Classifications

• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/37—Polymers
  • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • C11D3/3715—Polyesters or polycarbonates
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/02—Anionic compounds
  • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/66—Non-ionic compounds
  • C11D1/83—Mixtures of non-ionic with anionic compounds
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/37—Polymers
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/37—Polymers
  • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
  • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/37—Polymers
  • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
  • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
  • C11D7/22—Organic compounds

Definitions

• the present invention relates to a cleaning composition.
• This application claims priority based on Japanese Patent Application No. 2016-119315 filed in Japan on June 15, 2016, the contents of which are incorporated herein by reference.
• Patent Document 1 proposes a cleaning composition containing a copolymer of dimethyldiallylammonium halide and acrylamide. According to the cleaning composition of Cited Document 1, flexibility can be imparted to an object to be cleaned such as clothing. However, the cleaning composition of Patent Document 1 cannot provide a soft and voluminous tactile sensation, especially when a raised fabric made of polyester such as fleece is used as the object to be cleaned.
• the present invention has been made in view of the above circumstances, and an object of the present invention is to provide a cleaning composition that can provide a soft and voluminous feel.
• the component (A) includes at least one repeating unit selected from the group consisting of a repeating unit represented by the following general formula (a-1) and a repeating unit represented by the following general formula (a-2):
• a polymer having The component (B) is at least one selected from the group consisting of at least one repeating unit (b1) selected from the group consisting of alkylene terephthalate units and alkylene isophthalate units, an oxyalkylene unit, and polyoxyalkylene units.
• a detergent composition which is a water-soluble polymer having the repeating unit (b2).
• R 1 and R 2 each independently represents an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group having 1 to 3 carbon atoms, and X ⁇ represents a counter ion.
• R 3 and R 4 are each independently an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group having 1 to 3 carbon atoms, and X ⁇ is a counter ion.
• R 5 represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms
• R 6 and R 7 each independently represents a hydrogen atom, an alkyl group having 1 to 3 carbon atoms, or 1 to 3 carbon atoms. 3 hydroxyalkyl groups.
• the cleaning composition according to any one of [1] to [3], further comprising a nonionic surfactant.
• the cleaning composition of the present invention contains the following components (A) and (B).
• Component (A) a polymer having at least one repeating unit selected from the group consisting of a repeating unit represented by formula (a-1) and a repeating unit represented by formula (a-2) > Component (A) includes at least one repeating unit selected from the group consisting of repeating units represented by the following general formula (a-1) and repeating units represented by the following general formula (a-2). It is a polymer having.
• the cleaning composition of the present invention can give a soft and voluminous feel to the object to be washed after washing.
• R 1 and R 2 each independently represents an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group having 1 to 3 carbon atoms, and X ⁇ represents a counter ion.
• R 3 and R 4 are each independently an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group having 1 to 3 carbon atoms, and X ⁇ is a counter ion. ]
• the component (A) preferably further has a repeating unit represented by the following general formula (a-3).
• R 5 represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms
• R 6 and R 7 each independently represents a hydrogen atom, an alkyl group having 1 to 3 carbon atoms, or 1 to 3 carbon atoms. 3 hydroxyalkyl groups.
• the repeating unit represented by the general formula (a-1) and the repeating unit represented by the general formula (a-2) are dialkyl diallylammonium salts represented by the following general formula (a-4). It is a repeating unit derived from a monomer.
• R 8 and R 9 are each independently an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group having 1 to 3 carbon atoms, and X ⁇ is a counter ion. ]
• X ⁇ in the general formulas (a-1), (a-2) and (a-4) is a halogen ion such as chlorine ion or bromine ion, an inorganic acid ion such as sulfate ion, nitrate ion or sulfite ion, Examples thereof include organic acid ions such as methyl sulfate ion, acetate ion, and lactate ion.
• the weight average molecular weight of the component (A) is usually 1,000 to 5,000,000, preferably 3,000 to 2,000,000, and more preferably 10,000 to 2,000,000.
• the weight average molecular weight in this specification means the value calculated
• the form of polymerization of component (A) is not particularly limited, and may be block polymerization, random polymerization, or graft polymerization.
• the content ratio of the repeating unit represented by (a-1) and the repeating unit represented by (a-2) and the repeating unit represented by (a-3) in the component (A) is particularly limited.
• the molar ratio of the repeating unit represented by (a-1) and the repeating unit represented by (a-2) to the repeating unit represented by (a-3) is [[a ⁇ The total of the repeating units represented by 1) and the repeating units represented by (a-2)]:
• Examples of the polymer having at least one repeating unit selected from the group consisting of the repeating unit represented by the general formula (a-1) and the repeating unit represented by the general formula (a-2) include diallyl Examples thereof include polymers derived from dimethylammonium chloride, and examples of commercially available products include trade name “MARCOAT 100” manufactured by Lubrizol.
• Examples of the polymer having a repeating unit represented by -3) include diallyldimethylammonium chloride / acrylamide copolymer, diallyldimethylammonium chloride / acrylamide / acrylic acid terpolymer, and the like. As these polymers, synthetic products or commercially available products may be used.
• the polymer is not particularly limited, but can be produced by ordinary radical polymerization.
• it can be produced by polymerizing a monomer constituting the component (A) such as diallyldimethylammonium chloride or acrylamide by a polymerization method such as bulk polymerization, solution polymerization, emulsion polymerization, suspension polymerization or the like.
• a polymerization initiator used in ordinary radical polymerization for example, peroxides such as benzoyl peroxide and potassium persulfate, azobisisobutyronitrile, azobiscyanovaleric acid
• An azo compound such as can be used.
• Examples of commercial products of the copolymer include trade names “Murcoat 550”, “Mercoat 740”, “Mercoat 2200”, “Noverite 300”, “Noverite 302”, etc., manufactured by Lubrizol. Moreover, as a commercial item of the said terpolymer, brand name "Mercoat 3330", “Mercoat 3940", etc. by Lubrizol are mentioned, for example. These (A) components may be used individually by 1 type, and may be used in combination of 2 or more type.
• the content of the component (A) is preferably 0.1 to 5% by mass, more preferably 0.1 to 1.2% by mass, and more preferably 0.1 to 0.6% by mass with respect to the total mass of the cleaning composition. More preferred is mass%.
• the content of the component (A) is not more than the above upper limit value, it is easy to give a soft and voluminous feel.
• the content of the component (A) is at least the lower limit value, it is easy to give a soft and voluminous feel.
• ⁇ (B) component at least one selected from the group consisting of at least one repeating unit (b1) selected from the group consisting of an alkylene terephthalate unit and an alkylene isophthalate unit, an oxyalkylene unit, and a polyoxyalkylene unit
• b1 at least one repeating unit selected from the group consisting of an alkylene terephthalate unit and an alkylene isophthalate unit, an oxyalkylene unit, and a polyoxyalkylene unit
• alkylene terephthalate units constituting the water-soluble polymer of component (B)
• alkylene terephthalate units Is a unit represented by the following formula (b1-1).
• R 21 represents a lower alkylene group.
• the number of carbon atoms in R 21 is 1-4, preferably 2-4.
• Specific examples of the alkylene terephthalate unit include an ethylene terephthalate unit, an n-propylene terephthalate unit, an isopropylene terephthalate unit, an n-butylene terephthalate unit, an isobutylene terephthalate unit, a sec-butylene terephthalate unit, and a tert-butylene terephthalate unit. . Of these, isopropylene terephthalate units are preferred.
• the alkylene isophthalate unit is a unit represented by the following formula (b1-2).
• R 22 represents a lower alkylene group.
