WO2021117325A1 - 無方向性電磁鋼板とモータコアならびにそれらの製造方法 - Google Patents
無方向性電磁鋼板とモータコアならびにそれらの製造方法 Download PDFInfo
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
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- Y02T10/00—Road transport of goods or passengers
- Y02T10/60—Other road transportation technologies with climate change mitigation effect
- Y02T10/64—Electric machine technologies in electromobility
Definitions
- the present invention relates to non-oriented electrical steel sheets and motor cores suitable for use in the cores of small, high-power motors, and methods for manufacturing them.
- non-oriented electrical steel sheets used for iron cores (motor cores) of rotating machines are required to have better magnetic characteristics than before. ..
- the drive motor of a hybrid electric vehicle (HEV) needs to be compact and has a high output, and the non-oriented electrical steel sheet used as the material of the motor core has better magnetic characteristics (high magnetic flux density and low iron loss). ) Is being required.
- the motor core is divided into a fixed stator core and a rotating rotor core.
- the rotation speed of the motor tends to be increased due to the miniaturization and high output, and the HEV drive motor having a large outer diameter has a large outer diameter.
- a large centrifugal force acts on the rotor core.
- the rotor core has a very narrow portion (1 to 2 mm) called a bridge portion. Therefore, the non-oriented electrical steel sheets used for the rotor core of the HEV drive motor are strongly required to have higher strength than the conventional ones.
- the characteristics required for the non-oriented electrical steel sheet used for the motor core of the HEV drive motor it is not only excellent in magnetic characteristics but also high strength for the rotor core, and more for the stator core. It is desirable that the magnetic flux density is high and the iron loss is low. As described above, even if the motor core is the same, the required characteristics of the rotor core and the stator core are significantly different. On the other hand, from the viewpoint of manufacturing a motor core, it is desirable that the rotor core material and the stator core material can be collected at the same time from the same material steel sheet, particularly in order to increase the material yield and reduce the material inventory.
- the sheet thickness is 0.15 to 0.35 mm, and the yield strength of the steel sheet before annealing with strain is high.
- a rotor material and a stator material are simultaneously sampled from non-oriented electrical steel sheets having a pressure of 600 MPa or more by punching, and then laminated to assemble a rotor core and a stator core, and further, strain relief annealing is performed only on the stator core.
- a method for manufacturing a motor core in which the iron loss W 10/400 after strain relief annealing is 20 W / kg or less has been proposed.
- Patent Document 1 has a problem that expensive Ni is added in an amount of 0.5 mass% or more in order to increase the strength of the steel sheet, and the manufacturing cost is high. Further, the steel sheet of Patent Document 1 has a big problem that when it is subjected to strain relief annealing, the magnetic properties of the steel sheet, particularly the iron loss property, deteriorate, resulting in a decrease in motor efficiency.
- the present invention has been made in view of the above-mentioned problems of the prior art, and an object of the present invention is to use the same high-strength rotor core and a stator core having excellent magnetic characteristics after strain annealing without using expensive Ni.
- An object of the present invention is to provide a non-oriented electrical steel sheet that can be manufactured from a material and a motor core made of the above-mentioned steel sheet, and to propose a method for inexpensively manufacturing the above-mentioned non-oriented electrical steel sheet and a motor core.
- the inventors have made extensive studies focusing on the influence of the surface properties on the magnetic properties of the non-oriented electrical steel sheet. ..
- the deterioration of the magnetic properties due to the strain annealing is caused by the nitriding of the steel sheet surface layer at the time of strain annealing, and in order to suppress the nitriding of the steel sheet surface layer, a predetermined amount is applied to the steel material (slab).
- a predetermined amount is applied to the steel material (slab).
- C 0.0050 mass% or less
- Si 2.8 to 6.5 mass%
- Mn 0.1 to 2.0 mass%
- P 0.10 mass% or less
- S 0.0050 mass%
- Al 0.3 to 2.0 mass%
- N 0.0050 mass% or less
- Zn 0.0005 to 0.0050 mass%
- Ti 0.0030 mass% or less
- Nb 0.0030 mass% or less
- O It contains 0.0050 mass% or less, has a component composition in which the balance is composed of Fe and unavoidable impurities, and is selected from Sn, Sb, P, S, Se, As, Te, B, Pb and Bi on the surface of the steel plate.
- a non-directional electromagnetic steel plate having a coating layer containing at least one element.
- the non-oriented electrical steel sheet of the present invention is characterized by further containing at least one component of the following groups A to D in addition to the above component composition.
- Group A 1 or 2 selected from Sn: 0.005 to 0.20 mass% and Sb: 0.005 to 0.20 mass%
- Group B selected from Ca, Mg and REM 1 type or 2 or more types in total 0.0005-0.020 mass% -Group C: One or more selected from Cu, Ni, Cr and Co in total of 0.01 to 1.0 mass% -Group D; 1 or 2 selected from Mo: 0.001 to 0.1 mass% and W: 0.001 to 0.1 mass%
- the coating layer in the non-oriented electrical steel sheet of the present invention is characterized by being an insulating film formed on the surface of the steel sheet base steel.
- the coating layer in the non-oriented electrical steel sheet of the present invention is composed of an insulating film formed on the uppermost layer of the steel sheet surface and an intermediate layer formed between the insulating film and the surface of the steel sheet base steel.
- the intermediate layer is characterized by containing at least one element selected from Sn, Sb, P, S, Se, As, Te, B, Pb and Bi.
- the present invention relates to a method for producing a non-directional electromagnetic steel sheet by hot rolling, cold rolling, and finish annealing of a steel slab.
- the steel slab has a C: 0.0050 mass% or less and Si: 2. .8 to 6.5 mass%, Mn: 0.1 to 2.0 mass%, P: 0.10 mass% or less, S: 0.0050 mass% or less, Al: 0.3 to 2.0 mass%, N: 0. Contains 0050 mass% or less, Zn: 0.0005 to 0.0050 mass%, Ti: 0.0030 mass% or less, Nb: 0.0030 mass% or less and O: 0.0050 mass% or less, and the balance consists of Fe and unavoidable impurities.
- a coating layer having a component composition and containing at least one element selected from Sn, Sb, P, S, Se, As, Te, B, Pb and Bi is formed on the surface of the steel sheet after the finish annealing.
- the steel slab used in the method for producing a non-oriented electrical steel sheet is characterized by further containing at least one component of the following groups A to D in addition to the above component composition.
- Group A 1 or 2 selected from Sn: 0.005 to 0.20 mass% and Sb: 0.005 to 0.20 mass%
- Group B selected from Ca, Mg and REM 1 type or 2 or more types in total 0.0005-0.020 mass% -Group C: One or more selected from Cr, Co, Ni and Cu in total of 0.01 to 1.0 mass% -Group D; 1 or 2 selected from Mo: 0.001 to 0.1 mass% and W: 0.001 to 0.1 mass%
- the method for manufacturing the non-oriented electrical steel sheet is selected from Sn, Sb, P, S, Se, As, Te, B, Pb and Bi as the coating layer on the surface of the base steel of the steel sheet after finish annealing. It is characterized in that a coating agent containing at least one element is applied to form an insulating film having a nitriding inhibitory ability.
