WO2018025716A1 - 積層フィルム - Google Patents

積層フィルム Download PDF

Info

Publication number
WO2018025716A1
WO2018025716A1 PCT/JP2017/026999 JP2017026999W WO2018025716A1 WO 2018025716 A1 WO2018025716 A1 WO 2018025716A1 JP 2017026999 W JP2017026999 W JP 2017026999W WO 2018025716 A1 WO2018025716 A1 WO 2018025716A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
film
resin
polarizer
adhesive
Prior art date
Application number
PCT/JP2017/026999
Other languages
English (en)
French (fr)
Japanese (ja)
Inventor
将司 藤長
Original Assignee
住友化学株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 住友化学株式会社 filed Critical 住友化学株式会社
Priority to CN201780047899.4A priority Critical patent/CN109564316A/zh
Priority to KR1020197006293A priority patent/KR20190035848A/ko
Publication of WO2018025716A1 publication Critical patent/WO2018025716A1/ja

Links

Images

Classifications

    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/30—Polarising elements
    • G02B5/3025—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
    • G02B5/3033—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid
    • G02B5/3041—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid comprising multiple thin layers, e.g. multilayer stacks
    • G02B5/305—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid comprising multiple thin layers, e.g. multilayer stacks including organic materials, e.g. polymeric layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/22—Layered products comprising a layer of synthetic resin characterised by the use of special additives using plasticisers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J201/00—Adhesives based on unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J201/00—Adhesives based on unspecified macromolecular compounds
    • C09J201/02—Adhesives based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
    • C09J201/06—Adhesives based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing oxygen atoms
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/30—Polarising elements
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/30—Polarising elements
    • G02B5/3025—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/42—Polarizing, birefringent, filtering

