WO2015169069A1 - 薄膜晶体管及其制作方法、显示基板和显示装置 - Google Patents
薄膜晶体管及其制作方法、显示基板和显示装置 Download PDFInfo
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- WO2015169069A1 WO2015169069A1 PCT/CN2014/089900 CN2014089900W WO2015169069A1 WO 2015169069 A1 WO2015169069 A1 WO 2015169069A1 CN 2014089900 W CN2014089900 W CN 2014089900W WO 2015169069 A1 WO2015169069 A1 WO 2015169069A1
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- Prior art keywords
- zinc oxide
- thin film
- film transistor
- indium gallium
- gallium zinc
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- 239000010409 thin film Substances 0.000 title claims abstract description 66
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 48
- 239000000758 substrate Substances 0.000 title claims abstract description 41
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 322
- 239000011787 zinc oxide Substances 0.000 claims abstract description 161
- 229910052733 gallium Inorganic materials 0.000 claims abstract description 124
- 229910052738 indium Inorganic materials 0.000 claims abstract description 124
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims abstract description 122
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims abstract description 122
- 238000000151 deposition Methods 0.000 claims description 34
- 238000000034 method Methods 0.000 claims description 32
- 239000013078 crystal Substances 0.000 claims description 24
- 230000008569 process Effects 0.000 claims description 18
- YVTHLONGBIQYBO-UHFFFAOYSA-N zinc indium(3+) oxygen(2-) Chemical compound [O--].[Zn++].[In+3] YVTHLONGBIQYBO-UHFFFAOYSA-N 0.000 claims description 16
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 11
- 239000001301 oxygen Substances 0.000 claims description 11
- 229910052760 oxygen Inorganic materials 0.000 claims description 11
- 238000004544 sputter deposition Methods 0.000 claims description 10
- 238000005240 physical vapour deposition Methods 0.000 claims description 9
- 239000007789 gas Substances 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 238000001771 vacuum deposition Methods 0.000 claims description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims 4
- 229910052786 argon Inorganic materials 0.000 claims 2
- 230000000694 effects Effects 0.000 abstract description 11
- 238000013508 migration Methods 0.000 abstract description 6
- 230000005012 migration Effects 0.000 abstract description 6
- 238000005530 etching Methods 0.000 description 25
- 230000008021 deposition Effects 0.000 description 23
- 238000002425 crystallisation Methods 0.000 description 20
- 230000008025 crystallization Effects 0.000 description 20
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- 229910052725 zinc Inorganic materials 0.000 description 10
- 239000011701 zinc Substances 0.000 description 10
- 230000004888 barrier function Effects 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 239000010408 film Substances 0.000 description 6
- 238000000059 patterning Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 4
- 229910021417 amorphous silicon Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910001257 Nb alloy Inorganic materials 0.000 description 1
- 229910004205 SiNX Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- QNTVPKHKFIYODU-UHFFFAOYSA-N aluminum niobium Chemical compound [Al].[Nb] QNTVPKHKFIYODU-UHFFFAOYSA-N 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000000206 photolithography Methods 0.000 description 1
- 238000005289 physical deposition Methods 0.000 description 1
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000027756 respiratory electron transport chain Effects 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
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- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
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- H01L29/12—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
- H01L29/24—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only semiconductor materials not provided for in groups H01L29/16, H01L29/18, H01L29/20, H01L29/22
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/66007—Multistep manufacturing processes
- H01L29/66075—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
- H01L29/66227—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
- H01L29/66409—Unipolar field-effect transistors
- H01L29/66477—Unipolar field-effect transistors with an insulated gate, i.e. MISFET
- H01L29/66742—Thin film unipolar transistors
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/66007—Multistep manufacturing processes
- H01L29/66969—Multistep manufacturing processes of devices having semiconductor bodies not comprising group 14 or group 13/15 materials
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/786—Thin film transistors, i.e. transistors with a channel being at least partly a thin film
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/786—Thin film transistors, i.e. transistors with a channel being at least partly a thin film
- H01L29/78696—Thin film transistors, i.e. transistors with a channel being at least partly a thin film characterised by the structure of the channel, e.g. multichannel, transverse or longitudinal shape, length or width, doping structure, or the overlap or alignment between the channel and the gate, the source or the drain, or the contacting structure of the channel
Definitions
- Embodiments of the present invention relate to a thin film transistor, a method of fabricating the same, a display substrate, and a display device.
