WO2021187058A1 - Rouleau de film antiadhésif, son procédé de production, feuille de composant céramique, son procédé de production, composant céramique et son procédé de production - Google Patents

Rouleau de film antiadhésif, son procédé de production, feuille de composant céramique, son procédé de production, composant céramique et son procédé de production Download PDF

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Publication number
WO2021187058A1
WO2021187058A1 PCT/JP2021/007417 JP2021007417W WO2021187058A1 WO 2021187058 A1 WO2021187058 A1 WO 2021187058A1 JP 2021007417 W JP2021007417 W JP 2021007417W WO 2021187058 A1 WO2021187058 A1 WO 2021187058A1
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WIPO (PCT)
Prior art keywords
release film
roll
winding
ceramic
release
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PCT/JP2021/007417
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English (en)
Japanese (ja)
Inventor
飯島　忠良
泰彦 江守
修治 飯田
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Tdk株式会社
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Publication date
Application filed by Tdk株式会社 filed Critical Tdk株式会社
Priority to JP2022508173A priority Critical patent/JP7447987B2/ja
Publication of WO2021187058A1 publication Critical patent/WO2021187058A1/fr

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
    • B65H18/00—Winding webs
    • B65H18/08—Web-winding mechanisms
    • B65H18/26—Mechanisms for controlling contact pressure on winding-web package, e.g. for regulating the quantity of air between web layers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G13/00—Apparatus specially adapted for manufacturing capacitors; Processes specially adapted for manufacturing capacitors not provided for in groups H01G4/00 - H01G11/00
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G4/00—Fixed capacitors; Processes of their manufacture
    • H01G4/30—Stacked capacitors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G4/00—Fixed capacitors; Processes of their manufacture
    • H01G4/32—Wound capacitors

Definitions

  • the present disclosure relates to a release film roll and its manufacturing method, a ceramic part sheet and its manufacturing method, and a ceramic part and its manufacturing method.
  • Ceramic parts which are a type of electronic parts, are also becoming smaller year by year.
  • a multilayer ceramic capacitor which is a kind of ceramic component, the thickness of the dielectric layer and the internal electrode is reduced to increase the capacity.
  • a general multilayer ceramic capacitor is manufactured by forming a release film as a carrier film, forming a dielectric layer and an internal electrode on the carrier film to form a green sheet, and peeling and laminating the green sheet.
  • the withstand voltage performance that shows the resistance to the voltage strength that causes problems such as short circuit tends to decrease.
  • the thin portion causes a decrease in withstand voltage performance.
  • a monolithic ceramic capacitor having a dielectric layer having such a thin portion has a poor withstand voltage, and the yield of the monolithic ceramic capacitor is lowered.
  • the withstand voltage performance is improved and the yield of the multilayer ceramic capacitor is improved.
  • a ceramic green sheet is formed on the surface of the release layer of the release film drawn from the release film roll.
  • it is considered effective to increase the winding length of the release film wound on the release film roll to reduce the frequency of replacement of the release film roll. ..
  • the present disclosure provides a release film roll having high quality in a wound state and capable of sufficiently reducing unevenness and deformation on the surface of the release film, and a method for producing the same. Further, in the present disclosure, by using such a release film roll, a ceramic component sheet having excellent reliability and a method for manufacturing the same are provided. Further, in the present disclosure, by using such a ceramic part sheet, a ceramic part having excellent reliability and a method for manufacturing the same are provided.
  • the method for manufacturing a release film roll of the present disclosure includes a winding step of winding the release film on the winding roll while pressing the contact roll against the winding roll, and in the winding step, the contact roll is peeled while being rotationally driven. It winds up the film.
  • a transport roll can be used to transport the release film.
  • the take-up roll refers to a film roll in which a film containing a release film is wound around the winding core.
  • the contact roll in the winding process, the contact roll is pressed against the winding roll, and the release film is wound on the winding roll while the contact roll is rotationally driven.
  • the contact roll By pressing and rotating the contact roll, it is possible to promote the escape of air between the release films to be wound.
  • the torque of the take-up roll can be reduced to suppress the transfer of the uneven shape on the release film, and the occurrence of winding misalignment can be suppressed. Therefore, it is possible to manufacture a release film roll in which the quality of the wound state is high and the unevenness and deformation of the surface of the release film are sufficiently reduced.
  • the thickness of the release film is F [m]
  • the width of the release film is W [m]
  • the torque of the winding shaft that rotationally drives the winding roll is T [Nm].
  • the maximum value of the torque T [Nm] of the take-up shaft that rotationally drives the take-up roll in the take-up process is T max [Nm]
  • the minimum value is T min [Nm].
  • the above manufacturing method may include a transporting step of transporting the release film using a transport roll and a cutting step of cutting the release film along the longitudinal direction.
  • the release film Before cutting the release film, the release film may be sandwiched between a nip roll and a transport roll.
  • a predetermined tension By sandwiching the release film between the nip roll and the transport roll, a predetermined tension can be applied to the release film to be cut.
  • the cutting process can be smoothly performed, and the shape of the cut portion of the release film can be adjusted with high accuracy.
  • the release film roll according to one aspect of the present disclosure can be obtained by any of the above-mentioned manufacturing methods. Since this release film roll is obtained by any of the above-mentioned manufacturing methods, the quality of the wound state is high, and the unevenness and deformation of the surface of the release film are sufficiently reduced.
  • the method for manufacturing a ceramic component sheet according to one aspect of the present disclosure is a step of forming a ceramic green sheet on the surface of a release layer of a release film drawn from any of the above-mentioned release film rolls by using a paste containing ceramic powder. Has.
  • the above manufacturing method uses a release film drawn from any of the above release film rolls.
  • the release film roll can sufficiently suppress scratches on the surface of the release film due to unwinding and unevenness on the surface of the release film due to transfer. Therefore, it is possible to form a ceramic green sheet in which thickness variation and pinholes are sufficiently reduced over a wide region between the front end and the rear end of the release film wound on the release film roll. Therefore, it is possible to manufacture a ceramic component sheet having excellent reliability.