• R 22 has 1 to 4 carbon atoms, preferably 2 to 4 carbon atoms.
• the alkylene isophthalate unit include, for example, an ethylene isophthalate unit, a propylene isophthalate unit, an n-butylene isophthalate unit, a sec-butylene isophthalate unit, and a tert-butylene isophthalate unit. Of these, propylene isophthalate units are preferred.
• the (b1) unit a single type of alkylene isophthalate unit may be used alone, or a plurality of types of alkylene isophthalate units may be used in combination.
• the unit (b1) those selected from the above-mentioned alkylene terephthalate units and alkylene isophthalate units can be used alone or in combination of two or more. That is, the unit (b1) may be composed of only alkylene terephthalate units, may be composed only of alkylene isophthalate units, or may be composed of a mixture of alkylene terephthalate units and alkylene isophthalate units. May be.
• “Atleast one unit selected from the group consisting of oxyalkylene units and polyoxyalkylene units” (hereinafter also referred to as (b2) units) constituting the water-soluble polymer of component (B) is represented by the following formula (b- 2).
• -(R 23 O) s- (b-2) [Wherein R 23 represents a lower alkylene group, and s represents an integer of 1 to 100. ]
• R 23 has 1 to 4 carbon atoms, preferably 2 to 4 carbon atoms.
• s when s is 1, it is an oxyalkylene unit, and when s is 2 or more, it is a polyoxyalkylene unit.
• s is an integer of 1 to 100, preferably 1 to 80, particularly preferably 1 to 50.
• Specific examples of the (b2) unit include an oxyethylene unit and a polyoxyethylene unit; an oxypropylene unit and a polyoxypropylene unit; a polyoxyethylene polyoxypropylene unit, an oxyethylene unit and a polyoxyethylene Units are preferred.
• the unit (b2) one selected from the above oxyalkylene units and polyoxyalkylene units can be used alone or in combination of two or more. That is, the unit (b2) may be composed only of oxyalkylene units, may be composed only of polyoxyalkylene units, or may be composed of a mixture of oxyalkylene units and polyoxyalkylene units. May be.
• the component (B) is preferably a polymer compound in which the above-mentioned (b1) unit and (b2) unit are polymerized randomly or in blocks, and in particular, those in which the units are polymerized in blocks are preferred.
• the component B may contain units other than the above-mentioned units (b1) and (b2) (for example, units derived from a polymerization initiator, a polymerization terminator, etc., and other copolymerizable units). In that case, it is preferable that 80 mol% or more, preferably 90 mol% or more of the component (B) is composed of the (b1) unit and the (b2) unit.
• the “water-soluble polymer” in the component (B) means that 10 g of the polymer is added to 1000 g of water under the condition of 40 ° C. and stirred for 12 hours with a stirrer (thickness 8 mm, length 50 mm, 1 liter beaker). (200 rpm) means completely dissolved.
• component (B) examples include compounds represented by the following formula (b-3) or (b-4).
• a and B are each independently a hydrogen atom or a methyl group, preferably a methyl group, and R 24 , R 25 and R 26 are each independently an alkylene group having 2 to 4 carbon atoms, Preferably, it is an alkylene group having 2 to 3 carbon atoms, x1 is 0 to 10, preferably 0.5 to 5, particularly preferably 0.5 to 2.5, and y1 is 1 to 100, preferably 1 to 80, more preferably 1 to 50, still more preferably 10 to 50, particularly preferably 20 to 30, and z1 is 1 to 100, preferably 1 to 80, more preferably 1 to 50, still more preferably 10 to 50. Particularly preferred is 20-30. ]
• a and B are each independently a hydrogen atom or a methyl group, preferably a methyl group, and R 27 , R 28 and R 29 are each independently an alkylene group having 2 to 4 carbon atoms, An alkylene group having 2 to 3 carbon atoms is preferred, x2 is 0 to 10, preferably 0.5 to 5, particularly preferably 0.5 to 2.5, and y2 is 1 to 100, preferably 1 80, more preferably 1-50, still more preferably 10-50, particularly preferably 20-30, and z2 is 1-100, preferably 1-80, more preferably 1-50, still more preferably 10. To 50, particularly preferably 20 to 30.
• the ratio of x1 and y1 is preferably such that x1: y1 is 1: 5 to 1:20, more preferably 1: 8 to 1:18.
• the ratio of x2 and y2 is preferably such that x2: y2 is 1: 5 to 1:20, more preferably 1: 8 to 1:18.
• the component (B) preferably has a weight average molecular weight of 500 to 8000.
• the weight average molecular weight refers to a value obtained by converting a value measured by GPC (gel permeation chromatography) using THF (tetrahydrofuran) as a solvent and using PEG (polyethylene glycol) as a calibration curve.
• the lower limit of the weight average molecular weight is more preferably 800 or more, and particularly preferably 1000 or more.
• the upper limit of the weight average molecular weight is preferably 7000 or less, and particularly preferably 6000 or less. Therefore, the weight average molecular weight is preferably from 800 to 7000, particularly preferably from 1000 to 6000.
• the pH of component (B) (5% aqueous solution at 20 ° C.) is preferably 3-7.
• the melting point of component (B) is preferably 25 ° C. to 60 ° C.
• the viscosity (50 ° C.) of the component (B) is preferably 100 to 1000 mPa ⁇ s.
• the viscosity is a value measured using a No. 2 rotor with a Brookfield viscometer.
• Component (B) is a known substance and can be easily obtained on the market. Also, a synthesis method disclosed in the literature and the like: For example, Journal of Polymer Science 3, page 609-630 (1948), Journal of Polymer Science, volume 8, page 1-22 (1951), and the method described in JP-A-61-218699. . Specific examples of the component (B) include trade name: TexCare SRN-100 (manufactured by Clariant, weight average molecular weight: 2000 to 3000) and trade name: TexCare SRN-300 (manufactured by Clariant, weight average molecular weight: 7000). Are commercially available.
• TexCare SRN-100 is preferable because it has high solubility in water and little deterioration in cleaning performance after storage. Particularly preferred is a 70% aqueous solution of TexCare SRN-100, which is commercially available as trade name: TexCare SRN-170 (manufactured by Clariant).
• TexCare SRN-170 manufactured by Clariant.
• These (B) components may be used individually by 1 type, and may be used in combination of 2 or more type.
• the content of the component (B) is preferably 0.1 to 5% by mass, more preferably 0.1 to 3% by mass, and further preferably 0.2 to 1% by mass with respect to the total mass of the cleaning composition. preferable.
• the content of the component (B) is less than or equal to the above upper limit value, it is easy to give a soft and voluminous feel.
• the content of the component (B) is equal to or more than the lower limit value, it is easy to give a soft and voluminous feel.
• the mass ratio represented by component (A) / component (B) (hereinafter also referred to as A / B ratio) is preferably 0.02 to 50, more preferably 0.03 to 12, and preferably 0.1 to 3. Further preferred.
• the cleaning composition of the present invention can contain other components other than the above components (A) to (B) as necessary, as long as the effects of the present invention are not impaired.
• Agent nonionic surfactant, cationic surfactant, amphoteric surfactant, polymer other than components (A) and (B), water, organic solvent, thickener and solubilizer, metal ion scavenger (chelating agent) , Antioxidants, antiseptics, cleaning performance improvers, enzymes (proteases, lipases, cellulases, etc.), texture improvers, alkali builders (alkanolamines, etc.), hydrotropes, fluorescent agents, dye transfer inhibitors, recontamination prevention Agents, pearl agents, soil release agents, colorants, emulsifying agents, fragrances, insoluble particles, extracts of natural products, and the like.
