WO2017073537A1 - 断熱容器用積層体、断熱容器および断熱容器の製造方法 - Google Patents
断熱容器用積層体、断熱容器および断熱容器の製造方法 Download PDFInfo
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- WO2017073537A1 WO2017073537A1 PCT/JP2016/081520 JP2016081520W WO2017073537A1 WO 2017073537 A1 WO2017073537 A1 WO 2017073537A1 JP 2016081520 W JP2016081520 W JP 2016081520W WO 2017073537 A1 WO2017073537 A1 WO 2017073537A1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/065—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of foam
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
- B32B5/20—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material foamed in situ
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/14—Printing or colouring
- B32B38/145—Printing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5263—Macromolecular coatings characterised by the use of polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- B41M5/5281—Polyurethanes or polyureas
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
- B65D65/38—Packaging materials of special type or form
- B65D65/40—Applications of laminates for particular packaging purposes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B2038/0052—Other operations not otherwise provided for
- B32B2038/0084—Foaming
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2266/00—Composition of foam
- B32B2266/02—Organic
- B32B2266/0214—Materials belonging to B32B27/00
- B32B2266/025—Polyolefin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/304—Insulating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
Definitions
- This invention relates to the laminated body for heat insulation containers, a heat insulation container, and the manufacturing method of a heat insulation container.
- Patent Document 1 discloses a heat insulating container having a layer structure of foamed low density polyethylene (LDPE) / paper / medium density polyethylene (MDPE) from the surface side.
- LDPE low density polyethylene
- MDPE medium density polyethylene
- a general heat insulating container and a laminated body for a heat insulating container for molding the heat insulating container including the heat insulating container disclosed in Patent Document 1 are resins for foaming on the surface of paper serving as a base material (in Patent Document 1). Is a low-density polyethylene), and another resin (medium-density polyethylene in Patent Document 1) is also provided on the back side to form a laminated body for a heat insulating container. By heating this, moisture contained in the paper is evaporated. The surface side resin (low density polyethylene in Patent Document 1) is foamed by this water vapor, so-called water vapor foaming.
- a printed layer for imparting designability may be provided on the resin on the surface side.
- a part where the printed layer is provided a part where it is not provided, and a part where the printed layer is provided, even if the printed layer is thick or thin.
- the degree of foaming of the resin on the surface side located under each part may differ, which may cause a step on the surface of the printed layer and impair the design. It was.
- the present invention has been made in such a situation, and is a laminated body for a heat insulating container provided with a printing layer on the surface, and the surface layer can be foamed to a desired degree.
- a laminated body for a heat insulating container having excellent surface smoothness and capable of realizing a desired design, a heat insulating container formed using the laminated body for a heat insulating container, and a heat insulating container using the laminated body for a heat insulating container It is a main subject to provide a manufacturing method.
- the present invention provides a substrate layer composed of a printed layer, a surface layer, a cover layer, paper, and a water vapor barrier that blocks water vapor generated from the paper constituting the substrate layer from the outer surface side.
- the cover layer is made of at least a high-pressure method low density polyethylene, and the surface layer has a melting point measured according to JIS K6922-2 (2010).
- the cover layer is made of a polyethylene-based resin having a melting point higher than that of the high-pressure method low-density polyethylene, and the printing layer contains a urethane resin as a binder, and the total mass of the printing layer with respect to the total mass The ratio of the urethane resin is 18% by mass or more.
- the printing layer has a laminated structure in which a plurality of printing layers are stacked, and all the printing layers contain a urethane resin as a binder, and the total solid content of each printing layer
- the ratio of the urethane resin to the mass may be 18% by mass or more.
- the ratio of the thickness of the surface layer to the thickness of the cover layer before foaming may be 1: 2 to 1:30.
- cover layer may be foamed.
- the ratio of the thickness of the surface layer to the thickness of the cover layer after foaming may be 1:15 to 1: 360.
- the thickness of the cover layer after foaming may be 300 to 900 ⁇ m.
- Another invention of the present application for solving the above-mentioned problem is a heat insulating container having a body part and a bottom part, wherein at least the body part is constituted by the laminate for a heat insulating container of the present invention. .
- another invention of the present application for solving the above-mentioned problem is a method for manufacturing a heat insulating container having a body part and a bottom part, wherein at least the body part is constituted by the laminate for a heat insulating container of the present invention, and thereafter The cover layer of the laminated body for heat insulation containers is foamed by heating the laminated body for heat insulation containers that constitutes the body portion.
- the surface layer can be foamed to a desired degree despite the fact that the printed layer is provided on the surface layer. Moreover, even after the surface layer is foamed, the smoothness of the surface of the printed layer can be made good. Therefore, a desired design can be realized.
- FIG. 1 is a cross-sectional view of a laminate for a heat-insulating container according to an embodiment of the present invention in a state where a cover layer is not foamed.
- FIG. 2 is a cross-sectional view of a laminate for a heat insulating container in a state where a cover layer is foamed according to an embodiment of the present invention.
- the laminated body 10A for a heat insulating container includes a base layer 12 composed of a printed layer 15, a surface layer 16, a cover layer 11A, and paper in this order from the outer surface side. At least a water vapor barrier layer 13 that blocks water vapor generated from the paper constituting the base material layer 12 is provided on the surface of the base material layer 12 on the side where the cover layer 11A is not laminated. It is configured by being laminated.
- produces from the paper which comprises the base material layer 12 by heating 10A of laminated bodies for heat insulation containers concerning this embodiment shown in FIG. Polyethylene is in a foamed state.
- both the state where the cover layer (11A) is not foamed and the state where the cover layer (11) is foamed are expressed as a laminate for a heat insulating container (10A, 10).
- a laminate for a heat insulating container (10A, 10) the side located outside the heat insulation container
- the side located inside the heat insulation container is referred to as an “inner surface side”.
- the upper side is the “outer surface side” and the lower side is the “inner surface side”.
- each layer which comprises laminated body 10A, 10 for heat insulation containers is demonstrated.
- the cover layer 11A before foaming is made of at least a high pressure method low density polyethylene.
- the cover layer 11A (11) is used to clearly distinguish the high-pressure low-density polyethylene constituting the cover layer 11A (11) and the polyethylene resin constituting the surface layer 16 described later.
- the high-pressure method low-density polyethylene constituting is represented as “high-pressure method low-density polyethylene (B)”
- the polyethylene-based resin constituting the surface layer 16 is represented as “polyethylene-based resin (A)”.
- the high-pressure method low-density polyethylene (B) constituting the cover layer 11A in the present embodiment can be obtained by a conventionally known high-pressure method radical polymerization method.
- melt mass flow rate measured by JIS K6922-1 (1997) of the high-pressure low-density polyethylene (B) is 4 to 100 g / 10 min. It is preferably 10 to 30 g / 10 minutes, more preferably 10 to 25 g / 10 minutes.
