ZA200808000B - Metal complexes for use in the carbonylation of ethylenically unsaturated compounds - Google Patents

Metal complexes for use in the carbonylation of ethylenically unsaturated compounds

Info

Publication number
ZA200808000B
ZA200808000B ZA200808000A ZA200808000A ZA200808000B ZA 200808000 B ZA200808000 B ZA 200808000B ZA 200808000 A ZA200808000 A ZA 200808000A ZA 200808000 A ZA200808000 A ZA 200808000A ZA 200808000 B ZA200808000 B ZA 200808000B
Authority
ZA
South Africa
Prior art keywords
carbonylation
ethylenically unsaturated
metal complexes
unsaturated compounds
compounds
Prior art date
Application number
ZA200808000A
Other languages
English (en)
Inventor
Graham Ronald Eastham
Neil Tindale
Original Assignee
Lucite Int Uk Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lucite Int Uk Ltd filed Critical Lucite Int Uk Ltd
Publication of ZA200808000B publication Critical patent/ZA200808000B/xx

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • C07F17/02Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/36Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/006Palladium compounds
    • C07F15/0066Palladium compounds without a metal-carbon linkage

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
ZA200808000A 2006-04-13 2008-09-17 Metal complexes for use in the carbonylation of ethylenically unsaturated compounds ZA200808000B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GBGB0607494.2A GB0607494D0 (en) 2006-04-13 2006-04-13 Metal complexes

Publications (1)

Publication Number Publication Date
ZA200808000B true ZA200808000B (en) 2009-12-30

Family

ID=36571819

Family Applications (1)

Application Number Title Priority Date Filing Date
ZA200808000A ZA200808000B (en) 2006-04-13 2008-09-17 Metal complexes for use in the carbonylation of ethylenically unsaturated compounds

Country Status (14)

Country Link
US (1) US8445711B2 (ja)
EP (1) EP2007703B1 (ja)
JP (1) JP5583965B2 (ja)
KR (2) KR20140070592A (ja)
CN (1) CN101448773B (ja)
BR (1) BRPI0710504A2 (ja)
CA (1) CA2646403C (ja)
ES (1) ES2452722T3 (ja)
GB (1) GB0607494D0 (ja)
MY (1) MY156409A (ja)
RU (1) RU2470028C2 (ja)
TW (1) TWI410280B (ja)
WO (1) WO2007119079A1 (ja)
ZA (1) ZA200808000B (ja)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007516197A (ja) 2003-07-03 2007-06-21 ルーサイト インターナショナル ユーケー リミテッド エチレン性不飽和化合物のヒドロホルミル化方法
GB0403592D0 (en) 2004-02-18 2004-03-24 Lucite Int Uk Ltd A catalyst system
GB0411951D0 (en) 2004-05-28 2004-06-30 Lucite Int Uk Ltd Carbonylation of ester
GB0516556D0 (en) 2005-08-12 2005-09-21 Lucite Int Uk Ltd Improved catalyst system
KR101633325B1 (ko) 2005-11-17 2016-06-24 루사이트 인터내셔널 유케이 리미티드 에틸렌성 불포화 화합물의 카르보닐화
GB0607494D0 (en) 2006-04-13 2006-05-24 Lucite Int Uk Ltd Metal complexes
WO2008065448A1 (en) * 2006-12-02 2008-06-05 Lucite International Uk Limited Novel carbonylation ligands and their use in the carbonylation of ethylenically unsaturated compounds
DE502008000944D1 (de) * 2008-05-07 2010-08-26 Umicore Galvanotechnik Gmbh Verfahren zur Herstellung von Komplexen des Palladium(hydrogen) carbonats mit Aminliganden
GB0812297D0 (en) 2008-07-04 2008-08-13 Lucite Int Uk Ltd Novel carbonylation ligand sand thier use of in the carbonylation of ethylenically unsaturated compounds
GB201000078D0 (en) * 2010-01-05 2010-02-17 Lucite Int Uk Ltd Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporatng such ligands
US9018387B2 (en) 2010-06-11 2015-04-28 Air Products And Chemicals, Inc. Complexes of imidazole ligands
JP6455893B2 (ja) 2013-03-11 2019-01-23 ラトガース,ザ ステート ユニバーシティ オブ ニュー ジャージー 不斉転換のための有機金属の触媒作用
JP2013189715A (ja) * 2013-06-06 2013-09-26 Umicore Galvanotechnik Gmbh Pd電解質浴およびPd−Ni電解質浴
CN103450280B (zh) * 2013-08-14 2016-05-18 昆明贵金属研究所 二水合醋酸四氨合钯(ii)的一步法合成方法
WO2017135897A1 (en) * 2016-02-02 2017-08-10 Agency For Science, Technology And Research A catalyst for the carbonylation of alkenes
US10519094B2 (en) 2017-03-18 2019-12-31 Qatar Foundation For Education, Science And Community Development Metal-catalyzed alkoxycarbonylation of a lactone
WO2018187504A1 (en) 2017-04-04 2018-10-11 Randall Alley Stretch fastener
PL3502085T3 (pl) 2017-12-21 2020-08-24 Evonik Operations Gmbh Sposób bezpośredniego przekształcania alkenów w kwasy karboksylowe
ES2807542T3 (es) * 2017-12-21 2021-02-23 Evonik Operations Gmbh Procedimiento para la hidroxicarbonilación de diisobuteno catalizada con Pd: proporción ácido 3,5,5-trimetilhexanoico/H2O
EP3502084B1 (de) * 2017-12-21 2020-02-12 Evonik Operations GmbH Verfahren zur direkten umsetzung von diisobuten zu einer carbonsäure
CN111871461A (zh) * 2020-04-30 2020-11-03 杭州师范大学 一种海胆状钴基光催化剂及其制备方法