Definitions

  • the present invention relates to a laminated film.
  • a polarizing plate has been widely used as a polarized light supplying element and a polarized light detecting element in a display device such as a liquid crystal display device.
  • a polarizing plate having a configuration in which a protective film is bonded to one side or both sides of a polarizing film (polarizer layer) using an adhesive or the like is known.
  • a film made of a polyvinyl alcohol-based resin in which a dichroic dye such as iodine is oriented is known.
  • Iodine in the polarizing film exists as an iodine complex, and the iodine complex itself is oriented depending on the orientation of the polyvinyl alcohol resin. It is known that this iodine complex absorbs light in the visible region, so that the polarizing film exhibits polarization characteristics (polarization degree).
  • optical layers such as a phase difference plate and an optical compensation film having optical properties are provided on a polarizing film provided with a protective film, if necessary.
  • the optical layer may contain an additive such as a plasticizer for the purpose of improving the performance of the film.
  • the present invention has been made in view of such circumstances, and an object of the present invention is to provide a laminated film that can maintain a high degree of polarization even in a humid heat environment.
  • the present inventors have transferred the plasticizer contained in the optical layer to the polarizing film in a humid heat environment and reacted with the iodine complex contributing to the polarization. It was estimated that the degree of polarization of the resulting polarizing plate was reduced by the disappearance of the iodine complex.
  • the water contact angle on the surface of the adhesive layer is larger than 60 °, so that the migration of the plasticizer to the polarizing film can be suppressed.
  • the present invention has been completed.
  • One embodiment of the present invention is a material for forming a polarizer film in which a dichroic dye is oriented in a polyvinyl alcohol resin, and a resin film having a slow axis in a direction oblique to the absorption axis of the polarizer layer A resin layer, and an adhesive layer that adheres the polarizer layer and the resin layer, the resin layer includes a plasticizer, and the adhesive layer has a water contact angle on the surface of the adhesive layer, Provide a laminated film greater than 60 °.
  • both the polarizer layer and the resin layer may be long.
  • a laminated film capable of maintaining a high degree of polarization even in a humid heat environment is provided.
  • FIG. 1 is a schematic cross-sectional view showing an example of the layer configuration of the laminated film of the present embodiment.
  • the laminated film 1 of this embodiment includes a polarizer layer 11, a resin layer 21, and an adhesive layer 31 that bonds the polarizer layer 11 and the resin layer 21.
  • a protective film may be further laminated on the side of the polarizer layer 11 opposite to the resin layer 21.
  • the laminated film of the present embodiment may be long or may be a sheet obtained by cutting the long laminated film into a predetermined length.
  • the long laminated film includes a long polarizer layer and a long resin layer. The long polarizer layer and the long resin layer will be described later.
  • a polarizer layer refers to an optical film having the property of absorbing linearly polarized light having a vibration plane parallel to the optical axis and transmitting linearly polarized light having a vibration plane perpendicular to the optical axis.
  • the polarizer layer 11 of this embodiment is a film in which a dichroic dye is oriented in a polyvinyl alcohol-based resin (hereinafter sometimes referred to as “PVA-based resin”).
  • the thickness of the polarizer layer 11 is preferably 30 ⁇ m or less, more preferably 25 ⁇ m or less, further preferably 15 ⁇ m or less, particularly preferably 10 ⁇ m or less, and particularly preferably 7 ⁇ m or less. preferable.
  • the polarizer layer 11 When the polarizer layer 11 is a film in which a dichroic dye is oriented in a PVA-based resin, the polarizer layer 11 may be obtained by stretching a film original containing the PVA-based resin. When the thickness of the polarizer layer 11 is 7 ⁇ m or less, the polarizer layer 11 may be obtained by stretching a coating film containing a PVA-based resin formed on the substrate together with the substrate, and then peeling the substrate.
  • Examples of the substrate that may be used in the present embodiment include a polypropylene film, a polyethylene terephthalate film, a polycarbonate film, a triacetyl cellulose film, a norbornene film, a polyester film, and a polystyrene film.
  • Examples of the PVA resin used in the present embodiment include a saponified polyvinyl acetate resin.
  • the polyvinyl acetate resin include polyvinyl acetate, which is a homopolymer of vinyl acetate, and copolymers of vinyl acetate and other monomers copolymerizable therewith.
  • Examples of other monomers copolymerizable with vinyl acetate include unsaturated carboxylic acids, olefins, vinyl ethers, unsaturated sulfonic acids, and acrylamides having ammonium groups.
  • the saponification degree of the PVA resin is preferably 80 mol% or more, more preferably 90 mol% or more and 99.5 mol% or less, and further preferably 94 mol% or more and 99 mol% or less. .
  • the degree of saponification is 80 mol% or more, the moisture and heat resistance of the resulting laminated film 1 is improved.
  • polarized-light performance as saponification degree is 99.5 mol% or less is obtained.
  • the PVA resin may be a modified polyvinyl alcohol partially modified.
  • olefin modification with ethylene, propylene, etc . unsaturated carboxylic acid modification with acrylic acid, methacrylic acid, crotonic acid, etc .
  • one modified with an alkyl ester of unsaturated carboxylic acid, acrylamide or the like may be used.
  • the rate of modification of the PVA resin is preferably less than 30 mol%, more preferably less than 10%.
  • the dichroic dye can be sufficiently adsorbed, and a polarizer having sufficient polarization performance can be obtained.
  • the average degree of polymerization of the PVA-based resin is preferably 100 or more and 10,000 or less, more preferably 1500 or more and 8000 or less, and further preferably 2000 or more and 5000 or less.
  • a polarizer having sufficient polarization performance can be obtained.
  • the average degree of polymerization is 10,000 or less, the solubility in a solvent becomes good, and the formation of a film containing a PVA resin is easy.
  • PVA-based resins can be easily obtained, and preferable examples of commercially available products are trade names, “PVA124” and “PVA117” (both saponification degrees) manufactured by Kuraray Co., Ltd. : 98 to 99 mol%), “PVA624" (degree of saponification: 95 to 96 mol%), “PVA617” (degree of saponification: 94.5 to 95.5 mol%); manufactured by Nippon Synthetic Chemical Industry Co., Ltd.
  • dichroic dye used in the present embodiment examples include iodine or a dichroic organic dye.
  • Dichroic organic dyes include Red BR, Red LR, Red R, Pink LB, Rubin BL, Bordeaux GS, Sky Blue LG, Lemon Yellow, Blue BR, Blue 2R, Navy RY, Green LG, Violet LB, Violet B , Black H, Black B, Black GSP, Yellow 3G, Yellow R, Orange LR, Orange 3R, Scarlet GL, Scarlet KGL, Congo Red, Brilliant Violet BK, Spura Blue G, Spura Blue GL, Spura Orange GL, Direct Sky Blue , Direct First Orange S, and First Black.
  • dichroic dye Only one type of dichroic dye may be used alone, or two or more types may be used in combination.
  • the resin layer 21 of the present embodiment uses a resin film having a slow axis in a direction oblique to the absorption axis of the polarizer layer 11 as a forming material.
  • a resin film can be manufactured through a stretching process, and the resin film is left with a tensile stress in a direction oblique to the absorption axis of the polarizer layer 11.
  • the residual stress remaining in the resin film can contribute to a decrease in the degree of polarization of the polarizing plate.
  • the resin layer 21 has a slow axis in a direction oblique to the absorption axis of the polarizer layer 11.
  • the angle of the slow axis is 45 ⁇ 10 ° or 135 with respect to the absorption axis of the polarizer layer 11. It is preferably ⁇ 10 °.
  • the difference between the light phase in the fast axis direction and the light phase in the slow axis direction is ⁇ / 2.
  • the phase difference between the fast axis and the slow axis is ⁇ / 2
  • the laminated film 1 of the present embodiment is applied to a display device, the light that has passed through the laminated film 1 can be made into circularly polarized light. . Therefore, even when viewed through a polarizing glass, a configuration with excellent visibility can be obtained.
  • the resin layer 21 of the present embodiment is preferably a retardation layer having retardation characteristics and wavelength dispersion characteristics that satisfy the following formulas (1) to (4).
  • the resin layer 21 satisfies the formulas (1) to (4), when the laminated film 1 of the present embodiment is incorporated into a display device, the screen is viewed from various directions (azimuth and polar angles) through the polarizing glass. It is possible to effectively suppress the color change when viewing the screen. Thereby, the visibility of the image display device can be improved.
  • R e (590), R e (450), R e (550), and R e (630) represent in-plane retardation values at measurement wavelengths of 590 nm, 450 nm, 550 nm, and 630 nm, respectively, and R th ( 590) represents a thickness direction retardation value at a measurement wavelength of 590 nm.
  • These in-plane retardation value and thickness direction retardation value are values measured in an environment of a temperature of 23 ° C. and a relative humidity of 55%.
