WO2019093254A1 - Produit cosmétique pour la peau - Google Patents

Produit cosmétique pour la peau Download PDF

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Publication number
WO2019093254A1
WO2019093254A1 PCT/JP2018/040926 JP2018040926W WO2019093254A1 WO 2019093254 A1 WO2019093254 A1 WO 2019093254A1 JP 2018040926 W JP2018040926 W JP 2018040926W WO 2019093254 A1 WO2019093254 A1 WO 2019093254A1
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WO
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Prior art keywords
skin
skin cosmetic
water
cosmetic
mass
Prior art date
Application number
PCT/JP2018/040926
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English (en)
Japanese (ja)
Inventor
翔太 水野
昭則 小野
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株式会社 資生堂
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Application filed by 株式会社 資生堂 filed Critical 株式会社 資生堂
Priority to JP2019552769A priority Critical patent/JP7203751B2/ja
Publication of WO2019093254A1 publication Critical patent/WO2019093254A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/67—Vitamins
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/02—Preparations for care of the skin for chemically bleaching or whitening the skin

Definitions

  • the present invention relates to a skin cosmetic containing a whitening agent. More specifically, the present invention relates to a skin cosmetic which has a moderate hardness enough to stand on the skin, has a feel like pully jelly, and is excellent in the permeability to the keratin when applied to the skin.
  • the basic functions of skin care cosmetics include cleaning and wiping, anti-drying, anti-ultraviolet rays, anti-oxidation and activation.
  • skin care cosmetics with functions such as whitening, wrinkles and sagging improvement, and acne prevention. It is said that skin care cosmetics are mainly used in the order according to the so-called "beauty system".
  • This cosmetic system is a system in which after cleansing and cleansing with a cleanser, hydration (moisturizing) with a lotion and then application in the order of a cosmetic fluid, an emulsion and a cream.
  • all-in-one cosmetics in which one cosmetic has the function of a plurality of cosmetics applied after the cosmetic are also marketed, and it is useful for shortening the time required for skin care.
  • Patent Document 1 describes a skin external preparation containing a thickener comprising a microgel containing a hydrophilic compound having a gelling ability and the like and a skin lightening agent component.
  • the said skin external preparation is said to be stable without causing stickiness, squeakiness, excellent usability, and causing no weaning etc. even if the whitening component is highly blended.
  • Patent Document 2 discloses a skin external preparation containing a salt type whitening agent of ascorbic acid type / alkoxysalicylic acid type and carrageenan as a thickener, and describes that it is excellent in temporal stability and feeling in use. It is done.
  • the gel composed of carrageenan in Patent Document 2 is a pure, relatively elastic gel and has a high yield value and is hard to flow. However, it is taught that when the shear is greater than the yield value, the gel is deformed significantly, so that when the gel spreads on the skin, the gel is smashed fresh and squeezed, resulting in good spreading and no slimming or stickiness.
  • Patent Document 3 discloses a skin external preparation containing a hydrophobically modified polyether urethane and a microgel mainly composed of gellan gum, and said the skin external preparation has good spread and familiarity to the skin and is not sticky. It is done. And the example of the all-in-one gel which has the above characteristics is described (Example 2). However, there is no known skin cosmetic that has both a suitable hardness and an excellent feeling in use.
  • JP 2001-342125 A JP, 2005-120051, A JP, 2013-193963, A
  • the subject in the present invention is a novel skin cosmetic containing a skin-whitening agent, which has a suitable hardness that makes it stand on the skin and a feel like a pull-up jelly, and is superior in penetration when applied to the skin Providing skin cosmetics.
  • a water-soluble polymer is selected from polyoxyethylene polyoxypropylene alkyl (C18 to C28) ether and / or polyoxyethylene hydrogenated castor oil
  • the present invention is completed based on the finding that when it is blended in combination with polyethylene glycol having ethylene oxide having a number average degree of polymerization, a non-conventional base having an appropriate hardness and an excellent feeling in use can be obtained. It came to
  • the present invention (A) a skin-whitening agent selected from tranexamic acid and ascorbic acid glucoside; (B) polyethylene glycol having an average degree of polymerization of ethylene oxide of 4 to 20; (C) 0.15% by weight or more water-soluble polymer; (D) one or more selected from polyoxyethylene polyoxypropylene alkyl (C18 to C28) ether and polyoxyethylene hydrogenated castor oil; (E) contains water, It provides a skin cosmetic characterized in that the viscosity at 30 ° C. is in the range of 3,000 to 10,000 mPa ⁇ s.
