WO2016167587A1 - 진공증착용 항균성 프라이머 코팅제 및 이를 이용한 다중코팅 방법 - Google Patents
진공증착용 항균성 프라이머 코팅제 및 이를 이용한 다중코팅 방법 Download PDFInfo
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- WO2016167587A1 WO2016167587A1 PCT/KR2016/003916 KR2016003916W WO2016167587A1 WO 2016167587 A1 WO2016167587 A1 WO 2016167587A1 KR 2016003916 W KR2016003916 W KR 2016003916W WO 2016167587 A1 WO2016167587 A1 WO 2016167587A1
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- antimicrobial
- vacuum deposition
- coating
- primer coating
- dry
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/60—Deposition of organic layers from vapour phase
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/08—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
- B05D5/083—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface involving the use of fluoropolymers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/52—Two layers
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3405—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of organic materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2201/00—Polymeric substrate or laminate
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2203/00—Other substrates
- B05D2203/30—Other inorganic substrates, e.g. ceramics, silicon
- B05D2203/35—Glass
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/76—Hydrophobic and oleophobic coatings
Definitions
- the present invention relates to an antimicrobial primer coating agent for vacuum deposition and a multi-coating method using the same, and more particularly, to a nano-thickness coating between the base material and the functional coating layer to give an antimicrobial power to the primer coating layer to improve the adhesion.
- the present invention relates to a primer coating agent and a multi-coating method capable of exhibiting antibacterial activity without disturbing the water / oil repellency and durability of the water / oil repellent coating by forming a water / oil repellent functional coating layer on the antimicrobial primer coating layer formed using the same.
- the anti-fingerprint coating gives the surface water / oil repellent properties by using a fluorine-based compound, which reduces the surface energy and reduces the contact area between fingerprints and external contaminants and the coated surface, minimizing the staining of contaminants and It has a wiping characteristic.
- vacuum deposition In order to form such a thin film, a coating method called “vacuum deposition” is used in most cases.
- the coating process using vacuum deposition (surface modification) is performed by applying a high temperature heat source to a target (coating agent) in a very short time. This very good, low chemical loss and nano-size thin film coating without compromising optical properties is possible.
- the present invention relates to a technology for developing and utilizing a vacuum deposition system using nanotechnology that has antimicrobial activity.
- wood wood, elm, plum, etc.
- the sustainability is difficult to maintain, and also there is a problem that the functionality such as water repellency / oil repellency and slipping is not implemented.
- U.S. Patent Publication No. US 2011-0025933 (Applicant: VIZIO INC., TELEVISION WITH ANTIMICROBIAL COATING) discloses a technique for inhibiting the growth of microorganisms by coating and coating a coating containing an antimicrobial agent on the outer surface of a television. There is a problem that functionality such as water / oil repellency and slipperiness is not implemented.
- Japanese Patent Application No. 2007-322624 (Applicant: ZNO LAB, Antibacterial material and method for producing the same) is a vacuum deposition on glass substrates, plastics, etc. that can be used on the surface of touch panels or mobile phones, It discloses an antimicrobial material and a method of manufacturing the same, characterized in that the zinc oxide thin film is formed by a method such as sputtering, this also has a problem that the functionality such as water repellency / oil repellency and slip properties are not implemented, and also due to the metal thin film There is a problem that the optical properties are lowered.
- the present invention by coating a nano-thickness between the base material and the functional coating layer to impart antimicrobial power to the primer coating layer to improve the adhesion, the vacuum coating antimicrobial primer coating agent that can be applied by the vacuum deposition method of the touch-type display coating method, and By forming a water / oil repellent functional coating layer on the antimicrobial primer coating layer formed by using a multi-coating method that can exhibit antimicrobial power without disturbing the water repellency and durability of the water / oil repellent coating, soft touch when using smart electronic devices and household appliances It is a technical problem to have a sense and to be able to easily remove contamination such as fingerprints and to use it safely from contamination with bacteria.
- a first aspect of the present invention provides a dry antimicrobial primer coating for vacuum deposition, comprising a polycondensation reaction product of a silicone-based polymer and a functional organic-inorganic silane compound, and an antimicrobial material.