  • Plane retardation value R e, and the thickness direction retardation value R th refraction of the refractive index in the in-plane slow axis direction n x, plane fast axis direction (perpendicular to the plane slow axis direction)
  • the rate is n y
  • the refractive index in the thickness direction is n z
  • the thickness of the optical film is d, it is defined by the following formulas (S1) and (S2).
  • R e (590) in the formula (1) is preferably 105 to 170 nm.
  • R th (590) / R e (590) in the formula (2) is preferably 0.6 to 0.75.
  • R e (450) / R e (550) is preferably 0.86 to 0.98.
  • R e (630) / R e (550) is preferably 1.01 to 1.06.
  • the resin layer 21 can be produced by stretching a film containing a resin described later.
  • the stretching treatment include uniaxial stretching and biaxial stretching.
  • the stretching direction examples include a machine flow direction (MD) of an unstretched film, a direction perpendicular to the machine flow direction (TD), and a direction oblique to the machine flow direction (MD).
  • MD machine flow direction
  • TD machine flow direction
  • MD machine flow direction
  • MD direction perpendicular to the machine flow direction
  • MD direction oblique to the machine flow direction
  • the unstretched film refers to a film that is not stretched.
  • uniaxial stretching an unstretched film is stretched in any one of these directions.
  • the biaxial stretching may be simultaneous biaxial stretching that simultaneously stretches in two stretching directions, or may be sequential biaxial stretching that stretches in another direction after stretching in a predetermined direction.
  • the stretching process for example, two or more pairs of nip rolls with increased peripheral speed on the outlet side are used to stretch in the longitudinal direction (machine flow direction: MD), or the both ends of the unstretched film are gripped with a chuck and machine flow is performed. It can be performed by spreading in a direction (TD) orthogonal to the direction.
  • the retardation value and the wavelength dispersion can be controlled within the ranges of the above formulas (1) to (4) by adjusting the thickness of the film or adjusting the draw ratio.
  • the chromatic dispersion value can be controlled within the range of the above formulas (3) to (4) by adding a chromatic dispersion adjusting agent to the resin.
  • a long polarizing film has an absorption axis in the long side direction.
  • the long resin layer and the long polarizer layer can be bonded by roll-to-roll, and the angle between the absorption axis and the slow axis of the resin layer is within the above range. It is preferable that the resin layer 21 is manufactured by being obliquely stretched by biaxial stretching.
  • Examples of the resin forming the resin film include cellulose acetate resin, cycloolefin resin, polyolefin resin, acrylic resin, polyimide resin, polycarbonate resin, and polyester resin.
  • the cellulose acetate resin is composed of a cellulose portion or a complete acetate ester.
  • Examples of the cellulose acetate resin include triacetyl cellulose and diacetyl cellulose.
  • a resin film made of a cellulose acetate resin can be easily obtained as a commercial product.
  • all of them are trade names of “Fujitac (registered)” sold by FUJIFILM Corporation. Trademarks) TD80 ",” Fujitac (registered trademark) TD80UF “and” Fujitac (registered trademark) TD80UZ ",” KC8UX2M “and” KC8UY "sold by Konica Minolta Opto Corporation.
  • the cycloolefin resin forming the resin film is, for example, a thermoplastic amorphous resin having a monomer unit composed of a cyclic olefin (cycloolefin) such as norbornene or a polycyclic norbornene monomer (non-crystalline polyolefin). Also called resin.)
  • the cycloolefin-based resin may be a hydrogenated product of the above-mentioned cycloolefin ring-opening polymer or a hydrogenated product of a ring-opening copolymer using two or more kinds of cycloolefins. It may be an addition copolymer with an olefin and / or an aromatic compound having a vinyl group. In addition, a polar group may be introduced.
  • a resin film is formed using a copolymer of a cycloolefin and a chain olefin and / or an aromatic compound having a vinyl group
  • chain olefin examples include ethylene and propylene.
  • aromatic compound having a vinyl group examples include styrene, ⁇ -methylstyrene, and nuclear alkyl-substituted styrene.
  • the unit of the monomer composed of cycloolefin may be 50 mol% or less, preferably 15 to 50 mol%.
  • the monomer unit composed of the cycloolefin can be used in a relatively small amount as described above.
  • the unit of monomer composed of a chain olefin is preferably 5 to 80 mol%.
  • the unit of the monomer composed of an aromatic compound having a vinyl group is preferably 5 to 80 mol%.
  • Cycloolefin-based resins can be easily obtained from commercial products, and preferable examples of commercially available products are all trade names, manufactured by TOPAS ADVANCED POLYMERS GmbH, sold in Japan by Polyplastics Co., Ltd. "TOPAS (registered trademark)”, “Arton (registered trademark)” sold by JSR Corporation, “ZEONOR (registered trademark)” and “ZEONEX” sold by ZEON Corporation ) (Registered trademark) ”,“ Apel (registered trademark) ”sold by Mitsui Chemicals, Inc., and the like.
  • the thickness of the retardation layer is preferably 10 ⁇ m or more and 50 ⁇ m or less.
  • the resin layer 21 of the present embodiment contains a plasticizer for the purpose of imparting flexibility to the resin film and facilitating stretching in addition to the resin forming the resin film.
  • the plasticizer include polyhydric alcohols such as ethylene glycol, glycerin, propylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, and trimethylolpropane.
  • the plasticizer may be used alone or in combination of two or more.
  • ethylene glycol and glycerin are preferably used.
  • the water contact angle on the surface of the adhesive layer 31 is larger than 60 °.
  • the affinity between the adhesive layer 31 and the plasticizer is lowered. Therefore, it is thought that the adhesive layer 31 is difficult for the plasticizer to enter.
  • a humid heat environment for example, an environment having a room temperature of 60 ° C. and a humidity of 95%). It is speculated that the penetration of the plasticizer can be suppressed.
  • the upper limit is not particularly limited, but may be 100 °.
  • a conventionally known measurement method can be used as the method for measuring the water contact angle.
  • Conventionally known measurement methods include the ⁇ / 2 method, the tangent method, the curve fitting method, the droplet method, the expansion / contraction method, the sliding method, the Wilhelmy method, the permeation rate method, and the like. Among these, in this embodiment, a droplet method is used.
  • the thickness of the adhesive layer 31 is preferably 0.01 ⁇ m or more and 5 ⁇ m or less, more preferably 0.01 ⁇ m or more and 2 ⁇ m or less, and further preferably 0.01 ⁇ m or more and 1 ⁇ m or less. Sufficient adhesiveness can be acquired as the thickness of the adhesive bond layer 31 is 0.01 micrometer or more. Moreover, when the thickness of the adhesive layer 31 is 5 ⁇ m or less, the laminated film 1 is unlikely to have a poor appearance.
  • the material for forming the adhesive layer 31 is not particularly limited as long as the water contact angle on the surface of the adhesive layer 31 is larger than 60 °, and a cured product of a known active energy ray-curable adhesive composition may be used. it can.
  • the “active energy ray-curable adhesive composition” refers to an adhesive composition that is cured by irradiation with active energy rays (for example, ultraviolet rays, visible light, electron beams, X-rays, etc.).
  • the adhesive layer 31 is formed so that the moisture permeability of an evaluation sample obtained by applying and curing the adhesive composition on a triacetyl cellulose film to a thickness of 2 to 3 ⁇ m is 300 g / m 2 ⁇ 24 hr or less. It is preferable to select one. Although the lower limit of moisture permeability is not particularly limited, it is, for example, 50 g / m 2 ⁇ 24 hr. By using an adhesive layer having such a moisture permeability, a decrease in polarization degree can be further reduced.
  • the evaluation sample can be produced as follows. First, the adhesive composition is applied on a triacetyl cellulose film so as to have a thickness of 2 to 3 ⁇ m to form an adhesive composition layer.
  • the triacetyl cellulose film for measuring the moisture permeability of the evaluation sample has a thickness of 57.5 ⁇ m and moisture permeability (value calculated by the cup method (JIS Z 0208, temperature 40 ° C., humidity 90% RH)). Is 553 g / m 2 ⁇ 24 hr.
  • ultraviolet rays are applied from the adhesive composition layer side so that the integrated light amount is 400 mJ / cm 2, and the adhesive composition layer is cured to obtain an evaluation sample.
  • the moisture permeability of the obtained evaluation sample was measured by a cup method (JIS Z 0208, temperature 40 ° C., humidity 90% RH).
  • the active energy ray-curable compound contained in the active energy ray-curable adhesive composition is a cationic polymerizable compound or a radical polymerizable compound. It is preferable to include a cationically polymerizable compound and a radically polymerizable compound.
  • the cationic polymerizable compound and the radical polymerizable compound are included, an effect of increasing the hardness of the adhesive layer 31 can be expected, and furthermore, adjustment of the viscosity, the curing rate, and the like of the present composition can be performed more easily.
  • Examples of the cationic polymerizable compound used in the present embodiment include an oxetane compound and an epoxy compound. From the viewpoint of making the water contact angle on the surface of the adhesive layer 31 larger than 60 °, it is preferable to use only an oxetane compound, or an oxetane compound and an epoxy compound.