Family Cites Families (108)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3131204A (en) * 1962-02-09 1964-04-28 Grace W R & Co Novel diquaternary aminophosphonium compounds
US3564020A (en) * 1968-07-17 1971-02-16 Union Oil Co Preparation of angelica lactone
US4245115A (en) * 1977-09-14 1981-01-13 Mobil Oil Corporation Selective carbonylation of olefinically unsaturated hydrocarbons using palladium-arsine or -stibine catalysts
US4377708A (en) 1977-10-14 1983-03-22 Monsanto Company Hydrocarboxylation of vinyl alkanoates
DE3175174D1 (en) 1981-01-06 1986-09-25 Shell Int Research Process for the carbonylation of olefins
US4500727A (en) 1981-03-23 1985-02-19 Kuraray Co., Ltd. Process for producing methyl lactate
US4504684A (en) 1982-01-06 1985-03-12 The Standard Oil Company Metal coordination polymers as hydroformylation and hydrogenation catalysts
FR2530266B1 (fr) 1982-07-13 1985-07-12 Comp Generale Electricite Procede de preparation des acides arylacetiques et arylpropioniques
CA1231346A (en) 1982-09-30 1988-01-12 Eit Drent Process for the carbonylation of olefinically unsaturated compounds with a palladium catalyst
DE3480845D1 (de) * 1983-04-06 1990-02-01 Shell Int Research Verfahren zur herstellung von polyketonen.
CA1247640A (en) 1983-08-29 1988-12-28 James D. Burrington Alkoxycarbonylation or carbonylation with co and organic hydroxyl compound
NL8403035A (nl) * 1984-10-05 1986-05-01 Shell Int Research Werkwijze ter bereiding van polyketonen.
IN166314B (ja) * 1985-08-29 1990-04-07 Shell Int Research
GB8531624D0 (en) * 1985-12-23 1986-02-05 Shell Int Research Carbonylation of ethylenically unsaturated compounds
GB8605034D0 (en) 1986-02-28 1986-04-09 Shell Int Research Carbonylation of compounds
GB2195117B (en) 1986-09-16 1990-10-31 Agency Ind Science Techn Process for direct carbonylation of hydrocarbons
KR880007426A (ko) 1986-12-24 1988-08-27 오노 알버어스 팔라듐 촉매를 사용한 올레핀형 불포화 화합물의 카르보닐화 방법
GB8705699D0 (en) 1987-03-11 1987-04-15 Shell Int Research Carbonylation of olefinically unsaturated compounds
GB8719886D0 (en) 1987-08-22 1987-09-30 British Petroleum Co Plc Carboxylic acid esters/acids
US4960949A (en) 1988-12-22 1990-10-02 Eastman Kodak Company Low pressure rhodium catalyzed hydroformylation of olefins
US5103043A (en) 1989-03-03 1992-04-07 Shell Oil Company Carbonylation catalyst system
US5099062A (en) 1989-03-03 1992-03-24 Shell Oil Company Carbonylation catalyst and process
KR0148012B1 (ko) 1989-03-03 1998-08-17 오노 알버어스 신규한 포스핀으로 구성되는 촉매시스템 및 이를 이용한 아세틸렌형 또는 올레핀형 불포화화합물의 카르보닐화방법
US5158921A (en) 1989-03-03 1992-10-27 Shell Oil Company Carbonylation catalyst and process
US4950703A (en) * 1989-05-15 1990-08-21 Shell Oil Company Stabilized carbonmonoxide-olefin copolymer compositions
US5179225A (en) 1990-02-05 1993-01-12 Shell Oil Company Carbonylation catalyst system
CA2034971A1 (en) 1990-02-05 1991-08-06 Eit Drent Carbonylation catalyst system
GB9002491D0 (en) 1990-02-05 1990-04-04 Shell Int Research Carbonylation catalyst system
GB9014724D0 (en) 1990-07-03 1990-08-22 Shell Int Research Process for the preparation of alpha,beta-olefinically unsaturated compounds
CA2055628A1 (en) 1990-12-03 1992-06-04 Eit Drent Carbonylation process and catalyst composition
GB9026211D0 (en) 1990-12-03 1991-01-16 Shell Int Research Carbonylation process
