WO2023058477A1 - 含水チョコレート組成物及びその製造方法 - Google Patents

含水チョコレート組成物及びその製造方法 Download PDF

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Publication number
WO2023058477A1
WO2023058477A1 PCT/JP2022/035590 JP2022035590W WO2023058477A1 WO 2023058477 A1 WO2023058477 A1 WO 2023058477A1 JP 2022035590 W JP2022035590 W JP 2022035590W WO 2023058477 A1 WO2023058477 A1 WO 2023058477A1
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Prior art keywords
chocolate
water
weight
composition
chocolate composition
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English (en)
French (fr)
Japanese (ja)
Inventor
恵美 荒川
美紀 村松
拓磨 五十嵐
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Lotte Co Ltd
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Lotte Co Ltd
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Priority to EP22878348.6A priority Critical patent/EP4413865A4/en
Priority to JP2023504051A priority patent/JP7259147B1/ja
Priority to KR1020247014613A priority patent/KR20240065319A/ko
Publication of WO2023058477A1 publication Critical patent/WO2023058477A1/ja
Anticipated expiration legal-status Critical
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    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/50—Cocoa products, e.g. chocolate; Substitutes therefor characterised by shape, structure or physical form, e.g. products with an inedible support
    • A23G1/54—Composite products, e.g. layered, laminated, coated or filled
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/32—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/32—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds
    • A23G1/36—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds characterised by the fats used
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/50—Cocoa products, e.g. chocolate; Substitutes therefor characterised by shape, structure or physical form, e.g. products with an inedible support
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/56—Liquid products; Solid products in the form of powders, flakes or granules for making liquid products, e.g. for making chocolate milk, drinks and the products for their preparation, pastes for spreading or milk crumb

Definitions

  • the present invention relates to a water-containing chocolate composition, a chocolate-containing food containing the water-containing chocolate composition, and a method for producing them.
  • the chocolate fillings that have been distributed in the market so far do not have a sufficient chocolate flavor that can be felt from the fillings, and the fluidity of the fillings is not sufficient, so they do not fully satisfy consumer tastes.
  • Patent Document 1 discloses a greasy confectionery with a water-containing center whose outer shell is less likely to collapse.
  • chocolate dough is used for the production of the center, ie the filling, as described in paragraph 0031, and also includes a step of tempering.
  • it is considered that the water content in the filling is low and the oil-in-water emulsion is not formed.
  • An object of the present invention is to provide a water-containing chocolate composition that has a high chocolate flavor and sufficient fluidity.
  • the present invention is an oil-in-water emulsion obtained by emulsifying a tempered chocolate dough and an aqueous mixture containing 11% by weight or more and 18% by weight or less of cocoa butter and 9% by weight or more and 28% by weight or less of cocoa butter.
  • a hydrous chocolate composition is provided.
  • the water-containing chocolate composition of the present invention has the effect of maintaining its quality for a long period of time, and the chocolate-containing food containing the water-containing chocolate composition of the present invention has a sufficiently long shelf life.
  • the present invention provides the following hydrous chocolate composition as one embodiment. That is, a water-containing chocolate that is an oil-in-water emulsion obtained by emulsifying a tempered chocolate dough and an aqueous mixture containing 11% to 18% by weight of water and 9% to 28% by weight of cocoa butter. A composition is provided.
  • cacao beans refer to those obtained by fermenting and drying cacao (scientific name: Theobroma cacao) seeds. Cocoa nibs are cocoa beans from which the shell has been removed. Cocoa mass refers to ground cocoa nibs. Cocoa butter refers to fat obtained from cocoa beans, cocoa nibs or cocoa mass.
  • chocolate is not limited to the provisions of the fair competition code regarding the labeling of chocolates stipulated by the National Chocolate Industry Fair Trade Council, and refers to all compositions containing cocoa bean-derived components.
  • the water-containing chocolate composition refers to a composition containing water and chocolate dough, and the water-containing chocolate composition of the present invention contains 11% to 18% by weight of water and 9% to 28% by weight of cocoa butter.
  • the hydrous chocolate composition of the present invention comprises 15% to 27% by weight of cocoa butters, more preferably 16% to 20% by weight.
  • the raw material chocolate dough preferably contains 18% by weight or more of cocoa butter.
