WO2019131103A1 - トイレットペーパー - Google Patents

トイレットペーパー Download PDF

Info

Publication number
WO2019131103A1
WO2019131103A1 PCT/JP2018/045438 JP2018045438W WO2019131103A1 WO 2019131103 A1 WO2019131103 A1 WO 2019131103A1 JP 2018045438 W JP2018045438 W JP 2018045438W WO 2019131103 A1 WO2019131103 A1 WO 2019131103A1
Authority
WO
WIPO (PCT)
Prior art keywords
paper
toilet paper
tensile strength
toilet
ply
Prior art date
Application number
PCT/JP2018/045438
Other languages
English (en)
French (fr)
Japanese (ja)
Inventor
秀太 保井
Original Assignee
大王製紙株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 大王製紙株式会社 filed Critical 大王製紙株式会社
Priority to KR1020207015219A priority Critical patent/KR20200101910A/ko
Priority to US16/958,335 priority patent/US20210059484A1/en
Priority to EP18894199.1A priority patent/EP3733034B1/en
Publication of WO2019131103A1 publication Critical patent/WO2019131103A1/ja

Links

Images

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/002—Tissue paper; Absorbent paper
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47K—SANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
    • A47K10/00—Body-drying implements; Toilet paper; Holders therefor
    • A47K10/16—Paper towels; Toilet paper; Holders therefor
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/002—Tissue paper; Absorbent paper
    • D21H27/004—Tissue paper; Absorbent paper characterised by specific parameters
    • D21H27/005—Tissue paper; Absorbent paper characterised by specific parameters relating to physical or mechanical properties, e.g. tensile strength, stretch, softness
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/30—Multi-ply