- the method for producing the non-directional electromagnetic steel sheet is selected from Sn, Sb, P, S, Se, As, Te, B, Pb and Bi as the coating layer on the surface of the steel sheet base iron after the finish annealing.
- a treatment agent containing at least one element is applied to form an intermediate layer having a nitriding inhibitory ability, and an insulating film containing no of the above elements is formed on the intermediate layer.
- the present invention comprises a rotor core formed by laminating a core material processed into a core shape from the non-oriented electrical steel sheet described in any of the above, and a core processed into a core shape from the same non-oriented electrical steel sheet as described above.
- a motor core composed of a stator core obtained by laminating materials and then performing strain relief annealing, and the steel plate constituting the stator core has a relationship of iron loss W 10/800 (W / kg) with a plate thickness t (mm).
- the following equation (1) W 10/800 ⁇ 15 + 80 ⁇ t ⁇ ⁇ ⁇ (1)
- the N (Na as AlN) present as AlN in the layer from one side surface of the steel sheet to the thickness of 1/20 after the strain-removing annealing is 0.0100 mass% or less. It is a motor core.
- the non-directional electromagnetic steel plate manufactured by the method described in any of the above is processed into a core shape, laminated and assembled into a stator core and a rotor core, and then the stator core is subjected to strain relief annealing.
- the strain annealing is performed at a soaking temperature of 800 to 950 ° C. under an atmosphere consisting of one gas selected from nitrogen, hydrogen and a rare gas or a mixed gas of two or more.
- a method for manufacturing a motor core which comprises applying the heat soaking time under the condition of 0.5 to 3.0 hr.
- the iron loss W 10/800 (W / kg) of the steel sheet after the strain-removal annealing is related to the plate thickness t (mm), and the following equation (1); W 10/800 ⁇ 15 + 80 ⁇ t ⁇ ⁇ ⁇ (1)
- the N (Na as AlN) present as AlN in the layer from one side surface of the steel sheet to the thickness of 1/20 after the strain-removing annealing is 0.0100 mass% or less.
- the rotor core that requires high strength and the stator core that requires low iron loss after strain relief annealing can be manufactured from the same material steel sheet. Therefore, the non-oriented electrical steel sheet of the present invention is a hybrid. It can greatly contribute to the miniaturization and high output of motors used in automobiles, electric vehicles, vacuum cleaners, high-speed generators, air compressors, machine tools, and the like.
- an appropriate amount of Zn is contained in the steel material (slab) to form a film made of a composite compound such as an oxide containing Zn or Al on the surface of the steel sheet after finish annealing. Further, by including at least one element selected from Sn, Sb, P, S, Se, As, Te, B, Pb and Bi in the insulating film formed on the surface of the steel sheet after finish annealing. By imparting nitriding suppressing ability to both of the above coatings, nitriding of the surface layer of the steel sheet at the time of strain relief annealing is suppressed.
- the insulating film is composed of primary magnesium phosphate: Mg (H 2 PO 4 ) 2 (manufactured by Taihei Kagaku Sangyo) and acrylic resin (EFD-5560 manufactured by DIC) with a solid content ratio of 90:10 in mass% ratio.
- Mg (H 2 PO 4 ) 2 manufactured by Taihei Kagaku Sangyo
- acrylic resin EFD-5560 manufactured by DIC
- the coating liquid adjusted to a solid content concentration of 10 mass% using deionized water was mixed so that the ratio was 0.5 g / m 2 per side of the coating film after baking. It was applied to both sides of a steel plate and baked in a hot air furnace under the condition that the maximum plate temperature reached 280 ° C. (the soaking time was 0 s) in 30 s.
- the surface layer of the steel sheet specifically, the inside of the layer from one side surface of the steel sheet to the plate thickness 1/20 (hereinafter, "the layer from the one side surface of the steel sheet to the plate thickness 1/20" is simply referred to.
- the concentration of N Na as AlN
- plate thickness 1/20 layer As shown in FIG. 1 (b), the steel sheet of charge A having a high iron loss had a high iron loss.
- the "iron loss reference value" defined by the above equation (2) is the iron loss W 10/800 which is considered necessary to reduce the heat generation of the stator core and prevent the motor efficiency from being lowered. Is the upper limit of.
- the iron loss value largely depends on the plate thickness, and even if the steel sheet has the same characteristics, as shown in FIG. 4, the eddy current loss increases and increases as the plate thickness increases.
- the value was set as in the above equation (2) in relation to the plate thickness.
- FIG. 4 shows the relationship between the plate thickness and the iron loss of the example of the present invention described in the examples described later.
- the thickness cross section of the steel sheet after strain relief annealing was observed with an SEM (scanning electron microscope), and the iron loss exceeded the above iron loss reference value.
- SEM scanning electron microscope
- the concentration of N (Nas AlN) existing as AlN in the 1/20 layer of the plate thickness is analyzed by an electrolytic extraction method, and this N concentration is analyzed.
- the relationship between the iron loss W 10/800 and the iron loss W 10/800 is shown in FIG. From this figure, it can be seen that in the steel sheet in which Zn is added in an appropriate range to the steel material, the N concentration existing as AlN in the 1/20 layer of the plate thickness after strain relief annealing is 100 mass ppm (0.0100 mass%) or less. It was.
- nitriding during strain relief annealing is suppressed by adding Zn to the steel material is that a film made of a composite compound such as an oxide containing Zn or Al is formed on the surface of the steel sheet during strain relief annealing. Conceivable. Therefore, in the present invention, it is an essential requirement that the N concentration in the 1/20 layer of the steel sheet after strain relief annealing is 0.0100 mass% or less.
- the inventors examined a method other than the method of adding Zn to the steel material as a method of suppressing nitriding of the surface layer of the steel sheet during strain relief annealing.
- a method of suppressing nitriding of the surface layer of the steel sheet during strain relief annealing As a result, at least one element selected from Sn, Sb, P, S, Se, As, Te, B, Pb and Bi is contained in the insulating film formed on the surface of the steel plate before strain relief annealing. Therefore, the insulating film has a nitriding inhibitory ability, that is, by including the above element in the insulating film and mixing the compound containing the above element in the insulating film, the density and adhesion of the insulating film can be improved. As a result, it was found that the ability of the insulating film to suppress nitriding was greatly improved.
- Strain-removal annealing especially strain-relief annealing in which the soaking temperature is at a high temperature of 800 ° C. or higher, can be expected to improve iron loss by eliminating processing strain and coarsening crystal grains, but nitriding occurs on the surface layer of the steel sheet.
- the magnetic properties deteriorate, but by adding an appropriate amount of Zn to the steel material (slab) and adding an element that has a nitriding suppressing effect to the insulating film, nitriding during strain relief annealing can be improved. It can be effectively deterred.
- the effect of suppressing nitriding at the time of strain relief annealing by adding Zn to the steel material and adding an element having a nitriding suppressing effect into the insulating film is not sufficient, and both are used in combination. Therefore, it was found that the nitriding suppressing effect can be further enhanced.
