ZA200600568B - High temperature calcination of selectivated molecular sieve catalysts for activity and diffusional modification - Google Patents
High temperature calcination of selectivated molecular sieve catalysts for activity and diffusional modificationInfo
- Publication number
- ZA200600568B ZA200600568B ZA200600568A ZA200600568A ZA200600568B ZA 200600568 B ZA200600568 B ZA 200600568B ZA 200600568 A ZA200600568 A ZA 200600568A ZA 200600568 A ZA200600568 A ZA 200600568A ZA 200600568 B ZA200600568 B ZA 200600568B
- Authority
- ZA
- South Africa
- Prior art keywords
- activity
- high temperature
- molecular sieve
- temperature calcination
- sieve catalysts
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title 1
- 238000003837 high-temperature calcination Methods 0.000 title 1
- 230000004048 modification Effects 0.000 title 1
- 238000012986 modification Methods 0.000 title 1
- 239000002808 molecular sieve Substances 0.000 title 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 title 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
- B01J29/44—Noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
- C07C5/2708—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
- C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
- C07C6/123—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of only one hydrocarbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/12—After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/32—Reaction with silicon compounds, e.g. TEOS, siliconfluoride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/40—Special temperature treatment, i.e. other than just for template removal
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
- C07C2529/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
- C07C2529/44—Noble metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1037—Hydrocarbon fractions
- C10G2300/1044—Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1096—Aromatics or polyaromatics
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/30—Aromatics
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/625,322 US7238636B2 (en) | 2003-07-23 | 2003-07-23 | High temperature calcination of selectivated molecular sieve catalysts for activity and diffusional modification |
Publications (1)
Publication Number | Publication Date |
---|---|
ZA200600568B true ZA200600568B (en) | 2008-12-31 |
Family
ID=34080186
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ZA200600568A ZA200600568B (en) | 2003-07-23 | 2006-01-19 | High temperature calcination of selectivated molecular sieve catalysts for activity and diffusional modification |
Country Status (10)
Country | Link |
---|---|
US (1) | US7238636B2 (xx) |
EP (1) | EP1663484A1 (xx) |
JP (1) | JP4711960B2 (xx) |
KR (1) | KR101048577B1 (xx) |
CN (1) | CN1835798A (xx) |
CA (1) | CA2533157C (xx) |
RU (1) | RU2006105480A (xx) |
TW (1) | TW200523024A (xx) |
WO (1) | WO2005014169A1 (xx) |
ZA (1) | ZA200600568B (xx) |
Families Citing this family (38)
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US7553791B2 (en) * | 2002-11-14 | 2009-06-30 | Exxonmobil Chemical Patents Inc. | Heavy aromatics conversion catalyst composition and processes therefor and therewith |
US7060644B2 (en) * | 2004-01-08 | 2006-06-13 | Saudi Basic Industries Corporation | Aromatic alkylation catalyst and method |