- Oxide transistors have received wide attention due to their high mobility and compatibility with a-Si production lines.
- an oxide transistor having an etch barrier layer (ESL) structure develops a back channel etch type (BCE) oxide (such as indium gallium zinc) due to the disadvantage of a complicated process and insufficient competitiveness with respect to a-Si. Oxide) thin film transistors have become the focus of development.
- ESL etch barrier layer
- BCE back channel etch type oxide
- Embodiments of the present invention provide a thin film transistor, a method of fabricating the same, a display substrate, and a display device.
- a method of fabricating a thin film transistor comprising the steps of: fabricating an active having C-axis crystal orientation characteristics using indium gallium zinc oxide InGaO 3 (ZnO) m on a substrate. Layer, where m ⁇ 2.
- the active layer is formed by depositing an indium gallium zinc oxide layer on the substrate at least twice.
- an active layer having C-axis crystal orientation characteristics using indium gallium zinc oxide InGaO 3 (ZnO) m deposited by physical vapor deposition at a first power and a first rate a C-axis oriented first indium gallium zinc oxide layer; depositing a second indium gallium zinc oxide layer at a second power and a second rate by physical vapor deposition on the formed first layer of indium gallium zinc oxide layer
- the first indium gallium zinc oxide layer and the second indium gallium zinc oxide layer form an active layer, wherein the first power is less than the second power, and the first rate is less than the second rate.
- the temperature condition for forming the first indium gallium zinc oxide layer and the temperature condition for the second indium gallium zinc oxide layer are both 200 ° C to 400 ° C.
- the active layer is deposited by vacuum deposition using a Nd:YAG laser, and the laser has an output wavelength of 193 to 1064 nm, a repetition frequency of greater than 1 Hz, and a small pulse width. At 10ns.
- the active layer is deposited using a Nd:YAG laser under vacuum conditions, and the laser has an output wavelength of 1064 nm, a repetition rate of 10 Hz, and a pulse width of 10 ns.
- the first power is a laser power of 0.2 to 0.4 W before focusing.
- the first power is a laser power of 0.3 W before focusing.
- the first indium gallium zinc oxide layer is deposited for a period of 10 to 30 s, and the first indium gallium zinc oxide layer is formed to have a thickness of 0 ⁇ d ⁇ 10 nm.
- the second power is 0.5 to 1.0 W before the laser is focused.
- the second power is 0.5W before focusing.
- the first indium gallium zinc oxide layer and the second indium gallium zinc oxide layer are formed by sputtering under vacuum conditions.
- the first indium gallium zinc oxide layer is formed by one scan at a condition of the first power of 2 to 3 KW and an O 2 flow rate of 25 standard milliliters per minute;
- the second layer of indium gallium zinc oxide layer is formed by one scan at a condition of the second power of 4 to 6 KW and an O 2 flow rate of 25 standard milliliters per minute.
- the first indium gallium zinc oxide layer is formed by one scan under the condition that the first power is 3 KW and the O 2 flow rate is 25 standard milliliters per minute; the second layer of indium gallium zinc The oxide layer was formed by one scan under the conditions of the second power of 4.5 KW and the O 2 flow rate of 25 standard milliliters per minute.
- the indium zinc oxide InGaO 3 (ZnO) m comprises: any one of InGaZn 2 O 5 , InGaZn 3 O 6 , InGaZn 4 O 7 , InGaZn 5 O 8 or InGaZn 6 O 9 .
- the active layer is deposited in three layers on the substrate, wherein the indium gallium zinc oxide InGaO 3 (ZnO) m growth rate of each layer increases in a gradually increasing manner.
- At least one embodiment of the present invention also provides a thin film transistor including an active layer disposed on a substrate, wherein the active layer includes indium zinc oxide having C-axis crystal orientation characteristics,
- the indium zinc oxide is InGaO 3 (ZnO) m , where m ⁇ 2.