- the steel material contains an appropriate amount of Zn and the insulating coating contains an element having a nitriding suppressing effect, that is, the insulating coating has a nitriding suppressing ability.
- the second embodiment of the present invention is characterized in that nitriding of the surface layer of the steel sheet at the time of strain removal annealing is suppressed by imparting the above.
- the inventors immersed the steel sheet after finish annealing produced in ⁇ Experiment 1> described above in a treatment bath of zinc phosphate (PB-L47 manufactured by Nihon Parkerizing Co., Ltd.) for 30 seconds, washed it with water, and dried it with warm air. After forming an intermediate layer on the front and back surfaces of the steel sheet, an insulating film was applied on the intermediate layer to obtain a product plate.
- the basis weight of the intermediate layer was set so that the film thickness on one side was 30 nm.
- silica sol ST-C manufactured by Nissan Chemical Industries
- acrylic resin EPD-5560 manufactured by DIC
- a coating liquid adjusted to a solid content concentration of 10 mass% was applied to both sides of the steel sheet with a roll coater so that the coating film had a grain size of 0.5 g / m 2 on one side, and reached a maximum of 280 ° C in 30 s in a hot air furnace. It was baked under the condition that the plate temperature (equal heating time: 0 s) was obtained.
- the concentration of N (Nas AlN) present as AlN in the 1/20 layer of the sheet thickness was analyzed by an electrolytic extraction method.
- the iron loss W 10 Similar to FIG. 4, it was found that the Nas AlN of all the steel sheets having / 800 below the reference value was 100 mass ppm (0.0100 mass%) or less. From these results, an intermediate layer containing at least one element selected from Sn, Sb, P, S, Se, As, Te, B, Pb and Bi having a nitriding suppressing effect was formed on the surface of the steel sheet base iron and an insulating film. It was found that the same nitriding-suppressing effect as that of including the element having the nitriding-suppressing effect in the insulating film can be obtained by forming the mixture between the two.
- the insulating film can bear an insulating effect other than the nitriding suppressing function.
- the insulating film In order to improve the adhesion and scratch resistance of the insulating film, it is necessary to strengthen the bond of the insulating film itself, but as in the first embodiment, many elements are contained in the insulating film. If so, the bond tends to be weak.
- the insulating coating it is not necessary for the insulating coating to have a new function of suppressing nitriding, and the elements contained in the insulating coating can be limited, so that the bond of the coating itself remains strong. Can be maintained.
- the coating layer on the surface of the steel sheet has a multi-layer structure of an intermediate layer and an insulating film between the surface of the steel sheet base and the insulating film, so that corrosion resistance and moisture resistance are improved.
- the following effects can be obtained.
- the intermediate layer can be expected to have an insulating effect in addition to the nitriding suppressing effect, the total film thickness of the intermediate layer and the insulating film is made thinner than the film thickness of only the insulating film of the first embodiment. Therefore, it also has the effect of increasing the space factor (core magnetic flux).
- composition of the steel material (slab) used in the production of the non-oriented electrical steel sheet of the present invention will be described. There is no difference in the composition of the steel material used between the first embodiment and the second embodiment of the present invention.
- C contained in the product plate is a harmful element that forms carbides, causes magnetic aging, and deteriorates iron loss characteristics. Therefore, the upper limit of C contained in the material is limited to 0.0050 mass%. It is preferably 0.0040 mass% or less. Although the lower limit of C is not particularly specified, it is preferably about 0.0001 mass% from the viewpoint of reducing the decarburization cost in the refining step.
- Si 2.8-6.5 mass%
- Si has the effect of increasing the intrinsic resistance of the steel and reducing the iron loss, and has the effect of increasing the strength of the steel by solid solution strengthening. Therefore, Si is contained in an amount of 2.8 mass% or more.
- the upper limit is set to 6.5 mass%. It is preferably in the range of 3.0 to 6.0 mass%.
- Mn 0.1-2.0 mass%
- Mn is an element useful for increasing the intrinsic resistance and strength of steel, and is also an element for fixing S and improving hot brittleness, so that Mn is contained in an amount of 0.1 mass% or more.
- the upper limit is set to 2.0 mass%. It is preferably in the range of 0.2 to 1.5 mass%.
- MnS is preferentially formed and the formation of ZnS is suppressed, so that the formation of a film made of a composite compound containing a Zn oxide or the like can be promoted.
- P 0.10 mass% or less
- P is an element that increases the intrinsic resistance of steel and has a large effect of reducing eddy current loss. Moreover, since it has a large solid solution strengthening ability, it can be added as appropriate. However, excessive addition of P causes the steel to become brittle and deteriorates cold rollability, so the upper limit is set to 0.10 mass%. It is preferably 0.05 mass% or less.
- S 0.0050 mass% or less S is preferable because it becomes sulfide to form precipitates and inclusions and lowers manufacturability (hot rollability) and magnetic properties of the product plate. Therefore, the upper limit of S is 0.0050 mass%. It is preferably 0.0030 mass% or less.
- Al 0.3-2.0 mass%
- the upper limit is set to 2.0 mass%.
- the lower limit is set to 0.3 mass%. It is preferably in the range of 0.4 to 1.5 mass%.
- N 0.0050 mass% or less N is an element that forms and precipitates nitrides and deteriorates magnetic properties, and is therefore limited to 0.0050 mass% or less. It is preferably 0.0040 mass% or less.
- Ti and Nb are elements that form and precipitate fine precipitates and increase iron loss. If it exceeds 0.0030 mass% in either case, the above adverse effect becomes remarkable, so the upper limit is set to 0.0030 mass%. It is preferably 0.0020 mass% or less, respectively.
- O 0.0050 mass% or less
- O is an element that forms an oxide and exists in steel as an inclusion and deteriorates magnetic properties, and is therefore limited to 0.0050 mass% or less. It is preferably 0.0040 mass% or less.
- Zn 0.0005 to 0.0050 mass%
- Zn is one of the most important elements in the present invention, and since it has an effect of suppressing nitriding during strain relief annealing, it is contained in an amount of 0.0005 mass% or more. On the other hand, if it is added in excess of 0.0050 mass%, sulfide is formed and iron loss is increased, so the content is limited to 0.0050 mass% or less. It is preferably in the range of 0.001 to 0.004 mass%.
- the steel material used in the present invention contains Fe and unavoidable impurities as the balance other than the above-mentioned components, but may further contain at least one group of the following components A to D in addition to the above-mentioned components.
- Group A; One or two Sn and Sb selected from Sn: 0.005 to 0.20 mass% and Sb: 0.005 to 0.20 mass% improve the recrystallization texture and magnetic flux density. It has the effect of improving the iron loss characteristics.
- the element is preferably contained in an amount of 0.005 mass% or more. However, even if it is added in excess of 0.20 mass%, the above effect is saturated. Therefore, when Sn and Sb are added, it is preferable to add them in the range of 0.005 to 0.20 mass%, respectively. More preferably, each is in the range of 0.01 to 0.1 mass%.
