WO2023027559A1 - 블록 공중합체 및 이의 제조 방법 - Google Patents
블록 공중합체 및 이의 제조 방법 Download PDFInfo
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- WO2023027559A1 WO2023027559A1 PCT/KR2022/012838 KR2022012838W WO2023027559A1 WO 2023027559 A1 WO2023027559 A1 WO 2023027559A1 KR 2022012838 W KR2022012838 W KR 2022012838W WO 2023027559 A1 WO2023027559 A1 WO 2023027559A1
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- Prior art keywords
- block copolymer
- formula
- mol
- hydroxypropionate
- poly
- Prior art date
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- 229920001400 block copolymer Polymers 0.000 title claims abstract description 51
- 238000002360 preparation method Methods 0.000 title description 11
- -1 poly(3-hydroxypropionate) Polymers 0.000 claims description 38
- RKDVKSZUMVYZHH-UHFFFAOYSA-N 1,4-dioxane-2,5-dione Chemical compound O=C1COC(=O)CO1 RKDVKSZUMVYZHH-UHFFFAOYSA-N 0.000 claims description 14
- 239000000178 monomer Substances 0.000 claims description 14
- 229920005989 resin Polymers 0.000 claims description 12
- 239000011347 resin Substances 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 239000011342 resin composition Substances 0.000 claims description 7
- 239000003054 catalyst Substances 0.000 claims description 6
- 238000007151 ring opening polymerisation reaction Methods 0.000 claims description 6
- ALRHLSYJTWAHJZ-UHFFFAOYSA-M 3-hydroxypropionate Chemical compound OCCC([O-])=O ALRHLSYJTWAHJZ-UHFFFAOYSA-M 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- 229910052717 sulfur Inorganic materials 0.000 claims description 5
- BOZRCGLDOHDZBP-UHFFFAOYSA-N 2-ethylhexanoic acid;tin Chemical group [Sn].CCCCC(CC)C(O)=O BOZRCGLDOHDZBP-UHFFFAOYSA-N 0.000 claims description 4
- 125000002947 alkylene group Chemical group 0.000 claims description 3
- 125000000732 arylene group Chemical group 0.000 claims description 3
- 125000005549 heteroarylene group Chemical group 0.000 claims description 3
- 125000005842 heteroatom Chemical group 0.000 claims description 3
- 239000003999 initiator Substances 0.000 claims description 3
- 229910052772 Samarium Inorganic materials 0.000 claims description 2
- 125000003545 alkoxy group Chemical group 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 238000001125 extrusion Methods 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 239000010408 film Substances 0.000 claims description 2
- 239000006260 foam Substances 0.000 claims description 2
- 238000002347 injection Methods 0.000 claims description 2
- 239000007924 injection Substances 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000004745 nonwoven fabric Substances 0.000 claims description 2
- 229910052727 yttrium Inorganic materials 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 2
- ALRHLSYJTWAHJZ-UHFFFAOYSA-N 3-hydroxypropionic acid Chemical compound OCCC(O)=O ALRHLSYJTWAHJZ-UHFFFAOYSA-N 0.000 description 26
- 229920000954 Polyglycolide Polymers 0.000 description 20
- 239000004633 polyglycolic acid Substances 0.000 description 20
- 230000000052 comparative effect Effects 0.000 description 13
- 238000005481 NMR spectroscopy Methods 0.000 description 11
- 230000000704 physical effect Effects 0.000 description 11
- 238000005227 gel permeation chromatography Methods 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- BYEAHWXPCBROCE-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropan-2-ol Chemical compound FC(F)(F)C(O)C(F)(F)F BYEAHWXPCBROCE-UHFFFAOYSA-N 0.000 description 7
- 238000005259 measurement Methods 0.000 description 6
- 239000003208 petroleum Substances 0.000 description 5
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 4
- 239000001913 cellulose Substances 0.000 description 4
- 229920002678 cellulose Polymers 0.000 description 4
- 238000009264 composting Methods 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 2
- 229920006362 Teflon® Polymers 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000012662 bulk polymerization Methods 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 239000002361 compost Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000012046 mixed solvent Substances 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 239000010421 standard material Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229920003232 aliphatic polyester Polymers 0.000 description 1
- 229920006167 biodegradable resin Polymers 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000011088 calibration curve Methods 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000012776 electronic material Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000005003 food packaging material Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
- C08G63/08—Lactones or lactides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/91—Polymers modified by chemical after-treatment
- C08G63/912—Polymers modified by chemical after-treatment derived from hydroxycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2230/00—Compositions for preparing biodegradable polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/70—Post-treatment
- C08G2261/75—Reaction of polymer building blocks for the formation of block-copolymers
Definitions
- n is 10 to 700 and m is 10 to 700. More preferably, n is 20 or more, 30 or more, 40 or more, 50 or more, or 60 or more, and is 650 or less, 600 or less, 550 or less, 500 or less, or 450 or less.