  • the water-containing chocolate composition preferably contains 35% by weight or more and 50% by weight or less of sugars and/or sugar alcohols in total.
  • the percentages of cocoa butter, cocoa butter, and sugars and/or sugar alcohols referred to herein are based on the dry weight, and the percentage of water is based on the total water content derived from the raw materials.
  • Cocoa butters include cocoa butter and tempered cocoa butter alternatives (CBA).
  • CBA is a fat or oil having glyceride, trans acid, low trans acid, lauric acid, etc. as its structure.
  • CBA is divided into CBE (cocoa butter equivalent), CBI (cocoa butter improver), CBR (cocoa butter replacer), and CBS (cocoa butter substitute) according to the type.
  • Chocolate dough refers to a dough that is a raw material for chocolate.
  • the chocolate dough used to prepare the hydrous chocolate composition preferably contains 18% by weight or more of cocoa butter.
  • the chocolate dough can contain cocoa bean-derived raw materials, cocoa butter substitutes, sweeteners, dairy products, oils and fats, flavors, emulsifiers, etc. as raw materials.
  • Cocoa bean-derived ingredients can include cocoa butter, cocoa nibs, cocoa mass, cocoa powder, and the like.
  • Sweeteners include sugars, sugar alcohols, and high-intensity sweeteners. Examples of sugars and sugar alcohols are the same as the examples of sugars and/or sugar alcohols described later. Examples of high intensity sweeteners include stevioside, glycyrrhizic acid, aspartame, saccharin, acesulfame K, sucralose, neotame, alitame and mixtures thereof.
  • dairy products include milk, fresh cream, skim milk powder, whole milk powder, skim concentrated milk, whey powder, sweetened condensed milk, and mixtures thereof.
  • Fats and oils include vegetable oils and animal oils, and vegetable oils and fats include palm oil, coconut oil, soybean oil, sunflower oil, bran oil, bran oil, olive oil, grape seed oil, walnut oil, apricot kernel oil, virgin coconut oil, avocado oil. , cannabis oil, flax oil, almond oil, evening primrose oil, canola oil, cottonseed oil, sesame oil, or mixtures thereof. I can give an example.
  • flavoring agents include natural flavorings, synthetic flavorings, combined flavorings, alcohols, and mixtures thereof, preferably natural flavorings or synthetic flavorings, and vanilla flavoring and milk flavoring among others.
  • emulsifiers examples include lecithin, glycerin fatty acid esters, sucrose fatty acid esters, sorbitan fatty acid esters, and mixtures thereof.
  • Chocolate dough can be manufactured according to a general method. Examples include the following method.
  • a raw material mixture is prepared so as to contain 10 to 60% by weight of sugar, 5 to 80% by weight of cocoa butter and other cacao-derived raw materials, and 15 to 40% by weight of powdered milk.
  • a raw material mixture is pulverized by a refiner. The pulverized raw material mixture is scouring (conching), and in the latter stage of scouring, flavoring, remaining cocoa butter, emulsifier and the like are added as necessary to prepare chocolate dough.
  • Aqueous mixtures consist of water and components that either dissolve in water or are mixed without separation.
  • aqueous mixtures can include water, sweeteners, fruit juices, fruit sauces, alcohol, flavors, acidulants, dyes, fresh cream, alcoholic beverages, glycerin, thickeners, antioxidants, and the like.
  • sweeteners and flavoring agents are the same as those shown in the chocolate dough described above.
  • acidulants include hydrous citric acid, anhydrous citric acid, sodium citrate, lactic acid, sodium lactate, potassium lactate, malic acid, L-tartaric acids, succinic acids, or gluconic acids.
  • the water-based mixture is obtained by mixing the raw materials and, if necessary, heating and mixing.
  • the water-containing chocolate composition preferably contains 35% by weight or more and 50% by weight or less of sugars and/or sugar alcohols in total. Setting the sugars and/or sugar alcohols within this range contributes to improving the fluidity of the water-containing chocolate composition.
  • the sugars and/or sugar alcohols referred to herein include all sugars and sugar alcohols derived from chocolate dough or water-based mixtures or other raw materials.
