WO2019066374A3 - 폴리우레탄 매트릭스 수지와의 접착성 및 인장강도가 우수한 아라미드 직물, 그의 제조방법, 이를 포함하는 아라미드 직물 프리프레그 및 이를 포함하는 아라미드 직물 / 열가소성 폴리우레탄 수지 복합재 - Google Patents

폴리우레탄 매트릭스 수지와의 접착성 및 인장강도가 우수한 아라미드 직물, 그의 제조방법, 이를 포함하는 아라미드 직물 프리프레그 및 이를 포함하는 아라미드 직물 / 열가소성 폴리우레탄 수지 복합재 Download PDF

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Publication number
WO2019066374A3
WO2019066374A3 PCT/KR2018/011106 KR2018011106W WO2019066374A3 WO 2019066374 A3 WO2019066374 A3 WO 2019066374A3 KR 2018011106 W KR2018011106 W KR 2018011106W WO 2019066374 A3 WO2019066374 A3 WO 2019066374A3
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WIPO (PCT)
Prior art keywords
aramid fabric
aramid
same
matrix resin
fabric
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Application number
PCT/KR2018/011106
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English (en)
French (fr)
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WO2019066374A2 (ko
Inventor
박현정
양지은
윤상준
Original Assignee
코오롱인더스트리(주)
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Publication date
Application filed by 코오롱인더스트리(주) filed Critical 코오롱인더스트리(주)
Priority to JP2020512417A priority Critical patent/JP6862609B2/ja
Priority to EP18860886.3A priority patent/EP3647025B1/en
Priority to CN201880063229.6A priority patent/CN111183019B/zh
Priority to US16/640,473 priority patent/US11491742B2/en
Publication of WO2019066374A2 publication Critical patent/WO2019066374A2/ko
Publication of WO2019066374A3 publication Critical patent/WO2019066374A3/ko

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    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06Fibrous reinforcements only
    • B29C70/10Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
    • B29C70/16Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length
    • B29C70/22Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length oriented in at least two directions forming a two dimensional structure
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B29B15/12Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
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    • B29C70/34Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and shaping or impregnating by compression, i.e. combined with compressing after the lay-up operation
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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
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  • Chemical Kinetics & Catalysis (AREA)
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  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Woven Fabrics (AREA)
  • Reinforced Plastic Materials (AREA)
  • Laminated Bodies (AREA)
  • Moulding By Coating Moulds (AREA)

Abstract

(i) 아라미드 원사를 경사 및 위사로 사용하여 바스켓 조직의 아라미드 직물을 제직한 다음, (ii) 제직된 아라미드 직물을 호제인 수계 폴리우레탄 수지와 물로 이루어진 호제액에 침지한 후 압착 및 건조하여 폴리우레탄 매트릭스 수지와의 접착성 및 인장강도가 우수한 아라미드 직물을 제조한다. 본 발명은 제직된 아라미드 직물에 호제를 부여해 주기 때문에 제직전 아라미드 원사에 호제를 부여해 주는 방법과 비교시 제직 중 호제탈락으로 인한 제직효율 저하를 효과적으로 방지할 수 있다. 또한, 본 발명은 아라미드 직물의 표면 및 내부에 수계 폴리우레탄 수지를 부착 및 함침시켜 주기 때문에 폴리우레탄 매트릭스 수지와의 접착성이 향상되고, 아라미드 직물내 아라미드 원사들의 집속성이 높아져 아라미드 직물의 인장강도가 향상된다. 또한, 본 발명은 바스켓 조직으로 아라미드 직물을 제직하기 때문에 아라미드 직물의 치밀성이 낮아져 폴리우레탄 매트릭스 수지와의 젖음성(Wetting property)이 좋아져 결과적으로는 아라미드 직물과 폴리우레탄 매트릭스 수지 간의 접착력이 향상된다. 그로 인해, 본원발명의 아라미드 직물/열가소성 폴리우레탄 수지 복합재는 자동차 범퍼 등과 같이 내충격성이 요구되는 자동차 부품 소재 또는 전자부품소재 등으로 유용하다.
PCT/KR2018/011106 2017-09-28 2018-09-20 폴리우레탄 매트릭스 수지와의 접착성 및 인장강도가 우수한 아라미드 직물, 그의 제조방법, 이를 포함하는 아라미드 직물 프리프레그 및 이를 포함하는 아라미드 직물 / 열가소성 폴리우레탄 수지 복합재 WO2019066374A2 (ko)

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JP2020512417A JP6862609B2 (ja) 2017-09-28 2018-09-20 ポリウレタンマトリックス樹脂との接着性および引張強度に優れたアラミド織物、その製造方法、これを含むアラミド織物プリプレグ、並びにこれを含むアラミド織物/熱可塑性ポリウレタン樹脂複合材
EP18860886.3A EP3647025B1 (en) 2017-09-28 2018-09-20 Aramid fabric having excellent adhesion to polyurethane matrix resin and excellent tensile strength, method for producing same, aramid fabric prepreg comprising same, and aramid fabric/thermoplastic polyurethane matrix resin composite comprising same
CN201880063229.6A CN111183019B (zh) 2017-09-28 2018-09-20 芳纶织物、芳纶织物制备方法、芳纶织物预浸料、芳纶织物/热塑性聚氨酯基体树脂复合物
US16/640,473 US11491742B2 (en) 2017-09-28 2018-09-20 Aramid fabric having excellent adhesion to polyurethane matrix resin and excellent tensile strength, method for producing same, aramid fabric prepreg comprising same and aramid fabric/thermoplastic polyurethane matrix resin composite comprising same

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