- the silicone-based polymer and the functional organic-inorganic silane compound are polycondensed in the presence of the antimicrobial material.
- the antimicrobial substance is introduced into the polycondensation reaction product of the silicone-based polymer and the functional organic-inorganic silane compound, dispersed and mixed with each other.
- a process for preparing a mixture comprising: a) preparing a mixture comprising a silicone-based polymer, a functional organic-inorganic silane compound, and an antimicrobial material; And b) polycondensing the mixture.
- a method for preparing a dry antimicrobial primer coating for vacuum deposition is provided.
- a process for preparing a mixture comprising: i) preparing a mixture comprising a silicone-based polymer and a functional organic-inorganic silane compound; ii) polycondensation the mixture; And iii) injecting and dispersing the antimicrobial material into the result of the polycondensation reaction, and providing a method for preparing a dry antimicrobial primer coating for vacuum deposition.
- a method for producing a substrate comprising the steps of: 1) providing a substrate to be coated; 2) vacuum-depositing the dry antimicrobial primer coating of the present invention on the surface of the substrate to form an antimicrobial primer coating layer; And 3) vacuum depositing a dry water / oil repellent coating agent for vacuum deposition on the antimicrobial primer coating layer, which comprises a polycondensation reaction product of a fluorine-based polymer and a functional organic / inorganic silane compound to form a water / oil repellent functional coating layer.
- a multi-coating method of the substrate is provided.
- a coated article characterized in that it has a multi-coating layer on the surface comprising a vacuum deposition coating layer of the dry antimicrobial primer coating of the present invention and a water- and oil-repellent functional coating layer vacuum-deposited thereon. do.
- the vacuum deposition multi-coating formed according to the present invention exhibits excellent water and oil repellency with a surface water contact angle of 115 ° or more, excellent anti-fingerprint (AF), durability and optical properties (transmittance), and excellent antibacterial properties. It can be applied to various materials such as glass, plastic, and metal, and it is possible to greatly improve the base adhesion of the alkoxysilane end group of AF coating layer, which is hard to adhere to the plastic surface. It can be particularly suitably applied to the surface of smart devices, household appliances and other electronic products or parts thereof.
- FIG. 1 schematically shows a cross section of a substrate having a vacuum deposition multiple coating formed on the surface according to the invention.
- Figure 2 is an antimicrobial test for each of (a) tempered glass (TG), (b) polycarbonate (PC) and (c) polymethyl methacrylate (PMMA) having a vacuum deposition multiple coating formed according to the present invention. The pictures show the results.
- TG tempered glass
- PC polycarbonate
- PMMA polymethyl methacrylate
- a first aspect of the present invention provides a dry antimicrobial primer coating for vacuum deposition, comprising a polycondensation reaction product of a silicone-based polymer and a functional organic-inorganic silane compound, and an antimicrobial material.
- the silicone-based polymer and the functional organic-inorganic silane compound are polycondensed in the presence of the antimicrobial material.
- the antimicrobial substance is introduced into the polycondensation reaction product of the silicone-based polymer and the functional organic-inorganic silane compound, dispersed and mixed with each other.
- Silicone polymers usable in the present invention include, for example, modified silicone polymers having one or more functional groups selected from amino groups, epoxy groups, carboxyl groups, carbinol groups, methacryl groups, merceto groups and phenyl groups, or combinations thereof.
- the polymer of an aminoalkylsilane is mentioned.
- the functional organic-inorganic silane compound usable in the present invention includes at least one functional group (eg, an amino group, a vinyl group, an epoxy group, an alkoxy group, a halogen group, a mercapto group, a sulfide group, etc.) that performs a polycondensation reaction with the silicone-based polymer. It may be an organic-inorganic silane compound having.
- the functional organic-inorganic silane compound is aminopropyltriethoxysilane, aminopropyltrimethoxysilane, amino-methoxysilane, phenylaminopropyltrimethoxysilane, N- (2-aminoethyl) -3-aminopropyl Trimethoxysilane, N- ( ⁇ -aminoethyl) - ⁇ -aminopropylmethyldimethoxysilane, ⁇ -aminopropyltridimethoxysilane, ⁇ -aminopropyldimethoxysilane, ⁇ -aminopropyltriethoxysilane, ⁇ -Aminopropyl diethoxysilane, vinyl triethoxysilane, vinyl trimethoxysilane, vinyl tri (methoxyethoxy) silane, di-, tri- or tetraalkoxysilane, vinylmethoxysilane, vinyltrimethoxysi
- the antimicrobial material usable in the present invention may be selected from natural materials or extracts thereof, antimicrobial polymer compounds, metal-containing antimicrobial compounds and combinations thereof.
