AR104618A1 - Herbicidas derivados de compuestos bicíclicos sustituidos con arilo - Google Patents

Herbicidas derivados de compuestos bicíclicos sustituidos con arilo

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AR104618A1
AR104618A1 ARP160101388A ARP160101388A AR104618A1 AR 104618 A1 AR104618 A1 AR 104618A1 AR P160101388 A ARP160101388 A AR P160101388A AR P160101388 A ARP160101388 A AR P160101388A AR 104618 A1 AR104618 A1 AR 104618A1
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Argentina
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alkyl
ring
independently
cycloalkyl
alkoxy
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ARP160101388A
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English (en)
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Duncan Satterfield Andrew
Martin Stevenson Thomas
James Campbell Matthew
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Du Pont
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
    • A01N43/52—1,3-Diazoles; Hydrogenated 1,3-diazoles condensed with carbocyclic rings, e.g. benzimidazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/49—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by carboxyl groups
    • C07C205/50—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by carboxyl groups having nitro groups and carboxyl groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C205/53—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by carboxyl groups having nitro groups and carboxyl groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D487/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
    • C07D487/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
    • C07D487/04—Ortho-condensed systems
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/18—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
    • C07D207/22—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D207/24—Oxygen or sulfur atoms
    • C07D207/26—2-Pyrrolidones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/18—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
    • C07D207/22—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D207/24—Oxygen or sulfur atoms
    • C07D207/26—2-Pyrrolidones
    • C07D207/273—2-Pyrrolidones with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to other ring carbon atoms
    • C07D207/277—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals

Abstract