- the indium zinc oxide InGaO 3 (ZnO) m includes any one of InGaZn 2 O 5 , InGaZn 3 O 6 , InGaZn 4 O 7 , InGaZn 5 O 8 or InGaZn 6 O 9 .
- At least one embodiment of the present invention also provides a display substrate including a substrate And the thin film transistor disposed on the substrate.
- At least one embodiment of the present invention also provides a display device including the above display substrate.
- FIG. 1 is a schematic structural diagram of a display substrate according to an embodiment of the present invention.
- FIGS. 2a-2d are flowcharts showing the fabrication of a thin film transistor structure according to an embodiment of the present invention.
- the indium gallium zinc oxide has a high crystallization temperature, such as a commonly used indium gallium zinc oxide semiconductor thin film transistor device and a target component used in the preparation of the back sheet.
- InGaZnO 4 therefore, the sample deposited by the target target is not easily crystallized, and even when the substrate is heated to 500 degrees, the film cannot be crystallized.
- This method has high process requirements, thereby affecting the production efficiency and stability of the thin film transistor.
- embodiments of the present invention provide a thin film transistor, a method of fabricating the same, a display substrate, and a display device.
- the method changes the zinc content of the existing target by using an active layer formed by indium gallium zinc oxide InGaO 3 (ZnO) m having C-axis crystal orientation characteristics. The crystallization temperature of the indium gallium zinc oxide is lowered, and the stability of the bias voltage test of the thin film transistor is improved.
- the etch rate of the indium gallium zinc oxide sample after crystallization in the source and drain etching liquid is slow. Several times, precise control of the etching can be achieved.
- the material characteristics enable the thin film transistor to adopt a back channel etch type structure, which reduces the fabrication process of the etch barrier layer.
- the active layer made of InGaO 3 (ZnO) m has a good electron migration effect, improves the quality of the active layer produced, and further improves the quality of the display device.
- Embodiments of the present invention provide a method of fabricating a thin film transistor, the method comprising the following steps:
- An active layer having C-axis crystal orientation characteristics is formed on the substrate using indium gallium zinc oxide InGaO 3 (ZnO) m , where m ⁇ 2.
- the C-axis crystal orientation is such that the X-axis is oriented horizontally, the Y-axis is perpendicular to the X-axis, the Z-axis is perpendicular to the plane formed by the XY-axis, and the circular motion along the Z-axis is the C-axis orientation.
- the method by using an active layer having C-axis crystal orientation characteristics formed by indium gallium zinc oxide InGaO 3 (ZnO) m, the method changes the zinc content in the existing target and reduces the oxidation of indium gallium zinc.
- the crystallization temperature of the material improves the stability of the bias test of the thin film transistor.
- the etch rate of the indium gallium zinc oxide sample after crystallization in the source and drain etching liquid is slow. Several times, precise control of the etching can be achieved.
- the material characteristics enable the thin film transistor to adopt a back channel etch type structure, which reduces the fabrication process of the etch barrier layer.
- the active layer made of InGaO 3 (ZnO) m has a good electron transfer effect and improves the quality of the active layer produced.
- the indium zinc oxide InGaO 3 (ZnO) m may be, for example, any one of InGaZn 2 O 5 , InGaZn 3 O 6 , InGaZn 4 O 7 , InGaZn 5 O 8 or InGaZn 6 O 9 .
- the active layer is formed by using such an indium gallium zinc oxide, and since it has a low crystallization temperature, it can be crystallized at 200 to 400 ° C, thereby effectively reducing the crystallization temperature of the indium gallium zinc oxide.
- a first indium gallium zinc oxide layer having a C-axis orientation is deposited by physical vapor deposition at a first power and a first rate.
- a second indium gallium zinc oxide layer is deposited at a second rate.
- the first indium gallium zinc oxide layer and the second indium gallium zinc oxide layer form an active layer.
- the first power is less than the second power, and the first rate is less than the second rate.