BE1004336A3 (fr) 1991-01-15 1992-11-03 Analis Sa Procede de separation et de quantification de l'hemoglobine glycosylee hb a1c.
DE69204691T2 (de) 1991-01-15 1996-04-11 Shell Int Research Verfahren zur Karbonylierung von Olefin.
GB9105211D0 (en) 1991-03-12 1991-04-24 Shell Int Research Process for the preparation of alkanedioic acid derivatives
EP0495547B1 (en) * 1991-01-15 1996-04-24 Shell Internationale Researchmaatschappij B.V. Carbonylation of olefins
AT394735B (de) 1991-01-16 1992-06-10 Chem Fab Jos Ant Zezi Ges M B Mittel zum entfernen der oberflaechenschutzschicht fabriksneuer fahrzeuge od. dgl.
KR100230139B1 (ko) * 1991-02-15 1999-11-15 오노 알버어스 카르보닐화 촉매 시스템
GB9111583D0 (en) 1991-05-30 1991-07-24 Shell Int Research Carbonylation catalyst system
US5258546A (en) 1991-05-30 1993-11-02 Shell Oil Company Carbonylation catalyst system
US5247064A (en) * 1991-08-06 1993-09-21 Shell Oil Company Polymerization of co/olefin with p bidentate ligand
US5245098A (en) 1992-01-21 1993-09-14 The University Of Akron Process for preparation of non-conjugated diolefins
US5350876A (en) * 1992-06-29 1994-09-27 Shell Oil Company Carbonylation of conjugated dienes
EP0577205B1 (en) 1992-06-29 1997-10-08 Shell Internationale Researchmaatschappij B.V. Carbonylation of conjugated dienes
US5436356A (en) 1993-02-09 1995-07-25 Shell Oil Company Carbonylation process
SG42938A1 (en) 1993-02-26 1997-10-17 Ciba Geigy Ag Ferrocenc diphosphines as ligands for homogeneous catalysts
JP2600112B2 (ja) * 1994-11-02 1997-04-16 工業技術院長 含ケイ素高分子重合体の製造方法
PL320698A1 (en) 1994-11-29 1997-10-27 Lonza Ag Method of obtaining optically active metalocenylophosphines
GB9425911D0 (en) * 1994-12-22 1995-02-22 Ici Plc Process for the carbonylation of olefins and catalyst system for use therein
US5495041A (en) 1995-02-22 1996-02-27 Dsm N.W. Process for the preparation of a pentenoate ester
ES2150653T3 (es) 1995-02-24 2000-12-01 Novartis Ag Ferrocenildifosfinas sililadas, ferrocenildifosfinas sililadas unidas a soportes inorganicos o polimeros organicos, asi como complejos metalicos de estas, su obtencion y empleo.
US5719313A (en) * 1995-03-16 1998-02-17 Shell Oil Company Carbonylation catalyst system and a process for the carbonylation of acetylenically unsaturated compounds
CA2216153C (en) 1995-04-11 2008-02-05 Novartis Ag Dihalogenated ferrocenes and processes for the preparation thereof
US5567856A (en) * 1995-05-30 1996-10-22 Hoechst Celanese Corporation Synthesis of and hydroformylation with fluoro-substituted bidentate phosphine ligands
EP0912586B1 (en) 1996-07-10 2002-01-16 Syngenta Participations AG Functionalized ferrocenyldiphosphines, a process for their preparation and their use
US5710344A (en) 1996-11-08 1998-01-20 E. I. Du Pont De Nemours And Company Process to prepare a linear aldehyde
GB9705699D0 (en) 1997-03-19 1997-05-07 Ici Plc Process for the carbonylation of ethylene
US6489506B2 (en) 1997-03-19 2002-12-03 Lucite International Uk Limited Process for the palladium and phosphine ligand catalyzed carbonylation of ethylene
US6156934A (en) 1997-03-26 2000-12-05 Shell Oil Company Diphosphines
WO1998045040A1 (en) * 1997-04-07 1998-10-15 Dsm N.V. Carbonylation catalyst system
US6184391B1 (en) 1997-04-15 2001-02-06 Union Carbide Chemicals & Plastics Technology Corporation Processes for producing epsilon caprolactones and/or hydrates and/or esters thereof