- Group B One or more selected from Ca, Mg and REM in total 0.0005 to 0.020 mass% Ca, Mg and REM form stable sulfides and have the effect of improving grain growth during strain relief annealing.
- the total amount is preferably in the range of 0.0005 to 0.020 mass%. More preferably, it is in the range of 0.001 to 0.008 mass%.
- Cu, Ni, Cr and Co in total of 0.01 to 1.0 mass%
- Cu, Ni, Cr and Co have the effects of increasing the intrinsic resistance of steel to reduce iron loss and increasing the strength of steel.
- addition of more than 1 mass% causes an increase in raw material cost. Therefore, when the above elements are added, the total is preferably in the range of 0.01 to 1.0 mass%. More preferably, it is in the range of 0.1 to 0.5 mass%.
- Mo and W are elements that increase high temperature strength, Cracking can be suppressed.
- Mo and W are elements that increase high temperature strength, Cracking can be suppressed.
- the above effect is not sufficient when the contents of Mo and W are less than 0.001 mass% of each, while even if added in excess of 0.1 mass%, the above effect is saturated and the raw material cost is only increased. Is. Therefore, when Mo and W are added, it is preferably in the above range. More preferable contents are in the range of 0.0050 to 0.050 mass%, respectively.
- the method for manufacturing the non-oriented electrical steel sheet of the present invention will be described.
- a steel material (slab) having the above-mentioned composition is produced, the slab is hot-rolled to obtain a hot-rolled plate, and if necessary, the hot-rolled plate is annealed. It can be manufactured by a manufacturing process consisting of a series of steps of cold rolling to obtain a cold-rolled plate having a final plate thickness (product plate thickness), finish annealing, and then forming an insulating film.
- the step different between the first embodiment and the second embodiment of the present invention is a step of forming an insulating film on the steel sheet after the finish annealing.
- a specific description will be given.
- a steel having a component composition suitable for the above-mentioned invention is usually used in a converter, an electric furnace, a vacuum degassing device, or the like. It can be melted by a known refining process and manufactured by a conventional continuous casting method or an ingot-integral rolling method. A thin slab having a thickness of 100 mm or less may be produced by a direct casting method.
- the above slab is hot-rolled by a commonly known method to obtain a hot-rolled plate.
- the slab is reheated to a predetermined temperature in a heating furnace and then subjected to hot rolling, but after casting, the slab may be immediately subjected to hot rolling without being reheated. Further, in the case of a thin slab, hot rolling may be performed, or hot rolling may be omitted and the process may proceed as it is.
- the soaking temperature in the range of 800 to 1100 ° C. If the annealing temperature is less than 800 ° C, the effect of hot-rolled sheet annealing is small and a sufficient effect of improving magnetic properties cannot be obtained, while if it exceeds 1100 ° C, the crystal grains become coarse and brittle fracture during cold rolling. It promotes (plate breakage) and is disadvantageous in terms of manufacturing cost. Further, the soaking time is preferably 3 min or less from the viewpoint of ensuring productivity. More preferably, the soaking temperature is 850 to 1000 ° C., and the soaking time is 1 min or less.
- the steel sheet that has been hot-rolled or hot-rolled and then subjected to hot-rolled sheet annealing is a cold-rolled sheet having a final plate thickness by one cold-rolling or two or more cold-rolling sandwiching an intermediate annealing.
- the finish thickness (final plate thickness) of cold rolling is not particularly limited, but is preferably in the range of 0.10 to 0.35 mm. This is because if it is less than 0.10 mm, the productivity decreases, while if it exceeds 0.35 mm, the iron loss increases as shown in FIG.
- the cold-rolled plate with the final plate thickness is subjected to finish annealing.
- This condition is preferably continuous annealing in which heat is equalized for 1 to 300 s at a temperature of 700 to 900 ° C. If the soaking temperature is less than 700 ° C., recrystallization does not proceed sufficiently, good magnetic properties cannot be obtained, and the shape correction effect in continuous annealing cannot be sufficiently obtained. On the other hand, if the temperature exceeds 900 ° C., the crystal grain size becomes coarse and the strength decreases. From the viewpoint of ensuring the strength after finish annealing required for the rotor core, it is desirable that the finish annealing conditions be as low as possible and for a short time within the range where shape correction is possible.
- the steel sheet that has been subjected to the finish annealing is coated with a coating agent that serves as an insulating film on at least the surface of the steel sheet piece, heated and baked to form an insulating film, and is used as a product plate.
- the type of the insulating coating is not particularly limited, but one having a solid content made of an inorganic material or one made of an organic resin and an inorganic material is preferable.
- the insulating film contains an organic resin
- the ratio of the organic resin to the solid content after baking is preferably in the range of 70 mass% or less. This is because if the proportion of the organic resin exceeds 70 mass%, it causes deterioration of heat resistance.
- the type of the organic resin is not particularly limited, and conventionally known known ones can be used.
- acrylic resin, alkyd resin, styrene resin, polyolefin resin, epoxy resin, phenol resin, and urethane can be used.
- Any resin, polyester resin, melamine resin or the like can be preferably used.
- the type of the inorganic material is not particularly limited, and one or more of oxides, hydroxides, carbonates, carbides and the like composed of Si, Al, Ti, Zr, Cr and the like may be selected.
- components that may be contained in the coating agent for the insulating coating include, for example, rust preventives, surfactants, lubricants, and defoamers added to improve the characteristics and uniform coating properties of the insulating coating.
- rust preventives for example, rust preventives, surfactants, lubricants, and defoamers added to improve the characteristics and uniform coating properties of the insulating coating.
- agents for example, antioxidants, etc.
- known coloring pigments, extender pigments, and functional pigments may be included. These components can be contained within a range that does not deteriorate the performance of the insulating coating, specifically, as long as the solid content after baking is 5 mass% or less.
- the basis weight of the coating material to be applied is determined in consideration of obtaining sufficient insulating properties and obtaining a sufficient nitriding suppressing effect. Specifically, it is preferable to apply the basis weight after baking so that the basis weight is 0.1 g / m 2 or more per side, and more preferably 0.2 g / m 2 or more. However, as the basis weight increases, the cost of the coating material increases and the space factor when the iron core is used decreases. Therefore, the upper limit is preferably 10 g / m 2 per side. It is more preferably 5 g / m 2 or less, still more preferably 2 g / m 2 or less.
- the baking method after applying the coating agent is not particularly limited, and a baking method such as a hot air type, an infrared heating type, an induction heating type, etc., which is usually carried out, can be applied.
- the baking temperature may be in the temperature range where it is usually carried out, and for example, the maximum temperature reached of the steel sheet is preferably about 80 to 350 ° C.
- the heating time from the start to the end of heating is preferably in the range of 0.1 to 60 s, more preferably in the range of 1 to 30 s.
- the most important thing in the present invention is to form a coating layer (nitriding suppressing layer) having a nitriding suppressing ability on the surface of the steel sheet after the finish annealing described above.
- the method for forming the coating layer is as follows: the first embodiment of imparting a nitriding suppressing ability to the insulating film formed on the surface of the steel sheet base iron, and an intermediate layer having a nitriding suppressing ability between the surface of the steel sheet base iron and the insulating film. It differs from the second embodiment to be formed.