  • the content of the cationically polymerizable compound is preferably 10 parts by mass or more and 99 parts by mass or less, and more preferably 40 parts by mass or more and 99 parts by mass or less with respect to 100 parts by mass of the present composition.
  • oxetane compounds include 1,4-bis [(3-ethyl-3-oxetanyl) methoxymethyl] benzene, 3-ethyl-3- (phenoxymethyl) oxetane, and di [(3-ethyl-3-oxetanyl) methyl]. And ether, 3-ethyl-3- (2-ethylhexyloxymethyl) oxetane, and the like.
  • the content of the oxetane compound is preferably 1 part by mass or more and 50 parts by mass or less, and more preferably 10 parts by mass or more and 40 parts by mass or less with respect to 100 parts by mass of the present composition.
  • the oxetane compound may be used alone or in combination of two or more.
  • the present composition may contain an epoxy compound as necessary.
  • the epoxy compound is one of cationically polymerizable compounds like the oxetane compound, and can be cured by irradiation with active energy rays.
  • this composition contains an epoxy compound, the adhesiveness of the resin layer 21 and the polarizer layer 11 can be improved.
  • Examples of the epoxy compound include an aromatic epoxy compound, a glycidyl ether of a polyol having an alicyclic ring, an aliphatic epoxy compound, and an alicyclic epoxy compound.
  • Aromatic epoxy compounds include bisphenol type epoxy resins such as diglycidyl ether of bisphenol A, diglycidyl ether of bisphenol F and diglycidyl ether of bisphenol S; phenol novolac epoxy resins, cresol novolac epoxy resins and hydroxybenzaldehyde phenol novolacs Examples thereof include novolak-type epoxy resins such as epoxy resins; glycidyl ethers of tetrahydroxyphenylmethane, glycidyl ethers of tetrahydroxybenzophenone, and polyfunctional epoxy resins such as epoxidized polyvinylphenol.
  • glycidyl ether of a polyol having an alicyclic ring a nuclear hydrogenated polyhydroxy compound obtained by selectively hydrogenating an aromatic polyol under pressure in the presence of a catalyst under pressure is used as a glycidyl ether.
  • aromatic polyols include bisphenol type compounds such as bisphenol A, bisphenol F, and bisphenol S; novolac type resins such as phenol novolac resin, cresol novolac resin, hydroxybenzaldehyde phenol novolac resin; tetrahydroxydiphenylmethane, tetrahydroxybenzophenone, A polyfunctional compound such as polyvinylphenol is exemplified.
  • Glycidyl ether can be obtained by reacting an alicyclic polyol obtained by hydrogenating the aromatic ring of these aromatic polyols with epichlorohydrin.
  • glycidyl ethers of polyols having an alicyclic ring hydrogenated bisphenol A diglycidyl ether is preferable.
  • Examples of the aliphatic epoxy compound include polyglycidyl ethers of aliphatic polyhydric alcohols or alkylene oxide adducts thereof. Specifically, 1,4-butanediol diglycidyl ether; 1,6-hexanediol diglycidyl ether; glycerin triglycidyl ether; trimethylolpropane triglycidyl ether; polyethylene glycol diglycidyl ether; propylene glycol Diglycidyl ether of neopentyl glycol; by adding one or more alkylene oxides (ethylene oxide or propylene oxide) to aliphatic polyhydric alcohols such as ethylene glycol, propylene glycol or glycerin
  • alkylene oxides ethylene oxide or propylene oxide
  • the monofunctional epoxy compound represented by following formula (I) is also mentioned as an aliphatic epoxy compound.
  • R 1 is an optionally branched alkyl group having 1 to 15 carbon atoms. The number of carbon atoms of the alkyl group is preferably 6 or more, more preferably 6 to 10. Of these, a branched alkyl group is preferred.
  • Examples of the monofunctional epoxy compound represented by the formula (I) include 2-ethylhexyl glycidyl ether.
  • An alicyclic epoxy compound refers to a compound having at least one structure in the molecule that forms an oxirane ring with carbon atoms of the alicyclic ring.
  • a structure in which an oxirane ring is formed together with a carbon atom of an alicyclic ring means a structure represented by the following formula (II).
  • N in the formula is an integer of 2 to 5.
  • a compound in which a group in a form in which one or a plurality of hydrogen atoms in (CH 2 ) n in formula (II) are removed is bonded to another chemical structure is an alicyclic epoxy compound.
  • One or more hydrogen atoms in (CH 2 ) n forming the alicyclic ring may be substituted with a linear alkyl group such as a methyl group or an ethyl group.
  • the content of the epoxy compound is preferably 1 part by mass or more and 90 parts by mass or less, and more preferably 20 parts by mass or more and 80 parts by mass or less with respect to 100 parts by mass of the present composition.
  • the epoxy compound may be used alone or in combination of two or more.
  • radical polymerizable compound in addition to the cationically polymerizable compound such as the oxetane compound or the epoxy compound, a radical polymerizable compound may be included.
  • radical polymerizable compound examples include a compound having at least one (meth) acryloyloxy group in the molecule (hereinafter sometimes referred to as “(meth) acrylic compound”), and at least one ( Examples thereof include compounds having a meth) acrylamide group (hereinafter sometimes referred to as “(meth) acrylamide compounds”).
  • the “(meth) acryloyloxy group” means a methacryloyloxy group or an acryloyloxy group
  • the (meth) acrylamide group means a methacryloylamide group or an acryloylamide group.
  • (Meth) acrylic compounds include (meth) acrylate monomers having at least one (meth) acryloyloxy group in the molecule and (meth) acrylates having at least two (meth) acryloyloxy groups in the molecule.
  • An oligomer etc. are mentioned. These may be used alone or in combination of two or more. When two or more types are used in combination, two or more (meth) acrylate monomers may be used, two or more (meth) acrylate oligomers may be used, and, of course, one or more (meth) acrylate monomers. One or more (meth) acrylate oligomers may be used in combination.
  • Examples of (meth) acrylamide compounds include N-substituted (meth) acrylamide compounds.
  • An N-substituted (meth) acrylamide compound is a (meth) acrylamide compound having a substituent at the N-position.
  • a typical example of the substituent is an alkyl group.
  • the N-position substituents may be bonded to each other to form a ring, and —CH 2 — constituting the ring may be substituted with an oxygen atom. Further, a substituent such as an alkyl group or an oxo group ( ⁇ O) may be bonded to the carbon atom constituting the ring.
  • N-substituted (meth) acrylamides can generally be prepared by reaction of (meth) acrylic acid or its chloride with a primary or secondary amine.
  • the content of the radically polymerizable compound is preferably 1 part by mass or more and 70 parts by mass or less, and more preferably 10 parts by mass or more and 60 parts by mass or less with respect to 100 parts by mass of the present composition.
  • the radically polymerizable compound may be used alone or in combination of two or more.
  • the cationic polymerization initiator When this composition contains cationically polymerizable compounds, such as the said oxetane compound and the said epoxy compound, it is preferable that the cationic polymerization initiator is further included.
  • the cationic polymerization initiator generates a cationic species or a Lewis acid by irradiation with active energy rays such as visible light, ultraviolet rays, X-rays, and electron beams, and initiates a polymerization reaction of the cationic polymerizable compound.
  • active energy rays such as visible light, ultraviolet rays, X-rays, and electron beams
  • the cationic polymerization initiator include aromatic diazonium salts, onium salts such as aromatic iodonium salts and aromatic sulfonium salts, and iron-arene complexes.
  • aromatic diazonium salt examples include benzenediazonium hexafluoroantimonate, benzenediazonium hexafluorophosphate, and benzenediazonium hexafluoroborate.
  • aromatic iodonium salt examples include diphenyliodonium tetrakis (pentafluorophenyl) borate, diphenyliodonium hexafluorophosphate, diphenyliodonium hexafluoroantimonate, di (4-nonylphenyl) iodonium hexafluorophosphate, and the like.
  • aromatic sulfonium salt examples include triphenylsulfonium hexafluorophosphate, triphenylsulfonium hexafluoroantimonate, triphenylsulfonium tetrakis (pentafluorophenyl) borate, 4,4′-bis [diphenylsulfonio] diphenyl sulfide bishexa Fluorophosphate, 4,4'-bis [di ( ⁇ -hydroxyethoxy) phenylsulfonio] diphenyl sulfide bishexafluoroantimonate, 4,4'-bis [di ( ⁇ -hydroxyethoxy) phenylsulfonio] diphenyl sulfide bis Hexafluorophosphate, 7- [di (p-toluyl) sulfonio] -2-isopropylthioxanthone hexafluoroantimonate
  • iron-arene complexes examples include xylene-cyclopentadienyl iron (II) hexafluoroantimonate, cumene-cyclopentadienyl iron (II) hexafluorophosphate, xylene-cyclopentadienyl iron (II) tris ( (Trifluoromethylsulfonyl) methanide and the like.
  • cationic polymerization initiators can be easily obtained as commercial products.
  • the aromatic sulfonium salt is capable of absorbing light having a wavelength of 300 nm or more, having excellent curability, and obtaining a cured product having good mechanical strength and adhesion. preferable.
  • the cationic polymerization initiator may be used alone or in combination of two or more.
  • radical polymerization initiator When this composition contains said radically polymerizable compound, it is preferable that the radical polymerization initiator is further included. Any radical polymerization initiator may be used as long as it can initiate polymerization of a radical polymerizable compound such as a (meth) acrylic compound by irradiation with active energy rays, and a known one can be used.