- the density (hereinafter simply referred to as “density”) measured by JIS K6922-1 (1997) of the high-pressure low-density polyethylene (B) is 870 to 935 kg / m 3 because of its excellent foamability. More preferably, it is in the range of 890 to 935 kg / m 3 , more preferably 900 to 925 kg / m 3 .
- an antioxidant for the high-pressure low-density polyethylene (B) constituting the cover layer 11A in this embodiment, an antioxidant, a light stabilizer, an antistatic agent, a lubricant, an antiblocking agent, etc. are generally used for polyolefin resins as necessary.
- the additives that have been used may be added within a range that does not impair the object of the present invention.
- the mixing ratio is preferably 50 to 99% by weight for the high-pressure low-density polyethylene (B) and 1 to 50% by weight for the other polyolefins.
- Examples of the polyolefin to be mixed with the high-pressure low-density polyethylene (B) include ethylene / ⁇ -olefin copolymers, polypropylene, polybutene, and the like, and since it has excellent foamability, the density is 850 kg / m 3 or more and 920 kg / m. An ethylene / ⁇ -olefin copolymer (B) of less than 3 is preferred.
- Examples of the ⁇ -olefin used in such an ethylene / ⁇ -olefin copolymer (B) include propylene, 1-butene, 4-methyl-1-pentene, 3-methyl-1-butene, 1-pentene, 1-pentene, Examples include hexene, 1-heptene, 1-octene, 1-nonene, 1-decene, 1-undecene, 1-dodecene, and the like. One or more of these may be used.
- the method for obtaining the ethylene / ⁇ -olefin copolymer (B) is not particularly limited, and examples thereof include a high / medium / low pressure ion polymerization method using a Ziegler-Natta catalyst, a Philips catalyst, or a metallocene catalyst. Such a copolymer can be conveniently selected from commercially available products.
- the pellets are a mixture of pellets of the high-pressure method low-density polyethylene (B) and the polyolefin pellets in a solid state.
- a mixture obtained by melt-kneading with a single screw extruder, a twin screw extruder, a kneader, a Banbury or the like is preferable because a product with stable quality can be obtained.
- the melting temperature is preferably about the melting point of the polyethylene resin to about 300 ° C.
- the loss elastic modulus G obtained by measuring the dynamic viscoelasticity at 190 ° C. of a polyethylene resin (A) constituting the surface layer 16 described later using a cone-disk rheometer.
- the storage elastic modulus G ′ a (500) at an angular velocity ⁇ (s ⁇ 1 ) where (Pa) is 500 Pa is G ′ of the high-pressure low-density polyethylene (B) used for the cover layer 11A obtained by the same method. It is preferable that it is smaller than b (500) because stable extrusion molding is possible and an excellent foam appearance is obtained, and an excellent foam appearance is obtained when G ′ b (500) is 95 Pa or less. preferable.
- the thickness of the cover layer 11A before foaming is not particularly limited, but is preferably 10 to 150 ⁇ m from the viewpoint of economy, and more preferably 30 to 100 ⁇ m, more preferably 30 to 80 ⁇ m.
- the cover layer 11A before foaming shown in FIG. 1 is formed on the base material layer 12 as described above, and is heated by the water vapor generated from the paper constituting the base material layer 12 as shown in FIG.
- the cover layer 11 is in the foamed state.
- the heating temperature at this time is not particularly limited as long as it is equal to or higher than the melting point of the low-density polyethylene as a material and the laminated body 10 for heat-insulating containers is not altered, but is usually 100 to 200 ° C., preferably 110 to It is 160 ° C., more preferably 110 to 125 ° C.
- the heating time is not particularly limited, but is usually about 10 seconds to 5 minutes.
- the heating method is not particularly limited, and heating can be performed by a conventionally known method. Examples include heating with hot air, infrared rays, far infrared rays, microwaves, high frequencies, and the like.
- the thickness of the cover layer 11 after foaming is not particularly limited, but is preferably 20 to 1200 ⁇ m, more preferably 300 to 900 ⁇ m, and still more preferably 400 to 700 ⁇ m because of excellent heat insulation and foam appearance.
- the melting point measured by JIS K6922-2 (2010) on the cover layers 11A and 11 constitutes the cover layers 11A and 11.
- the high-pressure method low-density polyethylene (B) is characterized in that a surface layer composed of a polyethylene resin (A) higher than the melting point of the high-pressure method low-density polyethylene (B) is provided.
- the step between the white ink printing portion and the color ink printing portion is 200 ⁇ m. It becomes possible to suppress to less than.
- Examples of the polyethylene resin (A) constituting the surface layer 16 include medium / low pressure ethylene homopolymer, high pressure low density polyethylene, ethylene / ⁇ -olefin copolymer, ethylene / vinyl acetate copolymer, ethylene / acrylic. Examples include ethyl acetate copolymer, ethylene / acrylic acid copolymer, ethylene / methacrylic acid copolymer, ethylene / ⁇ -olefin copolymer (A), medium / low pressure ethylene homopolymer (A) However, it is particularly preferable because the expansion ratio of the cover layer 11A can be improved and the appearance of the laminate is also excellent.
- Examples of the ⁇ -olefin used in the ethylene / ⁇ -olefin copolymer (A) include propylene, 1-butene, 4-methyl-1-pentene, 3-methyl-1-butene, 1-pentene, 1-hexene, -Heptene, 1-octene, 1-nonene, 1-decene, 1-undecene, 1-dodecene and the like can be mentioned, and one or more of these can be used.
- the method for obtaining such an ethylene / ⁇ -olefin copolymer (A) is not particularly limited, and a high / medium / low pressure ion polymerization method using a Ziegler-Natta catalyst, a Phillips catalyst, or a metallocene catalyst may be used. It can be illustrated.
- a copolymer can be conveniently selected from commercially available products, but since it has an excellent laminate appearance, an ethylene / ⁇ -olefin copolymer obtained by a polymerization method using a Ziegler-Natta catalyst is used. Particularly preferred.
- the medium / low pressure ethylene homopolymer (A) can be obtained by a conventionally known medium / low pressure ion polymerization method.
- the MFR of the polyethylene resin (A) constituting the surface layer 16 in the present embodiment is in the range of 0.1 to 100 g / 10 minutes, more preferably 3 to 50 g / 10 minutes, the laminate is molded. Processing becomes easy.
- the ethylene / ⁇ -olefin copolymer (A) and the medium / low pressure ethylene homopolymer (A) constituting the surface layer 16 are blended with other polyolefins such as high pressure low density polyethylene and polypropylene.
- the blending ratio of these other polyolefins is preferably 1 to 30% by weight from the viewpoint of laminate moldability and laminate appearance.
- the polyethylene resin (A) constituting the surface layer 16 may be added to polyolefin resins such as an antioxidant, a light stabilizer, an antistatic agent, a lubricant, an antiblocking agent, etc.
- An agent may be added as long as the object of the present invention is not impaired.
- the thickness of the surface layer 16 is not particularly limited, but is preferably 1 to 20 ⁇ m, more preferably 4 to 12 ⁇ m, because of its excellent appearance.