• the anionic surfactant in the present invention is a known substance and can be easily obtained in the market. Of these, at least one anionic surfactant selected from the group consisting of sulfonic acid type anionic surfactants and sulfate ester type anionic surfactants (hereinafter also referred to as component (C)) is preferred.
• the sulfonic acid type anionic surfactant is an anionic surfactant having —SO 3 ⁇ M + in the molecule.
• the sulfate ester type anionic surfactant is an anionic surfactant having —OSO 3 ⁇ M + in the molecule.
• M + is a counter ion.
• Counter ions include metal ions, protonated amines, ammonium, and the like.
• component (C) include linear alkylbenzene sulfonates; ⁇ -olefin sulfonates; linear or branched alkyl sulfates; alkyl ether sulfates or alkenyl ether sulfates; alkyl groups And alkanesulfonic acid salts; ⁇ -sulfo fatty acid ester salts and the like.
• the linear alkylbenzene sulfonate the linear alkyl group preferably has 8 to 16 carbon atoms, and particularly preferably has 10 to 14 carbon atoms.
• the alkyl sulfate ester salt preferably has 10 to 20 carbon atoms.
• the alkyl ether sulfate ester salt or alkenyl ether sulfate ester salt has a linear or branched alkyl group or alkenyl group having 10 to 20 carbon atoms and is added with an average of 1 to 10 moles of ethylene oxide (that is, Polyoxyethylene alkyl ether sulfate ester salt or polyoxyethylene alkenyl ether sulfate ester salt) is preferable.
• the carbon number of the alkane sulfonate is 10 to 20, preferably 14 to 17, and the secondary alkane sulfonate is particularly preferable.
• a compound represented by the following formula (c-1) is preferable.
• R 43 CH (SO 3 M) COOR 44 (c-1) (In the formula (c-1), R 43 is a hydrocarbon group having 8 to 18 carbon atoms, R 44 is a hydrocarbon group having 1 to 6 carbon atoms, and M is a counter ion.) In the formula (c-1), the hydrocarbon group of R 43 has 8 to 18 carbon atoms. That is, the carbon number of the fatty acid residue of the ⁇ -sulfo fatty acid ester salt is 10-20.
• the hydrocarbon group for R 43 may be linear, branched, or may contain a cyclic structure.
• the hydrocarbon group for R 43 is preferably an aliphatic hydrocarbon group, more preferably a linear or branched alkyl group, or a linear or branched alkenyl group, and a linear alkyl group. Or a straight-chain alkenyl group is more preferable.
• the carbon number of R 44 is 1 to 6, preferably from 1 to 3.
• the hydrocarbon group for R 44 may be linear, branched, or may contain a cyclic structure.
• the hydrocarbon group for R 44 is preferably an aliphatic hydrocarbon group, more preferably a linear or branched alkyl group, or a linear or branched alkenyl group, and a linear alkyl group. A group or a branched alkyl group is more preferable.
• a methyl group, an ethyl group, an n-propyl group, an isopropyl group, and the like are preferable, a methyl group, an ethyl group, and an n-propyl group are preferable, and a methyl group is particularly preferable.
• the counter ion of M is preferably one capable of forming a water-soluble salt with R 43 CH (COOR 44 ) SO 3 — , for example, an alkali metal ion, a protonated amine, an ammonium ion Etc.
• alkali metal that can be the counter ion include sodium.
• the amine that can be a counter ion include primary to tertiary amines.
• the total number of carbon atoms of the amine is preferably 1-6.
• the amine may have a hydroxy group. Since the solubility of ⁇ -sulfo fatty acid ester salt in water increases, the amine preferably has a hydroxy group.
• Examples of the amine having a hydroxy group include alkanolamine, and the alkanol group preferably has 1 to 3 carbon atoms.
• Examples of the alkanolamine include monoethanolamine, diethanolamine, and triethanolamine.
• M is preferably an alkali metal ion and particularly preferably a sodium ion because it is easily available and the low-temperature stability of the liquid detergent can be further enhanced.
• R 43 in the formula (c-1) is a linear or branched alkyl group having 14 to 16 carbon atoms, or a linear or branched alkenyl group. And compounds in which R 44 is a methyl group are particularly preferred.
• linear alkylbenzene sulfonates, alkane sulfonates, polyoxyethylene alkyl ether sulfates, and ⁇ -olefin sulfonates are preferred.
• the salt include alkali metal salts such as sodium salt and potassium salt, ammonium salt, monoethanolamine salt, diethanolamine salt, triethanolamine salt, 2-amino-2-methylpropanol salt, 2-amino-2-methylpropanediol.
• basic amino acid salts such as lysine and arginine.
• component (C) is, for example, blended in the detergent composition in an acid form such as linear alkylbenzene sulfonic acid, neutralized with an alkaline agent such as caustic soda or monoethanolamine, and in the detergent composition.
• an alkaline agent such as caustic soda or monoethanolamine
• a salt form is also possible.
• These (C) components may be used alone or in combination of two or more.
• the content of the component (C) is preferably 2 to 20% by mass, more preferably 5 to 18% by mass, and still more preferably 10 to 16% by mass with respect to the total mass of the cleaning composition.
• the content of the component (C) is not more than the above upper limit value, it is easy to give a soft and voluminous feel.
• the content of the component (C) is equal to or higher than the lower limit, it is easy to give a soft and voluminous feel.
• the mass ratio represented by component (A) / component (C) (hereinafter also referred to as A / C ratio) is preferably 0.1 / 20 to 5/2, preferably 0.1 / 18 to 1.2 / 5. Is more preferable. By setting the A / C ratio within the above range, a soft and voluminous feel can be imparted.
• anionic surfactants other than the component (C) include higher fatty acid salts, alkyl ether carboxylates, polyoxyalkylene ether carboxylates, alkyl (or alkenyl) amide ether carboxylates, and acylaminocarboxylates.
• examples thereof include phosphate type anionic surfactants such as acid type, alkyl phosphate ester salt, polyoxyalkylene alkyl phosphate ester salt, polyoxyalkylene alkyl phenyl phosphate ester salt, and glycerin fatty acid ester monophosphate ester salt.
• Component (C) is preferably used in combination with a salt of a fatty acid having 8 to 22 carbon atoms (hereinafter also referred to as “higher fatty acid”).
• higher fatty acids include salts of single fatty acids such as caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, hydroxystearic acid, oleic acid, behenic acid, coconut oil fatty acid, beef tallow fatty acid And mixed fatty acids.
• salts of these higher fatty acids include alkali metal salts such as sodium salts and potassium salts, ammonium salts, monoethanolamine salts, diethanolamine salts, triethanolamine salts, 2-amino-2-methylpropanol salts, 2-amino- Examples include alkanolamine salts such as 2-methylpropanediol, and basic amino acid salts such as lysine and arginine.
• the nonionic surfactant (hereinafter also referred to as the component (D)) is not particularly limited, and examples thereof include polyoxyalkylene type nonionic surfactants, alkylphenols, fatty acids having 8 to 22 carbon atoms, and amines having 8 to 22 carbon atoms.
• Alkylene oxide adduct polyoxyethylene polyoxypropylene block copolymer, fatty acid alkanolamine, fatty acid alkanolamide, polyhydric alcohol fatty acid ester or its alkylene oxide adduct, polyhydric alcohol fatty acid ether, alkyl (or alkenyl) amine oxide, cured castor
• Examples include an alkylene oxide adduct of oil, a sugar fatty acid ester, an N-alkyl polyhydroxy fatty acid amide, and an alkyl glycoside. These may be used alone or in combination of two or more.