DE19721601A1 (de) 1997-05-23 1998-11-26 Hoechst Ag Polybetain-stabilisierte, Palladium-haltige Nanopartikel, ein Verfahren zu ihrer Herstellung sowie daraus hergestellte Katalysatoren zur Gewinnung von Vinylacetat
GB9717059D0 (en) 1997-08-13 1997-10-15 Ici Plc Method of manufacturing phosphine compound
DE19745904A1 (de) 1997-10-17 1999-04-22 Hoechst Ag Polymerstabilisierte Metallkolloid-Lösungen, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren für Brennstoffzellen
GB9722733D0 (en) 1997-10-29 1998-10-28 Ici Plc Production of esters
DE19754304A1 (de) 1997-12-08 1999-06-10 Hoechst Ag Polybetain-stabilisierte Platin-Nanopartikel, Verfahren zu ihrer Herstellung und Verwendung für Elektrokatalysatoren in Brennstoffzellen
EP0967015B1 (de) 1998-06-19 2005-01-12 Degussa AG Verwendung von Ferrocenylliganden zur katalytischen enantioselektiven Hydrierung
US6337406B1 (en) 1998-08-21 2002-01-08 The Penn State Research Foundation Asymmetric catalysis based on chiral phospholanes and hydroxyl phospholanes
US5962732A (en) * 1998-12-17 1999-10-05 E. I. Du Pont De Nemours And Company Process for the preparation of 3-pentenoic acid from butadiene using a nickel catalyst
DE19952348A1 (de) 1998-12-19 2000-06-21 Degussa Liganden und Komplexe zur enantioselektiven Hydrierung
GB9918229D0 (en) 1999-08-04 1999-10-06 Ici Plc Improvements relating to metal-compound catalysed processes
CA2385421C (en) 1999-09-20 2009-12-15 The Penn State Research Foundation Chiral phosphines, transition metal complexes thereof and uses thereof in asymmetric reactions
US6258979B1 (en) 1999-11-22 2001-07-10 Henri Kagan Chiral ferrocene phosphines active in asymmetric catalysis
MY127358A (en) * 2000-03-14 2006-11-30 Shell Int Research Process for the carbonylation of ethylenically unsaturated compounds
US6743911B2 (en) 2000-03-14 2004-06-01 Shell Oil Company Process for the carbonylation of pentenenitrile
TWI266760B (en) 2000-03-20 2006-11-21 Kvaerner Process Tech Ltd Process for the preparation of propane-1,3-diol
DE10023470A1 (de) 2000-05-12 2001-11-15 Basf Ag Verfahren zur Herstellung von Aldehyden
MY127093A (en) * 2000-05-17 2006-11-30 Lucite Int Uk Ltd Bidentate ligands useful in catalyst systems
DE10037961A1 (de) 2000-07-27 2002-02-07 Aventis Res & Tech Gmbh & Co Neue Phosphanliganden, deren Herstellung und ihre Verwendung in katalytischen Reaktionen
DE10048874A1 (de) * 2000-09-29 2002-04-11 Basf Ag Katalysatorsystem und Verfahren zur Carbonylierung
DE10060313A1 (de) 2000-12-04 2002-06-13 Basf Ag Verfahren zur Carbonylierung von Pentensäure und deren Derivate
AU2002228806A1 (en) 2000-12-11 2002-06-24 E.I. Du Pont De Nemours And Company Trocess for making 5-cyanovaleric acid, adipic acid or dimethyl adidpate
DE10228293A1 (de) * 2001-07-28 2003-02-13 Basf Ag Verfahren zur Herstellung von Dialkylketonen
US20030105348A1 (en) 2001-11-19 2003-06-05 Bunel Emilio E. Process for making 5-cyanovaleric acid, adipic acid or dimethyl adipate
CA2476736C (en) 2002-02-19 2012-06-05 Shell Internationale Research Maatschappij B.V. Process for the carbonylation of an ethylenically unsaturated compound and catalyst therefore
TWI301481B (en) 2002-08-10 2008-10-01 Lucite Int Uk Ltd A catalyst system