Definitions

  • the present invention relates to toilet paper.
  • the present invention relates to a toilet paper used for cleaning of the human body after excretion and wiping off other than the human body.
  • Toilet paper is mainly used for post-excretion cleaning applications, but other applications may vary by region, region or country. And, in toilet paper products, in addition to those for cleaning applications after excretory, it is a highly versatile tissue that is often used for wiping off objects other than the human body, such as facial applications such as a nosepiece, various articles, and tables. Some are also used as substitutes for paper.
  • toilet paper While this type of toilet paper is regarded as important for frequent tearing as a general purpose tissue paper, it is also used for wiping after excretion, so softness and a feeling of softness are also required. Furthermore, water degradability is also required assuming that it will be discarded in the flush toilet.
  • the toilet paper having a strong character of substitute for such tissue paper is thick and hard in order to increase the difficulty of tearing, and it is inferior to a special-purpose product in terms of texture.
  • the main subject of this invention is providing the toilet paper which is excellent also in the texture of a skin, having the intensity
  • the means for solving the above problems are as follows.
  • the first means is 3 or 4 ply toilet paper
  • the basis weight per one ply of toilet paper is 14.9 g / m 2 or more and 16.2 g / m 2 or less, and the paper thickness as a whole is 297 ⁇ m or more and 435 ⁇ m or less
  • the dry tensile strength is 451 cN / 25 mm or more and 1001 cN / 25 mm or less
  • the second means is the toilet paper of the first means, wherein the water absorption rate is less than 2.6 seconds.
  • the third means is the toilet paper according to the first means, which has a water-solubility of 36 seconds or less.
  • the toilet paper which is excellent also in the texture of a skin is provided, having the intensity
  • the toilet paper according to the present embodiment is particularly suitable, for example, in the form of a roll-shaped toilet roll which is formed in a long strip shape and wound around a paper tube.
  • the size etc. of the toilet roll is 101 to 106 mm in width L1, 100 to 120 mm in diameter L2, 18 to 70 m in winding length (total length of toilet paper), 35 to 50 mm in paper tube inner diameter L3. Is desirable. If it is this size, a common paper holder for toilet roll can be used, it is easy to use for cleaning application after excretion in the toilet space, and the length of toilet paper is also other than the cleaning application after the above excretion It is long enough to be used for general purpose like tissue paper.
  • the toilet paper according to the present invention is one in which the moisturizing agent is not externally added by coating or the like.
  • Humectants as external additives include glycerin, diglycerin, propylene glycol, 1,3-butylene glycol, polyhydric alcohols such as polyethylene glycol, sorbitol, glucose, xylitol, maltose, maltose, maltitol, mannitol, trehalose, etc.
  • a polyol can be illustrated. However, it is not denied that the above-mentioned components are contained, as long as it affects only to an extent that it is not worthy of being a moisturizing toilet paper. When a moisturizer is applied, it becomes difficult to secure strength.
  • a softener and a soft moisturizer which determine the softness and paper strength of the base paper itself internally added at the time of papermaking may be added.
  • the softener include fatty acid ester compounds and fatty acid amide compounds.
  • fatty acid amide compounds have the effect of coating the fiber surface.
  • the toilet paper according to the present embodiment is three ply or four ply. That is, three sheets are stacked to form a pair, or four sheets are stacked to form a pair.
  • a multi-ply structure such as 3-ply or 4-ply
  • the thickness of the entire paper can be increased while each ply is made thinner, and in particular, it is difficult to tear while enhancing texture of the skin such as "softness” and "softness". be able to.
  • it is hard to express a feeling of thickness if it is 2 ply, and it becomes easy to sense weakness in the degree of tearing when using for cleaning of goods as a general purpose article.
  • the toilet paper according to the present embodiment has excellent properties in tear resistance and texture by setting the following characteristics in any of the 3-ply and 4-ply.
  • the toilet paper according to the present embodiment is 3 ply or 4 ply, and all of the following basis weight, paper thickness, longitudinal dry tensile strength and transverse wet tensile strength to transverse dry tensile strength ratio In the case of filling, it becomes excellent in tear resistance and texture.
  • Its toilet paper according to the present embodiment one ply per basis weight of 14.9 g / m 2 or more 16.2 g / m 2 or less. If the basis weight of one ply is within this range, it is possible to make it sufficiently hard to break and have a good texture in the case of the above three or four ply, and it becomes easy to express water-solubility.
