WO2015129623A1 - 基板処理装置および基板処理方法 - Google Patents
基板処理装置および基板処理方法 Download PDFInfo
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- WO2015129623A1 WO2015129623A1 PCT/JP2015/055036 JP2015055036W WO2015129623A1 WO 2015129623 A1 WO2015129623 A1 WO 2015129623A1 JP 2015055036 W JP2015055036 W JP 2015055036W WO 2015129623 A1 WO2015129623 A1 WO 2015129623A1
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- Prior art keywords
- substrate
- lid
- chamber
- shielding plate
- internal space
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- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 14
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Images
Classifications
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- H—ELECTRICITY
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/67005—Apparatus not specifically provided for elsewhere
- H01L21/67011—Apparatus for manufacture or treatment
- H01L21/67155—Apparatus for manufacturing or treating in a plurality of work-stations
- H01L21/6719—Apparatus for manufacturing or treating in a plurality of work-stations characterized by the construction of the processing chambers, e.g. modular processing chambers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/67005—Apparatus not specifically provided for elsewhere
- H01L21/67011—Apparatus for manufacture or treatment
- H01L21/67017—Apparatus for fluid treatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/002—Processes for applying liquids or other fluent materials the substrate being rotated
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/04—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to gases
- B05D3/0466—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to gases the gas being a non-reacting gas
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02296—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer
- H01L21/02299—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer pre-treatment
- H01L21/02307—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer pre-treatment treatment by exposure to a liquid
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02296—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer
- H01L21/02318—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer post-treatment
- H01L21/02343—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer post-treatment treatment by exposure to a liquid
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3105—After-treatment
- H01L21/311—Etching the insulating layers by chemical or physical means
- H01L21/31105—Etching inorganic layers
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
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- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/67005—Apparatus not specifically provided for elsewhere
- H01L21/67011—Apparatus for manufacture or treatment
- H01L21/67017—Apparatus for fluid treatment
- H01L21/67023—Apparatus for fluid treatment for general liquid treatment, e.g. etching followed by cleaning
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- H—ELECTRICITY
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
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- H01L21/67005—Apparatus not specifically provided for elsewhere
- H01L21/67011—Apparatus for manufacture or treatment
- H01L21/67017—Apparatus for fluid treatment
- H01L21/67063—Apparatus for fluid treatment for etching
- H01L21/67075—Apparatus for fluid treatment for etching for wet etching
- H01L21/6708—Apparatus for fluid treatment for etching for wet etching using mainly spraying means, e.g. nozzles
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- H01L21/677—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for conveying, e.g. between different workstations
- H01L21/67703—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for conveying, e.g. between different workstations between different workstations
- H01L21/67718—Changing orientation of the substrate, e.g. from a horizontal position to a vertical position
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- H—ELECTRICITY
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- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/683—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
- H01L21/687—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches
- H01L21/68714—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches the wafers being placed on a susceptor, stage or support
- H01L21/68742—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches the wafers being placed on a susceptor, stage or support characterised by a lifting arrangement, e.g. lift pins
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/683—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
- H01L21/687—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches
- H01L21/68714—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches the wafers being placed on a susceptor, stage or support
- H01L21/68764—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using mechanical means, e.g. chucks, clamps or pinches the wafers being placed on a susceptor, stage or support characterised by a movable susceptor, stage or support, others than those only rotating on their own vertical axis, e.g. susceptors on a rotating caroussel
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- H—ELECTRICITY
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02041—Cleaning
- H01L21/02057—Cleaning during device manufacture
- H01L21/0206—Cleaning during device manufacture during, before or after processing of insulating layers
- H01L21/02063—Cleaning during device manufacture during, before or after processing of insulating layers the processing being the formation of vias or contact holes
Definitions
- the present invention relates to a substrate processing apparatus and a substrate processing method for processing a substrate.
- substrate In the manufacturing process of a semiconductor substrate (hereinafter simply referred to as “substrate”), various types of processing are performed on the substrate using various types of substrate processing apparatuses. For example, by supplying a chemical solution onto a substrate having a resist pattern formed on the surface, a process such as etching is performed on the surface of the substrate. Further, after the etching process is finished, a removal liquid is supplied onto the substrate to remove the resist, or a cleaning liquid is supplied onto the substrate to perform cleaning.
- oxygen may adversely affect the substrate.
- oxygen may be dissolved in a chemical solution used for processing, and the chemical solution may come into contact with the surface of the substrate, which may adversely affect the surface of the substrate.
- the metal film may be oxidized during the treatment. It is required to prevent such oxidation of the metal film as much as possible.
- a shielding portion is provided to face the substrate held by the substrate holding mechanism.
- the shielding portion includes a substrate facing surface that faces the upper surface of the substrate, and a peripheral wall portion that protrudes from the periphery of the substrate facing surface toward the substrate holding mechanism.
- a chemical solution obtained by mixing an inert gas-dissolved water with a reduced oxygen concentration and a chemical solution stock solution is supplied onto the substrate.
- by providing a blocking unit it is possible to block the atmosphere on the upper surface of the substrate from the atmosphere outside the blocking unit and suppress an increase in oxygen concentration in the atmosphere on the substrate. When the oxygen concentration on the substrate is reduced, oxidation of the metal film provided on the upper surface of the substrate is suppressed.
- the inside of the blocking part is not completely isolated from the outside, there is a limit in reducing the oxygen concentration of the atmosphere on the substrate.
- a substrate holding unit and a processing liquid supply unit are provided inside the chamber (processing chamber), the chamber is sealed after the substrate is carried in, and an inert gas or the like is supplied to the internal space to make it in a low oxygen state. It is done. However, a certain amount of time is required to make the internal space of the chamber sufficiently hypoxic.
- the present invention is directed to a substrate processing apparatus and a substrate processing method for processing a substrate, and has an object of quickly setting a desired gas atmosphere in a chamber.
- a substrate processing apparatus includes a substrate holding unit that holds a substrate in a horizontal state, a lower opening, a chamber lid that forms a lid internal space above the lower opening, and the lower opening and the vertical direction.
- a chamber body having an upper opening opposite to the chamber body and forming a body internal space, and the chamber lid portion is moved relative to the chamber body in the vertical direction, and the upper opening is covered by the chamber lid portion.
- a chamber opening / closing mechanism that forms a chamber that accommodates the substrate holding unit therein, a processing liquid supply unit that supplies a processing liquid to the upper surface of the substrate, and the upper surface of the substrate disposed in the lid internal space
- a shielding plate capable of closing the lower opening a shielding plate moving mechanism for moving the shielding plate relative to the chamber lid portion in the lid internal space, and the shielding plate.