• a polyoxyalkylene type nonionic surfactant is preferable (however, the component (F) is not included) from the viewpoint of improving the appearance stability while appropriately maintaining the viscosity of the liquid detergent. ).
• polyoxyalkylene type nonionic surfactant examples include a compound represented by the following general formula (d-1) (hereinafter referred to as “compound (d1)”), and a general formula (d-2).
• compound (d2) Compound (hereinafter referred to as “compound (d2)”) and the like. These may be used alone or in combination of two or more.
• R 54 —O — [(EO) s / (PO) t ] H (d-2)
• R 51 is a hydrocarbon group having 9 to 13 carbon atoms
• R 52 is an alkylene group having 2 to 4 carbon atoms
• R 53 is an alkyl group having 1 to 4 carbon atoms.
• . m represents the average number of repetitions of OR 52 and is a number from 5 to 25.
• R 54 is a hydrocarbon group having 10 to 22 carbon atoms
• EO is an oxyethylene group
• PO is an oxypropylene group.
• s represents the average number of repetitions of EO and is a number from 5 to 20
• t represents the average number of repetitions of PO and is a number from 0 to 4.
• the hydrocarbon group for R 51 may be linear or branched, or may contain a cyclic structure. Further, the hydrocarbon group of R 51 is preferably an aliphatic hydrocarbon group, a linear or branched alkyl group, or a linear or branched chain alkenyl group is more preferable.
• R 51 has 9 to 13 carbon atoms, preferably 10 to 13 carbon atoms, and more preferably 11 to 13 carbon atoms. When the carbon number of R 51 is 9 or more, the detergency is further increased. On the other hand, when the carbon number of R 51 is 13 or less, the storage stability is improved, and in particular, gelation is easily suppressed.
• the compound (d1) may be a mixture having a single chain length or a mixture having a plurality of chain lengths.
• R 51 is derived from the starting fatty acid (R 51 —COOH).
• R 53 is an alkyl group having 1 to 4 carbon atoms, preferably an alkyl group having 1 to 3 carbon atoms. Specific examples of R 53 include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, and an n-butyl group. A methyl group and an ethyl group are preferable, and a methyl group is more preferable.
• R 52 is an alkylene group having 2 to 4 carbon atoms, preferably an ethylene group or a propylene group. A plurality of R 52 in the formula may be different may be the same with each other. That is, the alkylene group for R 52 may be one kind alone, or two or more kinds may be combined.
• m OR 52 in the formula is an oxyethylene group or an oxyethylene group and an oxypropylene group are mixed because foaming during washing is good and inexpensive.
• the addition method of OR 52 is not particularly limited.
• the addition method when oxyethylene group and oxypropylene group are mixed includes random addition. It may be a block addition. Examples of the block addition method include a method of adding propylene oxide after adding ethylene oxide, a method of adding ethylene oxide after adding propylene oxide, a method of adding propylene oxide after adding ethylene oxide, and further adding ethylene oxide. Can be mentioned.
• m represents the average number of repetitions of OR 52 and is a number of 5 to 25.
• m is at least the lower limit value, the cleaning power, particularly the cleaning power against sebum stains is further improved.
• the solubility with respect to the water of a liquid detergent improves more as m is below an upper limit.
• OR 52 is oxyethylene groups
• m is preferably 5 to 20, and more preferably 12 to 18.
• OR 52 is a mixture of an oxyethylene group and an oxypropylene group
• m is particularly preferably 12 to 21.
• the average number of repeating oxypropylene groups is preferably 5 or less, more preferably 4 or less, and even more preferably 3 or less.
• the cleaning power and storage stability as liquid detergent may be reduced.
• the narrow ratio indicating the distribution ratio of the compounds having different OR 52 repeat numbers is 20% by mass or more.
• the upper limit of the narrow ratio is preferably substantially 80% by mass or less.
• the narrow ratio is more preferably 20 to 50% by mass, and further preferably 30 to 45% by mass because the storage stability and solubility in water are further improved. The higher the narrow rate, the easier it is to obtain better cleaning power. Moreover, it becomes easy to obtain the liquid detergent with few raw material odors derived from a compound (d1) as the said narrow rate becomes like this.
• the compound (d1) is 20 mass% or more, Most preferably, it is 30 mass% or more.
• a fatty acid ester which is a raw material of the compound (d1) coexists with the compound (d1), and an alkylene oxide adduct wherein m is 1 or 2 in the formula (d-1)
• the total proportion of the fatty acid ester as the raw material of the compound (d1) and the alkylene oxide adduct wherein m is 1 or 2 in the formula (d-1) Is preferably 0.5% by mass or less, and more preferably 0.2% by mass or less, based on the total mass of the compound (d1).
• the “narrow ratio” refers to a value represented by the following mathematical formula (S), which indicates a distribution ratio of alkylene oxide adducts having different numbers of added moles of alkylene oxide.
• m max represents the number of repetitions of OR 52 (addition moles) of the alkylene oxide adduct that is most abundant in the entire compound (d1).
• i represents the number of repetitions of OR 52 .
• Yi represents the proportion (mass%) of an alkylene oxide adduct having an added mole number of alkylene oxide present in the whole compound (d1).
• the narrow rate can be controlled by, for example, the method for producing the compound (d1).
• the method for producing the compound (d1) is not particularly limited. For example, a method of addition polymerization of an alkylene oxide to a fatty acid alkyl ester using a surface-modified composite metal oxide catalyst (see JP 2000-144179 A). ) Can be easily manufactured.
• such a surface-modified composite metal oxide catalyst specifically, metal ions (Al 3+ , Ga 3+ , In 3+ , Tl 3+ , Co 1) surface-modified with a metal hydroxide or the like are used. 3+ , Sc 3+ , La 3+ , Mn 2+, etc.) or a composite metal oxide catalyst such as magnesium oxide, or a calcined hydrotalcite surface-modified with a metal hydroxide and / or metal alkoxide A catalyst is mentioned. Further, in the surface modification of the composite metal oxide catalyst, the mixing ratio of the composite metal oxide and the metal hydroxide and / or metal alkoxide is changed to metal water with respect to 100 parts by mass of the composite metal oxide.
• the ratio of the oxide and / or metal alkoxide is preferably 0.5 to 10 parts by mass, and more preferably 1 to 5 parts by mass.
• a method for producing the compound (d1) there is also a method of adding an alkylene oxide to a fatty acid alkyl ester with an alkoxylation catalyst prepared from a mixture of an alkaline earth metal compound and oxyacid or the like.
• the above alkoxylation catalyst is disclosed in Japanese Patent No. 04977609, International Publication No. 1993/004030, International Publication No. 2002/038269, International Publication No. 2012/028435, and the like.
• alkaline earth of carboxylic acid Examples include an alkoxylation catalyst prepared from a mixture of a metal salt and / or an alkaline earth metal salt of hydroxycarboxylic acid and sulfuric acid.
• the hydrocarbon group of R 54 may contain may be also branched and straight-chain or cyclic structure.
• the hydrocarbon group for R 54 is preferably an aliphatic hydrocarbon group, more preferably a linear or branched alkyl group, or a linear or branched alkenyl group.
• R 54 has 10 to 20 carbon atoms, preferably 12 to 18 carbon atoms, and more preferably 12 to 14 carbon atoms. When the carbon number of R 54 is 10 or more, the detergency is further increased. On the other hand, when the carbon number of R 54 is 20 or less, the storage stability is improved, and in particular, gelation is easily suppressed.
• the compound (d2) may be a single chain length mixture or a plurality of chain length mixtures.
• R 54 is derived from a raw material alcohol (R 54 —OH). Examples of the alcohol include alcohols derived from natural fats and oils such as coconut oil, palm oil and beef tallow, and synthetic alcohols derived from petroleum.