Reivindicación 1: Un compuesto seleccionado de la fórmula (1), N-óxidos, estereoisómeros y sales de estos, en donde Q¹ es un anillo fenilo o bencilo, o un sistema de anillo naftalenilo; cada anillo o sistema de anillo está sustituido opcionalmente con hasta 5 sustituyentes seleccionados independientemente de R⁹; o un anillo heteroaromático completamente insaturado de 5 a 6 miembros o un sistema de anillo bicíclico heteroaromático de 8 a 10 miembros; cada anillo o sistema de anillo contiene miembros de anillo seleccionados de átomos de carbono y de 1 a 4 heteroátomos seleccionados independientemente de hasta 2 átomos de O, hasta 2 átomos de S y hasta 4 átomos de N, en donde hasta 3 miembros de anillo que son carbono se seleccionan independientemente de C(=O) y C(=S), y los miembros de anillo que son átomos de azufre se seleccionan independientemente de S(=O)ᵘ(=NR⁸)ᵛ; cada anillo o sistema de anillo está sustituido opcionalmente con hasta 5 sustituyentes seleccionados independientemente de R⁹ en miembros de anillo que son átomos de carbono y seleccionados de R¹⁰ en miembros de anillo que son átomos de nitrógeno; Q² es un anillo fenilo o un sistema de anillo naftalenilo; cada anillo o sistema de anillo está sustituido opcionalmente con hasta 5 sustituyentes seleccionados independientemente de R¹¹; o un anillo heteroaromático completamente insaturado de 5 a 6 miembros o un sistema de anillo bicíclico heteroaromático de 8 a 10 miembros; cada anillo o sistema de anillo contiene miembros de anillo seleccionados de átomos de carbono y de 1 a 4 heteroátomos seleccionados independientemente de hasta 2 átomos de O, hasta 2 átomos de S y hasta 4 átomos de N, en donde hasta 3 miembros de anillo que son carbono se seleccionan independientemente de C(=O) y C(=S), y los miembros de anillo que son átomos de azufre se seleccionan independientemente de S(=O)ᵘ(=NR⁸)ᵛ; cada anillo o sistema de anillo está sustituido opcionalmente con hasta 5 sustituyentes seleccionados independientemente de R¹¹ en miembros de anillo que son átomos de carbono y seleccionados de R¹² en miembros de anillo que son átomos de nitrógeno; R¹ y R² son, cada uno independientemente H, halógeno, hidroxilo o alquilo C₁₋₄; Y es O, S o NR¹⁵; A es una cadena saturada, parcialmente insaturada o completamente insaturada que contiene de 2 a 4 átomos seleccionados de hasta 4 átomos de carbono, hasta 1 átomo de O, hasta 1 átomo de S y hasta 2 átomos de N, en donde hasta 2 miembros de carbono se seleccionan independientemente de C(=O) y C(=S) y el miembro de átomo de azufre se selecciona de S(=O)ᵘ(=NR⁸)ᵛ; esa cadena está sustituida opcionalmente con hasta 5 sustituyentes seleccionados independientemente de R³ en átomos de carbono y R⁴ en átomos de