WO2023274022A1 - 隔热板材及其制备方法以及应用该隔热板材的冰箱 - Google Patents
隔热板材及其制备方法以及应用该隔热板材的冰箱 Download PDFInfo
- Publication number
- WO2023274022A1 WO2023274022A1 PCT/CN2022/100768 CN2022100768W WO2023274022A1 WO 2023274022 A1 WO2023274022 A1 WO 2023274022A1 CN 2022100768 W CN2022100768 W CN 2022100768W WO 2023274022 A1 WO2023274022 A1 WO 2023274022A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- heat insulation
- core material
- annular groove
- heat
- vacuum
- Prior art date
Links
- 238000009413 insulation Methods 0.000 title claims abstract description 84
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000011162 core material Substances 0.000 claims abstract description 53
- 239000000463 material Substances 0.000 claims abstract description 49
- 239000012774 insulation material Substances 0.000 claims abstract description 39
- 239000011248 coating agent Substances 0.000 claims description 28
- 238000000576 coating method Methods 0.000 claims description 28
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 13
- 229910052782 aluminium Inorganic materials 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 12
- 229920002635 polyurethane Polymers 0.000 claims description 11
- 239000004814 polyurethane Substances 0.000 claims description 11
- 239000011810 insulating material Substances 0.000 claims description 9
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 8
- -1 polyethylene Polymers 0.000 claims description 8
- 239000011888 foil Substances 0.000 claims description 6
- 239000004698 Polyethylene Substances 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 229910021485 fumed silica Inorganic materials 0.000 claims description 4
- 239000003365 glass fiber Substances 0.000 claims description 4
- 239000011491 glass wool Substances 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- 229920001155 polypropylene Polymers 0.000 claims description 4
- 238000000465 moulding Methods 0.000 claims description 3
- 230000006837 decompression Effects 0.000 claims description 2
- 238000007789 sealing Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 8
- 238000010030 laminating Methods 0.000 abstract 5
- 239000002648 laminated material Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000003672 processing method Methods 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical group [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000006261 foam material Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D23/00—General constructional features
- F25D23/06—Walls
- F25D23/062—Walls defining a cabinet
- F25D23/064—Walls defining a cabinet formed by moulding, e.g. moulding in situ
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L59/00—Thermal insulation in general
- F16L59/06—Arrangements using an air layer or vacuum
- F16L59/065—Arrangements using an air layer or vacuum using vacuum
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L59/00—Thermal insulation in general
- F16L59/02—Shape or form of insulating materials, with or without coverings integral with the insulating materials
- F16L59/029—Shape or form of insulating materials, with or without coverings integral with the insulating materials layered
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L59/00—Thermal insulation in general
- F16L59/04—Arrangements using dry fillers, e.g. using slag wool which is added to the object to be insulated by pouring, spreading, spraying or the like
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D23/00—General constructional features
- F25D23/06—Walls
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D23/00—General constructional features
- F25D23/06—Walls
- F25D23/065—Details
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D2201/00—Insulation
- F25D2201/10—Insulation with respect to heat
- F25D2201/14—Insulation with respect to heat using subatmospheric pressure
Definitions
- the invention relates to the field of refrigeration appliances, in particular to a heat insulating board, a preparation method thereof and a refrigerator using the heat insulating board.
- Vacuum insulation panel is a kind of vacuum insulation material, which is composed of filling core material and vacuum protection surface layer, which can effectively avoid heat transfer caused by air convection.
- the application of vacuum insulation panels on refrigerators is to directly attach flat vacuum insulation panels to the relatively flat surface of the refrigerator shell, and then fill them with foam.
- vacuum insulation panels often use aluminum foil. Or the material of evaporated aluminum is used as the coating material. Due to the high heat transfer coefficient of aluminum, the heat is directly transferred from one side to the other side through the coating material, resulting in a "thermal bridge effect" on the edge of the vacuum insulation panel. , the edge energy saving of the vacuum insulation panel is poor.
