WO2020237767A1 - 图形化衬底、外延片、制作方法、存储介质及led芯片 - Google Patents
图形化衬底、外延片、制作方法、存储介质及led芯片 Download PDFInfo
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- WO2020237767A1 WO2020237767A1 PCT/CN2019/093260 CN2019093260W WO2020237767A1 WO 2020237767 A1 WO2020237767 A1 WO 2020237767A1 CN 2019093260 W CN2019093260 W CN 2019093260W WO 2020237767 A1 WO2020237767 A1 WO 2020237767A1
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- patterned substrate
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/005—Processes
- H01L33/0062—Processes for devices with an active region comprising only III-V compounds
- H01L33/0075—Processes for devices with an active region comprising only III-V compounds comprising nitride compounds
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/02—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
- H01L33/20—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a particular shape, e.g. curved or truncated substrate
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/005—Processes
- H01L33/0062—Processes for devices with an active region comprising only III-V compounds
- H01L33/0066—Processes for devices with an active region comprising only III-V compounds with a substrate not being a III-V compound
- H01L33/007—Processes for devices with an active region comprising only III-V compounds with a substrate not being a III-V compound comprising nitride compounds
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/02—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
- H01L33/12—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a stress relaxation structure, e.g. buffer layer
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/02—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
- H01L33/26—Materials of the light emitting region
- H01L33/30—Materials of the light emitting region containing only elements of group III and group V of the periodic system
- H01L33/32—Materials of the light emitting region containing only elements of group III and group V of the periodic system containing nitrogen
Definitions
- the present invention relates to the field of LED technology, in particular to a patterned substrate, an epitaxial wafer, a manufacturing method, a storage medium and an LED chip.
- Micro LED Micro Light Emitting Diode
- Micro LED miniaturization matrix technology refers to the integration of high-density and small-size LED arrays on a chip; each pixel of the LED display can be addressed and individually driven to light up, Micro LED display
- the screen can be regarded as a miniature version of an outdoor LED display, reducing the pixel point distance from millimeters to micrometers.
- Micro LED has many advantages. It has the advantages of inorganic LEDs such as high efficiency, high brightness, high reliability and fast response time. It also has the characteristics of self-luminescence without a backlight, and it has the advantages of energy saving, small size, and simple mechanism.
- the manufacturing method of Micro LED display is as follows: firstly grow LED micro devices by molecular beam epitaxy on a sapphire substrate (and others such as SiC, Si, etc.), and then transfer the LED light emitting micro devices to a glass substrate. Since the size of the sapphire substrate for making LED micro-devices is basically the size of the silicon wafer, while the size of the glass substrate for making the display is much larger, it must be transported multiple times. Therefore, the core technology of Micro LED is the transportation of nano-level LEDs, not the technology of making LEDs. However, the manufacturing technology will also affect subsequent transportation. For example, to facilitate the transfer of large quantities and improve the yield, it is applied to Micro-LEDs.
- the wavelength uniformity of the epitaxial wafer is required to be within 1nm, and the current process can only achieve about 3nm.
- the LED epitaxial wafer is loaded with a substrate in a MOCVD (metal organic chemical vapor deposition) furnace, rotating at high speed in the chamber, using trimethylgallium sources such as TMGa and nitrogen as Ga and N sources, respectively, and ultrapure hydrogen as the carrier With gas, a ternary or quaternary GaN semiconductor layer is epitaxially grown on the substrate.
- MOCVD metal organic chemical vapor deposition
- each substrate will always rotate during the growth of the epitaxial layer. However, because of the constant rotation, the centrifugal force will cause uneven thickness on the monolithic epitaxial layer. The uneven thickness of the epitaxial layer will at least Causes uneven wavelength.
- a patterned substrate applied to a Micro LED wherein the patterned substrate includes a substrate body, and at least one accommodating groove is provided on the substrate body, and the accommodating groove can accommodate at least a portion The epitaxial material dropped during the epitaxial process.
- the accommodating groove includes: a first groove body in a fan ring shape, and when the patterned substrate is placed at a designated position of the MOCVD carrier, the axis of the first groove body Same as the axis of the carrier.
- a plurality of supporting pillars are provided on the substrate body, and a containing groove is formed between every two adjacent supporting pillars.
- a buffer layer is provided on the upper surface of the substrate body, and the containing groove is formed in the buffer layer.
- An epitaxial board comprising the patterned substrate as described above, the epitaxial board further comprising: an epitaxial layer, and the containing groove is formed between the epitaxial layer and the patterned substrate.
- a receiving groove is processed on the substrate body or the buffer layer on the upper surface of the substrate body to form a patterned substrate;
- the patterned substrate is loaded on the carrier in the MOVCD furnace, and processed to generate an epitaxial layer.
- An LED chip includes the patterned substrate as described above.
- the patterned substrate provided by the present invention is provided with at least one accommodating groove capable of accommodating at least a part of the epitaxial material dropped during the epitaxial process, so that the patterned substrate is placed in the MOCVD furnace. At least a part of the excess epitaxial material generated during the process of forming the epitaxial layer by internal high-speed rotation can fall into the accommodating groove without remaining on the epitaxial layer, which improves the problem of uneven thickness of the epitaxial layer, thereby increasing the wavelength Uniformity, that is, the patterned substrate provided by the present invention at least improves the problem of uneven wavelength.
