WO2018196334A1 - 一种真空玻璃产品 - Google Patents
一种真空玻璃产品 Download PDFInfo
- Publication number
- WO2018196334A1 WO2018196334A1 PCT/CN2017/110309 CN2017110309W WO2018196334A1 WO 2018196334 A1 WO2018196334 A1 WO 2018196334A1 CN 2017110309 W CN2017110309 W CN 2017110309W WO 2018196334 A1 WO2018196334 A1 WO 2018196334A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- glass substrate
- metal layer
- vacuum
- glass
- sealing structure
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
- C03C27/06—Joining glass to glass by processes other than fusing
- C03C27/08—Joining glass to glass by processes other than fusing with the aid of intervening metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K1/00—Soldering, e.g. brazing, or unsoldering
- B23K1/0008—Soldering, e.g. brazing, or unsoldering specially adapted for particular articles or work
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K1/00—Soldering, e.g. brazing, or unsoldering
- B23K1/002—Soldering by means of induction heating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K1/00—Soldering, e.g. brazing, or unsoldering
- B23K1/19—Soldering, e.g. brazing, or unsoldering taking account of the properties of the materials to be soldered
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B23/00—Re-forming shaped glass
- C03B23/20—Uniting glass pieces by fusing without substantial reshaping
- C03B23/24—Making hollow glass sheets or bricks
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B23/00—Re-forming shaped glass
- C03B23/20—Uniting glass pieces by fusing without substantial reshaping
- C03B23/24—Making hollow glass sheets or bricks
- C03B23/245—Hollow glass sheets
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
- C03C27/06—Joining glass to glass by processes other than fusing
- C03C27/10—Joining glass to glass by processes other than fusing with the aid of adhesive specially adapted for that purpose
-
- E—FIXED CONSTRUCTIONS
- E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
- E06B3/00—Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
- E06B3/66—Units comprising two or more parallel glass or like panes permanently secured together
-
- E—FIXED CONSTRUCTIONS
- E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
- E06B3/00—Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
- E06B3/66—Units comprising two or more parallel glass or like panes permanently secured together
- E06B3/6612—Evacuated glazing units
-
- E—FIXED CONSTRUCTIONS
- E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
- E06B3/00—Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
- E06B3/66—Units comprising two or more parallel glass or like panes permanently secured together
- E06B3/663—Elements for spacing panes
- E06B3/66309—Section members positioned at the edges of the glazing unit
- E06B3/66342—Section members positioned at the edges of the glazing unit characterised by their sealed connection to the panes
- E06B3/66357—Soldered connections or the like
-
- E—FIXED CONSTRUCTIONS
- E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
- E06B3/00—Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
- E06B3/66—Units comprising two or more parallel glass or like panes permanently secured together
- E06B3/673—Assembling the units
- E06B3/67326—Assembling spacer elements with the panes
- E06B3/67334—Assembling spacer elements with the panes by soldering; Preparing the panes therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2103/00—Materials to be soldered, welded or cut
- B23K2103/50—Inorganic material, e.g. metals, not provided for in B23K2103/02 – B23K2103/26
- B23K2103/54—Glass
-
- E—FIXED CONSTRUCTIONS
- E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
- E06B3/00—Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
- E06B3/66—Units comprising two or more parallel glass or like panes permanently secured together
- E06B3/663—Elements for spacing panes
- E06B3/66309—Section members positioned at the edges of the glazing unit
- E06B3/66333—Section members positioned at the edges of the glazing unit of unusual substances, e.g. wood or other fibrous materials, glass or other transparent materials
- E06B2003/66338—Section members positioned at the edges of the glazing unit of unusual substances, e.g. wood or other fibrous materials, glass or other transparent materials of glass
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/24—Structural elements or technologies for improving thermal insulation
- Y02A30/249—Glazing, e.g. vacuum glazing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B80/00—Architectural or constructional elements improving the thermal performance of buildings
- Y02B80/22—Glazing, e.g. vaccum glazing
Definitions
- the invention relates to the field of vacuum glass technology, in particular to a vacuum glass product.
- Vacuum glass is an emerging glass category, generally composed of two pieces of glass. It is a vacuum layer between two pieces of glass. Due to the existence of this vacuum layer, vacuum glass has good performance in sound insulation, heat insulation and anti-condensation. Performance is also more in line with the country's development requirements for energy conservation and environmental protection.