- Examples of the natural material or extract thereof include crab, shell of shrimp or extract thereof (e.g. chitosan), green tea or extract thereof (e.g. catechin), bark or extract thereof (e.g. Paeonol, Paeoniflorin, Paeonolide, sitosterol, Gallic acid, Methyl gallate, Tannic acid, Quercetin, etc., grapefruit or extracts thereof (e.g. naringin), citral, licorice or extracts thereof (e.g. flavonoids), cypress Trees or extracts thereof (e.g. phytoncide), bamboo or extracts thereof (e.g. polyphenols), germinated beans or extracts thereof (e.g.
- crab, shell of shrimp or extract thereof e.g. chitosan
- green tea or extract thereof e.g. catechin
- bark or extract thereof e.g. Paeonol, Paeoniflorin, Paeonolide, sitosterol, Gallic acid,
- glyceollins gold or extracts thereof (e.g. tyrosinase), horseradish or extracts thereof (e.g. Eg isothiocyanate), mustard or extracts thereof, hinokitol And combinations thereof.
- the extracts may be prepared by known extraction methods.
- antimicrobial polymer compound examples include at least one polymer compound selected from aromatic or heterocyclic polymers, acrylic or methacryl polymers, cationic conjugated polymer electrolytes, polysiloxane polymers, natural polymer mimic polymers, and phenol or benzoic acid derivative polymers, Or those having at least one functional group selected from ammonium base, phosphonium base, sulfonium base or other onium base, phenylamide group and diguanamid group attached to the branched polymer chain.
- polymer compound selected from aromatic or heterocyclic polymers, acrylic or methacryl polymers, cationic conjugated polymer electrolytes, polysiloxane polymers, natural polymer mimic polymers, and phenol or benzoic acid derivative polymers, Or those having at least one functional group selected from ammonium base, phosphonium base, sulfonium base or other onium base, phenylamide group and diguanamid group attached to the branched polymer chain.
- the metal-containing antimicrobial compound examples include organic compounds or complexes containing metal ions such as silver, copper, and zinc, and specifically, metal-chitin / chitosan, metal-carbonate, and metal-sulfate. , Metal-nitrates, metal-acetates, metal-zeolites and metal-phosphate compounds or complexes. Organics having excellent chelate-forming ability to metal ions include chitin / chitosan. Such metal-containing antimicrobial compounds can be prepared from various organic compounds.
- the antimicrobial material is harmless to the human body and has an initial antibacterial activity of 99.9% by coating an antimicrobial coating agent prepared using the natural material or its extract, or an antimicrobial polymer compound having stability and persistence. Excellent antibacterial effect can be obtained.
- chitosan chitosan
- peonol peonol: 1- (2-hydroxy-4-methoxyphenyl) ethanone
- a combination thereof may be used as the antimicrobial material.
- the content of the polycondensation reaction product of the silicone-based polymer and the functional organic-inorganic silane compound is preferably 80 to 99% by weight based on 100% by weight of the total weight of the coating agent, and is 85 to 95% by weight. It is more preferable that is.
- the content of the antimicrobial material is preferably 1 to 20% by weight, more preferably 5 to 15% by weight based on 100% by weight of the total weight of the coating agent.
- a process for preparing a mixture comprising: a) preparing a mixture comprising a silicone-based polymer, a functional organic-inorganic silane compound, and an antimicrobial material; And b) polycondensing the mixture.
- a method for preparing a dry antimicrobial primer coating for vacuum deposition is provided.
- a process for preparing a mixture comprising: i) preparing a mixture comprising a silicone-based polymer and a functional organic-inorganic silane compound; ii) polycondensation the mixture; And iii) injecting and dispersing the antimicrobial material into the result of the polycondensation reaction, and providing a method for preparing a dry antimicrobial primer coating for vacuum deposition.
