WO2017099158A1 - Cosmétique capillaire - Google Patents

Cosmétique capillaire Download PDF

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Publication number
WO2017099158A1
WO2017099158A1 PCT/JP2016/086475 JP2016086475W WO2017099158A1 WO 2017099158 A1 WO2017099158 A1 WO 2017099158A1 JP 2016086475 W JP2016086475 W JP 2016086475W WO 2017099158 A1 WO2017099158 A1 WO 2017099158A1
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Prior art keywords
hair
component
mass
hair cosmetic
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PCT/JP2016/086475
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English (en)
Japanese (ja)
Inventor
朋之 須澤
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花王株式会社
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Priority to SG11201804918SA priority Critical patent/SG11201804918SA/en
Publication of WO2017099158A1 publication Critical patent/WO2017099158A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring

Definitions

  • the present invention relates to hair cosmetics.
  • non-aqueous hair cosmetics especially products that are generally called hair oils, but due to the oil contained in the products, the oils are used at the time of application and after application to the hair.
  • problems such as the feeling of slipping over for a while, the feeling of unnatural hair bundles remaining, the appearance and feel of the hair after application, and the stickiness remaining.
  • Patent Document 1 discloses a hair oil using a polyether-modified silicone having a specific structure, a volatile oil, and ethanol in combination. This document discloses that this hair oil is free from oiliness immediately after application, has good hair fit, and improves the crispness over time.
  • Patent Document 2 discloses a split coat agent containing an organic solvent, volatile oil, and a specific dimethylpolysiloxane derivative. The document discloses that the split coat agent can coat split ends without stickiness and can be easily washed away.
  • Patent Document 1 JP-A-2011-195471
  • Patent Document 2 JP-A-8-40839
  • the present invention contains the following components (A) to (C), the content of the component (A) is 0.1% by mass or more and 10% by mass or less, and the total content of the component (B) and the component (C) is 30%.
  • a hair cosmetic composition having a mass ratio (B) / (C) of 0.8% to 99% by mass and above.
  • C) Silicone oil having a number average molecular weight of 100 or more and 1500 or less
  • Patent Document 1 When the hair oil of Patent Document 1 is applied to wet hair after shampooing, it can give a feeling of unity and conditioning after drying, but when applied to dry hair, there is still uneven application, There was a problem that the unity and feeling after drying were insufficient. In addition, when a sufficient amount is applied so that it can be uniformly applied to the entire hair, there is a problem that the weight and the feeling of hair bundle remain after drying.
  • the split hair coating agent of Patent Document 2 preferably contains 10 to 50% by weight, particularly 20 to 40% by weight, of a dimethylpolysiloxane derivative in the entire composition in order to coat split ends. .
  • the dimethylpolysiloxane derivative remaining on the hair in a large amount even after drying has left a feeling of weight and hair bundle, and it has been difficult to make it feel smooth.
  • the present invention has good wet spread when applied to dry hair, and dries immediately after application, does not give a squeaky feeling or a feeling of wet hair, and after drying the hair naturally without making hair bundles.
  • the present invention relates to a hair cosmetic that can be put together.
  • the inventors of the present invention have a problem in the above-described non-aqueous hair cosmetics mainly that the wet spreadability on dry hair is insufficient and that volatile oil takes time to volatilize after application. I thought and examined it. As a result, when specific silicone oil and lower alcohol are in a specific ratio, the surface tension of the solvent increases remarkably, and the hair cosmetic applied on the hair moves spontaneously on the hair surface, while the contained polymer is on the hair surface. Found to coat. As a result, the polymer component contained can be quickly and uniformly applied to the hair surface, and further dried extremely quickly, so that the presence of hair cosmetics disappears on the hair immediately after application, and after drying The invention was completed by finding that the hair of the hair was gathered.