  • radical polymerization initiators examples include acetophenone, 3-methylacetophenone, benzyldimethyl ketal, 1- (4-isopropylphenyl) -2-hydroxy-2-methylpropan-1-one, 2-methyl-1- [4- ( Acetophenone initiators such as methylthio) phenyl-2-morpholinopropan-1-one and 2-hydroxy-2-methyl-1-phenylpropan-1-one; benzophenone, 4-chlorobenzophenone and 4,4′-diamino Benzophenone initiators such as benzophenone; benzoin ether initiators such as benzoin propyl ether and benzoin ethyl ether; thioxanthone initiators such as 4-isopropylthioxanthone; xanthone, fluorenone, camphorquinone Benzaldehyde, such as anthraquinone, and the like.
  • radical polymerization initiators can be easily obtained.
  • “Darocur (registered trademark)” manufactured by BASF are available.
  • Lucirin (registered trademark) TPO and the like.
  • the radical polymerization initiator may be used alone or in combination of two or more.
  • the present composition may contain a photosensitizer, a solvent, a leveling agent, an antioxidant, a light stabilizer, an ultraviolet absorber, and the like as long as the effects of the present invention are not impaired.
  • photosensitizers examples include carbonyl compounds, organic sulfur compounds, persulfides, redox compounds, azo compounds, diazo compounds, halogen compounds, and photoreductive dyes.
  • Examples of the solvent that may be used in the present embodiment include aliphatic hydrocarbons such as n-hexane and cyclohexane; aromatic hydrocarbons such as toluene and xylene; methanol, ethanol, propanol, isopropanol, and n- Alcohols such as butanol; ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone and cyclohexanone; esters such as methyl acetate, ethyl acetate and butyl acetate; cellosolves such as methyl cellosolve, ethyl cellosolve and butyl cellosolve; Halogenated hydrocarbons such as methylene and chloroform.
  • aliphatic hydrocarbons such as n-hexane and cyclohexane
  • aromatic hydrocarbons such as toluene and xylene
  • leveling agent that may be used in the present embodiment, various compounds such as silicone, fluorine, polyether, acrylic acid copolymer, and titanate can be used.
  • antioxidants examples include primary antioxidants such as phenols and amines, and sulfur-based secondary antioxidants.
  • Examples of the light stabilizer that may be used in the present embodiment include hindered amine light stabilizers (HALS).
  • HALS hindered amine light stabilizers
  • Examples of ultraviolet absorbers that may be used in this embodiment include benzophenone-based, benzotriazole-based, and benzoate-based compounds.
  • the adjustment of the contact angle of the adhesive layer can be performed, for example, according to the following guidelines. That is, the contact angle of the adhesive layer depends on the structure of the compound contained as a main component in the curable resin composition and the combination of the compounds. For example, when an adhesive layer is formed from a curable resin composition, if the composition contains a polar group such as a hydroxyl group or an amino group, the contact angle tends to be low, and if it does not contain a polar group, the contact angle Tend to be higher.
  • a polar group such as a hydroxyl group or an amino group
  • FIG. 2 is a schematic cross-sectional view showing a modification of the layer configuration of the laminated film of the present embodiment.
  • a protective film 23 can be further laminated on the side of the polarizer layer 11 opposite to the side where the resin layer 21 is laminated.
  • a material for forming the protective film 23 the same resin as the material for forming the resin layer 21 can be used.
  • the material forming the resin layer 21 and the material forming the protective film 23 may be the same or different.
  • the protective film 23 can be laminated on the polarizer layer 11 via the adhesive layer 33.
  • the adhesive layer 33 include a water-based adhesive and an active energy ray-curable adhesive.
  • the active energy ray-curable adhesive include a cationic polymerization-type active energy ray-curable adhesive and a radical polymerization-type active energy.
  • a line curable adhesive is mentioned.
  • An adhesive layer may be provided instead of the adhesive layer 33.
  • Examples of the pressure-sensitive adhesive layer include a pressure-sensitive adhesive containing an acrylic resin.
  • An adhesive layer may be provided on the side opposite to the surface of the polarizer layer 11 on which the resin layer 21 is laminated, or on the side of the protective film opposite to the surface on which the polarizer layer 11 is laminated.
  • the laminated film 2 can be bonded to the liquid crystal cell of the display device.
  • the pressure-sensitive adhesive layer include a pressure-sensitive adhesive containing an acrylic resin.
  • the laminated film of the present invention is preferably arranged on the viewing side of the liquid crystal cell.
  • the laminated film 1 of this embodiment is (I) A layer of an adhesive composition having a cured water contact angle larger than 60 ° on one surface of the resin layer 21 having a slow axis (hereinafter sometimes referred to as “adhesive composition layer”). Forming a step; (Ii) The polarizer layer 11 and the adhesive composition layer formed on the resin layer 21 in (i) above have a slow axis of 45 ⁇ 10 ° with respect to the absorption axis of the polarizer layer 11.
  • the laminate obtained in (ii) above is irradiated with active energy rays (for example, ultraviolet rays, visible light, electron beams, X-rays, etc.), and the adhesive composition layer is cured to form an adhesive layer 31.
  • active energy rays for example, ultraviolet rays, visible light, electron beams, X-rays, etc.
  • a resin layer 21 having a slow axis is prepared.
  • the elongated polarizer layer may have an absorption axis in the flow direction.
  • a laminate laminate (laminated film) can be produced by roll-to-roll, and both can be arranged so that the angle formed by the absorption axis and the slow axis of the resin layer 21 falls within the above range.
  • the resin layer 21 is preferably manufactured by being obliquely stretched.
  • Examples of the stretching machine used for the oblique stretching include a tenter type stretching machine.
  • the tenter type stretching machine can apply a feeding force, a pulling force or a pulling force at different speeds in the left and right directions in the horizontal direction or the vertical direction or in both directions.
  • Examples of such a tenter-type stretching machine include a horizontal uniaxial stretching machine and a simultaneous biaxial stretching machine. Any suitable stretching machine can be used as long as the resin film can be continuously stretched obliquely. it can.
  • the present composition As a method for forming the adhesive composition layer on one surface of the resin layer 21, there is a method in which the present composition is directly applied and dried as necessary. Further, as another method, there is a method in which the present composition is applied to a transparent substrate film, dried as necessary, and then transferred to the polarizer layer 11. In the latter case, the base film is removed before the step (ii). As the transparent base film, the same resin as described above is used. Moreover, in the transparent substrate film, the application surface of the present composition may be subjected to a peeling treatment in advance.
  • a coating method of the present composition a known coating method can be employed, and examples thereof include a doctor blade, a wire bar, a die coater, a comma coater, and a gravure coater.
  • the polarizer layer 11 and the adhesive composition layer formed on the resin layer 21 in (i) above are bonded together, and the polarizer layer 11, the adhesive composition layer, and the resin layer 21 are bonded together. Are stacked in this order.
  • the adhesive composition layer is formed by irradiating the laminate obtained in (ii) with active energy rays such as visible light, ultraviolet rays, X-rays, or electron beams. It hardens
  • active energy rays such as visible light, ultraviolet rays, X-rays, or electron beams. It hardens
  • the light source used for irradiation with active energy rays is not particularly limited, but a light source having a light emission distribution at a wavelength of 400 nm or less is used.
  • a light source having a light emission distribution at a wavelength of 400 nm or less is used.
  • Examples of such a light source include a low pressure mercury lamp, a medium pressure mercury lamp, a high pressure mercury lamp, an ultrahigh pressure mercury lamp, a chemical lamp, a black light lamp, a microwave excitation mercury lamp, and a metal halide lamp.
  • the irradiation intensity of the active energy ray varies depending on the adhesive composition to be cured, but it is preferable that the irradiation intensity in the wavelength region effective for activating the cationic polymerization initiator is set in the range of 10 to 2500 mW / cm 2 .
  • the irradiation time of the active energy ray varies depending on the adhesive composition to be cured, but it is preferable to set the integrated light amount represented by the product of the irradiation intensity and the irradiation time in the range of 10 to 2500 mJ / cm 2 .
  • the adhesive composition layer is formed on one surface of the resin layer 21, but may be formed on one surface of the polarizer layer 11 or on both surfaces.
  • a protective film 23 may be laminated on the side of the polarizer layer 11 opposite to the side where the resin layer 21 is bonded, and further a pressure-sensitive adhesive for bonding to a liquid crystal cell.
  • a layer (not shown) may be provided.