- the ratio of the thickness of the surface layer 16 and the cover layer 11A before foaming is preferably 1: 2 to 1:30 because of excellent balance between heat insulating properties and foam appearance, more preferably 1: 4 to 1: 12, more preferably 1: 6 to 1:10.
- the ratio of the thickness of the surface layer 16 to the thickness of the cover layer 11 after foaming is preferably 1:15 to 1: 360, since it has an excellent balance between heat insulation and foam appearance, more preferably 1:45 to It is 1: 240, more preferably 1:80 to 1: 150.
- the thickness of the cover layer 11 after foaming is the preferable ratio by using paper having a large basis weight or paper having a high water content as the base material 12 or by increasing the thickness of the cover layer 11A before foaming. It is possible to make the thickness more than this, but even if it is thicker than this, the heat insulation and design will not be improved dramatically, and when used for heat insulation containers of normal size, It is considered to be.
- a printing layer 15 is provided on the surface layer 16, and the printing layer 15 includes a urethane resin as a binder resin, and is printed. Another characteristic is that the ratio of the urethane resin to the total mass of the total solid content of the layer is 18% by mass or more.
- the printing layer 15 is not necessarily a single layer, and as shown in FIGS. 1 and 2, a plurality of printing layers (in FIG. 1 and FIG. 2, three printing layers 15a, 15b, and 15c).
- all the printing layers (15a, 15b, and 15c) include a urethane resin as a binder, and each printing layer (15a, 15b, And the ratio of the urethane resin to the total mass of the total solid content of 15c) is preferably 18% by mass or more.
- the “urethane resin” as used in the present specification intends a urethane resin in a broad sense including a modified urethane resin such as a general urethane resin or urethane urea resin conventionally used in the technical field.
- the urethane resin used in the present invention is not particularly limited by the production method thereof, and may be various urethane resins obtained by applying a known or well-known method relating to the urethane resin. Although it does not specifically limit, In this invention, the urethane resin obtained by making a polyol compound and organic diisocyanate react is mentioned as one preferable embodiment of a urethane resin.
- Another embodiment includes a modified urethane resin obtained by modifying a prepolymer of a urethane resin with an amine compound or an amide compound.
- urethane resin is included as a binder resin and the ratio of the urethane resin to the total mass of the total solid content of the printing layer is 18% by mass or more.
- additives such as various pigments and dyes, and further wax can be freely used.
- binder resins used include nitrified cotton resins, vinyl copolymers, polyamide resins, alkyd resins, acrylic resins, rosin resins, dimer acid resins, maleic acid resins, and chlorinated polypropylene resins.
- inorganic and organic pigments and dyes generally used in printing inks can be used as colorants.
- inorganic pigments include titanium oxide, zinc oxide, zinc sulfide, barium sulfate, calcium carbonate, aluminum hydroxide, chromium oxide, silica, carbon black, aluminum, mica (mica), and the like.
- organic pigment examples include soluble azo pigments, insoluble azo pigments, azo lake pigments, condensed azo pigments, copper phthalocyanine pigments, and condensed polycyclic pigments.
- the colorants can be used alone or in admixture of two or more for the purpose of adjusting the hue and density.
- pigment dispersants in order to improve functionality as ink, print quality and various resistances, pigment dispersants, leveling agents, waxes, crosslinking agents, surfactants, antifoaming agents, plasticizers, titanium chelates, Additives such as light stabilizers, infrared absorbers, ultraviolet absorbers, fragrances, and flame retardants can also be included.
- the formation method of the printing layer 15 is not particularly limited, but may be formed by, for example, gravure printing or offset printing.
- the thickness of the printing layer 15 is not particularly limited, and can be appropriately designed to realize a desired design, but is usually about 0.1 to 10 ⁇ m.
- the base material layer 12 is made of paper. Since this paper becomes a basic material constituting the heat insulating container, it is possible to use paper having formability, bending resistance, rigidity, waist, strength and the like. As paper, for example, it is a main strength material, and uses various types of paper base materials such as high-size bleached or unbleached paper base, or pure white roll paper, kraft paper, paperboard, processed paper, and milk base paper. can do.
- the base material layer 12 may be a laminate of a plurality of these papers.
- Paper having a basis weight of about 80 to 600 g / m 2 , preferably about 100 to 450 g / m 2 and having a thickness of about 110 to 860 ⁇ m, preferably about 140 to 640 ⁇ m can be used. .
- the cover layer 11A and the water vapor blocking layer 13 described later are provided on the base material layer 12.
- the paper constituting the base material layer 12 in any stage such as a stage before being provided, or at the same time as these are provided, and further, a stage before heating the laminated body 10A for the heat insulating container is formed.
- it is preferable to adjust so that the water content in the paper is about 2 to 8%.
- the specific method of the moisture adjustment step is not particularly limited, and for example, paper may be soaked in water.
- the water vapor blocking layer 13 is provided on the inner surface side of the base material layer 12.
- the layer is a layer that functions to block water vapor generated from the paper constituting the base material layer 12 and efficiently send the generated water vapor to the cover layer 11A side. There is no particular limitation.
- Examples of the material of the water vapor blocking layer 13 include polyethylene resin (C) and clay (D).
- the density of the polyethylene-based resin (C) as the water vapor blocking layer 13 is preferably in the range of 925 to 970 kg / m 3 , more preferably 930 to 970 kg / m 3 , and still more preferably 935 because of its excellent heat insulation. ⁇ 965 kg / m 3 .
- Such a polyethylene resin (C) has a higher melting point than the high-pressure method low-density polyethylene (B) constituting the cover layer 11A, and water vapor blocking performance is also superior to that of the high-pressure method low-density polyethylene (B).
- it since it has excellent pinhole resistance, it can be suitably used as the water vapor blocking layer 13 in the laminated body 10A, 10 for the heat insulating container according to the present embodiment.
- the polyethylene-based resin (C) is an ethylene homopolymer or an ethylene / ⁇ -olefin copolymer and a composition thereof, and the molecular chain may be linear and has 6 or more carbon atoms. It may have a long chain branch.
- Such a polyethylene-based resin (C) is not particularly limited, and it is sufficient that the density range is not exceeded.
- Examples of the ethylene homopolymer include medium / low pressure ethylene homopolymer and high pressure low density polyethylene.
- the medium / low pressure ethylene homopolymer can be obtained by a conventionally known medium / low pressure ion polymerization method.
- the high pressure method low density polyethylene can be obtained by a conventionally known high pressure radical polymerization method.
- Examples of the ⁇ -olefin used in the ethylene / ⁇ -olefin copolymer include propylene, 1-butene, 4-methyl-1-pentene, 3-methyl-1-butene, 1-pentene, 1-hexene and 1-heptene. 1-octene, 1-nonene, 1-decene, 1-undecene, 1-dodecene, etc., and one or more of these may be used.
- the method for obtaining the ethylene / ⁇ -olefin copolymer is not particularly limited, and examples thereof include a high / medium / low pressure ion polymerization method using a Ziegler-Natta catalyst, a Philips catalyst, or a metallocene catalyst. Such a copolymer can be conveniently selected from commercially available products.
