AR018146A1 - Masa apropiada como catalizador, procedimiento para la hidrogenacion de alfa, omega-dinitrilos en presencia de dicha masa y uso de dicha masa comocatalizador de hidrogenacion - Google Patents
Masa apropiada como catalizador, procedimiento para la hidrogenacion de alfa, omega-dinitrilos en presencia de dicha masa y uso de dicha masa comocatalizador de hidrogenacionInfo
- Publication number
- AR018146A1 AR018146A1 ARP990100943A ARP990100943A AR018146A1 AR 018146 A1 AR018146 A1 AR 018146A1 AR P990100943 A ARP990100943 A AR P990100943A AR P990100943 A ARP990100943 A AR P990100943A AR 018146 A1 AR018146 A1 AR 018146A1
- Authority
- AR
- Argentina
- Prior art keywords
- omega
- hydrogenation
- alpha
- catalyst
- weight
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/889—Manganese, technetium or rhenium
- B01J23/8892—Manganese
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/44—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers
- C07C209/48—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers by reduction of nitriles
Abstract
Una masa apropiada como catalizador, que contiene: a) hierro o un compuesto a base de hierro o sus mezclas; b) de 0,001 a 0,3% en peso, con respecto a (a),de un promotor a base de 2, 3, 4 o 5 elementos seleccionados del grupo que comprende aluminio,silicio, circonio, titanio, vanadio; c) de 0 a 1% enpeso, con respecto a (a) de un compuesto a base de un metal alcalino y/o un metal alcalinotérreo, así como d) de 0,001 a 0,3% en peso, conrespecto a a), de manganeso. Un procedimiento para la hidrogenacion de alfa, omega-dinitrilos, en presencia de tales masas como catalizador, y al usode tales masas como catalizador en la hidrogenacion de alfa-omega-dinitrilos. Este procedimiento para la hidrogenacion de alfa, omega-dinitrilos (I) NC-(CH2)n-CN, en donde n es un numero entero de 1 hasta 10, opcionalmente 2, 3, 4, 5 y 6; en alfa, omega-aminonitrilos (II) NC-(CH2)n-NH2, en donde ntiene el significado anterior y/o alfa, omega-diaminas (III) H2N-CH2-(CH2)n-CH2-NH2 en donde n tiene el significado anterior; en presencia delcatalizador, así como catalizadores que permitan hidrogenar de manera simple y economica alfa, omega-dinitrilos con alta selectividad, teniendo elcatalizador una larga duracion. Las masas segun la invencion presentan, preferentemente, una superficie BET de 3 hasta 20 m2/g, un volumen de porostotal de 0,05 hasta 0,2 ml/g, un diámetro de poros medio de 0,03 hasta 0,1 micrones y una proporcion en volumen de poros en la region de 0,01 hasta0,1 micrones del 50 hasta 70%.Los porcentajes en peso indicados en (b) y (d) se refieren a los elementos, los porcentajes indicados en (c) a losoxidos de los metales alcalinos y alcalinotérreos. Estas indicaciones se refieren al componente (a). El componente (a) consta en un 90 hasta 100% enpeso, preferentemente en un 92 hasta 99% en peso, con respecto a (a), de oxidos de hierro, hidroxidos de hierro, oxihidroxidos de hierro o sus mezclas.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19809687A DE19809687A1 (de) | 1998-03-06 | 1998-03-06 | Hydrierkatalysator |
Publications (1)
Publication Number | Publication Date |
---|---|
