WO2020001140A1 - Plant culture mat and preparation method thereof - Google Patents

Plant culture mat and preparation method thereof Download PDF

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Publication number
WO2020001140A1
WO2020001140A1 PCT/CN2019/083385 CN2019083385W WO2020001140A1 WO 2020001140 A1 WO2020001140 A1 WO 2020001140A1 CN 2019083385 W CN2019083385 W CN 2019083385W WO 2020001140 A1 WO2020001140 A1 WO 2020001140A1
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Prior art keywords
plant
urea
formaldehyde
fiber
temperature
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PCT/CN2019/083385
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French (fr)
Chinese (zh)
Inventor
宁晓晖
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重庆盛方新材料科技有限公司
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Publication of WO2020001140A1 publication Critical patent/WO2020001140A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G13/00Protecting plants
    • A01G13/02Protective coverings for plants; Coverings for the ground; Devices for laying-out or removing coverings
    • A01G13/0256Ground coverings
    • A01G13/0268Mats or sheets, e.g. nets or fabrics
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05CNITROGENOUS FERTILISERS
    • C05C9/00Fertilisers containing urea or urea compounds
    • C05C9/02Fertilisers containing urea or urea compounds containing urea-formaldehyde condensates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G12/00Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08G12/02Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
    • C08G12/04Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
    • C08G12/10Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds with acyclic compounds having the moiety X=C(—N<)2 in which X is O, S or —N
    • C08G12/12Ureas; Thioureas
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00Compositions of lignin-containing materials
    • C08L97/02Lignocellulosic material, e.g. wood, straw or bagasse

Definitions

  • the present disclosure relates to the technical field of grass control and drought prevention, in particular to a planting mat and a preparation method thereof.
  • the present disclosure provides a novel plant cultivation mat and a preparation method thereof.
  • the present disclosure provides a planting mat composed of plant fibers and urea-formaldehyde glue; the plant fibers are bonded by the urea-formaldehyde glue to form a plant fiber layer; the average diameter of the plant fibers is 0.05 cm to 0.2 cm; and the plant fibers The thickness of the layer is 0.5 cm to 3 cm.
  • the weight ratio of the plant fiber is 50% to 80%, and the weight ratio of the urea-formaldehyde gum is 20% -50%.
  • the porosity of the planting mat is 10% to 50%.
  • the urea-formaldehyde gum is replaced with soybean gum or gelatin, pectin, white latex.
  • the plant fiber layer has a mesh shape.
  • the plant fiber is one or a mixture of coconut shell fiber, palm fiber, hemp fiber, bamboo fiber, straw fiber, and cotton stalk fiber.
  • the saturated water absorption of the plant cultivation mat is 50% -150%.
  • the present disclosure provides a method for preparing the above-mentioned planting mat, including the following steps:
  • step (6) Within 10-20 minutes after acid adjustment, use normal temperature water to check whether the gum solution obtained in step (6) has reached the end of the reaction.
  • the gum solution that has reached the end of the reaction drops into the white water and starts to form a white mist; if the reaction has been reached At the end point, immediately lower the temperature to about 75 ° C, adjust the pH value to 7.8 with caustic soda, and make the gel at a constant temperature;
  • the gel is cooled to 35-40 ° C, and a formaldehyde adsorbent is added to prepare the urea-formaldehyde gel, put it in a plastic bucket, seal the bucket lid, and store it in a cool room;
  • step (10) using the urea formaldehyde gum obtained in step (8) to spray glue the plant fibers treated in step (9) to form a plant fiber layer;
  • meshing the plant fibers in step (11) includes:
  • the preliminary locking degree in step (112) is lower than the locking degree in step (11).
  • the plant mat in this embodiment is composed of plant fibers and urea-formaldehyde glue; the plant fibers are bonded by the urea-formaldehyde glue to form a plant fiber layer; the average diameter of the plant fibers is 0.05 cm to 0.2 cm; and the thickness of the plant fiber layer is 0.5 cm Up to 3cm.
  • the weight ratio of the plant fiber is 50% to 80%, and the weight ratio of the urea-formaldehyde gum is 20% -50%.
  • the porosity of the cultivation mat is 10% to 50%.
  • the urea-formaldehyde gum is replaced with soybean gum or gelatin, pectin, and white latex.
  • Urea-formaldehyde gum has biodegradable properties. After a period of time, the degraded urea-formaldehyde gum can play the role of fertile soil without causing pollution to the environment. On the other hand, the urea-formaldehyde glue binds loose plant fibers and prolongs it. The life of the planting mat.
  • the plant fiber layer has a mesh shape.
  • the plant fiber is one or a mixture of coconut shell fiber, palm fiber, hemp fiber, bamboo fiber, straw fiber, and cotton stalk fiber.
  • the saturated water absorption of the plant cultivation mat is 50% -150%.
  • the plant fiber layer of the plant mat of the present disclosure has a porous structure.
  • the plant fiber layer with a porous structure guarantees a certain degree of porosity and air permeability of the plant cultivation pad, and is fixed in shape.
  • the implementation is simple and convenient.
  • the high porosity of the plant fiber layer and the water-swelling characteristics of the adhesive make the product light.
  • the characteristics of high quality, high porosity and saturated water absorption, and the characteristics of high lignin in plant fiber components ensure that the planting mats of the present disclosure have a long service life.
  • the planting mats of the present disclosure can reduce the temperature difference of the root soil of the plant. Reduce soil moisture evaporation, and is widely used for water conservation and weed control in cash crop plantations in dry and cold regions. After reaching the end of its useful life, the plant fiber and the degradable urea-formaldehyde gum in it decompose into fertilizers, which further nourish the plant root soil.
  • step (6) Within 10-20 minutes after acid adjustment, use normal temperature water to check whether the gum solution obtained in step (6) has reached the end of the reaction.
