WO2017110979A1 - Produit capillaire cosmétique - Google Patents

Produit capillaire cosmétique Download PDF

Info

Publication number
WO2017110979A1
WO2017110979A1 PCT/JP2016/088298 JP2016088298W WO2017110979A1 WO 2017110979 A1 WO2017110979 A1 WO 2017110979A1 JP 2016088298 W JP2016088298 W JP 2016088298W WO 2017110979 A1 WO2017110979 A1 WO 2017110979A1
Authority
WO
WIPO (PCT)
Prior art keywords
hair
mass
component
less
hair cosmetic
Prior art date
Application number
PCT/JP2016/088298
Other languages
English (en)
Japanese (ja)
Inventor
朋之 須澤
哲也 川相
Original Assignee
花王株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 花王株式会社 filed Critical 花王株式会社
Priority to SG11201805370SA priority Critical patent/SG11201805370SA/en
Publication of WO2017110979A1 publication Critical patent/WO2017110979A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair

Definitions

  • the present invention relates to hair cosmetics.
  • Patent Document 1 discloses a hair oil using a polyether-modified silicone having a specific structure, a volatile oil, and ethanol in combination. This document discloses that this hair oil is free from oiliness immediately after application, has good hair fit, and improves the crispness over time.
  • Patent Document 2 discloses a specific isoparaffinic hydrocarbon and a quick-drying hair oil containing the specific hydrocarbon.
  • the literature discloses that this quick-drying hair oil can be applied to wet hair to shorten the time to dry the hair and to give a conditioning effect to the dried hair.
  • Patent Document 3 a non-aqueous hair care composition containing a large amount of a base oil composed of isoparaffin, mineral oil, volatile silicone compound and a mixture thereof, and containing a hydrophilic material such as panthenol and a specific liquid alcohol in a certain ratio.
  • a base oil composed of isoparaffin, mineral oil, volatile silicone compound and a mixture thereof
  • a hydrophilic material such as panthenol and a specific liquid alcohol in a certain ratio.
  • Patent Document 1 JP 2011-195471 JP (Patent Document 2) JP 2015-003886 JP (Patent Document 3) JP 2014-527507 JP
  • the present invention comprises the following components (A) to (C), the mass ratio (A) / (B) of the component (A) to the component (B) is 0.8 or more and 99 or less, and the water content is
  • the present invention provides a hair cosmetic that is less than 5% by mass.
  • R 1 to R 8 each independently represents a hydrogen atom or a methyl group.
  • X represents —CH 2 —, —COO— or —CH 2 COO—.
  • n represents 1 to 7
  • m represents 0 to 2
  • l represents 0 to 2
  • n + m + 1 represents 1 to 7.
  • any one of R 4 to R 7 is a methyl group.
  • Patent Documents 1 to 3 can give a feeling of unity and conditioning after drying when applied to wet hair after shampooing. Since it was insufficient, there was a problem that the density after drying and the goodness of fingering were insufficient. In addition, when a sufficient amount is applied so that it can be uniformly applied to the entire hair, there is a problem that the weight and the feeling of hair bundle remain after drying. In Patent Document 1, problems still remain with respect to the unnatural hair bundle feeling and weight caused by volatile oil. In Patent Documents 2 and 3, the water evaporation speed of wet hair after washing is increased. Even if it was possible, there was room for improvement due to the strong unnatural touch caused by the volatile oil during the period from application to dry hair until drying.
  • the present inventors consider that the problem of the above-mentioned non-aqueous hair cosmetic is mainly that it takes time for the volatile oil to volatilize after application, and as a result of examination, a specific lipophilic solvent and a lower alcohol are used.
  • a specific lipophilic solvent and a lower alcohol are used.
  • the polymer and other ingredients contained in the hair cosmetics spread thinly and evenly very quickly, and as a result, immediately after application and after drying without giving the hair an unnatural feel and weight. Both were found to have a good feel.
  • this hair cosmetic sometimes has a problem that separation or white turbidity occurs when it absorbs water vapor in the air during use or storage.
  • the present invention when applied to dry hair, dries immediately after application, does not give a squeaky or oily feel, can naturally bundle hair without making a hair bundle after drying, and further use
  • the present invention relates to a hair cosmetic that hardly deteriorates in appearance even when water is mixed in or during storage.
  • the non-aqueous hair cosmetic containing a specific lipophilic solvent and a lower alcohol in a specific ratio contains a branched saturated or linear unsaturated aliphatic alcohol or an ether thereof
  • the present inventors are in use or stored. The inventors have found that the appearance is hardly deteriorated even when water is mixed therein, and that the touch after application is improved, and the invention has been completed.
  • the hair cosmetic composition of the present invention spreads thinly and evenly very quickly, it is dried quickly after applying the hair cosmetic composition, and there is no squeak or stickiness, and no oiliness is felt. Moreover, after drying, a natural unit can be given without giving unnatural hair bundle feeling and weight to the hair. Furthermore, the appearance of hair cosmetics is less likely to deteriorate due to moisture mixed during use and storage.
  • Component (A) is a component that controls the wetting and spreading properties of hair cosmetics and the drying rate on the hair in combination with component (B).
