WO2022154009A1 - 発光装置 - Google Patents

発光装置 Download PDF

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Publication number
WO2022154009A1
WO2022154009A1 PCT/JP2022/000709 JP2022000709W WO2022154009A1 WO 2022154009 A1 WO2022154009 A1 WO 2022154009A1 JP 2022000709 W JP2022000709 W JP 2022000709W WO 2022154009 A1 WO2022154009 A1 WO 2022154009A1
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WIPO (PCT)
Prior art keywords
metal
containing layer
layer
light emitting
emitting device
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
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PCT/JP2022/000709
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English (en)
French (fr)
Japanese (ja)
Inventor
純 高橋
範明 和氣
真滋 中嶋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tohoku Pioneer Corp
Pioneer Corp
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Tohoku Pioneer Corp
Pioneer Corp
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Priority to JP2022575605A priority Critical patent/JPWO2022154009A1/ja
Priority to US18/271,142 priority patent/US20230413597A1/en
Publication of WO2022154009A1 publication Critical patent/WO2022154009A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/80—Constructional details
    • H10K59/805—Electrodes
    • H10K59/8052—Cathodes
    • H10K59/80522—Cathodes combined with auxiliary electrodes
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B33/00—Electroluminescent light sources
    • H05B33/12—Light sources with substantially two-dimensional [2D] radiating surfaces
    • H05B33/26—Light sources with substantially two-dimensional [2D] radiating surfaces characterised by the composition or arrangement of the conductive material used as an electrode
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B33/00—Electroluminescent light sources
    • H05B33/12—Light sources with substantially two-dimensional [2D] radiating surfaces
    • H05B33/26—Light sources with substantially two-dimensional [2D] radiating surfaces characterised by the composition or arrangement of the conductive material used as an electrode
    • H05B33/28—Light sources with substantially two-dimensional [2D] radiating surfaces characterised by the composition or arrangement of the conductive material used as an electrode of translucent electrodes
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/80—Constructional details
    • H10K50/805—Electrodes
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/80—Constructional details
    • H10K50/805—Electrodes
    • H10K50/82—Cathodes
    • H10K50/826—Multilayers, e.g. opaque multilayers
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/80—Constructional details
    • H10K50/84—Passivation; Containers; Encapsulations
    • H10K50/846—Passivation; Containers; Encapsulations comprising getter material or desiccants
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K2102/00—Constructional details relating to the organic devices covered by this subclass
    • H10K2102/20—Metallic electrodes, e.g. using a stack of layers
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K2102/00—Constructional details relating to the organic devices covered by this subclass
    • H10K2102/301—Details of OLEDs
    • H10K2102/351—Thickness
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/80—Constructional details
    • H10K59/87—Passivation; Containers; Encapsulations
    • H10K59/871—Self-supporting sealing arrangements
    • H10K59/872—Containers

Definitions

  • the present invention relates to a light emitting device.
  • Patent Document 1 describes a light emitting device including a first electrode, an organic layer, and a plurality of second electrodes arranged in a stripe shape and having a light-shielding property.
  • the region of the light emitting device located between the adjacent second electrodes is a translucent portion through which light from the outside is transmitted.
  • the light emitting device has a translucent property due to a translucent portion.
  • the first metal containing each second electrode is contained.
  • the layer may be covered by a second metal-containing layer.
  • a voltage can be supplied to each first metal-containing layer via the second metal-containing layer while maintaining the translucency of the light emitting device.
  • the thickness of the second metal-containing layer is relatively thin, the metals contained in the second metal-containing layer may be separated from each other in a plurality of islands, and the flatness of the second metal-containing layer may not be ensured.
  • the invention according to claim 1 With the board A first electrode located on the substrate and having translucency, The organic layer located on the first electrode and A plurality of first metal-containing layers located on the organic layer and having a light-shielding property, A metal compound-containing layer that covers the plurality of first metal-containing layers and has translucency, A second metal-containing layer that covers the metal compound-containing layer and has translucency, It is a light emitting device provided with.