  • the laminated film original fabric (elongated laminated film) of the present embodiment includes a strip-shaped polarizing film original fabric (long-shaped polarizer layer), a belt-shaped resin film original fabric (long-shaped resin layer), and And an adhesive layer that bonds the polarizing film original and the resin film original.
  • the original polarizing film is a strip-shaped film made of a PVA-based resin, and a dichroic dye is oriented in the longitudinal direction of the film.
  • the PVA resin and the dichroic dye are the same as described above.
  • the resin film raw fabric is formed by stretching a strip-shaped film made of a thermoplastic resin and a plasticizer in a direction oblique to the longitudinal direction of the film. Thereby, a roll, a toe, and a roll are attained at the time of lamination
  • the thermoplastic resin and the plasticizer are the same as described above.
  • the resin film original is preferably a retardation film original.
  • a slow axis is given at an arbitrary angle with respect to the absorption axis of the polarizing film original fabric.
  • the arbitrary angle is preferably 45 ⁇ 10 ° or 135 ⁇ 10 ° with respect to the absorption axis of the polarizing film original.
  • the adhesive layer contains a cured product of the same adhesive composition as described above as a forming material.
  • the water contact angle at the surface of the adhesive layer is greater than 60 °.
  • the affinity between the adhesive layer 31 and the plasticizer becomes low. Therefore, it is thought that the adhesive layer 31 is difficult for the plasticizer to enter. This suppresses the intrusion of the plasticizer even in the case where the plasticizer moves from the resin film original to the polarizing film original in a humid heat environment (for example, at room temperature of 60 ° C. and humidity of 95%). Presumed to be possible.
  • the unstretched film used in this example refers to a film that has not been stretched.
  • the droplet method was applied as a method for measuring the water contact angle on the surface of the adhesive layer.
  • two cycloolefin resin films (trade name “ZEONOR (registered trademark)” manufactured by Nippon Zeon Co., Ltd.) having a thickness of 50 ⁇ m were prepared.
  • each prepared curable resin composition active energy ray-curable adhesive composition
  • Another film was stacked on the coated surface.
  • the laminate was irradiated with ultraviolet rays from one surface so that the integrated light amount was 250 mJ / cm 2 in accordance with Example 1, and the curable resin composition was cured.
  • a water-based adhesive composition In the case of a water-based adhesive composition, one cycloolefin resin film as described above was prepared. And the corona treatment was given to the single side
  • MD transmittance and TD transmittance in a wavelength range of 380 nm to 780 nm were measured with a spectrophotometer with an integrating sphere (manufactured by JASCO Corporation, “V7100”).
  • the degree of polarization at each wavelength was calculated based on the formula (T1) using the MD transmittance and the TD transmittance.
  • MD transmittance indicates the transmittance when the direction of polarized light emitted from the Glan-Thompson prism is parallel to the transmission axis of the laminated film sample.
  • TD transmittance refers to the transmittance when the direction of polarized light emitted from the Glan-Thompson prism is orthogonal to the transmission axis of the laminated film sample.
  • the evaluation sample was produced as follows. First, the adhesive composition was applied onto a triacetyl cellulose film using a bar coater so as to have a thickness of 2 to 3 ⁇ m to form an adhesive composition layer.
  • the triacetyl cellulose film for measuring the moisture permeability of the evaluation sample has a thickness of 57.5 ⁇ m and moisture permeability (value calculated by the cup method (JIS Z 0208, temperature 40 ° C., humidity 90% RH)).
  • an ultraviolet ray is irradiated using a D bulb manufactured by Fusion UV Systems Co., Ltd. so that the integrated light amount becomes 400 mJ / cm 2 , the adhesive composition layer is cured, and the evaluation sample and did.
  • the moisture permeability of the obtained evaluation sample was measured by a cup method (JIS Z 0208, temperature 40 ° C., humidity 90% RH).
  • Adhesive Composition According to the blending amounts shown in Tables 2 to 7, adhesive compositions of Examples and Comparative Examples were prepared. However, the names of the compounds used for the preparation may be indicated by abbreviations.
  • the cationic polymerization initiator “Adekaoptomer (registered trademark) SP-150” is a propylene carbonate solution, and Tables 2 to 5 show the amount of active ingredients.
  • the epoxy-based crosslinking agent “Smileze Resin (registered trademark) 650” is an aqueous solution, but in Table 7, it is indicated by the amount of the active ingredient.
  • Table 1 shows the structure of the oxetane compound.
  • DMAA dimethylacrylamide, obtained from KJ Chemicals.
  • 4HBA 4-hydroxybutyl acrylate, obtained from Nippon Kasei Co., Ltd.
  • UV-3700B urethane acrylate, obtained from Nippon Synthetic Chemical Industry Co., Ltd.
  • CHDMMA 1,4-cyclohexanedimethanol monoacrylate, obtained from Nippon Kasei Co., Ltd.
  • A-DCP tricyclodecane dimethanol diacrylate, obtained from Shin-Nakamura Chemical Co., Ltd.
  • aqueous solution having a weight ratio of potassium iodide / boric acid / water of 8.5 / 8.5 / 100 at 72 ° C. for 300 seconds.
  • the film was washed with pure water at 26 ° C. for 20 seconds, and then dried at 65 ° C. to prepare a polarizer layer in which iodine was oriented on a uniaxially stretched polyvinyl alcohol film.
  • the thickness of the polarizer was 12 ⁇ m.
  • R e (590), R e (450), R e (550), and R e (630) represent in-plane retardation values at measurement wavelengths of 590 nm, 450 nm, 550 nm, and 630 nm, respectively
  • R th (590 ) Represents a thickness direction retardation value at a measurement wavelength of 590 nm.
  • the adhesive composition obtained in the production example was applied to the surface of the resin layer (b) where the hard coat layer was not formed to form an adhesive composition layer.
  • the adhesive composition was applied using a bar coater (manufactured by Daiichi Rika Co., Ltd.) so that the film thickness after curing was about 2 ⁇ m.
  • a corona discharge treatment was performed on one side of an unstretched film (trade name “ZEONOR (registered trademark)” manufactured by Nippon Zeon Co., Ltd.) using a norbornene-based resin having a thickness of 23 ⁇ m as a forming material.
  • the adhesive composition was applied to the corona discharge treated surface in the same manner as the resin layer to form an adhesive composition layer.
  • the unstretched film is a raw material for the protective film in the laminated film.
  • Adhesive composition formed on the other surface of the polarizer layer and an unstretched film while bonding one surface of the polarizer layer prepared in (a) above and the adhesive composition layer formed on the resin layer.
  • the layers were bonded together to produce a laminate.
  • a pasting apparatus manufactured by Fuji Pla Co., Ltd., “LPA3301”
  • the angle formed by the absorption axis of the polarizer layer and the slow axis of the resin layer was set to 45 °.
  • the accumulated light amount is 250 mJ / cm 2 from the unstretched film side of the obtained laminate.
  • the adhesive composition layer was cured by irradiating with UV rays.
  • the laminated film which consists of a protective film / polarizer layer / adhesive layer / resin layer / hard coat layer was produced.
  • Example 13 297g / m 2 ⁇ 24hr
  • Example 15 251g / m 2 ⁇ 24hr
  • Comparative Example 2 307g / m 2 ⁇ 24hr
  • Comparative Example 3 428g / m 2 ⁇ 24hr
  • Comparative Example 4 529 g / m 2 ⁇ 24hr
  • Comparative Example 6 (C) A laminated film of Comparative Example 6 was produced in the same manner as in Example 1 except that the following operation was performed in the production of the laminated film.
  • the resin layer prepared in (b) above was bonded to one surface of the polarizer layer prepared in (a) via the aqueous adhesive composition obtained in the production example. Then, after drying at 80 degreeC for 5 minute (s), it cured at 40 degreeC and 23% RH for 72 hours, and produced the laminated
  • (C-1) Production of Laminated Film By means of a nip roll, one side of the polarizer layer produced in (a-1) above was passed through the aqueous adhesive composition obtained in the above production example via (b- The resin layer prepared in 1) was bonded, and the protective film prepared in (b-2) was bonded to the other surface via the same adhesive composition to prepare a laminate. At this time, the slow axis of the resin layer and the absorption axis of the polarizer layer were made substantially parallel. When the protective film prepared in (b-2) was bonded, the side without the hard coat layer was the bonding surface with the polarizer layer. Next, while maintaining the tension of the laminate, the laminate was passed through a drying furnace to dry the adhesive to obtain a laminate film.
  • a pressure-sensitive adhesive layer (thickness 15 ⁇ m) having a storage elastic modulus of about 0.7 MPa was provided on the opposite side of the resin layer from the adhesive surface with the polarizer layer.
  • the laminated film was bonded to glass via this pressure-sensitive adhesive layer to obtain an evaluation sample.
  • the sample was allowed to stand for 250 hours in an environment of a temperature of 65 ° C. and a relative humidity of 90% as in the evaluation of the heat and humidity resistance, and the visibility corrected polarization degree before and after being left was compared. As a result, the amount of change ⁇ Py in the visibility correction polarization degree was 0.3% or less.
  • the present invention can be used as a polarization supply element or a polarization detection element in a display device such as a liquid crystal display device.