  • the monohydric alcohol having 1 to 4 carbon atoms of component (A) a saturated or unsaturated aliphatic alcohol can be used. These monohydric alcohols can be used alone or in combination of two or more.
  • ethanol, propanol, isopropanol, and tert-butyl alcohol are preferable, ethanol and isopropanol are more preferable, and ethanol is still more preferable.
  • the content of the component (A) in the hair cosmetic composition of the present invention is preferably 45% by mass or more, more preferably 55% by mass or more, and still more preferably 60% by mass from the viewpoint of speed of drying and lack of bundle feeling.
  • it is preferably 98% by mass or less, more preferably 90% by mass or less, still more preferably 80% by mass or less, and further preferably 75% by mass or less.
  • Component (B) is a lipophilic solvent selected from the group consisting of (B1) a liquid oil having 9 to 21 carbon atoms represented by general formula (1) and (B2) a silicone having a number average molecular weight of 100 to 1500. is there.
  • Component (B) is a component that controls the wetting and spreading properties of hair cosmetics in combination with component (A). In combination with component (A), it gives a smooth and natural feel without giving an unpleasant presence after application to hair.
  • (B1) Liquid oil of 9 to 21 carbon atoms represented by general formula (1)
  • the liquid oil of component (B1) is represented by the following general formula (1).
  • R 1 to R 8 each independently represents a hydrogen atom or a methyl group.
  • X represents —CH 2 —, —COO— or —CH 2 COO—.
  • n represents 1 to 7
  • m represents 0 to 2
  • l represents 0 to 2
  • n + m + 1 represents 1 to 7.
  • any one of R 4 to R 7 is a methyl group.
  • isododecane, hydrogenated polyisobutene, isononyl isononanoate, and isopropyl isostearate are preferred, isododecane, hydrogenated polyisobutene, and isononanoyl isononyl are more preferred, and isododecane and hydrogenated polyisobutene are more preferred.
  • Preferred liquid oils include isododecane and hydrogenated polyisobutene in which X is —CH 2 —, m is 0, l is 0, and n is 1 to 3.
  • n in the general formula (1) represents the average degree of polymerization of isobutene in parentheses, more preferably 1 to 2, and even more preferably 1.
  • Component (B1) can be used either alone or in combination of two or more.
  • Silicone component (B2) having a number average molecular weight of 100 or more and 1500 or less is a silicone having a number average molecular weight of 100 or more and 1500 or less.
  • the number average molecular weight is preferably 150 or more, more preferably 200 or more, from the viewpoint of slipperiness after coating and good finger performance. Further, from the viewpoint of lack of hair bundle feeling after drying and lightness, it is preferably 1000 or less, more preferably 700 or less, and even more preferably 500 or less.
  • the component (B2) is preferably a volatile silicone from the viewpoint of lightness after drying and from the viewpoint of not giving an unpleasant presence to the hair cosmetic after drying.
  • Volatile silicone is a highly volatile organic compound or volatile organic compound prescribed by WHO (World Health Organization), and has a boiling point of 260 ° C or lower. Further, as the volatile silicone, those having a boiling point of 50 ° C. or more are preferable.
  • silicone examples include cyclic silicones such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, and methylcyclopolysiloxane; octamethyltrisiloxane, tetradecamethylhexasiloxane, methyltrimethicone, Examples thereof include chain silicones such as methylpolysiloxane having a kinematic viscosity at 25 ° C. of 0.5 mm 2 / s to 10 mm 2 / s.
  • decamethylcyclopentasiloxane, methyl trimethicone, linear silicones are preferred, such as methyl polysiloxane of less than 6 mm 2 / s kinematic viscosity of 0.5 mm 2 / s or more at 25 ° C., decamethylcyclopentasiloxane, methyltri Meticon is more preferred.
  • Component (B2) can be used either alone or in combination of two or more.
  • component (B) either component (B1) or component (B2) can be used, or component (B1) and component (B2) can be used in combination. You can also.
  • the content of the component (B) in the hair cosmetic composition of the present invention is preferably 1% by mass or more, more preferably 10% by mass or more, and still more preferably 20% from the viewpoint of slipperiness after application and good fingering. From the viewpoint of lack of hair bundle feeling and lightness after drying, preferably 52% by mass or less, more preferably 45% by mass or less, and further preferably 40% by mass. % Or less, more preferably 35% by mass or less.
  • the mass ratio (A) / (B) of the component (A) and the component (B) in the hair cosmetic composition of the present invention is 0.8 or more and 99 or less.
  • component (B1) is used as component (B)
  • the hair cosmetic composition of the present invention has a unique property that spreads quickly on the surface whether it is a hydrophilic surface or a hydrophobic surface. Show. For this reason, whether it is healthy hair or damaged hair, hair makeup that spontaneously and quickly spreads on the hair surface as soon as the hair cosmetic is applied to the hair surface, and the hair cosmetic quickly dries on the hair surface. I guess the fee was obtained.