• s represents an average number of repetitions of EO, is a number of 5 to 20, is preferably a number of 12 to 18, and is more preferably a number of 12 to 16. When s is within the above range, the cleaning power of the liquid detergent, particularly the cleaning power against sebum dirt, is further improved.
• t represents the average number of repetitions of PO, and is a number from 0 to 4, preferably a number from 0 to 3, and particularly preferably 0.
• t is within the above range, gelation of the liquid detergent is likely to be suppressed, and good foamability is easily obtained at the time of rinsing.
• EO and PO may be added in a block shape or may be added in a random shape.
• the addition method includes adding ethylene oxide followed by propylene oxide, adding propylene oxide followed by ethylene oxide, and adding ethylene oxide followed by propylene oxide. And a method of adding ethylene oxide further.
• the addition mole number distribution of alkylene oxide is not particularly limited and can be controlled by the production method of compound (d2) and the like.
• a general alkali catalyst such as sodium hydroxide or potassium hydroxide
• alkoxyl such as magnesium oxide to which metal ions such as Al 3+ , Ga 3+ , In 3+ , Tl 3+ , Co 3+ , Sc 3+ , La 3+ , Mn 2+ and the like described in Japanese Patent Publication No. 6-15038 are added.
• metal ions such as Al 3+ , Ga 3+ , In 3+ , Tl 3+ , Co 3+ , Sc 3+ , La 3+ , Mn 2+ and the like described in Japanese Patent Publication No. 6-15038 are added.
• Specific examples of the compound (d2) include the following compounds. ⁇ Product name “Leox CL-70” (mixture of 12 carbon alcohol and 14 carbon alcohol) manufactured by Lion Co., Ltd. or product name Safol 23 (12 carbon alcohol and 13 carbon alcohol) manufactured by Sasol A compound obtained by adding 12 mol or 15 mol of EO to an alcohol such as A compound obtained by adding 9 mol, 12 mol or 15 mol of EO to a natural alcohol such as “CO-1214” or “CO-1270” manufactured by P & G.
• the component (D) is preferably at least one selected from the group consisting of the compound (d1) and the compound (d2), particularly from the viewpoints of detergency against sebum stains and difficulty in gelation in a high concentration region. Among these, it is more preferable to use a combination of the compound (d1) and the compound (d2) or the compound (d1).
• the compound (d1) is preferably a polyoxyethylene fatty acid alkyl ester in which R 52 is an ethylene group, and among them, a polyoxyethylene fatty acid methyl ester in which R 53 is a methyl group (hereinafter referred to as “MEE”).
• MEE polyoxyethylene fatty acid methyl ester
• the solubility to water improves. Furthermore, it is thought that it contributes to good fluidity at a high concentration. Therefore, when the polyoxyethylene fatty acid alkyl ester is poured into the water in the washing machine tub, the concentration of the polyoxyethylene fatty acid alkyl ester in the washing liquid quickly becomes uniform and comes into contact with the object to be washed at a predetermined concentration from the initial stage of washing. Therefore, it is considered that high detergency can be obtained. Furthermore, as the compound (d2), among the above-mentioned compounds, a primary alcohol ethoxylate obtained by adding ethylene oxide to a primary alcohol is particularly preferable.
• the content of the component (D) is preferably 10 to 50% by mass, more preferably 10 to 40% by mass, and further preferably 15 to 30% by mass with respect to the total mass of the cleaning composition.
• the content of the component (D) is 10% by mass or more, sufficient detergency is obtained, and when the content is 50% by mass or less, thickening is suppressed and the storage stability of the liquid detergent can be maintained better.
• cationic surfactant examples include alkyltrimethylammonium salts, dialkyldimethylammonium salts, alkylbenzyldimethylammonium salts, and alkylpyridinium salt cationic surfactants.
• amphoteric surfactant examples include alkyl betaine type, alkyl amide betaine type, imidazoline type, alkyl amino sulfone type, alkyl amino carboxylic acid type, alkyl amide carboxylic acid type, amide amino acid type, phosphoric acid type amphoteric surfactant. Is mentioned.
• polymers other than components (A) and (B) examples include a repeating unit derived from a monomer represented by the following general formula (e-1) and a monomer represented by the following general formula (e-2). And polymers containing at least one repeating unit selected from the group consisting of the repeating units (hereinafter also referred to as component (E)).
• the component (E) serves as a structuring agent.
• the cleaning composition is structured. Therefore, for example, when the liquid detergent contains insoluble particles, the insoluble particles can be uniformly dispersed in the liquid detergent, and the state can be maintained. In addition, the storage stability and re-contamination prevention property of the liquid detergent are enhanced.
• R 11 represents a hydrogen atom or a methyl group
• R 12 represents a hydrogen atom
• R 13 is a hydrogen atom or a methyl group
• R 14 is an alkyl group having 1 to 40 carbon atoms.
• the repeating unit derived from the monomer represented by the general formula (e-1) is represented by the general formula (e-1) when the monomer component containing the monomer represented by the general formula (e-1) is polymerized. It is a repeating unit derived from the represented monomer.
• Examples of the monomer represented by the general formula (e-1) include acrylic acid and methacrylic acid. Any one of these monomers represented by the general formula (e-1) may be used alone, or two or more may be used in combination.
• R 13 is a hydrogen atom or a methyl group, preferably a hydrogen atom.
• the alkyl group for R 14 may be linear or branched, or may contain a cyclic structure.
• the alkyl group in R 14 has 1 to 40 carbon atoms, preferably 1 to 20 carbon atoms, and more preferably 1 to 10 carbon atoms.
• the repeating unit derived from the monomer represented by the general formula (e-2) is represented by the general formula (e-2) when the monomer component containing the monomer represented by the general formula (e-2) is polymerized. It is a repeating unit derived from the represented monomer. Examples of the monomer represented by the general formula (e-2) include methyl acrylate, ethyl acrylate, n-propyl acrylate, n-butyl acrylate, octyl acrylate, decyl acrylate, dodecyl acrylate, and acrylic.
• Acrylic acid esters such as icosyl acid; and methacrylic acid esters such as methyl methacrylate, ethyl methacrylate, n-propyl methacrylate, n-butyl methacrylate, decyl methacrylate, dodecyl methacrylate, and icosyl methacrylate. Any one of these monomers represented by the general formula (e-2) may be used alone, or two or more thereof may be used in combination.
• Component (E) may be cross-linked or non-cross-linked, but is preferably cross-linked. As what (E) component is bridge
• an allyl ether compound is mentioned suitably, for example.
• the allyl ether compound include allyl ether, sugar allyl ether, sugar alcohol allyl ether, and the like.
• the sugar in the allyl ether of sugar include sucrose.
• the sugar alcohol in the allyl ether of the sugar alcohol include pentaerythritol.
• the component (E) any one type may be used alone, or two or more types may be used in combination.
• the component (E) is a repeating unit other than the repeating unit derived from the monomer represented by the general formula (e-1) and the repeating unit derived from the monomer represented by the general formula (e-2). (Other repeating units) may be included.
• repeating units include repeating units derived from other monomers.
• the other monomer is not particularly limited as long as it is copolymerizable with the monomer represented by the general formula (e-1) and the monomer represented by the general formula (e-2), and one or more types may be used. it can.
• e-1 the monomer represented by the general formula (e-1)
• e-2 the monomer represented by the general formula (e-2)
• one or more types may be used. it can.
• E As a specific example of a component, the following brand names are mentioned, for example.