  • the toilet paper according to the present embodiment has a paper thickness of 297 ⁇ m or more and 435 ⁇ m or less as a whole of 3 plies or 4 plies. If the paper thickness is in this range, sufficient stiffness in tearing can be ensured in the case of 3 or 4 plies based on the above-mentioned basis weight, and it is possible to make the skin feel particularly soft and particularly good.
  • the basis weight which concerns on this invention is based on the basis weight measuring method of JISP 8124 (1998).
  • the paper thickness is measured using a dial thickness gauge (thickness measuring instrument) "PEACOCK G type" (manufactured by Ozaki Mfg. Co., Ltd.) after sufficiently conditioning the test piece under the conditions of JIS P 8111 (1998). And the value. Specifically, make sure that there is no dirt or dust between the plunger and the measuring table, lower the plunger on the measuring table, move the memory of the dial thickness gauge, and then set the zero point, and then Then, raise the plunger and place the test piece on the measurement table, slowly lower the plunger and read the gauge at that time. At the time of measurement, keep in mind that the terminal of a metal plunger (a circular plane with a diameter of 10 mm) vertically contacts the paper plane. In addition, the load at the time of this paper thickness measurement is about 70 gf.
  • the toilet paper according to the present embodiment has a dry tensile strength in the longitudinal direction of 451 cN / 25 mm or more and 1001 cN / 25 mm or less. This dry tensile strength is a very high value as compared to a dedicated wipe after excretion.
  • the toilet paper of the present embodiment is sufficiently hard to break when used for general purpose because of such high dry tensile strength.
  • the dry tensile strength in the longitudinal direction is high, it is easy to develop particularly smooth texture.
  • the ratio of the lateral wet tensile strength to the lateral dry tensile strength is 0.09 or more. This is a higher value than the conventional product.
  • the “lateral dry tensile strength” is considered not to have an individual functionality such as “softness” or “softness” but to have an overall “skin feel” functionality.
  • the dry tensile strength in the lateral direction is preferably 180 cN / 25 mm or more and 395 cN / 25 mm or less.
  • the lateral wet paper strength tends to show the weakest value among the indicators showing the strength of the paper.
  • the wet paper strength in the lateral direction is high, the durability of the wiping in the wet state or the so-called feeling of relief at the time of cleaning after using the shower toilet is excellent.
  • the ratio of the lateral wet tensile strength to the lateral dry tensile strength is as high as 0.09 or more. That is, it is excellent in the balance between the texture and the toughness.
  • the lateral wet tensile strength is 25 cN / 25 mm or more from the point that it does not break in actual use such as wiping application after excretion in the toilet space, and that it is necessary to have a sense of security at the time of wiping It is desirable that it is 40 cN / 25 mm or less. Within this range, the ratio of the wet tensile strength lateral to the dry tensile strength lateral is equal to or greater than 0.09, which is very preferable in securing the softness in use.
  • the longitudinal direction of the paper is also referred to as the MD direction, and is the flow direction in papermaking.
  • the lateral direction of the paper is also referred to as a CD direction, which is a direction orthogonal to the flow direction (MD direction) in papermaking.
  • the dry tensile strength according to the present invention is a value measured based on JIS P 8113 (2006), and is measured as follows.
  • the test piece used the thing cut
  • As a testing machine a load cell tensile testing machine TG-200N manufactured by Minebea Co., Ltd. and a corresponding machine corresponding thereto are used.
  • the gripping distance is 100 mm, and the tensile speed is set to 100 mm / min.
  • the measurement is performed in the procedure of clamping the both ends of the test piece to the clamp of the tester, applying a tensile load in the vertical direction to the paper piece, and reading the indicated value (digital value) when the paper breaks.
  • Five sets of samples are prepared in each of the longitudinal direction and the lateral direction and measured five times each, and the average of the measured values is taken as the dry tensile strength in each direction.
  • a plurality of sheets were stacked to measure the dry tensile strength in accordance with the number of product plies.
  • the dry tensile strength of the base paper was also measured according to the number of product plies.
  • the wet tensile strength is a value measured based on JIS P 8135 (1998), and is measured as follows.
  • the test piece used the thing cut
  • the tissue paper is measured as it is in the case of multiple plies.
  • As a testing machine a load cell tensile testing machine TG-200N manufactured by Minebea Co., Ltd. and a corresponding machine corresponding thereto are used.
  • the gripping distance is 100 mm, and the tensile speed is set to 50 mm / min.
  • the specimen used is one that has been cured for 10 minutes in a dryer at 105 ° C.