  • the expression "A is located on B” means, for example, that A is directly located on B without any other element (eg, layer) located between A and B. It may be used, or it may mean that another element (for example, a layer) is partially or wholly located between A and B.
  • expressions indicating the orientations such as “up”, “bottom”, “left”, “right”, “front”, and “back” are basically used in combination with the orientation of the drawing, for example, a book. It is not construed as being limited to the direction in which the invention described in the specification is used.
  • the expression "A and B overlap" means that at least a part of A is in the same place as at least a part of B in a projected image from a certain direction unless otherwise specified.
  • the plurality of elements may be in direct contact with each other or may be separated from each other.
  • the anode means an electrode for injecting holes into a layer containing a light emitting material (for example, an organic layer), and the cathode means an electrode for injecting electrons into a layer containing a light emitting material.
  • a light emitting material for example, an organic layer
  • the cathode means an electrode for injecting electrons into a layer containing a light emitting material.
  • the expressions "anode” and “cathode” may also mean other terms such as “hole injection electrode” and “electron injection electrode” or "positive electrode” and “negative electrode”.
  • the "light emitting device” in the present specification includes a device having a light emitting element such as a display or lighting.
  • the “light emitting device” may also include wiring, an IC (integrated circuit), a housing, etc. that are directly, indirectly, or electrically connected to the light emitting element.
  • connection means a state in which a plurality of elements are connected directly or indirectly.
  • an adhesive or a joining member is connected between a plurality of elements, it may be simply expressed as "a plurality of elements are connected”.
  • each member and each element may be singular or plural. However, this is not limited to the case where "singular” or “plural” is clarified in the context.
  • the expression "A includes B” is not limited to A being composed only of B, and means that A can be composed of elements other than B, unless otherwise specified. ..
  • cross section means a surface that appears when the light emitting device is cut in the direction in which pixels, light emitting materials, etc. are laminated, unless otherwise specified.
  • the expression "A covers B” means that A contacts B without any other element (for example, a layer) located between A and B unless otherwise specified. Alternatively, it may mean that another element (eg, a layer) is partially or wholly located between A and B.
  • a has translucency means that the average transmittance of A in the wavelength band of 400 nm or more and 700 nm or less is, for example, 50% or more.
  • a has a light-shielding property means that the average transmittance of A in the wavelength band of 400 nm or more and 700 nm or less is, for example, less than 50%.
  • a contains a as a main component means that the amount of a contained in A is 75 parts by mass or more with respect to 100 parts by mass of the total mass of A, unless otherwise specified. do.
  • metal means not only a metal composed of a single metal element but also an alloy unless otherwise specified.
  • FIG. 1 is a schematic cross-sectional view of the light emitting device 10 according to the embodiment.
  • the light emitting device 10 includes a substrate 100, a first electrode 110, an organic layer 120, an electron injection layer 122, a plurality of first metal-containing layers 132, a metal compound-containing layer 134, a second metal-containing layer 136, a cap layer 150, and a seal.
  • a part 160 and a desiccant 170 are provided.
  • the substrate 100 has a first surface 102 and a second surface 104.
  • the first electrode 110, the organic layer 120, the electron injection layer 122, the plurality of first metal-containing layers 132, the metal compound-containing layer 134, the second metal-containing layer 136, the cap layer 150, the sealing portion 160, and the desiccant 170 are It is located on the first surface 102 side.
  • the second surface 104 is located on the opposite side of the first surface 102.
  • the first side S1 indicated by the arrow indicates the side of the light emitting device 10 where the organic layer 120 is located with respect to the side where the plurality of first metal-containing layers 132 are located.
  • the second side S2 indicated by the arrow indicates the side of the light emitting device 10 where the plurality of first metal-containing layers 132 are located with respect to the side where the organic layer 120 is located.
  • the double-headed arrows indicating the first side S1 and the second side S2 indicate the direction perpendicular to the first surface 102 or the second surface 104.
  • the substrate 100 has translucency.
  • the substrate 100 may have a single layer or a plurality of layers.