  • the skin cosmetic composition of the present invention is water-based while having a moderate hardness enough to stand on the skin and has a jelly-like appearance and feel. Furthermore, it is well-suited to the skin, can provide cool coolness, and is excellent in the feeling that an active ingredient such as a skin lightening agent penetrates the skin.
  • (A) Skin-lightening agent selected from tranexamic acid and ascorbic acid glucoside The skin-lightening agent to be incorporated into the skin cosmetic composition of the present invention is tranexamic acid and / or ascorbic acid glucoside.
  • Tranexamic acid is conventionally used as a whitening agent in cosmetics and the like.
  • Tranexamic acid in the present invention can be selected from tranexamic acid and its salt and its derivative.
  • Examples of tranexamic acid salts include metal salts such as magnesium salts, calcium salts, sodium salts and potassium salts, and inorganic salts such as phosphates, hydrochlorides, hydrobromides and sulfates.
  • tranexamic acid esters for example, vitamin A esters, vitamin E esters, vitamin C esters, vitamin esters such as vitamin D esters, phenyl esters, hydroquinone esters, gentisic acid esters, etc.
  • examples thereof include tranexamic acid amide (methylamide or a salt thereof), tranexamic acid dimer and the like.
  • the ascorbic acid glucoside is not particularly limited as long as it is a glucoside of ascorbic acid used as a whitening agent in cosmetics and the like.
  • L-ascorbic acid glucosides such as L-ascorbic acid 2-glucoside, L-ascorbic acid diglucoside and the like can be mentioned.
  • the blending amount of the whitening agent (component (a)) in the skin cosmetic of the present invention is not particularly limited, but usually 0.5 to 5.0% by mass, preferably 0.55 to 4.0% by mass. More preferably, it is 0.6 to 3.0% by mass.
  • the polyethylene glycol blended in the skin cosmetic composition of the present invention comprises ethylene oxide having an average degree of polymerization of 4 to 20, preferably 4 to 12. That is, the following formula (A): H (OCH 2 CH 2 ) n OH (A) And a polymer of ethylene oxide represented by and having an average value of n of 4 to 20, preferably 4 to 12.
  • polyethylene glycol 200 (INCI name: PEG-4), polyethylene glycol 300 (INCI name: PEG-6), polyethylene glycol 400 (INCI name: PEG-8), polyethylene glycol 600 (INCI name: PEG- 12) and polyethylene glycol 1000 (INCI name: PEG-20) and the like. If polyethylene glycol containing ethylene oxide having an average degree of polymerization of more than 20 is used in the system of the present invention, the desired hardness can be obtained, but the skin becomes unfamiliar and feels sticky.
  • the blending amount of polyethylene glycol (component (b)) having an average polymerization degree of ethylene oxide of 4 to 20 in the skin cosmetic of the present invention is usually 0.1 to 3% by mass, preferably 0.2 to 2.5. % By mass, more preferably 0.3 to 2% by mass.
  • the water-soluble polymer to be added to the skin cosmetic of the present invention is not particularly limited as long as it is used as an aqueous thickener in cosmetics and the like. Among them, from the viewpoint of obtaining appropriate hardness in the present invention, it is preferable to use one or more selected from carboxyvinyl polymers and hydrophobically modified polyether urethanes.
  • the carboxyvinyl polymer (INCI name: carbomer) is an acidic polymer (crosslinked polyacrylic acid) based on an acrylic acid polymer.
  • carbomer crosslinked polyacrylic acid
  • Carbopol 940, 941, 980, 981, 934, 2984, 5984 manufactured by BF Goodrich
  • Hibis Wako 104, 105 manufactured by Wako Pure Chemical Industries, Ltd.
  • the carboxyvinyl polymer in the present invention may be alkyl-modified (eg, acrylic acid / alkyl acrylate (C10-30) copolymer, etc.).
  • Hydrophobically modified polyether urethane is a kind of associative thickener, and it is believed that hydrophobic portions associate in an aqueous medium to exhibit a thickening effect (see Patent Document 3).
  • a hydrophobic modified polyether urethane having a structure represented by the following formula (I) is preferably used.
  • R 1 represents an alkyl group having 2 to 4 carbon atoms
  • R 2 and R 4 each independently represent an alkylene group having 2 to 4 carbon atoms or a phenylethylene group.
  • it is an alkylene group having 2 to 4 carbon atoms.
  • R 3 represents an alkylene group having 1 to 10 carbon atoms which may have a urethane bond.
  • R 5 represents a linear, branched or secondary alkyl group having 8 to 36, preferably 12 to 24 carbon atoms.
  • m is a number of 2 or more.
  • h is a number of 1 or more.
  • k is a number of 1 to 500.
  • it is a number of 100 to 300.
  • n is a number of 1 to 200.
  • it is a number of 10 to 100.