  • the gum solution that has reached the end of the reaction drops into the white water and starts to form a white mist; if the reaction has been reached At the end point, immediately lower the temperature to about 75 ° C, adjust the pH value to 7.8 with caustic soda, and make the gel at a constant temperature;
  • the gel is cooled to 35-40 ° C, and a formaldehyde adsorbent is added to prepare the urea-formaldehyde gel, put it in a plastic bucket, seal the bucket lid, and store it in a cool room;
  • step (10) using the urea formaldehyde gum obtained in step (8) to spray glue the plant fibers treated in step (9) to form a plant fiber layer;
  • step of meshing the plant fibers in step (11) includes:
  • the preliminary locking degree in step (112) is lower than the locking degree in step (11).
  • the planting mat is a palm silk planting mat
  • the thickness of the planting mat that is, the thickness of the palm silk fiber layer
  • the planting mat can effectively increase the moisture content of the soil around the roots of the apple tree.
  • the soil temperature is reduced by 3.4% in summer and 56.3% in winter. It has a good protective effect on the surface soil of the orchard, and improves the The tolerance of heat, drought and waterlogging makes the tree body safe and healthy through the four seasons.
  • the planting mat is a straw fiber planting mat with a thickness of 1 cm.
  • a planting mat is applied in a lemon orchard, and by covering the planting mat within a range of 30-80 cm around the canopy of the lemon fruit tree, the long grass around the canopy is inhibited and normal fertility is effectively retained.
  • the effect of reducing soil compaction and activating soil microbial indicators is obvious.
  • the nitrogen, phosphorus, potassium, and organic matter contents in the soil of the lemon trees with planting mats were significantly enhanced, which effectively improved the soil quality.
  • the planting mat is a jute fiber planting mat with a thickness of 1.5CM.
  • the winter root heat preservation effect of the vine is significantly improved. Vine vines are mainly damaged by winter roots. When the ground temperature of the grape root system drops to -6 ° C, the roots of the grapes will have different degrees of freezing damage; when the ground temperature drops to -8 ° C, all of them will freeze to death. In order to achieve a better cold protection effect, when the second cold-proof soil is buried, covering the planting mat before burying the soil can obviously increase the temperature at the root of the grape.
  • the width (bottom width) of the cold-proof soil is not less than 1.8 meters, the front side is trapezoidal, and the upper width is 1-2 meters. It can be compacted after burying.
  • the planting mat may further include a retaining layer, the retaining layer is provided at least on the plant fiber layer, and a retaining layer may be provided on the uppermost layer of the planting mat and on the lowermost layer. Set up a retaining layer.
  • the retaining layer is used to fasten the plant fiber layer.
  • the holding layer may be formed of plastic, organic resin, polypropylene, glass fiber, or the like, and has a grid-like shape.
  • the holding layer is fixed to the plant fiber layer by means of bonding, articulation or binding, so that the integrity of the planting mat is enhanced.
  • the planting mat may further include a weed control agent.
  • the weed control agent can be made into small spheres, a plurality of sphere-shaped weed control agents can be interspersed between plant fibers, and these weeds are bonded by a bonding material such as urea formaldehyde The control agent adheres to the plant fibers.
  • step 3 when preparing the planting mat, in step 3 described above, the plant fibers are subjected to a meshing process (the opened and carded plant fibers are laid into a net shape), and the weed control agent is also included. Scattered in plant fibers.
  • the plant fiber can be made into a plant fiber layer in the manner described above, and the plurality of plant fiber layers can be adhered by stacking a plurality of plant fiber layers, using an adhesive such as a urea-formaldehyde glue, and the like. (Also can be locked in other ways) to form a planting mat, and a control agent layer made of a weed control agent is placed between some adjacent plant fiber layers. The control agent layer is preferably placed on the lowest fiber layer.
  • a weed control agent layer after making a single-layer plant cultivation mat by the above method, it further includes the steps of stacking at least two layers of plant cultivation mats, and setting weed control on the bottom plant cultivation mats.
  • Agent layer, and spraying treatment is performed on the contact surface of each layer by using an adhesive such as urea-formaldehyde glue; and then drying.
  • the weed control agent contains 35% of the herbicide raw material, 30% of the slow-release material, 25% of the diluent, 5% of the binder, and 5% Pesticide auxiliaries.
  • the herbicide raw material is a systemic-conduction herbicide raw material medicine, which can be absorbed by the roots, leaves, coleoptiles or stems of weeds, and can be transmitted to plants to cause weeds to die; including but not limited to The following herbicide APIs: Prometryn (RM), Metsulfuron (MF), Chlorsulfuron (CF), Paraquat, Ganoderma, Alachlor, Diuron, 2,4-D, Cima
  • the herbicide raw materials may also include auxiliary ingredients.
  • the auxiliary ingredients may be selected from broad-spectrum inorganic compound herbicides such as borax, potassium chlorate, or copper sulfate; and herbicide raw materials in which a single component or multiple components are mixed.
  • a drug substance with a long-acting half-life is preferred.
  • the sustained release material is ethyl cellulose, ethyl methyl cellulose, hypromellose or carboxymethyl cellulose.
  • the diluent is microcrystalline cellulose.
  • the binder was ethyl cellulose ethanol.
  • Preparation method of weed control agent for example: after mixing prometryn and borax in a certain ratio, add ethyl cellulose, microcrystalline cellulose, and crush it through an 80 mesh sieve; add the mixed material to a certain amount of 5% ethyl Cellulose (EC) ethanol solution is used as a binder to make a soft material. Wet particles are passed through a 16-mesh sieve. 3. Soft material extrusion: Put the wet particles into the extruder and press the extrusion aperture to 1.5mm; the extrusion frequency is 20 , Blast frequency of 50, extruded into strips; 4.
  • EC ethyl Cellulose
  • the extrudate is added to the spheronization machine and spheronized at a speed of 800 rpm, taken out after 10 minutes to obtain pellets; 5. drying: prepared pellets Put it at 40 ° C and dry for 8 hours.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Pest Control & Pesticides (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Soil Sciences (AREA)
  • Wood Science & Technology (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
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Abstract

A plant culture mat and a preparation method thereof. The plant culture mat consists of plant fibers and urea-formaldehyde glue. The plant fibers are bound by the urea-formaldehyde glue to form a plant fiber layer. The plant fibers have an average diameter of 0.05 to 0.2 cm. The plant fiber layer has a thickness of 0.5 to 3 cm. The plant culture mat is degradable and has good water retention and weed control.