  • the thickness of the substrate 100 is, for example, 10 ⁇ m or more and 1000 ⁇ m or less.
  • the substrate 100 is, for example, a glass substrate.
  • the substrate 100 may be a resin substrate containing an organic material (for example, PEN (polyethylene naphthalate), PES (polyether sulfone), PET (polyethylene terephthalate) or polyimide).
  • an inorganic barrier layer for example, SiN or SiON
  • SiN or SiON may be located on at least one of the first surface 102 and the second surface 104.
  • the first electrode 110 has translucency.
  • the first electrode 110 is located on the first surface 102.
  • the first electrode 110 functions as an anode.
  • the first electrode 110 is made of ITO (Indium Tin Oxide), IZO (Indium Zinc Oxide), IWZO (Indium Tungsten Zinc Oxide), ZnO (Zinc Oxide), IGZO (Zinc Oxide), IGZO (India Zinc Oxide), etc. Includes.
  • the first electrode 110 may contain a metal such as sterling silver or a silver alloy. In this example, the thickness of the first electrode 110 is so thin that the first electrode 110 has translucency.
  • the organic layer 120 has translucency.
  • the organic layer 120 is located on the first electrode 110.
  • the organic layer 120 includes a light emitting layer.
  • the light emitting layer emits light by organic electroluminescence (EL).
  • the organic layer 120 may appropriately include other layers such as a hole injection layer (HIL), a hole transport layer (HTL), and an electron transport layer (ETL).
  • HIL hole injection layer
  • HTL hole transport layer
  • ETL electron transport layer
  • the electron injection layer 122 is located on the organic layer 120.
  • the electron injection layer 122 contains an alkali metal compound such as Li 2 O. If the electron injection layer 122 contains a metal such as an alkali metal such as Li or an alkaline earth metal such as Ca instead of the alkali metal compound, the case where the electron injection layer 122 contains an alkali metal compound is compared with the case where the electron injection layer 122 contains an alkali metal compound.
  • the electron injection layer 122 preferably contains an alkali metal compound rather than a metal.
  • the electron injection layer 122 may not be provided. Further, the electron injection layer 122 may contain a metal.
  • the plurality of first metal-containing layers 132, the metal compound-containing layer 134, and the second metal-containing layer 136 are located on the electron injection layer 122.
  • the cap layer 150 covers the second metal-containing layer 136.
  • the cap layer 150 contains, for example, an organic material. This organic material may be the same as the organic material contained in the organic layer 120, for example.
  • the sealing portion 160 is a laminate including a first electrode 110, an organic layer 120, an electron injection layer 122, a plurality of first metal-containing layers 132, a metal compound-containing layer 134, a second metal-containing layer 136, and a cap layer 150. It is sealed.
  • the sealing portion 160 is a sealing can attached to the first surface 102 of the substrate 100 via the adhesive layer 162. Further, the space between the sealing portion 160 and the laminated body is hollow.
  • the sealing portion 160 is not limited to the example shown in FIG.
  • the sealing portion 160 may be a sealing layer that covers the laminated body.
  • the sealing layer contains an inorganic extinct material such as alumina (Al 2 O 3 ) and titania (TIO 2 ) formed by ALD (Atomic Layer Deposition).
  • the desiccant 170 is located in the region sealed by the sealing portion 160.
  • the desiccant 170 is attached to a surface of the sealing portion 160 located on the region side sealed by the sealing portion 160.
  • the plurality of first metal-containing layers 132 are located on the electron injection layer 122.
  • Each first metal-containing layer 132 has a light-shielding property, specifically, a light reflection property.
  • the first metal-containing layer 132 contains a metal as a main component.
  • the first metal-containing layer 132 contains aluminum such as pure aluminum and an aluminum alloy.
  • the metal contained in the first metal-containing layer 132 is not limited to the above example.
  • the thickness of the first metal-containing layer 132 is not particularly limited, but can be, for example, 50 nm or more and 300 nm or less.
  • the first metal-containing layer 132 functions to support the injection of electrons into the organic layer 120.