- additives generally used for polyolefin resins such as an antioxidant, a light stabilizer, an antistatic agent, a lubricant, an antiblocking agent and the like are impaired as necessary. Although it does not matter if it is added in such a range, it is preferable that the additive is not included (no additive) because it is used as the innermost layer of the heat insulating container.
- the method for forming the water vapor barrier layer 13 made of polyethylene resin (C) is not particularly limited, and as with the cover layer 11, extrusion coating, pre-made film lamination, dry lamination, or the like is used.
- the thickness of the water vapor blocking layer 13 composed of the polyethylene resin (C) is not particularly limited, but it is usually preferably about 10 to 50 ⁇ m.
- clay (D) when clay (D) is used as a material for the water vapor barrier layer 13, that is, when the clay coat layer is used as the water vapor barrier layer 13, the clay coat layer applies a coating liquid containing clay to the base material layer 12.
- the clay particles are spread on the surface of the base material layer 12 on which the cover layer is not provided.
- the clay (D) used is not particularly limited as long as it is generally called clay or clay, but kaolin, talc, bentonite, smectite, vermiculite, mica, chlorite, kibushi clay, gyrome clay, halloysite. Mica is used. Of these, kaolin and talc are preferably used as the clay. Kaolin has excellent concealability and water absorption, and talc has low hardness (Mohs hardness 1) and excellent heat resistance. Improvement in dimensional stability can be expected.
- the clay coat layer preferably contains calcium carbonate, titanium dioxide, amorphous silica, expandable barium sulfate, satin white and the like as a pigment in addition to clay (D).
- calcium carbonate or titanium dioxide as the pigment, the smoothness of the surface of the clay coat layer can be increased and the concealability can be increased.
- calcium carbonate is preferably used because it is inexpensive.
- the coating liquid for coating the clay coat layer contains the above clay (D), a binder, and other pigments and additives as necessary in a solvent.
- a solvent water, alcohol or the like is usually used.
- binder latex binders (eg, styrene butadiene latex, acrylic latex vinyl acetate latex), water-soluble binders (eg, starch (modified starch, oxidized starch, hydroxyethyl etherified starch, phosphate ester) Modified starch), polyvinyl alcohol, casein and the like.
- additives that can be used include pigment dispersants, antifoaming agents, antifoaming agents, viscosity modifiers, lubricants, water resistance agents, water retention agents, coloring materials, and printability improvers.
- the coating method of the clay coat layer is not particularly limited, and a conventionally known coating method is used, but a coating method such as air knife coating, blade coating, short dwell coating, or cast coating is used.
- the application amount and thickness of the clay coat layer are not particularly limited, but the basis weight after drying is usually 5 to 40 g / m 2 , preferably 10 to 40 g / m 2 .
- the basis weight after drying is less than 5 g / m 2 , water vapor generated from the paper constituting the base material layer 12 cannot be efficiently blocked, and the cover layer 11 cannot be brought into a desired foamed state. If the basis weight after drying exceeds 40 g / m 2 , the overall thickness of the laminated body 10 for a heat-insulating container may become too thick, and the production suitability may deteriorate.
- the clay coat layer is provided in order to improve the printability of paper. This is because printing quality is improved when printing is performed on paper on which the clay coat layer is formed.
- the clay coat layer is formed on the inner side of the base material layer 12, that is, the surface of the packaging material 10 on which the printing layer is not provided, and from the paper of the base material layer 12 In the point which prevents the water vapor
- the water vapor barrier layer 13 is not necessarily a single layer and may have a laminated structure of two or more layers.
- a polyethylene-based resin may be laminated on the inner surface of the clay coat layer in order to impart box making properties.
- a PET film for example, a PET film, a film in which an inorganic oxide is deposited on the inner side of the water vapor barrier layer 13, or a metal foil such as an aluminum foil
- a barrier layer made of MX nylon or the like may be provided.
- the heat insulating container according to the present embodiment is a heat insulating container having a body part and a bottom part, and at least the body part is constituted by the laminated body 10 and 10A for heat insulating containers described above. That is, the cover layer of the laminated body for a heat insulating container constituting the body part of the heat insulating container according to the present embodiment may be in a state before foaming or in a state after foaming, but heat insulation as a final product. The cover layer of the container is in a state after foaming.
- the body portion is constituted by the heat insulating container laminate 10A before the cover layer 11A is foamed, and the heat insulating container laminate 10A is heated to laminate the heat insulating container.
- the body cover layer may be foamed. More specifically, after forming the laminated body 10A for heat insulation container according to the present embodiment (before foaming), punching, skive hemming the end face so that the contents do not contact the end face, the bottom in the molding machine, If necessary, the top portion may be heat-sealed by hot air heating, flame heating, or the like to form a container, and then heated to foam the cover layer to form a heat insulating container.
- the shape of the heat insulating container may be appropriately determined according to the use and purpose, and examples thereof include shapes such as a gobel top type, a brick type, a flat top type, and a cup type.
- a polyethylene cap, a pull tab type opening mechanism, or the like may be appropriately provided at the spout of the heat insulating container.
- the contents filled in the heat insulating container according to the present embodiment are not particularly limited, and various solids and liquids can be used as the contents.
- the contents may be dry noodles, miso soup, various soups, and the like.
- Example 1 The laminated body for heat insulation containers of Example 1 which consists of the following structures by said preparation method was obtained.
- ⁇ Layer structure Print layer / surface layer / cover layer / base material layer / water vapor barrier layer / print layer: Ratio of urethane resin to the total mass of the total solid content of the printed layer after drying 35% by mass ⁇
- Surface layer LLDPE (Nipolon-L M72 manufactured by Tosoh Corporation) Density 925kg / m 3 MFR 20g / 10min Melting temperature 121 ° C 10 ⁇ m thickness
- Cover layer LDPE (Tosoh Co., Ltd.
- Example 2 The laminated body for heat insulation containers of Example 2 which consists of the following structures by said production method was obtained.
- ⁇ Layer structure Print layer / surface layer / cover layer / base material layer / water vapor barrier layer / print layer: Ratio of urethane resin to the total mass of the total solid content of the printed layer after drying 35% by mass ⁇
- Surface layer LLDPE (Nipolon-L M72 manufactured by Tosoh Corporation) Density 925kg / m 3 MFR 20g / 10min Melting temperature 121 ° C Thickness 5 ⁇ m ⁇ Cover layer: LDPE (Tosoh Co., Ltd.
- Example 3 The laminated body for heat insulation containers of Example 3 which consists of the following structures by said production method was obtained.