  • (PEG-240 / decyltetradeces-20 / HDI) copolymer (INCI name: PEG-240 / HDI COPOLYMER BIS-DECYLTETRADECETH-20 ETHER) is preferable Used.
  • Examples of commercially available (PEG-240 / decyltetradeceth-20 / HDI) copolymer include “Adecanol GT-700” (manufactured by ADEKA Co., Ltd.).
  • the “moderate hardness” in the present invention is such a hardness that a proper amount can be taken with a finger when taking out the cosmetic from the container, and that it can stand on the skin in a pleasing manner.
  • To stand up means that the cosmetic is placed in a bulging state on the skin, like water droplets on a water repellent substrate.
  • the viscosity measured with a B-type viscometer at 30 ° C. is in the range of about 3,000 to about 10,000 mPa ⁇ s.
  • the compounding amount of the water-soluble polymer (component (c)) in the skin cosmetic composition of the present invention is such that the cosmetic composition has an appropriate hardness. That is, the water-soluble polymer (component (c)) is blended in an amount such that the viscosity of the cosmetic at 30 ° C. is in the range of about 3,000 to about 10,000 mPa ⁇ s. Therefore, the compounding amount of the water-soluble polymer may vary depending on the properties (such as molecular weight) of the water-soluble polymer. In the case of water-soluble polymers generally used in cosmetics, if the amount is less than 0.15% by mass, in many cases, the hardness will not be adequate. Therefore, the content of the water-soluble polymer is usually 0.15% by mass or more.
  • the upper limit value of the compounding amount of the water-soluble polymer may be an amount satisfying the above-mentioned viscosity.
  • the content is preferably 0.4% by mass or less, more preferably 0.35% by mass.
  • the upper limit value is about 5% by mass, preferably about 3% by mass, and more preferably about 2.5% by mass.
  • polyoxyethylene polyoxypropylene alkyl (C18 to C28) ether One or more selected from polyoxyethylene polyoxypropylene alkyl (C18 to C28) ether and polyoxyethylene hydrogenated castor oil (d)
  • the component acting as an emulsifier in the system of the present invention is there.
  • the polyoxyethylene polyoxypropylene alkyl (C18 to C28) ether one having a structure represented by the following formula (II) is preferably used.
  • R is a linear or branched alkyl group having 18 to 28 carbon atoms
  • m is a number of 2 to 24
  • n is a number of 10 to 38.
  • POP (13) POE (24) 2-decyl tetradecyl ether is particularly preferable, and its commercially available product "S-safe 1324 (D)" (NOF CORPORATION) Company company) can be used.
  • the polyoxyethylene hydrogenated castor oil used in the present invention has an HLB of 10 or more, for example, PEG-30 hydrogenated castor oil, PEG-40 hydrogenated castor oil, PEG-50 hydrogenated castor oil, PEG- 60 hydrogenated castor oil, PEG-80 hydrogenated castor oil, and PEG-100 hydrogenated castor oil are preferably used.
  • the blending amount of the component (d) in the skin cosmetic of the present invention is usually 0.05 to 0.5% by mass, preferably 0.1 to 0.4% by mass, more preferably 0.1 to 0.3 It is mass%.
  • the water soluble polymer (c) and one or more selected from (d) polyoxyethylene polyoxypropylene alkyl (C18 to C28) ether and polyoxyethylene hydrogenated castor oil It is preferable to set the blending amount ratio of (1) in the range of 20: 1 to 1: 1, more preferably in the range of 15: 1 to 2: 1.
  • the amount of water to be incorporated into the skin cosmetic of the present invention is not particularly limited, but it is usually 60 to 95% by mass, preferably 70 to 90% by mass.
  • the skin cosmetic composition of the present invention may further contain other optional components to be blended in the skin care cosmetic composition.
  • the moisturizing and moisturizing effect of the skin can be enhanced by blending (f) a moisturizing agent.
  • a moisturizing agent glycerin (dynamite glycerin), 1,3-butylene glycol, dipropylene glycol, polyoxyethylene polyoxypropylene alkyl ether (however, except for those corresponding to the component (d)), hyaluronic acid or acetylated hyaluronic acid An acid and its salt etc. can be illustrated.
  • glycerin dipropylene glycol, polyoxyethylene polyoxypropylene alkyl (C1 to C3) ether (eg, polyoxyethylene (14) polyoxypropylene (7) dimethyl ether etc.), hyaluronic acid and acetylation It is preferable to combine and mix
  • diglycerin is blended, stickiness may occur upon drying after applying a cosmetic.
  • the skin cosmetic of the present invention By further blending the skin cosmetic of the present invention with (g) a cooling agent, it is possible to improve the feeling of coolness when applied to the skin and to give the skin a feeling of firmness.
  • the cooling agent to be blended is not particularly limited as long as it can be used as a cosmetic or a skin external preparation, and menthols such as l-menthol, camphors, borneols, etc. can be exemplified.