- a specific description will be given.
- the first embodiment of the present invention is used as a coating layer having a nitriding suppressing ability on the insulating film formed on the surface of the steel sheet base iron after finish annealing, and is used in the insulating film in order to have a nitriding suppressing function.
- the method of incorporating at least one element selected from Sn, Sb, P, S, Se, As, Te, B, Pb and Bi in the insulating coating is not particularly limited, but as an inorganic compound, Examples thereof include a method of dissolving or dispersing in a coating agent for an insulating coating. Those that can be dissolved in the coating agent are dissolved, and those that are difficult to dissolve are mixed and dispersed.
- the form of the inorganic compound any one such as an oxide, a carbide, a hydroxide, a carbonate, a chromate, and a phosphate can be used.
- the blending amount of these elements is preferably 0.001 mass% or more in total in terms of the ratio of the elements in the coating film after baking. However, if it is added in an excessive amount, it causes deterioration of corrosion resistance and film adhesion, so the upper limit is preferably about 10 mass%.
- a second embodiment of the present invention is a form in which an insulating film formed on the surface of a steel sheet after finish annealing and an intermediate layer having a nitriding inhibitory ability are formed between the insulating film and the surface of the steel sheet base iron.
- the intermediate layer is characterized by containing at least one element selected from Sn, Sb, P, S, Se, As, Te, B, Pb and Bi.
- the nitriding suppressing function it is not necessary for the nitriding suppressing function to be carried by the insulating coating, and the elements contained in the insulating coating can be limited to the minimum, so that a strong bond is maintained and excellent flaw resistance is provided. You can get sex.
- the method for forming an intermediate layer containing at least one element selected from the above Sn, Sb, P, S, Se, As, Te, B, Pb and Bi is not particularly limited, but for example, the above.
- examples thereof include a method in which a treatment liquid containing an element is attached to the surface of a steel sheet by dipping or spraying, or is applied to the surface of a steel sheet by a roll coat or the like, and then dried.
- the conditions for forming the intermediate layer are not particularly limited, but in consideration of productivity, it is preferable to select a method capable of treating at room temperature in a time of 10 s or more and 10 min or less.
- a plating process or a dry process by a CVD method or a PVD method may be applied.
- the intermediate layer to be formed may be two or more layers.
- the motor core is usually composed of a rotor core that requires high strength and a stator core that requires low iron loss and high magnetic flux density.
- the former rotor core is used as a motor core in the state where a steel plate coated with an insulating film is punched into a core shape after finish annealing, laminated, and fixed, while the latter stator core is used. After finish annealing, the steel sheet covered with the insulating film is processed into a core shape by punching, etc., laminated and fixed, and further strain-removed and annealed for the purpose of improving magnetic characteristics, and then used as a motor core. It is common to be done.
- the stress relief annealing in an inert gas atmosphere such as Ar gas or N 2 gas is preferably carried out under the conditions of 800 ⁇ 950 °C ⁇ 0.5 ⁇ 3hr .
- the temperature of the strain annealing is less than 800 ° C. and the time is less than 0.5 hr, the grain growth effect of the crystal grains by the strain annealing is small and the iron loss improving effect cannot be sufficiently obtained. Therefore, the iron loss after the strain annealing is not sufficiently obtained. There is a risk that W 10/800 will not be able to clear the iron loss reference value defined by the above-mentioned equation (2).
- the temperature of strain relief annealing exceeds 950 ° C. and the time exceeds 3 hr, it becomes difficult to secure insulation between the laminated steel sheets. More preferable strain removing and annealing conditions are in the range of 800 to 875 ° C. ⁇ 1 to 2 hr.
- the steel sheet after the strain annealing has an appropriate amount of Zn added to the steel material and has a coating layer having a nitriding inhibitory ability on the surface of the steel sheet, so that nitrification during the strain annealing is suppressed. Therefore, the concentration of N (Nas AlN) existing as AlN in the layers from one side surface of the steel sheet to the 1/20 layer of the sheet thickness (1/20 layer of the sheet thickness) after strain relief annealing is 100 mass ppm or less (0.0100 mass). % Or less).
- the coating agent for the insulating coating which is a combination of the above in the configuration shown in Table 2, is applied to both sides of the steel sheet with a roll coater so that the basis weight per side becomes the value shown in Table 2, and is shown in Table 2 in a hot air drying furnace. It was baked under the above conditions to make a product plate.
- iron loss W 10/800 was measured by the Epstein test, and the steel sheet after strain removal annealing was subjected to electrolytic extraction in a plate thickness of 1/20 layer.
- the concentration of N (Nas AlN) present as AlN was analyzed.
- test pieces having a width of 100 mm and a length of 200 mm having the rolling direction (L direction) as the length direction are collected from the product plate covered with the insulating coating under each condition, and the two test pieces are taken. After sliding for 10 s at a relative speed of 2 cm / s with a pressure of 1 kg / cm 2 applied, visually observe the presence or absence of scratches on the surface of the test piece, and scratch resistance according to the following criteria. The attachment was evaluated.
- the agent is applied and dried to form an intermediate layer having a film thickness of 5 to 100 nm after drying, and then the components C to G shown in Table 6 are combined in the configuration shown in Table 5 to form an insulating coating.
- the agent was applied to both surfaces of the steel sheet with a roll coater so that the basis weight on one side had the values shown in Table 5, and baked in a hot air drying furnace under the conditions shown in Table 5 to obtain a product plate.
- test pieces having a width of 100 mm and a length of 200 mm having the rolling direction (L direction) as the length direction were collected under each condition, and the same as in Example 1.
- L direction rolling direction
- the technique of the present invention has the effect of increasing the strength of the insulating film, it can be applied not only to the field of non-oriented electrical steel sheets but also to grain-oriented electrical steel sheets.