- the existing technical solution is that when the vacuum insulation panels are attached to the outer shell of the refrigerator, a layer of thermal insulation material with a small thickness is added between them for transition. Since the size of the thermal insulation material is smaller than the size of the vacuum insulation panels, the edge of the vacuum insulation panels is at In the suspended state, when the polyurethane is foamed, due to the disorder of the foam material and the small thickness of the suspended space, the polyurethane will not be filled, and then there will be voids, affecting the appearance and other quality defects.
- the object of the present invention is to provide a heat insulation board and its preparation method and a refrigerator using the heat insulation board to solve the above problems.
- an embodiment of the present invention provides a heat insulation panel, including a vacuum insulation panel and a heat insulation material;
- the vacuum insulation panel includes a core material and a coating material, and one side of the core material is open There is an annular groove, the coating material wraps the core material, and a vacuum is formed between the core material and the coating material; the heat insulating material is arranged in the annular groove wrapped by the coating material, so The thermal insulation material is located on the same plane as the vacuum insulation panel, and the thermal resistance of the thermal insulation material is higher than that of the coating material.
- the heat insulation board further includes: the coating material is aluminum foil or evaporated aluminum.
- the heat insulation board further includes: the core material is at least one of glass fiber, glass wool and fumed silica.
- the heat insulation board further includes: the heat insulation material is at least one of foamed styrene, foamed polyurethane, foamed polyethylene, and foamed polypropylene.
- the heat insulation board further includes: the thickness of the annular groove is 1/2-2/3 of the thickness of the core material.
- the heat insulation board further includes: one side end surface of the annular groove is flush with the side end surface of the core material, so that the bonded end surface of the heat insulation material and the The end faces of the vacuum insulation panels are on the same plane.
- the heat insulation board further includes: a getter is placed inside the core material.
- an embodiment of the present invention provides a refrigerator, which includes an outer shell and an inner container, and the heat insulation board and foamed polyurethane as described in the above technical solution are arranged between the refrigerator outer shell and the inner container, and The surface where the heat insulating material is located is attached to the refrigerator shell.
- an embodiment of the present invention provides a method for preparing a heat-insulating board, the method comprising the following steps: processing one side of the prepared core material into an annular groove; Put it into a prefabricated film-coated material bag; vacuumize and heat-seal the core material and film-coated material bag to obtain a vacuum insulation panel with an annular groove; mold the heat-insulating material according to the size of the annular groove, The thermal resistance of the thermal insulation material is higher than the thermal resistance of the coating material; the cut thermal insulation material is bonded in the annular groove of the vacuum insulation panel, wherein the thermal insulation material and the vacuum insulation panel are located on the same plane, .
- the preparation method of the heat insulation board further includes: the core material is integrally formed or made into a unit size and then laminated.
- the heat insulation board and its preparation method disclosed in the present invention reduce the heat transferred to the edge and inside of the vacuum insulation board through the heat insulation material, and reduce the heat loss at the edge of the vacuum insulation board.
- the "thermal bridge effect" has played a good thermal insulation effect.
- Fig. 1 is a schematic longitudinal sectional view of a refrigerator according to an embodiment of the present invention
- Fig. 2 is a schematic cross-sectional view of a heat insulating board according to an embodiment of the present invention
- Fig. 3 is a schematic cross-sectional view of a vacuum insulation panel according to an embodiment of the present invention.
- Fig. 4 is a flowchart of a method for preparing a heat insulating board according to an embodiment of the present invention.
- an embodiment of the present invention provides a refrigerator 1, comprising an outer shell 11 and an inner container 13, and a heat insulating board 3 and a foamed polyurethane 5 are arranged between the refrigerator outer shell 11 and the inner container 13, and the The surface where the heat insulating material 3 is located is attached to the refrigerator casing 11 .
- a heat insulation panel 3 provided by an embodiment of the present invention includes a vacuum insulation panel 31 and a heat insulation material 33 .