  • the hair cosmetic composition of the present invention has a hydrophobic surface even if it is a hydrophilic surface. Even if it is a healthy hair or a damaged hair, when applied to hair, the hair cosmetics exhibit the property of spontaneously moving on the hair surface from top to bottom while spreading sideways. For this reason, it is presumed that the hair cosmetic was obtained that spontaneously and quickly spreads on the hair surface while the hair cosmetic dries quickly on the hair surface.
  • the mass ratio (A) / (B) of the component (A) to the component (B) is preferably 1 or more, more preferably 1.2 or more, still more preferably 1.5 or more, and 2 or more. Is more preferably 50 or less, more preferably 30 or less, still more preferably 10 or less, and still more preferably 5 or less.
  • Component (C) Branched saturated or linear unsaturated aliphatic alcohol having 14 to 24 carbon atoms or ether thereof
  • Component (C) is a component that suppresses appearance deterioration due to moisture mixed in hair cosmetics, and is a branched saturated or linear unsaturated aliphatic alcohol having 14 to 24 carbon atoms or an ether thereof.
  • branched saturated aliphatic alcohols include isostearyl alcohol such as hexyl decanol, 16-methylheptadecanol, octyl decanol, decyl octanol, 2-octyldodecanol, 2-decyltetradecanol, and the like.
  • linear unsaturated aliphatic alcohol examples include oleyl alcohol.
  • ether examples include isostearyl glyceryl ether. Of these, isostearyl alcohol and isostearyl glyceryl ether are preferable, and isostearyl alcohol is more preferable.
  • the content of the component (C) in the hair cosmetic of the present invention is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, from the viewpoint of not causing appearance deterioration of the hair cosmetic during use and storage. More preferably, it is 1% by mass or more, more preferably 2% by mass or more, and preferably 10% by mass or less, more preferably 8% by mass or less, further preferably from the viewpoint of no unpleasant presence after drying. Is 6% by mass or less.
  • Component (D) Polymer for hair cosmetics having solubility or dispersibility in water or ethanol
  • the hair cosmetic of the present invention can further contain a polymer for hair cosmetics having solubility or dispersibility in water or ethanol as component (D).
  • Component (D) can be dissolved or stably dispersed in water or ethanol without using a surfactant from the viewpoint of being able to exist stably in a solvent having polarity as in component (A). It is preferable that This component (D) is applied uniformly on the hair surface according to the structure of the present invention, so that it feels uncomfortable due to the polymer and feels a natural unity and natural feel on the hair after drying.
  • a component capable of providing As such a hair cosmetic polymer having solubility or dispersibility in water or ethanol a film-forming polymer or a polyether-modified silicone is preferable.
  • a film-forming polymer as component (D).
  • the film-forming polymer that can be used for component (D) is not particularly limited as long as it has solubility or dispersibility in water or ethanol, and it has a high setting power generally used for hairdressing agents. Any one having a relatively low setting force can be used.
  • Such film-forming polymers include silicone graft polymers, urethane polymer compounds, polyvinyl pyrrolidone polymer compounds, anionic vinyl ether polymer compounds, anionic polyvinyl acetate polymer compounds, anionic (meth) Acrylic polymer compounds, amphoteric (meth) acrylic polymer compounds, nonionic (meth) acrylic polymer compounds, cationic (meth) acrylic polymer compounds, maleimide polymer compounds and the like can be mentioned.
  • silicone-based graft polymer examples include polysilicone-9 such as poly (N-formylethyleneimine) organopolysiloxane, poly (N-acetylethyleneimine) organopolysiloxane, poly (N-propionylethyleneimine) organopolysiloxane; Organopolysiloxane graft polymer described in International Publication No.
  • silicone-28 such as silicone-28; alkyl acrylate copolymer methylpolysiloxane ester such as KP-545 (Shin-Etsu Chemical Co., Ltd.); Silsoft Spread TT (Momentive) Polysilicone-17 such as Albiacrylate; alkyl acrylate / methacrylic acid / silicone copolymers such as Rubyflex Silk (BASF).
  • alkyl acrylate copolymer methylpolysiloxane ester such as KP-545 (Shin-Etsu Chemical Co., Ltd.)
  • Silsoft Spread TT (Momentive) Polysilicone-17 such as Albiacrylate
  • alkyl acrylate / methacrylic acid / silicone copolymers such as Rubyflex Silk (BASF).
  • poly (N-formylethyleneimine) organopolysiloxane poly (N-acetylethyleneimine) from the viewpoints of setability, non-stickiness upon drying, softness after application, and fingering after application
  • Organopolysiloxane Poly (N-propionylethyleneimine) Organopolysiloxane, etc.-9
  • Organopolysiloxane graft polymer described in International Publication No. 2014/002707 such as Polysilicone-28, KP-545 (Shin-Etsu) More preferred are alkyl acrylate copolymer methylpolysiloxane esters such as Chemical Industries).
  • urethane polymer compounds examples include polyurethanes such as Ruby Set P.U.R. (BASF Japan); polyurethane-14 / AMP-acrylates copolymers such as Dynam X (Akzo Nobel).
  • Polyvinylpyrrolidone polymers include Rubiscol K12, Rubiscol K17, Rubiscol K30, Rubiscol L60, Rubiscol K80, Rubiscol K90 (BASF); PVP K15, PVP K17, PVP K30, PVP K60, PVP Polyvinylpyrrolidone such as K90, PVP K120 (above Ashland), etc .; Rubiscol VA28, Rubiscol VA37, Rubiscol VA55, Rubiscol VA64P, Rubiscor VA73 (above, BASF); Rubiscol Plus (BASF), etc.