- Plate is provided with said cover inner space gas supply unit for supplying a gas into a state where the superposed on the lower opening of the chamber lid. According to the substrate processing apparatus, the inside of the chamber can be quickly brought into a desired gas atmosphere.
- the substrate further includes a substrate moving mechanism that moves the substrate together with the substrate holding portion relative to the chamber in the up-down direction, and the shielding plate includes the chamber lid portion.
- the substrate In a state of being separated from the lower opening, the substrate is relatively moved between the lid inner space and the main body inner space through the lower opening and the upper opening in the chamber by the substrate moving mechanism. To do.
- the chamber lid portion has a cup-shaped lid body portion that is turned upside down, and extends radially inward from the lower end portion of the lid body portion, and the lower opening at the center portion. And the lower surface of the shielding plate overlaid on the lower opening is in contact with the upper surface of the lid bottom surface over the entire periphery of the lower opening. Close the opening.
- the upper surface of the bottom surface portion of the lid is directed downward as it goes outward in the radial direction, and the internal space of the lid is connected to a connection portion between the bottom surface portion of the chamber lid portion and the lid body portion.
- a discharge port for discharging the liquid inside is provided.
- a gas outlet is provided in the center of the lower surface of the shielding plate, and the lower surface of the shielding plate and the substrate are interposed by the gas supply unit via the gas outlet.
- the gas is supplied to a space between the upper surface.
- the apparatus further comprises a substrate rotating mechanism that rotates the substrate together with the substrate holding part about the central axis facing the up-down direction, and the chamber body is located below the chamber lid part. And a cup portion which is located over the entire circumference of the substrate holding portion and which receives the processing liquid scattered from the rotating substrate.
- the chamber body is located over the entire circumference on the radially outer side of the cup portion, and forms an outer cylinder portion that is in contact with the chamber lid portion, and an upper end of the outer cylinder portion. And an outer cylinder connecting portion that closes a gap between the cup portion and the cup portion.
- the apparatus further includes a substrate rotation mechanism that rotates the substrate together with the substrate holding portion about the central axis facing the vertical direction, and the substrate rotates in the inner space of the lid. , The shielding plate rotates around the central axis at a position close to the substrate.
- the substrate processing method includes a substrate holding unit that holds a substrate in a horizontal state, a lower opening, a chamber lid that forms a lid internal space above the lower opening, and the lower opening and the vertical direction.
- a substrate processing apparatus comprising: a chamber main body having an upper opening facing the substrate and forming a main body inner space; and a shielding plate disposed in the lid inner space, facing the upper surface of the substrate and capable of closing the lower opening.
- a substrate processing method for processing the substrate wherein: a) supplying a gas to the inner space of the lid in a state where the shielding plate is overlaid on the lower opening of the chamber lid portion; b) A step of holding the substrate by the substrate holding portion in a state where the chamber lid portion is separated from the chamber main body, and c) moving the chamber lid portion relative to the chamber main body in the vertical direction, Covering the opening with the chamber lid portion to form a chamber for accommodating the substrate and the substrate holding portion therein; d) raising the shielding plate relative to the chamber lid portion and Separating the shielding plate from the lower opening, e) supplying the gas into the chamber, and f) supplying a processing liquid to the upper surface of the substrate.
- the inside of the chamber can be quickly brought into a desired gas atmosphere.
- FIG. 1 is a cross-sectional view showing a configuration of a substrate processing apparatus 1 according to an embodiment of the present invention.
- the substrate processing apparatus 1 is a single-wafer type apparatus that supplies a processing liquid to a substantially disk-shaped semiconductor substrate 9 (hereinafter simply referred to as “substrate 9”) to process the substrates 9 one by one.
- substrate 9 substantially disk-shaped semiconductor substrate 9
- FIG. 1 the provision of parallel oblique lines is omitted in the cross section of a part of the configuration of the substrate processing apparatus 1 (the same applies to other cross sectional views).
- the substrate processing apparatus 1 includes a chamber 21, a substrate holding unit 31, a substrate rotating mechanism 35, a first moving mechanism 41, a second moving mechanism 42, a third moving mechanism 43, a shielding plate 51, and a shielding plate.
- a rotation mechanism 55 and a housing 11 are provided.
- the housing 11 accommodates the chamber 21, the substrate holding part 31, the shielding plate 51, and the like.
- the chamber 21 has a substantially cylindrical shape with a lid and a bottom with the central axis J1 facing in the vertical direction as the center.
- the chamber 21 includes a chamber main body 22 and a chamber lid portion 23.
- the chamber body 22 and the chamber lid portion 23 face each other in the vertical direction. In the state shown in FIG. 1, the chamber main body 22 and the chamber lid portion 23 are separated from each other in the vertical direction.
- the chamber main body 22 has a substantially cylindrical shape with a bottom centered on the central axis J1, and forms a main body internal space 221.
- the chamber lid portion 23 has a substantially cylindrical shape with a lid centered on the central axis J1, and forms a lid internal space 231.
- the outer diameter of the chamber body 22 and the outer diameter of the chamber lid 23 are approximately equal.
- the chamber body 22 has a substantially circular upper opening 222.
- the chamber lid 23 has a substantially circular lower opening 232.
- the upper opening 222 of the chamber body 22 faces the lower opening 232 of the chamber lid 23 in the vertical direction.
- the diameter of the upper opening 222 of the chamber body 22 and the diameter of the lower opening 232 of the chamber lid 23 are approximately equal.
- the size of the inner space 231 of the chamber lid 23 in the radial direction centered on the central axis J1 is larger than the size (that is, the diameter) of the lower opening 232 in the radial direction. Details of the structure of the chamber body 22 and the chamber lid 23 will be described later.
- the substrate holding part 31 has a substantially disc shape centered on the central axis J1.
- the substrate holding unit 31 is disposed below the substrate 9 and holds the outer edge portion of the substrate 9 in a horizontal state. In the state shown in FIG. 1, the substrate holding portion 31 is located between the chamber body 22 and the chamber lid portion 23 in the vertical direction.
- the diameter of the substrate holding part 31 is larger than the diameter of the substrate 9.
- the diameter of the substrate holding part 31 is smaller than the diameter of the upper opening 222 of the chamber body 22 and the diameter of the lower opening 232 of the chamber lid part 23.