  • the hair cosmetic composition of the present invention spontaneously moves on the hair surface with dry hair and dries quickly. For this reason, the polymer in the hair cosmetic quickly spreads thinly and evenly on the hair surface, and after application, the presence of the hair cosmetic disappears quickly, and there is no unnatural hair bundle feeling and nothing is attached Gives a natural unity while being a touch. Furthermore, there is no squeak or stickiness when applied, and the hair does not feel wet.
  • Component (A) Polymer for hair cosmetics having solubility or dispersibility in water or ethanol
  • Component (A) is a polymer that can be dissolved or stably dispersed in water or ethanol without using a surfactant, and can be present stably in a polar solvent such as component (B). It is.
  • This component (A) is a component that can be applied uniformly on the hair surface according to the structure of the present invention, and can give the hair a natural unity and natural feel without feeling the presence of the polymer. .
  • a hair cosmetic polymer having solubility or dispersibility in water or ethanol a film-forming polymer or a polyether-modified silicone is preferable.
  • a film-forming polymer as the component (A).
  • the film-forming polymer that can be used for the component (A) is not particularly limited as long as it has solubility or dispersibility in water or ethanol, and has a high setting power generally used for hairdressing agents. Any one having a relatively low setting force can be used.
  • Such film-forming polymers include silicone graft polymers, urethane polymer compounds, polyvinyl pyrrolidone polymer compounds, anionic vinyl ether polymer compounds, anionic polyvinyl acetate polymer compounds, anionic (meth) Acrylic polymer compounds, amphoteric (meth) acrylic polymer compounds, nonionic (meth) acrylic polymer compounds, cationic (meth) acrylic polymer compounds, maleimide polymer compounds and the like can be mentioned.
  • silicone-based graft polymer examples include polysilicone-9 such as poly (N-formylethyleneimine) organopolysiloxane, poly (N-acetylethyleneimine) organopolysiloxane, poly (N-propionylethyleneimine) organopolysiloxane; Organopolysiloxane graft polymer described in International Publication No.
  • silicone-28 such as silicone-28; alkyl acrylate copolymer methylpolysiloxane ester such as KP-545 (Shin-Etsu Chemical Co., Ltd.); Silsoft Spread TT (Momentive) Polysilicone-17 such as Albiacrylate; alkyl acrylate / methacrylic acid / silicone copolymers such as Rubyflex Silk (BASF).
  • alkyl acrylate copolymer methylpolysiloxane ester such as KP-545 (Shin-Etsu Chemical Co., Ltd.)
  • Silsoft Spread TT (Momentive) Polysilicone-17 such as Albiacrylate
  • alkyl acrylate / methacrylic acid / silicone copolymers such as Rubyflex Silk (BASF).
  • poly (N-formylethyleneimine) organopolysiloxane poly (N-acetylethyleneimine) from the viewpoints of setability, non-stickiness upon drying, softness after application, and fingering after application
  • Organopolysiloxane Poly (N-propionylethyleneimine) Organopolysiloxane, etc.-9
  • Organopolysiloxane graft polymer described in International Publication No. 2014/002707 such as Polysilicone-28, KP-545 (Shin-Etsu) More preferred are alkyl acrylate copolymer methylpolysiloxane esters such as Chemical Industries).
  • urethane polymer compounds examples include polyurethanes such as Ruby Set P.U.R. (BASF Japan); polyurethane-14 / AMP-acrylates copolymers such as Dynam X (Akzo Nobel).
  • Polyvinylpyrrolidone polymers include Rubiscol K12, Rubiscol K17, Rubiscol K30, Rubiscol L60, Rubiscol K80, Rubiscol K90 (BASF); PVP K15, PVP K17, PVP K30, PVP K60, PVP Polyvinylpyrrolidone such as K90, PVP K120 (above Ashland), etc .; Rubiscol VA28, Rubiscol VA37, Rubiscol VA55, Rubiscol VA64P, Rubiscor VA73 (above, BASF); Rubiscol Plus (BASF), etc.