- the first indium gallium zinc oxide layer is formed by slow deposition, and the first indium gallium zinc oxide layer can obtain a better crystallization effect due to the slow deposition rate.
- the first indium zinc oxide layer can be used as a crystal nucleus when the second indium gallium zinc oxide layer is crystallized, thereby improving the second indium gallium zinc oxide.
- the crystallization rate of the layer further increases the fabrication efficiency of the active layer while allowing the resulting active layer to have C-axis crystal orientation characteristics.
- both the first indium gallium zinc oxide layer and the second indium gallium zinc oxide layer are formed at a temperature of 200 ° C to 400 ° C. Therefore, the temperature at which the indium gallium zinc oxide crystallizes is lowered as compared with the general technique.
- the active layer is formed by physical deposition, different processes can be employed.
- a first indium gallium zinc oxide layer having a C-axis crystal orientation characteristic may be deposited at a first power and a first rate by a laser pulse method; on the formed first indium gallium zinc oxide layer A second indium gallium zinc oxide layer is deposited at the second power and the second rate, and the first indium gallium zinc oxide layer and the second indium gallium zinc oxide layer form an active layer.
- an active layer is formed using a Nd:YAG pulsed laser.
- the output wavelength of the laser is 193-1064 nm, for example 1064 nm, the repetition frequency is greater than 1 Hz, for example 10 Hz, and the pulse width is less than or equal to 10 ns.
- the mechanical pump of the vacuum system is turned on, and the vacuum chamber is evacuated.
- the degree of vacuum reaches 0 to 5 Pa
- the molecular pump is turned on and the vacuuming operation is continued.
- the molecular pump When the degree of vacuum reached 2.5 ⁇ 10 -4 Pa, the molecular pump was turned off, the mechanical pump was turned on, and oxygen was simultaneously introduced into the vacuum chamber to maintain the oxygen partial pressure at 10.0 Pa.
- the laser before focusing uses a first power of 0.2-0.4W, for example, 0.3W, a temperature of 200-400 degrees when depositing an indium gallium zinc oxide layer, a deposition time of 10-30s, and a first rate.
- a first indium gallium zinc oxide layer having a thickness between 0 ⁇ d ⁇ 10 nm.
- the oxygen flow rate is reduced, the vacuum chamber pressure is maintained at 5.0 Pa, and the laser is used to have a second power of 0.5-1.0 W, for example 0.5 W, before focusing, and a second deposition rate is formed on the first indium gallium zinc oxide layer.
- the active layer may be formed by sputtering.
- the degree of vacuum reaches 2.5 ⁇ 10 ⁇ 4 Pa
- the deposition temperature is kept at 200 to 400 degrees
- oxygen and Ar gas are introduced into the vacuum chamber.
- O: Ar 1:4.
- the power during deposition is 2-3 KW of the first power, for example, 3 KW, the flow rate of O 2 is 25 ML/min, and the number of scans is 1 time, so that the indium gallium zinc oxide forms the first indium gallium zinc oxide at the first rate. Layer of matter.
- the deposition power is increased to a second power of 4-6 KW, for example, 4.5 KW, and the O 2 flow rate is 25
- the ML/min, the number of scans was 1 and deposited to the desired film thickness to form the active layer.
- two layers of indium gallium zinc oxide layers are formed by different process conditions: a first indium gallium zinc oxide layer is formed by slow deposition, and the first indium gallium zinc oxide layer is formed due to a slow deposition rate. A better crystallization effect can be obtained. And, in the subsequent rapid deposition to form the second indium gallium zinc oxide layer, the first indium zinc oxide layer can serve as a crystal nucleus when the second indium gallium zinc oxide layer is crystallized, thereby improving the second indium gallium zinc oxide. The crystallization rate of the layer further increases the fabrication efficiency of the active layer, and at the same time, the resulting active layer has C-axis crystal orientation characteristics.
- the etch rate of the thus-crystallized InGaO 3 (ZnO) m sample in the source and drain etching solutions is slower than that of the uncrystallized indium zinc oxide sample in the source and drain etching solutions.
- precise control of the etching can be achieved.