- the upper opening 222 of the chamber body 22 and the lower opening 232 of the chamber lid 23 face the substrate 9 and the substrate holding unit 31 in the vertical direction.
- the substrate rotation mechanism 35 is disposed below the substrate holding unit 31. The substrate rotation mechanism 35 rotates the substrate 9 together with the substrate holder 31 around the central axis J1.
- the shielding plate 51 has a substantially disc shape centered on the central axis J1.
- the shielding plate 51 is disposed in a lid internal space 231 that is an internal space of the chamber lid portion 23.
- the size (that is, the diameter) of the shielding plate 51 in the radial direction is preferably larger than the diameter of the lower opening 232 of the chamber lid 23.
- the shielding plate 51 can close the lower opening 232 of the chamber lid 23.
- the shielding plate 51 faces the upper surface 91 of the substrate 9 held by the substrate holding part 31 in the vertical direction via the lower opening 232.
- the shielding plate rotating mechanism 55 is disposed on the upper side of the shielding plate 51.
- the shielding plate rotation mechanism 55 is, for example, a hollow shaft motor. By the shielding plate rotating mechanism 55, the shielding plate 51 rotates around the central axis J1 in the lid internal space 231 of the chamber lid portion 23. The rotation of the shielding plate 51 by the shielding plate rotation mechanism 55 is performed independently of the rotation of the substrate 9 by the substrate rotation mechanism 35.
- the rotating shaft 551 of the shielding plate rotating mechanism 55 is connected to the shielding plate 51 through a through hole provided in the upper portion of the housing 11 and a through hole provided in the upper portion of the chamber lid portion 23.
- a part around the through hole of the housing 11 and a part around the through hole of the chamber lid 23 are connected by a substantially cylindrical expansion / contraction member 111 (for example, a bellows) that can expand and contract in the vertical direction.
- the rotary shaft 551 is provided with a substantially disc-shaped flange portion 553, and a substantially cylindrical shape in which an outer peripheral portion of the flange portion 553 and a portion around the through hole of the housing 11 can expand and contract in the vertical direction.
- an elastic member 552 for example, bellows.
- the space inside the housing 11 and the space outside the housing 11 are isolated by the flange portion 553 and the elastic member 552.
- the expansion / contraction member 111 separates the space inside the chamber lid 23 from the space inside the housing 11 and outside the chamber lid 23.
- FIG. 2 is a block diagram showing the gas-liquid supply unit 18 and the gas-liquid discharge unit 19 provided in the substrate processing apparatus 1.
- the gas-liquid supply unit 18 includes a processing liquid supply unit 811 and a gas supply unit 812.
- the processing liquid supply unit 811 includes an upper central nozzle 181, a chemical solution supply unit 813, and a pure water supply unit 814.
- the chemical solution supply unit 813 and the pure water supply unit 814 are connected to the upper central nozzle 181 through valves.
- the gas supply unit 812 includes an upper center nozzle 181, a plurality of lid nozzles 182, and an inert gas supply unit 816.
- the inert gas supply unit 816 is connected to the upper central nozzle 181 through a valve.
- the inert gas supply unit 816 is also connected to a plurality of lid nozzles 182 via valves.
- the plurality of lid nozzles 182 are provided on the upper portion of the chamber lid portion 23.
- the plurality of lid nozzles 182 are arranged circumferentially around the central axis J1.
- a first gas ejection port 184 is provided at the lower end of each lid nozzle 182.
- the inert gas delivered from the inert gas supply unit 816 is supplied to the lid internal space 231 from a plurality of first gas outlets 184 provided in the upper part of the chamber lid 23.
- the upper central nozzle 181 is provided in the rotating shaft 551 of the shielding plate rotating mechanism 55.
- the central portion of the lower end of the upper central nozzle 181 has a processing liquid (that is, a chemical solution from the chemical solution supply unit 813 and a pure solution from the pure water supply unit 814 toward the upper surface 91 of the substrate 9.
- a treatment liquid discharge port 183 for supplying water is provided.
- a substantially annular second gas ejection port 185 is provided around the processing liquid ejection port 183 at the lower end of the upper central nozzle 181.
- the inert gas delivered from the inert gas supply unit 816 is a space below the shielding plate 51 from the second gas ejection port 185 (that is, a space between the lower surface 512 of the shielding plate 51 and the upper surface 91 of the substrate 9).
- Supplied towards The lower end of the upper central nozzle 181 is disposed at approximately the same position as the lower surface 512 of the shielding plate 51 in the vertical direction. That is, the treatment liquid discharge port 183 and the second gas jet port 185 of the upper central nozzle 181 are provided in the central portion of the lower surface 512 of the shielding plate 51.
- the gas-liquid discharge unit 19 includes a main body discharge port 226a, a lid part discharge port 237, a gas-liquid separation unit 193, a main body exhaust unit 194, a chemical solution recovery unit 195, a liquid discharge unit 196, and a gas-liquid separation unit 197. And a lid exhaust part 198 and a drainage part 199.
- the main body discharge port 226 a is provided in the chamber main body 22 and is connected to the gas-liquid separator 193.
- the gas-liquid separation unit 193 is connected to the main body exhaust unit 194, the chemical solution recovery unit 195, and the drainage unit 196 through valves.
- the lid discharge port 237 is provided in the chamber lid 23 and is connected to the gas-liquid separator 197.
- the gas-liquid separation unit 197 is connected to the lid exhaust unit 198 and the drainage unit 199 via valves. Each configuration of the gas-liquid supply unit 18 and the gas-liquid discharge unit 19 is controlled by the control unit 10.
- the first moving mechanism 41, the second moving mechanism 42, the third moving mechanism 43, the substrate rotating mechanism 35, and the shielding plate rotating mechanism 55 (see FIG. 1) are also controlled by the control unit 10.
- the chemical solution supplied onto the substrate 9 from the chemical solution supply unit 813 via the upper central nozzle 181 is, for example, a polymer removing solution or an etching solution such as hydrofluoric acid or an aqueous tetramethylammonium hydroxide solution.
- the pure water supply unit 814 supplies pure water (DIW: deionized water) to the substrate 9 through the upper central nozzle 181.
- the processing liquid supply unit 811 may include another supply unit that supplies a processing liquid other than the chemical liquid and the pure water.
- the gas supplied from the inert gas supply unit 816 is, for example, nitrogen (N 2 ) gas.
- the gas supply unit 812 may include another supply unit that supplies an inert gas other than the nitrogen gas or a gas other than the inert gas.