- the vacuum insulation panel 31 includes a core material 311 and a coating material 313, and an annular groove 315 is opened on one side of the core material 311, and the coating material 313 wraps the core material 311. A vacuum is formed between the core material 311 and the coating material 313 .
- the core material 311 can be at least one of glass fiber, glass wool, and fumed silica;
- the coating material 313 can be a material that can block external air such as aluminum foil or evaporated aluminum;
- the material 33 can be at least one of foamed styrene, foamed polyurethane, foamed polyethylene, and foamed polypropylene.
- a getter 317 may be placed inside the core material 311 for absorbing the escaped gas in the core material 311 to further maintain the vacuum degree in the vacuum insulation panel 31 .
- annular groove 315 is opened on one side of the core material 311. Since the coating material 313 is selected from flexible materials such as aluminum foil or evaporated aluminum, it can be understood that the coating material 313 wraps the core material 311 and forms a vacuum.
- the vacuum insulation panel 31 also has an annular groove 315 structure.
- the heat insulation material 33 is arranged in the annular groove 315 wrapped by the film material 313, the heat insulation material 33 and the The vacuum insulation panels 31 are located on the same plane, the heat resistance of the insulation material 33 is higher than that of the coating material 313, and the heat from the outside of the refrigerator is transferred to the edge of the vacuum insulation panel 31 and the heat inside the refrigerator through the edge of the insulation material 33 Reduced, reducing the "thermal bridging effect" at the edge of the vacuum insulation panel, which also reduces the heat transfer to the interior of the refrigerator.
- the upper surface of the heat insulation material 33 is located on the same plane as the vacuum insulation panel 31, so that the heat insulation panel 3 has a flat surface, which is convenient for being attached to a refrigerator shell and other application scenarios.
- the thickness of the annular groove 315 can be 1/2-2/3 of the thickness of the core material 311, and the annular groove 315 can be arranged near the edge of the core material 311. Further, the annular groove 315 can be It is arranged at a position where one side end surface is flush with the side end surface of the core material 311. Since the heat insulating material 33 is arranged in the annular groove 315 wrapped by the coating material 313, the end surface of the bonded heat insulating material 33 is insulated from the vacuum heat The end faces of the boards 31 are on the same plane, which makes the heat insulation board 3 form a rectangular cross section.
- the heat insulation board 3 has a rectangular cross-section, and the path of external heat transfer through the surface of the coating material 313 becomes longer, further reducing the heat transfer to the interior of the refrigerator, so that the heat insulation board 3 has a better heat insulation effect.
- the refrigerator shell 11 and the liner 13 are filled with foamed polyurethane 5
- the surface of the heat insulation board 3 is smooth and flat, there will be no narrow space that cannot be filled by the foamed polyurethane, avoiding the occurrence of cavities and affecting the quality of the appearance surface, etc. question.
- one embodiment of the present invention provides a method for preparing a heat insulation board, the method comprising the following steps:
- the core material of the heat insulation board can be processed by one-piece molding, or it can be made into a unit size and then laminated. It can be understood that any production method for preparing a core material of a conventional shape can be used.
- the core material may be at least one of glass fiber, glass wool and fumed silica.
- the processing method of the annular groove can choose any conventional processing method, such as milling.
- the thickness of the annular groove may be 1/2-2/3 of the thickness of the core material, and the position of the annular groove may be close to the edge of the end face of the core material.
- the coating material can be a gas barrier material such as aluminum foil or evaporated aluminum.
- the film-coated material bag After decompressing and vacuumizing the core material and the film-coated material bag, the film-coated material bag is heat-pressed and sealed to obtain a vacuum insulation panel with an annular groove.
- the thermal resistance of the thermal insulation material is higher than the thermal resistance of the coating material.
- a mold is prepared according to the size of the annular groove, and a heat insulating material is prepared in the mold.