  • the "rear end" of the release film means one end on the side in contact with the winding core
  • the "tip" of the release film means one end on the side appearing on the outer peripheral surface of the release film roll.
  • the method for manufacturing ceramic parts includes a step of obtaining a laminate containing a ceramic green sheet using the ceramic parts sheet obtained by the above-mentioned manufacturing method, and a step of firing the laminate to obtain a sintered body. It has a step of obtaining.
  • ceramic parts are manufactured using a release film in which surface irregularities and thickness fluctuations due to unwinding and transfer are sufficiently suppressed. As a result, it is possible to form a ceramic green sheet in which thickness variation and pinholes are sufficiently reduced. Therefore, it is possible to manufacture a ceramic part having excellent reliability.
  • the ceramic component sheet according to one aspect of the present disclosure is obtained by forming a green sheet containing a ceramic green sheet on the surface of the release layer of the release film drawn from any of the above-mentioned release film rolls.
  • the above-mentioned ceramic component sheet is obtained by using a release film drawn from any of the above-mentioned release film rolls.
  • the release layer of the release film is sufficiently suppressed from surface irregularities and deformation due to unwinding and transfer. Therefore, the thickness variation and pinhole of the ceramic green sheet can be sufficiently reduced.
  • the ceramic component sheet obtained by forming the green sheet including such a ceramic green sheet has excellent reliability.
  • the ceramic component according to one aspect of the present disclosure includes a sintered body obtained by forming a laminate including a ceramic green sheet of the ceramic component sheet and firing the laminate.
  • the thickness variation and pinholes of the ceramic green sheet are sufficiently reduced.
  • the ceramic parts are excellent in reliability because they include a sintered body obtained by firing a laminate containing such a ceramic green sheet.
  • the release film roll capable of sufficiently reducing the unevenness and deformation on the surface of the release film and the production thereof.
  • a method can be provided. Further, by using such a release film roll, it is possible to provide a ceramic component sheet having excellent reliability and a method for producing the same. Further, by using such a ceramic component sheet, it is possible to provide a ceramic component sheet having excellent reliability and a method for manufacturing the same.
  • FIG. 1 is a perspective view of a release film roll according to an embodiment.
  • FIG. 2 is a cross-sectional view showing an example of a release film.
  • FIG. 3 is a diagram showing an example of a release film roll manufacturing apparatus.
  • FIG. 4 is a diagram showing another example of a release film roll manufacturing apparatus.
  • FIG. 5 is a diagram schematically showing a change in the tension of the release film wound on the winding roll at the winding portion.
  • FIG. 6 is a diagram showing an example of a control method in the winding unit.
  • FIG. 7 is a cross-sectional view of the ceramic component sheet according to the embodiment.
  • FIG. 8 is a cross-sectional view showing a ceramic component according to an embodiment.
  • FIG. 1 is a perspective view of a release film roll according to an embodiment.
  • the release film roll 100 of FIG. 1 includes a release film 20 having a base film and a release layer, and a winding core 10 around which the release film 20 is wound.
  • the release film 20 is used as a carrier film in, for example, in the manufacturing process of ceramic parts represented by a multilayer ceramic capacitor. In this manufacturing process, for example, a ceramic green sheet to be a dielectric green sheet and an electrode green sheet to be an internal electrode are formed on a release film by coating or printing, and then these are peeled off and laminated. , Ceramic parts are manufactured by firing the laminate.
  • the release film 20 is drawn out from the release film roll 100 and used.
  • Examples of the material of the winding core 10 include paper, plastic, and metal. In the production of ceramic parts, particles cause pinholes, so those containing lightweight plastic that does not generate paper dust are preferable. Such examples include ABS resin, bakelite and fiber reinforced plastics. Fiber reinforced plastics can be preferably used because they have flexibility in addition to high mechanical strength. Examples of the fiber reinforced plastic include those in which the fibers are reinforced with a thermosetting resin. Examples of the resin include epoxy resin and unsaturated polyester resin. Examples of the fiber include glass fiber and aramid fiber. The resin may be an unsaturated polyester resin in consideration of cost and the like. From the same point of view, the fiber may be glass fiber.
  • the outer diameter of the winding core 10 may be 150 mm or less, and may be 100 mm or less. As a result, the size of the release film roll 100 can be reduced, and the installation space and transportation cost can be reduced.
  • the winding length of the release film 20 wound around the winding core 10 may be 4000 m or more, 5000 m or more, or 6000 m or more.
  • the thickness of the release film 20 may be 10 to 110 ⁇ m and may be 20 to 60 ⁇ m.
  • the width of the release film 20 may be, for example, 0.1 to 2 m.
  • the direction in which the release film is conveyed when the release film is pulled out and wound is referred to as the longitudinal direction
  • the direction orthogonal to the longitudinal direction of the release film is referred to as the width direction of the release film.
  • FIG. 2 is a cross-sectional view showing an example of a release film.
  • the release film 20 has a base film 22 and a release layer 24 on one surface thereof.
  • the base film 22 may be a synthetic resin film.
  • the synthetic resin include polyolefin resins such as polyester resin, polypropylene resin and polyethylene resin, acrylic resins such as polylactic acid resin, polycarbonate resin and polymethylmethacrylate resin, polyamide resins such as polystyrene resin and nylon, polyvinyl chloride resin and polyretan. Examples thereof include resins, fluororesins, and polyphenylene sulfide resins. Of these, polyester resin is preferable. Of the polyester resins, polyethylene terephthalate (PET) is more preferable from the viewpoint of mechanical properties, transparency, cost and the like.
  • PET polyethylene terephthalate
  • the thickness of the base film 22 is preferably 10 to 100 ⁇ m, more preferably 20 to 50 ⁇ m. If the thickness is less than 10 ⁇ m, the physical characteristics such as the dimensional stability of the release film 20 tend to be impaired. If the thickness exceeds 100 ⁇ m, the manufacturing cost per unit area of the release film 20 tends to increase.