  • Polyvinylcaprolactam PVP / VA E-735, PVP / VA E-635, PVP / VA E-535, PVP / VA E-335, PVP / VA S-630, PVP / VA W-735 (above, Ashland) (Vinyl pyrrolidone / vinyl acetate) copolymer, etc .; polyvinyl pyrrolidone / vinyl acetate / vinyl propionate terpolymers such as rubiscol VAP343 (BASF); rubiflex (BASF); copolymer Polyvinylpyrrolidone / dimethylaminomethyl / acrylic acid copolymer such as 845, copolymer 937, copolymer 958 (above Ashland); polyvinylpyrrolidone / dimethylaminoethyl methacrylate / vinylcaprolactam such as copolymer VC-713 (Ashland) Copolymers; (VP /
  • (vinyl pyrrolidone / vinyl acetate) copolymer and polyvinyl pyrrolidone are more preferable from the viewpoints of smoothness immediately after coating, setability, no stickiness upon drying, and softness after coating.
  • anionic vinyl ether polymers examples include (vinyl methyl ether / ethyl maleate) copolymers such as Gantrez ES-225 (Ashland); (vinyl methyl ether / maleic acid) such as Gantrez ES-425 (Ashland) Butyl) copolymer and the like.
  • a (vinyl methyl ether / butyl maleate) copolymer is preferable from the viewpoints of setability, non-stickiness upon drying, and softness after coating.
  • anionic polyvinyl acetate polymer compounds include vinyl acetate / crotonic acid copolymers such as Resin 28-1310 (Akzo Nobel) and Rubiset CA66 (BASF); Resin 28-2930 (Akzo Nobel) (Vinyl acetate / crotonic acid / vinyl neodecanoate) copolymer; vinyl acetate / crotonic acid / vinyl propionate copolymer such as Rubiset CAP (BASF).
  • vinyl acetate / crotonic acid copolymers such as Resin 28-1310 (Akzo Nobel) and Rubiset CA66 (BASF); Resin 28-2930 (Akzo Nobel) (Vinyl acetate / crotonic acid / vinyl neodecanoate) copolymer; vinyl acetate / crotonic acid / vinyl propionate copolymer such as Rubiset CAP (BASF).
  • anionic (meth) acrylic polymer compounds include acrylic resin alkanolamine solutions such as plus size L-53P and plus size L-9540B (above, Kyoyo Chemical Industry Co., Ltd.); acrylics such as diamond hold (Mitsubishi Chemical Corporation) Acid / acrylic acid ester copolymer; Ultrahold 8, Ultrahold strong (above, BASF), Anformer V-42, Dermacryl 79 (above, Akzo Nobel), etc.
  • Acrylic acid / Acrylic amide / Acrylic Examples include ethyl acrylate copolymers; alkyl acrylate copolymers such as Aniset NF-1000 and Aniset HS-3000 (Osaka Organic Chemical Co., Ltd.).
  • amphoteric (meth) acrylic polymer compounds include (methacryloyloxyethylcarboxybetaine / Yukaformer M-75, Yukaformer R205, Yukaformer 301, Yukaformer SM (Mitsubishi Chemical), RAM Resin (Osaka Organic Chemical) Alkyl methacrylate) copolymers; (Octylacrylamide / hydroxypropyl acrylate / butylaminoethyl methacrylate) copolymers such as anformer 28-4910, anformer LV-71 (above Akzo Nobel); anformer HC ( (Alkyl acrylate / octyl acrylamide) copolymers such as Akzo Nobel); (Acrylates / lauryl acrylate / stearyl acrylate / ethylamine oxide oxide) copolymers such as Diaformer Z-651 (Mitsubishi Chemical) That.
  • Nonionic (meth) acrylic polymer compounds include (dimethylacrylamide / hydroxyethyl acrylate / methoxyethyl acrylate) copolymers such as plus size L-2700 and plus size L-2714 (above, Kyoyo Chemical Co., Ltd.) Is mentioned.
  • Examples of the cationic (meth) acrylic polymer compound include an alkylacrylamide / acrylate / alkylaminoalkylacrylamide / polyethylene glycol methacrylate copolymer described in JP-A-2-809911; and JP-A-8-291206.