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Chemical & Material Sciences (AREA)
  • Nonlinear Science (AREA)
  • Mathematical Physics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Polarising Elements (AREA)
  • Laminated Bodies (AREA)
PCT/JP2017/026999 2016-08-03 2017-07-26 積層フィルム WO2018025716A1 (ja)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201780047899.4A CN109564316A (zh) 2016-08-03 2017-07-26 层叠膜
KR1020197006293A KR20190035848A (ko) 2016-08-03 2017-07-26 적층 필름

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2016152715 2016-08-03
JP2016-152715 2016-08-03

Publications (1)

Publication Number Publication Date
WO2018025716A1 true WO2018025716A1 (ja) 2018-02-08

Family

ID=61072721

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2017/026999 WO2018025716A1 (ja) 2016-08-03 2017-07-26 積層フィルム

Country Status (5)

Country Link
JP (1) JP2018025792A (zh)
KR (1) KR20190035848A (zh)
CN (1) CN109564316A (zh)
TW (1) TW201815574A (zh)
WO (1) WO2018025716A1 (zh)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110609348A (zh) * 2018-06-14 2019-12-24 住友化学株式会社 带有粘接层的层叠体、层叠体、液晶层层叠体、液晶膜的制造方法、光学层叠体的制造方法
JP2020024368A (ja) * 2018-07-26 2020-02-13 三菱ケミカル株式会社 活性エネルギー線硬化性樹脂組成物、偏光フィルム保護層、およびそれを用いた偏光板
WO2023053798A1 (ja) * 2021-09-28 2023-04-06 日東電工株式会社 偏光フィルム、画像表示装置及び偏光フィルムの製造方法

Citations (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007133350A (ja) * 2005-10-11 2007-05-31 Fujifilm Corp 画像表示装置
JP2008009329A (ja) * 2006-06-30 2008-01-17 Jsr Corp 偏光板およびその製造方法
JP2008031212A (ja) * 2006-07-26 2008-02-14 Lintec Corp 光学機能性フィルム貼合用粘着剤、粘着剤付き光学機能性フィルム及びその製造方法
JP2008083307A (ja) * 2006-09-27 2008-04-10 Konica Minolta Opto Inc 偏光板、偏光板の製造方法、及び液晶表示装置
JP2008134384A (ja) * 2006-11-28 2008-06-12 Kyoritsu Kagaku Sangyo Kk 偏光板
JP2010078700A (ja) * 2008-09-24 2010-04-08 Nitto Denko Corp 偏光板用接着剤、偏光板、その製造方法、光学フィルムおよび画像表示装置
JP2010091602A (ja) * 2008-10-03 2010-04-22 Sumitomo Chemical Co Ltd 偏光板および液晶表示装置
JP2010229392A (ja) * 2009-03-05 2010-10-14 Dic Corp カチオン重合性接着剤及びそれを用いて得られた偏光板
JP2013061561A (ja) * 2011-09-14 2013-04-04 Konica Minolta Advanced Layers Inc 偏光板およびこれを用いた表示装置
JP2013142863A (ja) * 2012-01-12 2013-07-22 Sumitomo Chemical Co Ltd 光硬化性接着剤、それを用いた偏光板および積層光学部材
JP2013152457A (ja) * 2011-12-27 2013-08-08 Konica Minolta Inc 偏光板およびこれを用いた表示装置
JP2013181096A (ja) * 2012-03-01 2013-09-12 Toagosei Co Ltd フィルム又はシート用活性エネルギー線硬化型接着剤組成物
JP2014043099A (ja) * 2012-08-03 2014-03-13 Kyoritsu Kagaku Sangyo Kk 積層フィルムの製造方法、接着剤組成物キット及び反応開始剤組成物
WO2014058042A1 (ja) * 2012-10-11 2014-04-17 東亞合成株式会社 光硬化性接着剤組成物、偏光板とその製造法、光学部材及び液晶表示装置
JP2014071202A (ja) * 2012-09-28 2014-04-21 Fujifilm Corp 偏光板および液晶表示装置
JP2015028607A (ja) * 2013-06-26 2015-02-12 Ｋｊケミカルズ株式会社 偏光板用活性エネルギー線硬化性接着剤
JP2016090964A (ja) * 2014-11-11 2016-05-23 コニカミノルタ株式会社 液晶表示装置とその製造方法
JP2016122181A (ja) * 2014-12-24 2016-07-07 住友化学株式会社 偏光板及び液晶表示装置
JP2016136171A (ja) * 2015-01-23 2016-07-28 コニカミノルタ株式会社 光学フィルム、円偏光板及び有機エレクトロルミネッセンス表示装置