Abstract
Description
記
・A群;Sn:0.005~0.20mass%およびSb:0.005~0.20mass%のうちから選ばれる1種または2種
・B群;Ca,MgおよびREMのうちから選ばれる1種または2種以上を合計で0.0005~0.020mass%
・C群;Cu,Ni,CrおよびCoのうちから選ばれる1種または2種以上を合計で0.01~1.0mass%
・D群;Mo:0.001~0.1mass%およびW:0.001~0.1mass%のうちから選ばれる1種または2種
記
・A群;Sn:0.005~0.20mass%およびSb:0.005~0.20mass%のうちから選ばれる1種または2種
・B群;Ca,MgおよびREMのうちから選ばれる1種または2種以上を合計で0.0005~0.020mass%
・C群;Cr,Co,NiおよびCuのうちから選ばれる1種または2種以上を合計で0.01~1.0mass%
・D群;Mo:0.001~0.1mass%およびW:0.001~0.1mass%のうちから選ばれる1種または2種
W10/800≦15+80×t ・・・(1)
を満たし、かつ、上記歪取焼鈍後の鋼板の片側表面から板厚1/20までの層内においてAlNとしての存在するN(N as AlN)が0.0100mass%以下であることを特徴とするモータコアである。
W10/800≦15+80×t ・・・(1)
を満たし、かつ、上記歪取焼鈍後の鋼板の片側表面から板厚1/20までの層内においてAlNとして存在するN(N as AlN)が0.0100mass%以下とすることを特徴とする。
[第1の実施の形態]
本発明の第1の実施の形態は、鋼素材(スラブ)中にZnを適正量含有することで、仕上焼鈍後の鋼板表面にZnやAlを含む酸化物等の複合化合物からなる被膜を形成し、さらに、仕上焼鈍後の鋼板表面に被成する絶縁被膜中にSn,Sb,P,S,Se,As,Te,B,PbおよびBiから選ばれる少なくとも1種の元素を含ませることで、上記両被膜に窒化抑制能を付与することによって、歪取焼鈍時の鋼板表層の窒化を抑制することを特徴とする。
<実験1>
C:0.0025mass%、Si:3.5mass%、Mn:0.6mass%、P:0.01mass%、S:0.0015mass%、Al:0.9mass%、N:0.0023mass%、Ti:0.0011mass%、Nb:0.0009mass%およびO:0.0021mass%を含有し、残部がFeおよび不可避不純物からなる成分組成の鋼を2チャージ(チャージA,B)溶製し、連続鋳造法で鋼素材(スラブ)とした後、該スラブを熱間圧延して板厚1.9mmの熱延板とし、950℃×30sの熱延板焼鈍を施した後、酸洗し、冷間圧延して最終板厚0.30mmの冷延板とし、vol%比でH2:N2=20:80の雰囲気下で、800℃×10sの仕上焼鈍を施した後、該仕上焼鈍後の鋼板表裏面に絶縁被膜を被成し、製品板とした。ここで、上記絶縁被膜は、第一リン酸マグネシウム:Mg(H2PO4)2(太平化学産業製)とアクリル樹脂(DIC製EFD-5560)を固形分比率がmass%比で90:10の割合となるよう混合し、脱イオン水を用いて固形分濃度を10mass%に調整した塗布液を、焼き付け後の塗膜の目付量が片面当たり0.5g/m2となるようロールコーターで鋼板両面に塗布し、熱風炉で、30sで280℃の最高到達板温(均熱時間は0s)となる条件で焼き付けることで被成した。
そこで、歪取焼鈍時の鋼板表面における窒化挙動および歪取焼鈍後の鉄損特性に及ぼすZn含有量の影響を調査する以下の実験を行った。
C:0.0027mass%、Si:3.6mass%、Mn:0.8mass%、P:0.01mass%、S:0.0018mass%、Al:1.1mass%、N:0.0021mass%、Ti:0.0012mass%、Nb:0.0008mass%およびO:0.0022mass%を含有し、かつ、Znを0.0001~0.01mass%の範囲で種々に変化して含有し、残部がFeおよび不可避不純物からなる成分組成の鋼を真空溶解炉で溶製し、鋳造して鋼塊とし、熱間圧延して板厚2.0mmの熱延板とし、940℃×30sの熱延板焼鈍を施した後、酸洗し、冷間圧延して最終板厚0.25mmの冷延板とした後、vol%比でH2:N2=20:80の雰囲気下で、780℃×10sの仕上焼鈍を施した後、鋼板表裏面に、上記<実験1>と同条件で絶縁被膜を被成し、製品板とした。
W10/800=15+80×t ・・・(2)
で定義される鉄損基準値より鉄損が下回っていることがわかった。
上記のように、本発明の第1の実施の形態は、鋼素材中にZnを適正量含有させるとともに、絶縁被膜中に窒化抑制効果のある元素を含ませる、すなわち、絶縁被膜に窒化抑制能を付与することで歪取焼鈍時の鋼板表層の窒化を抑制することを特徴としているが、本発明の第2の実施の形態は、上記第1の実施の形態の絶縁被膜に替えて、上記絶縁被膜と鋼板の地鉄表面との間に、窒化抑制効果のある元素を含有した中間層を形成する(したがって、絶縁被膜には窒化抑制効果のある元素は含まない)ことで、高温での歪取焼鈍時の鋼板表層の窒化を抑制することを特徴とする。
これらの結果から、窒化抑制効果のあるSn,Sb,P,S,Se,As,Te,B,PbおよびBiから選ばれる少なくとも1種の元素を含有する中間層を鋼板地鉄表面と絶縁被膜の間に形成することによっても、絶縁被膜中に上記窒化抑制効果のある元素を含ませるのと同様の窒化抑制効果が得られることがわかった。
製品板中に含まれるCは、炭化物を形成して磁気時効を起こし、鉄損特性を劣化させる有害元素である。そのため、素材中に含まれるCの上限は0.0050mass%に制限する。好ましくは0.0040mass%以下である。なお、Cの下限は、特に規定しないが、精錬工程での脱炭コストを低減する観点から、0.0001mass%程度とするのが好ましい。
Siは、鋼の固有抵抗を高め、鉄損を低減する効果があり、また、固溶強化により鋼の強度を高める効果があるため、2.8mass%以上含有させる。一方、6.5mass%を超えると、鋼が脆化し、圧延することが困難になるため、上限は6.5mass%とする。好ましくは3.0~6.0mass%の範囲である。
Mnは、Siと同様、鋼の固有抵抗と強度を高めるのに有用な元素であり、また、Sを固定して熱間脆性を改善する元素でもあるため、0.1mass%以上含有させる。一方、2.0mass%を超える添加は、スラブ割れ等を起こして製鋼工程の操業性が悪化するため、上限は2.0mass%とする。好ましくは0.2~1.5mass%の範囲である。特に、Mnを0.2mass%以上含有させると、MnSが優先して形成され、ZnSの形成が抑制されるため、Zn酸化物等を含む複合化合物からなる被膜の形成を促進することができる。
Pは、鋼の固有抵抗を高め、渦電流損の低減効果が大きい元素である。また、固溶強化能が大きいため、適宜添加することができる。しかし、Pの過剰な添加は、鋼が脆化し、冷間圧延性の悪化を招くので、上限は0.10mass%とする。好ましくは0.05mass%以下である。
Sは、硫化物となって析出物や介在物を形成し、製造性(熱間圧延性)や製品板の磁気特性を低下させるので、少ないほど好ましい。よって、Sの上限は0.0050mass%とする。好ましくは0.0030mass%以下である。