- the conditions of the polycondensation reaction in the polycondensation reaction step is not particularly limited, for example, it may be carried out by reflux reaction at 100 ⁇ 200 °C temperature under an inert gas (for example, argon, nitrogen).
- the reaction mixture may be irradiated with ultrasonic waves and / or UV while the reaction is performed.
- the result of the polycondensation reaction may optionally go through a stabilization step.
- a stabilization step There are no particular limitations to the stabilization conditions, and for example, the result of the polycondensation reaction can be stabilized by leaving it at room temperature for 24 hours.
- a method for producing a substrate comprising the steps of: 1) providing a substrate to be coated; 2) vacuum-depositing the dry antimicrobial primer coating of the present invention on the surface of the substrate to form an antimicrobial primer coating layer; And 3) vacuum depositing a dry water / oil repellent coating agent for vacuum deposition on the antimicrobial primer coating layer, which comprises a polycondensation reaction product of a fluorine-based polymer and a functional organic / inorganic silane compound to form a water / oil repellent functional coating layer.
- a multi-coating method of the substrate is provided.
- the antimicrobial material is arranged at the base of the coating layer to exert the antimicrobial activity during the life of the coating.
- the water / oil repellent functional coating layer exhibits contamination resistance, water / oil repellency, surface lubrication activity, anti-fingerprint properties, and the like.
- the substrate to be coated is not particularly limited as long as it can be coated by a vacuum deposition method, glass (eg tempered glass (TG), etc.), plastic (eg acrylic, polycarbonate (PC), polymethylmetha) Substrates of various materials such as methacrylate (PMMA), polyethylene terephthalate (PET), acrylonitrile-butadiene-styrene (ABS) resins, etc.) and metals (eg, SUS, etc.) may be coated by the method of the present invention. .
- glass eg tempered glass (TG), etc.
- plastic eg acrylic, polycarbonate (PC), polymethylmetha
- PMMA methacrylate
- PET polyethylene terephthalate
- ABS acrylonitrile-butadiene-styrene
- metals eg, SUS, etc.
- the water / oil repellent coating agent for forming the water / oil repellent functional coating layer includes a polycondensation reaction product of the fluoropolymer and the functional organic / inorganic silane compound.
- the fluorine-based polymer usable in the water / oil repellent coating may be a perfluorinated polymer.
- the fluorine-based polymer is a perfluoropolyether, a vinylidene fluoride (Vinylidene fluoride) polymer, a tetrafluoroethylene polymer, a hexafluoropropylene polymer, a chlorotrifluoroethylene polymer and It may be selected from a combination of these, preferably perfluorinated polyether.
- those usable in the antimicrobial primer coating agent described above may be used without limitation.
- vacuum deposition there is no particular limitation on the method of vacuum deposition, and it can be carried out using conventional vacuum deposition methods and equipment. According to one embodiment of the present invention, it is possible to perform vacuum deposition coating using a 2050 ⁇ vacuum deposition equipment (Electron-beam evaporation, Thermal evaporation, Thermal sputter, etc.) by PVD (Physical Vapor Deposition) method.
- the advantage of vacuum deposition is that various materials can be easily applied to the coating, there is little loss of coating chemicals, and a clean and uniform thin film can be formed.
- the overall configuration of the device is relatively simple, and since the thermal and electrical complexity of the thin film is small, it is suitable for the study of the physical properties of the film during thin film formation.
- a coated article characterized in that it has a multi-coating layer on the surface comprising a vacuum deposition coating layer of the dry antimicrobial primer coating of the present invention and a water- and oil-repellent functional coating layer vacuum-deposited thereon. do.
- the article may be a smart device having a touch type display such as a mobile phone or a tablet PC of various materials such as glass, plastic and metal, a home appliance, a vending machine, a common interactive information device, an external electronic device that can be touched by hand, or a part thereof. It is preferably a smart device having a touch type display or a part thereof.
- a functional organic-inorganic silane compound aminopropyltriethoxysilane
- 50 g of a perfluoropolyether, a fluoropolymer, and a polycondensation reaction was performed at about 150 ° C. under an inert argon gas atmosphere. It was stabilized at room temperature for 24 hours to prepare a dry water / oil repellent coating (AF coating).