- FIG. 1 is a schematic diagram of the structure of a patterned substrate in a preferred embodiment of the present invention.
- Figure 2 is a schematic diagram of the structure of an epitaxial wafer in a preferred embodiment of the present invention.
- FIG. 3 is a top view of the patterned substrate placed in the MOCVD cavity in the preferred embodiment of the present invention.
- Fig. 4 is a flow chart of a method for manufacturing an epitaxial wafer in a preferred embodiment of the present invention.
- the patterned substrate 100 provided by the present invention (in FIG. 3, 300 represents the carrier in the MOCVD, and the six circles placed on the carrier 300 represent the patterned substrate 100. It is understood that the carrier 300 can accommodate the number of patterned substrates 100 can be increased or decreased, not limited to six), applied to Micro LED, as shown in Figure 1, Figure 2 and Figure 3, which includes: the substrate body 101, the At least one accommodating groove 103 is provided above the substrate body 101.
- the accommodating groove 103 has the function of receiving and accommodating the surplus epitaxial material 104 during the forming process of the epitaxial layer 200.
- the excess epitaxial material 104 will be thrown out of the plane where the unformed epitaxial layer 200 is located along with the rotation of the MOCVD furnace; if the containing groove 103 is not provided, the excess epitaxial material 104 will be thrown out.
- the epitaxial material 104 will adhere to the unformed epitaxial layer 200, which will eventually cause uneven thickness on the surface of the epitaxial layer 200; when the accommodating groove 103 is provided, part or all of the epitaxial material 104 thrown out It will fall into the accommodating groove 103, so that the problem of uneven thickness of the monolithic epitaxial layer 200 can be improved or solved, thereby improving or solving the problem of uneven wavelength.
- the accommodating groove 103 can be selectively completed by a photolithography process, so that the accommodating groove 103 can be formed on the patterned substrate 100 according to a preset position to ensure the performance of the epitaxial wafer and the LED chip after molding.
- the accommodating groove 103 is provided with a plurality of accommodating grooves 103 along the center line of the substrate body 101 (the center line here means that the substrate body 101 can be divided into symmetrical Any straight line of the two semicircles) are arranged in sequence, that is, the plurality of accommodating grooves 103 are arranged in sequence from one side of the substrate body 101 to the other side. Further, the arrangement density of the plurality of accommodating grooves 103 gradually decreases from one side to the other. Specifically, when the patterned substrate 100 is placed in the MOCVD, the accommodating grooves 103 are arranged on the side with a lower density near the other side.
- the center of the carrier 300, the other side is away from the center of the carrier 300; because the farther from the axis of the carrier 300, the greater the centrifugal force, therefore, when the patterned substrate 100 is placed in the MOCVD internal and epitaxial formation
- a plurality of supporting pillars 102 are provided on the upper surface of the patterned substrate 100, and a receiving groove 103 is formed between every two supporting pillars 102.
- the supporting pillars 102 are fan-shaped. Ring. It should be noted that there is no limitation on whether each accommodating groove 103 is connected, that is, the adjacent accommodating grooves 103 may be connected or not connected.
- the accommodating groove 103 includes: a first groove body in a fan ring shape.
- the axis of the first groove body The line is the same as the axis line of the carrier 300.
- the accommodating groove 103 itself has a fan ring shape, or at least a part of it has a fan ring shape, so as to adapt to the ejection law of the epitaxial material, and further improve the epitaxial material receiving capacity of the accommodating groove 103.
- a buffer layer is provided on the upper surface of the patterned substrate 100, and the containing groove 103 is formed in the buffer layer.
- the lattice constant of the material of the support pillar 102 matches the lattice constant of the substrate, and a doped nitride material similar to the material of the buffer layer or a silicon-based doped material can be used.
- the present invention also provides an epitaxial wafer, which includes the patterned substrate 100 as described above, and an epitaxial layer 200 formed on the patterned substrate 100, as shown in FIG. 2 in detail. From the comparison of FIG. 1 and FIG. 2, it can be seen that before the patterned substrate 100 is loaded into the MOVCD furnace, there is no epitaxial material 104 in the accommodating groove 103; and after the epitaxial layer 200 is formed, there remains in the accommodating groove 103 There is an epitaxial material 104. Therefore, the epitaxial wafer is disassembled to check whether the accommodating groove 103 has an epitaxial material 104. It can be known whether the epitaxial wafer is made by the method provided by the present invention.
- a plurality of patterned substrates 100 are respectively placed on the carrier 300 according to a certain rule, and then the carrier 300 is placed in the MOCVD cavity, and then the patterned substrate of FIG. 2 is grown in the MOCVD cavity.
- the accommodating groove 103 is annularly distributed on the substrate body 101 in a plan view, and the center of the ring of the accommodating groove 103 coincides with the center of the carrier 300 in the MOCVD chamber. In this way, during the epitaxial growth process, each substrate 100 rotates at a high speed with the chamber carrier 300, and the centrifugal force generated by the rotation causes the epitaxial layer 200 material to expand to the side.