- the back channel etch type structure thin film transistor requires the etching solution to have different etching selectivity ratios to the active layer and the source and drain layers, otherwise the channel may be greatly damaged during the source and drain layer pattern process. The channel is etched away.
- the in-crystalized InGaO 3 (ZnO) m is less affected by the source and drain etching liquids than the amorphous indium zinc oxide, and the physical properties enable the back channel to be engraved.
- Etched oxide thin film transistor structure Compared with the etch barrier type thin film transistor structure, the etch stop layer can be saved in a separate patterning process, which can simplify the fabrication process of the oxide thin film transistor and save the manufacturing cost.
- FIG. 2 is a flow chart showing a structure of a thin film transistor according to an embodiment of the present invention. A method for fabricating a thin film transistor according to an embodiment of the present invention will be described in detail below with reference to FIGS. 2a to 2d.
- Step 1 The transparent substrate 1 is cleaned by a standard method.
- Step 2 As shown in FIG. 2a, a gate electrode 2 is formed on the transparent substrate 1.
- a gate metal layer of 50 to 400 nm is deposited by sputtering or evaporation to form a gate electrode 2 by patterning.
- Step 3 As shown in FIG. 2b, a gate insulating layer 3 is formed on the gate 2.
- a gate insulating layer 3 of SiNx or SiO x having a thickness of 100 to 500 nm is prepared by plasma enhanced chemical vapor deposition, wherein x is a natural number.
- Step 4 As shown in FIG. 2c, an active layer 4 having C-axis crystal orientation characteristics, wherein m ⁇ 2, is formed using indium gallium zinc oxide InGaO 3 (ZnO) m .
- a first indium gallium zinc oxide layer having a C-axis orientation is deposited by physical vapor deposition at a first power and a first rate.
- the physical vapor deposition method can be a sputtering or laser pulse method.
- the laser system used is a Nd:YAG pulsed laser having an output wavelength of 193-1064 nm, for example, 1064 nm, a repetition frequency greater than 1 Hz, for example, 10 Hz, and a pulse width of 10 ns or less.
- Embodiments of the invention employ the third harmonic of the laser (wavelength 355 nm).
- the mechanical pump of the vacuum system is turned on to evacuate the vacuum chamber. When the degree of vacuum reaches 0 to 5 Pa, the molecular pump is turned on and the vacuuming operation is continued. When the degree of vacuum reached 2.5 ⁇ 10 -4 Pa, the molecular pump was turned off, the mechanical pump was turned on, and oxygen was simultaneously introduced into the vacuum chamber to maintain the oxygen partial pressure at 10.0 Pa.
- the average power of the laser before focusing is 0.2-0.4 W, for example, 0.3 W.
- the temperature of depositing the indium gallium zinc oxide layer is 200-400 degrees, and the deposition time is 10-30 s, forming a layer of 0-10 nm indium gallium zinc oxide layer, that is, the first indium gallium zinc oxide layer.
- the first indium gallium zinc oxide layer acts as a seed crystal to improve crystallization properties.
- the oxygen flow rate is decreased, the vacuum chamber pressure is 5.0 Pa, and the average laser power before focusing is 0.5-1.0 W, for example, 0.5 W, and deposition is continued on the first indium gallium zinc oxide layer to form a second indium gallium zinc oxide layer.
- the desired thickness to form an active layer.
- the power during deposition is 2-3 KW of the first power, for example 3 KW, the flow rate of O 2 is 25 ML/min, and the number of scans is 1 time, so that the indium gallium zinc oxide forms the first indium gallium zinc oxide at the first rate.
- Floor 2-3 KW of the first power, for example 3 KW, the flow rate of O 2 is 25 ML/min, and the number of scans is 1 time, so that the indium gallium zinc oxide forms the first indium gallium zinc oxide at the first rate.
- a second layer of indium gallium zinc oxide layer is deposited on the deposited first layer of indium gallium zinc oxide layer.
- the deposition power is increased to a second power of 4-6 KW, for example, 4.5 KW, an O 2 flow rate of 25 cc/min, a number of scans, and deposition to a desired film thickness to form an active layer.