- AF coating dry water / oil repellent coating
- the tempered glass (TG) was multi-coated by E / B (Electron-beam) evaporation method in a 2050 ⁇ vacuum deposition equipment.
- E / B Electro-beam
- the tempered glass was wet cleaned with a 5 wt% alkali cleaner (cleaning agent for tempered glass) in a 10 bath washer before coating.
- Vacuum deposition conditions were initial etching: 180 seconds and temperature: 80 ° C.
- the contact angle of the coated surface was measured using a contact angle measuring device.
- the size of one droplet was 3 ⁇ l and in order to confirm the uniformity of the coating, the contact angle of 5 points per coated sample was measured and averaged.
- the contact angle was measured.
- the change in the contact angle after the test compared to the initial contact angle of the coated sample was within 15 ° to proceed to PASS.
- the contact angle was measured. When the change in the contact angle after the test compared to the initial contact angle of the coated sample was within 15 ° to proceed to PASS.
- the surface of the sample coated with 5 wt% sodium chloride (NaCl) aqueous solution was sprayed, left for 72 hours, and the contact angle was measured. When the change in the contact angle after the test compared to the initial contact angle of the coated sample was within 15 ° to proceed to PASS.
- Pencils were prepared up to H-9H, and the load was set at 1 kg and tested twice by coating on the coating surface.
- E. coli ATCC 8739
- Staphylococcus aureus ATCC 6538P
- 400 ⁇ l of the diluted bacterial solution was inoculated on the surface of the coated sample and incubated in a constant temperature and humidity environment for 24 hours, and then desorption was performed to confirm the antibacterial result.
- a dry water / oil repellent coating (AF coating agent) was prepared in the same manner as in Example 1.
- Multicoating was performed on the polycarbonate (PC) substrate in the same manner as in Example 2.
- the initial contact angle was measured by the method described above and the initial antimicrobial activity was tested. The test results are shown in Table 3 below.
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Abstract
Description
Claims (16)
- 실리콘계 중합체와 기능성 유무기실란 화합물의 중축합 반응 결과물, 및 항균 물질을 포함하는, 진공 증착용 건식 항균성 프라이머 코팅제.
- 제1항에 있어서. 실리콘계 중합체와 기능성 유무기실란 화합물이 항균 물질의 존재하에 중축합되는 것을 특징으로 하는 진공 증착용 건식 항균성 프라이머 코팅제.
- 제1항에 있어서. 실리콘계 중합체와 기능성 유무기실란 화합물의 중축합 반응 결과물에 항균 물질이 투입되고 분산되어 서로 혼합되는 것을 특징으로 하는 진공 증착용 건식 항균성 프라이머 코팅제.
- 제1항에 있어서. 실리콘계 중합체가 아미노기, 에폭시기, 카르복실기, 카르비놀기, 메타크릴기, 메르켑토기 및 페닐기로부터 선택되는 하나 이상의 관능기를 갖는 변성 실리콘 중합체 또는 그 조합인 것을 특징으로 하는 진공 증착용 건식 항균성 프라이머 코팅제.
- 제1항에 있어서, 기능성 유무기실란 화합물이 아미노프로필트리에톡시실란, 아미노프로필트리메톡시실란, 아미노-메톡시실란, 페닐아미노프로필트리메톡시실란, N-(2-아미노에틸)-3-아미노프로필트리메톡시실란, N-(β-아미노에틸)-γ-아미노프로필메틸디메톡시실란, γ-아미노프로필트리디메톡시실란, γ-아미노프로필디메톡시실란, γ-아미노프로필트리에톡시실란, γ-아미노프로필디에톡시실란, 비닐트리에톡시실란, 비닐트리메톡시실란, 비닐트리(메톡시에톡시)실란, 디-, 트리- 또는 테트라알콕시실란, 비닐메톡시실란, 비닐트리메톡시실란, 비닐에폭시실란, 비닐트리에폭시실란, 3-글리시독시프로필트리메톡시실란, 3-메타크릴옥시프로필트리메톡시실란, γ-글리시독시프로필트리에톡시실란, γ-메타크릴옥시프로필트리메톡시실란, 클로로트리메틸실란, 트리클로로에틸실란, 트리클로로메틸실란, 트리클로로페닐실란, 트리클로로비닐실란, 메르캡토프로필트리에톡시실란, 트리플루오로프로필트리메톡시실란, 비스(트리메톡시실릴프로필)아민, 비스(3-트리에톡시실릴프로필)테트라설파이드, 비스(트리에톡시실릴프로필)디설파이드, (메타크릴옥시)프로필트리메톡시실란, 2-(3,4-에폭시시클로헥실)에틸트리메톡시실란, 3-글리시독시프로필메틸디에톡시실란, 3-글리시독시프로필디에톡시실란, 3-글리시독시프로필트리에톡시실란, p-스티릴트리메톡시실란 및 이들의 조합으로부터 선택되는 것을 특징으로 하는 진공 증착용 건식 항균성 프라이머 코팅제.