  • Polyquaternium-99 such as plus size L-515 (Kohyo Chemical Industry Co., Ltd.)
  • alkyl acrylamide / acrylate / alkyl aminoalkyl acrylamide / polyethylene glycol methacrylate copolymer described in JP-A-2-809911 the alkyl acrylamide / alkyl aminoalkyl acrylamide / polyethylene glycol methacrylate copolymer described in JP-A-2-809911
  • alkyl acrylamide / alkyl aminoalkyl acrylamide / polyethylene glycol methacrylate described in JP-A-8-291206.
  • a copolymer, polyquaternium-11 is preferred.
  • maleimide polymer compound examples include (isobutylene / ethylmaleimide / hydroxyethylmaleimide) copolymers such as Aquaflex FX-64 (IS Japan Co., Ltd.).
  • silicone-based graft polymers silicone-based graft polymers, polyvinylpyrrolidone-based polymer compounds, anionic polyvinyl acetate-based polymer compounds, and amphoteric (metabolites) from the viewpoints of setability, non-stickiness of dry wrinkles, and softness after coating.
  • Acrylic polymer compounds, nonionic (meth) acrylic polymers, and cationic (meth) acrylic compounds are more preferred.
  • polyether-modified silicone as the component (A) from the viewpoint of further improving the absence of creaking immediately after coating and the unity after drying.
  • the polyether-modified silicone that can be used for the component (A) is not particularly limited as long as it has solubility or dispersibility in water or ethanol.
  • Polyoxyethylene-modified silicone, polypropylene-modified silicone, polyoxyethylene / Examples thereof include polyoxypropylene-modified silicone and polyglycerin-modified silicone, and examples of the modification include a pendant type (side chain modified type) and a linear copolymer type.
  • Such a polyether-modified silicone is preferably a copolymer having a block chain of an organosiloxane chain and a polyalkylene chain, such as Silsoft A + (Momentive) (PEG-40 / PPG-8 ⁇ ⁇ methylaminopropyl / hydro Propylene dimethicone) copolymer; Polysilicone-13 such as FZ-2222, FZ-2233, CB2250 (Toray Dow Corning); PEG-12 dimethicone such as Silwet L-8600 (Momentive), Silsoft 900 (Momentive) PPG-12 dimethicone; PEG-10 dimethicone such as Silsoft 860 (Momentive); Silbis 104 (Toray Dow Corning) (bisisobutyl PEG-14 / amodimethicone) copolymer; Sil Style 401 (Toray Dow Corning) ) (Bisisobutyl PEG / PPG-20 / 35 / Amodimethi
  • a copolymer having a block chain of an amino-modified organopolysiloxane chain and a polyoxyalkylene chain is preferable, such as (bisisobutyl PEG-14 / amodimethicone) copolymer, (bisisobutyl PEG / PPG-20 / 35 / amodimethicone).
  • linear copolymeric amino-polyether modified silicones such as) copolymers, bis-isopropanolamino-PG-propyl dimethicone / bis-isobutyl PEG-14 copolymer, (bisisobutyl PEG-15 / amodimethicone) copolymer, More preferred is a (bisisobutyl PEG-15 / amodimethicone) copolymer.
  • These hair cosmetic polymers can be used either alone or in combination of two or more, but as a component (A) from the viewpoint of further improving both the natural unity and the natural feel. It is preferable to use the aforementioned film-forming polymer and polyether-modified silicone in combination.
  • component (A) is an amphiphilic film-forming polymer or polyether-modified silicone.
  • the amphiphilic film-forming polymer is a set polymer containing 10 to 98% of a hydrophobic portion by mass ratio. Examples of such amphiphilic set polymers include Polysilicone-9 and Polysilicone-28. Polysilicone-9 is particularly preferable.