- the active layer pattern 4 is finally formed by a patterning process.
- Step 5 as shown in Figure 2d, forming source 5 and drain 6;
- a source 5 and a drain 6 having a thickness of 50 to 400 nm are prepared by sputtering using a material such as molybdenum, aluminum, an aluminum-niobium alloy, or copper, and photolithography and etching are performed according to a desired pattern.
- the method provided by the embodiment of the present invention reduces the formation of the active layer 4 having C-axis crystal orientation characteristics by using indium gallium zinc oxide InGaO 3 (ZnO) m , m ⁇ 2 .
- the crystallization temperature of the indium gallium zinc oxide improves the stability of the formed active layer 4, and the active layer 4 made of InGaO 3 (ZnO) m has a good electron transporting effect.
- the display substrate In the production of the display substrate, in addition to the above-described steps of fabricating the thin film transistor, as needed, other structures, such as pixel electrodes, pixel defining layers, anodes, etc., which are provided for display in the display substrate, are not required, and the present invention is not specific to the display substrate.
- the structure is limited.
- the display substrate provided by the embodiment of the present invention may include a pixel electrode 7 connected to the drain electrode 6 through a via hole.
- the active layer to be formed may be divided into three or more layers, wherein the growth rate of the indium gallium zinc oxide InGaO 3 (ZnO) m of each layer may be gradually increased.
- the manner of the increase is increased, and the power of the corresponding deposition laser or sputtering apparatus or the like is also gradually changed to obtain the desired active layer.
- the method for fabricating the thin film transistor of the embodiment of the present invention changes the zinc content of the existing target component by using an active layer formed by indium gallium zinc oxide InGaO 3 (ZnO) m having C-axis crystal orientation characteristics.
- the crystallization temperature of the indium gallium zinc oxide is lowered, and the stability of the bias test of the thin film transistor is improved.
- the etch rate of the indium gallium zinc oxide sample after crystallization in the source and drain etching liquid is slow. Several times, precise control of the etching can be achieved.
- the characteristics of the active layer material enable the thin film transistor to adopt a back channel etch type structure, which reduces the fabrication process of the etch barrier layer separately, can simplify the fabrication process of the oxide thin film transistor, and save the manufacturing cost.
- the active layer made of InGaO 3 (ZnO) m has a good electron migration effect and improves the quality of the produced active layer.
- an embodiment of the present invention provides a thin film transistor including an active layer 4 disposed on a substrate 1, wherein the active layer 4 is indium gallium zinc oxide InGaO 3 (ZnO) m A film layer having C-axis crystal orientation characteristics, wherein m ⁇ 2 is formed.
- the indium gallium zinc oxide of the embodiment of the present invention is InGaO 3 (ZnO) m , m ⁇ 2, and therefore, the indium gallium zinc oxide forming the active layer 4 can be made of materials of different compositions; for example, the above InGaO 3 (ZnO) m may be any of InGaZn 2 O 5 , InGaZn 3 O 6 , InGaZn 4 O 7 , InGaZn 5 O 8 or InGaZn 6 O 9 . These materials have a change in the content of zinc in the composition of the target in the general art, and finally lower the crystallization temperature of the oxide active layer.
- the active layer 4 made of InGaO 3 (ZnO) m has a good electron transporting effect and improves the quality of the active layer 4.
- the etched InGaO 3 (ZnO) m sample is etched in the source and drain etchants.
- the etch rate is several times slower and precise control of the etch can be achieved.
- the indium gallium zinc oxide provided by the embodiment of the present invention is not limited to the ones listed in the above specific examples, and any indium gallium zinc oxide satisfying InGaO 3 (ZnO) m and m ⁇ 2 can be applied to the present invention. In the examples.
- the structure of the thin film transistor provided by the embodiment of the present invention further includes a gate electrode 2, and a gate insulating layer 3 disposed between the gate electrode 2 and the active layer 4.
- the structure of the thin film transistor provided in this embodiment is: a gate electrode 2, a gate insulating layer 3 disposed above the gate electrode 2, and an active layer 4 disposed above the gate insulating layer 3, respectively, and the active layer 4
- the source 5 and the drain 6 are connected, wherein the source 5, the drain 6, and the active layer 4 form a back channel etch type structure.