- the chamber body 22 includes an outer cylinder part 223, an outer cylinder connection part 224, a cup part 225, and a main body bottom part 226.
- the cup part 225 has a substantially cylindrical shape centered on the central axis J1.
- the cup portion 225 is located over the entire circumference on the radially outer side of the substrate rotation mechanism 35 below the chamber lid portion 23.
- the cup part 225 includes a substantially cylindrical cup side wall part 227a centering on the central axis J1, and a substantially annular plate-shaped cup canopy part 227b extending radially inward from the upper end of the cup side wall part 227a.
- the central opening of the cup canopy 227b is the upper opening 222 described above.
- the outer cylinder part 223 has a substantially cylindrical shape centered on the central axis J1.
- the outer cylinder part 223 is located over the entire circumference on the radially outer side of the cup part 225.
- the outer cylinder part 223 is, for example, a bellows in which a plurality of circumferential fold lines and a plurality of circumferential valley fold lines are alternately arranged in the vertical direction.
- the lower end portion of the outer cylinder portion 223 is connected to the upper end portion of the side wall portion of the main body bottom portion 226 over the entire circumference.
- the main body discharge port 226a is provided on the bottom surface of the main body bottom 226.
- the main body discharge port 226 a is disposed below the substrate 9, the substrate holding part 31, and the cup part 225 in the main body internal space 221 that is an internal space of the chamber main body 22.
- the liquid and gas in the chamber body 22 are discharged out of the chamber body 22 (that is, outside the chamber 21) through the body discharge port 226a.
- a plurality of main body discharge ports 226a arranged in the circumferential direction may be provided in the circumferential direction.
- the outer cylinder connecting part 224 has a substantially annular plate shape centered on the central axis J1.
- the outer cylinder connection part 224 connects the upper end part of the outer cylinder part 223 and the outer edge part of the cup part 225.
- the outer cylinder connection part 224 connects the upper end part of the outer cylinder part 223 and the outer edge part of the cup canopy part 227b.
- the outer cylinder connection portion 224 closes the gap between the upper end portion of the outer cylinder portion 223 and the cup portion 225.
- the chamber lid portion 23 includes a lid main body portion 233 and a lid bottom surface portion 234.
- the lid body 233 has a substantially cylindrical shape with a lid centered on the central axis J1. In other words, the lid main body 233 has a cup shape that is upside down.
- the through hole in the central portion of the lid main body portion 233 that is, the through hole in the upper portion of the chamber lid portion 23 is formed by the elastic members 111 and 552, a part of the upper portion of the housing 11, and the flange portion 553. Blocked. These members that close the through hole may be regarded as a part of the lid main body 233.
- a cylindrical space formed by the elastic members 111 and 552 is a part of the lid internal space 231.
- the lid bottom surface portion 234 has a substantially annular plate shape centered on the central axis J1, and the above-described lower opening 232 is provided in the central portion.
- the lid bottom surface portion 234 extends radially inward from the lower end portion of the lid main body portion 233.
- the upper surface 235 and the lower surface 236 of the lid bottom surface part 234 are inclined surfaces that go downward as they go radially outward.
- the lid discharge port 237 described above is provided at a connection portion between the lid bottom surface portion 234 and the lid main body portion 233 of the chamber lid portion 23. The liquid and gas in the lid internal space 231 are discharged via the lid discharge port 237.
- the shielding plate 51 is overlaid on the lower opening 232 of the chamber lid 23.
- the lower surface 512 of the shielding plate 51 is in contact with the upper surface 235 of the lid bottom surface portion 234 over the entire circumference around the lower opening 232.
- the outer peripheral portion of the lower surface 512 of the shielding plate 51 is in contact with the entire surface of the upper surface 235 of the lid bottom surface portion 234 in the vicinity of the lower opening 232.
- the lower opening 232 of the chamber lid 23 is closed by the shielding plate 51, and the lid internal space 231 above the lower opening 232 becomes a closed space.
- the contact portion between the shielding plate 51 and the lid bottom surface portion 234 does not have a completely airtight structure, and thus the lid internal space 231 is not completely blocked from the external space.
- the part may be an airtight structure including a seal member or the like, and the lid internal space 231 may be a sealed space isolated from the external space.
- the first moving mechanism 41 is disposed, for example, on the upper side of the housing 11.
- the first moving mechanism 41 moves the shielding plate 51 in the vertical direction together with the shielding plate rotating mechanism 55.
- the shielding plate 51 is moved in the vertical direction in the lid internal space 231 of the chamber lid 23 by the first moving mechanism 41.
- the first moving mechanism 41 includes, for example, a motor and a ball screw (the same applies to the second moving mechanism 42 and the third moving mechanism 43).
- the second moving mechanism 42 is disposed on the side of the chamber body 22 and moves the chamber lid 23 in the vertical direction. Specifically, the chamber lid portion 23 is moved between the “upper position” shown in FIG. 1 and the “lower position” shown in FIG.
- the lower opening 232 is positioned above the substrate 9 on the substrate holding unit 31 in a state where the chamber lid 23 is disposed at the upper position, and the lower opening 232 is disposed in a state where the chamber lid 23 is disposed at the lower position. Is located below the substrate 9 on the substrate holding portion 31.
- the shielding plate 51 is also moved in the vertical direction by the first moving mechanism 41, and the shielding plate 51 is moved relative to the chamber lid 23.
- the relative position in the vertical direction is changed. That is, the first moving mechanism 41 and the second moving mechanism 42 are shielding plate moving mechanisms that move the shielding plate 51 in the vertical direction relative to the chamber lid portion 23 in the lid internal space 231 of the chamber lid portion 23. is there.
- the third moving mechanism 43 is disposed on the side of the chamber main body 22 and moves a part of the chamber main body 22 in the vertical direction. Specifically, the cup portion 225 of the chamber body 22 is moved by the third moving mechanism 43 between the “lower position” shown in FIGS. 1 and 3 and the “upper position” shown in FIG. Moving.
- the upper opening 222 is located below the substrate 9 on the substrate holding portion 31, and when the cup portion 225 is disposed at the upper position, the upper opening 222 is the substrate. It is located above the substrate 9 on the holding unit 31.
- the outer cylinder part 223 expands and contracts in the vertical direction.
- the relative position in the vertical direction of the shielding plate 51 with respect to the chamber lid portion 23 is changed even when the cup portion 225 of the chamber body 22 moves from the lower position to the upper position above the lower position. Is done.
- the main body bottom 226 and the substrate holder 31 of the chamber main body 22 do not move in the vertical direction.