  • the base film 22 may contain a filler (filler) to the extent that the transparency is not impaired from the viewpoint of sufficiently increasing the mechanical strength of the release film 20.
  • a filler filler
  • the shape of the filler is transferred to the release layer 24 of the release film 20 adjacent to the release film roll 100 along the radial direction. Can be sufficiently suppressed.
  • the filler is not particularly limited, and examples thereof include calcium carbonate, calcium phosphate, silica, kaolin, talc, titanium oxide, fumed silica, alumina, and organic particles.
  • the release layer 24 is formed by applying a solution containing a release agent on one surface of the base film 22 and drying and curing the solution.
  • the coating method is not particularly limited, and a reverse coating method, a gravure coating method, a rod coating method, a bar coating method, a Meyer bar coating method, a die coating method, a spray coating method, or the like may be used.
  • Hot air drying, infrared drying, natural drying and the like can be used for drying. It is preferable to heat it in order to suppress moisture dew condensation during drying, and it may be about 60 to 120 ° C.
  • Examples of the release agent used for forming the release layer 24 include silicone-based release agents, long-chain alkyl-based release agents, fluorine-based release agents, and aminoalkyd resin-based release agents.
  • Silicone-based release agents include addition reaction-type silicone release agents, condensation-type silicone release agents, ultraviolet-curable release agents, and the like, depending on the difference in curing reaction.
  • the curing conditions may be appropriately selected according to the curing system of the release agent.
  • the release agent is an addition reaction type silicone, it can be cured by performing a heat treatment at 80 to 130 ° C. for several tens of seconds.
  • it is an ultraviolet curing system, it can be cured by irradiating ultraviolet rays using a mercury lamp, a metal halide lamp, or the like as a light source.
  • radical polymerization is carried out by irradiating with ultraviolet rays, it is preferable to perform curing in a nitrogen atmosphere in order to prevent oxygen inhibition. It is preferable that the thickness variation width of the release layer 24 is small.
  • the addition reaction type silicone release agent is cured by reacting hydrogensiloxane with a polydimethylsiloxane having a vinyl group introduced at the end and / or side chain.
  • a platinum catalyst can be used for curing. For example, it can be cured in several tens of seconds to several minutes at a curing temperature of about 100 ° C.
  • the thickness of the release layer 24 may be about 50 to 300 nm.
  • K847, KS847T, KS-776L, KS-776A, KS-841, KS-774, KS-3703T, KS-3601, etc. (all trade names) manufactured by Shin-Etsu Chemical Co., Ltd. are used. Can be mentioned.
  • the release layer 24 may be composed of, for example, a (meth) acrylate component and a cured product of (meth) acrylate-modified silicone. Since such a cured product can be cured by ultraviolet rays, the thickness of the release layer 24 can be increased. Therefore, for example, when the base film 22 contains a filler, the surface (peeling surface) of the release layer 24 can be smoothed by covering the protrusions caused by the filler. In this case, the thickness of the release layer 24 may be 300 to 3000 nm.
  • (Meta) acrylate monomer and (meth) acrylate-modified silicone oil that are incompatible with each other may be used. These are mixed in a solvent together with a reaction initiator, applied to the base film 22, and then the solvent is dried. In this way, the silicone-modified silicone oil may be cured by ultraviolet rays in a state where it is localized in the vicinity of the surface to form the release layer 24.
  • Known (meth) acrylate-modified silicone oils can be used.
  • X-22-164A, X-22-164B, X-22-174DX, X-22-2445 all trade names manufactured by Shin-Etsu Chemical Co., Ltd. can be mentioned.
  • the surface of the release layer 24 in the release film 20 is preferably smooth.
  • the surface roughness (Rp) of the release layer 24 is preferably 100 nm or less, and more preferably 50 nm or less.
  • the surface roughness (Rp) of the release layer 24 in this embodiment is the maximum mountain height defined by JIS B 0601-2001, and is measured using a contact-type surface roughness meter or a scanning white interference microscope. Can be done.
  • the method for manufacturing the release film roll 100 includes a transfer step of conveying the release film using a transfer roll, a cutting step of cutting the release film along the longitudinal direction, and a winding roll of the contact roll. It has a winding step of winding the release film with a winding roll while pressing the film.
  • the transfer step may be performed before or after the cutting step, or both.
  • FIG. 3 is a diagram showing an example of a manufacturing apparatus for manufacturing the release film roll 100.
  • a release film roll 200 is used.
  • a release film 20A having a width wider than that of the release film 20 (for example, 1 to 2 m) is wound around the winding core 11.
  • the release film roll 200 is manufactured by winding the release film 20A around the winding core 11 by a known method.
  • a plurality of release layers may be formed side by side in a striped pattern so as to be parallel to the longitudinal direction of the base film.
  • the release film 20A may be wound around the winding core 11 with the base film side on the inside, or may be wound with the release layer side on the inside.
  • the winding length of the release film roll 200 may be longer than the winding length of the release film roll 100.
  • the release film roll 200 may be produced with a length that is an integral multiple of the winding length of the release film roll 100 and a length that includes a loss associated with the cutting operation. In this case, in the winding step, after the release film roll 100 is completed, the release film 20A unwound from the release film roll 200 is cut along the width direction to manufacture another release film roll 100. 200 may continue to be used. This makes it possible to improve the efficiency of productivity.
  • the winding core 11 of the release film roll 200 is inserted into the rotating shaft 202 at the feeding portion 110 provided on the upstream side, and the rotating shaft 202 rotatably supports the release film roll 200. Further, the manufacturing apparatus 300 includes a pair of rolls 50 that vertically sandwich the release film 20A drawn from the release film roll 200.
  • the manufacturing apparatus 300 includes a cutting unit 120 for performing a cutting process and a winding unit 130 for performing a winding process on the downstream side of the pair of rolls 50 for performing the transport process in this order.
  • the material of the pair of rolls 50 examples include metal, plastic, rubber and the like.
  • the upper roll 50a and the lower roll 50b constituting the pair of rolls 50 may be made of different materials.