- the heat insulating material may be at least one of foamed styrene, foamed polyurethane, foamed polyethylene, foamed polypropylene, or other materials with higher thermal resistance than the coating material.
- the surface of the cut heat insulation material is relatively flat and smooth, and the heat insulation material can be fixed in the annular groove of the vacuum heat insulation panel by means of double-sided tape, roller glue, or the like.
- the preparation method of the heat-insulating board provided by the invention has a simple process and is convenient for production and processing; meanwhile, the prepared heat-insulating board can have a good thermal insulation effect.
- a groove for accommodating the getter is processed inside the core material, and the getter is put in.
- the getter can absorb the escaped gas in the core material, further ensuring The degree of vacuum inside the insulation board. Further, the getter can be calcium oxide getter.
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- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Thermal Insulation (AREA)
- Refrigerator Housings (AREA)
Abstract
Description
Claims (10)
- 一种隔热板材,包含真空绝热板和隔热材料;所述真空绝热板包含芯材及覆膜材料,其特征在于,所述芯材一面上开有一环形槽,所述覆膜材料包裹所述芯材,所述芯材与所述覆膜材料之间形成真空;所述隔热材料设置于所述覆膜材料包裹后的环形槽内,所述隔热材料与所述真空绝热板位于同一平面,所述隔热材料热阻高于所述覆膜材料热阻。
- 根据权利要求1所述的隔热板材,其特征在于,所述覆膜材料为铝箔或蒸镀铝。
- 根据权利要求1所述的隔热板材,其特征在于,所述芯材为玻璃纤维、玻璃棉以及气相二氧化硅中的至少一种。
- 根据权利要求1所述的隔热板材,其特征在于,所述隔热材料为发泡苯乙烯、发泡聚氨酯、发泡聚乙烯、发泡聚丙烯中的至少一种。
- 根据权利要求1所述的隔热板材,其特征在于,所述环形槽的厚度为所述芯材厚度的1/2-2/3。
- 根据权利要求1所述的隔热板材,其特征在于,所述环形槽的一侧端面与所述芯材侧端面齐平,使粘结后的所述隔热材料端面与所述真空绝热板端面在同一平面。
- 根据权利要求1所述的隔热板材,其特征在于,所述芯材内部放置有吸气剂。
- 一种冰箱,包含外壳和内胆,其特征在于,如权利要求1所述的隔热板材和发泡聚氨酯设置于冰箱外壳和内胆之间,且所述隔热材料所在面贴附于冰箱外壳上。
- 一种隔热板材的制备方法,其特征在于,该方法包括如下步骤:将制备好的芯材一面加工出环形槽;将带有环形槽的芯材装入预制好的覆膜材料袋中;对芯材和覆膜材料袋进行减压抽真空和热封处理,得到带有环形槽的真空绝热板;根据环形槽的尺寸模制隔热材料,所述隔热材料热阻高于所述覆膜材料热阻;将裁切好的隔热材料粘结在真空绝热板环形槽内,其中,隔热材料与所述真空绝热板位于同一平面。
- 根据权利要求9所述的隔热板材的制备方法,其特征在于,所述芯材为一体 成型或制成单元尺寸后层叠加工。
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
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AU2022300959A AU2022300959A1 (en) | 2021-06-28 | 2022-06-23 | Thermal insulation board and preparation method therefor and refrigerator using thermal insulation board |
EP22831838.2A EP4365474A1 (en) | 2021-06-28 | 2022-06-23 | Thermal insulation board and preparation method therefor and refrigerator using thermal insulation board |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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CN202110718600.1 | 2021-06-28 | ||
CN202110718600.1A CN115596930A (zh) | 2021-06-28 | 2021-06-28 | 隔热板材及其制备方法以及应用该隔热板材的冰箱 |
Publications (1)
Publication Number | Publication Date |