  • index which shows surface property is 6.6 or more and 10.3 or less. If the MMD is less than 6.6, the surface is too slippery to deteriorate the wiping properties. If the MMD is more than 10.3, the touch may be poor and it may not be suitable for use as a toilet paper.
  • the measurement of MMD uses the measuring device 100 shown in FIG. 2 while bringing the contact surface of the friction element into contact with the surface of the measurement sample to which a tension of 20 g / cm is given in a predetermined direction with a contact pressure of 25 g.
  • the friction element has a contact surface in which 20 piano wires P having a diameter of 0.5 mm are adjacent to each other and each has a length and a width of 10 mm. It is assumed that a unit bulging portion whose tip is formed of 20 piano wires P (curvature radius of 0.25 mm) is formed on the contact surface.
  • the softness of the toilet paper of the present embodiment is preferably 1.8 cN / 100 mm or more and 3.5 cN / 100 mm or less. Softness is one of the indicators of softness that is considered to be softer as its value is lower. In the case of tissue paper or toilet paper, it is considered to be sufficiently soft if it is 1.0 cN / 100 mm or less.
  • the measurement of softness refers to the value measured based on the handle ohm method according to JIS L 1096 E method (1990). However, the size of the test piece is 100 mm ⁇ 100 mm, and the clearance is 5 mm. Measurement is made 5 times each in the longitudinal direction and in the lateral direction with 1 ply, and the average value of all 10 times is taken. Softness is unitless, but in consideration of the size of the test piece, cN / It may be expressed in units of 100 mm.
  • Raw material pulp for toilet paper that is, the fiber material constituting the toilet paper, mechanical pulp such as grandwood pulp (GP), pressure-ized groundwood pulp (PGW), thermomechanical pulp (TMP), etc .; semi-chemical pulp (CP) ), Softwood high yield unbleached kraft pulp (HNKP), softwood bleached kraft pulp (NBKP), hardwood unbleached kraft pulp (LUKP), hardwood bleached kraft pulp (LBKP) etc. Chemical pulp; Deinking pulp (DIP), waste Waste paper pulp such as pulp (WP) may be mentioned. Fibers other than pulp may be included.
  • mechanical pulp such as grandwood pulp (GP), pressure-ized groundwood pulp (PGW), thermomechanical pulp (TMP), etc .
  • semi-chemical pulp (CP) Softwood high yield unbleached kraft pulp (HNKP), softwood bleached kraft pulp (NBKP), hardwood unbleached kraft pulp (LUKP), hardwood bleached kraft pulp (LBKP) etc.
  • the pulp can be used singly or in combination of two or more.
  • chemical pulp containing no filler and foreign matter is preferred.
  • those containing more LBKP (also referred to as L wood or hardwood pulp) than NBKP (also referred to as N wood or softwood pulp) are used. That is, a chemical pulp having a ratio of NBKP to LBKP (NBKP / LBKP) of 50/50 to 30/70 is preferable. Because the fiber thickness of NBKP is thicker than that of LBKP, the more NBKP, the more bulky.
  • the raw material pulp may contain woods such as straw pulp, bamboo pulp, kenaf pulp, and herbs.
  • waste paper pulp may be blended, but waste paper pulp is hard to develop "softness", so it is extremely desirable to be composed of only NBKP and LBKP of virgin pulp.
  • polyester fibers such as polyethylene terephthalate, polybutylene terephthalate and copolymers thereof, polyolefin fibers such as polyethylene, polypropylene and polystyrene, acrylic fibers such as polyacrylonitrile, acrylic fibers such as modacrylic and the like
  • Polyamide fibers such as nylon 6, nylon 66, nylon 12 etc.
  • polyvinyl alcohol fibers such as polyvinylidene chloride fibers, polyvinyl chloride fibers
  • synthetic fibers such as urethane fibers
  • semi-synthetic fibers such as triacetate fibers, diacetate fibers, viscose rayon And regenerated cellulose fibers such as copper ammonia rayon, polynozic rayon and lyocell
  • chemical fibers such as regenerated fibers obtained by spinning collagen, alginic acid and chitin in solution Rukoto can.
  • the polymer constituting the chemical fiber may be in the form of a homopolymer, a modified
  • the toilet paper of the present embodiment desirably has a water absorption rate of less than 2.4 seconds.
  • the water can be absorbed quickly at the time of wiping off the water having a water absorption speed of less than 2.4 seconds or at the time of cleaning after using a so-called shower toilet.
  • it becomes easy to use for wiping off articles other than wiping after excretion that is, for dusting of the edge of a wash basin or a toilet, or on a table or a floor.
  • the end portion of the winding which is referred to as a tail
  • the penetration of the tail paste becomes rapid and the tail portion It will be possible to fix it stably.
  • the measurement of water absorption rate is based on old JIS S 3104 (1985).
  • the water absorption test uses a pipette or the like adjusted to about 0.1 mL of one drop to be dropped, and a test piece (a plurality of stacked pieces) on a support base having a hole with a diameter of 40 mm or more at the center. Place a drop of distilled water at a temperature of 20 ⁇ 1 ° C from a height of 10 mm. From when the water droplet contacts the test piece, the time until it is completely absorbed and the reflected light disappears is measured in 0.1 second units. The test is performed 5 times and the average is used to determine.