  • the upper roll 50a may be a transport roll whose surface is at least made of rubber from the viewpoint of sufficiently contacting the release film 20A with the upper roll 50a.
  • the lower roll 50b may be a metal nip roll in order to prevent the lower roll 50b itself from being deformed and the transport speed from becoming unstable.
  • the configuration of the pair of rolls 50 is not particularly limited, and in the modified example, the upper roll 50a may be a nip roll and the lower roll 50b may be a transport roll.
  • the pair of rolls 50 may have a function of making the tension of the release film 20A different between the upstream side and the downstream side thereof.
  • a torque acts on the rotating shaft 202 of the feeding portion 110 in the direction opposite to the traveling direction of the release film 20A, and tension is applied to the release film 20A.
  • the torque in the opposite direction can be applied by using friction torque, an electromagnetic brake, or the like. Since the pair of rolls 50 have a function of making the tension of the release film 20A different, the tension of the release film 20 in the cutting portion 120 and the winding portion 130 can be controlled with a high degree of freedom.
  • the cutting portion 120 has an upper blade roll 60a and a lower blade roll 60b.
  • the upper blade roll 60a may have a plurality of upper blades mounted at predetermined intervals along the direction of its rotation axis.
  • the upper blade of the upper blade roll 60a may be adapted to mesh with the lower blade roll 60b.
  • the release film 20A that has passed through the pair of rolls 50 is cut along the longitudinal direction between the upper blade roll 60a and the lower blade roll 60b. As a result, it is divided into a release film 20 having a width of, for example, 100 to 500 mm.
  • the plurality of release film rolls 100 can be manufactured at one time. ..
  • a known slitter such as a gang blade can be used for the cutting portion 120.
  • the cutting portion 120 may not be provided.
  • one release film roll 100 can be obtained from one release film roll 200.
  • the take-up portion 130 includes a take-up shaft 102 that is inserted into the take-up core 10 of the take-up roll 100a and rotatably supports the take-up core 10.
  • the release film 20 obtained by being cut by the cutting portion 120 is wound around the winding core 10 attached to the winding shaft 102 at the winding portion 130.
  • the take-up shaft 102 rotates with a predetermined torque, and the contact roll 70 presses the take-up release film 20 toward the winding core 10. That is, the release film 20 is wound while being pressed by the contact roll 70.
  • the take-up property of the release film 20 can be improved. Further, the magnitude of the pressure of the contact roll 70 on the take-up roll 100a may be appropriately adjusted.
  • the contact roll 70 rotates in the direction opposite to that of the take-up shaft 102, but the contact roll 70 is not limited to this.
  • the contact roll 70 and the take-up shaft 102 may rotate in the same direction.
  • FIG. 4 is a diagram showing another example of a manufacturing apparatus for manufacturing the release film roll 100.
  • the manufacturing apparatus 301 of FIG. 4 differs from the manufacturing apparatus 300 of FIG. 3 in that it has a winding unit 131 instead of the winding unit 130.
  • the feeding portion 110 and the cutting portion 120 of the manufacturing apparatus 301 may be the same as those of the manufacturing apparatus 300.
  • the take-up portion 131 of the manufacturing apparatus 301 the release film 20 first comes into contact with the contact roll 70, goes around the contact roll 70 about half a turn in the state of being in contact with the contact roll 70, and then turns around the contact roll 70 and the take-up roll 100a. It is sandwiched between and.
  • the release film 20 is wound by a winding shaft 102 that rotates with a predetermined torque while being pressed between the contact roll 70 and the winding roll 100a. Also in this example, the release film 20 is wound while being pressed by the contact roll 70.
  • the take-up property of the release film 20 can be improved by rotationally driving the contact roll 70 and rotating the take-up shaft 102 with a predetermined take-up torque.
  • FIG. 5 is a diagram schematically showing a change in tension applied to the release film 20 wound on the winding roll 100a in the winding portions 130 and 131.
  • the horizontal axis of FIG. 5 is the size of the roll shape of the take-up roll 100a, and the vertical axis is the tension applied to the release film 20 to be taken up.
  • the straight line 1 in FIG. 5 shows the change in tension when the release film 20 is wound under constant tension control.
  • the release film is wound with a constant tension from the start to the end of winding, so that the protrusions on the surface of the winding core and the shape of the filler contained in the release film are formed on the release film inside. It is transferred, and unevenness is likely to occur on the surface of the release layer of the release film.
  • Curve 2 in FIG. 5 shows the change in tension when the release film is wound by the taper tension control.
  • the tension applied to the release film 20 to be wound can be reduced as compared with the straight line 1. Therefore, it is possible to prevent the surface of the release layer 24 of the release film 20 from being uneven.
  • Curve 3 in FIG. 5 shows a change in tension when the release film 20 is wound by controlling the torque of the winding shaft 102 to be constant.
  • the tension applied to the release film 20 to be wound can be further reduced as compared with the curve 2. Therefore, it is possible to sufficiently prevent the surface of the release layer 24 of the release film 20 from being uneven.
  • the contact roll 70 is rotationally driven by a drive unit. Even if the release film 20 is wound with a low tension as shown in the curve 3 of FIG. 5, since the contact roll 70 is rotationally driven while being pressed by the contact roll 70, the release film 20 is adjacent to each other along the radial direction of the winding roll 100a. The air between the release films 20 can be reduced. As a result, the occurrence of winding misalignment, sliding phenomenon, and winding tightening can be suppressed, and the occurrence of irregularities such as wrinkles and scratches on the release layer 24 can be suppressed.
  • the rotation speed of the contact roll 70 may be finely adjusted as appropriate. When the cutting speed in the cutting portion 120 is constant, the rotation speed of the contact roll 70 may be substantially constant.
  • the material of the contact roll 70 examples include metal, plastic, and rubber. When the release film 20 is easily charged, the contact roll 70 may be made conductive. The diameter of the contact roll 70 may be appropriately adjusted according to the material of the contact roll 70. For example, if it is a hard material, a material having a relatively large diameter may be used, and if it is a soft material, a material having a relatively small diameter may be used.