Alは、Siと同様、鋼の固有抵抗を高めて、鉄損を低減する効果がある。しかし、2.0mass%を超えると、鋼が脆化し、圧延することが困難になるため、上限は2.0mass%とする。一方、Alが0.3mass%未満となると、微細な窒化物を形成して析出し、却って鉄損特性を悪化させるため、下限は0.3mass%とする。好ましくは0.4~1.5mass%の範囲である。
Nは、窒化物を形成して析出し、磁気特性を劣化させる元素であるため、0.0050mass%以下に制限する。好ましくは0.0040mass%以下である。
TiおよびNbは、微細析出物を形成して析出し、鉄損を増加させる元素である。いずれも0.0030mass%を超えると上記悪影響が顕著になるため、それぞれ上限は0.0030mass%とする。好ましくはそれぞれ0.0020mass%以下である。
Oは、酸化物を形成して介在物として鋼中に存在し、磁気特性を劣化させる元素であるため、0.0050mass%以下に制限する。好ましくは0.0040mass%以下である。
Znは、本発明において最も重要な元素の一つであり、歪取焼鈍時の窒化を抑制する効果があるため、0.0005mass%以上含有させる。一方、0.0050mass%を超えて添加すると、硫化物を形成して鉄損を増加させるため、0.0050mass%以下に制限する。好ましくは0.001~0.004mass%の範囲である。
・A群;Sn:0.005~0.20mass%およびSb:0.005~0.20mass%のうちから選ばれる1種または2種
SnおよびSbは、再結晶集合組織を改善し、磁束密度と鉄損特性を改善する効果がある。上記効果を得るためには、上記元素は0.005mass%以上の含有するのが好ましい。しかし、0.20mass%を超えて添加しても、上記効果は飽和する。よって、SnおよびSbを添加する場合は、それぞれ0.005~0.20mass%の範囲で添加するのが好ましい。より好ましくは、それぞれ0.01~0.1mass%の範囲である。
Ca,MgおよびREMは、安定な硫化物を形成し、歪取焼鈍時の粒成長性を改善する効果がある。上記効果を得るためには、上記元素を合計で0.0005mass%以上添加するのが好ましい。一方、0.020mass%超え添加しても、上記効果は飽和してしまう。よって、上記元素を添加する場合は、合計で0.0005~0.020mass%の範囲とするのが好ましい。より好ましくは、0.001~0.008mass%の範囲である。
Cu,Ni,CrおよびCoは、鋼の固有抵抗を高めて鉄損を低減したり、鋼の強度を高めたりする効果がある。上記効果を得るためには、Cu,Ni,CrおよびCoを合計で0.01mass%以上添加するのが好ましい。しかし、1mass%を超える添加は原料コストの上昇を招く。よって、上記元素を添加する場合は、合計で0.01~1.0mass%の範囲とするのが好ましい。より好ましくは、0.1~0.5mass%の範囲である。
MoおよびWは、いずれも表面欠陥(ヘゲ)を抑制するのに有効な元素である。本発明の鋼板は高合金鋼であるため、表面が酸化され易く、表面割れに起因するヘゲの発生が懸念されるが、高温強度を高める元素であるMoやWを微量添加することで、割れを抑制することができる。上記効果は、MoおよびWの含有量がそれぞれの0.001mass%を下回ると十分ではなく、一方、0.1mass%を超えて添加しても、上記効果が飽和し、原料コストが上昇するだけである。よって、Mo,Wを添加する場合は上記範囲とするのが好ましい。より好ましい含有量はそれぞれ0.0050~0.050mass%の範囲である。
本発明の無方向性電磁鋼板は、上記した成分組成を有する鋼素材(スラブ)を製造し、該スラブを熱間圧延して熱延板とし、必要に応じて熱延板焼鈍を施した後、冷間圧延して最終板厚(製品板厚)の冷延板とし、仕上焼鈍した後、絶縁被膜を被成する一連の工程からなる製造工程で製造することができる。なお、本発明の第1の実施の形態と第2の実施の形態で異なる工程は、上記仕上焼鈍後の鋼板に絶縁被膜を被成する工程である。以下、具体的に説明する。
上記絶縁被膜の種類は特に限定しないが、固形分が無機材料からなるもの、または、有機樹脂と無機材料からなるものが好ましい。無機材料を含有させることで、溶接性や耐熱性を確保でき、また、有機樹脂を含有させることで、プレス成形性を向上することができるので、用途に応じて適宜選択するのが好ましい。なお、絶縁被膜に有機樹脂を含ませる場合、焼付後の固形分に占める有機樹脂の割合は70mass%以下の範囲とするのが好ましい。有機樹脂の割合が70mass%を超えると、耐熱性の劣化の原因となるためである。
本発明の第1の実施の形態は、仕上焼鈍後の鋼板地鉄表面に被成する絶縁被膜に窒化抑制能を有する被覆層として使用する形態であり、窒化抑制機能をもたせるため、絶縁被膜中にSn,Sb,P,S,Se,As,Te,B,PbおよびBiから選ばれる少なくとも1種の元素を含ませることを特徴としている。これらの元素を絶縁被膜中に含ませることで、絶縁被膜の密度および密着性が向上し、絶縁被膜に窒化抑制効果を付与することができる。
本発明の第2の実施形態は、仕上焼鈍後の鋼板表面に被成した絶縁被膜と、該絶縁被膜と鋼板地鉄表面との間に窒化抑制能を有する中間層を形成する形態であり、上記中間層中にSn,Sb,P,S,Se,As,Te,B,PbおよびBiから選ばれる少なくとも1種の元素を含ませることを特徴としている。これらの元素を中間層中に含ませることで、中間層に窒化抑制効果を付与することができるだけでなく、絶縁効果や防錆効果も付随的に期待できる。また、中間層と絶縁被膜の合計膜厚を、第1の実施形態の絶縁被膜の膜厚よりも薄くできるので、占積率(コア磁束)を向上させることができる。
モータコアは、通常、高強度が求められるロータコアと、低鉄損高磁束密度が求められるステータコアから構成されている。前者のロータコアは、仕上焼鈍後、絶縁被膜を被成した鋼板を打抜加工等でコア形状に加工し、積層し、固定したそのままの状態で、モータコアとして使用されるが、後者のステータコアは、仕上焼鈍後、絶縁被膜を被成した鋼板を打抜加工等でコア形状に加工し、積層し、固定した後、さらに、磁気特性の向上を目的として歪取焼鈍を施した後、モータコアとして使用されるのが一般的である。
W10/800=15+80×t ・・・(2)
で定義される鉄損基準値をクリアすることができる。
また、上記絶縁被膜を被成した製品板から、圧延方向(L方向)を長さ方向とする幅100mm、長さ200mmの試験片を各条件で2枚ずつ採取し、該2枚の試験片を重ね合わせ、圧力1kg/cm2を付加した状態で、相対速度2cm/sで10s間摺動させた後、試験片表面の擦り傷の発生有無を目視で観察し、下記の基準で、耐疵付性を評価した。
<耐疵付性評価基準>
◎:擦り傷の発生が殆ど認められない(合格)
〇:若干の擦り傷が認められる(合格)
×:擦り傷が明確に認められる(不合格)
さらに、上記絶縁被膜を被成した製品板から、圧延方向(L方向)を長さ方向とする幅100mm、長さ200mmの試験片を各条件で2枚ずつ採取し、被試験面にセロハン粘着テープを貼り、被試験面を圧縮側として、鋼板に対して直径5mmの丸棒を用いて180°曲げを行った後、セロハン粘着テープを剥がして、被膜剥離面積を算定し、下記基準で被膜密着性を評価した。