Description

植培垫及其制备方法Plant cultivation mat and preparation method thereof 技术领域Technical field
本公开涉及控草防旱技术领域,尤其涉及一种植培垫及其制备方法。The present disclosure relates to the technical field of grass control and drought prevention, in particular to a planting mat and a preparation method thereof.
背景技术Background technique
我国是农业大国,传统的控草防旱的方法一般采用以下几种:China is a large agricultural country. The traditional methods of controlling grass and preventing drought generally adopt the following methods:
1、人工锄抚。即采用人工法于果树周边锄松0-15厘米厚土壤;其优点是可操作性强,清理仔细;缺点:费工费时,需多次作业,易引发水土流失,防旱、保墒与控草效果差。1. Artificial stroking. That is, the artificial method is used to pinch pines with a thickness of 0-15 cm around the fruit trees. Its advantages are strong operability and careful cleaning. Disadvantages: labor-intensive and time-consuming, multiple operations are required, which can easily cause soil erosion, drought prevention, soil conservation and grass control poor effect.
2、人工打药。即采用人工打药控草。其优点是除草效果明显;缺点:农药操作不当时,易误伤果树幼苗或造成环境污染与土壤残留。2, artificial medicine. That is to control the grass artificially. Its advantages are obvious herbicidal effects; disadvantages: improper pesticide operation can easily damage fruit tree seedlings or cause environmental pollution and soil residues.
3、人工锄抚与稻草或地膜覆盖。与人工锄抚相似,不过在锄抚后再覆盖一层5-10厘米的稻草;一方面覆盖可以改善土壤结构,保水保墒;另一方面阻挡了太阳光直接照射地面,起到降温的作用,减少土壤水分的蒸发,达到保墒的目的,能为水果、经济作物的生长、土壤微生物创造更适宜的土壤环境。实践表明地膜、秸秆等材料覆盖能有效控制果园杂草与保墒防旱,地膜覆盖具有保水性强、质轻耐久等特性,能起到显著增温保水与控草作用。优点是增加树根部覆盖,且可降温与增加土壤有机质;缺点:稻草极易腐烂,效果短,且腐烂后易兹生害虫,为其提供产卵环境。而地膜由于无法降解,必将对环境存在较大影响。3. Artificial stinging and straw or plastic film covering. It is similar to artificial strokes, but it is covered with a layer of 5-10 cm of straw after the strokes. On the one hand, it can improve the soil structure and retain water and water. It can reduce the evaporation of soil moisture and achieve the purpose of preserving soil moisture. It can create a more suitable soil environment for the growth of fruits, cash crops, and soil microorganisms. Practice has shown that mulching film, straw and other materials can effectively control weeds in the orchard and protect the mulch and prevent drought. The mulching film has the characteristics of strong water retention, light weight and durability, and can play a significant role in increasing temperature and water and controlling grass. It has the advantages of increasing the root cover of the tree, and can reduce the temperature and increase the organic matter in the soil. Disadvantages: Straw is extremely susceptible to rot, and its effect is short. Since the mulch film cannot be degraded, it will have a great impact on the environment.
发明内容Summary of the invention
为了解决至少一个背景技术中提到的技术问题,本公开提供一种新型的植培垫及其制备方法。In order to solve at least one of the technical problems mentioned in the background, the present disclosure provides a novel plant cultivation mat and a preparation method thereof.
一方面,本公开提供一种植培垫,植培垫由植物纤维和脲醛胶构成;植物纤维通过脲醛胶粘合,形成植物纤维层;植物纤维的平均直径为0.05cm至0.2cm;以及植物纤维层的厚度为0.5cm至3cm。In one aspect, the present disclosure provides a planting mat composed of plant fibers and urea-formaldehyde glue; the plant fibers are bonded by the urea-formaldehyde glue to form a plant fiber layer; the average diameter of the plant fibers is 0.05 cm to 0.2 cm; and the plant fibers The thickness of the layer is 0.5 cm to 3 cm.
根据本公开的至少一个实施方式,植物纤维的重量比例为50%至80%,脲醛胶的重量比例为20%-50%。According to at least one embodiment of the present disclosure, the weight ratio of the plant fiber is 50% to 80%, and the weight ratio of the urea-formaldehyde gum is 20% -50%.
根据本公开的至少一个实施方式,植培垫的孔隙率为10%至50%。According to at least one embodiment of the present disclosure, the porosity of the planting mat is 10% to 50%.
根据本公开的至少一个实施方式,脲醛胶替换为大豆胶或明胶、果胶、白乳胶。According to at least one embodiment of the present disclosure, the urea-formaldehyde gum is replaced with soybean gum or gelatin, pectin, white latex.
根据本公开的至少一个实施方式,植物纤维层呈网格状。According to at least one embodiment of the present disclosure, the plant fiber layer has a mesh shape.
根据本公开的至少一个实施方式,植物纤维是椰壳纤维、棕榈纤维、麻纤维、竹纤维、秸秆纤维、棉秆纤维中的一种,或多种混合而成。According to at least one embodiment of the present disclosure, the plant fiber is one or a mixture of coconut shell fiber, palm fiber, hemp fiber, bamboo fiber, straw fiber, and cotton stalk fiber.
根据本公开的至少一个实施方式,植培垫的饱和吸水率为50%-150%。According to at least one embodiment of the present disclosure, the saturated water absorption of the plant cultivation mat is 50% -150%.