nitrógeno; cada R³ es independientemente halógeno, ciano, hidroxilo, -CO₂H, alquilo C₁₋₄, haloalquilo C₁₋₄, alcoxi C₁₋₄, alquiltio C₁₋₄, haloalcoxi C₁₋₄, alcoxialquilo C₂₋₄, alquilcarbonilo C₂₋₄, alcoxicarbonilo C₂₋₄, cicloalquilo C₃₋₆ o cicloalquilalquilo C₄₋₆; o dos R³ adyacentes se consideran en conjunto con el o los átomos de carbono a los cuales están unidos para formar un anillo cicloalquilo C₃₋₇; cada R⁴ es independientemente ciano, alquilo C₁₋₄, haloalquilo C₁₋₄, alcoxi C₁₋₄, alquilcarbonilo C₂₋₄, alcoxicarbonilo C₂₋₄ o cicloalquilo C₃₋₆; J es -CR⁵R⁶- o -CR⁵R⁶-CR⁵ᵃR⁶ᵃ-, en donde la entidad -CR⁵R⁶- está conectada directamente al N; R⁵ y R⁶ son, cada uno independientemente H, halógeno, hidroxilo, alquilo C₁₋₄ o alcoxi C₁₋₄; o R⁵ y R⁶ se consideran en conjunto con el átomo de carbono al cual están unidos para formar un anillo cicloalquilo C₃₋₇; R⁵ᵃ y R⁶ᵃ son, cada uno independientemente H, halógeno o alquilo C₁₋₄; o R⁵ᵃ y R⁶ᵃ se consideran en conjunto con el átomo de carbono al cual están unidos para formar un anillo cicloalquilo C₃₋₇; R⁷ es H, hidroxilo, amino, alquilo C₁₋₆, haloalquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₃₋₆, alcoxialquilo C₂₋₈, haloalcoxialquilo C₂₋₈, alquiltioalquilo C₂₋₈, alquilsulfinilalquilo C₂₋₈, alquilsulfonilalquilo C₂₋₈, alquilcarbonilo C₂₋₈, haloalquilcarbonilo C₂₋₈, cicloalquilcarbonilo C₄₋₁₀, alcoxicarbonilo C₂₋₈, haloalcoxicarbonilo C₂₋₈, cicloalcoxicarbonilo C₄₋₁₀, alquilaminocarbonilo C₂₋₈, dialquilaminocarbonilo C₃₋₁₀, cicloalquilaminocarbonilo C₄₋₁₀, alcoxi C₁₋₆, alquiltio C₁₋₆, haloalquiltio C₁₋₆, cicloalquiltio C₃₋₈, alquilsulfinilo C₁₋₆, haloalquilsulfinilo C₁₋₆, cicloalquilsulfinilo C₃₋₈, alquilsulfonilo C₁₋₆, haloalquilsulfonilo C₁₋₆, cicloalquilsulfonilo C₃₋₈, alquilaminosulfonilo C₁₋₆, dialquilaminosulfonilo C₂₋₈, trialquilsililo C₃₋₁₀ o G¹; cada R⁸ es independientemente H, ciano, alquilcarbonilo C₂₋₃ o haloalquilcarbonilo C₂₋₃; cada R⁹ es independientemente halógeno, ciano, nitro, alquilo C₁₋₈, cianoalquilo C₁₋₄, cianoalcoxi C₁₋₄, haloalquilo C₁₋₈, nitroalquilo C₁₋₈, alquenilo C₂₋₈, haloalquenilo C₂₋₈, nitroalquenilo C₂₋₈, alquinilo C₂₋₈, haloalquinilo C₂₋₈, cicloalquilalquilo C₄₋₁₀, halocicloalquilalquilo C₄₋₁₀, alquilcicloalquilalquilo C₅₋₁₂, cicloalquilalquenilo C₅₋₁₂, cicloalquilalquinilo C₅₋₁₂, cicloalquilo C₃₋₈, halocicloalquilo C₃₋₈, alquilcicloalquilo C₄₋₁₀, cicloalquilcicloalquilo C₆₋₁₂, cicloalquenilo C₃₋₈, halocicloalquenilo C₃₋₈, alcoxialquilo C₂₋₈, haloalcoxialquilo C₂₋₈, haloalcoxialcoxi C₃₋₈, hidroxialquilo C₁₋₄, cicloalcoxialquilo C₄₋₁₀, alcoxialcoxialquilo