GB0228018D0 (en) 2002-11-30 2003-01-08 Lucite Int Uk Ltd Carbonylation of ester
GB0218613D0 (en) 2002-08-10 2002-09-18 Lucite Int Uk Ltd Process for the carbonylation of ethylenically unsaturated compounds
US20040115475A1 (en) * 2002-08-14 2004-06-17 Matsushita Electric Industrial Co., Ltd. Aromatic methylidene compound, methylstyrul compound for producing the same, production electroluminescent element
ES2429871T3 (es) 2002-09-12 2013-11-18 Lucite International Uk Limited Un sistema catalizador que comprende un ligando de 1,2-bis-(fosfin)metaloceno
CA2498293C (en) * 2002-09-12 2012-05-22 Lucite International Uk Limited Catalyst system comprising chelating ligand and group viiib metal
CA2500095C (en) 2002-09-26 2011-10-18 Shell Internationale Research Maatschappij B.V. Process for the hydroformylation of an ethylenically unsaturated compound
JP4464388B2 (ja) * 2003-02-14 2010-05-19 高砂香料工業株式会社 ホスフィン化合物、中間体、パラジウム錯体、及び該錯体を使用する不飽和化合物の製造方法
CA2526348A1 (en) 2003-05-22 2004-12-02 Shell Internationale Research Maatschappij B.V. Process for the carbonylation of a conjugated diene
JP2007516197A (ja) 2003-07-03 2007-06-21 ルーサイト インターナショナル ユーケー リミテッド エチレン性不飽和化合物のヒドロホルミル化方法
GB0403592D0 (en) 2004-02-18 2004-03-24 Lucite Int Uk Ltd A catalyst system
WO2005082830A1 (en) 2004-02-26 2005-09-09 Shell Internationale Research Maatschappij B.V. Process for the carbonylation of ethylenically or acetylenically unsaturated compounds
GB0411951D0 (en) 2004-05-28 2004-06-30 Lucite Int Uk Ltd Carbonylation of ester
SE527991C2 (sv) 2004-12-07 2006-08-01 Glow Ab Vattenrenare med UV-lampa och filter samt demonterbara delar
WO2006084892A2 (en) 2005-02-11 2006-08-17 Shell Internationale Research Maatschappij B.V. Process for the preparation of a dicarboxylic acid
TW200633972A (en) 2005-02-11 2006-10-01 Shell Int Research Process for the carbonylation of a conjugated diene
GB0516556D0 (en) * 2005-08-12 2005-09-21 Lucite Int Uk Ltd Improved catalyst system
KR101633325B1 (ko) * 2005-11-17 2016-06-24 루사이트 인터내셔널 유케이 리미티드 에틸렌성 불포화 화합물의 카르보닐화
CN101437808A (zh) 2006-03-21 2009-05-20 耶鲁大学 由芳香化合物与氨或金属酰胺反应合成芳基胺的方法
GB0607494D0 (en) 2006-04-13 2006-05-24 Lucite Int Uk Ltd Metal complexes
GB2437250C (en) * 2006-04-18 2012-08-15 Iti Scotland Ltd Method and system for monitoring the condition of livestock
GB0625518D0 (en) 2006-12-21 2007-01-31 Lucite Int Uk Ltd Carbonylation of conjugated dienes
TWI473785B (zh) 2007-06-01 2015-02-21 Bp Chem Int Ltd 使用金屬螯配位體催化劑用於醋酸之生產的羰基化方法
GB0713624D0 (en) * 2007-07-13 2007-08-22 Lucite Int Uk Ltd Improved solvent for catalyst system

Also Published As

Publication number Publication date
CN101448773B (zh) 2015-02-11
GB0607494D0 (en) 2006-05-24
ES2452722T3 (es) 2014-04-02
US8445711B2 (en) 2013-05-21
TW200744756A (en) 2007-12-16
KR101531050B1 (ko) 2015-06-23
CN101448773A (zh) 2009-06-03
EP2007703B1 (en) 2013-12-18
KR20140070592A (ko) 2014-06-10
RU2470028C2 (ru) 2012-12-20
JP5583965B2 (ja) 2014-09-03
EP2007703A1 (en) 2008-12-31
BRPI0710504A2 (pt) 2012-06-05
RU2008144698A (ru) 2010-05-20
JP2009533409A (ja) 2009-09-17
MY156409A (en) 2016-02-26
KR20090009860A (ko) 2009-01-23
AU2007238407A1 (en) 2007-10-25
CA2646403C (en) 2014-11-18
US20090312561A1 (en) 2009-12-17
WO2007119079A1 (en) 2007-10-25
CA2646403A1 (en) 2007-10-25
TWI410280B (zh) 2013-10-01

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