  • the content of the component (A) in the hair cosmetic composition of the present invention is 0.1% by mass or more, preferably 0.5% by mass or more, more preferably 1% by mass or more from the viewpoint of imparting hair cohesiveness. is there. Further, from the viewpoint of giving a natural feel and unity feeling without giving the hair a feeling of weight or hair bundle, it is 10% by mass or less, preferably 7% by mass or less, more preferably 5% by mass or less.
  • Component (B) is a component that controls the wetting and spreading properties of the hair cosmetic containing component (A) and the drying rate on the hair in combination with component (C).
  • the monohydric alcohol having 1 to 4 carbon atoms as the component (B) a saturated or unsaturated aliphatic alcohol can be used. These monohydric alcohols can be used alone or in combination of two or more.
  • ethanol, propanol, isopropanol, and tert-butyl alcohol are preferable, ethanol and isopropanol are more preferable, and ethanol is still more preferable.
  • the content of the component (B) in the hair cosmetic composition of the present invention is preferably 45% by mass or more, more preferably 55% by mass or more, and still more preferably 60% by mass from the viewpoint of speed of drying and lack of bundle feeling.
  • it is preferably 98% by mass or less, more preferably 90% by mass or less, more preferably 80% by mass or less, and further preferably 75% by mass or less.
  • Component (C) silicone having a number average molecular weight of 100 to 1500
  • Component (C) is a silicone having a number average molecular weight of 100 or more and 1500 or less, and in combination with Component (B), a component that controls the wet spread of the hair cosmetic and the drying speed of the hair cosmetic on the hair. It is.
  • silicone examples include cyclic silicones such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, and methylcyclopolysiloxane; octamethyltrisiloxane, tetradecamethylhexasiloxane, methyltrimethicone, Examples thereof include chain silicones such as methylpolysiloxane having a kinematic viscosity at 25 ° C. of 0.5 mm 2 / s to 10 mm 2 / s.
  • decamethylcyclopentasiloxane, methyl trimethicone, linear silicones are preferred, such as methyl polysiloxane of less than 6 mm 2 / s kinematic viscosity of 0.5 mm 2 / s or more at 25 ° C., decamethylcyclopentasiloxane, methyltri Meticon is more preferred.
  • the number average molecular weight of the component (C) is preferably 100 or more, more preferably 150 or more, and more preferably 200 or more, from the viewpoint of slipperiness after coating and good fingering. Further, from the viewpoint of lack of hair bundle feeling after drying and lightness, it is preferably 1000 or less, more preferably 700 or less, and even more preferably 500 or less.
  • the component (C) is preferably a volatile silicone from the viewpoint of lightness after drying and the absence of presence of the agent.
  • Volatile silicone is a highly volatile organic compound or volatile organic compound prescribed by WHO (World Health Organization), and has a boiling point of 260 ° C. or lower. Further, as the volatile silicone, those having a boiling point of 50 ° C. or more are preferable.
  • the content of the component (C) in the hair cosmetic composition of the present invention is preferably 1% by mass or more, more preferably 10% by mass or more, and still more preferably 20% from the viewpoint of slipperiness after application and good fingering. From the viewpoint of lack of hair bundle feeling and lightness after drying, preferably 52% by mass or less, more preferably 45% by mass or less, and further preferably 40% by mass. % Or less, more preferably 35% by mass or less.
  • the mass ratio (B) / (C) of the component (B) to the component (C) in the hair cosmetic composition of the present invention is 0.8 or more and 99 or less.
  • the surface tension of the hair cosmetic composition of the present invention becomes very high, when applied to hair, the droplets move spontaneously from top to bottom while spreading horizontally.
  • the polymer contained in the hair cosmetic spontaneously and quickly spreads on the hair surface and the hair cosmetic dries quickly on the hair surface. For this reason, it is difficult to form a hair bundle after application, the presence of the hair cosmetic disappears promptly, and a natural unit is given while having a touch that is not attached.
  • the mass ratio (B) / (C) of the component (B) to the component (C) is preferably 1 or more, more preferably 1.2 or more, still more preferably 1.5 or more, and 2 or more. Is more preferably 50 or less, more preferably 30 or less, still more preferably 10 or less, and still more preferably 5 or less.