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4007920B2 (ja) * 2002-02-01 2007-11-14 日東電工株式会社 粘着型光学フィルムおよび画像表示装置
JP4402096B2 (ja) * 2006-11-15 2010-01-20 日東電工株式会社 偏光板、その製造方法、光学フィルムおよび画像表示装置
JP4744496B2 (ja) 2007-04-16 2011-08-10 日東電工株式会社 偏光板、光学フィルムおよび画像表示装置
JP6434309B2 (ja) * 2012-08-06 2018-12-05 株式会社クラレ 積層体、偏光フィルムおよび偏光フィルムの製造方法

Patent Citations (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007133350A (ja) * 2005-10-11 2007-05-31 Fujifilm Corp 画像表示装置
JP2008009329A (ja) * 2006-06-30 2008-01-17 Jsr Corp 偏光板およびその製造方法
JP2008031212A (ja) * 2006-07-26 2008-02-14 Lintec Corp 光学機能性フィルム貼合用粘着剤、粘着剤付き光学機能性フィルム及びその製造方法
JP2008083307A (ja) * 2006-09-27 2008-04-10 Konica Minolta Opto Inc 偏光板、偏光板の製造方法、及び液晶表示装置
JP2008134384A (ja) * 2006-11-28 2008-06-12 Kyoritsu Kagaku Sangyo Kk 偏光板
JP2010078700A (ja) * 2008-09-24 2010-04-08 Nitto Denko Corp 偏光板用接着剤、偏光板、その製造方法、光学フィルムおよび画像表示装置
JP2010091602A (ja) * 2008-10-03 2010-04-22 Sumitomo Chemical Co Ltd 偏光板および液晶表示装置
JP2010229392A (ja) * 2009-03-05 2010-10-14 Dic Corp カチオン重合性接着剤及びそれを用いて得られた偏光板
JP2013061561A (ja) * 2011-09-14 2013-04-04 Konica Minolta Advanced Layers Inc 偏光板およびこれを用いた表示装置
JP2013152457A (ja) * 2011-12-27 2013-08-08 Konica Minolta Inc 偏光板およびこれを用いた表示装置
JP2013142863A (ja) * 2012-01-12 2013-07-22 Sumitomo Chemical Co Ltd 光硬化性接着剤、それを用いた偏光板および積層光学部材
JP2013181096A (ja) * 2012-03-01 2013-09-12 Toagosei Co Ltd フィルム又はシート用活性エネルギー線硬化型接着剤組成物
JP2014043099A (ja) * 2012-08-03 2014-03-13 Kyoritsu Kagaku Sangyo Kk 積層フィルムの製造方法、接着剤組成物キット及び反応開始剤組成物
JP2014071202A (ja) * 2012-09-28 2014-04-21 Fujifilm Corp 偏光板および液晶表示装置
WO2014058042A1 (ja) * 2012-10-11 2014-04-17 東亞合成株式会社 光硬化性接着剤組成物、偏光板とその製造法、光学部材及び液晶表示装置
JP2015028607A (ja) * 2013-06-26 2015-02-12 Ｋｊケミカルズ株式会社 偏光板用活性エネルギー線硬化性接着剤
JP2016090964A (ja) * 2014-11-11 2016-05-23 コニカミノルタ株式会社 液晶表示装置とその製造方法
JP2016122181A (ja) * 2014-12-24 2016-07-07 住友化学株式会社 偏光板及び液晶表示装置
JP2016136171A (ja) * 2015-01-23 2016-07-28 コニカミノルタ株式会社 光学フィルム、円偏光板及び有機エレクトロルミネッセンス表示装置

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110609348A (zh) * 2018-06-14 2019-12-24 住友化学株式会社 带有粘接层的层叠体、层叠体、液晶层层叠体、液晶膜的制造方法、光学层叠体的制造方法
CN110609348B (zh) * 2018-06-14 2022-09-13 住友化学株式会社 带有粘接层的层叠体、层叠体、液晶层层叠体、液晶膜的制造方法、光学层叠体的制造方法
JP2020024368A (ja) * 2018-07-26 2020-02-13 三菱ケミカル株式会社 活性エネルギー線硬化性樹脂組成物、偏光フィルム保護層、およびそれを用いた偏光板
WO2023053798A1 (ja) * 2021-09-28 2023-04-06 日東電工株式会社 偏光フィルム、画像表示装置及び偏光フィルムの製造方法

Also Published As

Publication number Publication date
CN109564316A (zh) 2019-04-02
JP2018025792A (ja) 2018-02-15
KR20190035848A (ko) 2019-04-03
TW201815574A (zh) 2018-05-01

Similar Documents

Publication Publication Date Title
JP6439794B2 (ja) 粘着剤付き偏光板及び液晶表示装置
TWI689755B (zh) 偏光板及液晶顯示裝置
TWI570454B (zh) 複合相位差板及使用該複合相位差板之複合偏光板
JP2010286764A (ja) 光学積層体およびその製造方法
WO2018025716A1 (ja) 積層フィルム
WO2018025717A1 (ja) 積層フィルム
WO2018025698A1 (ja) 積層フィルム
JP6377322B2 (ja) 光学フィルム積層体及びそれを用いた複合偏光板
WO2018025714A1 (ja) 積層フィルム
TWI591389B (zh) 偏光板之製造方法
JP6707807B2 (ja) 偏光板及び液晶表示装置
KR101875256B1 (ko) 편광판, 고휘도 편광판 및 ips 모드 액정 표시 장치
TWI818906B (zh) 光學積層體
WO2018025715A1 (ja) 積層フィルム
JP2015113397A (ja) 表面改質されたシクロオレフィン系樹脂フィルムの製造方法及び偏光板の製造方法
JP2015206967A (ja) 複合偏光板の製造方法

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 17836822

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

ENP Entry into the national phase

Ref document number: 20197006293

Country of ref document: KR

Kind code of ref document: A

122 Ep: pct application non-entry in european phase

Ref document number: 17836822

Country of ref document: EP

Kind code of ref document: A1