  • Polyvinylcaprolactam PVP / VA E-735, PVP / VA E-635, PVP / VA E-535, PVP / VA E-335, PVP / VA S-630, PVP / VA W-735 (above, Ashland) (Vinyl pyrrolidone / vinyl acetate) copolymer, etc .; polyvinyl pyrrolidone / vinyl acetate / vinyl propionate terpolymers such as rubiscol VAP343 (BASF); rubiflex (BASF); copolymer Polyvinylpyrrolidone / dimethylaminomethyl / acrylic acid copolymer such as 845, copolymer 937, copolymer 958 (above Ashland); polyvinylpyrrolidone / dimethylaminoethyl methacrylate / vinylcaprolactam such as copolymer VC-713 (Ashland) Copolymers; (VP /
  • (vinyl pyrrolidone / vinyl acetate) copolymer and polyvinyl pyrrolidone are more preferable from the viewpoints of smoothness immediately after coating, setability, no stickiness upon drying, and softness after coating.
  • anionic vinyl ether polymers examples include (vinyl methyl ether / ethyl maleate) copolymers such as Gantrez ES-225 (Ashland); (vinyl methyl ether / maleic acid) such as Gantrez ES-425 (Ashland) Butyl) copolymer and the like.
  • a (vinyl methyl ether / butyl maleate) copolymer is preferable from the viewpoints of setability, non-stickiness upon drying, and softness after coating.
  • anionic polyvinyl acetate polymer compounds include vinyl acetate / crotonic acid copolymers such as Resin 28-1310 (Akzo Nobel) and Rubiset CA66 (BASF); Resin 28-2930 (Akzo Nobel) (Vinyl acetate / crotonic acid / vinyl neodecanoate) copolymer; vinyl acetate / crotonic acid / vinyl propionate copolymer such as Rubiset CAP (BASF).
  • vinyl acetate / crotonic acid copolymers such as Resin 28-1310 (Akzo Nobel) and Rubiset CA66 (BASF); Resin 28-2930 (Akzo Nobel) (Vinyl acetate / crotonic acid / vinyl neodecanoate) copolymer; vinyl acetate / crotonic acid / vinyl propionate copolymer such as Rubiset CAP (BASF).
  • anionic (meth) acrylic polymer compounds include acrylic resin alkanolamine solutions such as plus size L-53P and plus size L-9540B (above, Kyoyo Chemical Industry Co., Ltd.); acrylics such as diamond hold (Mitsubishi Chemical Corporation) Acid / acrylic acid ester copolymer; Ultrahold 8, Ultrahold strong (above, BASF), Anformer V-42, Dermacryl 79 (above, Akzo Nobel), etc.
  • Acrylic acid / Acrylic amide / Acrylic Examples include ethyl acrylate copolymers; alkyl acrylate copolymers such as Aniset NF-1000 and Aniset HS-3000 (Osaka Organic Chemical Co., Ltd.).
  • amphoteric (meth) acrylic polymer compounds include (methacryloyloxyethylcarboxybetaine / Yukaformer M-75, Yukaformer R205, Yukaformer 301, Yukaformer SM (Mitsubishi Chemical), RAM Resin (Osaka Organic Chemical) Alkyl methacrylate) copolymers; (Octylacrylamide / hydroxypropyl acrylate / butylaminoethyl methacrylate) copolymers such as anformer 28-4910, anformer LV-71 (above Akzo Nobel); anformer HC ( (Alkyl acrylate / octyl acrylamide) copolymers such as Akzo Nobel); (Acrylates / lauryl acrylate / stearyl acrylate / ethylamine oxide oxide) copolymers such as Diaformer Z-651 (Mitsubishi Chemical) That.
  • Nonionic (meth) acrylic polymer compounds include (dimethylacrylamide / hydroxyethyl acrylate / methoxyethyl acrylate) copolymers such as plus size L-2700 and plus size L-2714 (above, Kyoyo Chemical Co., Ltd.) Is mentioned.
  • Examples of the cationic (meth) acrylic polymer compound include an alkylacrylamide / acrylate / alkylaminoalkylacrylamide / polyethylene glycol methacrylate copolymer described in JP-A-2-809911; and JP-A-8-291206.
  • Polyquaternium-99 such as plus size L-515 (Kohyo Chemical Industry Co., Ltd.)
  • alkyl acrylamide / acrylate / alkyl aminoalkyl acrylamide / polyethylene glycol methacrylate copolymer described in JP-A-2-809911 the alkyl acrylamide / alkyl aminoalkyl acrylamide / polyethylene glycol methacrylate copolymer described in JP-A-2-809911
  • alkyl acrylamide / alkyl aminoalkyl acrylamide / polyethylene glycol methacrylate described in JP-A-8-291206.
  • a copolymer, polyquaternium-11 is preferred.
  • maleimide polymer compound examples include (isobutylene / ethylmaleimide / hydroxyethylmaleimide) copolymers such as Aquaflex FX-64 (IS Japan Co., Ltd.).
  • silicone-based graft polymers silicone-based graft polymers, polyvinylpyrrolidone-based polymer compounds, anionic polyvinyl acetate-based polymer compounds, and amphoteric (metabolites) from the viewpoints of setability, non-stickiness of dry wrinkles, and softness after coating.
  • Acrylic polymer compounds, nonionic (meth) acrylic polymers, and cationic (meth) acrylic compounds are more preferred.
  • a polyether-modified silicone as the component (D) from the viewpoint of further improving the creaking immediately after coating and the unity after drying.
  • the polyether-modified silicone that can be used for the component (D) is not particularly limited as long as it has solubility or dispersibility in water or ethanol.
  • Polyoxyethylene-modified silicone, polypropylene-modified silicone, polyoxyethylene / Examples thereof include polyoxypropylene-modified silicone and polyglycerin-modified silicone, and examples of the modification include a pendant type (side chain modified type) and a linear copolymer type.
  • Such a polyether-modified silicone is preferably a copolymer having a block chain of an organosiloxane chain and a polyalkylene chain, such as Silsoft A + (Momentive) (PEG-40 / PPG-8 ⁇ ⁇ methylaminopropyl / hydro Propylene dimethicone) copolymer; Polysilicone-13 such as FZ-2222, FZ-2233, CB2250 (Toray Dow Corning); PEG-12 dimethicone such as Silwet L-8600 (Momentive), Silsoft 900 (Momentive) PPG-12 dimethicone; PEG-10 dimethicone such as Silsoft 860 (Momentive); Silbis 104 (Toray Dow Corning) (bisisobutyl PEG-14 / amodimethicone) copolymer; Sil Style 401 (Toray Dow Corning) ) (Bisisobutyl PEG / PPG-20 / 35 / Amodimethi