  • FIG. 6 is a diagram showing an example of a control method in the winding unit 130 of FIG.
  • the take-up unit 130 rotates to drive the take-up shaft 102 to rotate based on the torque control unit 81a that controls the torque T of the take-up shaft 102 that rotationally drives the take-up roll 100a and the torque information from the torque control unit 81a. It may have a drive unit 82.
  • the rotary drive unit 82 is rotationally driven so that the torque (winding torque) of the take-up shaft 102 becomes T based on the torque information from the torque control unit 81a.
  • the take-up roll 100a is a release film roll in which the release film 20 is being taken up, and becomes the release film roll 100 when the winding is completed.
  • T / (FW) values may be maintained in the range of 70,000-420,000 N / m. This value indicates the magnitude of the torque applied by the take-up shaft 102 per unit cross section of the release film 20.
  • the air in the film can be reduced so that the release films can be sufficiently adhered to each other.
  • the value of T / (FW) in the winding process may be in the range of 70,000 to 280,000 N / m, and in the range of 100,000 to 210,000 N / m. There may be.
  • the fluctuation of the torque T of the take-up shaft 102 is small.
  • the maximum value of the torque T [N ⁇ m] of the winding shaft 102 in the winding process is T max [N ⁇ m]
  • the minimum value is T min [N ⁇ m]
  • the maximum value T max and the minimum value T are satisfied.
  • T min ⁇ 0.8 ⁇ T ave (2) T max ⁇ 1.1 x T ave (3)
  • the change width of the torque T of the winding shaft 102 can be reduced by satisfying the following (1) and (2), or the formulas (3) and (4). As a result, the tightening that may occur due to the increase in torque T can be sufficiently suppressed.
  • the torque T is constant in the winding step, the winding tension of the release film 20 decreases as the roll diameter r of the winding roll 100a increases.
  • the release film 20 is wound by rotational drive while being pressed by the contact roll 70, the amount of air between the release films 20 adjacent in the radial direction is sufficient even if the winding tension is low. Can be reduced to.
  • the manufacturing apparatus 300 includes a torque control unit 81b that controls the torque T'of the rotary shaft 72 of the contact roll 70, and a rotary drive unit 83 that rotationally drives the rotary shaft 72 based on torque information from the torque control unit 81b. You can do it.
  • the rotary drive unit 83 is rotationally driven so that the torque of the rotary shaft 72 becomes T'based on the torque information from the torque control unit 81b.
  • the torque T'of the contact roll 70 is reduced so that the release film 20 is not excessively tensioned. If the torque T'is increased as the winding progresses and the roll diameter r is increased, the torque T'of the contact roll 70 can assist the decrease in the tension of the release film 20 when the torque T is constant. can. As a result, the amount of air in the take-up roll 100a can be reduced, and the fluttering of the release film 20 due to the decrease in tension can be suppressed to improve the stability at the time of cutting.
  • the manufacturing apparatus 300 may be composed of a pressing control unit 81c that controls the pressing P of the contact roll 70 against the take-up roll 100a, and a cylinder unit 84 that generates an actual pressing.
  • the cylinder portion 84 is pressed by sending compressed air into the cylinder.
  • the pressure of the contact roll is controlled by adjusting the air pressure of the compressed air.
  • the pressing P of the contact roll 70 against the take-up roll 100a may be gradually increased as the roll diameter r increases.
  • the torque T of the take-up shaft 102 is constant, the tension of the release film 20 decreases as the roll diameter r increases. Therefore, if the pressing P of the contact roll 70 is increased, the amount of air between the release films 20 adjacent to each other in the radial direction can be sufficiently reduced.
  • the pressing may be set according to the cutting speed in the cutting step, the width of the release film 20, and the like.
  • the take-up shaft 102 may include a fixing mechanism for fixing the take-up core 10 to the take-up shaft 102. After the winding of the release film 20 is completed and the release film roll 100 is obtained, the contact roll 70 is moved by using the cylinder portion 84 to be separated from the release film roll 100. Then, the fixing mechanism of the take-up shaft 102 is released, and the release film roll 100 is removed from the take-up shaft 102. In this way, the release film roll 100 can be manufactured.
  • the release film 20 is pressed against the take-up roll 100a by the contact roll 70 in the winding step, and the release film 20 is taken up while the contact roll 70 is rotationally driven. ing.
  • the contact roll 70 presses the release film 20 wound around the take-up roll 100a with the pressing P toward the take-up roll 100a. Further, the contact roll 70 is rotationally driven by the torque T'. Therefore, it is possible to promote the escape of air between the release films 20 to be wound and suppress the occurrence of unwinding. Further, the torque T of the take-up shaft 102 of the take-up roll 100a can be reduced to reduce the transfer of the uneven shape to the surface of the release layer 24 of the release film 20. Therefore, it is possible to manufacture the release film roll 100 in which the quality of the wound state is high and the unevenness and deformation of the surface of the release film 20 are sufficiently reduced.
  • the control unit 80 includes torque control units 81a and 81b and a pressing control unit 81c.
  • the control unit 80 includes a main storage device such as a CPU, ROM and RAM, an input device such as a keyboard and mouse, an output device such as a display, a transmission / reception unit for transmitting / receiving data to / from various measurement units, a hard disk, and the like. It may be configured as a normal computer system including an auxiliary storage device and the like.
  • the torque control units 81a and 81b and the pressing control unit 81c may be included in one computer system, or each may be configured by an individual computer system.
  • the torque control unit 81a, the rotation drive unit 82, and the take-up shaft 102 do not have to be composed of individual hardware, and may be composed of one or two hardware.
  • the functions of the torque control unit 81a and the rotary drive unit 82 may be realized by a commercially available torque motor.
  • the method of torque control by the torque control unit 81 is not particularly limited, and for example, a friction shaft may be used.
  • the torque control unit 81b, the rotation drive unit 83, and the rotation shaft 72 do not have to be composed of individual hardware, and may be composed of one or two hardware.