• a crosslinking type (E) component As a commercial item of a crosslinking type (E) component, the brand name which is a crosslinked type copolymer which consists of two or more types of monomers chosen from the alkyl acrylate, the alkyl methacrylate, acrylic acid, and methacrylic acid made from Lubrizol, for example “Carbopol Aqua 30”; a cross-linked copolymer consisting of two or more monomers selected from alkyl acrylates (C1 to C4 and C8), alkyl methacrylates (C1 to C4 and C8), acrylic acid and methacrylic acid manufactured by Lubrizol “Carbopol Aqua SF-1” which is a coalescence; a cross-linked copolymer comprising two or more monomers selected from alkyl acrylate (C10 to C30), alkyl methacrylate (C10 to C30) and acrylic acid manufactured by Lubrizol Product name "Carbopol” EZ-4 ”; trade name“ ACUSOL 830
• non-crosslinking type (E) component for example, a trade name of a copolymer composed of two or more monomers selected from alkyl acrylate, alkyl methacrylate, acrylic acid and methacrylic acid manufactured by Lubrizol. "Novethix HC200" etc. are mentioned.
• E non-crosslinking type
• the content of the component (E) is preferably 0.1 to 5.0% by mass, and more preferably 0.5 to 2.5% by mass with respect to the total mass of the cleaning composition.
• the liquid detergent can be structured.
• the mass ratio represented by component (A) / component (E) (hereinafter also referred to as A / E ratio) is preferably 0.05 to 1.25, more preferably 0.1 to 1.25.
• the cleaning composition of the present invention can contain an organic solvent (hereinafter also referred to as component (F)), for example, a monohydric alcohol having 2 to 4 carbon atoms, a polyhydric alcohol having 2 to 4 carbon atoms, and the following formula: It is a solvent selected from the group consisting of a glycol ether solvent represented by (f-1) and a solvent represented by the following formula (f-2).
• component (F) a solvent selected from the group consisting of a glycol ether solvent represented by (f-1) and a solvent represented by the following formula (f-2).
• R 31 - (OR 32) m OH ⁇ (f-1) [Wherein R 31 represents an alkyl group having 1 to 6 carbon atoms or a phenyl group, R 32 represents an alkylene group having 2 to 4 carbon atoms, and m represents an average addition mole number and is 1 to 5.
• Examples of the monohydric alcohol having 2 to 4 carbon atoms include ethanol, 1-propanol, 2-propanol, 1-butanol and the like.
• Examples of the polyhydric alcohol having 2 to 4 carbon atoms include ethylene glycol, propylene glycol, butylene glycol, glycerin and the like.
• Examples of the glycol ether solvent represented by the formula (f-1) include ethylene glycol monobutyl ether, ethylene glycol monohexyl ether, ethylene glycol monophenyl ether, propylene glycol monophenyl ether, diethylene glycol monomethyl ether, and diethylene glycol monobutyl ether. Can be mentioned.
• Examples of the solvent represented by the formula (f-2) include 3-methoxymethanol, 3-methoxy-3-methylbutanol, 3-methoxy-3-ethylbutanol, 3-methoxy-3-propylbutanol, and 3-methoxy.
• ethanol, propylene glycol, diethylene glycol monobutyl ether, and 3-methoxy-3-methylbutanol are preferable from the viewpoint of fluidity as a liquid detergent, mild odor, and availability of raw materials.
• These (F) components may be used individually by 1 type, and may be used in combination of 2 or more type.
• the content of the component (F) is preferably 3 to 25% by mass with respect to the total mass of the cleaning composition.
• the content of the component (F) is not more than the above upper limit value, it is easy to impart fluidity and liquid stability as a liquid detergent.
• the content of the component (F) is equal to or higher than the lower limit, it is easy to impart fluidity and liquid stability as a liquid detergent.
• thickener and solubilizer examples include triethylene glycol, tetraethylene glycol, polyethylene glycol having an average molecular weight of about 200, polyethylene glycol having an average molecular weight of about 400, polyethylene glycol having an average molecular weight of about 1000, and glycols such as dipropylene glycol, Examples include paratoluenesulfonic acid, benzoate, and urea.
• the cleaning composition of the present invention contains a viscosity reducing agent and a solubilizing agent
• the content of the viscosity reducing agent and the solubilizing agent is preferably 0.01 to 15% by mass with respect to the total mass of the cleaning composition. .
• Metal ion scavenger (chelating agent) examples include malonic acid, succinic acid, malic acid, diglycolic acid, tartaric acid, and citric acid.
• the content of the metal ion scavenger is preferably 0.1 to 20% by mass relative to the total mass of the cleaning composition.
• antioxidant examples include butylhydroxytoluene, distyrenated cresol, sodium sulfite, sodium hydrogen sulfite and the like.
• the content of the antioxidant is preferably 0.01 to 2% by mass relative to the total mass of the cleaning composition.
• Preservative As preservatives, “Caisson CG” (trade name) manufactured by Dow Chemical Company, “Acciside MBS” (trade name) manufactured by So Japan Co., Ltd., “NIPACIDE BIT” manufactured by Clariant Co., Ltd. 20 "(trade name).
• colorants include Acid Red 138, Polar Red RLS, Acid Yellow 203, Acid Blue 9, Blue No. 1, Blue No. 205, Green No. 3, Red No. 106, Yellow No. 203, and Turquoise P-GR (all products Name) and other general-purpose dyes and pigments.
• the content of the colorant is preferably 0.00005 to 0.005% by mass with respect to the total mass of the cleaning composition.
• the emulsifying agent examples include a polystyrene emulsion and a polyvinyl acetate emulsion, and usually include an emulsion having a solid content of 30 to 50% by mass. Specifically, a polystyrene emulsion (manufactured by Seiden Chemical Co., Ltd. (trade name) ) Cybinol RPX-196 PE-3, solid content of 40% by mass).
• the content of the emulsifying agent is preferably 0.01 to 0.5% by mass with respect to the total mass of the cleaning composition.
• fragrances include fragrance ingredients described in JP-A-2002-146399.
• the content of the fragrance is preferably 0.01 to 2% by mass relative to the total mass of the cleaning composition.
• Insoluble particles are particles that are difficult to dissolve in the components constituting the liquid detergent. Specific examples of the insoluble particles include capsule particles, beads and pearlescent agents for imparting unique product aesthetics, bentonite, carboxymethylcellulose (CMC), and the like.
• Capsule particles are those in which an active ingredient is encapsulated by a capsule wall formed of a polymer compound.
• the capsule particles can be produced by a known method, and examples thereof include an interfacial polymerization method and an in-situ polymerization method.
• the polymer compound that forms the capsule wall include polyacrylic acid-based, polyvinyl-based, polymethacrylic acid-based, melamine-based, and urethane-based synthetic polymers. Any of these may be used alone or in combination of two or more.
• the active ingredient include a fragrance ingredient and a sunscreen ingredient (such as an ultraviolet absorber and an ultraviolet scattering agent).
• capsule particles in which a fragrance component is encapsulated by a capsule wall formed of a polymer compound are also referred to as “capsule fragrance”.
• Specific examples of the capsule flavor include capsule flavor A, capsule flavor B, and capsule flavor C shown below.
• Capsule flavor A contains the following flavor components. Limonene (0.10% by mass), ethyl 2-methylbutyrate (3.50% by mass), tripral (5.00% by mass), galvascon (0.20% by mass), spirogalvanone (0.60% by mass) ), Cyclaset (9.00% by mass), cyclobate (0.10% by mass), tricyclodecenyl acetate (19.00% by mass), bellox (18.00% by mass), nectaryl (15.00) Mass%), tetrahydrolinalol (14.00 mass%), ⁇ -ionone (0.50 mass%), ⁇ -ionone (14.00 mass%), dipropylene glycol (1.00 mass%).