- ⁇ Layer structure Print layer / surface layer / cover layer / base material layer / water vapor barrier layer / print layer: Ratio of urethane resin to the total mass of the total solid content of the printed layer after drying 35% by mass ⁇
- Petrocene 212) Density 919kg / m 3 Melting temperature 107 ° C MFR13g / 10min Thickness before foaming 70 ⁇ m 750 ⁇ m thickness after foaming (including surface layer) ⁇
- Base material layer Nippon Paper Industries Co., Ltd. Cup base paper Basis weight 280g / m 2 ⁇ Water vapor barrier layer: MDPE (Tosoh Co., Ltd. Petrocene LW04-1) Density 940kg / m 3 MFR 7g / 10min Melting temperature 133 ° C 40 ⁇ m thickness
- Example 4 The laminated body for heat insulation containers of Example 4 which consists of the following structures by said production method was obtained.
- ⁇ Layer structure Print layer / surface layer / cover layer / base material layer / water vapor barrier layer / print layer: Ratio of urethane resin to the total mass of the total solid content of the printed layer after drying 35% by mass ⁇
- Surface layer LLDPE (Nipolon-L M65 manufactured by Tosoh Corporation) Density 920kg / m 3 MFR 20g / 10min Melting temperature 120 ° C 10 ⁇ m thickness
- Cover layer LDPE (Tosoh Co., Ltd.
- Petrocene 212) Density 919kg / m 3 Melting temperature 107 ° C MFR13g / 10min Thickness before foaming 60 ⁇ m 700 ⁇ m thickness after foaming (including surface layer) ⁇
- Base material layer Nippon Paper Industries Co., Ltd. Cup base paper Basis weight 280g / m 2 ⁇ Water vapor barrier layer: MDPE (Tosoh Co., Ltd. Petrocene LW04-1) Density 940kg / m 3 MFR 7g / 10min Melting temperature 133 ° C 40 ⁇ m thickness
- Example 5 The laminated body for heat insulation containers of Example 5 which consists of the following structures by said production method was obtained.
- ⁇ Layer structure Print layer / surface layer / cover layer / base material layer / water vapor barrier layer / print layer: Ratio of urethane resin to the total mass of the total solid content of the printed layer after drying 25% by mass ⁇
- Surface layer LLDPE (Nipolon-L M72 manufactured by Tosoh Corporation) Density 925kg / m 3 MFR 20g / 10min Melting temperature 121 ° C Thickness 5 ⁇ m ⁇ Cover layer: LDPE (Tosoh Co., Ltd.
- Petrocene 212) Density 919kg / m 3 MFR 13g / 10min Melting temperature 107 ° C 60 ⁇ m thickness before foaming Thickness after foaming 600 ⁇ m (including surface layer) ⁇
- Base material layer Nippon Paper Industries Co., Ltd. Cup base paper Basis weight 280g / m 2 ⁇ Water vapor barrier layer: MDPE (Tosoh Co., Ltd. Petrocene LW04-1) Density 940kg / m 3 MFR 7g / 10min Melting temperature 133 ° C 40 ⁇ m thickness
- Example 6 The laminated body for heat insulation containers of Example 6 which consists of the following structures was obtained with said preparation method.
- ⁇ Layer structure Print layer / surface layer / cover layer / base material layer / water vapor barrier layer / print layer: 18% by mass of urethane resin relative to the total mass of the total solid content of the printed layer after drying
- Surface layer LLDPE (Nipolon-L M72 manufactured by Tosoh Corporation) Density 925kg / m 3 MFR 20g / 10min Melting temperature 121 ° C Thickness 5 ⁇ m
- Cover layer LDPE (Tosoh Co., Ltd.
- Comparative Example 1 The laminated body for heat insulation containers of the comparative example 1 which consists of the following structures by said production method was obtained.
- ⁇ Layer structure Print layer / surface layer / cover layer / base material layer / water vapor barrier layer / print layer: Ratio of urethane resin to the total mass of the total solid content of the printed layer after drying 35% by mass ⁇
- Example 2 The laminated body for heat insulation containers of Example 2 which consists of the following structures by said production method was obtained.
- ⁇ Layer structure Print layer / surface layer / cover layer / base material layer / water vapor barrier layer / print layer: Ratio of urethane resin to the total mass of the total solid content of the printed layer after drying 10% by mass ⁇
- Surface layer LLDPE (Nipolon-L M72 manufactured by Tosoh Corporation) Density 925kg / m 3 MFR 20g / 10min Melting temperature 121 ° C Thickness 5 ⁇ m ⁇ Cover layer: LDPE (Tosoh Co., Ltd.
- the laminates for heat insulating containers of Examples 1 to 6 and Comparative Examples 1 to 3 were evaluated for foam thickness, foam followability, and foam appearance. Each evaluation is as follows.
- the thickness before and after foaming was measured using a thickness meter (Dial Thickness Gauge G: manufactured by Ozaki Mfg. Co., Ltd.), and the sum of the thicknesses of the surface layer and the cover layer of the portion where white ink and color ink were laminated was calculated from the difference. And evaluated according to the following criteria.
- C Less than 300 ⁇ m
- Step difference between the white ink printing portion and the color ink portion is less than 100 ⁇ m
- Table 1 shows the evaluation results for each of the foam thickness, foam followability, and foam appearance.