FR2887538B1 (fr) * | 2005-06-28 | 2008-01-04 | Inst Francais Du Petrole | Procede de traitement d'une zeolithe a petits et/ou moyens pores et son utilisation en oligomerisation des olefines legeres |
US7335621B2 (en) * | 2006-04-19 | 2008-02-26 | Exxonmobil Chemical Patents Inc. | Catalyst compositions and preparation thereof |
US7790795B2 (en) | 2006-05-25 | 2010-09-07 | Exxonmobil Chemical Patents Inc. | Scratch and mar resistant polymer compositions, methods for making and articles made from the same |
FR2901716B1 (fr) * | 2006-05-30 | 2008-08-29 | Inst Francais Du Petrole | Utilisation d'un catalyseur a base de zeolithe itq-6 en isomerisation d'une coupe c8 aromatique |
US7595275B2 (en) * | 2006-08-15 | 2009-09-29 | Exxonmobil Chemical Patents Inc. | Catalyst compositions and their synthesis |
US7563358B2 (en) | 2006-08-24 | 2009-07-21 | Exxonmobil Chemical Patents Inc. | Process for the production of benzene, toluene, and xylenes |
US7381676B1 (en) * | 2007-01-16 | 2008-06-03 | Exxonmobil Chemical Patents Inc. | Catalyst composition and its use thereof in aromatics alkylation |
WO2008115482A1 (en) * | 2007-03-20 | 2008-09-25 | Exxonmobil Research And Engineering Company | Apparatus and method for steaming treatment of molecular sieves |
CN101284232B (zh) * | 2007-04-13 | 2013-01-16 | 微宏动力系统(湖州)有限公司 | 甲烷溴氧化制溴甲烷及其转化制碳氢化合物的催化剂 |
WO2009116995A1 (en) * | 2008-03-18 | 2009-09-24 | Uop Llc | Ethylbenzene conversion and xylene isomerization processes and catalysts therefor |
US8450545B2 (en) * | 2008-07-25 | 2013-05-28 | Phillips 66 Company | Process for converting an oxygenated feed to high octane gasoline |
US8846559B2 (en) * | 2008-11-03 | 2014-09-30 | Saudi Basic Industries Corporation | Stable shape-selective catalyst for aromatic alkylation and methods of using and preparing |
JP5577587B2 (ja) * | 2008-11-25 | 2014-08-27 | 株式会社明電舎 | 低級炭化水素芳香族化触媒の製造方法及び低級炭化水素芳香族化触媒 |
JP5756461B2 (ja) | 2009-06-12 | 2015-07-29 | アルベマール・ユーロプ・エスピーアールエル | Sapo分子篩触媒と、その調製および使用 |
US8062987B2 (en) * | 2009-10-05 | 2011-11-22 | Saudi Basic Industries Corporation | Phosphorus-containing zeolite catalysts and their method of preparation |
US8575055B2 (en) | 2010-03-30 | 2013-11-05 | Uop Llc | Surface-modified zeolites and methods for preparing the same |
CN103153461B (zh) * | 2010-10-11 | 2015-11-25 | 埃克森美孚化学专利公司 | 加氢烷基化催化剂的活化和使用 |
CN103121913B (zh) * | 2011-11-18 | 2015-02-11 | 中国石油化工股份有限公司 | 甲苯择形歧化催化剂制备方法 |
US9278342B2 (en) | 2012-07-02 | 2016-03-08 | Saudi Basic Industries Corporation | Method of modifying a phosphorus-containing zeolite catalyst |
CN104107717B (zh) * | 2013-04-16 | 2016-12-28 | 中国石油化工股份有限公司 | 提高二甲苯选择性的甲苯歧化催化剂及其用途 |
EP3337610B1 (en) * | 2015-08-18 | 2020-04-29 | BP Corporation North America Inc. | Method for making desilicated zsm-5 catalysts for xylene isomerization |
CN106466628A (zh) * | 2015-08-20 | 2017-03-01 | 中国石油化工股份有限公司 | Zsm-23/sapo-34复合分子筛催化剂及其合成方法 |
EP3170555A1 (en) * | 2015-11-20 | 2017-05-24 | Reliance Industries Limited | Naphtha reforming catalyst based on gallium- and/or zinc-modified zeolite, preparation thereof, and catalytic reforming process |
CN108144653B (zh) * | 2016-12-04 | 2019-12-10 | 中国科学院大连化学物理研究所 | 一种油脂加氢催化剂制备及催化剂和应用 |
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KR102049352B1 (ko) | 2017-11-01 | 2019-11-28 | 한국화학연구원 | 산 처리된 zsm-5를 통한 프로필렌으로부터 선택적 에틸렌의 제조방법 |