  • Examples of other optional components include, but are not limited to, emollients, ultraviolet light absorbers, various drugs, lower alcohols (alcohols having 6 or less carbon atoms), oils, inorganic and organic powders, and the like.
  • emollients ultraviolet light absorbers
  • various drugs lower alcohols (alcohols having 6 or less carbon atoms)
  • oils inorganic and organic powders, and the like.
  • it may be preferable to set the amount of oil to be 20% by mass or less, for example, 10% by mass or less or 5% by mass or less.
  • the skin cosmetic composition of the present invention is prepared by mixing each component and appropriately stirring and mixing while heating as necessary.
  • the skin cosmetic composition of the present invention contains a novel base which is aqueous but has a moderate hardness that gives rise to a plump on the skin, has a good fit when applied to the skin and does not feel sticky, and is a whitening agent or It is possible to give a feeling that the active ingredient such as a moisturizer rapidly penetrates to the keratin. Therefore, for example, it is preferable to provide as an all-in-one skin care cosmetic etc. having all the functions of conventional lotions, emulsions, masks, astringents and cosmetic solutions.
  • the present invention will be described in more detail by way of examples, but the present invention is not limited by these examples.
  • the compounding amount is shown as% by mass based on the total amount of the composition to which the component is compounded unless otherwise stated.
  • Skin cosmetics were prepared according to the formulations listed in Tables 1 and 2 below. About cosmetics (sample) of each case, pH value and viscosity measurement (B-type viscometer, No. 3, 12 rpm, 30 degreeC) were performed. In addition, the expert panel evaluated "hardness of cosmetic (sample)", “no stickiness” and “early familiarity”. Evaluation criteria are as follows.
  • Comparative Example 4 in which the blending amount of the (c) water-soluble polymer is less than 0.15% by mass is a soft cosmetic in which the viscosity of the cosmetic does not reach 3,000 mPa ⁇ s. As a result, it was difficult to take an appropriate amount from the container, and it did not become a base of hardness that stands on the skin.
  • Comparative Example 5 in which the blending amount of the carboxyvinyl polymer was large and the viscosity exceeded 10,000 mPa ⁇ s, the cosmetic was too hard to take out an appropriate amount from the container.
  • Prescription example 1 Display name Compounding amount (mass%) Ion exchange water remaining amount ethyl alcohol 10 Dynamite Glycerin 3.5 Dipropylene glycol 3 Acetylated sodium hyaluronate 0.0001 Sodium hyaluronate 0.0009 Polyethylene glycol 400 0.5 Polyoxyethylene (14) Polyoxypropylene (7) Dimethyl Ether 1.5 (Dimethylacrylamide / Acryloyldimethyltaurine Na) Crosspolymer 0.2 POP (13) POE (24) 2-decyl tetradecyl ether 0.1 Potassium hydroxide 0.04 Tranexamic acid 2 Glycylglycine 0.05 l-menthol 0.04 EDTA-2Na ⁇ 2H 2 O appropriate amount sodium pyrosulfite appropriate amount phenoxyethanol appropriate amount perfume appropriate amount total 100
  • Prescription example 2 Display name Compounding amount (mass%) Ion exchange water remaining amount ethyl alcohol 10 Dynamite Glycerin 3.5 Dipropylene glycol 3 Acetylated sodium hyaluronate 0.0001 Sodium hyaluronate 0.0009 Polyethylene glycol 400 0.5 Polyoxyethylene (14) Polyoxypropylene (7) Dimethyl Ether 1.5 Acrylic acid / methacrylic acid alkyl copolymer 0.3 POP (13) POE (24) 2-decyl tetradecyl ether 0.1 Potassium hydroxide 0.04 Tranexamic acid 2 Glycylglycine 0.05 l-menthol 0.04 EDTA-2Na ⁇ 2H 2 O appropriate amount sodium pyrosulfite appropriate amount phenoxyethanol appropriate amount perfume appropriate amount total 100
  • Prescription example 3 Display name Compounding amount (mass%) Ion exchange water remaining amount ethyl alcohol 10 Dynamite Glycerin 3.5 Dipropylene glycol 3 Acetylated sodium hyaluronate 0.0001 Sodium hyaluronate 0.0009 Polyethylene glycol 400 0.5 Polyoxyethylene (14) Polyoxypropylene (7) Dimethyl Ether 1.5 (Alkyl acrylate / Steareth-20 methacrylate) copolymer 0.9 POP (13) POE (24) 2-decyl tetradecyl ether 0.1 Potassium hydroxide 0.04 Tranexamic acid 2 Glycylglycine 0.05 l-menthol 0.04 Sodium lauryl sulfate appropriate amount EDTA-2Na ⁇ 2H 2 O appropriate amount sodium pyrosulfite appropriate amount phenoxyethanol appropriate amount fragrance appropriate amount total 100
  • Prescription example 4 Display name Compounding amount (mass%) Ion exchange water remaining amount ethyl alcohol 10 Dynamite Glycerin 3.5 Dipropylene glycol 3 Acetylated sodium hyaluronate 0.0001 Sodium hyaluronate 0.0009 Polyethylene glycol 400 1.5 Polyoxyethylene (14) Polyoxypropylene (7) Dimethyl Ether 1.5 (PEG-240 / decyltetradeces-20 / HDI) copolymer 1.5 POP (13) POE (24) 2-decyl tetradecyl ether 0.1 4-Methoxysalicylic acid potassium salt 1 Glycylglycine 0.05 l-menthol 0.04 EDTA-2Na ⁇ 2H 2 O appropriate amount sodium pyrosulfite appropriate amount phenoxyethanol appropriate amount perfume appropriate amount total 100