另一方面,本公开提供上述植培垫的制备方法,包括以下步骤:In another aspect, the present disclosure provides a method for preparing the above-mentioned planting mat, including the following steps:
根据本公开的至少一个实施方式,According to at least one embodiment of the present disclosure,
(1)把计量的甲醛放入反应釜中;(1) Put the metered formaldehyde into the reaction kettle;
(2)在不断搅拌下,把烧碱液加入甲醛内,调整pH值至7.8,并开始慢慢升温到25-30℃;(2) Under constant stirring, add caustic soda to formaldehyde, adjust the pH value to 7.8, and begin to slowly raise the temperature to 25-30 ° C;
(3)在不断搅拌下,把尿素总用量的50%加进反应釜,并在30分钟内升温至60℃,优选的,每10分钟约升温10℃;(3) Under constant stirring, add 50% of the total amount of urea to the reaction kettle, and raise the temperature to 60 ° C within 30 minutes, preferably, approximately 10 ° C every 10 minutes;
(4)当反应釜内温度达到60℃,第二次加入尿素总用量的25%,不断搅拌,并控制如前升温速度,控制在30分钟内使温度升至90℃;(4) When the temperature in the reactor reaches 60 ° C, add 25% of the total amount of urea for the second time, keep stirring, and control the heating rate as before, and control the temperature to rise to 90 ° C within 30 minutes;
(5)最后加入尿素剩余部分,在90℃保温30分钟;(5) Finally, the remaining portion of urea is added and kept at 90 ° C for 30 minutes;
(6)恒温后即用液体烧碱(浓度36%)调整pH值至4.5;(6) Adjust the pH to 4.5 with liquid caustic soda (concentration 36%) immediately after constant temperature;
(7)调酸后的10-20分钟内,用常温清水检验步骤(6)得到的胶液是否达到反应终点,达到反应终点的胶液滴入清水内即起白色雾状;如已达到反应终点,立即降温至75℃左右,再用烧碱调整pH值为7.8,并恒温成胶;(7) Within 10-20 minutes after acid adjustment, use normal temperature water to check whether the gum solution obtained in step (6) has reached the end of the reaction. The gum solution that has reached the end of the reaction drops into the white water and starts to form a white mist; if the reaction has been reached At the end point, immediately lower the temperature to about 75 ° C, adjust the pH value to 7.8 with caustic soda, and make the gel at a constant temperature;
(8)成胶后立即把胶冷却至35-40℃,并加入甲醛吸附剂,制得脲醛胶,放进胶桶,密封桶盖,放置阴凉室内保存;(8) Immediately after the gel is formed, the gel is cooled to 35-40 ° C, and a formaldehyde adsorbent is added to prepare the urea-formaldehyde gel, put it in a plastic bucket, seal the bucket lid, and store it in a cool room;
(9)对植物纤维进行网格化处理;(9) Grid processing of plant fibers;
(10)使用步骤(8)得到的脲醛胶对步骤(9)网格化处理后的植物纤维进行喷胶处理形成植物纤维层;以及(10) using the urea formaldehyde gum obtained in step (8) to spray glue the plant fibers treated in step (9) to form a plant fiber layer; and
(11)对植物纤维层进行锁紧,烘干。(11) Lock and dry the plant fiber layer.
根据本公开的至少一个实施方式,步骤(11)的对植物纤维进行网格化处理包括:According to at least one embodiment of the present disclosure, meshing the plant fibers in step (11) includes:
(111)对植物纤维进行开松和梳理;(111) opening and carding the plant fibers;
(112)将开松和梳理后的植物纤维铺成网状,再进行初步锁紧。(112) The opened and carded plant fibers are laid into a net shape, and then preliminary locking is performed.
根据本公开的至少一个实施方式,步骤(112)中的初步锁紧程度低于步骤(11)中的锁紧程度。According to at least one embodiment of the present disclosure, the preliminary locking degree in step (112) is lower than the locking degree in step (11).
具体实施方式detailed description
下面对本公开作进一步的详细说明。可以理解的是,此处所描述的具体实施方式仅用于解释相关内容,而非对本公开的限定。The disclosure is described in further detail below. It can be understood that the specific embodiments described herein are only used to explain related content, rather than limiting the present disclosure.
需要说明的是,在不冲突的情况下,本公开中的实施方式及实施方式中的特征可以相互组合。It should be noted that, in the case of no conflict, the embodiments in the present disclosure and the features in the embodiments can be combined with each other.
本实施方式中的植培垫由植物纤维和脲醛胶构成;植物纤维通过脲醛胶粘合,形成植物纤维层;植物纤维的平均直径为0.05cm至0.2cm;以及植物纤维层的厚度为0.5cm至3cm。The plant mat in this embodiment is composed of plant fibers and urea-formaldehyde glue; the plant fibers are bonded by the urea-formaldehyde glue to form a plant fiber layer; the average diameter of the plant fibers is 0.05 cm to 0.2 cm; and the thickness of the plant fiber layer is 0.5 cm Up to 3cm.
本公开的至少一个实施方式中,植物纤维的重量比例为50%至80%,脲醛胶的重量比例为20%-50%。In at least one embodiment of the present disclosure, the weight ratio of the plant fiber is 50% to 80%, and the weight ratio of the urea-formaldehyde gum is 20% -50%.
本公开的至少一个实施方式中,植培垫的孔隙率为10%至50%。In at least one embodiment of the present disclosure, the porosity of the cultivation mat is 10% to 50%.
本公开的至少一个实施方式中,脲醛胶替换为大豆胶或明胶、果胶、白乳胶。In at least one embodiment of the present disclosure, the urea-formaldehyde gum is replaced with soybean gum or gelatin, pectin, and white latex.
脲醛胶一方面具有生物可降解的特性,一段时间后,降解后的脲醛胶可以起到肥沃土壤的作用,不对环境造成污染;另一方面,脲醛胶将松散的植物纤维粘合在一起,延长了植培垫的使用寿命。Urea-formaldehyde gum has biodegradable properties. After a period of time, the degraded urea-formaldehyde gum can play the role of fertile soil without causing pollution to the environment. On the other hand, the urea-formaldehyde glue binds loose plant fibers and prolongs it. The life of the planting mat.