- the lower opening 232 of the chamber lid portion 23 is formed in the upper opening 222 of the chamber body 22.
- the upper opening 222 is covered with the chamber lid 23 while facing each other.
- the chamber 21 having a sealed space that is, a space including the lid internal space 231 and the main body internal space 221 and hereinafter referred to as “chamber space” is formed.
- the connecting portion between the lid main body portion 233 and the lid bottom surface portion 234 comes into contact with the outer cylinder portion 223 of the chamber main body 22 to form the chamber 21.
- the upper opening 222 of the chamber body 22 is similarly formed in the chamber lid portion 23.
- the chamber 21 is formed by being covered with.
- the substrate 9 and the substrate holder 31 are accommodated in the chamber 21 (that is, the chamber space). That is, the second moving mechanism 42 and the third moving mechanism 43 move the chamber lid portion 23 in the vertical direction relative to the chamber body 22 and cover the upper opening 222 of the chamber body 22 with the chamber lid portion 23.
- the chamber lid portion 23 is located at the upper position, and the cup portion 225 of the chamber body 22 is located at the lower position.
- the chamber 21 is in an open state.
- the shielding plate 51 is superimposed on the lower opening 232 of the chamber lid portion 23 in plan view so that the lower surface 512 of the shielding plate 51 is in contact with the upper surface 235 of the lid bottom surface portion 234.
- the lower opening 232 is closed and the lid internal space 231 becomes a closed space.
- the gas supply unit 812 see FIG.
- step S11 2) supplies nitrogen gas to the lid internal space 231 via the plurality of first gas ejection ports 184. Further, the gas in the lid internal space 231 is discharged from the lid discharge port 237 to the outside of the chamber lid 23. As a result, the lid internal space 231 is filled with nitrogen gas (step S11).
- the lower opening 232 of the chamber lid 23 does not necessarily need to be airtightly closed by the shielding plate 51. If the shielding plate 51 overlaps the lower opening 232, the shielding plate 51 and It may be a closed form in which a slight gap exists between the lid bottom surface portion 234 and the lid bottom surface portion 234. Even in such a closed form, the amount of nitrogen gas supplied from the gas supply unit 812 to the lid internal space 231 is controlled, the amount of nitrogen gas flowing into the lid internal space 231, the gap, and the lid part discharge. By making the amount of gas flowing out from the port 237 approximately equal, the lid internal space 231 is filled with nitrogen gas.
- the oxygen concentration in the lid internal space 231 can be reduced to a low oxygen state necessary to the process.
- the substrate 9 is illustrated, but step S ⁇ b> 11 is performed before the substrate 9 is carried into the substrate processing apparatus 1.
- the substrate 9 is carried into the housing 11 from the loading / unloading port (not shown) provided in the housing 11 with the chamber lid 23 being separated from the chamber main body 22 as described above, and is held by the substrate holding portion 31.
- Step S12 the substrate 9 is held by the substrate holding unit 31 above the upper opening 222 of the chamber body 22.
- FIG. 6 is a cross-sectional view for explaining an example of the surface state of the substrate 9 processed by the substrate processing apparatus 1.
- a polymer residue that is, a residue after dry etching or ashing
- the metal pattern may be a single film of metal such as copper or tungsten, or may be a multilayer film in which a plurality of metal films are stacked.
- the multilayer film is, for example, a laminated film in which a barrier metal film for preventing diffusion is formed on the surface of a copper film.
- an interlayer insulating film 911 is formed on the upper surface 91 of the substrate 9.
- a lower wiring trench 912 is formed by dug down from the upper surface.
- a copper wiring 913 is embedded in the lower wiring groove 912.
- a low dielectric constant insulating film 915 as an example of a film to be processed is laminated via an etch stopper film 914.
- an upper wiring groove 916 is formed by digging from the upper surface.
- a via hole 917 reaching the surface of the copper wiring 913 from the bottom surface of the upper wiring groove 916 is formed in the low dielectric constant insulating film 915. Copper is buried in the upper wiring trench 916 and the via hole 917 in a lump.
- the upper wiring trench 916 and the via hole 917 are subjected to a dry etching process after a hard mask is formed on the low dielectric constant insulating film 915, and a portion exposed from the hard mask in the low dielectric constant insulating film 915 is removed. Is formed. After the formation of the upper wiring trench 916 and the via hole 917, an ashing process is performed, and the unnecessary hard mask is removed from the low dielectric constant insulating film 915.
- the reaction product including the components of the low dielectric constant insulating film 915 and the hard mask becomes a polymer residue, and the surface of the low dielectric constant insulating film 915 (the inner surfaces of the upper wiring trench 916 and the via hole 917) ) Etc.
- a process for removing the polymer residue from the surface of the low dielectric constant insulating film 915 is performed by supplying a polymer removing solution to the surface of the substrate 9.
- step S13 the shielding plate 51 rises relative to the chamber lid 23, and the shielding plate 51 is separated upward from the lower opening 232 of the chamber lid 23 in the chamber 21 (step S13).
- the substrate 9 held by the substrate holding portion 31 passes through the lower opening 232 of the chamber lid portion 23 and the lid inner space 231.
- the substrate 9 is located in the lid internal space 231 in the chamber space. Since the lid internal space 231 is filled with nitrogen gas as described above, by moving the substrate 9 to the lid internal space 231, a nitrogen gas atmosphere (that is, a low oxygen content) can be quickly generated around the substrate 9. Atmosphere).
- a nitrogen gas atmosphere that is, a low oxygen content
- the supply of nitrogen gas by the gas supply unit 812 is continued until a series of processing on the substrate 9 is completed after step S ⁇ b> 11.
- nitrogen gas is supplied to the lid internal space 231 from the first gas outlets 184 (see FIG. 2) of the plurality of lid nozzles 182 positioned above the shielding plate 51, so that the inside of the lid
- the air pressure in the space 231 becomes higher than the air pressure in the main body internal space 221.
- the lid internal space 231 is in a positive pressure state.
- the nitrogen gas in the lid internal space 231 flows out from the gap between the shielding plate 51 and the lid bottom surface portion 234 of the chamber lid portion 23 to the main body internal space 221 through the lower opening 232 and the upper opening 222. (In other words, it is sent from the lid internal space 231 to the main body internal space 221).
- the gas in the main body internal space 221 is discharged from the main body discharge port 226a to the outside of the chamber 21.
- the nitrogen gas from the gas supply unit 812 is also supplied and filled in the main body internal space 221.