- 제1항에 있어서, 항균 물질이 천연 소재 또는 그 추출물, 항균성 고분자 화합물, 금속-함유 항균성 화합물 및 이들의 조합으로부터 선택되는 것을 특징으로 하는 진공 증착용 건식 항균성 프라이머 코팅제.
- 제1항에 있어서, 항균 물질이 페오놀인 것을 특징으로 하는 진공 증착용 건식 항균성 프라이머 코팅제.
- a) 실리콘계 중합체, 기능성 유무기실란 화합물 및 항균 물질을 포함하는 혼합물을 제조하는 단계; 및 b) 상기 혼합물을 중축합 반응시키는 단계;를 포함하는, 진공 증착용 건식 항균성 프라이머 코팅제의 제조방법.
- i) 실리콘계 중합체 및 기능성 유무기실란 화합물을 포함하는 혼합물을 제조하는 단계; ii) 상기 혼합물을 중축합 반응시키는 단계; 및 iii) 상기 중축합 반응의 결과물에 항균 물질을 투입하고 분산시켜 혼합하는 단계;를 포함하는, 진공 증착용 건식 항균성 프라이머 코팅제의 제조방법.
- 제8항 또는 제9항에 있어서,실리콘계 중합체가 아미노기, 에폭시기, 카르복실기, 카르비놀기, 메타크릴기, 메르켑토기 및 페닐기로부터 선택되는 하나 이상의 관능기를 갖는 변성 실리콘 중합체 또는 그 조합이고;기능성 유무기실란 화합물이 아미노프로필트리에톡시실란, 아미노프로필트리메톡시실란, 아미노-메톡시실란, 페닐아미노프로필트리메톡시실란, N-(2-아미노에틸)-3-아미노프로필트리메톡시실란, N-(β-아미노에틸)-γ-아미노프로필메틸디메톡시실란, γ-아미노프로필트리디메톡시실란, γ-아미노프로필디메톡시실란, γ-아미노프로필트리에톡시실란, γ-아미노프로필디에톡시실란, 비닐트리에톡시실란, 비닐트리메톡시실란, 비닐트리(메톡시에톡시)실란, 디-, 트리- 또는 테트라알콕시실란, 비닐메톡시실란, 비닐트리메톡시실란, 비닐에폭시실란, 비닐트리에폭시실란, 3-글리시독시프로필트리메톡시실란, 3-메타크릴옥시프로필트리메톡시실란, γ-글리시독시프로필트리에톡시실란, γ-메타크릴옥시프로필트리메톡시실란, 클로로트리메틸실란, 트리클로로에틸실란, 트리클로로메틸실란, 트리클로로페닐실란, 트리클로로비닐실란, 메르캡토프로필트리에톡시실란, 트리플루오로프로필트리메톡시실란, 비스(트리메톡시실릴프로필)아민, 비스(3-트리에톡시실릴프로필)테트라설파이드, 비스(트리에톡시실릴프로필)디설파이드, (메타크릴옥시)프로필트리메톡시실란, 2-(3,4-에폭시시클로헥실)에틸트리메톡시실란, 3-글리시독시프로필메틸디에톡시실란, 3-글리시독시프로필디에톡시실란, 3-글리시독시프로필트리에톡시실란, p-스티릴트리메톡시실란 및 이들의 조합으로부터 선택되며;항균 물질이 천연 소재 또는 그 추출물, 항균성 고분자 화합물, 금속-함유 항균성 화합물 및 이들의 조합으로부터 선택되는 것을 특징으로 하는,진공 증착용 건식 항균성 프라이머 코팅제의 제조방법.