C₃₋₁₀, alquiltioalquilo C₂₋₈, alquilsulfinilalquilo C₂₋₈, alquilsulfonilalquilo C₂₋₈, alquilaminoalquilo C₂₋₈, haloalquilaminoalquilo C₂₋₈, cicloalquilaminoalquilo C₄₋₁₀, dialquilaminoalquilo C₃₋₁₀, -CHO, alquilcarbonilo C₂₋₈, haloalquilcarbonilo C₂₋₈, cicloalquilcarbonilo C₄₋₁₀, -C(=O)OH, alcoxicarbonilo C₂₋₈, haloalcoxicarbonilo C₂₋₈, cicloalcoxicarbonilo C₄₋₁₀, cicloalquilalcoxicarbonilo C₅₋₁₂, -C(=O)NH₂, alquilaminocarbonilo C₂₋₈, cicloalquilaminecarbonilo C₄₋₁₀, dialquilaminocarbonilo C₃₋₁₀, alcoxi C₁₋₈, haloalcoxi C₁₋₈, alcoxialcoxi C₂₋₈, alqueniloxilo C₂₋₈, haloalqueniloxilo C₂₋₈, haloalcoxihaloalcoxi C₂₋₈, alquiniloxilo C₃₋₈, haloalquiniloxilo C₃₋₈, cicloalcoxi C₃₋₈, halocicloalcoxi C₃₋₈, cicloalquilalcoxi C₄₋₁₀, alquilcarbonilalcoxi C₃₋₁₀, alquilcarboniloxilo C₂₋₈, haloalquilcarboniloxilo C₂₋₈, cicloalquilcarboniloxilo C₄₋₁₀, alquilsulfoniloxilo C₁₋₈, haloalquilsulfoniloxilo C₁₋₈, alquiltio C₁₋₈, haloalquiltio C₁₋₈, cicloalquiltio C₃₋₈, alquilsulfinilo C₁₋₈, haloalquilsulfinilo C₁₋₈, alquilsulfonilo C₁₋₈, haloalquilsulfonilo C₁₋₈, cicloalquilsulfonilo C₃₋₈, formilamino, alquilcarbonilamino C₂₋₈, haloalquilcarbonilamino C₂₋₈, alcoxicarbonilamino C₂₋₈, alquilsulfonilamino C₁₋₆, haloalquilsulfonilamino C₁₋₆, -SF₅, -SCN, SO₂NH₂, trialquilsililo C₃₋₁₂, trialquilsililalquilo C₄₋₁₂, trialquilamialcoxi C₄₋₁₂ o G²; cada R¹¹ es independientemente halógeno, ciano, nitro, alquilo C₁₋₈, cianoalquilo C₁₋₄, cianoalcoxi C₁₋₄, haloalquilo C₁₋₈, nitroalquilo C₁₋₈, alquenilo C₂₋₈, haloalquenilo C₂₋₈, nitroalquenilo C₂₋₈, alquinilo C₂₋₈, haloalquinilo C₂₋₈, cicloalquilalquilo C₄₋₁₀, halocicloalquilalquilo C₄₋₁₀, alquilcicloalquilalquilo C₅₋₁₂, cicloalquilalquenilo C₅₋₁₂, cicloalquilalquinilo C₅₋₁₂, cicloalquilo C₃₋₈, halocicloalquilo C₃₋₈, alquilcicloalquilo C₄₋₁₀, cicloalquilcicloalquilo C₆₋₁₂, cicloalquenilo C₃₋₈, halocicloalquenilo C₃₋₈, alcoxialquilo C₂₋₈, haloalcoxialquilo C₂₋₈, haloalcoxialalcoxialquilo C₃₋₈, hidroxialquilo C₁₋₄, cicloalcoxialquilo C₄₋₁₀, alcoxialcoxialquilo C₃₋₁₀, alquiltioalquilo C₂₋₈, alquilsulfinilalquilo C₂₋₈, alquilsulfonilalquilo C₂₋₈, alquilaminoalquilo C₂₋₈, haloalquilaminoalquilo C₂₋₈, cicloalquilaminoalquilo C₄₋₁₀, dialquilaminoalquilo C₃₋₁₀, -CHO, alquilcarbonilo C₂₋₈, haloalquilcarbonilo C₂₋₈, cicloalquilcarbonilo C₄₋₁₀, -C(=O)OH, alcoxicarbonilo C₂₋₈, haloalcoxicarbonilo C₂₋₈, cicloalcoxicarbonilo C₄₋₁₀, cicloalquilalcoxicarbonilo C₅₋₁₂, -C(=O)NH₂, alquilaminocarbonilo C₂₋₈, cicloalquilaminocarbonilo C₄₋₁₀, dialquilaminocarbonilo C₃₋₁₀, alcoxi C₁₋₈, haloalcoxi C₁₋₈, alcoxialcoxi C₂₋₈, alqueniloxilo