• Capsule flavor B contains the following flavor components. Tripral (2.40% by mass), cyclaset (10.00% by mass), tricyclodecenyl propionate (10.00% by mass), isopropylmethyl-2-butyrate (1.70% by mass), manzanate (2.00% by mass), Beldox (14.00% by mass), allyl amyl glycolate (2.00% by mass), allyl cyclohexylpropionate (5.00% by mass), ⁇ -decalactone (0.50) %), ⁇ -undecalactone (7.50% by weight), ⁇ -damascone (0.25% by weight), nerol (0.20% by weight), Hedion (5.00% by weight), lyial (12.
• Capsule flavor C includes the following flavor components. Hexyl salicylate (3.71% by mass), ethyl 2-methylbutyrate (3.30% by mass), dihydroeugenol (8.49% by mass), camphor (1.46% by mass), 1,4-cineole (1.28% by mass), Beldox (9.04% by mass), ⁇ -nonalactone (0.84% by mass), ⁇ -decalactone (2.58% by mass), ⁇ -undecalactone (3.70% by mass) %), Allyl caproate (7.47 mass%), hexyl acetate (1.27 mass%), geranyl propionate (6.38 mass%), prenyl acetate (1.52 mass%), allyl phenoxy acetate (0.60% by mass), dimethylbenzylcarbinyl butyrate (0.95% by mass), nectaryl (8.54% by mass), geranyl acetate (11.13% by mass), lily (11.51% by mass), cycla
• extracts such as natural products include Inuenju, Uwaurushi, Echinacea, Koganebana, Yellowfin, Ouren, Allspice, Oregano, Enju, Chamomile, Honeysuckle, Clara, Keigai, Kay, Bay bay, Honoki, Burdock, Comfrey, Jasho, Waremokou, Peonies, Ginger, Solidago, Elderberry, Sage, Mistletoe, Prunus, Thyme, Prunus, Clove, Satsuma Mandarin, Tea Tree, Barberry, Dokudami, Nanten, Nyuko, Yorigusa, Shirogaya, Bow Fu, Dutch Hyu, Mountain, Gray , Murasakitagayasan, yamahakka, cypress, yamajiso, eucalyptus, lavender, rose, rosemary, balun, cedar, gilead balsamno , Ringworm, kochia, Polygonum
• These components may be used individually by 1 type, and may be used in combination of 2 or more type. Further, antifoaming of 2-ethylhexyl 2-ethylhexanoate (2-ethylhexyl isooctylate), 2-ethylbutyl 2-ethylhexanoate, 2-ethyloctyl 2-ethylhexanoate described in JP-A-2017-8139, etc. An agent having an effect may be included.
• the cleaning composition of the present invention contains these agents having an antifoaming effect, the content thereof is preferably 0 to 2.0% by mass with respect to the total mass of the cleaning composition. The total amount of the components constituting the cleaning composition does not exceed 100% by mass.
• the cleaning composition of the present invention preferably has a pH of 4 to 10 at 25 ° C., more preferably 4 to 9, and even more preferably 4 to 8.
• the pH of the cleaning composition can be adjusted by adding a pH adjusting agent as necessary.
• the pH adjuster is optional as long as the effects of the present invention are not impaired, but sulfuric acid, sodium hydroxide, potassium hydroxide, alkanolamine and the like are preferable.
• pH means a value measured with a pH meter (product name: HM-30G, manufactured by Toa DKK Co., Ltd.) with a measurement target at 25 ° C.
• the cleaning composition of the present invention contains the component (A) and the component (B), the component (A) is a copolymer of dimethyl diallyl ammonium and acrylamide, and the component (B) is represented by the formula (b-3) Or it is preferable that it is a compound represented by (b-4).
• the cleaning composition of the present invention contains the component (A) and the component (B), the component (A) is a copolymer of dimethyl diallyl ammonium and acrylamide, and the component (B) is represented by the formula (b-3) Or the compound represented by (b-4), wherein the content of the component (A) is 0.1 to 5% by mass relative to the total mass of the cleaning composition, and the content of the component (B) However, the content is preferably 0.1 to 5% by mass relative to the total mass of the cleaning composition.
• the cleaning composition of the present invention contains the component (A), the component (B), and the component (C), the component (A) is a copolymer of dimethyldiallylammonium and acrylamide, and the component (B) is represented by the formula In the compound represented by (b-3) or (b-4), the component (C) is preferably a linear alkylbenzene sulfonate.
• the cleaning composition of the present invention contains the component (A), the component (B), and the component (C), the component (A) is a copolymer of dimethyldiallylammonium and acrylamide, and the component (B) is represented by the formula (B-3) or a compound represented by (b-4), wherein the component (C) is a linear alkylbenzene sulfonate, and the content of the component (A) is based on the total mass of the cleaning composition.
• the content of component (B) is 0.1 to 5% by mass relative to the total mass of the cleaning composition, and the content of component (C) is The content is preferably 2 to 20% by mass with respect to the total mass of the cleaning composition.
• the cleaning composition of the present invention contains (A) component, (B) component, (C) component, and (D) component, and (A) component is a copolymer of dimethyldiallylammonium and acrylamide.
• B) component is a compound represented by formula (b-3) or (b-4)
• C) component is a linear alkylbenzene sulfonate
• D) component is represented by formula (d-1) or A compound represented by (d-2) is preferred.
• the cleaning composition of the present invention contains (A) component, (B) component, (C) component, and (D) component, and (A) component is a copolymer of dimethyldiallylammonium and acrylamide.
• B) component is a compound represented by formula (b-3) or (b-4)
• (C) component is a linear alkylbenzene sulfonate
• (D) component is represented by formula (d-1) or The compound represented by (d-2)
• the content of the component (A) is 0.1 to 5% by mass with respect to the total mass of the cleaning composition
• the content of the component (B) is The content of the component (C) is 2 to 20% by mass with respect to the total mass of the cleaning composition
• the content of the components is preferably 10 to 50% by mass with respect to the total mass of the cleaning composition.
• the cleaning composition of the present invention contains (A) component, (B) component, (C) component, (D) component, and (E) component, and (A) component is composed of dimethyldiallylammonium and acrylamide.
• a copolymer the component (B) is a compound represented by the formula (b-3) or (b-4), the component (C) is a linear alkylbenzene sulfonate, and the component (D) is a compound represented by the formula (b) d-1) or a compound represented by (d-2), wherein the component (E) is selected from two or more monomers selected from the group consisting of alkyl acrylate, alkyl methacrylate, acrylic acid, and methacrylic acid.
• the cleaning composition of the present invention contains (A) component, (B) component, (C) component, (D) component, and (E) component, and (A) component is composed of dimethyldiallylammonium and acrylamide.
• a copolymer the component (B) is a compound represented by the formula (b-3) or (b-4), the component (C) is a linear alkylbenzene sulfonate, and the component (D) is a compound represented by the formula (b) d-1) or a compound represented by (d-2), wherein the component (E) is selected from two or more monomers selected from the group consisting of alkyl acrylate, alkyl methacrylate, acrylic acid, and methacrylic acid. It is a cross-linked copolymer to be synthesized, the content of component (A) is 0.1 to 5% by mass with respect to the total mass of the cleaning composition, and the content of component (B) is washed.
• the content of the component is 2 to 20% by mass with respect to the total mass of the cleaning composition, the content of the component (D) is 10 to 50% by mass with respect to the total mass of the cleaning composition, The content of component E) is preferably 0.1 to 5.0% by mass with respect to the total mass of the cleaning composition.