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
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Abstract

La présente invention a pour objet un nouveau produit cosmétique pour la peau dans lequel est mélangé un agent de blanchiment, qui a une dureté convenant pour la formation d'une boule gonflée ronde lorsqu'il est placé sur la peau, qui procure une sensation gélatineuse similaire à celle de la gelée et qui offre une excellente sensation de pénétration lorsqu'il est appliqué sur la peau. Ce produit cosmétique pour la peau est caractérisé en ce qu'il contient : (a) un agent de blanchiment qui est choisi entre l'acide tranexamique et le glucoside de l'acide ascorbique ; (b) un polyéthylèneglycol dans lequel un degré moyen de polymérisation de l'oxyde d'éthylène est de 4 à 20 ; (c) 0,15 % en masse ou plus d'un polymère hydrosoluble ; (d) un ou plusieurs composants choisis parmi les éthers alkyliques polyoxyéthyléniques/polyoxypropyléniques (en C18-C28) et les huiles de ricin hydrogénées polyoxyéthyléniques ; et (e) de l'eau, la viscosité du produit cosmétique pour la peau à 30°C étant dans la plage de 3 000 à 10 000 mPa·s.
PCT/JP2018/040926 2017-11-07 2018-11-05 Produit cosmétique pour la peau WO2019093254A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2019552769A JP7203751B2 (ja) 2017-11-07 2018-11-05 皮膚化粧料