AR018146A1 true AR018146A1 (es) | 2001-10-31 |
Family
ID=7859988
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP990100943A AR018146A1 (es) | 1998-03-06 | 1999-03-05 | Masa apropiada como catalizador, procedimiento para la hidrogenacion de alfa, omega-dinitrilos en presencia de dicha masa y uso de dicha masa comocatalizador de hidrogenacion |
Country Status (27)
Country | Link |
---|---|
US (3) | US6297394B1 (es) |
EP (1) | EP1071653B1 (es) |
JP (1) | JP2002505192A (es) |
KR (1) | KR100553283B1 (es) |
CN (1) | CN1185205C (es) |
AR (1) | AR018146A1 (es) |
AT (1) | ATE247623T1 (es) |
AU (1) | AU2835699A (es) |
BG (1) | BG64753B1 (es) |
BR (1) | BR9908505A (es) |
CA (1) | CA2322185C (es) |
CZ (1) | CZ294316B6 (es) |
DE (2) | DE19809687A1 (es) |
EA (1) | EA003285B1 (es) |
ES (1) | ES2207184T3 (es) |
HU (1) | HUP0101241A3 (es) |
ID (1) | ID25619A (es) |
MY (1) | MY122207A (es) |
NO (1) | NO317588B1 (es) |
PL (1) | PL342900A1 (es) |
PT (1) | PT1071653E (es) |
SI (1) | SI1071653T1 (es) |
SK (1) | SK12382000A3 (es) |
TR (1) | TR200002588T2 (es) |
TW (1) | TW518252B (es) |
UA (1) | UA66841C2 (es) |
WO (1) | WO1999044984A1 (es) |
Families Citing this family (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10151558A1 (de) * | 2001-10-23 | 2003-04-30 | Basf Ag | Als Katalysatorvorstufe geeignete oxidische Masse |
DE10151559A1 (de) * | 2001-10-23 | 2003-04-30 | Basf Ag | Als Katalysator geeignete Masse |
DE10321788A1 (de) * | 2003-05-14 | 2004-12-09 | Basf Ag | Polyamide |
KR101106334B1 (ko) | 2003-09-10 | 2012-01-18 | 바스프 에스이 | 액체 프탈로니트릴을 연속적으로 수소화시켜디아미노크실렌을 제조하는 방법 |
US7728174B2 (en) | 2005-08-02 | 2010-06-01 | Basf Se | Continuous hydrogenation processes for the preparation of xylylenediamines |
CN101277764A (zh) | 2005-08-03 | 2008-10-01 | Ccmi公司 | 表面活性固相非均相催化剂的增强 |
JP4670603B2 (ja) * | 2005-11-18 | 2011-04-13 | 株式会社デンソー | 触媒用粒子およびその製造方法 |
US8031804B2 (en) * | 2006-04-24 | 2011-10-04 | Parkervision, Inc. | Systems and methods of RF tower transmission, modulation, and amplification, including embodiments for compensating for waveform distortion |
ES2463686T3 (es) * | 2006-05-09 | 2014-05-28 | Basf Se | Procedimiento para la producción de aminoalquilonitrilos y diaminas a partir de nitrilos de este tipo |
US7709541B2 (en) * | 2006-07-14 | 2010-05-04 | Headwaters Technology Innovation, Llc | Fischer-Tropsch catalysts incorporating promoter for increasing yields of C5+ hydrocarbons and methods for making and using same |
EP1900428B1 (en) | 2006-08-09 | 2016-01-06 | Mitsubishi Gas Chemical Company, Inc. | Production method of primary amines and catalysts for producing primary amines |
US8440852B2 (en) | 2007-03-01 | 2013-05-14 | Basf Se | Method for producing tetraethylenepentamine |
EP2132163A1 (de) | 2007-03-01 | 2009-12-16 | Basf Se | Verfahren zur herstellung von ethylenaminen aus roh-aan |
JP5399270B2 (ja) | 2007-03-01 | 2014-01-29 | ビーエーエスエフ ソシエタス・ヨーロピア | エチレンジアミンの製造方法 |
US8299249B2 (en) | 2007-03-01 | 2012-10-30 | Basf Se | Method for producing TETA by means of EDDN |
JP5393486B2 (ja) | 2007-03-01 | 2014-01-22 | ビーエーエスエフ ソシエタス・ヨーロピア | トリエチレンテトラアミンの製造方法 |