  • the work function of the metal contained in the first metal-containing layer 132 is larger than, for example, the minimum empty orbital (LUMO) of the electron transport material contained in the organic layer 120, and is larger than the work function of the metal contained in the second metal-containing layer 136. It's getting smaller.
  • the work function of the metal contained in the first metal-containing layer 132 can be 3.5 eV or more and 4.4 eV or less.
  • the work function of the metal contained in the first metal-containing layer 132 is not limited to this example.
  • a plurality of light emitting portions 142 and translucent portions 144 are defined in the light emitting device 10 by the plurality of first metal-containing layers 132.
  • Each light emitting unit 142 includes a portion of the first electrode 110, the organic layer 120, and the electron injection layer 122 that overlaps with each first metal-containing layer 132 in a direction perpendicular to the first surface 102 or the second surface 104, and a first unit. It has a metal-containing layer 132 and.
  • the light generated in the organic layer 120 in the light emitting unit 142 and emitted toward the first electrode 110 passes through the first electrode 110 and the substrate 100 and is emitted from the first side S1.
  • the light generated in the organic layer 120 in the light emitting unit 142 and emitted toward the first metal-containing layer 132 is reflected by the first metal-containing layer 132 and passes through the first electrode 110 and the substrate 100 to pass through the first metal-containing layer 132. It is emitted from the side S1.
  • the light transmitting portion 144 is located between the light emitting portions 142 adjacent to each other in the direction parallel to the first surface 102 or the second surface 104.
  • a light-shielding member is not provided in the light-transmitting portion 144 and the region of the light emitting device 10 that overlaps the light-transmitting portion 144 in the direction perpendicular to the first surface 102 or the second surface 104. Therefore, the light from the outside of the light emitting device 10 can be transmitted from one of the first side S1 and the second side S2 to the other. As a result, the light emitting device 10 has translucency.
  • the metal compound-containing layer 134 covers a plurality of first metal-containing layers 132.
  • the metal compound-containing layer 134 has translucency.
  • the metal compound-containing layer 134 contains a metal compound such as a metal oxide or a metal sulfide as a main component.
  • the metal compound-containing layer 134 includes molybdenum oxide (VI), molybdenum oxide (IV) and other molybdenum oxide, tungsten oxide (VI) and other tungsten oxide, vanadium oxide (V) and other vanadium oxide, and titanium oxide (IV).
  • tantalum oxide such as tantalum oxide (V)
  • renium oxide such as renium oxide (VI)
  • zinc sulfide preferably contains molybdenum oxide (VI).
  • the metal compound contained in the metal compound-containing layer 134 is not limited to the above example.
  • a metal compound having an oxidation number different from the oxidation number exemplified above can be used as long as the metal compound is chemically stable.
  • a metal compound having a work function close to the work function of molybdenum oxide (VI) can be used.
  • the work function of the metal compound contained in the metal compound-containing layer 134 can be made larger than 5.7 eV.
  • the work function of the metal compound contained in the metal compound-containing layer 134 is not limited to this example.
  • the thickness of the second metal-containing layer 136 is ensured to ensure the translucency of the second metal-containing layer 136 as compared with the case where the metal compound-containing layer 134 is not provided.
  • the flatness of the second metal-containing layer 136 can be improved while making the thickness sufficiently thin.
  • the amount of metal deposited in the second metal-containing layer 136 is relatively small at the initial stage of deposition such as vapor deposition of the metal contained in the second metal-containing layer 136. At this time, a plurality of islands separated from the core of the metal contained in the second metal-containing layer 136 are formed.
  • the amount of metal deposited in the second metal-containing layer 136 increases, a plurality of islands are connected to each other to form a continuous layer. Therefore, it is sufficient to ensure the translucency of the second metal-containing layer 136 on the electron-injected layer 122 and the plurality of first metal-containing layers 132 in a state where the metal compound-containing layer 134 is not provided. Even if an attempt is made to form the second metal-containing layer 136 having a thinness, the metals contained in the second metal-containing layer 136 do not form a continuous layer and may be separated from each other in a plurality of islands.