- the sealing quality of vacuum glass directly affects the performance of vacuum glass.
- the sealing of vacuum glass mainly adopts two methods: one is to seal with low glass powder, and the other is to seal with metal.
- the metal is used for sealing, the metal layer is first prepared at the edge of the opposite surface of the two glass substrates, and then the brazing process is used to firmly connect the metal layer and the solder, thereby achieving airtight sealing of the two glass substrates. .
- the brazing material can be heated by high frequency induction heating, and the high frequency induction welding head is coiled by the high frequency induction coil.
- the center line of the high-frequency induction welding head is aligned with the center line of the welding strip, and the high-frequency induction welding head advances at a constant speed along the center line of the welding belt, thereby achieving gas-tight welding around the vacuum glass.
- the metal layer in the sealing region is heated during operation of the high frequency induction soldering tip.
- the glass substrate often has a phenomenon in which the metal layer 3 is over-fired in the corner region 5, so that the bonding strength between the metal layer 3 and the glass substrate is greatly reduced.
- the metal layer is a silver film layer sintered on a glass substrate
- silver in the silver film in the corner region of the glass substrate is melted into the brazing material with excessive heating, so that the vacuum glass produced at the corner portion is welded.
- the sharp drop has affected the reliability and service life of vacuum glass welding.
- the inventors have found that the high-frequency induction welding head must have a process of deceleration-direction-acceleration at the corner region, and therefore, the vacuum
- the induction heating time of the inner corner of the glass corner area is too long, and the heating speed of the edge of the metal layer during heating is significantly greater than the heating speed of the center of the metal layer, which is the main cause of overburning of the metal layer in the corner area, the corner area
- the inner corners are particularly hot.
- the inductive power of the layer prevents the over-burning of the metal layer in the corner area.
- a way of changing the relative position of the running track of the center of the high-frequency induction welding head to the center line of the width direction of the metal layer is to change the shape of the metal layer so that the inner and outer edges of the metal layer in the corner area are curved.
- the high-frequency induction welding head walks in the center line of the width direction of the metal layer when running in the corner area, thereby avoiding the problem of over-burning of the metal layer in the corner area.
- a vacuum glass product can be obtained based on the above sealing method.
- the structure of the vacuum glass product is as follows:
- a vacuum glass product comprising:
- a sealing structure disposed between the first glass substrate and the second glass substrate and adjacent to edges of the first glass substrate and the second glass substrate for airtightly bonding the first glass substrate and the second glass substrate Forming a vacuum lumen;
- the sealing structure includes: a metal layer respectively fixed on opposite faces of the first glass substrate and the second glass substrate; and an intermediate solder layer connecting the two metal layers; the metal layer is in a corner region of the glass substrate Curved transition structure.
- the two metal layers and the intermediate solder layer are matched in width.
- an air suction port is disposed on the first glass substrate or the second glass substrate.
- a gas adsorbent for absorbing residual gas is disposed in the vacuum chamber.
- the metal layer is sintered on the first glass substrate and the second glass substrate by a metal paste, respectively.
- the straight line segment of the metal layer has a width d
- the arc radius of the inner edge of the metal layer is r
- the straight section of the metal layer has a width of 8 mm, the arc radius of the metal layer at the inner edge of the corner region is 3 mm, and the radius of the metal layer at the outer edge of the corner region is 11 mm.
- the invention changes the shape of the sealing structure in the corner region of the glass substrate, and replaces the chamfer with an arc excessively, so that in the induction welding, the time for repeatedly heating the inner corner portion of the welding strip is reduced, so that the welding strip is more uniformly heated in the corner region, thereby obtaining a seal.
- FIG. 1 is a schematic view of a vacuum glass ribbon in the prior art
- FIG. 2 is a schematic structural view of a rectangular vacuum glass
- Figure 3 is a side seal structure diagram of a vacuum glass product
- Figure 4 is a schematic structural view of a triangular vacuum glass
- 1 glass substrate 1 supports, 3 metal layers, 4 arc-shaped transition structures, 5 corner regions, 6 first glass substrate, 7 first metal layer, 8 intermediate solder layer, 9 second metal layer, 10 Two glass substrates, 11 vacuum chambers, 12 sealed structure.