  • sugars include monosaccharides such as glucose, galactose, fructose, arabinose, xylose, fucose, sorbose, rhamnose, ribose, tagatose, isomerized liquid sugar, and N-acetylglucosamine; sugar (sucrose), milk sugar (lactose), maltose (maltose), lactulose, trehalose, isotrehalose, neotrehalose, trehalulose, palatinose (isomaltulose), disaccharides such as melibiose; , panose, etc.), oligo-N-acetylglucosamine, galactosyl sucrose, galactosyl lactose, galactopyranosyl ( ⁇ 1-3) galactopyranosyl ( ⁇ 1-4) glucopyranose, galactopyranosyl ( ⁇ 1-3) glucopyranose , galacto
  • sugar alcohols include isomaltitol, erythritol, xylitol, sorbitol, maltitol, maltotetritol, maltotriitol, mannitol, lactitol, reduced palatinose, reduced isomaltooligosaccharide, reduced xylooligosaccharide, reduced gentiooligosaccharide, and reduced maltose.
  • sugar alcohols include starch syrup, reduced starch syrup, and mixtures thereof.
  • Tempering refers to an operation for aligning the crystals of oils and fats such as chocolate into stable crystals for the purpose of suppressing blooming of chocolate and improving gloss, meltability in the mouth, releasability, heat resistance, and the like.
  • crystals of oils and fats such as chocolate, from type I to type VI, and type V is the stable crystal type.
  • tempering tempering by temperature treatment and tempering using a seed agent.
  • Tempering by temperature treatment will be described.
  • the above six types of crystals have different melting points, and tempering by temperature treatment utilizes the difference in melting points. Operation is as follows. That is, first, the chocolate dough is heated to about 40 to 50° C. to melt. It is cooled to about 27-28°C and then rewarmed to about 28-31°C. Upon cooling, initial crystal formation occurs, and upon reheating, melting of unstable crystals and stable crystallization occur, resulting in V-type crystals. After the above operation, cooling and aging further grow V-type crystals.
  • the seed agent is an additive containing a V-shaped template (seed), and by adding the seed agent, the chocolate dough undergoes stable crystallization based on the template and becomes V-shaped crystals.
  • the operation is performed by a method suitable for each seeding agent, the chocolate material is brought to a temperature suitable for the seeding agent, and an appropriate amount of seeding agent at a suitable temperature is added thereto.
  • tempering may be tempering by temperature treatment or tempering using a seed agent.
  • a tempered chocolate dough refers to a chocolate dough that has been subjected to any of the above tempering methods and has V-shaped crystals as the main crystals.
  • Emulsification refers to making a water-based liquid and an oil-based liquid into a dispersion solvent (emulsion). Emulsification is achieved by vigorously stirring the liquids together. Alternatively, it is emulsified using an emulsifier. Emulsions can be of the type either oil-in-water (O/W) emulsions, in which oil droplets are dispersed in water, or water-in-oil (W/O) emulsions. Whether it is an oil-in-water type or a water-in-oil type depends on the amount of liquid and the type of emulsifier.
  • O/W oil-in-water
  • W/O water-in-oil
  • lecithin lecithin, glycerin fatty acid esters, sucrose fatty acid esters, sorbitan fatty acid esters, and mixtures thereof can be exemplified. Both liquids are emulsified by adding an emulsifier to the water-based liquid and the oil-based liquid and stirring.
  • an oil-in-water emulsion can be obtained by stirring the tempered chocolate dough and the water-based mixture with a mixer.
  • the weight ratio of the tempered chocolate dough to the water-based mixture is appropriately selected, preferably 2:3 to 2:1.
  • an emulsifier it can be added as necessary.
  • Mixers are not limited, and homomixers, homogenizers, open mixers and the like can be used.
  • the present invention provides a chocolate-containing food comprising an outer shell and a water-containing chocolate composition, wherein the water-containing chocolate composition is encapsulated in the outer shell.
  • the outer shell can be chocolate, fat composition, biscuit, cake, candy, gummies, ice cream, etc. Chocolate is particularly preferred.
  • the chocolate-containing food described above in which the outer shell is chocolate may be referred to as water-containing chocolate composition-encapsulated outer shell chocolate.
  • the following example can be given as a method for producing the water-containing chocolate composition-encapsulated shell chocolate.
  • a chocolate dough for the upper portion of the chocolate outer shell and a chocolate dough for the bottom portion of the chocolate outer shell are prepared and tempered.
  • the process of encapsulating the water-containing chocolate composition in the chocolate shell is carried out as follows. After the tempered chocolate dough for the upper part of the chocolate outer shell is filled in a mold and cooled and pressed to solidify the chocolate dough, excess chocolate dough is scraped off to form the upper chocolate outer shell.