本公开的至少一个实施方式中,植物纤维层呈网格状。In at least one embodiment of the present disclosure, the plant fiber layer has a mesh shape.
本公开的至少一个实施方式中,植物纤维是椰壳纤维、棕榈纤维、麻纤维、竹纤维、秸秆纤维、棉秆纤维中的一种,或多种混合而成。In at least one embodiment of the present disclosure, the plant fiber is one or a mixture of coconut shell fiber, palm fiber, hemp fiber, bamboo fiber, straw fiber, and cotton stalk fiber.
本公开的至少一个实施方式中,植培垫的饱和吸水率为50%-150%。In at least one embodiment of the present disclosure, the saturated water absorption of the plant cultivation mat is 50% -150%.
本公开的植培垫的植物纤维层具有多孔结构。具有多孔结构的植物纤维层保证了植培垫既有一定的孔隙率和透气性,又固定成型,实 施简单方便,植物纤维层的高孔隙率以及粘合剂的遇水膨胀特性使得产品具有轻质、高孔隙率和饱和吸水率的特性,植物纤维成分中高木质素的特点保证了本公开的植培垫具有较长的使用寿命,本公开的植培垫可降低植物根系土壤的温差,减少土壤水分蒸发,广泛适用于缺水地区以及寒冷地区的经济作物种植园的保水抑草。达到使用年限后,植物纤维以及其中的可降解脲醛胶腐烂成肥料,进一步养化植物根系土壤。The plant fiber layer of the plant mat of the present disclosure has a porous structure. The plant fiber layer with a porous structure guarantees a certain degree of porosity and air permeability of the plant cultivation pad, and is fixed in shape. The implementation is simple and convenient. The high porosity of the plant fiber layer and the water-swelling characteristics of the adhesive make the product light. The characteristics of high quality, high porosity and saturated water absorption, and the characteristics of high lignin in plant fiber components ensure that the planting mats of the present disclosure have a long service life. The planting mats of the present disclosure can reduce the temperature difference of the root soil of the plant. Reduce soil moisture evaporation, and is widely used for water conservation and weed control in cash crop plantations in dry and cold regions. After reaching the end of its useful life, the plant fiber and the degradable urea-formaldehyde gum in it decompose into fertilizers, which further nourish the plant root soil.
本实施方式的植培垫的制备方法,包括以下步骤:The method for preparing a planting mat according to this embodiment includes the following steps:
(1)把计量的甲醛放入反应釜中;(1) Put the metered formaldehyde into the reaction kettle;
(2)在不断搅拌下,把烧碱液加入甲醛内,调整pH值至7.8,并开始慢慢升温到25-30℃;(2) Under constant stirring, add caustic soda to formaldehyde, adjust the pH value to 7.8, and begin to slowly raise the temperature to 25-30 ° C;
(3)在不断搅拌下,把尿素总用量的50%加进反应釜,并在30分钟内升温至60℃,优选的,每10分钟约升温10℃;(3) Under constant stirring, add 50% of the total amount of urea to the reaction kettle, and raise the temperature to 60 ° C within 30 minutes, preferably, approximately 10 ° C every 10 minutes;
(4)当反应釜内温度达到60℃,第二次加入尿素总用量的25%,不断搅拌,并控制如前升温速度,控制在30分钟内使温度升至90℃;(4) When the temperature in the reactor reaches 60 ° C, add 25% of the total amount of urea for the second time, keep stirring, and control the heating rate as before, and control the temperature to rise to 90 ° C within 30 minutes;
(5)最后加入尿素剩余部分,在90℃保温30分钟;(5) Finally, the remaining portion of urea is added and kept at 90 ° C for 30 minutes;
(6)恒温后即用液体烧碱(浓度36%)调整pH值至4.5;(6) Adjust the pH to 4.5 with liquid caustic soda (concentration 36%) immediately after constant temperature;
(7)调酸后的10-20分钟内,用常温清水检验步骤(6)得到的胶液是否达到反应终点,达到反应终点的胶液滴入清水内即起白色雾状;如已达到反应终点,立即降温至75℃左右,再用烧碱调整pH值为7.8,并恒温成胶;(7) Within 10-20 minutes after acid adjustment, use normal temperature water to check whether the gum solution obtained in step (6) has reached the end of the reaction. The gum solution that has reached the end of the reaction drops into the white water and starts to form a white mist; if the reaction has been reached At the end point, immediately lower the temperature to about 75 ° C, adjust the pH value to 7.8 with caustic soda, and make the gel at a constant temperature;
(8)成胶后立即把胶冷却至35-40℃,并加入甲醛吸附剂,制得脲醛胶,放进胶桶,密封桶盖,放置阴凉室内保存;(8) Immediately after the gel is formed, the gel is cooled to 35-40 ° C, and a formaldehyde adsorbent is added to prepare the urea-formaldehyde gel, put it in a plastic bucket, seal the bucket lid, and store it in a cool room;
(9)对植物纤维进行网格化处理;(9) Grid processing of plant fibers;
(10)使用步骤(8)得到的脲醛胶对步骤(9)网格化处理后的植物纤维进行喷胶处理形成植物纤维层;以及(10) using the urea formaldehyde gum obtained in step (8) to spray glue the plant fibers treated in step (9) to form a plant fiber layer; and
(11)对植物纤维层进行锁紧,烘干。(11) Lock and dry the plant fiber layer.
本公开的至少一个实施方式中,步骤(11)的对植物纤维进行网格化处理包括:In at least one embodiment of the present disclosure, the step of meshing the plant fibers in step (11) includes:
(111)对植物纤维进行开松和梳理;(111) opening and carding the plant fibers;
(112)将开松和梳理后的植物纤维铺成网状,再进行初步锁紧。(112) The opened and carded plant fibers are laid into a net shape, and then preliminary locking is performed.
本公开的至少一个实施方式中,步骤(112)中的初步锁紧程度低于步骤(11)中的锁紧程度。In at least one embodiment of the present disclosure, the preliminary locking degree in step (112) is lower than the locking degree in step (11).