- nitrogen gas is supplied into the chamber 21 by the gas supply unit 812 and is filled (step S15).
- step S15 the process of step S15 is referred to as “gas replacement process”.
- step S ⁇ b> 15 the nitrogen gas from the gas supply unit 812 is interposed between the lower surface 512 of the shielding plate 51 and the upper surface 91 of the substrate 9 through the second gas ejection port 185 (see FIG. 2) of the upper central nozzle 181. It is also supplied to the space. Thereby, the atmosphere of the space between the shielding plate 51 and the substrate 9 can be quickly replaced with a nitrogen gas atmosphere.
- nitrogen gas may be supplied from the second gas outlet 185 as necessary.
- the gas replacement process in step S15 can be performed more efficiently.
- the shielding plate 51, the chamber lid portion 23, and the cup portion 225 of the chamber main body 22 move upward.
- the chamber lid part 23 and the cup part 225 of the chamber main body 22 respectively move from the lower position shown in FIG. 3 to the upper position shown in FIG. In other words, the substrate 9 is lowered relative to the chamber 21 together with the substrate holding portion 31 by the second moving mechanism 42 and the third moving mechanism 43.
- the second moving mechanism 42 and the third moving mechanism 43 are substrate moving mechanisms that move the substrate 9 together with the substrate holding portion 31 relative to the chamber 21 in the vertical direction.
- the relative position of the shielding plate 51 with respect to the chamber lid 23 is not changed, and the state where the shielding plate 51 is spaced upward from the lower opening 232 of the chamber lid 23 is maintained.
- Step S16 the cup portion 225 is positioned over the entire circumference on the radially outer side of the substrate 9 and the substrate holding portion 31 below the chamber lid portion 23.
- the processing liquid is supplied onto the upper surface 91 of the rotating substrate 9 by the processing liquid supply unit 811 through the processing liquid discharge port 183 (see FIG. 2) of the upper central nozzle 181 (step S17).
- the processing liquid supplied to the central portion of the rotating substrate 9 moves radially outward on the upper surface 91 by centrifugal force and scatters from the outer edge of the substrate 9 to the cup portion 225.
- the processing liquid received by the cup unit 225 is discharged out of the chamber 21 through a main body discharge port 226a disposed below the cup unit 225.
- step S17 a predetermined process is performed on the upper surface 91 of the substrate 9 by supplying the processing liquid to the upper surface 91 of the substrate 9 for a predetermined time.
- the processing in step S17 is referred to as “liquid processing”.
- step S ⁇ b> 17 the chemical liquid (for example, the polymer removal liquid or the etching liquid) supplied from the chemical liquid supply unit 813 is supplied onto the substrate 9 for a predetermined time, and then the supply of the chemical liquid is stopped. Thereby, the chemical
- the chemical solution on the substrate 9 is scattered to the cup portion 225 by the rotation of the substrate 9 and is removed from the substrate 9.
- the chemical solution received by the cup unit 225 is discharged out of the chamber 21 through the main body discharge port 226a and is collected by the chemical solution collection unit 195 (see FIG. 2). Subsequently, the pure water supplied from the pure water supply unit 814 is supplied onto the substrate 9 for a predetermined time, whereby the rinsing process of the upper surface 91 of the substrate 9 is performed. The pure water received by the cup unit 225 is discharged out of the chamber 21 through the main body discharge port 226a and discarded by the drainage unit 196.
- a plurality of cups arranged concentrically on the cup portion 225 may be provided.
- the cup that receives the processing liquid from the substrate 9 is also switched.
- the nitrogen gas is supplied to the lid internal space 231 from the first gas ejection ports 184 of the plurality of lid nozzles 182 positioned above the shielding plate 51.
- the air pressure in the lid internal space 231 is higher than the air pressure in the main body internal space 221 and the lid internal space 231 is in a positive pressure state.
- the nitrogen gas in the lid internal space 231 passes through the lower opening 232 and the upper opening 222 from the gap between the shielding plate 51 and the lid bottom surface portion 234 of the chamber lid portion 23. To the internal space 221 of the main body. Further, the nitrogen gas that has flowed into the main body internal space 221 from the lid internal space 231 is sucked through the main body discharge port 226 a and discharged out of the chamber 21.
- a substantially cylindrical nitrogen gas stream that passes in the vicinity of the outer peripheral edge of the shielding plate 51, the vicinity of the outer peripheral edge of the lower opening 232, the vicinity of the outer peripheral edge of the upper opening 222, and the vicinity of the outer peripheral edge of the substrate 9 is 21 is formed. Since the supply of the processing liquid to the upper surface 91 of the substrate 9 is performed inside the substantially cylindrical airflow, the mist or fume of the processing liquid passes through the substantially cylindrical airflow and the shielding plate 51 and the bottom surface of the lid. It is possible to suppress the entry into the lid internal space 231 from the gap with the portion 234. Further, the mist or fume of the processing liquid can be quickly moved downward by the air flow, and can be quickly discharged out of the chamber 21.
- the main body discharge port 226 a is disposed below the cup portion 225, whereby the airflow can be easily formed.
- the flow rate of the airflow can be easily adjusted by changing the supply amount of nitrogen gas from the plurality of lid nozzles 182 and the size of the gap between the shielding plate 51 and the lid bottom surface portion 234. can do.
- the main body discharge port 226 a is not necessarily disposed below the cup portion 225, and is disposed below the substrate 9 and the substrate holding portion 31 located in the main body internal space 221. It only has to be done.
- step S17 nitrogen gas may be supplied also to the space between the lower surface 512 of the shielding plate 51 and the upper surface 91 of the substrate 9 through the second gas outlet 185 of the upper central nozzle 181.
- a downward air flow toward the upper surface 91 of the substrate 9 is formed, so that mist or fumes of the processing liquid existing in the space above the substrate 9 can be reduced. It can extrude toward the substantially cylindrical airflow.
- the first moving mechanism 41, the second moving mechanism 42, and the third moving mechanism 43 are driven, whereby the shielding plate 51, the chamber lid portion 23, and the cup portion 225 of the chamber main body 22 are driven. Moves downward.
- the chamber lid part 23 and the cup part 225 of the chamber body 22 each move from the upper position shown in FIG. 4 to the lower position shown in FIG. In other words, the substrate 9 is raised relative to the chamber 21 together with the substrate holder 31 by the second moving mechanism 42 and the third moving mechanism 43.
- the relative position of the shielding plate 51 with respect to the chamber lid 23 is not changed, and the state where the shielding plate 51 is spaced upward from the lower opening 232 of the chamber lid 23 is maintained.