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WO2023274022A1 true WO2023274022A1 (zh) | 2023-01-05 |
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PCT/CN2022/100768 WO2023274022A1 (zh) | 2021-06-28 | 2022-06-23 | 隔热板材及其制备方法以及应用该隔热板材的冰箱 |
Country Status (4)
Country | Link |
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EP (1) | EP4365474A1 (zh) |
CN (1) | CN115596930A (zh) |
AU (1) | AU2022300959A1 (zh) |
WO (1) | WO2023274022A1 (zh) |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11201379A (ja) * | 1998-01-13 | 1999-07-30 | Sanyo Electric Co Ltd | 真空断熱材およびその製造方法 |
JP2001295985A (ja) * | 2000-04-18 | 2001-10-26 | Isuzu Motors Ltd | 真空断熱材、および断熱パネル |
CN201739710U (zh) * | 2010-04-20 | 2011-02-09 | 福建赛特新材料有限公司 | 一种板面带凹槽的真空绝热板 |
JP2011153721A (ja) * | 2010-01-26 | 2011-08-11 | Hitachi Appliances Inc | 冷蔵庫 |
CN104964124A (zh) * | 2014-08-01 | 2015-10-07 | 常州山由帝奥绝缘材料制造有限公司 | 带缺口和/或通孔的真空绝热板及其生产方法 |
CN105371580A (zh) * | 2015-12-15 | 2016-03-02 | 合肥华凌股份有限公司 | 真空绝热板和冰箱 |
CN205316798U (zh) * | 2015-12-15 | 2016-06-15 | 合肥华凌股份有限公司 | 真空绝热板和冰箱 |
CN107461569A (zh) * | 2016-06-06 | 2017-12-12 | 福建赛特新材股份有限公司 | 一种真空绝热板的开孔发泡结构件及真空绝热板 |
CN109707954A (zh) * | 2018-12-28 | 2019-05-03 | 青岛海尔股份有限公司 | 真空绝热板及具有其的冰箱 |
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2021
- 2021-06-28 CN CN202110718600.1A patent/CN115596930A/zh active Pending
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2022
- 2022-06-23 AU AU2022300959A patent/AU2022300959A1/en active Pending
- 2022-06-23 WO PCT/CN2022/100768 patent/WO2023274022A1/zh active Application Filing
- 2022-06-23 EP EP22831838.2A patent/EP4365474A1/en active Pending
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11201379A (ja) * | 1998-01-13 | 1999-07-30 | Sanyo Electric Co Ltd | 真空断熱材およびその製造方法 |
JP2001295985A (ja) * | 2000-04-18 | 2001-10-26 | Isuzu Motors Ltd | 真空断熱材、および断熱パネル |
JP2011153721A (ja) * | 2010-01-26 | 2011-08-11 | Hitachi Appliances Inc | 冷蔵庫 |
CN201739710U (zh) * | 2010-04-20 | 2011-02-09 | 福建赛特新材料有限公司 | 一种板面带凹槽的真空绝热板 |
CN104964124A (zh) * | 2014-08-01 | 2015-10-07 | 常州山由帝奥绝缘材料制造有限公司 | 带缺口和/或通孔的真空绝热板及其生产方法 |
CN105371580A (zh) * | 2015-12-15 | 2016-03-02 | 合肥华凌股份有限公司 | 真空绝热板和冰箱 |
CN205316798U (zh) * | 2015-12-15 | 2016-06-15 | 合肥华凌股份有限公司 | 真空绝热板和冰箱 |
CN107461569A (zh) * | 2016-06-06 | 2017-12-12 | 福建赛特新材股份有限公司 | 一种真空绝热板的开孔发泡结构件及真空绝热板 |
CN109707954A (zh) * | 2018-12-28 | 2019-05-03 | 青岛海尔股份有限公司 | 真空绝热板及具有其的冰箱 |
Also Published As
Publication number | Publication date |
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EP4365474A1 (en) | 2024-05-08 |
CN115596930A (zh) | 2023-01-13 |
AU2022300959A1 (en) | 2024-01-18 |
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