  • water-degradability it is desirable for water-degradability to be within 36 seconds. If the water degradability is within 36 seconds, the risk of clogging the piping when the water is discarded to the flush toilet etc. decreases in each step.
  • the measurement of this water solubility is according to JIS P 4501 (1993). In the test for ease of loosening, a 300 mL beaker containing 300 mL of water (water temperature 20 ⁇ 5 ° C.) is placed on a magnetic stirrer, and the rotational speed of the rotor is adjusted to 600 ⁇ 10 revolutions / minute. Insert a test piece of 114 ⁇ 2 mm square on one side and press the stopwatch.
  • the number of revolutions of the rotor drops once to about 500 revolutions due to the resistance of the test piece, and the number of revolutions increases as the test piece is loosened. When this number of revolutions recovers to 540 revolutions, the stopwatch is stopped and the time is measured in one-second units. The results for ease of loosening are expressed in averages of 5 tests.
  • the rotor is a disc having a diameter of 35 mm and a thickness of 12 mm.
  • the adjustment of the dry tensile strength and the wet tensile strength can be easily performed by internally adding a dry strength agent or a wet strength agent to the stock or wet paper, It may be adjusted by a method not using a paper strength agent such as the number of plies, the type of pulp, and the blending ratio of pulp. Wet strength agents tend to balance wet strength and water solubility.
  • dry strength agent examples include starch, polyacrylamide, CMC (carboxymethylcellulose) or a salt thereof, carboxymethylcellulose sodium, calcium carboxymethylcellulose, carboxymethylcellulose zinc and the like.
  • dry strength agent When the dry strength agent is internally added, it may be added to the pulp slurry at about 1.0 kg / t of pulp or less.
  • wet paper strength agents examples include polyamidepolyamine epichlorohydrin resin, urea resin, acid colloid / melamine resin, thermally crosslinkable coated PAM, and the like.
  • a temporary wet strength agent temporary wet strength agent
  • cationic temporary wet strength agents are desirable.
  • Temporary wet strength agents reduce the wet strength of the paper immediately thereafter, while essentially maintaining the strength of the paper immediately after contact with water.
  • the surface does not become rough or torn when the amount of moisture is wiped off, and it has excellent strength in general-purpose, particularly versatile wiping of moisture, and is also excellent in texture of the skin, A large amount of water at the time of disposal, for example, the water flow in the flush toilet can be disintegrated.
  • a temporary wet paper strengthening agent for example, TS-20 manufactured by Starlight PMC Co., Ltd., a glyoxylated polyacrylamide, a polymeric aldehyde-functional compound such as a cationic glyoxylated polyacrylamide, or a dihydric aldehyde of glyoxal
  • the copolymer of the acrylamide monomer and other copolymerizable unsaturated monomers, dialdehyde starch, etc. are mentioned. You may use these multiple types.
  • the content in the paper is about 0.5 to 20.0 kg / pulp t.
  • the preferred content is 1.0 to 12.0 kg / pulp t.
  • a more preferable content is 4.0 to 8.0 kg / pulp t. If it is less than 0.5 kg / pulp t, the wet strength may not be sufficiently enhanced, and if it is more than 20.0 kg / pulp t, the water solubility may be too slow.
  • the tissue paper according to the present embodiment is a 3-ply or 4-ply tissue paper, it may be embossed. More preferably, it is desirable that the embossed protrusion be a double embossment facing the inner side of the ply laminate. In the case of double embossing, it is desirable that embossing is performed for 1 to 2 plies in the case of 3 plies, and that 1 to 3 plies are embossed in the case of 4 plies. That is, there may be unembossed plies in the plies.
  • a lamination embossing process having a structure in which known lamination pastes such as starch, carboxymethylcellulose, aqueous ink and the like are applied to the tops of the projections and the plies are adhered to each other via the tops of the projections.
  • the area, depth and range of the individual embossings in embossing are not necessarily limited, they have a substantially flat top surface on one side, the area of the top surface is 0.50 to 2.50 mm 2 and the embossed recess depth It is preferable that 5 to 30 emboss pieces having a size of 0.05 to 0.50 mm are formed per 10 mm square so that the area to which the embossing pressure is applied is 5 to 20% of the whole.
  • the embossed recess depth is a value measured by using a one-shot 3D measurement macroscope VR-3200 or its equivalent manufactured by Keyence Corporation and the image analysis software “VR-H1A” or its equivalent software.
  • the measurement is performed under the conditions of a magnification of 12 ⁇ and a visual field area of 24 mm ⁇ 18 mm.
  • the magnification and the visual field area can be appropriately changed depending on the size of the emboss.
  • a specific measurement procedure uses the above software to obtain an embossed recess depth (measured cross-sectional curve) profile at a line segment that crosses the longest part of the edge of one embossing in the image.
  • ⁇ c 800 ⁇ m (where, ⁇ c is a “filter that defines the boundary between the roughness component and the bending component” described in JIS-B 0601 “3.1.1.2”))