C₂₋₈, haloalqueniloxilo C₂₋₈, haloalcoxihaloalcoxi C₂₋₈, alquiniloxilo C₃₋₈, haloalquiniloxilo C₃₋₈, cicloalcoxi C₃₋₈, halocicloalcoxi C₃₋₈, cicloalquilalcoxi C₄₋₁₀, alquilcarbonilalcoxi C₃₋₁₀, alquilcarboniloxilo C₂₋₈, haloalquilcarboniloxilo C₂₋₈, cicloalquilcarboniloxilo C₄₋₁₀, alquilsulfoniloxilo C₁₋₈, haloalquilsulfoniloxilo C₁₋₈, alquiltio C₁₋₈, haloalquiltio C₁₋₈, cicloalquiltio C₃₋₈, alquilsulfinilo C₁₋₈, haloalquilsulfinilo C₁₋₈, alquilsulfonilo C₁₋₈, haloalquilsulfonilo C₁₋₈, cicloalquilsulfonilo C₃₋₈, formilamino, alquilcarbonilamino C₂₋₈, haloalquilcarbonilamino C₂₋₈, alcoxicarbonilamino C₂₋₈, alquilsulfonilamino C₁₋₆, haloalquilsulfonilamino C₁₋₆, -SF₅, -SCN, SO₂NH₂, trialquilsililo C₃₋₁₂, trialquilsililalquilo C₄₋₁₂, trialquilsililalcoxi C₄₋₁₂ o G³; cada R¹⁰ y R¹² es independientemente ciano, alquilo C₁₋₃, alquenilo C₂₋₃, alquinilo C₂₋₃, cicloalquilo C₃₋₆, alcoxialquilo C₂₋₃, alcoxi C₁₋₃, alquilcarbonilo C₂₋₃, alcoxicarbonilo C₂₋₃, alquilaminoalquilo C₂₋₃ o dialquilaminoalquilo C₃₋₄; R¹⁵ es H, ciano, alquilo C₁₋₄, haloalquilo C₁₋₄, (C=O)CH₃ o -(C=O)CF₃; cada G¹ es independientemente fenilo, fenilmetilo, piridinilmetilo, piridiniloxilo, fenilcarbonilo, fenoxilo, feniletinilo, fenilsulfonilo, fenilcarbonilo(alquilo C₁₋₄); o un anillo heteroaromático de 5 ó 6 miembros, cada uno sustituido opcionalmente en miembros de anillo con hasta 5 sustituyentes seleccionados independientemente de R¹³; cada G² es independientemente fenilo, fenilmetilo, piridinilmetilo, fenilcarbonilo, fenilcarbonilalquilo, fenoxilo, feniletinilo, fenilsulfonilo o piridiloxilo; o un anillo heteroaromático de 5 ó 6 miembros, cada uno sustituido opcionalmente en miembros de anillo con hasta 5 sustituyentes seleccionados independientemente de R¹⁴; o R¹⁶ON=CR¹⁷-, (R¹⁸)₂C=NO-, (R¹⁹)₂NN=CR¹⁷-, (R¹⁸)₂C=NNR²⁰-, R²¹N=CR¹⁷-, (R¹⁸)₂C=N-, R²²ON=CR¹⁷C(R²³)₂- o (R¹⁸)₂C=NOC(R²³)₂-, en donde el enlace libre que se proyecta hacia la derecha indica el punto de conexión a Q¹; cada G³ es independientemente fenilo, fenilmetilo, piridinilmetilo, fenilcarbonilo, fenilcarbonilalquilo, fenoxilo, feniletinilo, fenilsulfonilo o piridiloxilo; o un anillo heteroaromático de 5 ó 6 miembros, cada uno sustituido opcionalmente en miembros de anillo con hasta 5 sustituyentes seleccionados independientemente de R¹⁵; cada R¹³, R¹⁴ y R¹⁵ es independientemente halógeno, ciano, hidroxilo, amino, nitro, -CHO, -C(=O)OH, -C(=O)NH₂, -SO₂NH₂, alquilo C₁₋₆, haloalquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, alquilcarbonilo C₂₋₈, haloalquilcarbonilo C₂₋₈, alcoxicarbonilo C₂₋₈, cicloalcoxicarbonilo