<被膜密着性判定基準>
◎:被膜剥離面積<5%(合格)
〇:5%≦被膜剥離面積<10%(合格)
×:被膜剥離面積≧10%(不合格)
また、上記中間層と絶縁被膜を有する製品板から、圧延方向(L方向)を長さ方向とする幅100mm、長さ200mmの試験片を各条件で2枚ずつ採取し、実施例1と同様、該2枚の試験片を重ね合わせ、圧力1kg/cm2を付加した状態で、相対速度2cm/sで10s間摺動させた後、試験片表面の擦り傷の発生有無を目視で観察し、下記の基準で、耐疵付性を評価した。
<耐疵付性評価基準>
◎:擦り傷の発生が殆ど認められない(合格)
〇:若干の擦り傷が認められる(合格)
×:擦り傷が明確に認められる(不合格)
さらに、上記絶縁被膜を被成した製品板から、圧延方向(L方向)を長さ方向とする幅100mm、長さ200mmの試験片を各条件で2枚ずつ採取し、被試験面にセロハン粘着テープを貼り、被試験面を圧縮側として、鋼板に対して直径5mmの丸棒を用いて180°曲げを行った後、セロハン粘着テープを剥がして、被膜剥離面積を算定し、下記基準で被膜密着性を評価した。
<被膜密着性判定基準>
◎:被膜剥離面積<5%(合格)
〇:5%≦被膜剥離面積<10%(合格)
×:被膜剥離面積≧10%(不合格)
Claims (11)
- C:0.0050mass%以下、Si:2.8~6.5mass%、Mn:0.1~2.0mass%、P:0.10mass%以下、S:0.0050mass%以下、Al:0.3~2.0mass%、N:0.0050mass%以下、Zn:0.0005~0.0050mass%、Ti:0.0030mass%以下、Nb:0.0030mass%以下およびO:0.0050mass%以下を含有し、残部がFeおよび不可避不純物からなる成分組成を有し、
鋼板の表面に、Sn,Sb,P,S,Se,As,Te,B,PbおよびBiから選ばれる少なくとも1種の元素を含有する被覆層を有することを特徴とする無方向性電磁鋼板。 - 上記成分組成に加えてさらに、下記A~D群のうちの少なくとも1群の成分を含有することを特徴とする請求項1に記載の無方向性電磁鋼板。
記
・A群;Sn:0.005~0.20mass%およびSb:0.005~0.20mass%のうちから選ばれる1種または2種
・B群;Ca,MgおよびREMのうちから選ばれる1種または2種以上を合計で0.0005~0.020mass%
・C群;Cu,Ni,CrおよびCoのうちから選ばれる1種または2種以上を合計で0.01~1.0mass%
・D群;Mo:0.001~0.1mass%およびW:0.001~0.1mass%のうちから選ばれる1種または2種 - 上記被覆層は、鋼板地鉄表面に形成された絶縁被膜であることを特徴とする請求項1または2に記載の無方向性電磁鋼板。
- 上記被覆層は、鋼板表面の最上層に形成された絶縁被膜と、該絶縁被膜と鋼板地鉄表面との間に形成された中間層とからなり、
該中間層が、Sn,Sb,P,S,Se,As,Te,B,PbおよびBiから選ばれる少なくとも1種の元素を含有することを特徴とする請求項1または2に記載の無方向性電磁鋼板。 - 鋼スラブを熱間圧延し、冷間圧延し、仕上焼鈍して無方向性電磁鋼板を製造する方法において、
上記鋼スラブは、C:0.0050mass%以下、Si:2.8~6.5mass%、Mn:0.1~2.0mass%、P:0.10mass%以下、S:0.0050mass%以下、Al:0.3~2.0mass%、N:0.0050mass%以下、Zn:0.0005~0.0050mass%、Ti:0.0030mass%以下、Nb:0.0030mass%以下およびO:0.0050mass%以下を含有し、残部がFeおよび不可避不純物からなる成分組成を有し、
上記仕上焼鈍後に鋼板表面に、Sn,Sb,P,S,Se,As,Te,B,PbおよびBiから選ばれる少なくとも1種の元素を含有する被覆層を形成することを特徴とする無方向性電磁鋼板の製造方法。 - 上記鋼スラブは、上記成分組成に加えてさらに、下記A~D群のうちの少なくとも1群の成分を含有することを特徴とする請求項5に記載の無方向性電磁鋼板の製造方法。
記
・A群;Sn:0.005~0.20mass%およびSb:0.005~0.20mass%のうちから選ばれる1種または2種
・B群;Ca,MgおよびREMのうちから選ばれる1種または2種以上を合計で0.0005~0.020mass%
・C群;Cu,Ni,CrおよびCoのうちから選ばれる1種または2種以上を合計で0.01~1.0mass%
・D群;Mo:0.001~0.1mass%およびW:0.001~0.1mass%のうちから選ばれる1種または2種 - 上記仕上焼鈍後の鋼板の地鉄表面に、上記被覆層として、Sn,Sb,P,S,Se,As,Te,B,PbおよびBiから選ばれる少なくとも1種の元素を含有する被覆剤を塗布して窒化抑制能を有する絶縁被膜を被成することを特徴とする請求項5または6に記載の無方向性電磁鋼板の製造方法。
- 上記仕上焼鈍後の鋼板地鉄表面に、上記被覆層として、Sn,Sb,P,S,Se,As,Te,B,PbおよびBiから選ばれる少なくとも1種の元素を含有する処理剤を塗布して窒化抑制能を有する中間層を形成し、該中間層の上に上記元素を含有していない絶縁被膜を被成することを特徴とする請求項5または6に記載の無方向性電磁鋼板の製造方法。
- 請求項1~4のいずれか1項に記載の無方向性電磁鋼板からコア形状に加工したコア材を積層してなるロータコアと、上記と同一の無方向性電磁鋼板からコア形状に加工したコア材を積層した後、歪取焼鈍を施してなるステータコアからなるモータコアであって、
上記ステータコアを構成する鋼板は、鉄損W10/800(W/kg)が板厚t(mm)との関係で下記(1)式を満たし、かつ、
上記歪取焼鈍後の鋼板の片側表面から板厚1/20までの層内においてAlNとしての存在するN(N as AlN)が0.0100mass%以下であることを特徴とするモータコア。
記
W10/800≦15+80×t ・・・(1) - 請求項5~8のいずれか1項に記載の方法で製造された無方向性電磁鋼板をコア形状に加工し、積層してステータコアとロータコアに組み立てた後、上記ステータコアに歪取焼鈍を施すステータコアとロータコアからなるモータコアの製造方法において、
上記歪取焼鈍を、窒素、水素および希ガスから選ばれる1種のガスまたは2種以上の混合ガスからなる雰囲気下で、均熱温度800~950℃、均熱時間0.5~3.0hrの条件で施すことを特徴とするモータコアの製造方法。 - 上記歪取焼鈍後の鋼板の鉄損W10/800(W/kg)が板厚t(mm)との関係で下記(1)式を満たし、かつ、
上記歪取焼鈍後の鋼板の片側表面から板厚1/20までの層内においてAlNとして存在するN(N as AlN)が0.0100mass%以下とすることを特徴とする請求項10に記載のモータコアの製造方法。
記
W10/800≦15+80×t ・・・(1)
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