CA2698892C (en) * | 2007-09-17 | 2015-11-10 | Shell Internationale Research Maatschappij B.V. | A catalyst composition useful in the catalytic reduction of sulfur compound contained in a gas stream and a method of making and using such composition |
EP2193841A1 (en) * | 2008-12-08 | 2010-06-09 | Sasol Technology (Proprietary) Limited | Hydrocarbon synthesis catalyst and process with improved selectivity to short chain products |
CA2746006C (en) | 2008-12-08 | 2016-01-26 | Reinier Crous | Olefin selective ft catalyst composition and preparation thereof |
CN102803213B (zh) | 2009-06-18 | 2015-05-13 | 巴斯夫欧洲公司 | 甲基取代的teta化合物 |
US9012638B2 (en) | 2011-08-31 | 2015-04-21 | Basf Se | Process for preparing EDDN and/or EDMN by conversion of FACH and EDA |
WO2013030255A1 (de) | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von eddn und/oder edmn sowie verfahren zur herstellung von deta und/oder teta |
WO2013030254A1 (de) | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von teta und/oder deta |
EP2751069B1 (de) | 2011-08-31 | 2017-10-11 | Basf Se | Verfahren zur herstellung von eddn und/oder edmn |
WO2013030174A1 (de) | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von edfa und/oder edmfa und deta und/oder teta |
JP2014525942A (ja) | 2011-08-31 | 2014-10-02 | ビーエーエスエフ ソシエタス・ヨーロピア | Fachとedaの反応によるeddnおよび/またはedmnの製造方法 |
WO2013030161A1 (de) | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von eddn und/oder edmn durch umsetzung von edfa und/oder edmfa mit hcn |
WO2013030023A1 (de) | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von eddn und/oder edmn sowie ein verfahren zur herstellung von deta und/oder teta |
WO2013030259A1 (de) | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von teta |
US9096497B2 (en) | 2011-08-31 | 2015-08-04 | Basf Se | Process for preparing EDDN and EDMN |
WO2013030249A1 (de) | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von aminen durch hydrierung von nitrilen |
EP2751067A1 (de) | 2011-08-31 | 2014-07-09 | Basf Se | Verfahren zur aufarbeitung von reaktionsausträgen aus der hydrierung von eddn bzw. edmn |
US8946459B2 (en) | 2011-08-31 | 2015-02-03 | Basf Se | Process for preparing EDDN and/or EDMN by reacting EDFA and/or EDMFA with HCN |
WO2013030144A1 (de) | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von eddn, edmn, teta und deta |
US8952156B2 (en) | 2011-08-31 | 2015-02-10 | Basf Se | Process for working up reaction outputs from the hydrogenation of EDDN or EDMN |
EP2951154B1 (de) | 2013-01-30 | 2017-04-19 | Basf Se | 2,6-bis-(aminomethyl)piperidin- (2,6-bamp-), 2,6-bis-(isocyanomethyl)piperidin- (diisocyanat-) und 2,6-dicyanopiperidin-derivate (2,6-dcp-derivate) und ihre verwendung in der herstellung von epoxyharzen, polyurethanen, polyetherolen und polyamiden |
WO2014131620A1 (de) | 2013-02-28 | 2014-09-04 | Basf Se | Verfahren zur herstellung von eda unter verwendung von so2-freier blausäure |
WO2014131674A2 (en) | 2013-03-01 | 2014-09-04 | Basf Se | Amine composition |
US9776175B2 (en) * | 2013-03-19 | 2017-10-03 | Korea Institute Of Energy Research | Iron-based catalyst and method for preparing the same and use thereof |
WO2017142898A1 (en) | 2016-02-16 | 2017-08-24 | Invista North America S.A R.L. | Promoter for selective nitrile hydrogenation |