下面结合实例来说明本公开的植培垫的效果。The effect of the planting mat of the present disclosure will be described below with examples.
实施例1苹果园养护Example 1 Apple Orchard Maintenance
本实施例中,植培垫为棕榈丝植培垫,植培垫厚度(即棕榈丝纤维层厚度)为1.5cm。In this embodiment, the planting mat is a palm silk planting mat, and the thickness of the planting mat (that is, the thickness of the palm silk fiber layer) is 1.5 cm.
将植培垫铺在苹果树根周围,面积4平方,1亩苹果园共50颗苹果树,共铺植培垫200平方;Place planting mats around the roots of apple trees, covering an area of 4 square meters. There are 50 apple trees in 1 acre apple orchard, and a total of 200 square meters of planting mats.
本实施例中,植培垫可有效提高苹果树根部周边土壤含水量,夏天降低土壤温度3.4%,冬天提高土壤温度56.3%,对果园表层土壤起到了很好的保护作用,提高果树对冷、热、旱、涝的忍耐力,使树体安全健康度过四季。In this embodiment, the planting mat can effectively increase the moisture content of the soil around the roots of the apple tree. The soil temperature is reduced by 3.4% in summer and 56.3% in winter. It has a good protective effect on the surface soil of the orchard, and improves the The tolerance of heat, drought and waterlogging makes the tree body safe and healthy through the four seasons.
实施例2柠檬果园养护Example 2 Maintenance of Lemon Orchard
本实施例中,植培垫为秸秆纤维植培垫,厚度为1CM。In this embodiment, the planting mat is a straw fiber planting mat with a thickness of 1 cm.
本实例中,应用植培垫在柠檬果园中,通过在柠檬果树树冠周边30-80cm范围内覆盖植培垫,形成了抑制树冠周边长草,有效保留了正常肥力。同时降低土地板结、活化土壤微生物指标也效果明显。通过对比试验,铺设了植培垫的柠檬树的土壤中的氮、磷、钾、有机质含量得到明显增强,有效改良了土壤质量。In this example, a planting mat is applied in a lemon orchard, and by covering the planting mat within a range of 30-80 cm around the canopy of the lemon fruit tree, the long grass around the canopy is inhibited and normal fertility is effectively retained. At the same time, the effect of reducing soil compaction and activating soil microbial indicators is obvious. Through comparative tests, the nitrogen, phosphorus, potassium, and organic matter contents in the soil of the lemon trees with planting mats were significantly enhanced, which effectively improved the soil quality.
实施例3葡萄园养护Example 3 Vineyard Conservation
本实施例中,植培垫为黄麻纤维植培垫,厚度为1.5CM。In this embodiment, the planting mat is a jute fiber planting mat with a thickness of 1.5CM.
本实施例中,显著改善了葡萄树冬季根部保温作用。葡萄树冬季受冻害主要是其根部。当葡萄根系处的地温降到-6℃时,其根系就会发生不同程度的冻害;地温降到-8℃时,就会全部冻死。为达到更好的防寒效果,在埋第二次防寒土时,先覆盖植培垫再埋土,可明显提高葡萄根处的温度。防寒土的宽度(底宽)不小于1.8米,正面呈梯形,上宽为1-2米,埋后压紧即可。In this embodiment, the winter root heat preservation effect of the vine is significantly improved. Vine vines are mainly damaged by winter roots. When the ground temperature of the grape root system drops to -6 ° C, the roots of the grapes will have different degrees of freezing damage; when the ground temperature drops to -8 ° C, all of them will freeze to death. In order to achieve a better cold protection effect, when the second cold-proof soil is buried, covering the planting mat before burying the soil can obviously increase the temperature at the root of the grape. The width (bottom width) of the cold-proof soil is not less than 1.8 meters, the front side is trapezoidal, and the upper width is 1-2 meters. It can be compacted after burying.
在本公开的一个可选实施方式中,植培垫还可以包括保持层,该保持层至少设置在植物纤维层之上,也可以在植培垫的最上层设置一层保持层并且在最下层设置一层保持层。保持层用于紧固植物纤维层。该保持层可以由塑料、有机树脂、聚丙烯、玻璃纤维等形成,其形状为网格状。并且该保持层通过粘结、铰接或绑扎的方式与植物纤维层相固定, 这样增强了植培垫的整体性。In an optional embodiment of the present disclosure, the planting mat may further include a retaining layer, the retaining layer is provided at least on the plant fiber layer, and a retaining layer may be provided on the uppermost layer of the planting mat and on the lowermost layer. Set up a retaining layer. The retaining layer is used to fasten the plant fiber layer. The holding layer may be formed of plastic, organic resin, polypropylene, glass fiber, or the like, and has a grid-like shape. In addition, the holding layer is fixed to the plant fiber layer by means of bonding, articulation or binding, so that the integrity of the planting mat is enhanced.
在本公开的一个可选实施方式中,植培垫还可以包括杂草控制剂。In an alternative embodiment of the present disclosure, the planting mat may further include a weed control agent.
在一个实施方式中,将该杂草控制剂可以制成小的圆球形,可以使多个圆球形的杂草控制剂散布在植物纤维之间,并且通过脲醛胶等粘合材料将这些杂草控制剂粘附至植物纤维上。In one embodiment, the weed control agent can be made into small spheres, a plurality of sphere-shaped weed control agents can be interspersed between plant fibers, and these weeds are bonded by a bonding material such as urea formaldehyde The control agent adheres to the plant fibers.
这样,在制备该植培垫时,在上述的步骤3中,对植物纤维进行网格化处理(将开松和梳理后的植物纤维铺成网状)的同时,还包括将杂草控制剂散布在植物纤维中。In this way, when preparing the planting mat, in step 3 described above, the plant fibers are subjected to a meshing process (the opened and carded plant fibers are laid into a net shape), and the weed control agent is also included. Scattered in plant fibers.