• the cleaning composition of the present invention contains (A) component, (B) component, (C) component, (D) component, (E) component, and (F) component, and (A) component is dimethyldiallyl.
• a copolymer of ammonium and acrylamide wherein the component (B) is a compound represented by the formula (b-3) or (b-4), the component (C) is a linear alkylbenzene sulfonate, and (D ) Component is a compound represented by formula (d-1) or (d-2), and (E) component is selected from the group consisting of alkyl acrylate, alkyl methacrylate, acrylic acid, and methacrylic acid.
• the cleaning composition of the present invention contains (A) component, (B) component, (C) component, (D) component, (E) component, and (F) component, and (A) component is dimethyldiallyl.
• a copolymer of ammonium and acrylamide wherein the component (B) is a compound represented by the formula (b-3) or (b-4), the component (C) is a linear alkylbenzene sulfonate, and (D ) Component is a compound represented by formula (d-1) or (d-2), and (E) component is selected from the group consisting of alkyl acrylate, alkyl methacrylate, acrylic acid, and methacrylic acid.
• a cross-linked copolymer synthesized from a plurality of types of monomers wherein the component (F) is a monohydric alcohol having 2 to 4 carbon atoms, or an organic solvent represented by the formula (f-1) or (f-2) And the content of the component (A) is the total quality of the cleaning composition
• the content of component (B) is 0.1 to 5% by mass relative to the total mass of the cleaning composition
• the content of component (C) is 2 to 20% by mass with respect to the total mass of the cleaning composition
• the content of component (D) is 10 to 50% by mass with respect to the total mass of the cleaning composition
• the content of component (E) The amount is 0.1 to 5.0% by mass with respect to the total mass of the cleaning composition
• the content of the component (F) is 3 to 25% by mass with respect to the total mass of the cleaning composition. Is preferred.
• the cleaning composition of the present invention is produced by a conventionally known method for producing a detergent.
• the cleaning composition is a liquid
• the cleaning composition is powdery
• a dry blend method in which each raw material is mixed with powder
• a dry granulation method in which the raw material is granulated while flowing, and a liquid binder is sprayed while flowing the powdered raw material
• Agitation granulation method to granulate
• extrusion granulation method to knead the raw material and extrude it with an extruder
• pulverization granulation method to knead the raw material and pulverize it
• spray drying slurry containing raw material And spray drying method for example, a dry blend method in which each raw material is mixed with powder
• a dry granulation method in which the raw material is granulated while flowing, and a liquid binder is sprayed while flowing the powdered raw material
• Agitation granulation method to granulate
• extrusion granulation method to knead the raw material and extrude it with an extruder
• pulverization granulation method
• the cleaning composition of the present invention As a method of using the cleaning composition of the present invention, for example, when used for cleaning textile products, the cleaning composition is poured into water together with the laundry at the time of washing. And a method of directly applying the agent composition, a method of preliminarily dissolving the detergent composition in water and immersing clothes. Also preferred is a method in which the detergent composition is applied to the laundry and then allowed to stand as appropriate, followed by normal laundry using a normal laundry solution. Examples of the articles to be washed include textiles such as clothes, fabrics, sheets, curtains, and carpets.
• C′-1 straight chain alkyl (carbon number 10 to 14) benzenesulfonic acid, trade name “Lypon LH-200”, average molecular weight: 322, manufactured by Lion Corporation, forms a salt with monoethanolamine in the system Existing as a linear alkylbenzene sulfonate (C-1) (average molecular weight: 383).
• D-1 polyoxyethylene alkyl ether (added with an average of 15 moles of ethylene oxide to natural alcohol CO-1270 (trade name, manufactured by Procter & Gamble)).
• E component] (E-1) A cross-linked copolymer synthesized from two or more monomers selected from the group consisting of alkyl acrylate, alkyl methacrylate, acrylic acid, and methacrylic acid, trade names “Carbopol Aqua30”, Lubrizol Made by company.
• F-1 Ethanol, trade name “specific alcohol 95 degree synthesis”, manufactured by Nippon Alcohol Sales Co., Ltd.
• F-2 Diethylene glycol monobutyl ether, trade name “butyl diglycol”, manufactured by Nippon Emulsifier Co., Ltd. -F-3: 3-methoxy-3-methylbutanol, trade name "Solfit", manufactured by Kuraray Co., Ltd.
• Common component a Polyethylene glycol: Trade name “PEG # 1000-60L” (manufactured by Lion Corporation) 2 mass%.
• coconut fatty acid NOF Corporation 4 mass%.
• Sodium benzoate trade name “Sodium benzoate”, manufactured by Toa Gosei Co., Ltd. 0.5 mass%.
• Citric acid trade name “liquid citric acid”, manufactured by Yushi Kogyo Co., Ltd., 0.5% by mass.
• Dibutyl hydroxytoluene trade name “SUMILZER BHT-R”, manufactured by Sumitomo Chemical Co., Ltd. 0.05 mass%.
• Fragrance Fragrance component a described in JP-A 2009-108248: 0.8% by mass.
• -Capsule flavor the above-mentioned capsule flavor A ... 0.1 mass%.
• -Green No. 3 (pigment): Trade name “Green No. 3”, manufactured by Hagi Kasei Co., Ltd. 0.0002% by mass.
• coconut fatty acid NOF Corporation 4 mass%.
• Sodium benzoate trade name “Sodium benzoate”, manufactured by Toa Gosei Co., Ltd. 0.5 mass%.
• Citric acid trade name “liquid citric acid”, manufactured by Yushi Kogyo Co., Ltd., 0.5% by mass.
• Dibutyl hydroxytoluene trade name “SUMILZER BHT-R”, manufactured by Sumitomo Chemical Co., Ltd. 0.05 mass%.
• Fragrance Fragrance component a described in JP-A 2009-108248: 0.8% by mass.
• -Capsule flavor the above-mentioned capsule flavor A ... 0.1 mass%.
• -Green No. 3 (pigment) Trade name “Green No. 3”, manufactured by Hagi Kasei Co., Ltd.
• a cleaning composition having the composition shown in Table 1 was prepared by the following procedure. Put polyethylene glycol, component (C), component (D), component (F), coconut fatty acid, pH adjuster (monoethanolamine) and water in a 500 mL beaker, and stir well with a magnetic stirrer (manufactured by MITAMURA KOGYO INC.). did. Subsequently, other components (A), (E), sodium benzoate, and citric acid water were added and stirred. After confirming that the pH at 25 ° C. was around 7, component (B), A dye, a fragrance (dibutylhydroxytoluene was previously dissolved), and a capsule fragrance were added to obtain a cleaning composition.
• the unit of the blending amount of each component is “mass%”.
• the blending component is not blended.
• the water content “balance” is an amount necessary to make the entire cleaning composition 100% by mass.
• surface the ratio (A / C ratio) of the compounding quantity of (A) component and (C) component in a cleaning composition is written together. The following evaluation was performed about the obtained cleaning composition. The results are also shown in Table 1.
• ⁇ Criteria 1 point: A very unsatisfactory finish that is not fluffy compared to the control fabric (a finish without any volume). 2 points: An unsatisfactory finish that is not fluffy compared to the control fabric (finish without volume). 3 points: A finish similar to that of the control cloth. 4 points: A soft and nice finish (volume finish) compared to the control cloth. 5 points: Compared to the control cloth, it has a soft and very nice finish (very voluminous finish). From the average value of the scoring results of five panelists, the finished feeling was evaluated according to the following criteria. ⁇ Evaluation criteria ⁇ A: 4 or more points. ⁇ : 3.5 or more and less than 4 points. ⁇ : 3 or more and less than 3.5. X: Less than 3 points.

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• 2017
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