  • the functions of the torque control unit 81b and the rotary drive unit 83 may be realized by a commercially available torque motor.
  • the pressing control unit 81c and the cylinder unit 84 do not have to be composed of individual hardware, and may be composed of one hardware.
  • FIG. 7 is a cross-sectional view of the ceramic parts sheet according to the embodiment of the present disclosure.
  • the ceramic green sheet 32 and the electrode green sheet are used on the surface 24a of the release layer 24 of the release film 20 drawn from the release film roll 100 by using a paste containing ceramic powder and an electrode paste. It has a step of forming a green sheet 30 including 34.
  • the ceramic green sheet 32 can be formed by applying a ceramic paste containing ceramic powder and drying it.
  • the electrode green sheet 34 can be formed by applying an electrode paste on a ceramic green sheet 32 and drying it.
  • the ceramic paste can be prepared by kneading a dielectric raw material (ceramic powder) and an organic vehicle.
  • the dielectric raw material include various compounds that become composite oxides or oxides by firing. For example, it can be appropriately selected and used from carbonates, nitrates, hydroxides, organometallic compounds and the like.
  • the dielectric material may be a powder having an average particle size of 4 ⁇ m or less, preferably 0.1 to 3.0 ⁇ m.
  • the electrode paste is selected from the group consisting of, for example, conductive materials such as various conductive metals and alloys, and materials that become conductive materials after firing with various oxides, organic metal compounds, and resists.
  • conductive materials such as various conductive metals and alloys, and materials that become conductive materials after firing with various oxides, organic metal compounds, and resists.
  • One and an organic vehicle can be kneaded and prepared.
  • the conductor material used in producing the electrode paste it is preferable to use a Ni metal, a Ni alloy, or a mixture thereof.
  • the electrode paste may contain a plasticizer to improve the adhesiveness. Examples of the plasticizer include phthalates such as benzyl butyl phthalate (BBP), adipic acid, phosphoric acid esters, glycols and the like.
  • BBP benzyl butyl phthalate
  • adipic acid such as benzyl butyl phthalate (BBP), adipic acid, phosphoric acid esters, glycol
  • the organic vehicle contained in the ceramic paste and the electrode paste is prepared by dissolving the binder resin in an organic solvent.
  • the binder resin used in the organic vehicle include ethyl cellulose, acrylic resin, butyral resin, polyvinyl acetal, polyvinyl alcohol, polyolefin, polyurethane, polystyrene, and copolymers thereof.
  • a butyral-based resin specifically, a polyvinyl butyral-based resin.
  • the mechanical strength of the ceramic green sheet can be increased.
  • One or both of the ceramic paste and the electrode paste contains, if necessary, at least one additive selected from the group consisting of various dispersants, plasticizers, charge removers, dielectrics, glass frits, insulators and the like. May be good.
  • the above-mentioned ceramic paste is applied to the surface 24a of the release layer 24 of the release film 20 by using, for example, a doctor blade device or the like. Then, the applied ceramic paste is dried in a drying device at a temperature of, for example, 50 to 100 ° C. for 1 to 20 minutes to form a ceramic green sheet 32.
  • the ceramic green sheet 32 shrinks to 5-25% as compared to before drying.
  • the above-mentioned electrode paste is printed on the surface 32a of the ceramic green sheet 32 using, for example, a screen printing device so as to have a predetermined pattern.
  • the printed electrode paste is dried in a drying device at a temperature of, for example, 50 to 100 ° C. for 1 to 20 minutes to form an electrode green sheet 34. In this way, it is possible to obtain the ceramic component sheet 40 in which the ceramic green sheet 32 and the electrode green sheet 34 are sequentially laminated on the release layer 24 of the release film 20.
  • the thickness variation width of the ceramic green sheet 32 becomes large.
  • the release film 20 drawn out from the release film roll 100 scratches and irregularities due to unwinding, sliding phenomenon, and the like are sufficiently reduced in the release layer 24. Therefore, it is possible to form the ceramic green sheet 32 in which the thickness variation and pinholes are sufficiently suppressed over a wide region between the front end and the rear end of the release film 20 wound around the release film roll 100.
  • the ceramic component manufactured by using the ceramic component sheet 40 provided with such a ceramic green sheet is excellent in reliability.
  • the thickness of the ceramic green sheet 32 and the electrode green sheet 34 may be 1.0 ⁇ m or less, respectively. Since the thickness fluctuation is suppressed even if the thickness is small as described above, a ceramic part having high reliability can be obtained.
  • the ceramic component sheet of the present disclosure is not limited to that of FIG. 7, and may be composed of only the ceramic green sheet 32 without having the electrode green sheet, for example.
  • the method for manufacturing a ceramic component includes a laminating step of preparing a plurality of ceramic component sheets and laminating a plurality of green sheets of the ceramic component sheet to obtain a laminate, and firing the laminate to bake. It has a firing step of obtaining a body and an electrode forming step of forming a terminal electrode on the sintered body to obtain a monolithic ceramic capacitor.
  • FIG. 8 is a cross-sectional view showing an example of a multilayer ceramic capacitor manufactured by the above-mentioned manufacturing method.
  • the multilayer ceramic capacitor 90 includes an inner layer portion 92 and a pair of outer layer portions 93 that sandwich the inner layer portion 92 in the stacking direction.
  • the monolithic ceramic capacitor 90 has a terminal electrode 95 on the side surface.
  • the inner layer portion 92 has a plurality of (13 layers in this example) ceramic layers 96 (dielectric layers) and a plurality of (12 layers in this example) internal electrode layers 94.
  • the ceramic layer 96 and the internal electrode layer 94 are alternately laminated.
  • the internal electrode layer 94 is electrically connected to the terminal electrode 95.
  • the outer layer portion 93 is formed of a ceramic layer. This ceramic layer may be formed in the same manner as the ceramic green sheet 32, for example.
  • the release film 20 of the ceramic component sheet 40 shown in FIG. 7 is peeled off to obtain a green sheet 30.