在本公开的另一实施方式中,可以通过上述的方式将植物纤维制成植物纤维层,并且通过叠置多个植物纤维层、通过脲醛胶等粘合剂等将多个植物纤维层进行粘合,(也可以通过其他方式进行锁紧),来形成植培垫,并且在某相邻的植物纤维层之间放置由杂草控制剂形成的控制剂层。该控制剂层优选地放置于最下层的纤维层上。In another embodiment of the present disclosure, the plant fiber can be made into a plant fiber layer in the manner described above, and the plurality of plant fiber layers can be adhered by stacking a plurality of plant fiber layers, using an adhesive such as a urea-formaldehyde glue, and the like. (Also can be locked in other ways) to form a planting mat, and a control agent layer made of a weed control agent is placed between some adjacent plant fiber layers. The control agent layer is preferably placed on the lowest fiber layer.
在增加杂草控制剂层的实施方式中,通过上述方法制作出单层植培垫之后,还包括步骤,将至少两层植培垫叠置,并且在最底层的植培垫上设置杂草控制剂层,并且在各层的接触面上使用脲醛胶等粘合剂来进行进行喷胶处理;然后烘干。In the embodiment of adding a weed control agent layer, after making a single-layer plant cultivation mat by the above method, it further includes the steps of stacking at least two layers of plant cultivation mats, and setting weed control on the bottom plant cultivation mats. Agent layer, and spraying treatment is performed on the contact surface of each layer by using an adhesive such as urea-formaldehyde glue; and then drying.
在本公开的一个可选实施方式中,按照重量比,杂草控制剂中包含35%的除草剂原料、30%的缓释材料、25%的稀释剂、5%的粘合剂及5%的农药助剂。其中,除草剂原料为内吸传导型的除草剂原料药,这些除草剂可被杂草根系、叶片、芽鞘或茎部吸收,传导至植物体内,使杂草死亡;包括但并不仅局限于以下除草剂原料药:扑草净(RM)、甲磺隆(MF)、氯磺隆(CF)、百草枯、盖草能、甲草胺、敌草隆、2,4-D、西玛津等;除草剂原料还可以包括辅助成分,辅助成分可以选择为硼砂、氯酸钾或硫酸铜等广谱无机化合物除草剂;及它们中单一成分或多成分复配的除草剂原料药。优选药效半衰期长的原料药。缓释材料为乙基纤维素、乙基甲基纤维素、羟丙甲纤维素或羧甲基纤维素。稀释剂为微晶纤维素。粘合剂为乙基纤维素乙醇液。In an alternative embodiment of the present disclosure, according to the weight ratio, the weed control agent contains 35% of the herbicide raw material, 30% of the slow-release material, 25% of the diluent, 5% of the binder, and 5% Pesticide auxiliaries. Among them, the herbicide raw material is a systemic-conduction herbicide raw material medicine, which can be absorbed by the roots, leaves, coleoptiles or stems of weeds, and can be transmitted to plants to cause weeds to die; including but not limited to The following herbicide APIs: Prometryn (RM), Metsulfuron (MF), Chlorsulfuron (CF), Paraquat, Ganoderma, Alachlor, Diuron, 2,4-D, Cima The herbicide raw materials may also include auxiliary ingredients. The auxiliary ingredients may be selected from broad-spectrum inorganic compound herbicides such as borax, potassium chlorate, or copper sulfate; and herbicide raw materials in which a single component or multiple components are mixed. A drug substance with a long-acting half-life is preferred. The sustained release material is ethyl cellulose, ethyl methyl cellulose, hypromellose or carboxymethyl cellulose. The diluent is microcrystalline cellulose. The binder was ethyl cellulose ethanol.
杂草控制剂的制备方式例如:将扑草净和硼砂按一定比例混合后,加入乙基纤维素,微晶纤维素,粉碎过80目筛;将混合的物料加入一定 量的5%乙基纤维素(EC)的乙醇溶液作粘合剂制成软材,过16目筛制得湿颗粒3.软材挤出:将湿颗粒投入挤压机按挤出孔径1.5mm;挤出频率20,鼓风频率50,挤压成条状物;4.滚圆:将挤出物分次加入滚圆机内滚圆,滚圆转速800rpm,10min后取出得微丸;5.烘干:制备出的微丸置于40℃干燥8小时即得。Preparation method of weed control agent: for example: after mixing prometryn and borax in a certain ratio, add ethyl cellulose, microcrystalline cellulose, and crush it through an 80 mesh sieve; add the mixed material to a certain amount of 5% ethyl Cellulose (EC) ethanol solution is used as a binder to make a soft material. Wet particles are passed through a 16-mesh sieve. 3. Soft material extrusion: Put the wet particles into the extruder and press the extrusion aperture to 1.5mm; the extrusion frequency is 20 , Blast frequency of 50, extruded into strips; 4. spheronization: the extrudate is added to the spheronization machine and spheronized at a speed of 800 rpm, taken out after 10 minutes to obtain pellets; 5. drying: prepared pellets Put it at 40 ° C and dry for 8 hours.
本领域的技术人员应当理解,上述实施方式仅仅是为了清楚地说明本公开,而并非是对本公开的范围进行限定。对于所属领域的技术人员而言,在上述公开的基础上还可以做出其它变化或变型,并且这些变化或变型仍处于本公开的范围内。It should be understood by those skilled in the art that the foregoing implementations are merely for the purpose of clearly illustrating the present disclosure, and are not intended to limit the scope of the present disclosure. For those skilled in the art, other changes or modifications may be made on the basis of the above disclosure, and these changes or modifications are still within the scope of the present disclosure.

Claims (10)

  1. 一种植培垫,其特征在于,所述植培垫由植物纤维和脲醛胶构成;所述植物纤维通过所述脲醛胶粘合,形成植物纤维层;A planting mat, characterized in that the planting mat is composed of plant fibers and urea-formaldehyde glue; the plant fibers are bonded by the urea-formaldehyde glue to form a plant fiber layer;
    所述植物纤维的平均直径为0.05cm至0.2cm;以及The plant fibers have an average diameter of 0.05 cm to 0.2 cm; and
    所述植物纤维层的厚度为0.5cm至3cm。The thickness of the plant fiber layer is 0.5 cm to 3 cm.