- the back channel etch type structure omits the arrangement of the etch barrier layer on the active layer, and the thin film transistor has a simple structure and a simple manufacturing process, low fabrication cost, and high production efficiency.
- the active layer 4 formed of indium gallium zinc oxide InGaO 3 (ZnO) m by using the active layer 4 formed of indium gallium zinc oxide InGaO 3 (ZnO) m , the content of zinc in the existing target is changed, and the crystallization temperature of the indium gallium zinc oxide is lowered, thereby improving The stability of the formed active layer 4 is achieved. And the active layer 4 made of InGaO 3 (ZnO) m has a good electron migration effect and improves the quality of the active layer 4.
- the etched InGaO 3 (ZnO) m sample is etched in the source and drain etchants. The etch rate is several times slower and precise control of the etch can be achieved.
- the back channel etch type structure thin film transistor requires the etching solution to have different etching selectivity ratios to the active layer and the source and drain layers, otherwise the channel may be greatly damaged during the patterning of the source and drain layers. Even the channel is etched away.
- the in-crystalized InGaO 3 (ZnO) m is less affected by the source and drain etching liquids than the amorphous indium zinc oxide, and the physical properties enable the back channel to be engraved.
- Etched oxide thin film transistor structure Compared with the etch barrier type thin film transistor structure, the etch stop layer can be saved in a separate patterning process, which can simplify the fabrication process of the oxide thin film transistor and save the manufacturing cost.
- the embodiment of the invention further provides a display substrate comprising a substrate 1 and the thin film transistor of any one of the substrates 1 disposed on the substrate 1.
- the display substrate may further include other structures, such as a pixel electrode, a pixel defining layer, an anode, and the like, which are provided for display, and the present invention does not limit the specific structure of the display substrate.
- the display substrate provided by the embodiment of the present invention may include a pixel electrode 7, and the pixel electrode 7 passes through a via and a drain. The pole 6 is connected.
- the display substrate in the embodiment of the present invention has a thin film transistor which changes the content of zinc in the existing target by using an active layer formed by indium gallium zinc oxide InGaO 3 (ZnO) m and having C-axis crystal orientation characteristics.
- the crystallization temperature of the indium gallium zinc oxide is lowered, and the stability of the bias voltage test of the thin film transistor is improved.
- the etch rate of the indium gallium zinc oxide sample after crystallization in the source and drain etching liquid is slow. Several times to achieve precise control of the etch.
- the characteristics of the material enable the thin film transistor to adopt a back channel etch type structure, which reduces the fabrication process of the etch barrier layer.
- the active layer made of InGaO 3 (ZnO) m has a good electron migration effect, improves the quality of the active layer produced, and further improves the quality of the display device.
- Embodiments of the present invention also provide a display device including the display substrate.
- the active layer 4 having C-axis crystal orientation characteristics formed by indium gallium zinc oxide InGaO 3 (ZnO) m , the crystallization temperature of the indium gallium zinc oxide is lowered, thereby improving the formation.
- the active layer 4 made of InGaO 3 (ZnO) m has a good electron migration effect, improves the quality of the active layer 4 produced, and further improves the quality of the display device.