  • the amount of metal deposited in the second metal-containing layer 136 in the state where the metal compound-containing layer 134 is not provided is an amount sufficient for the metal contained in the second metal-containing layer 136 to form a continuous layer. Then, the thickness of the second metal-containing layer 136 cannot be made thin enough to ensure the translucency of the second metal-containing layer 136.
  • the second metal-containing layer 136 is formed on the electron-injected layer 122 and the plurality of first metal-containing layers 132 via the metal compound-containing layer 134, the metal contained in the second metal-containing layer 136 is formed.
  • the deposited amount is contained in the metal compound-containing layer 134 even if the amount of metal contained in the second metal-containing layer 136 is not sufficient to form a continuous layer.
  • the metal contained in the second metal-containing layer 136 can form a continuous layer. That is, the metal compound-containing layer 134 functions as an anchor for the second metal-containing layer 136.
  • the metal compound-containing layer 134 When the metal compound-containing layer 134 is provided, it is possible to suppress the generation of light from the organic layer 120 in the translucent portion 144 as compared with the case where the metal compound-containing layer 134 is not provided. Specifically, if the second metal-containing layer 136 is provided on the electron injection layer 122 and the plurality of first metal-containing layers 132 in a state where the metal compound-containing layer 134 is not provided, the translucent portion. Electrons may be injected from the second metal-containing layer 136 in 144 into the organic layer 120 via the electron injection layer 122, and light may be generated from the organic layer 120 in the translucent portion 144.
  • the metal compound-containing layer 134 when the metal compound-containing layer 134 is provided, the electron injection from the second metal-containing layer 136 to the organic layer 120 in the translucent portion 144 can be suppressed by the metal compound-containing layer 134. Therefore, when the metal compound-containing layer 134 is provided, it is possible to suppress the generation of light from the organic layer 120 in the translucent portion 144 as compared with the case where the metal compound-containing layer 134 is not provided.
  • the thickness of the metal compound-containing layer 134 can be 10 ⁇ or more and 50 ⁇ or less.
  • the thickness of the metal compound-containing layer 134 is smaller than the lower limit of the range of the example, as compared with the case where the thickness of the metal compound-containing layer 134 is smaller than the lower limit of the range of the example.
  • the electron injection from 136 to the organic layer 120 can be suppressed by the metal compound-containing layer 134.
  • the second metal-containing layer 136 is compared with the case where the thickness of the metal compound-containing layer 134 is larger than the upper limit of the range of the example. It is possible to prevent the injection of electrons into the first metal-containing layer 132 from being blocked by the metal compound-containing layer 134.
  • the thickness of the metal compound-containing layer 134 is not limited to this example.
  • the second metal-containing layer 136 covers the metal compound-containing layer 134.
  • the second metal-containing layer 136 has translucency.
  • the second metal-containing layer 136 contains a metal as a main component.
  • the second metal-containing layer 136 contains at least one selected from the group consisting of silver such as pure silver and silver alloys, gold such as pure gold and gold alloys, and copper such as pure copper and copper alloys. From the viewpoint of the translucency of the second metal-containing layer 136, the second metal-containing layer 136 preferably contains silver.
  • the metal contained in the second metal-containing layer 136 is not limited to the above example.
  • the work function of the metal contained in the second metal-containing layer 136 is larger than 4.5 eV.
  • the work function of the metal contained in the second metal-containing layer 136 is not limited to this example.
  • the thickness of the second metal-containing layer 136 can be 6.0 nm or more and 15 nm or less.
  • the thickness of the second metal-containing layer 136 is included in the second metal-containing layer 136 as compared with the case where the thickness of the second metal-containing layer 136 is smaller than the lower limit of the range of the example. It is possible to prevent the metals to be separated from each other in a plurality of islands.
  • the thickness of the second metal-containing layer 136 is within the range of the example, the thickness of the second metal-containing layer 136 is smaller than the lower limit of the range of the example, as compared with the case where the thickness of the second metal-containing layer 136 is smaller than the lower limit of the range of the example.