- spatially relative terms such as “upper”, “lower”, “left”, “right”, etc. may be used herein to describe the relationship of one element or feature shown in the figure to another element or feature. . It will be understood that the spatial terms are intended to encompass different orientations of the device in use or operation. For example, elements in the “a” or “an” Thus, the exemplary term “lower” can encompass both an s. The device may be otherwise positioned (rotated 90 degrees or at other orientations), and the relative description of the space used herein may be interpreted accordingly.
- the vacuum glass product of the present embodiment includes: a first glass substrate 6 and a second glass substrate 10 each having a rectangular shape, and the first glass substrate 6 and the second glass substrate 10 are stacked on top of each other.
- An air suction port is provided on the first glass substrate 6 or the second glass substrate 10.
- a sealing structure is disposed between the first glass substrate 6 and the second glass substrate 10, the sealing structure is disposed near an edge of the first glass substrate 6 and the second glass substrate 10, and the sealing structure 12 is used for the first glass substrate 6 and the
- the two glass substrates 6 are hermetically bonded to form a vacuum chamber 11.
- a vacuum chamber is disposed in the vacuum chamber 11 and is provided with a gas adsorbent for collecting residual gas, and a plurality of supports 2 for receiving the first glass substrate 6 and the second glass. The pressure of the substrate 10.
- the sealing structure 12 is specifically: a first metal layer 7, an intermediate solder layer 8 and a second metal layer 9, the first metal layer 7, the second metal layer 9 and the intermediate solder layer 8 are matched in width, wherein the first metal The layer 7 is fixed on the lower surface of the first glass substrate 6 by a sintering process by a metal paste, and the second metal layer 9 is fixed on the upper surface of the second glass substrate 9 by a metal paste by a sintering process, and the intermediate solder layer 8 The first metal layer 7 and the second metal layer 9 are welded by a high frequency induction head.
- the sealing structure 12 has an arcuate transition structure 4 at a corner region of the glass substrate.
- the width is 8 mm, the radius of the metal layer at the inner edge of the corner region is 3 mm, and the radius of the metal layer at the outer edge of the corner region is 11 mm.
- the structure of the embodiment is substantially the same as that of the embodiment 1, except that the first glass substrate 6 and the second glass substrate 10 in the embodiment are triangular in shape, and the finished glass product is Vacuum glass with a triangle.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Joining Of Glass To Other Materials (AREA)
- Securing Of Glass Panes Or The Like (AREA)
- Manufacture Of Electron Tubes, Discharge Lamp Vessels, Lead-In Wires, And The Like (AREA)
Abstract
Description
Claims (7)
- 一种真空玻璃产品,所述真空玻璃产品包括:第一玻璃基板;与所述第一玻璃基板相对放置的第二玻璃基板;密封结构,设置在第一玻璃基板和所述第二玻璃基板之间,且靠近第一玻璃基板和第二玻璃基板的边缘处,用于将第一玻璃基板和第二玻璃基板气密结合,形成真空内腔;支撑物,设置在所述真空内腔中,用于承受第一玻璃基板和第二玻璃基板的压力;其特征在于,其中,所述密封结构包括:分别固结在第一玻璃基板和第二玻璃基板相向面上的金属层,以及连接两个所述金属层的中间焊料层;所述金属层在玻璃基板的拐角区域呈弧形过渡结构。
- 如权利要求1所述的真空玻璃产品,其特征在于,两个所述金属层和所述中间焊料层在宽度上相匹配。
- 如权利要求1所述的真空玻璃产品,其特征在于,所述第一玻璃基板或所述第二玻璃基板上设置有抽气口。