  • a copolymer having a block chain of an amino-modified organopolysiloxane chain and a polyoxyalkylene chain is preferable, such as (bisisobutyl PEG-14 / amodimethicone) copolymer, (bisisobutyl PEG / PPG-20 / 35 / amodimethicone).
  • linear copolymeric amino-polyether modified silicones such as) copolymers, bis-isopropanolamino-PG-propyl dimethicone / bis-isobutyl PEG-14 copolymer, (bisisobutyl PEG-15 / amodimethicone) copolymer, More preferred is a (bisisobutyl PEG-15 / amodimethicone) copolymer.
  • film-forming polymers and polyether-modified silicones can be used either alone or in combination of two or more, but from the viewpoint of further improving both the natural unity feeling and natural feeling after drying. It is preferable to use a film-forming polymer and a polyether-modified silicone in combination as component (D).
  • component (D) is an amphiphilic film-forming polymer or polyether-modified silicone.
  • the amphiphilic film-forming polymer is a set polymer containing 10% to 98% of a hydrophobic portion by mass ratio. Examples of such amphiphilic film-forming polymers include Polysilicone-9 and Polysilicone-28. Polysilicone-9 is particularly preferable.
  • the content of the component (D) in the hair cosmetic composition of the present invention is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, and still more preferably 1% by mass from the viewpoint of imparting hair cohesiveness after drying. % Or more. Further, from the viewpoint of giving a natural feel and unity feeling without giving the hair a feeling of weight and hair bundle after drying, it is preferably 10% by mass or less, more preferably 7% by mass or less, and further preferably 5% by mass or less. .
  • the component (E) further includes polyol, urea, organic acid, polyoxyalkylene alkyl glucoside and It is preferable to contain one or more selected from polyoxyalkylene glyceryl ethers.
  • Suitable polyols include 1,3-butanediol, glycerin, polyglycerin and the like.
  • Suitable organic acids include lactic acid, malic acid, citric acid and the like.
  • Suitable polyoxyalkylene alkyl glucosides include PPG-10 methyl glucose, PPG-20 methyl glucose, methyl glucose-10, methyl glucose-20 and the like.
  • Suitable polyoxyalkylene glyceryl ethers include PEG / PPG / polybutylene glycol-8 / 5/3 glycerol.
  • urea, lactic acid, and glycerin are preferable from the viewpoint of high-temperature storage stability, and urea is more preferable.
  • the content of the component (E) in the hair cosmetic composition of the present invention is preferably 0.1% by mass or more, more preferably 0.5% by mass or more from the viewpoint of ensuring high-temperature stability, and high-temperature stability and natural feel. From the viewpoint of achieving both, it is preferably 3% by mass or less, more preferably 2% by mass or less.
  • the hair cosmetic composition of the present invention preferably contains no water. However, mixing of a trace amount to a small amount (for example, 0.0001% by mass or more) of water may be unavoidable. In such a case, it is preferable that the amount of water is small. Specifically, the water content is preferably less than 5% by mass, more preferably less than 3% by mass, and even more preferably less than 0.5% by mass.
  • cosmetic oils other than components (B) and (D) can be incorporated within the limits that do not interfere with the effects of the present invention.
  • the content of the cosmetic oil other than components (B) and (D) in the hair cosmetic is preferably 0.1% by mass or more and 10% by mass or less.
  • Such cosmetic oils include glycerides such as castor oil, cacao oil, mink oil, avocado oil, olive oil; waxes such as beeswax, whale wax, lanolin, carnauba wax; isopropyl myristate, hexyl laurate, lactic acid Cetyl, propylene glycol monostearate, oleyl oleate, hexadecyl 2-ethylhexanoate, esters of octyldodecyl myristate; dimethylpolysiloxane, methylphenylpolysiloxane, epoxy-modified silicone oil, amino-modified silicone oil, alkyl-modified silicone Examples thereof include silicone derivatives excluding those contained in components (B) and (D) such as oil.
  • glycerides such as castor oil, cacao oil, mink oil, avocado oil, olive oil
  • waxes such as beeswax, whale wax, lanolin, carnauba
  • the hair cosmetic composition of the present invention can contain a fragrance, a pigment, and a preservative and an antioxidant to prevent the daily deterioration of the hair cosmetic composition in order to increase the commercial value.
  • a fragrance e.g., peppermint, kaolin, kaolin, kaolin, kaolin, kaolin, kaolin, kaolin, kaolin, kaolin, kaolin, kaolin, kaolin, kaolin, kaolin, etc. You can also.
  • the dosage form of the hair cosmetic composition of the present invention is not particularly limited, and can be transparent liquid, lotion, emulsion, mist (hair mist, hair spray), foam (hair mousse), etc. It is preferable that the dosage form is applied in the form of a non-aerosol, and more preferably a non-aerosol type dosage form.
  • component (D) is an amphiphilic film-forming polymer or polyether from the viewpoint of excellent dispersibility and solubility in both component (A) and component (B). A modified silicone is preferred.
  • the content of each component refers to the content in the entire composition of the aerosol stock solution that does not contain a propellant.
  • the hair cosmetic composition of the present invention can be used by filling an arbitrary container in accordance with the dosage form. Since the appearance of the hair cosmetic of the present invention hardly deteriorates even when water is mixed, the material of the container may be any material as long as it is generally used in the field of hair cosmetics. Even a container made of a material having moisture permeability, such as a plastic container, is excellent in that it can be suitably used.