  • the conductivity of the metal can be increased.
  • the thickness of the second metal-containing layer 136 is within the range of the example, the thickness of the second metal-containing layer 136 is larger than the upper limit of the range of the example, as compared with the case where the thickness of the second metal-containing layer 136 is larger than the upper limit of the range of the example.
  • the translucency of the metal can be increased.
  • the thickness of the second metal-containing layer 136 is not limited to this example.
  • the combination of the materials contained in the first metal-containing layer 132, the metal compound-containing layer 134, and the second metal-containing layer 136 is as follows.
  • the combination of MoO 3 for the metal compound-containing layer 134 and Ag for the second metal-containing layer 136 is exemplified.
  • FIG. 2 is a diagram showing a first example of a layout of a plurality of first metal-containing layers 132 viewed from the first side S1 or the second side S2 of the light emitting device 10.
  • Each of the plurality of first metal-containing layers 132 is surrounded by the translucent portion 144 when viewed from the direction perpendicular to the first surface 102 or the second surface 104.
  • each of the plurality of first metal-containing layers 132 has an island shape separated from each other via the translucent portion 144. If a plurality of first metal-containing layers 132 are arranged in a stripe shape, a plurality of first metal-containing layers 132 are arranged in the vertical direction or the horizontal direction when viewed from the first side S1 or the second side S2.
  • the visibility of the translucency of the light emitting device 10 when viewed from the first side S1 or the second side S2 may be affected by the orientation of the light emitting device 10 such as metal.
  • the first is compared with the case where the plurality of first metal-containing layers 132 are arranged in a stripe shape. It is possible to suppress the influence of the orientation of the light emitting device 10 on the visibility of the light emitting device 10 when viewed from the side S1 or the second side S2.
  • the voltage can be supplied to the plurality of first metal-containing layers 132 via the second metal-containing layer 136 that covers the plurality of first metal-containing layers 132. If a voltage is supplied to each of the first metal-containing layers 132 via the wiring drawn from each of the first metal-containing layers 132, the wiring drawn from each of the first metal-containing layers 132 allows the light emitting device 10 to pass through. The visibility of light can be affected. On the other hand, in the present embodiment, it is not necessary to provide the wiring drawn out from the first metal-containing layer 132. Therefore, it is possible to suppress the influence of the wiring drawn from the first metal-containing layer 132 on the visibility of the translucency of the light emitting device 10.
  • the plurality of first metal-containing layers 132 are regularly arranged when viewed from the direction perpendicular to the first surface 102 or the second surface 104. Specifically, the plurality of first metal-containing layers 132 are arranged in a tetragonal lattice pattern. As a result, the patterns of the plurality of first metal-containing layers 132 have translational symmetry. The plurality of first metal-containing layers 132 may be arranged in a lattice pattern different from the tetragonal lattice pattern, for example, in a rectangular lattice pattern.
  • first metal-containing layers 132 When a plurality of first metal-containing layers 132 are regularly arranged when viewed from a direction perpendicular to the first surface 102 or the second surface 104, a plurality of first metal-containing layers 132 when viewed from a direction perpendicular to the first surface 102 or the second surface 104. Compared with the case where the first metal-containing layers 132 of No. 1 are arranged irregularly, the distribution of the brightness of the plurality of light emitting portions 142 and the distribution of the translucent portions 144 when viewed from the first side S1 can be obtained. Can be uniform.
  • the plurality of first metal-containing layers 132 may be arranged irregularly when viewed from the direction perpendicular to the first surface 102 or the second surface 104.
  • each first metal-containing layer 132 is a circle when viewed from the direction perpendicular to the first surface 102 or the second surface 104.
  • the shape of each first metal-containing layer 132 is not limited to this example.
  • the shape of each first metal-containing layer 132 may be a polygon such as a triangle, a quadrangle, a pentagon, a hexagon, or an octagon when viewed from a direction perpendicular to the first surface 102 or the second surface 104. Or may be elliptical.
  • the shapes of the first metal-containing layers 132 may be the same as or different from each other when viewed from the direction perpendicular to the first surface 102 or the second surface 104.
