CN110740646B (zh) | 2017-03-21 | 2022-05-10 | Fmc公司 | 除草剂混合物、组合物和方法 |
KR102620213B1 (ko) | 2017-03-21 | 2024-01-03 | 에프엠씨 코포레이션 | 피롤리디논 및 이의 제조 방법 |
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TWI694982B (zh) | 2020-06-01 |
KR102542215B1 (ko) | 2023-06-12 |
TW201632497A (zh) | 2016-09-16 |
RU2017123114A3 (es) | 2019-07-17 |
BR112017009701A2 (pt) | 2018-02-20 |
ES2759267T3 (es) | 2020-05-08 |
BR112017009701B1 (pt) | 2021-09-08 |
HUE047582T2 (hu) | 2020-05-28 |
US20180057442A1 (en) | 2018-03-01 |
AU2015361018A1 (en) | 2017-04-27 |
RU2712831C2 (ru) | 2020-02-03 |
US10227286B2 (en) | 2019-03-12 |
EP3230264B1 (en) | 2019-09-11 |
IL252637A (en) | 2017-11-30 |
AU2015361018B2 (en) | 2020-01-16 |
RU2017123114A (ru) | 2019-01-11 |
IL252637A0 (en) | 2017-07-31 |
CN107001260B (zh) | 2020-11-10 |
EP3230264A1 (en) | 2017-10-18 |
KR20170090491A (ko) | 2017-08-07 |
JP2017538785A (ja) | 2017-12-28 |
WO2016094117A1 (en) | 2016-06-16 |
CN107001260A (zh) | 2017-08-01 |
SG11201702924WA (en) | 2017-05-30 |
JP6611816B2 (ja) | 2019-11-27 |
PL3230264T3 (pl) | 2020-03-31 |
MX2017007087A (es) | 2017-09-05 |
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