- Step S18 when the chamber 21 moves from the upper position to the lower position, the substrate 9 moves from the main body inner space 221 to the lid inner space 231 through the upper opening 222 and the lower opening 232 in the chamber 21.
- Step S18 In the lid internal space 231, the upper surface 91 of the substrate 9 and the lower surface 512 of the shielding plate 51 are opposed to each other in the vertical direction.
- step S19 the process of step S19 is referred to as “drying process”.
- the rotation speed of the substrate 9 in step S19 is larger than the rotation speed of the substrate 9 in step S17.
- step S ⁇ b> 19 the processing liquid splashed from the rotating substrate 9 is received by the inner surface of the lid main body portion 233 and the upper surface 235 of the lid bottom surface portion 234, and moves to the connection portion between the lid main body portion 233 and the lid bottom surface portion 234. To do. Then, the processing liquid (that is, the processing liquid removed from the substrate 9 in step S19) is discharged out of the chamber lid 23 (that is, outside the chamber 21) by the lid discharge port 237.
- the upper surface 235 of the lid bottom surface portion 234 is an inclined surface that goes downward as it goes outward in the radial direction. This prevents the processing liquid on the upper surface 235 from moving toward the lower opening 232. Further, since the processing liquid on the upper surface 235 moves radially outward, the processing liquid can be quickly discharged from the lid internal space 231.
- the shielding plate 51 When the substrate 9 is rotated by the substrate rotating mechanism 35 in the lid internal space 231 (that is, in step S19), the shielding plate 51 is positioned close to the upper surface 91 of the substrate 9 in the vertical direction by the shielding plate rotating mechanism 55. Thus, the substrate 9 rotates about the central axis J1 in the same rotational direction as the substrate 9 at a rotational speed approximately equal to the rotational speed of the substrate 9.
- the shielding plate 51 By disposing the shielding plate 51 in the vicinity of the upper surface 91 of the substrate 9, it is possible to suppress (or prevent) the processing liquid scattered from the substrate 9 from reattaching to the upper surface 91 of the substrate 9. Further, when the shielding plate 51 rotates, the processing liquid adhering to the upper surface 511 and the lower surface 512 of the shielding plate 51 can be scattered around and removed from the shielding plate 51.
- step S ⁇ b> 19 nitrogen gas is introduced into the space between the lower surface 512 of the shielding plate 51 and the upper surface 91 of the substrate 9 via the second gas ejection port 185 (see FIG. 2) of the upper central nozzle 181. Is supplied. Thereby, the processing liquid can be discharged more rapidly from the space between the substrate 9 and the shielding plate 51 and the drying of the substrate 9 can be promoted.
- the first moving mechanism 41 and the second moving mechanism 42 are driven to move the shielding plate 51 and the chamber lid portion 23 upward.
- the chamber lid 23 moves from the lower position shown in FIG. 3 to the upper position shown in FIG.
- the chamber lid 23 and the chamber body 22 are separated in the vertical direction, and the chamber 21 is opened.
- the substrate 9 subjected to the above-described series of processing is carried out of the housing 11 from a carry-in / out opening (not shown) provided in the housing 11 (step S20).
- the shielding plate 51 descends relative to the chamber lid portion 23 and contacts the lid bottom surface portion 234 to close the lower opening 232.
- the nitrogen gas supplied from the gas supply unit 812 fills the lid internal space 231 with nitrogen gas, as in step S11.
- the above-described steps S11 to S20 are sequentially performed on the plurality of substrates 9.
- the shielding plate 51 having a larger radial size than the lower opening 232 is provided in the lid internal space 231 of the chamber lid portion 23.
- the gas supplied from the gas supply unit 812 is supplied from the gas supply unit 812 while the shielding plate 51 is overlaid on the lower opening 232.
- 23 lid internal space 231 is filled.
- the gas supplied from the gas supply unit 812 is an inert gas such as nitrogen gas, so that the substrate 9 can be rapidly processed in a low oxygen atmosphere. As a result, the oxidation or the like of the metal film provided on the upper surface 91 of the substrate 9 can be suppressed.
- the chamber lid portion 23 includes the lid main body portion 233 and the lid bottom surface portion 234.
- step S ⁇ b> 11 the lower surface 512 of the shielding plate 51 is in contact with the upper surface 235 of the lid bottom surface portion 234, thereby closing the lower opening 232 of the chamber lid portion 23. Thereby, the filling of the gas in the lid internal space 231 can be performed quickly and easily.
- the substrate 9 is positioned in the lid internal space 231 filled with gas in advance. As a result, immediately after the formation of the chamber 21, the periphery of the substrate 9 can be quickly brought into a desired gas atmosphere.
- step S15 the gas replacement process is performed with the substrate 9 placed in the lid internal space 231, and in step S16, the chamber 21 is moved to the upper position by the second moving mechanism 42 and the third moving mechanism 43.
- the substrate 9 moves relatively from the lid internal space 231 to the main body internal space 221.
- step S17 liquid processing is performed on the substrate 9 with the substrate 9 placed in the main body internal space 221, and in step S18, the chamber 21 is moved to the lower position by the second moving mechanism 42 and the third moving mechanism 43.
- the substrate 9 moves relatively from the main body internal space 221 to the lid internal space 231.
- step S ⁇ b> 19 the substrate 9 is dried with the substrate 9 placed in the lid internal space 231.
- the second moving mechanism 42 and the third moving mechanism 43 move the substrate 9 relative to the chamber 21 between the lid internal space 231 and the main body internal space 221. Functions as a substrate moving mechanism.
- the relative movement of the substrate 9 by the substrate moving mechanism is as follows: In the chamber 21, this is performed via the lower opening 232 and the upper opening 222 in a state where the shielding plate 51 is spaced upward from the lower opening 232 of the chamber lid 23. Thereby, a space in which a plurality of processes (that is, a series of processes of gas replacement process, liquid process and drying process) is performed between the main body internal space 221 and the lid internal space 231 according to the processing content. Can be switched.
- the processing liquid scattered from the rotating substrate 9 is received by the cup portion 225 disposed below the chamber lid portion 23.
- the process liquid used for the liquid process can be easily recovered.
- the outer cylinder portion 223 that forms the chamber 21 by contacting the chamber lid portion 23 is provided around the cup portion 225.