  • ⁇ c is a “filter that defines the boundary between the roughness component and the bending component” described in JIS-B 0601 “3.1.1.2”
  • the minimum between two inflection points P1 and P2 that are convex upward and the inflection points P1 and P2 Determine the value, and set it as the minimum value Min of the depth. Further, the average value of the depth values of the inflection points P1 and P2 is taken as the maximum value Max of the depth.
  • the embossed recess depth maximum value Max ⁇ minimum value Min.
  • the distance (length) of the inflection points P1 and P2 on the XY plane is defined as the length of the longest part.
  • the embossed recess depth is also measured for the shortest portion in the direction perpendicular to the longest portion, and the larger value is adopted as the embossed recess depth. The above measurements are made for any 10 embossments on the toilet paper surface, and the average value is taken as the final embossed recess depth.
  • the toilet paper of the present embodiment is particularly suitable to be in the form of a toilet roll.
  • the preferred form of the toilet roll using the toilet paper of this embodiment is a winding hardness of 0.45 to 0.60 kgf, a winding length of 20 to 30 m, and a winding diameter of 100 to 117 mm.
  • the winding hardness is measured with a PI gauge manufactured by Muratec KDS Co., Ltd. or a corresponding machine. Specifically, a pi gauge is wound around the roll circumference and pulled in the tangential direction of the roll to squeeze the roll central part, and the tension when the diameter of the roll central part is shrunk 3 mm from the original state is a push-pull gauge It was measured. Similar to the winding diameter, it was measured by ⁇ gauge.
  • the ⁇ gauge is a stainless steel measure that is wound around the roll circumference and the diameter is read from its length.
  • the toilet roll according to the toilet paper according to the examples of the present invention (Examples 1 to 9), Comparative Examples 1 to 4 and Conventional Examples 1 to 6 was manufactured, and the physical properties and composition of the toilet paper wound on the toilet roll. While measuring the value, a sensory test was conducted on "Toughness when wet / Toughness to tear (objective)", “Softness of touch”, “Feeling feeling” and “Smoothness”. The measurement methods of basis weight, paper thickness, tensile strength for drying and wetting, MMD, softness, winding hardness, water absorption speed and water-disintegratability are as described above.
  • the test method of sensory evaluation is as follows. The test is conducted by 15 evaluators, and each sample is evaluated 5 times for each sample, and the average value excluding the outlier score is taken as the score of the evaluator in a certain sample. Also, with the score of Conventional Example 1 as 4 points, each sample is scored at 1 to 7 points, and the average value of each evaluator is calculated and scored. In this evaluation, if nine evaluators evaluate each sample for each evaluator five times, it is possible to make an evaluation without any bias.
  • the toilet paper used as a sample was a total of 19 types of four comparative examples, nine types of Example, and six types of conventional examples which are commercial products.
  • standard sample is a toilet paper with the highest share, and is a sample which most consumers have touched.
  • the items of sensory evaluation are four items: “Toughness when wet / Hard to tear (objective)", “softness of the skin”, “softness”, and “smoothness”.
  • the softness of the skin when the evaluator pulled out the toilet paper and touched it with a hand was scored in 7 steps with the score of the reference sample being 4.
  • the evaluator pulled out the toilet paper, rolled it up, and the soft feeling when touched was scored in 7 steps with the score of the reference sample being 4.
  • the “smoothness” was obtained by scoring the smoothness when the evaluator pulled out the toilet paper and touched it with a hand in seven steps with the score of the reference sample being 4.
  • the examples according to the present invention are “strength when wet / difficulty in tearing (objective)", “softness of the skin”, “soft feeling”, “smoothness” In each sensory evaluation of “a”, the value is significantly superior to that of each conventional example.
  • the results were excellent in each stage with respect to “durability / wetness when wet (objective)", “soft feeling” and “smoothness”.
  • the evaluation of Comparative Example 3 is high with respect to the "softness of the touch”
  • the example is a multi-ply example, considering that the comparative example 3 is a 2-ply with respect to the 3-ply or 4-ply.
  • the softness of the texture is equal to or higher than that of Comparative Example 3 of 2 ply.
  • the examples according to the present invention are excellent in sensory evaluation, and the water absorption speed is higher in each step than the conventional example and the comparative example, and also have durability. That is, the toilet paper which concerns on this invention is a toilet paper which is hard to tear in wiping use other than a human body, and is further excellent in the texture of the skin at the time of the person's wiping.