- 제8항 또는 제9항에 있어서, 중축합 반응이 불활성 가스 하의 100~200℃ 온도에서 환류 반응으로 수행되는 것을 특징으로 하는 진공 증착용 건식 항균 코팅제의 제조방법.
- 1) 코팅될 기재를 제공하는 단계; 2) 상기 기재 표면에 제1항 내지 제7항 중 어느 한 항의 건식 항균성 프라이머 코팅제를 진공증착시켜 항균성 프라이머 코팅층을 형성하는 단계; 및 3) 상기 항균성 프라이머 코팅층 위에, 불소계 중합체와 기능성 유무기실란 화합물의 중축합 반응 결과물을 포함하는 진공 증착용 건식 발수/발유성 코팅제를 진공증착시켜 발수/발유 기능성 코팅층을 형성하는 단계;를 포함하는, 기재의 다중코팅 방법.
- 제12항에 있어서, 기재가 유리, 플라스틱 또는 금속 소재인 것을 특징으로 하는 기재의 다중코팅 방법.
- 제12항에 있어서, 불소계 중합체가 과불소화 폴리에테르, 플루오르화비닐리덴 중합체, 테트라플루오로에틸렌 중합체, 헥사플루오르프로필렌 중합체, 염화삼불화에틸렌 중합체 및 이들의 조합으로부터 선택되는 것을 특징으로 하는, 기재의 다중코팅 방법.
- 제1항 내지 제7항 중 어느 한 항의 건식 항균성 프라이머 코팅제의 진공증착 코팅층 및 그 위에 진공증착된 발수/발유 기능성 코팅층을 포함하는 다중코팅층을 표면에 갖는 것을 특징으로 하는, 코팅된 물품.
- 제15항에 있어서, 물품이 터치형 디스플레이를 갖는 스마트 기기, 생활가전, 자판기, 공용 쌍방향 정보기기, 손으로 터치할 수 있는 외장 전자제품, 또는 그 부품인 것을 특징으로 하는, 코팅된 물품.
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Cited By (3)
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---|---|---|---|---|
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JP2022120796A (ja) * | 2021-02-05 | 2022-08-18 | 住友化学株式会社 | 積層体 |
WO2022224892A1 (ja) * | 2021-04-20 | 2022-10-27 | 富士フイルム株式会社 | 積層体 |
WO2022255158A1 (ja) | 2021-05-31 | 2022-12-08 | 信越化学工業株式会社 | 抗菌・抗カビ・抗ウイルス性を有する撥水撥油部材及び撥水撥油部材の製造方法並びに物品 |
CN115160928B (zh) * | 2022-05-13 | 2023-06-13 | 广钢气体(广州)有限公司 | 一种抗菌硅橡胶涂层及其制备方法和应用 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH10109906A (ja) * | 1996-10-03 | 1998-04-28 | Taishiyoo Technos:Kk | 工業用抗菌防黴剤 |
JPH11293154A (ja) * | 1998-04-10 | 1999-10-26 | Toray Ind Inc | 防カビ性コーティング膜 |
US20040225039A1 (en) * | 2001-09-11 | 2004-11-11 | Karsten Hackbarth | UV-curing anti-fingerprinting coatings |
US20060110537A1 (en) * | 2004-11-23 | 2006-05-25 | Hon Hai Precision Industry Co., Ltd. | Anti-fingerprint coating construction |
KR20140069801A (ko) * | 2012-11-30 | 2014-06-10 | 삼성전자주식회사 | 복합기능 코팅 구조 및 이를 형성하는 방법 |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0827404A (ja) * | 1994-05-09 | 1996-01-30 | Nippon Sheet Glass Co Ltd | 抗菌性コーティング用組成物、そのコーティング法、および抗菌性被覆物品 |
JPH1121509A (ja) * | 1997-07-02 | 1999-01-26 | Ohashi Kagaku Kogyo Kk | 建築物屋根材補修用塗料 |
JPH11264067A (ja) * | 1998-03-18 | 1999-09-28 | Nikon Corp | 不活性化された酸化ケイ素系薄膜の製造方法 |
JP2000328230A (ja) * | 1999-05-20 | 2000-11-28 | Toray Ind Inc | 有機膜の成膜法 |
JP2000351941A (ja) * | 1999-06-10 | 2000-12-19 | Jsr Corp | 防汚性物品用コーティング組成物および防汚性物品 |