  • the mold is filled with the tempered chocolate dough for the upper part of the chocolate outer shell, the mold is inverted, and the chocolate is allowed to flow down to a predetermined weight of the chocolate dough for the upper part of the chocolate outer shell. Scrape off to form a chocolate crust top.
  • a separately prepared hydrous chocolate composition is filled on top of the cooled chocolate shell. The surface of the water-containing chocolate composition is leveled by vibration or the like, and then cooled.
  • a tempered chocolate dough for the bottom of the outer shell chocolate is filled here, excess chocolate dough is scraped off, and the mixture is cooled. Thereafter, it is removed from the mold, the encapsulation step is completed, and the water-containing chocolate composition-encapsulated shell chocolate is completed. The finished wet chocolate composition-encapsulated shell chocolate is appropriately packaged.
  • the proportion of the water-containing chocolate composition in the outer shell chocolate encapsulating the water-containing chocolate composition is 40% by weight or more and 70% by weight or less, and the proportion of the shell chocolate is 30% by weight or more and 60% by weight or less. Also, the amount of the water-containing chocolate composition-encapsulated shell chocolate is preferably 3 to 50 grams per grain.
  • the expiration date refers to the period during which the quality of the target food is maintained and it can be eaten deliciously.
  • the water-containing chocolate composition-encapsulated outer shell chocolate containing the water-containing chocolate composition of the present invention maintains good fluidity, mouthfeel, luster, and softness of the water-containing chocolate composition 9 months after production. It was confirmed.
  • a chocolate-containing food product containing the water-containing chocolate composition of the present invention can have an upper shelf life of 5 to 18 months. Although it is not necessary to set a lower limit for the best-before date, it is preferable to set the best-before date to one month or more for reasons such as convenience of distribution in the market.
  • the storage temperature is preferably 25°C or lower, more preferably 23°C or lower.
  • the present invention includes a step of tempering the chocolate dough (step A), and mixing and emulsifying the tempered chocolate dough and the water-based mixture obtained in step A to obtain an oil-in-water emulsion and (step B), wherein the water-containing chocolate composition contains 11% by weight or more and 18% by weight or less of water and 9% by weight or more and 28% by weight or less of cocoa butter.
  • the chocolate dough contains 18% by weight or more of cocoa butter.
  • the water-containing chocolate composition contains 35% by weight or more and 50% by weight or less of sugars and/or sugar alcohols in total.
  • step A is either step A-1 or step A-2 below.
  • step A-1 chocolate dough is heated to about 40 to 50° C. to melt. It is cooled to about 27-28°C and then rewarmed to about 28-31°C.
  • step A-2 the chocolate dough is brought to an addition temperature suitable for the seed agent, and an appropriate amount of the seed agent at the appropriate temperature is added.
  • step B the tempered chocolate dough and the water-based mixture are stirred at a weight ratio of 2:3 to 2:1.
  • a step of tempering the chocolate dough (step A), mixing and emulsifying the tempered chocolate dough and the water-based mixture obtained in the step A to obtain an oil-in-water emulsion
  • a method for producing a chocolate-containing food comprising a step of obtaining a water-containing chocolate composition (step B) and a step of enclosing the water-containing chocolate composition obtained in step B in an outer shell (step C), A method is provided wherein the chocolate composition contains 11% to 18% by weight of water and 9% to 28% by weight of cocoa butters.
  • the chocolate dough contains 18% by weight or more of cocoa butter.
  • the water-containing chocolate composition contains 35% by weight or more and 50% by weight or less of sugars and/or sugar alcohols in total.
  • sugars and/or sugar alcohols in total.
  • the hydrous chocolate compositions of Examples 1 to 10 were produced according to the method described above. That is, a water-containing chocolate composition was obtained by emulsifying a tempered chocolate dough and a water-based mixture. Tempering in Examples 1 to 8 was tempering by temperature treatment. Examples 9 and 10 were tempering with a seeding agent. In addition, as Comparative Examples 1 to 4, water-containing chocolate compositions were produced by emulsifying chocolate dough with an aqueous mixture without tempering. The compositions of the water-containing chocolate compositions of Examples and Comparative Examples are shown in Tables 1 to 3 below.