CN108435246B (zh) * | 2018-02-01 | 2021-07-27 | 浙江工业大学 | 一种多级孔同晶取代Ga-ZSM-5分子筛催化剂的制备方法 |
JP7307807B2 (ja) | 2018-10-30 | 2023-07-12 | エクソンモービル ケミカル パテンツ インコーポレイテッド | 微多孔性モレキュラーシーブ触媒のか焼 |
CN112007692B (zh) * | 2019-05-31 | 2024-03-29 | 国家能源投资集团有限责任公司 | 用于费托合成蜡生产的润滑油基础油脱蜡的催化剂及其制备方法和用途 |
CN110373223B (zh) * | 2019-07-29 | 2020-06-23 | 华东理工大学 | 一种催化裂化抗焦活化剂及其制备方法 |
CN112517049B (zh) * | 2019-09-19 | 2022-05-24 | 中国石油化工股份有限公司 | 丙烷脱氢制丙烯催化剂及其制备方法和应用 |
US10843930B1 (en) | 2019-11-13 | 2020-11-24 | Saudi Arabian Oil Company | Systems and methods for synthesis of ZSM-22 zeolite |
CN110947416B (zh) * | 2019-12-18 | 2023-06-13 | 武汉科技大学 | 用于nh3-scr的铁/分子筛催化剂及其制备方法和应用 |
CN112661169A (zh) * | 2020-12-22 | 2021-04-16 | 北京元泰达环保科技有限公司 | 一种多级结构zsm-22分子筛 |
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US5567666A (en) | 1995-05-15 | 1996-10-22 | Mobil Oil Corporation | Selectivated zeolite catalyst treated with a dealuminizing agent |
US5849968A (en) | 1995-06-06 | 1998-12-15 | Mobil Oil Corporation | Hydrocarbon conversion process with alkaline earth metal ion exchanged selectivated zeolite catalyst |
US5602066A (en) | 1995-06-29 | 1997-02-11 | Mobil Oil Corporation | Method of making a liquid washed selectivated zeolite catalyst |
ZA978671B (en) | 1996-10-02 | 1999-03-26 | Mobil Oil Corp | Selective para-xylene production by toluene methylation |
US6051519A (en) | 1998-02-10 | 2000-04-18 | Phillips Petroleum Company | Ethylbenzene reduction catalyst composition and processes therefor and therewith |
US7119239B2 (en) * | 2002-06-19 | 2006-10-10 | Exxonmobil Chemical Patents Inc. | Manufacture of xylenes using reformate |
AU2003243674A1 (en) * | 2002-06-19 | 2004-01-06 | Exxonmobil Chemical Patents Inc. | Manufacture of xylenes from reformate |
US7081556B2 (en) * | 2002-11-01 | 2006-07-25 | Exxonmobil Chemical Patents Inc. | Aromatics conversion with ITQ-13 |
US7074739B2 (en) * | 2002-11-19 | 2006-07-11 | Exxonmobil Chemical Patents Inc. | Multi-component molecular sieve catalyst compositions and their use in aromatics reactions |
-
2003
- 2003-07-23 US US10/625,322 patent/US7238636B2/en not_active Expired - Fee Related
-
2004
- 2004-06-16 JP JP2006521066A patent/JP4711960B2/ja not_active Expired - Fee Related
- 2004-06-16 CN CNA2004800235675A patent/CN1835798A/zh active Pending
- 2004-06-16 RU RU2006105480/04A patent/RU2006105480A/ru unknown
- 2004-06-16 EP EP04755249A patent/EP1663484A1/en not_active Withdrawn
- 2004-06-16 WO PCT/US2004/018970 patent/WO2005014169A1/en active Application Filing
- 2004-06-16 KR KR1020067001442A patent/KR101048577B1/ko not_active IP Right Cessation
- 2004-06-16 CA CA2533157A patent/CA2533157C/en not_active Expired - Fee Related
- 2004-06-24 TW TW093118208A patent/TW200523024A/zh unknown
-
2006
- 2006-01-19 ZA ZA200600568A patent/ZA200600568B/xx unknown
Also Published As
Publication number | Publication date |
---|---|
CA2533157C (en) | 2012-07-24 |
JP2006528061A (ja) | 2006-12-14 |
CN1835798A (zh) | 2006-09-20 |
KR20060041262A (ko) | 2006-05-11 |
RU2006105480A (ru) | 2007-09-20 |
TW200523024A (en) | 2005-07-16 |
CA2533157A1 (en) | 2005-02-17 |
US20050020435A1 (en) | 2005-01-27 |
EP1663484A1 (en) | 2006-06-07 |
US7238636B2 (en) | 2007-07-03 |
WO2005014169A1 (en) | 2005-02-17 |
JP4711960B2 (ja) | 2011-06-29 |
KR101048577B1 (ko) | 2011-07-12 |
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