- the weight ratio of the poly(3-hydroxypropionate) and glycolide monomers in step 2 is 1:99 to 99:1. More preferably, the weight ratio of poly(3-hydroxypropionate) and glycolide monomers in step 2 is 1:50 to 50:1, 1:20 to 20:1, 1:10 to 10:1, or 1:1 to 1:10.
- the weight average molecular weight (Mw) and number average molecular weight (Mn) of the block copolymers prepared in Examples 1 and 2 were measured using gel permeation chromatography (GPC, Waters E2640), and the results are shown in FIG. 4 and shown in FIG. 5 .
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Polyesters Or Polycarbonates (AREA)
- Biological Depolymerization Polymers (AREA)
Abstract
Description
인장강도 (MPa) | 영률 (MPa) | 인장 신율 (%) | |
비교예 2 | N/D | N/D | N/D |
실시예 1 | 32.6 | 1402 | 49.27 |
Claims (14)
- 하기 화학식 1로 표시되는,블록 공중합체:[화학식 1]상기 화학식 1에 있어서,R1, 및 R2는 각각 독립적으로, 수소, N, O, S, 또는 치환 또는 비치환된 C1-20 알킬이고,X1, 및 X2는 각각 독립적으로, 직접 결합, -COO-, -NR'CO-, -(NR')(COO)-, -R'NCONR'-, 또는 -OCOO-이고,R'는 각각 독립적으로, 수소, 또는 C1-20 알킬이고,L은 직접 결합; 치환 또는 비치환된 C1-10 알킬렌; 치환 또는 비치환된 C6-60 아릴렌; 또는 치환 또는 비치환된 N, O, 및 S로 구성되는 군으로부터 선택되는 어느 하나 이상의 헤테로원자를 포함하는 C2-60 헤테로아릴렌이고,n 및 m은 각각 독립적으로, 1 내지 10,000의 정수이다.
- 제1항에 있어서,X1, X2, 및 L은 직접 결합인,블록 공중합체.
- 제1항에 있어서,n은 10 내지 700이고,m은 10 내지 700인,블록 공중합체.
- 제1항에 있어서,블록 공중합체의 중량평균분자량은 10,000 g/mol 내지 500,000 g/mol인,블록 공중합체.
- 폴리(3-하이드록시프로피오네이트)를 제조하는 단계(단계 1);폴리(3-하이드록시프로피오네이트) 개시제의 존재 하에, 글리콜라이드 단량체를 개환 중합하여 블록 공중합체를 제조하는 단계(단계 2)를 포함하는,블록 공중합체의 제조 방법.
- 제6항에 있어서,상기 단계 1의 폴리(3-하이드록시프로피오네이트)는 중량평균분자량이 1,000 g/mol 내지 500,000 g/mol인,블록 공중합체의 제조 방법.
- 제6항에 있어서,상기 단계 2의 폴리(3-하이드록시프로피오네이트) 및 글리콜라이드 단량체의 중량비는 1:99 내지 99:1인블록 공중합체의 제조 방법.
- 제6항에 있어서,상기 단계 2는 하기 화학식 4로 표시되는 촉매 존재 하에서 진행되는,블록 공중합체의 제조 방법:[화학식 4]MA1 pA2 2-p상기 화학식 4에서,M은 Al, Mg, Zn, Ca, Sn, Fe, Y, Sm, Lu, Ti 또는 Zr이고,p는 0 내지 2의 정수이고,A1과 A2는 각각 독립적으로 알콕시 또는 카르복실기이다.
- 제6항에 있어서,촉매는 주석(II) 2-에틸헥사노에이트인,블록 공중합체의 제조 방법.
- 제1항 내지 제5항에 따른 블록 공중합체를 포함하는, 수지.