  • the total content of the component (B) and the component (C) in the hair cosmetic composition of the present invention is 30% by mass or more and 50% by mass from the viewpoint of lightness after drying and no presence of the agent. % Or more is preferable, and 70 mass% or more is preferable. Moreover, 99.9 mass% or less is preferable, 99 mass% or less is more preferable, and 98 mass% or less is still more preferable.
  • the component (D) further includes polyol, urea, organic acid, polyoxyalkylene alkyl glucoside and It is preferable to contain one or more selected from polyoxyalkylene glyceryl ethers.
  • Suitable polyols include 1,3-butanediol, glycerin, polyglycerin and the like.
  • Suitable organic acids include lactic acid, malic acid, citric acid and the like.
  • Suitable polyoxyalkylene alkyl glucosides include PPG-10 methyl glucose, PPG-20 methyl glucose, methyl glucose-10, methyl glucose-20 and the like.
  • Suitable polyoxyalkylene glyceryl ethers include PEG / PPG / polybutylene glycol-8 / 5/3 glycerol. Among these, urea, lactic acid, and glycerin are preferable from the viewpoint of high-temperature storage stability, and urea is more preferable.
  • the content of the component (D) in the hair cosmetic composition of the present invention is preferably 0.1% by mass or more, more preferably 0.5% by mass or more from the viewpoint of ensuring high-temperature stability, and from the viewpoint of maintaining a natural feel. , Preferably 3% by mass or less, more preferably 2% by mass or less.
  • the hair cosmetic composition of the present invention preferably contains no water. However, mixing of a trace amount to a small amount (for example, 0.0001% by mass or more) of water may be unavoidable. In such a case, it is preferable that the amount of water is small. Specifically, the water content is preferably less than 5% by mass, more preferably less than 3% by mass, and even more preferably less than 0.5% by mass.
  • cosmetic oils other than components (A) and (C) can be contained within the limits that do not hinder the effects of the present invention.
  • the content of cosmetic oils other than components (A) and (C) in the hair cosmetic is preferably 0.1 to 10% by mass.
  • Such cosmetic oils include glycerides such as castor oil, cacao oil, mink oil, avocado oil, olive oil; waxes such as beeswax, whale wax, lanolin, carnauba wax; isopropyl myristate, hexyl laurate, lactic acid Cetyl, propylene glycol monostearate, oleyl oleate, hexadecyl 2-ethylhexanoate, esters of octyldodecyl myristate; dimethylpolysiloxane, methylphenylpolysiloxane, epoxy-modified silicone oil, amino-modified silicone oil, alkyl-modified silicone Examples include silicone derivatives other than those contained in component (A) or (C) such as oil.
  • glycerides such as castor oil, cacao oil, mink oil, avocado oil, olive oil
  • waxes such as beeswax, whale wax, lanolin, carnauba wax
  • the hair cosmetic composition of the present invention can contain a fragrance, a pigment, and a preservative and an antioxidant to prevent the daily deterioration of the hair cosmetic composition in order to increase the commercial value.
  • a fragrance e.g., peppermint, kaolin, kaolin, kaolin, kaolin, kaolin, kaolin, kaolin, kaolin, kaolin, kaolin, kaolin, kaolin, kaolin, kaolin, etc. You can also.
  • the dosage form of the hair cosmetic composition of the present invention is not particularly limited, and can be transparent liquid, lotion, emulsion, mist (hair mist, hair spray), foam (hair mousse), etc. It is preferable that the dosage form is applied in the form of a non-aerosol, and more preferably a non-aerosol type dosage form.
  • the component (A) has a high amphiphilic film-forming property from the viewpoint of excellent dispersibility and solubility in both the component (B) and the component (C).
  • a molecular or polyether-modified silicone is preferred.
  • the content of each component refers to the content in the entire composition of the aerosol stock solution that does not contain a propellant.