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JP2017214390 2017-11-07
JP2017-214390 2017-11-07

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WO2019093254A1 true WO2019093254A1 (fr) 2019-05-16

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Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002284664A (ja) * 2001-03-29 2002-10-03 Shiseido Co Ltd 美白用皮膚外用剤
JP2004091360A (ja) * 2002-08-30 2004-03-25 Kanebo Ltd 化粧料
JP2005120051A (ja) * 2003-10-20 2005-05-12 Shiseido Co Ltd 皮膚外用剤
JP2005206464A (ja) * 2004-01-19 2005-08-04 Kao Corp シェービング剤組成物
JP2006282603A (ja) * 2005-04-01 2006-10-19 Kanebo Home Products Kk 化粧料
JP2008007430A (ja) * 2006-06-27 2008-01-17 Kracie Home Products Kk ゲル状化粧料及びその製造方法
JP2009286757A (ja) * 2008-05-30 2009-12-10 Shiseido Co Ltd 水中油型皮膚外用剤
WO2010113930A1 (fr) * 2009-03-31 2010-10-07 株式会社資生堂 Préparation externe pour la peau
JP2014065692A (ja) * 2012-09-27 2014-04-17 Mandom Corp ジェル状皮膚用化粧料
JP2015040180A (ja) * 2013-08-20 2015-03-02 株式会社マンダム シェービング用ジェル状組成物

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002284664A (ja) * 2001-03-29 2002-10-03 Shiseido Co Ltd 美白用皮膚外用剤
JP2004091360A (ja) * 2002-08-30 2004-03-25 Kanebo Ltd 化粧料
JP2005120051A (ja) * 2003-10-20 2005-05-12 Shiseido Co Ltd 皮膚外用剤
JP2005206464A (ja) * 2004-01-19 2005-08-04 Kao Corp シェービング剤組成物
JP2006282603A (ja) * 2005-04-01 2006-10-19 Kanebo Home Products Kk 化粧料
JP2008007430A (ja) * 2006-06-27 2008-01-17 Kracie Home Products Kk ゲル状化粧料及びその製造方法
JP2009286757A (ja) * 2008-05-30 2009-12-10 Shiseido Co Ltd 水中油型皮膚外用剤
WO2010113930A1 (fr) * 2009-03-31 2010-10-07 株式会社資生堂 Préparation externe pour la peau
JP2014065692A (ja) * 2012-09-27 2014-04-17 Mandom Corp ジェル状皮膚用化粧料
JP2015040180A (ja) * 2013-08-20 2015-03-02 株式会社マンダム シェービング用ジェル状組成物

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JP7203751B2 (ja) 2023-01-13
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