- the excess epitaxial material 104 falls into the ring groove In 103, the thickness distribution and flatness of the epitaxial growth layer on the substrate are made uniform.
- the epitaxial wafer is then subjected to a chip segment process to produce a special chip for Micro-LED.
- the pattern structure layer groove distribution shape on the surface of the substrate is a concentric ring centered on the center of the MOCVD cavity, and the radii of the concentric rings are arranged at unequal intervals, but the accommodating grooves of each substrate are from the normal direction of the cavity center Beyond 103, the density gradually increases.
- the material thickness and flatness of the epitaxial layer 200 are uniform, so that the manufactured Micro LED chip has a concentrated wavelength range and uniform brightness and color coordinates. It is conducive to the subsequent huge transfer of Micro-LEDs, and improves product efficiency and yield.
- the epitaxial layer includes: an undoped GaN layer, an N-type doped layer, a current spreading layer, an MQW active region, a P-type AlGaN layer, and a P-type layer.
- a current flows, the electrons in the N-type region and the holes in the P-type region enter the MQW active region and recombine, emitting visible light in the desired wavelength range.
- the epitaxial layer includes: a buffer layer, an undoped GaN layer, an N-type doped layer, a current spreading layer, an MQW active region, a P-type AlGaN layer, and a P-type layer.
- the specific structure of the epitaxial layer can form different differential structures according to the different patterned materials on the substrate.
- the present invention also provides a method for manufacturing the epitaxial wafer as described above, which includes the steps:
- a receiving groove is processed on the patterned substrate or the buffer layer on the upper surface of the patterned substrate, as described in the foregoing patterned substrate and epitaxial wafer embodiments.
- the present invention also provides an LED chip, the LED chip includes the above-mentioned patterned substrate, and the manufacturing method is as follows:
- a receiving groove is processed on the patterned substrate or the buffer layer on the upper surface of the patterned substrate, as described in the foregoing patterned substrate and epitaxial wafer embodiments.
- the present invention also provides a storage medium on which a computer program is stored, wherein when the computer program is executed by a processor, the steps of the above-mentioned epitaxial wafer manufacturing method are realized.
- Non-volatile memory may include read only memory (ROM), programmable ROM (PROM), electrically programmable ROM (EPROM), electrically erasable programmable ROM (EEPROM), or flash memory.
- Volatile memory may include random access memory (RAM) or external cache memory.
- RAM is available in many forms, such as static RAM (SRAM), dynamic RAM (DRAM), synchronous DRAM (SDRAM), double data rate SDRAM (DDRSDRAM), enhanced SDRAM (ESDRAM), synchronous chain Road (SyNchliNk) DRAM (SLDRAM), memory bus (Rambus) direct RAM (RDRAM), direct memory bus dynamic RAM (DRDRAM), and memory bus dynamic RAM (RDRAM), etc.
Abstract
Description
Claims (10)
- 一种图形化衬底,应用于Micro LED,其特征在于,所述图形化衬底包括:衬底本体,所述衬底本体上设置有至少一个容置槽,所述容置槽可容置至少一部分外延过程中掉落的外延材料。
- 根据权利要求1所述的图形化衬底,其特征在于,所述容置槽包括:呈扇环形的第一槽体,当所述图形化衬底放置于MOCVD的载体的指定位置时,所述第一槽体的轴心线与所述载体的轴心线相同。
- 根据权利要求1所述的图形化衬底,其特征在于,所述容置槽设置有多个,多个容置槽沿所述衬底本体的中心线依次排布,且排布密度由一端向另一端依次递减。
- 根据权利要求1所述的图形化衬底,其特征在于,所述衬底本体上设置有多个支撑柱体,每两个相邻的支撑柱体之间形成有一个容置槽。
- 根据权利要求1至4中任意一项所述的图形化衬底,其特征在于,所述衬底本体的上表面设置有缓冲层,所述容置槽形成于所述缓冲层。
- 根据权利要求1至4中任意一项所述的图形化衬底,其特征在于,所述容置槽通过光刻制程完成。
- 一种包括如权利要求1至5中任意一项所述图形化衬底的外延板,其特征在于,所述外延板还包括:外延层,所述容置槽形成于所述外延层与图形化衬底之间。
- 一种如权利要求7所述外延片的制作方法,其特征在于,所述制作方法包括步骤:根据预设的图形化制程,在衬底本体或衬底本体上表面的缓冲层上加工出容置槽,形成图形化衬底;将所述图形化衬底装载至MOVCD炉内的载体上,并加工生成外延层。
- 一种存储介质,所述存储介质上存储有计算机程序,其特征在于,所述计算机程序被处理器执行时实现如权利要求8所述的制作方法的步骤。
- 一种LED芯片,其特征在于,所述LED芯片包括如权利要求1至6中任意一项所述的图形化衬底。
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- 2019-06-27 US US17/613,762 patent/US20220231187A1/en active Pending
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