  2. 根据权利要求1所述的植培垫,其特征在于,所述植物纤维的重量比例为50%至80%,所述脲醛胶的重量比例为20%-50%。The plant mat according to claim 1, wherein a weight ratio of the plant fibers is 50% to 80%, and a weight ratio of the urea-formaldehyde gum is 20% -50%.
  3. 根据权利要求1所述的植培垫,其特征在于,所述植培垫的孔隙率为10%至50%。The plant cultivation mat according to claim 1, wherein the plant cultivation mat has a porosity of 10% to 50%.
  4. 根据权利要求1-3任一项所述的植培垫,其特征在于,所述脲醛胶替换为大豆胶或明胶、果胶、白乳胶。The plant cultivation mat according to any one of claims 1 to 3, wherein the urea-formaldehyde glue is replaced with soybean glue or gelatin, pectin, and white latex.
  5. 根据权利要求1-3任一项所述的植培垫,其特征在于,所述植物纤维层呈网格状。The plant cultivation mat according to any one of claims 1 to 3, wherein the plant fiber layer is in a grid shape.
  6. 根据权利要求1-3任一项所述的植培垫,其特征在于,所述植物纤维是椰壳纤维、棕榈纤维、麻纤维、竹纤维、秸秆纤维、棉秆纤维中的一种,或多种混合而成。The plant cultivation mat according to any one of claims 1 to 3, wherein the plant fiber is one of coconut fiber, palm fiber, hemp fiber, bamboo fiber, straw fiber, and cotton stalk fiber, or A variety of blends.
  7. 根据权利要求1-3任一项所述的植培垫,其特征在于,所述植培垫的饱和吸水率为50%-150%。The plant cultivation mat according to any one of claims 1 to 3, wherein the saturated water absorption of the plant cultivation mat is 50% -150%.
  8. 制备权利要求1-3任一项所述的植培垫的方法,其特征在于,包括以下步骤:The method for preparing a planting mat according to any one of claims 1 to 3, comprising the following steps:
    (1)把计量的甲醛放入反应釜中;(1) Put the metered formaldehyde into the reaction kettle;
    (2)在不断搅拌下,把烧碱液加入甲醛内,调整pH值至7.8,并开始慢慢升温到25-30℃;(2) Under constant stirring, add caustic soda to formaldehyde, adjust the pH value to 7.8, and begin to slowly raise the temperature to 25-30 ° C;
    (3)在不断搅拌下,把尿素总用量的50%加进反应釜,并在30分钟内升温至60℃,优选的,每10分钟约升温10℃;(3) Under constant stirring, add 50% of the total amount of urea to the reaction kettle, and raise the temperature to 60 ° C within 30 minutes, preferably, approximately 10 ° C every 10 minutes;
    (4)当反应釜内温度达到60℃,第二次加入尿素总用量的25%,不断搅拌,并控制如前升温速度,控制在30分钟内使温度升至90℃;(4) When the temperature in the reactor reaches 60 ° C, add 25% of the total amount of urea for the second time, keep stirring, and control the heating rate as before, and control the temperature to rise to 90 ° C within 30 minutes;
    (5)最后加入尿素剩余部分,在90℃保温30分钟;(5) Finally, the remaining portion of urea is added and kept at 90 ° C for 30 minutes;
    (6)恒温后即用液体烧碱(浓度36%)调整pH值至4.5;(6) Adjust the pH to 4.5 with liquid caustic soda (concentration 36%) immediately after constant temperature;
    (7)调酸后的10-20分钟内,用常温清水检验步骤(6)得到的胶液是否达到反应终点,达到反应终点的胶液滴入清水内即起白色雾状;如已达到反应终点,立即降温至75℃左右,再用烧碱调整pH值为7.8,并恒温成胶;(7) Within 10-20 minutes after acid adjustment, use normal temperature water to check whether the gum solution obtained in step (6) has reached the end of the reaction. The gum solution that has reached the end of the reaction drops into the white water and starts to form a white mist. At the end point, immediately lower the temperature to about 75 ° C, adjust the pH value to 7.8 with caustic soda, and make the gel at a constant temperature;
    (8)成胶后立即把胶冷却至35-40℃,并加入甲醛吸附剂,制得所述脲醛胶,放进胶桶,密封桶盖,放置阴凉室内保存;(8) Immediately after the gel is formed, the gel is cooled to 35-40 ° C, and a formaldehyde adsorbent is added to prepare the urea-formaldehyde gel, put into a plastic bucket, seal the bucket lid, and store in a cool room;
    (9)对植物纤维进行网格化处理;(9) Grid processing of plant fibers;
    (10)使用步骤(8)得到的脲醛胶对步骤(9)网格化处理后的植物纤维进行喷胶处理形成植物纤维层;以及(10) using the urea formaldehyde gum obtained in step (8) to spray glue the plant fibers treated in step (9) to form a plant fiber layer; and
    (11)对所述植物纤维层进行锁紧,烘干。(11) The plant fiber layer is locked and dried.
  9. 根据权利要求8所述的方法,其特征在于,所述步骤(11)的对植物纤维进行网格化处理包括:The method according to claim 8, wherein the step of meshing the plant fibers in the step (11) comprises:
    (111)对植物纤维进行开松和梳理;(111) opening and carding the plant fibers;
    (112)将开松和梳理后的植物纤维铺成网状,再进行初步锁紧。(112) The opened and carded plant fibers are laid into a net shape, and then preliminary locking is performed.
  10. 根据权利要求8所述的方法,其特征在于,步骤(112)中的初步锁紧程度低于步骤(11)中的锁紧程度。The method according to claim 8, wherein the preliminary locking degree in step (112) is lower than the locking degree in step (11).
PCT/CN2019/083385 2018-06-27 2019-04-19 Plant culture mat and preparation method thereof WO2020001140A1 (en)

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