Landscapes

  • Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Sanitary Thin Papers (AREA)
  • Paper (AREA)
PCT/JP2018/045438 2017-12-27 2018-12-11 トイレットペーパー WO2019131103A1 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
KR1020207015219A KR20200101910A (ko) 2017-12-27 2018-12-11 화장지
US16/958,335 US20210059484A1 (en) 2017-12-27 2018-12-11 Toilet paper
EP18894199.1A EP3733034B1 (en) 2017-12-27 2018-12-11 Toilet paper

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2017252551A JP7084717B2 (ja) 2017-12-27 2017-12-27 トイレットペーパー
JP2017-252551 2017-12-27

Publications (1)

Publication Number Publication Date
WO2019131103A1 true WO2019131103A1 (ja) 2019-07-04

Family

ID=67067135

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2018/045438 WO2019131103A1 (ja) 2017-12-27 2018-12-11 トイレットペーパー

Country Status (6)

Country Link
US (1) US20210059484A1 (ko)
EP (1) EP3733034B1 (ko)
JP (1) JP7084717B2 (ko)
KR (1) KR20200101910A (ko)
CN (1) CN109965759B (ko)
WO (1) WO2019131103A1 (ko)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7133943B2 (ja) * 2018-02-28 2022-09-09 大王製紙株式会社 ティシュペーパー
JP6689944B1 (ja) * 2018-11-30 2020-04-28 大王製紙株式会社 トイレットペーパー

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005168582A (ja) * 2003-12-08 2005-06-30 Daio Paper Corp 水解性衛生紙
JP2009161900A (ja) * 2009-01-20 2009-07-23 Daio Paper Corp 水解性衛生紙
JP2015126771A (ja) * 2013-12-27 2015-07-09 日本製紙クレシア株式会社 トイレットペーパー及びその製造方法
JP2016193042A (ja) * 2015-03-31 2016-11-17 大王製紙株式会社 ティシュペーパー
JP2017169681A (ja) 2016-03-22 2017-09-28 王子ホールディングス株式会社 トイレットペーパー