  • the chocolate dough tempered by the temperature treatment and the water-based mixture were stirred with a mixer at a weight ratio of 1:1 to emulsify them in an oil-in-water type to obtain a water-containing chocolate composition.
  • the content of the water-containing chocolate composition is 10% by weight of whole milk powder, 18% by weight of cocoa butter, 47% by weight of sugars and sugar alcohols, 16% by weight of water, and 9% of others (both weight percentages including water in the mixture). Met.
  • a water-containing chocolate composition-encapsulated shell chocolate was produced.
  • the upper part of the chocolate-shell accounted for 35% by weight, the water-containing chocolate composition for 40% by weight, and the bottom part for the chocolate-for-shell 25% by weight.
  • Tables 1 and 2 the total composition of cocoa butters, sugars and sugar alcohols is shown by dry weight. Moisture percentages are based on the total moisture from the ingredients.
  • the water-containing chocolate composition of each example and comparative example was enclosed in a chocolate shell to obtain a water-containing chocolate composition-encapsulated shell chocolate.
  • these may be referred to as the outer shell chocolates in which the water-containing chocolate composition is enclosed in Examples 1 to 10, the outer shell chocolates in which the water-containing chocolate composition is enclosed in Comparative Examples 1 to 4, and the like.
  • Comparative Examples 1 to 4 and Examples 1 to 10 were stored at 18° C. for 4 to 8 weeks from the time of production of the water-containing chocolate composition-encapsulated shell chocolate, which was performed on the same day as the production of the water-containing chocolate composition. It was later subjected to an evaluation test. Each evaluation result is shown in Table 1. 18° C. is the temperature generally used for aging to stabilize chocolate products. Furthermore, Comparative Example 2 and Example 3 were subjected to an evaluation test and a viscosity measurement test after being stored at 18°C for 24 hours, after being stored at 23°C for 9 months, and after being stored at 25°C for 9 months. rice field.
  • Comparative Examples 1, 3, 4 and Examples 1, 5, 8, 9, 10 were subjected to the evaluation test and the viscosity measurement test after being stored at 23° C. for 9 months.
  • Tables 2 and 3 show the storage temperatures, periods, evaluation results, and viscosity measurement test results.
  • the viscosity indicates the average value of the results of two measurements.
  • Table 4 shows the viscosity ratio after storage. In calculating this ratio, the average value of two measurements was used for each viscosity.
  • the evaluation test was conducted as follows.
  • the water-containing chocolate composition-encapsulated outer shell chocolates of Examples 1 to 10 and Comparative Examples 1 to 4 which had been stored at each temperature for a specified period of time, were temperature-controlled to 25°C immediately before the evaluation test.
  • a chocolate analysis panel of five people ate and observed the outer shell chocolates containing the water-containing chocolate compositions of Examples 1 to 10 and Comparative Examples 1 to 4 after each storage period, and evaluated each water-containing chocolate composition. made an evaluation. Fluidity was evaluated as a primary evaluation, and melting in the mouth, luster and softness were evaluated as a secondary evaluation.
  • the evaluation criteria were as follows. In all results, the ratings were concordant with an analytical panel of 5 people.
  • Fluidity A A semi-solid and viscous substance that feels as if it slides on the tongue when put in the mouth.
  • B A semi-solid, viscous state that remains on the tongue.
  • C A semi-solid state that is viscous, tight, and stays on the tongue.
  • D It is in a semi-solid state and viscous, and grains are generated and it is in a crumbly state.
  • A A state in which the time to cling in the mouth is short.
  • B A state in which the feeling of clinging in the mouth is weak.
  • C A state in which a strong feeling of clinging to the mouth is felt.
  • D A state in which the feeling of clinging to the mouth is strongly felt and the tongue is rough.
  • Gloss A A state in which light is reflected on the water-containing chocolate composition on the cut surface of the outer shell chocolate encapsulating the water-containing chocolate composition, giving off a gloss.
  • B When light hits the water-containing chocolate composition on the cut surface of the outer shell chocolate encapsulating the water-containing chocolate composition, the light is reflected weakly as a whole.
  • C A state in which when light hits the water-containing chocolate composition on the cut surface of the outer shell chocolate encapsulating the water-containing chocolate composition, only a part of the light is weakly reflected.