  • the width W1 of the first metal-containing layer 132 can be 0.050 mm or more and 1.0 mm or less when viewed from the direction perpendicular to the first surface 102 or the second surface 104.
  • the width W1 is within the range of the example, the total light emitting area of the plurality of light emitting units 142 can be increased as compared with the case where the width W1 is smaller than the lower limit of the range of the example.
  • the translucency of the light emitting device 10 can be increased as compared with the case where the width W1 is larger than the upper limit of the range of the example.
  • the width W1 is not limited to this example.
  • the width W2 of the translucent portion 144 between the adjacent first metal-containing layers 132 when viewed from the direction perpendicular to the first surface 102 or the second surface 104 is set to 0.050 mm or more and 2.0 mm or less. be able to.
  • the width W2 is within the range of the example, the translucency of the light emitting device 10 can be increased as compared with the case where the width W1 is smaller than the lower limit of the range of the example.
  • the width W2 is within the range of the example, the total light emitting area of the plurality of light emitting units 142 can be increased as compared with the case where the width W1 is larger than the upper limit of the range of the example.
  • the width W2 is not limited to this example.
  • the ratio W1 / W2 of the width W1 to the width W2 can be 0.50 or more and 1.7 or less when viewed from the direction perpendicular to the first surface 102 or the second surface 104.
  • the ratio W1 / W2 is in the range of the example, the total light emitting area of the plurality of light emitting units 142 can be increased as compared with the case where the ratio W1 / W2 is smaller than the lower limit of the range of the example.
  • the translucency of the light emitting device 10 can be increased as compared with the case where the ratio W1 / W2 is larger than the upper limit of the range of the example.
  • the ratio W1 / W2 is not limited to this example.
  • FIG. 3 is a diagram showing a second example of the layout of the plurality of first metal-containing layers 132 viewed from the first side S1 or the second side S2 of the light emitting device 10.
  • the example shown in FIG. 3 is the same as the example shown in FIG. 2 except for the following points.
  • the plurality of first metal-containing layers 132 are arranged in an oblique lattice pattern when viewed from the direction perpendicular to the first surface 102 or the second surface 104. Also in the example shown in FIG. 3, the orientation of the light emitting device 10 when viewed from the first side S1 or the second side S2 as compared with the case where the plurality of first metal-containing layers 132 are arranged in a stripe shape. It is possible to suppress the influence of the light emitting device 10 on the visibility of the light emitting device 10.
  • the plurality of first metal-containing layers 132 when viewed from the direction perpendicular to the first surface 102 or the second surface 104, the plurality of first metal-containing layers 132 have an island shape separated from each other via the translucent portion 144.
  • the plurality of first metal-containing layers 132 may be arranged in a stripe shape when viewed from the direction perpendicular to the first surface 102 or the second surface 104.

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  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Electroluminescent Light Sources (AREA)
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JP2016207541A (ja) * 2015-04-24 2016-12-08 株式会社カネカ 透明導電フィルムおよび表示デバイス、並びに、透明導電フィルムの製造方法および表示デバイスの製造方法
WO2018061102A1 (ja) * 2016-09-28 2018-04-05 パイオニア株式会社 発光装置

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JP2010123439A (ja) * 2008-11-20 2010-06-03 Fujifilm Corp 有機電界発光素子
EP2398086A1 (en) * 2010-06-17 2011-12-21 Nederlandse Organisatie voor toegepast -natuurwetenschappelijk onderzoek TNO Opto-electric device and method of manufacturing thereof
JP6110695B2 (ja) * 2012-03-16 2017-04-05 株式会社半導体エネルギー研究所 発光装置
WO2018011902A1 (ja) * 2016-07-12 2018-01-18 パイオニア株式会社 発光システム及び移動体
US11335890B2 (en) * 2016-12-19 2022-05-17 Pioneer Corporation Light-emitting device and light-emitting system

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WO2018061102A1 (ja) * 2016-09-28 2018-04-05 パイオニア株式会社 発光装置

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