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6265052B1 (en) * 1999-02-09 2001-07-24 The Procter & Gamble Company Tissue paper
CA2383267A1 (en) * 1999-08-19 2001-02-22 Mark John Steinhardt A multi-ply tissue having a high caliper, low density, absorbent layer
CA2324786C (en) * 1999-11-01 2014-02-25 Fort James Corporation Multi-ply absorbent paper product having impressed pattern
JP3619808B2 (ja) * 2002-01-08 2005-02-16 大王製紙株式会社 トイレット用巻取衛生ロール紙
US7662257B2 (en) * 2005-04-21 2010-02-16 Georgia-Pacific Consumer Products Llc Multi-ply paper towel with absorbent core
JP3726083B2 (ja) * 2003-01-08 2005-12-14 大王製紙株式会社 シングルプライトイレットペーパー及びその製造方法
EP1845193A1 (fr) * 2006-04-14 2007-10-17 Georgia-Pacific France Feuille absorbante délitable multiplis, rouleau et procédé de fabrication associés
US7563344B2 (en) * 2006-10-27 2009-07-21 Kimberly-Clark Worldwide, Inc. Molded wet-pressed tissue
JP4570669B2 (ja) * 2008-03-31 2010-10-27 大王製紙株式会社 衛生薄葉紙
JP5394684B2 (ja) * 2008-07-31 2014-01-22 大王製紙株式会社 衛生薄葉紙
JP2010035659A (ja) * 2008-07-31 2010-02-18 Daio Paper Corp 衛生薄葉紙製品及びその製造方法
JP5602998B2 (ja) * 2008-09-19 2014-10-08 大王製紙株式会社 衛生薄葉紙ロール
JP5497310B2 (ja) * 2009-02-27 2014-05-21 大王製紙株式会社 水解性衛生薄葉紙及びトイレットペーパーロール
JP5314065B2 (ja) * 2011-02-22 2013-10-16 大王製紙株式会社 トイレットロール製品の製造方法及びトイレットロール製品
CN104271837A (zh) * 2012-05-08 2015-01-07 宝洁公司 纤维结构及其制备方法
JP5755697B2 (ja) * 2013-08-30 2015-07-29 大王製紙株式会社 トイレットロール
FI3289139T3 (fi) * 2015-04-29 2023-09-20 Essity Hygiene & Health Ab Pehmopaperi, joka käsittää miscanthuksesta peräisin olevia massakuituja, ja menetelmä sen valmistamiseksi
JP6188855B1 (ja) * 2016-03-31 2017-08-30 大王製紙株式会社 ティシュペーパー

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005168582A (ja) * 2003-12-08 2005-06-30 Daio Paper Corp 水解性衛生紙
JP2009161900A (ja) * 2009-01-20 2009-07-23 Daio Paper Corp 水解性衛生紙
JP2015126771A (ja) * 2013-12-27 2015-07-09 日本製紙クレシア株式会社 トイレットペーパー及びその製造方法
JP2016193042A (ja) * 2015-03-31 2016-11-17 大王製紙株式会社 ティシュペーパー
JP2017169681A (ja) 2016-03-22 2017-09-28 王子ホールディングス株式会社 トイレットペーパー

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP3733034A4

Also Published As

Publication number Publication date
JP2019115593A (ja) 2019-07-18
CN109965759A (zh) 2019-07-05
KR20200101910A (ko) 2020-08-28
JP7084717B2 (ja) 2022-06-15
CN109965759B (zh) 2023-03-28
EP3733034A4 (en) 2021-08-25
EP3733034B1 (en) 2022-06-29
EP3733034A1 (en) 2020-11-04
US20210059484A1 (en) 2021-03-04

Similar Documents

Publication Publication Date Title
US10213066B2 (en) Coreless roll of absorbent sheet and method for manufacturing the same
JP5497310B2 (ja) 水解性衛生薄葉紙及びトイレットペーパーロール
JP2010202986A5 (ko)
JP5485520B2 (ja) 衛生薄葉紙及びその製造方法
WO2019131103A1 (ja) トイレットペーパー
JP2017064191A (ja) トイレットペーパー及びトイレットペーパーの品質評価方法
JP2009240721A5 (ko)
WO2020179379A1 (ja) トイレットペーパー
KR102644625B1 (ko) 화장지
JP5384998B2 (ja) 産業用ワイプ
JP5496590B2 (ja) 衛生用薄葉紙及び衛生用薄葉紙の製造方法
JP6985323B2 (ja) トイレットペーパー
WO2023053494A1 (ja) トイレットロール
US20240209576A1 (en) Toilet paper and method for producing toilet paper
JP7493328B2 (ja) トイレットロール
WO2023053495A1 (ja) トイレットロール
WO2023053496A1 (ja) トイレットロール
WO2020195259A1 (ja) トイレットペーパー及びトイレットペーパーの製造方法
JP2023051121A5 (ko)
JP2023051120A5 (ko)
JP2023051122A5 (ko)

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 18894199

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

ENP Entry into the national phase

Ref document number: 2018894199

Country of ref document: EP

Effective date: 20200727