  • D A state in which light is not reflected at all even when the water-containing chocolate composition on the cut surface of the outer shell chocolate encapsulating the water-containing chocolate composition is exposed to light.
  • Softness A A state in which the pieces are united, but can be easily deformed by the force of the tongue.
  • B A state in which a unity is formed but is not easily deformed.
  • C A state in which elasticity is felt although it is a unity.
  • D It is in a rough and hard state although it is one unity.
  • Viscosity was measured as follows. That is, the water-containing chocolate composition was scraped from the shell chocolate encapsulating the water-containing chocolate composition, and dynamic viscoelasticity was measured using a rheometer (MCR102 manufactured by Anton Paar). The sample was sandwiched between parallel plates temperature-controlled to 20° C., and temperature dispersion measurement was performed. Specifically, a sinusoidal vibration was applied to the sample while heating from 20°C to 35°C at a rate of temperature increase of 2°C/min, and the viscosity at 30°C was calculated. The measurement conditions were as follows.
  • Viscosity is an index indicating the flexibility of an object, and it can be said that the lower the viscosity, the higher the fluidity, and the higher the viscosity, the lower the fluidity. It is preferable that the water-containing chocolate composition used for the water-containing chocolate composition-encapsulated outer shell chocolate of the present invention has high fluidity, and that the change in state over time is small.
  • the water-containing chocolate compositions of Examples 1 to 8 which were tempered by temperature treatment, showed fluidity in the outer-shell chocolate encapsulating the water-containing chocolate composition after storage for 4 to 8 weeks after production. , melting in the mouth, luster, and softness were all A or B, which were excellent.
  • Comparative Examples 1 to 4 the evaluation was C or D after storage for 4 to 8 weeks after production. If the evaluation is A or B, it is determined that sufficient quality is maintained.
  • the water-containing chocolate composition of Example 3 had fluidity in the outer shell chocolate encapsulating the water-containing chocolate composition after storage for 24 hours and after storage for 9 months after production. , melting in the mouth, luster, and softness were evaluated as A or B, which were very excellent. On the other hand, in Comparative Example 2, the evaluation was A after storage for 24 hours, but the evaluation was C or D after storage for 9 months. In addition, the water-containing chocolate compositions of Examples 1, 3, 5, 8, 9 and 10 were evaluated as D in all points of fluidity, melting in the mouth, luster and softness after storage at 23°C for 9 months.
  • the water-containing chocolate compositions of Examples 3, 5, 9 and 10 were evaluated as A or B in all points of fluidity, melt in the mouth, gloss and softness after storage at 23 ° C. for 9 months. was From this result, it can be said that the water-containing chocolate composition of the present invention containing 9% by weight or more and 28% by weight or less of cocoa butter and using a tempered chocolate dough maintained good quality after storage. In particular, it can be said that the quality after storage is maintained more preferably when 15% to 27% by weight of cocoa butter is contained. Further, from the results in Tables 2 and 4, after storage at 23° C., the viscosity was kept lower in all of the tested examples than in the corresponding comparative examples.
  • Example 8 contains 28% by weight of cocoa butter, the maximum amount within the scope of the present invention, and exhibits a particularly effective chocolate flavor, while maintaining such an effect and 9 months at 23 ° C.
  • the viscosity after storage was remarkably suppressed compared to the corresponding Comparative Example 4.
  • the viscosity after storage at 23° C. for 9 months was lower than that of any of the comparative examples after storage.
  • the viscosity of the water-containing chocolate composition of the present invention after storage is kept lower when it contains 15% to 27% by weight of cocoa butter.
  • the water-containing chocolate composition of Example 3 in particular had a significantly low viscosity after storage at 23°C for 9 months and after storage at 25°C for 9 months. rice field. From these results, it was found that the viscosity of the water-containing chocolate composition of the present invention after storage was remarkably reduced at any storage temperature when the cocoa butter content was 16% to 20% by weight. I can say.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
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  • Polymers & Plastics (AREA)
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PCT/JP2022/035590 2021-10-04 2022-09-26 含水チョコレート組成物及びその製造方法 Ceased WO2023058477A1 (ja)

Priority Applications (3)

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EP22878348.6A EP4413865A4 (en) 2021-10-04 2022-09-26 CHOCOLATE COMPOSITION CONTAINING WATER AND PROCESS FOR PRODUCING THE SAME
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TW202329821A (zh) 2023-08-01
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