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Abstract
Description
発泡前のカバー層11Aは、少なくとも高圧法低密度ポリエチレンから構成されている。なお、以下の説明においては、カバー層11A(11)を構成する高圧法低密度ポリエチレンと、後述する表面層16を構成するポリエチレン系樹脂とを明確に区別するため、カバー層11A(11)を構成する高圧法低密度ポリエチレンについては、「高圧法低密度ポリエチレン(B)」と表記し、表面層16を構成するポリエチレン系樹脂については、「ポリエチレン系樹脂(A)」と表記する。
本実施形態にかかる断熱容器用積層体10A、10にあっては、前記カバー層11A、11上に、JIS K6922-2(2010年)により測定される融点が、前記カバー層11A、11を構成する高圧法低密度ポリエチレン(B)の融点よりも高いポリエチレン系樹脂(A)から構成されている表面層が設けられている点に特徴を有している。このような材質から構成される表面層16を設けることにより、カバー層11Aを、後述する印刷層15の影響を受けることなく、均一に発泡せしめることができる。より具体的には、例えば、後述する印刷層15が白インキ印刷部と色インキ印刷部とから構成される場合であっても、白インキ印刷部と色インキ印刷部との間の段差を200μm未満に抑えることが可能となる。
本発明の実施形態にかかる断熱容器用積層体10A、10にあっては、前記表面層16上に印刷層15が設けられており、当該印刷層15はバインダー樹脂としてウレタン樹脂を含み、かつ刷層層の全固形分の合計質量に対する当該ウレタン樹脂の割合が18質量%以上である点にも特徴を有している。このような特定のバインダーを含む印刷層15を用いることにより、印刷層15の追従性を向上せしめることができ、カバー層11Aが発泡状態となった際に当該カバー層11Aの発泡にうまく追従し、表面平滑性を担保でき、優れた意匠性を発揮することができる。なお、このような印刷層15は、必ずしも表面層16の全面に形成されている必要はなく、図1や図2に示すように、部分的に形成されていてもよい。
基材層12は紙から構成されている。この紙は、断熱容器を構成する基本素材となることから賦型性、耐屈曲性、剛性、腰、強度等を有するものを使用することができる。紙としては、例えば、主強度材であり、強サイズ性の晒または未晒の紙基材、あるいは、純白ロール紙、クラフト紙、板紙、加工紙、ミルク原紙等の各種の紙基材を使用することができる。基材層12は、これらの紙を複数層重ねたものであってもよい。また、紙は、坪量80~600g/m2程度、好ましくは坪量100~450g/m2程度であり、厚さ110~860μm程度、好ましくは140~640μm程度のものを使用することができる。
本実施形態にかかる断熱容器用積層体10A、10にあっては、基材層12の内面側に水蒸気遮断層13が設けられている。当該層は、基材層12を構成する紙から発生する水蒸気を遮断し、発生した水蒸気を効率良くカバー層11A側に送るために機能する層であり、したがって当該機能を有する層であれば、特に限定されることはない。
本実施形態にかかる断熱容器用積層体10A、10にあっては、上述した各層の他、種々の機能を発揮する層が含まれていてもよい。
以下に本願発明の実施形態にかかる断熱容器、および断熱容器の製造方法について説明する。
紙から構成される基材層の裏面に310℃の温度でTダイより押し出し、引き取り速度が100m/分、エアギャップ長さが140mmで40μmの厚さになるよう押出しラミネートを行うことで水蒸気遮断層を形成した。さらに、基材層の表面に引き取り速度が60m/分で表面層とカバー層を共押しすることで表面層とカバー層を形成した。ついでグラビア校正機により、表面層上に白インキを全面印刷した後、色インキをパターン状に印刷することで発泡前の断熱容器用積層体を得た。その後、当該断熱容器用積層体を裁断して円柱状にし、対流式オーブンを用いて120℃で5分間加熱することでカバー層を発泡させて発泡後の断熱容器用積層体を得た。
上記の作製方法により、以下の構成からなる実施例1の断熱容器用積層体を得た。
・層構成:
印刷層/表面層/カバー層/基材層/水蒸気遮断層
・印刷層:
乾燥後の印刷層の全固形分の合計質量に対するウレタン樹脂の割合35質量%
・表面層:
LLDPE(東ソー(株)製ニポロン-L M72)
密度925kg/m3
MFR20g/10分
溶融温度121℃
厚さ10μm
・カバー層:
LDPE(東ソー(株)製ペトロセン 212)
密度919kg/m3
MFR13g/10分
溶融温度107℃
発泡前の厚さ60μm
発泡後の厚さ700μm(表面層を含む)
・基材層:
日本製紙(株)製コップ原紙
坪量280g/m2
・水蒸気遮断層:
MDPE(東ソー(株)製ペトロセン LW04-1)
密度940kg/m3
MFR7g/10分
溶融温度133℃
厚さ40μm
上記の作製方法により、以下の構成からなる実施例2の断熱容器用積層体を得た。
・層構成:
印刷層/表面層/カバー層/基材層/水蒸気遮断層
・印刷層:
乾燥後の印刷層の全固形分の合計質量に対するウレタン樹脂の割合35質量%
・表面層:
LLDPE(東ソー(株)製ニポロン-L M72)
密度925kg/m3
MFR20g/10分
溶融温度121℃
厚さ5μm
・カバー層:
LDPE(東ソー(株)製ペトロセン 212)
密度919kg/m3
MFR13g/10分
溶融温度107℃
発泡前の厚さ60μm
発泡後の厚さ700μm(表面層を含む)
・基材層:
日本製紙(株)製コップ原紙
坪量280g/m2
・水蒸気遮断層:
MDPE(東ソー(株)製ペトロセン LW04-1)
密度940kg/m3
MFR7g/10分
溶融温度133℃
厚さ40μm
上記の作製方法により、以下の構成からなる実施例3の断熱容器用積層体を得た。
・層構成:
印刷層/表面層/カバー層/基材層/水蒸気遮断層
・印刷層:
乾燥後の印刷層の全固形分の合計質量に対するウレタン樹脂の割合35質量%
・表面層:
LLDPE(東ソー(株)製ニポロン-L M72)
密度925kg/m3
MFR20g/10分
溶融温度121℃
厚さ2.5μm
・カバー層:
LDPE(東ソー(株)製ペトロセン 212)
密度919kg/m3
溶融温度107℃
MFR13g/10分
発泡前の厚さ70μm
発泡後の厚さ750μm(表面層を含む)
・基材層:
日本製紙(株)製コップ原紙
坪量280g/m2
・水蒸気遮断層:
MDPE(東ソー(株)製ペトロセン LW04-1)
密度940kg/m3
MFR7g/10分
溶融温度133℃
厚さ40μm
上記の作製方法により、以下の構成からなる実施例4の断熱容器用積層体を得た。
・層構成:
印刷層/表面層/カバー層/基材層/水蒸気遮断層
・印刷層:
乾燥後の印刷層の全固形分の合計質量に対するウレタン樹脂の割合35質量%
・表面層:
LLDPE(東ソー(株)製ニポロン-L M65)
密度920kg/m3
MFR20g/10分
溶融温度120℃
厚さ10μm
・カバー層:
LDPE(東ソー(株)製ペトロセン 212)
密度919kg/m3
溶融温度107℃
MFR13g/10分
発泡前の厚さ60μm
発泡後の厚さ700μm(表面層を含む)
・基材層:
日本製紙(株)製コップ原紙
坪量280g/m2
・水蒸気遮断層:
MDPE(東ソー(株)製ペトロセン LW04-1)
密度940kg/m3
MFR7g/10分
溶融温度133℃
厚さ40μm
上記の作製方法により、以下の構成からなる実施例5の断熱容器用積層体を得た。
・層構成:
印刷層/表面層/カバー層/基材層/水蒸気遮断層
・印刷層:
乾燥後の印刷層の全固形分の合計質量に対するウレタン樹脂の割合25質量%
・表面層:
LLDPE(東ソー(株)製ニポロン-L M72)
密度925kg/m3
MFR20g/10分
溶融温度121℃
厚さ5μm
・カバー層:
LDPE(東ソー(株)製ペトロセン 212)
密度919kg/m3
MFR13g/10分
溶融温度107℃
発泡前の厚さ60μm
発泡後の厚さ600μm(表面層を含む)
・基材層:
日本製紙(株)製コップ原紙
坪量280g/m2
・水蒸気遮断層:
MDPE(東ソー(株)製ペトロセン LW04-1)
密度940kg/m3
MFR7g/10分
溶融温度133℃
厚さ40μm
上記の作製方法により、以下の構成からなる実施例6の断熱容器用積層体を得た。
・層構成:
印刷層/表面層/カバー層/基材層/水蒸気遮断層
・印刷層:
乾燥後の印刷層の全固形分の合計質量に対するウレタン樹脂の割合18質量%
・表面層:
LLDPE(東ソー(株)製ニポロン-L M72)
密度925kg/m3
MFR20g/10分
溶融温度121℃
厚さ5μm
・カバー層:
LDPE(東ソー(株)製ペトロセン 212)
密度919kg/m3
MFR13g/10分
溶融温度107℃
発泡前の厚さ60μm
発泡後の厚さ400μm(表面層を含む)
・基材層:
日本製紙(株)製コップ原紙
坪量280g/m2
・水蒸気遮断層:
MDPE(東ソー(株)製ペトロセン LW04-1)
密度940kg/m3
MFR7g/10分
溶融温度133℃
厚さ40μm
上記の作製方法により、以下の構成からなる比較例1の断熱容器用積層体を得た。
・層構成:
印刷層/表面層/カバー層/基材層/水蒸気遮断層
・印刷層:
乾燥後の印刷層の全固形分の合計質量に対するウレタン樹脂の割合35質量%
・表面層:
LDPE(東ソー(株)製ペトロセン 213)
密度918kg/m3
溶融温度102℃
MFR8g/10分
厚さ10μm
・カバー層:
LDPE(東ソー(株)製ペトロセン 212)
密度919kg/m3
MFR13g/10分
溶融温度107℃
発泡前の厚さ60μm
発泡後の厚さ650μm(表面層を含む)
・基材層:
日本製紙(株)製コップ原紙
坪量280g/m2
・水蒸気遮断層:
MDPE(東ソー(株)製ペトロセン LW04-1)
密度940kg/m3
MFR7g/10分
溶融温度133℃
厚さ40μm
上記の作製方法により、以下の構成からなる実施例2の断熱容器用積層体を得た。
・層構成:
印刷層/表面層/カバー層/基材層/水蒸気遮断層
・印刷層:
乾燥後の印刷層の全固形分の合計質量に対するウレタン樹脂の割合10質量%
・表面層:
LLDPE(東ソー(株)製ニポロン-L M72)
密度925kg/m3
MFR20g/10分
溶融温度121℃
厚さ5μm
・カバー層:
LDPE(東ソー(株)製ペトロセン 212)
密度919kg/m3
MFR13g/10分
溶融温度107℃
発泡前の厚さ60μm
発泡後の厚さ250μm(表面層を含む)
・基材層:
日本製紙(株)製コップ原紙
坪量280g/m2
・水蒸気遮断層:
MDPE(東ソー(株)製ペトロセン LW04-1)
密度940kg/m3
MFR7g/10分
溶融温度133℃
厚さ40μm
上記の作製方法により、以下の構成からなる比較例3の断熱容器用積層体を得た。
・層構成:
印刷層/カバー層/基材層/水蒸気遮断層
・印刷層:
乾燥後の印刷層の全固形分の合計質量に対するウレタン樹脂の割合35質量%
・カバー層:
LDPE(東ソー(株)製ペトロセン 212)
密度919kg/m3
MFR13g/10分
溶融温度107℃
発泡前の厚さ60μm
発泡後の厚さ700μm(表面層を含む)
・基材層:
日本製紙(株)製コップ原紙
坪量280g/m2
・水蒸気遮断層:
MDPE(東ソー(株)製ペトロセン LW04-1)
密度940kg/m3
MFR7g/10分
溶融温度133℃
厚さ40μm
発泡前後の厚みは、厚み計(ダイヤルシックネスゲージG:(株)尾崎製作所製)を用いて測定し、差分から白インキと色インキを積層した部位の表面層とカバー層の厚みの和を算出し、以下の基準に従って評価した。
A:450μm以上
B:300μm以上450μm未満
C:300μm未満
発泡後の印刷層の表面について、白インキ印刷部の厚みと、この白インキ印刷部に積層された色インキ印刷部の厚みを厚み計(ダイヤルシックネスゲージG:(株)尾崎製作所製)を用いて測定し、その差分を段差とした。そして、この段差について以下の基準に従って評価した。
A:白インキ印刷部と色インキ部分の段差が100μm未満
B:白インキ印刷部と色インキ部分の段差が100μm以上200μm未満
C:白インキ印刷部と色インキ部分の段差が200μm以上
発泡後の色インキ印刷部の外観状態を目視による観察と指触を行ない、表面の滑らかさを以下の基準に従って評価した。
A:表面が滑らかで、凹凸を感じない。
B:わずかに凹凸を感じる。
C:かなり凹凸があり、ざらつきを感じる。
上記発泡厚み、発泡追随性、および発泡外観のそれぞれについての評価結果を表1に示す。
10A…断熱容器用積層体(発泡前)
11…カバー層(発泡後)
11A…カバー層(発泡前)
12…基材層
13…水蒸気遮断層
15…印刷層
16…表面層
Claims (8)
- 外面側から、印刷層、表面層、カバー層、紙から構成される基材層、前記基材層を構成する紙から発生する水蒸気を遮断する水蒸気遮断層、を少なくとも有する断熱容器用積層体であって、
前記カバー層は、少なくとも高圧法低密度ポリエチレンから構成されており、
前記表面層は、JIS K6922-2(2010年)により測定される融点が、前記カバー層を構成する高圧法低密度ポリエチレンの融点よりも高いポリエチレン系樹脂から構成されており、
前記印刷層は、バインダーとしてウレタン樹脂を含み、かつ印刷層の全固形分の合計質量に対する当該ウレタン樹脂の割合が18質量%以上である、
ことを特徴とする断熱容器用積層体。 - 前記印刷層が複数の印刷層を重ねた積層構造を有しており、すべての印刷層が、バインダーとしてウレタン樹脂を含み、かつ各印刷層の全固形分の合計質量に対する当該ウレタン樹脂の割合が18質量%以上であることを特徴とする請求項1に記載の断熱容器用積層体。
- 前記表面層の厚さと発泡前の前記カバー層の厚さの比が1:2~1:30であることを特徴とする請求項1または2に記載の断熱容器用積層体。
- 前記カバー層が発泡していることを特徴とする請求項1~3のいずれか一項に記載の断熱容器用積層体。
- 前記表面層の厚さと発泡後の前記カバー層の厚さの比が1:15~1:360であることを特徴とする請求項4に記載の断熱容器用積層体。
- 発泡後の前記カバー層の厚さが300~900μmであることを特徴とする請求項4または5に記載の断熱容器用積層体。
- 胴部と底部を有する断熱容器であって、
少なくとも前記胴部は、前記請求項1~6のいずれか一項に記載の断熱容器用積層体によって構成されていることを特徴とする断熱容器。 - 胴部と底部を有する断熱容器の製造方法であって、
少なくとも前記胴部を、前記請求項1~3のいずれか一項に記載の断熱容器用積層体によって構成し、
その後、前記胴部を構成する断熱容器用積層体を加熱することで断熱容器用積層体のカバー層を発泡させることを特徴とする断熱容器の製造方法。
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2019001097A (ja) * | 2017-06-16 | 2019-01-10 | 大日本印刷株式会社 | 断熱容器用積層体、断熱容器、及び断熱容器の製造方法 |
WO2019065557A1 (ja) * | 2017-09-29 | 2019-04-04 | 大日本印刷株式会社 | 断熱容器用積層体、断熱容器、断熱容器用積層体の製造方法、および断熱容器の製造方法 |
WO2019065556A1 (ja) * | 2017-09-29 | 2019-04-04 | 大日本印刷株式会社 | 断熱容器用積層体、断熱容器、断熱容器用積層体の製造方法、および断熱容器の製造方法 |
JP2019064016A (ja) * | 2017-09-28 | 2019-04-25 | 大日本印刷株式会社 | 断熱容器用積層体、断熱容器、および断熱容器の製造方法 |
WO2019130179A1 (en) * | 2017-12-28 | 2019-07-04 | Stora Enso Oyj | A paperboard for packaging of liquid and/or frozen food |