  • the hair cosmetic composition of the present invention can be suitably used as a hair styling agent.
  • a method for use as a hair styling agent that is, as a hair styling method, any method can be adopted as long as the hair cosmetic composition of the present invention is applied to the hair and the hair style is adjusted.
  • the hair cosmetic composition of the present invention may be applied to wet hair or dry hair, but is preferably applied to dry hair.
  • hair cosmetic directly in the form of a mist, and to shape the hair while combing with a handbrush, comb, brush or the like.
  • ⁇ 1> Contains the following components (A) to (C), the mass ratio (A) / (B) of component (A) to component (B) is 0.8 or more and 99 or less, and the water content is less than 5% by mass Hair cosmetics.
  • R 1 to R 8 each independently represents a hydrogen atom or a methyl group.
  • X represents —CH 2 —, —COO— or —CH 2 COO—.
  • n represents 1 to 7
  • m represents 0 to 2
  • l represents 0 to 2
  • n + m + 1 represents 1 to 7.
  • any one of R 4 to R 7 is a methyl group.
  • component (A) is ethanol, propanol, isopropanol, tert-butyl alcohol, more preferably ethanol, isopropanol, and still more preferably ethanol.
  • component (A) is preferably 45% by mass or more, more preferably 55% by mass or more, still more preferably 60% by mass or more, and preferably 98% by mass or less, more preferably 90% by mass or less, More preferably, it is 80 mass% or less, More preferably, it is 75 mass% or less,
  • the liquid oil having 9 to 21 carbon atoms represented by the general formula (1) of component (B) is preferably isododecane, hydrogenated polyisobutene, isononyl isononanoate or isopropyl isostearate, and isododecane, hydrogenated polyisobutene or isononanoic acid.
  • the number average molecular weight of the silicone of component (B) is preferably 150 or more, more preferably 200 or more, and preferably 1000 or less, more preferably 700 or less, more preferably 500 or less ⁇ 1> to ⁇
  • ⁇ 7> The hair cosmetic composition according to any one of ⁇ 1> to ⁇ 6>, wherein the silicone of component (B) is preferably a volatile silicone.
  • the content of component (B) is preferably 1% by mass or more, more preferably 10% by mass or more, still more preferably 20% by mass or more, still more preferably 25% by mass or more, and preferably 52% by mass or less.
  • the mass ratio (A) / (B) of component (A) to component (B) is preferably 1 or more, more preferably 1.2 or more, still more preferably 1.5 or more, still more preferably 2 or more, and preferably 50
  • Component (C) is preferably isostearyl alcohol, 2-octyldodecanol, 2-decyltetradecanol, oleyl alcohol, isostearyl glyceryl ether, more preferably isostearyl alcohol, isostearyl glyceryl ether, more preferably isostearyl.
  • the hair cosmetic composition according to any one of ⁇ 1> to ⁇ 9>, which is alcohol.
  • the content of component (C) is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, still more preferably 1% by mass or more, still more preferably 2% by mass or more, and preferably 10% by mass or less.
  • component (D) is preferably a film-forming polymer or a polyether-modified silicone.
  • the content of component (D) is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, still more preferably 1% by mass or more, and preferably 10% by mass or less, more preferably 7% by mass or less,
  • the component (E) further includes one or more selected from polyols, ureas, organic acids, polyoxyalkylene alkyl glucosides and polyoxyalkylene glyceryl ethers, and any one of ⁇ 1> to ⁇ 14> The hair cosmetic composition described.
  • component (E) is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, and preferably 3% by mass or less, more preferably 2% by mass or less.
  • the hair cosmetic composition according to ⁇ 1> to ⁇ 16> wherein the moisture content is preferably less than 5% by mass, more preferably less than 3% by mass, even more preferably less than 0.5% by mass, and even more preferably no water.
  • the hair cosmetic composition according to any one of ⁇ 1> to ⁇ 17> which is preferably used by filling a container made of a material having moisture permeability, more preferably a plastic container.
  • the hair cosmetics shown in Table 1 having a good water resistance test were pump spray containers manufactured by Yoshino Seisakusho Co., Ltd. (sprayers having an average particle diameter of 60 ⁇ m when the hair cosmetics of Examples and Comparative Examples were sprayed. And the performance was evaluated according to the following method and criteria.
  • evaluation hair bundle A hair bundle with a length of 30 cm and a weight of 8 g was made of Japanese weak hair with no chemical treatment history. After wetting the hair bundle with 40 ° C. tap water for 30 seconds, 3 g of Kao's success medicinal shampoo h was applied, washed by lathering for 30 seconds, and rinsed with 40 ° C. tap water for 30 seconds. This shampoo operation was repeated twice. Next, 3 g of model rinse shown in the following prescription was applied, allowed to blend for 15 seconds, and then rinsed with tap water at 40 ° C. for 30 seconds. Next, after drying with towels, those naturally dried under laboratory conditions for 6 hours were used as evaluation hair bundles.
  • composition of model rinse Ingredient (mass%) Cetearyl alcohol 2.0 Steartrimonium chloride 0.76 Distearyldimonium chloride 2.7 Propylene glycol 5.0 Isopropanol 0.6 Ethylparaben 0.1 Ion exchange water balance ⁇ br/> 100 in total