C₄₋₁₀, cicloalquilalcoxicarbonilo C₅₋₁₂, alquilaminocarbonilo C₂₋₈, dialquilaminocarbonilo C₃₋₁₀, alcoxi C₁₋₆, haloalcoxi C₁₋₆, alquilcarboniloxilo C₂₋₈, alquiltio C₁₋₆, haloalquiltio C₁₋₆, alquilsulfinilo C₁₋₆, haloalquilsulfinilo C₁₋₆, alquilsulfonilo C₁₋₆, haloalquilsulfonilo C₁₋₆, alquilaminosulfonilo C₁₋₆, dialquilaminosulfonilo C₂₋₈, trialquilsililo C₃₋₁₀, alquilamino C₁₋₆, dialquilamino C₂₋₈, alquilcarbonilamino C₂₋₈, alquilsulfonilamino C₁₋₆; cada R¹⁶ es independientemente H, alquilo C₁₋₆, cicloalquilo C₃₋₈, cicloalquilalquilo C₄₋₈, haloalquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₃₋₆, alcoxialquilo C₂₋₈, haloalcoxialquilo C₂₋₈, alquiltioalquilo C₂₋₈, alquilsulfinilalquilo C₂₋₈, alquilsulfonilalquilo C₂₋₈, alquilcarbonilo C₂₋₈, haloalquilcarbonilo C₂₋₈, cicloalquilcarbonilo C₄₋₁₀, alcoxicarbonilo C₂₋₈, haloalcoxicarbonilo C₂₋₈, cicloalcoxicarbonilo C₄₋₁₀, alquilaminocarbonilo C₂₋₈, dialquilaminocarbonilo C₃₋₁₀, cicloalquilaminocarbonilo C₄₋₁₀, alquilsulfinilo C₁₋₆, haloalquilsulfinilo C₁₋₆, cicloalquilsulfinilo C₃₋₈, alquilsulfonilo C₁₋₆, haloalquilsulfonilo C₁₋₆, cicloalquilsulfonilo C₃₋₈, alquilaminosulfonilo C₁₋₆, dialquilaminosulfonilo C₂₋₈, trialquilsililo C₃₋₁₀ o G¹; cada R¹⁷ es independientemente H, alquilo C₁₋₆, cicloalquilo C₃₋₈, cicloalquilalquilo C₄₋₈, haloalquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₃₋₆, alcoxialquilo C₂₋₈, haloalcoxialquilo C₂₋₈, alquiltioalquilo C₂₋₈, alquilsulfinilalquilo C₂₋₈, alquilsulfonilalquilo C₂₋₈, alcoxi C₁₋₆, alquiltio C₁₋₆, haloalquiltio C₁₋₆, cicloalquiltio C₃₋₈, trialquilsililo C₃₋₁₀ o G¹; cada R¹⁸ es independientemente H, hidroxilo, alquilo C₁₋₆, cicloalquilo C₃₋₈, cicloalquilalquilo C₄₋₈, haloalquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₃₋₆, alcoxialquilo C₂₋₈, haloalcoxialquilo C₂₋₈, alquiltioalquilo C₂₋₈, alquilsulfinilalquilo C₂₋₈, alquilsulfonilalquilo C₂₋₈, alquilcarbonilo C₂₋₈, haloalquilcarbonilo C₂₋₈, cicloalquilcarbonilo C₄₋₁₀, alcoxicarbonilo C₂₋₈, haloalcoxicarbonilo C₂₋₈, cicloalcoxicarbonilo C₄₋₁₀, alquilaminocarbonilo C₂₋₈, dialquilaminocarbonilo C₃₋₁₀, cicloalquilaminocarbonilo C₄₋₁₀, alcoxi C₁₋₆, alquiltio C₁₋₆, haloalquiltio C₁₋₆, cicloalquiltio C₃₋₈, alquilsulfinilo C₁₋₆, haloalquilsulfinilo C₁₋₆, cicloalquilsulfinilo C₃₋₈, alquilsulfonilo C₁₋₆, haloalquilsulfonilo C₁₋₆, cicloalquilsulfonilo C₃₋₈, alquilaminosulfonilo C₁₋₆, dialquilaminosulfonilo C₂₋₈, trialquilsililo C₃₋₁₀ o G¹; cada R¹⁹ es independientemente H, alquilo C₁₋₆, cicloalquilo C₃₋₈, cicloalquilalquilo C₄₋₈, haloalquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₃₋₆, alcoxialquilo