WO2019186640A1 (ja) * | 2018-03-26 | 2019-10-03 | 大日本印刷株式会社 | 断熱容器用積層体、断熱容器、断熱容器用積層体の製造方法、および断熱容器の製造方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013193351A (ja) * | 2012-03-21 | 2013-09-30 | Japan Polyethylene Corp | 発泡性積層体及び発泡加工紙ならびにそれを用いた断熱容器 |
JP2014069530A (ja) * | 2012-10-01 | 2014-04-21 | Tosoh Corp | 発泡積層体 |
JP2014124797A (ja) * | 2012-12-25 | 2014-07-07 | Tosoh Corp | 発泡積層体の製造方法及びその発泡積層体 |
JP2015098106A (ja) * | 2013-11-18 | 2015-05-28 | 東ソー株式会社 | 発泡積層体の製造方法及び発泡積層体 |
JP2015098109A (ja) * | 2013-11-18 | 2015-05-28 | 東ソー株式会社 | 発泡積層体の製造方法及び発泡積層体 |
JP2015098107A (ja) * | 2013-11-18 | 2015-05-28 | 東ソー株式会社 | 発泡積層体の製造方法及びその発泡積層体 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57110439A (en) | 1980-12-29 | 1982-07-09 | Nihon Dixie Co Ltd | Vessel made of heat insulating paper and its manufacture |
JPH05320370A (ja) * | 1992-05-27 | 1993-12-03 | Dainippon Ink & Chem Inc | ラミネート方法 |
JPH09201910A (ja) * | 1996-01-30 | 1997-08-05 | Toppan Printing Co Ltd | 耐汚染性を有する化粧シート |
JP3809682B2 (ja) * | 1996-12-13 | 2006-08-16 | 凸版印刷株式会社 | 紙カップおよびその製造方法 |
JP4372853B2 (ja) * | 1997-10-20 | 2009-11-25 | 大日本印刷株式会社 | 発泡加工紙 |
JP2001270059A (ja) * | 2000-01-20 | 2001-10-02 | Toppan Printing Co Ltd | 耐水性を有する紙製包装材料およびこの紙製包装材料を用いた包装容器 |
WO2009119800A1 (ja) * | 2008-03-28 | 2009-10-01 | 日清食品ホールディングス株式会社 | 印刷用インキ組成物、該インキ組成物を用いた紙製容器材料および断熱性発泡紙製容器 |
JP2011051631A (ja) * | 2009-09-02 | 2011-03-17 | Dnp Fine Chemicals Co Ltd | 容器用ラベル印刷物 |
KR101072737B1 (ko) * | 2009-09-18 | 2011-10-11 | 율촌화학 주식회사 | 셀 포장재 및 그 제조방법 |
JP5782895B2 (ja) * | 2011-07-26 | 2015-09-24 | 日本ポリエチレン株式会社 | 発泡性積層体、発泡加工紙及び断熱容器 |
-
2016
- 2016-10-25 KR KR1020207012877A patent/KR20200051067A/ko active Application Filing
- 2016-10-25 WO PCT/JP2016/081520 patent/WO2017073537A1/ja active Application Filing
- 2016-10-25 JP JP2017525640A patent/JPWO2017073537A1/ja active Pending
- 2016-10-25 KR KR1020187011968A patent/KR20180059889A/ko active Application Filing
-
2018
- 2018-03-20 PH PH12018500602A patent/PH12018500602A1/en unknown
-
2019
- 2019-02-13 JP JP2019023614A patent/JP2019108169A/ja active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013193351A (ja) * | 2012-03-21 | 2013-09-30 | Japan Polyethylene Corp | 発泡性積層体及び発泡加工紙ならびにそれを用いた断熱容器 |
JP2014069530A (ja) * | 2012-10-01 | 2014-04-21 | Tosoh Corp | 発泡積層体 |
JP2014124797A (ja) * | 2012-12-25 | 2014-07-07 | Tosoh Corp | 発泡積層体の製造方法及びその発泡積層体 |
JP2015098106A (ja) * | 2013-11-18 | 2015-05-28 | 東ソー株式会社 | 発泡積層体の製造方法及び発泡積層体 |
JP2015098109A (ja) * | 2013-11-18 | 2015-05-28 | 東ソー株式会社 | 発泡積層体の製造方法及び発泡積層体 |
JP2015098107A (ja) * | 2013-11-18 | 2015-05-28 | 東ソー株式会社 | 発泡積層体の製造方法及びその発泡積層体 |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2019001097A (ja) * | 2017-06-16 | 2019-01-10 | 大日本印刷株式会社 | 断熱容器用積層体、断熱容器、及び断熱容器の製造方法 |
JP2019064016A (ja) * | 2017-09-28 | 2019-04-25 | 大日本印刷株式会社 | 断熱容器用積層体、断熱容器、および断熱容器の製造方法 |
WO2019065557A1 (ja) * | 2017-09-29 | 2019-04-04 | 大日本印刷株式会社 | 断熱容器用積層体、断熱容器、断熱容器用積層体の製造方法、および断熱容器の製造方法 |
WO2019065556A1 (ja) * | 2017-09-29 | 2019-04-04 | 大日本印刷株式会社 | 断熱容器用積層体、断熱容器、断熱容器用積層体の製造方法、および断熱容器の製造方法 |
JP2019064684A (ja) * | 2017-09-29 | 2019-04-25 | 大日本印刷株式会社 | 断熱容器用積層体、断熱容器、断熱容器用積層体の製造方法、および断熱容器の製造方法 |
JP2019064683A (ja) * | 2017-09-29 | 2019-04-25 | 大日本印刷株式会社 | 断熱容器用積層体、断熱容器、断熱容器用積層体の製造方法、および断熱容器の製造方法 |
WO2019130179A1 (en) * | 2017-12-28 | 2019-07-04 | Stora Enso Oyj | A paperboard for packaging of liquid and/or frozen food |
US11486095B2 (en) | 2017-12-28 | 2022-11-01 | Stora Enso Oyj | Paperboard for packaging of liquid and/or frozen food |
WO2019186640A1 (ja) * | 2018-03-26 | 2019-10-03 | 大日本印刷株式会社 | 断熱容器用積層体、断熱容器、断熱容器用積層体の製造方法、および断熱容器の製造方法 |
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