JP2001347136A (ja) * | 2000-06-09 | 2001-12-18 | Kansai Paint Co Ltd | 光触媒活性塗膜を形成可能な無機系塗料及び該塗料を用いた塗装方法 |
DE10054248A1 (de) * | 2000-11-02 | 2002-05-08 | Inst Neue Mat Gemein Gmbh | Mikrobizid beschichteter Gegenstand, Verfahren zu dessen Herstellung und dessen Verwendung |
JP4460361B2 (ja) * | 2003-06-02 | 2010-05-12 | 日本メナード化粧品株式会社 | メラニン産生促進剤 |
JP2008065110A (ja) * | 2006-09-08 | 2008-03-21 | Seiko Epson Corp | 防汚性光学物品 |
JP2010535286A (ja) * | 2007-08-02 | 2010-11-18 | セコ コーポレイション リミテッド | 乾式真空蒸着を用いた多層薄膜の製造方法 |
CN104603345A (zh) * | 2012-08-09 | 2015-05-06 | 纳幕尔杜邦公司 | 改善的阻隔织物 |
KR101677024B1 (ko) * | 2015-03-20 | 2016-11-17 | 주식회사 쎄코 | 항균력을 갖는 진공증착용 발수형 나노 코팅제 및 이를 이용한 코팅 방법 |
CN105176342B (zh) * | 2015-10-08 | 2018-05-15 | 厦门博恩思应用材料科技有限公司 | 一种纳米抗菌防指纹药液材料、其制备方法及其应用 |
-
2015
- 2015-04-16 KR KR1020150053693A patent/KR101690091B1/ko active IP Right Grant
-
2016
- 2016-04-15 WO PCT/KR2016/003916 patent/WO2016167587A1/ko active Application Filing
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Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH10109906A (ja) * | 1996-10-03 | 1998-04-28 | Taishiyoo Technos:Kk | 工業用抗菌防黴剤 |
JPH11293154A (ja) * | 1998-04-10 | 1999-10-26 | Toray Ind Inc | 防カビ性コーティング膜 |
US20040225039A1 (en) * | 2001-09-11 | 2004-11-11 | Karsten Hackbarth | UV-curing anti-fingerprinting coatings |
US20060110537A1 (en) * | 2004-11-23 | 2006-05-25 | Hon Hai Precision Industry Co., Ltd. | Anti-fingerprint coating construction |
KR20140069801A (ko) * | 2012-11-30 | 2014-06-10 | 삼성전자주식회사 | 복합기능 코팅 구조 및 이를 형성하는 방법 |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114381200A (zh) * | 2020-10-21 | 2022-04-22 | 惠州市海兰新材料有限公司 | 复合抗菌防霉涂料及其使用方法 |
CN112625411A (zh) * | 2020-12-10 | 2021-04-09 | 好维股份有限公司 | 一种可生物降解的抗菌牙刷及其生产工艺 |
CN112625411B (zh) * | 2020-12-10 | 2023-03-10 | 好维股份有限公司 | 一种可生物降解的抗菌牙刷及其生产工艺 |
CN113698816A (zh) * | 2021-08-12 | 2021-11-26 | 盘锦海兴科技股份有限公司 | 一种抗菌涂层及其制备方法与应用 |
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KR20160123540A (ko) | 2016-10-26 |
CN107580636B (zh) | 2020-01-14 |
DE112016001751T5 (de) | 2018-01-18 |
JP2018521199A (ja) | 2018-08-02 |
CN107580636A (zh) | 2018-01-12 |
JP6595696B2 (ja) | 2019-10-23 |
KR101690091B1 (ko) | 2016-12-27 |
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