C₂₋₈, haloalcoxialquilo C₂₋₈, alquiltioalquilo C₂₋₈, alquilsulfinilalquilo C₂₋₈, alquilsulfonilalquilo C₂₋₈, alquilcarbonilo C₂₋₈, haloalquilcarbonilo C₂₋₈, cicloalquilcarbonilo C₄₋₁₀, alcoxicarbonilo C₂₋₈, haloalcoxicarbonilo C₂₋₈, cicloalcoxicarbonilo C₄₋₁₀, alquilaminocarbonilo C₂₋₈, dialquilaminocarbonilo C₃₋₁₀, cicloalquilaminocarbonilo C₄₋₁₀, alcoxi C₁₋₆, alquilsulfinilo C₁₋₆, haloalquilsulfinilo C₁₋₆, cicloalquilsulfinilo C₃₋₈, alquilsulfonilo C₁₋₆, haloalquilsulfonilo C₁₋₆, cicloalquilsulfonilo C₃₋₈, alquilaminosulfonilo C₁₋₆, dialquilaminosulfonilo C₂₋₈, trialquilsililo C₃₋₁₀ o G¹; cada R²⁰ es independientemente H, alquilo C₁₋₆, cicloalquilo C₃₋₈, cicloalquilalquilo C₄₋₈, haloalquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₃₋₆, alcoxialquilo C₂₋₈, haloalcoxialquilo C₂₋₈, alquiltioalquilo C₂₋₈, alquilsulfinilalquilo C₂₋₈, alquilsulfonilalquilo C₂₋₈, alcoxi C₁₋₆, trialquilsililo C₃₋₁₀ o G¹; cada R²¹ es independientemente H, hidroxilo, amino, alquilo C₁₋₆, cicloalquilo C₃₋₈, cicloalquilalquilo C₄₋₈, haloalquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₃₋₆, alcoxialquilo C₂₋₈, haloalcoxialquilo C₂₋₈, alquiltioalquilo C₂₋₈, alquilsulfinilalquilo C₂₋₈, alquilsulfonilalquilo C₂₋₈, alquilcarbonilo C₂₋₈, haloalquilcarbonilo C₂₋₈, cicloalquilcarbonilo C₄₋₁₀, alcoxicarbonilo C₂₋₈, haloalcoxicarbonilo C₂₋₈, cicloalcoxicarbonilo C₄₋₁₀, alquilaminocarbonilo C₂₋₈, dialquilaminocarbonilo C₃₋₁₀, cicloalquilaminocarbonilo C₄₋₁₀, alcoxi C₁₋₆, alquilsulfinilo C₁₋₆, haloalquilsulfinilo C₁₋₆, cicloalquilsulfinilo C₃₋₈, alquilsulfonilo C₁₋₆, haloalquilsulfonilo C₁₋₆, cicloalquilsulfonilo C₃₋₈, alquilaminosulfonilo C₁₋₆, dialquilaminosulfonilo C₂₋₈, trialquilsililo C₃₋₁₀ o G¹; cada R²² es independientemente H, alquilo C₁₋₄, cicloalquilo C₃₋₈, cicloalquilalquilo C₄₋₈, haloalquilo C₁₋₄, alcoxi C₁₋₄, haloalcoxi C₁₋₄, alcoxialquilo C₂₋₄, alquilcarbonilo C₂₋₄, alcoxicarbonilo C₂₋₄ o cicloalquilo C₃₋₆; cada R²³ es independientemente H, halógeno, ciano, hidroxilo, alquilo C₁₋₄, cicloalquilo C₃₋₈, cicloalquilalquilo C₄₋₈, haloalquilo C₁₋₄, alcoxi C₁₋₄, haloalcoxi C₁₋₄, alcoxialquilo C₂₋₄, alquilcarbonilo C₂₋₄, alcoxicarbonilo C₂₋₄ o cicloalquilo C₃₋₈; y cada u y v es independientemente 0, 1 ó 2 en cada instancia de S(=O)ᵘ(=NR⁸)ᵛ, siempre que la suma de u y v sea 0, 1 ó 2; y siempre que el compuesto sea distinto de un compuesto de la fórmula (1), en donde Q¹ es Ph(3-CF₃); Q² es Ph(2-F); R¹ es H; R² es H; Y es O; A es -CH₂CH₂-; J es -CR⁵R⁶-; R⁵ es H; R⁶ es H; y R⁷ es H.
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