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne un produit capillaire cosmétique qui contient les constituants suivants (A) à (C), le rapport massique (A)/(B) étant de 0,8 à 99 compris, et la teneur en eau étant inférieure à 5 %. (A) : un alcool mono-hydrique C1-4; (B) un solvant lipophile choisi parmi les huiles liquides C9-21 représentées par la formule (1) [R1-R8 sont H ou CH3. X représente -CH2-, -COO- ou -CH2COO-. n vaut 1 à 7, m et l valent 0 à 2 et n+m+l est compris entre 1 et 7. Lorsque m et l sont chacun égaux ou supérieurs à 1, l'un parmi R4-R7 est CH3.] et les silicones ont un poids moléculaire moyen en nombre de 100 à 1 500 compris; (C) est un alcool aliphatique insaturé linéaire ou saturé ramifié C14-24, ou son éther.
PCT/JP2016/088298 2015-12-25 2016-12-22 Produit capillaire cosmétique WO2017110979A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SG11201805370SA SG11201805370SA (en) 2015-12-25 2016-12-22 Hair cosmetic

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2015-255119 2015-12-25
JP2015255119 2015-12-25

Publications (1)

Publication Number Publication Date
WO2017110979A1 true WO2017110979A1 (fr) 2017-06-29

Family

ID=59089519

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2016/088298 WO2017110979A1 (fr) 2015-12-25 2016-12-22 Produit capillaire cosmétique

Country Status (4)

Country Link
JP (1) JP6903428B2 (fr)
SG (1) SG11201805370SA (fr)
TW (1) TWI775736B (fr)
WO (1) WO2017110979A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3892335A4 (fr) * 2018-12-07 2022-09-07 Kao Corporation Composition cosmétique pour la peau

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6955615B1 (ja) * 2020-09-04 2021-10-27 コタ株式会社 油性毛髪化粧料