  • the hair cosmetic composition of the present invention can be suitably used as a hair styling agent.
  • a method for use as a hair styling agent that is, as a hair styling method, any method can be adopted as long as the hair cosmetic composition of the present invention is applied to the hair and the hair style is adjusted.
  • the hair cosmetic composition of the present invention may be applied to wet hair or dry hair, but is preferably applied to dry hair.
  • hair cosmetic directly in the form of a mist, and to shape the hair while combing with a handbrush, comb, brush or the like.
  • the hair cosmetics shown in Table 1 are filled into a pump spray container (manufactured by Yoshino Seisakusho Co., Ltd.) (using a sprayer having an average particle diameter of 60 ⁇ m when the hair cosmetics of Examples and Comparative Examples are sprayed), Performance evaluation was performed according to the following methods and standards.
  • the composition had a high viscosity and could not be applied by mist spraying using a sprayer. Therefore, when performing performance evaluation according to the following method and criteria, the liquid was applied to the hair bundle after being held in hand. The method was adopted.
  • a hair bundle with a length of 30 cm and a weight of 8 g was made of Japanese weak hair with no chemical treatment history.
  • the hair bundle was coated with 3 g of Kao's success medicated shampoo h, foamed and washed for 30 seconds, and rinsed with tap water at 40 ° C. for 30 seconds. This shampoo operation was repeated twice.
  • 3 g of model rinse shown in the following prescription was applied, allowed to blend for 15 seconds, and then rinsed with tap water at 40 ° C. for 30 seconds.
  • After drying with towels, those naturally dried under laboratory conditions for 6 hours were used as evaluation hair bundles.
  • composition of model rinse Ingredient (mass%) Cetearyl alcohol 2.0 Steartrimonium chloride 0.76 Distearyldimonium chloride 2.7 Propylene glycol 5.0 Isopropanol 0.6 Ethylparaben 0.1 Ion exchange water balance ⁇ br/> 100 in total

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Abstract

La présente invention comprend des composants (A) à (C). La teneur en composant (A) est de 0,1 à 10 % en masse, la teneur totale en composant (B) et en composant (C) est de 30 % en masse ou plus, et le rapport massique (B)/(C) du composant (B) et du composant (C) est de 0,8 à 99. (A) est un polymère pour un produit cosmétique capillaire qui est soluble ou dispersible dans l'eau ou l'éthanol, (B) est un alcool monohydrique en C1-4 et (C) est une huile de silicone ayant un poids moléculaire moyen en nombre de 100 à 1500.
PCT/JP2016/086475 2015-12-11 2016-12-08 Cosmétique capillaire WO2017099158A1 (fr)

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JP2015241723 2015-12-11
JP2015-241723 2015-12-11

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WO2017099158A1 true WO2017099158A1 (fr) 2017-06-15

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KR102363134B1 (ko) * 2017-09-27 2022-02-15 애경산업(주) 실리콘중수(w/s) 유화형 모발 화장료 조성물
JP6982301B2 (ja) * 2017-10-13 2021-12-17 株式会社ダリヤ 毛髪化粧料

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JPH03145414A (ja) * 1989-10-31 1991-06-20 Procter & Gamble Co:The シリコーンヘアスプレー組成物
JPH04368317A (ja) * 1991-06-13 1992-12-21 Shiseido Co Ltd 毛髪化粧料
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Publication number Priority date Publication date Assignee Title
EP3501486A1 (fr) * 2017-12-21 2019-06-26 Kao Corporation Composition, procédé, et dispositif de coloration temporaire de fibres kératiniques
EP3501485A1 (fr) * 2017-12-21 2019-06-26 Kao Corporation Composition, procédé, et dispositif de coloration temporaire de fibres kératiniques
US10576035B2 (en) 2017-12-21 2020-03-03 Kao Corporation Composition, process, and device for temporary coloring of keratin fibers

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TW201739444A (zh) 2017-11-16
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TWI800477B (zh) 2023-05-01

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