EP3515898B1 (de) | 2016-09-19 | 2020-11-11 | Basf Se | Verfahren zur herstellung von polyaminen ausgehend von dinitrilen und/oder aminonitrilen |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE848654C (de) | 1950-08-19 | 1952-09-08 | Basf Ag | Verfahren zur Herstellung von partiellen Hydrierungsprodukten des Adipinsaeuredinitrils |
CA915707A (en) | 1969-07-11 | 1972-11-28 | J. Kershaw Bernard | Hydrogenation of adiponitrile |
BE758035A (fr) * | 1969-10-29 | 1971-04-26 | Halcon International Inc | Procede de couplage par reduction de composes organiques halogenes |
GB1486890A (en) | 1973-09-12 | 1977-09-28 | Ici Ltd | Catalysts and their use in hydrogenation |
NL7408053A (nl) * | 1973-09-12 | 1975-03-14 | Ici Ltd | Hydrogeneringskatalysator en werkwijze voor de bereiding daarvan. |
US4064172A (en) | 1973-09-12 | 1977-12-20 | Imperial Chemical Industries Limited | Hexamethylene diamine by hydrogenation of adiponitrile in presence of an activated iron oxide catalyst |
US4282381A (en) | 1980-08-21 | 1981-08-04 | E. I. Du Pont De Nemours And Company | Process for purifying hexamethylenediamine |
JPH0820666B2 (ja) * | 1987-02-24 | 1996-03-04 | 旭光学工業株式会社 | フアインダ−装置 |
DE4446893A1 (de) | 1994-12-27 | 1996-07-04 | Basf Ag | Verfahren zur Herstellung von aliphatischen alpha,omega-Aminonitrilen |
DE19533484A1 (de) * | 1995-09-12 | 1997-03-13 | Basf Ag | Monomodale und polymodale Katalysatorträger und Katalysatoren mit engen Porengrößenverteilungen und deren Herstellverfahren |
ES2169381T3 (es) * | 1996-09-10 | 2002-07-01 | Basf Ag | Procedimiento para la obtencion de alfa,omega-aminonitrilos alifaticos. |
DE10151559A1 (de) * | 2001-10-23 | 2003-04-30 | Basf Ag | Als Katalysator geeignete Masse |
-
1998
- 1998-03-06 DE DE19809687A patent/DE19809687A1/de not_active Withdrawn
-
1999
- 1999-02-23 SK SK1238-2000A patent/SK12382000A3/sk unknown
- 1999-02-23 US US09/622,773 patent/US6297394B1/en not_active Expired - Lifetime
- 1999-02-23 WO PCT/EP1999/001150 patent/WO1999044984A1/de active IP Right Grant
- 1999-02-23 TR TR2000/02588T patent/TR200002588T2/xx unknown
- 1999-02-23 EP EP99908940A patent/EP1071653B1/de not_active Expired - Lifetime
- 1999-02-23 PT PT99908940T patent/PT1071653E/pt unknown
- 1999-02-23 AT AT99908940T patent/ATE247623T1/de not_active IP Right Cessation
- 1999-02-23 BR BR9908505-4A patent/BR9908505A/pt not_active Application Discontinuation
- 1999-02-23 PL PL99342900A patent/PL342900A1/xx unknown
- 1999-02-23 AU AU28356/99A patent/AU2835699A/en not_active Abandoned
- 1999-02-23 HU HU0101241A patent/HUP0101241A3/hu unknown
- 1999-02-23 JP JP2000534529A patent/JP2002505192A/ja not_active Withdrawn
- 1999-02-23 CN CNB998037192A patent/CN1185205C/zh not_active Ceased
- 1999-02-23 ID IDW20001721A patent/ID25619A/id unknown
- 1999-02-23 KR KR1020007009834A patent/KR100553283B1/ko not_active IP Right Cessation
- 1999-02-23 DE DE59906684T patent/DE59906684D1/de not_active Expired - Lifetime
- 1999-02-23 EA EA200000894A patent/EA003285B1/ru not_active IP Right Cessation
- 1999-02-23 CA CA002322185A patent/CA2322185C/en not_active Expired - Fee Related
- 1999-02-23 SI SI9930440T patent/SI1071653T1/xx unknown