  • One side 30b of the green sheet 30 is laminated on the outer layer green sheet.
  • Another release film 20 is peeled from another ceramic component sheet 40 to obtain another green sheet 30, so that the electrode green sheet 34 of the first peeled green sheet and one side 30b of the other green sheet 30 face each other.
  • Laminate After that, by repeating such a procedure and laminating the green sheet 30, a laminated body can be obtained. That is, in this laminating step, the release film 20 is peeled off to obtain a green sheet 30, and the green sheet 30 is sequentially laminated. By repeating this procedure a plurality of times, a laminated body is formed. Finally, a green sheet for the outer layer is also laminated.
  • the number of green sheets laminated in the laminated body is not particularly limited, and may be, for example, tens to hundreds of layers.
  • a thick outer layer green sheet on which no electrode layer is formed may be provided on both end faces orthogonal to the stacking direction of the laminated body. After forming the laminate, the laminate may be cut to obtain green chips.
  • the laminated body (green chips) obtained in the laminating step is fired to obtain a sintered body.
  • the firing conditions are 1100 to 1300 ° C., and it is preferable to carry out the firing in an atmosphere such as a mixed gas of humidified nitrogen and hydrogen.
  • the partial pressure of oxygen in the atmosphere at the time of firing is preferably 10-2 Pa or less, more preferably 10-2 to 10-8 Pa.
  • a binder removal treatment can be performed under normal conditions. For example, when a base metal such as Ni or a Ni alloy is used as the conductor material of the internal electrode layer, it is preferably performed at 200 to 600 ° C.
  • heat treatment may be performed to reoxidize the ceramic layer constituting the sintered body.
  • the holding temperature or the maximum temperature in the heat treatment is preferably 1000 to 1100 ° C.
  • Oxygen partial pressure during the heat treatment is preferably higher oxygen partial pressure than the reducing atmosphere at firing, and more preferably 10 -2 Pa ⁇ 1Pa. It is preferable that the sintered body thus obtained is subjected to end face polishing by, for example, barrel polishing, sandblasting, or the like.
  • the multilayer ceramic capacitor 90 shown in FIG. 8 can be obtained by baking the terminal electrode paste on the side surface of the sintered body to form the terminal electrode 95.
  • a release film roll 100 having a release layer in which scratches due to unevenness and unwinding of the release film 20 are sufficiently reduced is used. Therefore, variations in thickness and pinholes in the ceramic layer 96 and the internal electrode layer 94 can be sufficiently reduced. Therefore, the decrease in withstand voltage is suppressed and the reliability is excellent.
  • the present disclosure is not limited to the above embodiments.
  • the ceramic component of the present disclosure is not limited to the multilayer ceramic capacitor, and may be, for example, another ceramic component.
  • the ceramic component may be, for example, a varistor or a multilayer inductor.
  • a release agent solution was prepared by the following procedure. 0.25 parts by mass of acrylate-modified silicone oil (trade name: X-22-2445, manufactured by Shin-Etsu Chemical Co., Ltd.), 100 parts by mass of methyl ethyl ketone, and 100 parts by mass of toluene with respect to 100 parts by mass of nonanediol diacrylate. Prepared. These were placed in a metal container and stirred and mixed to obtain a colorless and transparent solution.
  • acrylate-modified silicone oil trade name: X-22-2445, manufactured by Shin-Etsu Chemical Co., Ltd.
  • a coating solution was prepared by adding 2.5 parts by mass of a reaction initiator (trade name: Omnirad 127, manufactured by IGM Rasin's BV) to the above solution.
  • a coating liquid is extruded from a slit of an coating device to be applied to one surface of a biaxially stretched polyethylene terephthalate film (PET film, thickness: 30 ⁇ m) having a width of 1100 mm, and hot air at a temperature of 80 ° C. is applied for 30 seconds to apply methyl ethyl ketone and toluene. Evaporated. In this way, a coating layer was formed on the PET film.
  • a reaction initiator trade name: Omnirad 127, manufactured by IGM Rasin's BV
  • the coating layer was cured by irradiating ultraviolet rays in a nitrogen atmosphere with an oxygen concentration of 100 ppm to form a peeling layer having a peeling function.
  • a release film (before cutting) having a release layer on one side of the PET film was obtained.
  • the surface roughness (Rp) of the release layer of the release film was measured using a scanning white interference microscope (device name: VS1540, manufactured by Hitachi High-Tech Science Corporation). As a result, the surface roughness (Rp) of the peeled layer was 30 nm.
  • the thickness of the release layer was 1 ⁇ m.
  • Such a release film was wound around a winding core to obtain a release film roll (before cutting). The total length of the produced release film was 7,000 m.
  • the release film roll 200 (before cutting) was attached to the rotating shaft 202 using the manufacturing apparatus as shown in FIG. At the cutting portion 120, the release film pulled out from the release film roll 200 (before cutting) was cut into five along the longitudinal method to obtain a size of 200 mm in width. As shown in FIG. 3, five release films (after cutting) were wound around a winding core 10 made of FRP having an outer diameter of 88.2 mm so that the release layer 24 was on the outside. At the time of winding, the contact roll 70 was pressed against the winding roll 100a, and the release film was wound around the winding core 10 while rotating the winding shaft 102 and the contact roll 70. A friction shaft was used as the take-up shaft 102.
  • the torque T of the take-up shaft 102 was kept constant at 0.868 Nm. That is, the maximum value T max and the minimum value T min were also 0.868 N / m. The value of T / (FW) was 140,000 N / m. The winding length of the five release film rolls obtained was 6000 m.
  • a dielectric green sheet was formed as a ceramic component sheet by the following procedure.
  • BaTiO 3 based powder as a ceramic powder, polyvinyl butyral as an organic binder (PVB), and methanol were respectively prepared as a solvent.
  • 10 parts by mass of an organic binder and 165 parts by mass of a solvent were mixed with 100 parts by mass of the ceramic powder and kneaded with a ball mill to obtain a dielectric slurry.