- 如权利要求1所述的真空玻璃产品,其特征在于,所述真空内腔中设置有用于吸收残余气体的气体吸附剂。
- 如权利要求1所述的真空玻璃产品,其特征在于,所述金属层由金属浆料分别烧结在所述第一玻璃基板和所述第二玻璃基板上。
- 如权利要求1所述的真空玻璃产品,其特征在于,所述金属层直线段的宽度为d,金属层在拐角区域内缘的弧形半径为r,金属层在拐角区域外缘的弧形半径为R,其中,d=R-r。
- 如权利要求1所述的真空玻璃产品,其特征在于,所述金属层直线段的宽度为8mm,金属层在拐角区域内缘的弧形半径为3mm,金属层在拐角区域外缘的弧形半径为11mm。
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2017412184A AU2017412184B2 (en) | 2017-04-26 | 2017-11-10 | Vacuum glass product |
EP17908035.3A EP3584231A4 (en) | 2017-04-26 | 2017-11-10 | VACUUM GLASS PRODUCT |
CA3056172A CA3056172C (en) | 2017-04-26 | 2017-11-10 | Vacuum insulated glass product |
JP2019557858A JP7023982B2 (ja) | 2017-04-26 | 2017-11-10 | 真空ガラス製品 |
KR1020197033453A KR102360064B1 (ko) | 2017-04-26 | 2017-11-10 | 진공 유리 제품 |
RU2019136434A RU2736249C1 (ru) | 2017-04-26 | 2017-11-10 | Изделие в виде вакуумного стеклопакета |
US16/607,178 US11459814B2 (en) | 2017-04-26 | 2017-11-10 | Vacuum insulated glass product |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710282659 | 2017-04-26 | ||
CN201710282659.4 | 2017-04-26 | ||
CN201720920604.7U CN207002586U (zh) | 2017-04-26 | 2017-07-27 | 一种真空玻璃产品 |
CN201720920604.7 | 2017-07-27 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2018196334A1 true WO2018196334A1 (zh) | 2018-11-01 |
Family
ID=60430289
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CN2017/110309 WO2018196334A1 (zh) | 2017-04-26 | 2017-11-10 | 一种真空玻璃产品 |
PCT/CN2018/081812 WO2018196570A1 (zh) | 2017-04-26 | 2018-04-04 | 一种真空玻璃的感应加热焊接方法 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CN2018/081812 WO2018196570A1 (zh) | 2017-04-26 | 2018-04-04 | 一种真空玻璃的感应加热焊接方法 |
Country Status (9)
Country | Link |
---|---|
US (2) | US11459814B2 (zh) |
EP (2) | EP3584231A4 (zh) |
JP (2) | JP7023982B2 (zh) |
KR (2) | KR102360064B1 (zh) |
CN (2) | CN207002586U (zh) |
AU (2) | AU2017412184B2 (zh) |
CA (2) | CA3056172C (zh) |
RU (2) | RU2736249C1 (zh) |
WO (2) | WO2018196334A1 (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115745429A (zh) * | 2022-11-23 | 2023-03-07 | 四川零零昊科技有限公司 | 真空玻璃在线封口系统、在线封口方法和连续生产系统 |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN207002586U (zh) * | 2017-04-26 | 2018-02-13 | 洛阳兰迪玻璃机器股份有限公司 | 一种真空玻璃产品 |
CN109494196B (zh) * | 2018-12-21 | 2021-01-01 | 西安赛尔电子材料科技有限公司 | 一种高硅铝合金封装外壳及其制作方法 |
CN114735952A (zh) * | 2021-01-08 | 2022-07-12 | 洛阳兰迪玻璃机器股份有限公司 | 真空玻璃封接方法及真空玻璃、真空玻璃封接用焊料带 |
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US11384593B2 (en) | 2022-07-12 |
CN207002586U (zh) | 2018-02-13 |
CN107417140A (zh) | 2017-12-01 |
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CA3056164C (en) | 2021-11-09 |
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CA3056172A1 (en) | 2018-11-01 |
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WO2018196570A1 (zh) | 2018-11-01 |
JP2020517568A (ja) | 2020-06-18 |
KR102216059B1 (ko) | 2021-02-16 |
AU2018259536A1 (en) | 2019-11-07 |
EP3584232A4 (en) | 2020-04-08 |
AU2017412184A1 (en) | 2019-11-07 |
AU2018259536B2 (en) | 2020-08-13 |
JP6902624B2 (ja) | 2021-07-14 |
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US11459814B2 (en) | 2022-10-04 |
CA3056172C (en) | 2022-08-30 |
AU2017412184B2 (en) | 2020-12-10 |
EP3584231A1 (en) | 2019-12-25 |
EP3584232A1 (en) | 2019-12-25 |
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CA3056164A1 (en) | 2018-11-01 |
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