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2942008A (en) * 1956-12-10 1960-06-21 Irwin I Lubowe Solubilizing of mineral, vegetable, and animal oils for cosmetic, pharmaceutical, and industrial purposes
JPS59112910A (ja) * 1982-12-07 1984-06-29 ダウ・コ−ニング・リミテツド ヘアスプレ−組成物
JPH10218740A (ja) * 1997-02-04 1998-08-18 Shiseido Co Ltd 毛髪化粧料
JPH1179953A (ja) * 1997-07-18 1999-03-23 Kose Corp 毛髪化粧料
JP2001348313A (ja) * 2000-04-06 2001-12-18 Kao Corp 毛髪化粧料
JP2003137739A (ja) * 2001-11-02 2003-05-14 Shiseido Co Ltd スプレー式毛髪化粧料
JP2005206552A (ja) * 2004-01-26 2005-08-04 Kanebo Cosmetics Inc エアゾールスプレー組成物
JP2010053083A (ja) * 2008-08-28 2010-03-11 Mandom Corp エアゾールスプレー型整髪剤用組成物
JP2014034528A (ja) * 2012-08-07 2014-02-24 Takara Belmont Co Ltd 頭髪用化粧料
JP2014133717A (ja) * 2013-01-10 2014-07-24 Mandom Corp エアゾールスプレー整髪剤組成物及びエアゾールスプレー整髪剤

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2942008A (en) * 1956-12-10 1960-06-21 Irwin I Lubowe Solubilizing of mineral, vegetable, and animal oils for cosmetic, pharmaceutical, and industrial purposes
JPS59112910A (ja) * 1982-12-07 1984-06-29 ダウ・コ−ニング・リミテツド ヘアスプレ−組成物
JPH10218740A (ja) * 1997-02-04 1998-08-18 Shiseido Co Ltd 毛髪化粧料
JPH1179953A (ja) * 1997-07-18 1999-03-23 Kose Corp 毛髪化粧料
JP2001348313A (ja) * 2000-04-06 2001-12-18 Kao Corp 毛髪化粧料
JP2003137739A (ja) * 2001-11-02 2003-05-14 Shiseido Co Ltd スプレー式毛髪化粧料
JP2005206552A (ja) * 2004-01-26 2005-08-04 Kanebo Cosmetics Inc エアゾールスプレー組成物
JP2010053083A (ja) * 2008-08-28 2010-03-11 Mandom Corp エアゾールスプレー型整髪剤用組成物
JP2014034528A (ja) * 2012-08-07 2014-02-24 Takara Belmont Co Ltd 頭髪用化粧料
JP2014133717A (ja) * 2013-01-10 2014-07-24 Mandom Corp エアゾールスプレー整髪剤組成物及びエアゾールスプレー整髪剤

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3892335A4 (fr) * 2018-12-07 2022-09-07 Kao Corporation Composition cosmétique pour la peau
US11938207B2 (en) 2018-12-07 2024-03-26 Kao Corporation Cosmetic composition for skin

Also Published As

Publication number Publication date
TW201722397A (zh) 2017-07-01
SG11201805370SA (en) 2018-07-30
TWI775736B (zh) 2022-09-01
JP2017119685A (ja) 2017-07-06
JP6903428B2 (ja) 2021-07-14

Similar Documents

Publication Publication Date Title
KR100287807B1 (ko) 모발컨디셔닝조성물
CA2634685C (fr) Nouvelles compositions de traitement capillaire
EP2928563B1 (fr) Composition comprenant une résine de silicone et une gomme de silicone, produits de soin personnel la contenant
KR101051897B1 (ko) 정발용 화장료
JP5535832B2 (ja) 整髪用化粧料
JP6955859B2 (ja) 毛髪化粧料
WO2017099158A1 (fr) Cosmétique capillaire
EP2468238B1 (fr) Fixateur de cheveux volumisant avec amélioration de la technique sensorielle
JP6903428B2 (ja) 毛髪化粧料
JP6618404B2 (ja) 乳化保湿化粧料およびその使用方法
TW201121578A (en) Hairdressing cosmetic
JP2003342137A (ja) 染毛剤組成物
JP6909179B2 (ja) 油性化粧料
JP2001114656A (ja) 少なくとも１つのシリコーン／アクリル酸コポリマーと少なくとも１つのコンディショニング剤を含む化粧品組成物
JPH0720851B2 (ja) 毛髪化粧料
JP4136962B2 (ja) 毛髪化粧料
JP3822118B2 (ja) 毛髪化粧料
JPH01175923A (ja) 毛髪化粧料
JP2005082518A (ja) エアゾール型整髪料
JP2002370941A (ja) 毛髪化粧料
KR102363134B1 (ko) 실리콘중수(w/s) 유화형 모발 화장료 조성물
KR101965065B1 (ko) 투명성 고형왁스 조성물
JPWO2019155673A1 (ja) 整髪剤組成物
JPH0477414A (ja) 水性整髪剤組成物
JP2004143074A (ja) 霧状毛髪化粧料

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 16878866

Country of ref document: EP

Kind code of ref document: A1

WWE Wipo information: entry into national phase

Ref document number: 11201805370S

Country of ref document: SG

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 16878866

Country of ref document: EP

Kind code of ref document: A1