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Abstract
Description
Claims (22)
- 一种薄膜晶体管的制作方法,包括:在衬底上采用铟镓锌氧化物InGaO3(ZnO)m形成具有C轴结晶取向特性的有源层,其中m≥2。
- 如权利要求1所述的薄膜晶体管的制作方法,其中所述有源层通过在所述衬底上至少两次沉积铟镓锌氧化物层而形成。
- 如权利要求1或2所述的薄膜晶体管的制作方法,其中,在采用铟镓锌氧化物InGaO3(ZnO)m形成具有C轴结晶取向特性的有源层过程中,通过物理气相沉积方式以第一功率和第一速率沉积具有C轴结晶取向特性的第一铟镓锌氧化物层;以及在形成的第一层铟镓锌氧化物层上通过物理气相沉积方式以第二功率和第二速率沉积第二铟镓锌氧化物层,所述第一铟镓锌氧化物层和第二铟镓锌氧化物层形成所述有源层;所述第一功率小于所述第二功率,所述第一速率小于所述第二速率。
- 如权利要求1-3任一项所述的薄膜晶体管的制作方法,其中所述形成第一铟镓锌氧化物层的温度条件和第二铟镓锌氧化物层的温度条件均为200℃~400℃。
- 如权利要求1-4任一项所述的薄膜晶体管的制作方法,其中采用Nd:YAG激光器在真空条件下沉积形成所述有源层,以及所述激光器的输出波长为193~1064nm,重复频率为大于1Hz,脉宽小于10ns。
- 如权利要求1-4任一项所述的薄膜晶体管的制作方法,其中采用Nd:YAG激光器在真空条件下沉积形成所述有源层,以及所述激光器的输出波长为1064nm,重复频率为10Hz,脉宽为10ns。
- 如权利要求5或6所述的薄膜晶体管的制作方法,其中,所述第一功率为激光器聚焦前功率为0.2~0.4W。
- 如权利要求5或6所述的薄膜晶体管的制作方法,其中,所述第一功率为激光器聚焦前功率为0.3W。
- 如权利要求3-8任一项所述的薄膜晶体管的制作方法,其中沉积所述第一铟镓锌氧化物层的时间为10~30s,形成的所述第一铟镓锌氧化物层的厚度大于0,小于等于10nm。
- 如权利要求9所述的薄膜晶体管的制作方法,其中所述第二功率为激光器聚焦前功率为0.5~1.0W。
- 如权利要求9所述的薄膜晶体管的制作方法,其中所述第二功率为激光器聚焦前功率为0.5W。
- 如权利要求3或4所述的薄膜晶体管的制作方法,其中所述第一铟镓锌氧化物层和所述第二铟镓锌氧化物层在真空条件下以溅射方式形成。
- 如权利要求12所述的薄膜晶体管的制作方法,其中,在真空条件下进行溅射时,向真空室通入氧气和氩气混合气。
- 如权利要求13所述的薄膜晶体管的制作方法,其中所述氧气和氩气比例为O:Ar=1:4。
- 如权利要求14所述的薄膜晶体管的制作方法,其中,所述第一铟镓锌氧化物层以2~3KW的所述第一功率,O2流量为25标况毫升/分的条件,一次扫描形成;以及所述第二层铟镓锌氧化物层以4~6KW的所述第二功率,O2流量为25标 况毫升/分的条件,一次扫描形成。
- 如权利要求14所述的薄膜晶体管的制作方法,其中,所述第一铟镓锌氧化物层以3KW的所述第一功率,O2流量为25标况毫升/分的条件,一次扫描形成;以及所述第二层铟镓锌氧化物层以4.5KW的所述第二功率,O2流量为25标况毫升/分的条件,一次扫描形成。
- 如权利要求1-16任一项所述的薄膜晶体管的制作方法,其中所述铟稼锌氧化物InGaO3(ZnO)m包含:InGaZn2O5、InGaZn3O6、InGaZn4O7、InGaZn5O8或InGaZn6O9中的任一种。
- 如权利要求2所述的薄膜晶体管的制作方法,其中所述有源层分成三层在所述衬底上沉积形成,其中每一层的铟镓锌氧化物InGaO3(ZnO)m生长速度以逐渐递增的方式增大。
- 一种薄膜晶体管,包括设置于衬底上的有源层,其中所述有源层包括具有C轴结晶取向特性的铟稼锌氧化物,所述铟稼锌氧化物为InGaO3(ZnO)m,其中m≥2。
- 如权利要求19所述的薄膜晶体管,其中所述铟稼锌氧化物InGaO3(ZnO)m包含:InGaZn2O5、InGaZn3O6、InGaZn4O7、InGaZn5O8或InGaZn6O9中的任一种。
- 一种显示基板,包括衬底以及设置在所述衬底上的如权利要求19或20所述的薄膜晶体管。
- 一种显示装置,包括如权利要求21所述的显示基板。
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