- 1999-02-23 ES ES99908940T patent/ES2207184T3/es not_active Expired - Lifetime
- 1999-02-23 CZ CZ20003237A patent/CZ294316B6/cs not_active IP Right Cessation
- 1999-02-23 UA UA2000105672A patent/UA66841C2/uk unknown
- 1999-03-05 TW TW088103356A patent/TW518252B/zh not_active IP Right Cessation
- 1999-03-05 MY MYPI99000815A patent/MY122207A/en unknown
- 1999-03-05 AR ARP990100943A patent/AR018146A1/es unknown
-
2000
- 2000-09-05 NO NO20004424A patent/NO317588B1/no unknown
- 2000-09-18 BG BG104773A patent/BG64753B1/bg unknown
-
2001
- 2001-05-08 US US09/851,214 patent/US6852669B2/en not_active Expired - Fee Related
-
2004
- 2004-02-12 US US10/776,544 patent/US7091153B2/en not_active Expired - Fee Related
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
AR018146A1 (es) | Masa apropiada como catalizador, procedimiento para la hidrogenacion de alfa, omega-dinitrilos en presencia de dicha masa y uso de dicha masa comocatalizador de hidrogenacion | |
EA200300894A1 (ru) | Водная вязкоупругая жидкость | |
UY27329A1 (es) | Champues con alcohol de behenilo | |
DE60117802D1 (de) | Verbesserung der bitterkeit von bier | |
DE69231830D1 (de) | Gasgefüllte Mikrospheren enthaltende Kontrastmittel zur diagnostischen Bilderzeugung | |
DK0639577T3 (da) | Phosphonooxymethyl- eller methylthiomethylestere af taxanderivater som antitumormidler | |
ES2173138T3 (es) | Composicion adhesiva antimicrobiana para uso dental. | |
KR100274373B1 (en) | Methylthiomethyl ethers of taxane derivatives | |
EA200500723A1 (ru) | Соединения бензофурана, композиции и способы лечения и профилактики инфекций, вызванных вирусом гепатита c, и связанных с ним заболеваний | |
ES2078313T3 (es) | Sales de n,n'-(1-oxo-1,2-etanodiil)-bis(acido aspartico) y uso en composiciones detergentes. | |
MX165401B (es) | Composiciones antioxidantes compatibles con polimero de hidrocarburo poliinsaturado | |
CO4230158A1 (es) | Composiciones para el arreglo del cabello | |
DE69432409T2 (de) | Verwendung der NDV zur Herstellung eines Medikaments zur Krebsbehandlung | |
UY27503A1 (es) | Nuevos derivados de piperazina | |
ES2186222T3 (es) | Agentes espesantes para composiciones acuosas liquidas. | |
CA2026335A1 (en) | Furfuryl alcohol mixtures for use as cleaning agents | |
ES2092284T3 (es) | Composicion y procedimiento de higiene bucal. | |
AR040607A1 (es) | Derivados aldehido de polietilenglicol | |
CO4930324A1 (es) | Composicion quimica que contiene un sistema preservativo y metodo para elaborar y usar tal composicion | |
PT1219703E (pt) | Molho balsamico para uso alimentar com base em vinagre balsamico de modena | |
ATE504654T1 (de) | Promotoren zur expression in modifiziertem vaccinia virus ankara | |
ES2025769T3 (es) | Procedimiento para preparar catalizadores de hidrotratamiento a partir de hidrogeles. | |
ATE404219T1 (de) | Rekombinante poxvirus-calicivirus zusammensetzungen und anwendungen | |
NO20030919D0 (no) | Trombomodulinanaloger til anvendelse ved rekonvalesens etter ryggmargsskade | |
AR017142A1 (es) | Procedimiento para la obtencion de alfa, omega, aminonitrilos alifaticos |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
FB | Suspension of granting procedure |