  • the release film roll was set in the coating machine, and the dielectric slurry was applied to the release layer side of the release film drawn from the release film roll to form a dielectric green sheet on the surface of the release layer of the release film.
  • the set value of the thickness of the dielectric green sheet was 0.9 ⁇ m.
  • the thickness fluctuation width of the dielectric green sheet is measured along the longitudinal direction while traversing in the width direction of the release film using a transmission type X-ray film thickness meter (trade name: AccureX, manufactured by Hutec Co., Ltd.) installed in-line. Was measured continuously.
  • the thickness fluctuation width was obtained from the average value, the maximum value, and the minimum value of the thickness.
  • a dielectric green sheet was not formed on the release film having a length of 100 m from the rear end of the release film roll wound around the winding core due to restrictions on the apparatus of the coating machine.
  • the thickness fluctuation width of the pinhole and the dielectric green sheet was investigated. If the thickness of the dielectric green sheet is in the range of 0.855 ⁇ m to 0.945 ⁇ m, that is, the thickness fluctuation width is 0.045 ⁇ m ( ⁇ 5% of the set thickness), it is considered as a good product. The thickness variation width was 0.03 ⁇ m, which was a good product. No pinholes were detected.
  • Examples 2 to 7 A release film roll was produced in the same manner as in Example 1 except that the torque T of the take-up shaft 102 was changed as shown in Table 1 by changing the friction shaft used as the take-up shaft 102. The quality of the wound state, the formation of the dielectric green sheet, and the evaluation were carried out in the same manner as in Example 1. The results are as shown in Table 1.
  • Example 1 The same friction shaft as in Example 7 was used.
  • the release film was wound without using a contact roll.
  • the cut surface (end surface) of the release film was not uniform on the side surface of the release film roll.
  • the inner release film slid and the release film roll was deformed into a bamboo shoot shape. It is considered that this is because the contact roll was not used even though the tension of the release film to be wound decreased as the roll diameter increased. In this state, the dielectric slurry cannot be coated by the coating apparatus, so the evaluation is completed at this point.
  • the release film roll was unwound and the release film was observed, deformation was observed as if the release film was broken in a region within about 3 cm inside from the side end portion.
  • the dielectric green increases toward the inside.
  • the thickness fluctuation width of the sheet deteriorated, and the thickness fluctuation width of the dielectric green-green sheet was 0.06 ⁇ m.
  • the thickness fluctuation width exceeded the range of ⁇ 5% of the set thickness, which was a defect.
  • the release film having a length in the range of 100 m to 250 m from the rear end of the release film roll wound around the winding core a portion where the dielectric green sheet was thinned in the form of a pinhole was observed.
  • the present disclosure even if the winding length of the release film is lengthened, the quality of the wound state is high, and the unevenness and deformation on the surface of the release film are sufficiently reduced. Can be provided. Further, by using such a release film roll, it is possible to provide a ceramic component sheet having excellent reliability and a method for producing the same. Further, by using such a ceramic part sheet, it is possible to provide a ceramic part having excellent reliability and a method for manufacturing the same.
  • Terminal electrode 96 ... Ceramic layer, 100 ... Peeling Film roll, 102 ... Winding shaft, 110 ... Feeding part, 120 ... Cutting part, 130, 131 ... Winding part, 200 ... Release film roll, 202 ... Rotating shaft, 300, 301 ... Manufacturing equipment.

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  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Laminated Bodies (AREA)
  • Ceramic Capacitors (AREA)
  • Absorbent Articles And Supports Therefor (AREA)

Abstract

L'invention concerne un procédé de production d'un rouleau de film antiadhésif, ledit procédé de production comprenant une étape d'enroulement dans laquelle un film de séparation est enroulé sur un rouleau d'enroulement tout en pressant un rouleau de contact sur le rouleau d'enroulement, lors de l'étape d'enroulement, le film antiadhésif est enroulé tout en entraînant en rotation le rouleau de contact. L'invention concerne également un procédé de production d'une feuille de composant céramique, ledit procédé de production comprenant une étape dans laquelle une pâte qui comprend une poudre de céramique est utilisée pour former une feuille crue de céramique sur une surface d'une couche antiadhésive du film antiadhésif, qui a été tiré à partir du rouleau de film antiadhésif obtenu par l'intermédiaire du procédé de production susmentionné.
PCT/JP2021/007417 2020-03-18 2021-02-26 Rouleau de film antiadhésif, son procédé de production, feuille de composant céramique, son procédé de production, composant céramique et son procédé de production WO2021187058A1 (fr)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004196873A (ja) * 2002-12-16 2004-07-15 Toyobo Co Ltd ポリエステルフィルムロール
JP2006062826A (ja) * 2004-08-27 2006-03-09 Fuji Photo Film Co Ltd 巻取り装置および巻取り方法
JP2011206995A (ja) * 2010-03-29 2011-10-20 Tdk Corp 剥離フィルム、剥離フィルムロール及びセラミック部品シート、並びにセラミック部品の製造方法
WO2014061410A1 (fr) * 2012-10-19 2014-04-24 東レ株式会社 Film polyester à orientation biaxiale pour agent de démoulage

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5338519B2 (ja) * 2008-09-30 2013-11-13 Ｔｄｋ株式会社 剥離フィルム及びセラミック部品シート
JP6694981B2 (ja) 2019-02-07 2020-05-20 藤森工業株式会社 剥離性に優れた離型フィルム

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004196873A (ja) * 2002-12-16 2004-07-15 Toyobo Co Ltd ポリエステルフィルムロール
JP2006062826A (ja) * 2004-08-27 2006-03-09 Fuji Photo Film Co Ltd 巻取り装置および巻取り方法
JP2011206995A (ja) * 2010-03-29 2011-10-20 Tdk Corp 剥離フィルム、剥離フィルムロール及びセラミック部品シート、並びにセラミック部品の製造方法
WO2014061410A1 (fr) * 2012-10-19 2014-04-24 東レ株式会社 Film polyester à orientation biaxiale pour agent de démoulage

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