- 제11항의 수지를 포함하는, 수지 조성물.
- 제12항에 있어서,상기 수지 조성물은 사출 성형품, 압출 성형품, 인플레이션 성형품, 섬유, 부직포, 발포체, 필름, 및 시트로 구성되는 군으로부터 선택되는 어느 하나 이상의 성형품으로 성형되는,수지 조성물.
- 제1항 내지 제5항에 따른 블록 공중합체를 포함하는, 물품.
Priority Applications (4)
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JP2023546130A JP2024505534A (ja) | 2021-08-27 | 2022-08-26 | ブロック共重合体およびその製造方法 |
EP22861767.6A EP4227344A1 (en) | 2021-08-27 | 2022-08-26 | Block copolymer and preparation method therefor |
US18/039,676 US20240010788A1 (en) | 2021-08-27 | 2022-08-26 | Block copolymer and method for preparation thereof` |
CN202280007553.2A CN116635450A (zh) | 2021-08-27 | 2022-08-26 | 嵌段共聚物及其制备方法 |
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KR10-2021-0113916 | 2021-08-27 | ||
KR20210113916 | 2021-08-27 |
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WO2023027559A1 true WO2023027559A1 (ko) | 2023-03-02 |
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US (1) | US20240010788A1 (ko) |
EP (1) | EP4227344A1 (ko) |
JP (1) | JP2024505534A (ko) |
KR (1) | KR20230031803A (ko) |
CN (1) | CN116635450A (ko) |
WO (1) | WO2023027559A1 (ko) |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100280193A1 (en) * | 2009-05-01 | 2010-11-04 | E. I. Du Pont De Nemours And Company | Antistatic poly(hydroxyalkanoic acid) compositions |
US20160229952A1 (en) * | 2010-07-28 | 2016-08-11 | Coleen Pugh | Functional biodegradable polymers |
KR20200115165A (ko) * | 2019-03-26 | 2020-10-07 | 주식회사 엘지화학 | 블록 공중합체 제조 방법 |
KR102249223B1 (ko) * | 2018-12-28 | 2021-05-07 | 성균관대학교산학협력단 | 고강도 인체흡수성 폴리글리콜산계 블록공중합체 수지 및 이의 제조 방법 |
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2022
- 2022-08-26 JP JP2023546130A patent/JP2024505534A/ja active Pending
- 2022-08-26 EP EP22861767.6A patent/EP4227344A1/en active Pending
- 2022-08-26 KR KR1020220107866A patent/KR20230031803A/ko unknown
- 2022-08-26 US US18/039,676 patent/US20240010788A1/en active Pending
- 2022-08-26 CN CN202280007553.2A patent/CN116635450A/zh active Pending
- 2022-08-26 WO PCT/KR2022/012838 patent/WO2023027559A1/ko active Application Filing
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100280193A1 (en) * | 2009-05-01 | 2010-11-04 | E. I. Du Pont De Nemours And Company | Antistatic poly(hydroxyalkanoic acid) compositions |
US20160229952A1 (en) * | 2010-07-28 | 2016-08-11 | Coleen Pugh | Functional biodegradable polymers |
KR102249223B1 (ko) * | 2018-12-28 | 2021-05-07 | 성균관대학교산학협력단 | 고강도 인체흡수성 폴리글리콜산계 블록공중합체 수지 및 이의 제조 방법 |
KR20200115165A (ko) * | 2019-03-26 | 2020-10-07 | 주식회사 엘지화학 | 블록 공중합체 제조 방법 |
Non-Patent Citations (1)
Title |
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LITTLE ALASTAIR, WEMYSS ALAN M., HADDLETON DAVID M., TAN BOWEN, SUN ZHAOYANG, JI YANG, WAN CHAOYING: "Synthesis of Poly(Lactic Acid-co-Glycolic Acid) Copolymers with High Glycolide Ratio by Ring-Opening Polymerisation", POLYMERS, vol. 13, no. 15, pages 2458, XP093038707, DOI: 10.3390/polym13152458 * |
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Publication number | Publication date |
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JP2024505534A (ja) | 2024-02-06 |
EP4227344A1 (en) | 2023-08-16 |
KR20230031803A (ko) | 2023-03-07 |
CN116635450A (zh) | 2023-08-22 |
US20240010788A1 (en) | 2024-01-11 |
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