- the outer cylinder connection part 224 By closing the gap between the upper part of the outer cylinder part 223 and the cup part 225 by the outer cylinder connection part 224, the space filled with the gas from the gas supply part 812 in the chamber 21 can be reduced. As a result, the time required for the gas replacement process in step S15 can be shortened.
- the above-described substantially cylindrical airflow is not necessarily formed. Even when the above-described substantially cylindrical airflow is not formed in the chamber 21, the lid internal space 231 is made to be in a positive pressure state by making the pressure in the lid internal space 231 higher than the pressure in the main body internal space 221. Further, it is possible to suppress the mist, fume, and the like of the processing liquid from entering the lid internal space 231 through the gap between the shielding plate 51 and the lid bottom surface portion 234.
- the substrate processing apparatus 1 can be variously changed.
- the gas may not be ejected from the second gas ejection port 185 provided at the center of the lower surface 512 of the shielding plate 51.
- the second gas ejection port 185 may be omitted.
- the lower opening 232 of the chamber lid 23 may be blocked by the shielding plate 51 by the lower surface 512 of the shielding plate 51 coming into contact with the lid bottom surface portion 234 of the chamber lid 23. Even in this case, it is possible to prevent the mist or fume of the processing liquid from entering the lid internal space 231.
- the shielding plate 51 adjacent to the upper surface 91 of the substrate 9 may be fixed to the substrate holding unit 31 in the circumferential direction and may be rotated together with the substrate 9 and the substrate holding unit 31 by the substrate rotating mechanism 35.
- the processing liquid can be removed from the shielding plate 51 while preventing the processing liquid from reattaching to the substrate 9 during the drying process.
- the shielding plate rotation mechanism 55 may be omitted.
- the chamber opening / closing mechanism includes a second moving mechanism 42 that moves the chamber lid portion 23 and a third moving mechanism 43 that moves the cup portion 225 of the chamber body 22.
- One of the second moving mechanism 42 and the third moving mechanism 43 may be omitted, and only the other may be used as the chamber opening / closing mechanism.
- the shielding plate moving mechanism includes a first moving mechanism 41 that moves the shielding plate 51 and a second moving mechanism 42 that moves the chamber lid 23.
- One of the second moving mechanisms 42 may be omitted, and only the other may be used as the shielding plate moving mechanism.
- the above-described substrate moving mechanism includes a second moving mechanism 42 that moves the chamber lid portion 23 and a third moving mechanism 43 that moves the cup portion 225 of the chamber body 22.
- the mechanism may be, for example, a mechanism that moves the substrate holding unit 31 in the vertical direction in the chamber 21 while the chamber 21 is stopped.
- the chamber lid 23 does not necessarily have to move from the upper position to the lower position.
- the chamber 21 may be formed by moving the cup portion 225 of the chamber body 22 from the lower position shown in FIG. 1 to the upper position shown in FIG.
- the shielding plate 51 is moved upward by the first moving mechanism 41 and separated upward from the lower opening 232 of the chamber lid 23.
- step S ⁇ b> 15 the gas replacement process is performed with the substrate 9 positioned in the main body internal space 221. For this reason, the relative movement (step S16) of the substrate 9 from the lid internal space 231 to the main body internal space 221 is omitted, and the liquid processing of the substrate 9 (step S17) is performed following step S15.
- a chamber lid portion 23 a having an outer diameter smaller than that of the chamber body 22 may be provided as shown in FIG. 7.
- the lower end of the outer periphery of the substantially cylindrical chamber lid portion 23a with the lid is in contact with the upper surface of the cup portion 225 of the chamber body 22, so that the upper opening 222 of the chamber body 22 is blocked by the chamber lid portion 23a.
- the chamber 21 is formed.
- the chamber lid portion 23a is not provided with the lid bottom surface portion 234 (see FIG. 1), and the radial size of the lower opening 232 is approximately equal to the radial size of the chamber lid portion 23a.
- a shielding plate 51 having a radial size slightly smaller than the outer diameter of the chamber lid portion 23a is disposed in the lid internal space 231.
- the shielding plate 51 is overlapped with the lower opening 232 in a plan view at substantially the same position as the lower opening 232 of the chamber lid 23 in the vertical direction, a slight gap remains around the lower opening 232, but the lower opening 232 is substantially Obstructed.
- the lid internal space 231 is filled with gas from the gas supply unit 812.
- a shielding plate 51 a having an outer diameter slightly smaller than the diameter of the lower opening 232 may be provided as shown in FIG. 8.
- a shielding plate 51 a whose radial size is slightly smaller than the diameter of the lower opening 232 is disposed in the lid internal space 231.
- the shielding plate 51a is overlapped with the lower opening 232 in a plan view at substantially the same position as the lower opening 232 of the chamber lid 23 in the vertical direction, leaving a slight gap around it, but the lower opening 232 is substantially Obstructed.
- the gas from the gas supply unit 812 is supplied to the lid internal space 231 and filled.
- various substrates other than the semiconductor substrate may be processed. Further, the substrate processing apparatus 1 can perform various liquid treatments desirably performed in a low oxygen environment using various processing liquids such as hydrochloric acid and hydrofluoric acid as well as polymer removal and etching.
- the gas supplied to the chamber 21 to realize the low oxygen state is not limited to nitrogen gas, and may be other inert gas such as argon.
- the gas supplied to the chamber 21 is a gas for making the inside of the chamber 21 a desired gas atmosphere, for example, a mixed gas whose gas composition ratio is controlled (that is, a mixture of a plurality of types of gases). Also good.
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Abstract
Description
チャンバ21内において、遮蔽板51がチャンバ蓋部23の下部開口232から上方に離間している状態で、下部開口232および上部開口222を介して行われる。これにより、基板9に対する複数の処理(すなわち、ガス置換処理、液処理および乾燥処理の一連の処理)が行われる空間を、処理内容に合わせて、本体内部空間221と蓋内部空間231との間で切り替えることができる。
9 基板
21 チャンバ
22 チャンバ本体
23,23a チャンバ蓋部
31 基板保持部
35 基板回転機構
41 第1移動機構
42 第2移動機構
43 第3移動機構
51,51a 遮蔽板
91 (基板の)上面
185 第2ガス噴出口
221 本体内部空間
222 (チャンバ本体の)上部開口
223 外筒部
224 外筒接続部
225 カップ部
226a 本体排出ポート
231 蓋内部空間
232 (チャンバ蓋部の)下部開口
233 蓋本体部
234 蓋底面部
235 (蓋底面部の)上面
237 蓋部排出ポート
512 (遮蔽板の)下面
811 処理液供給部
812 ガス供給部
J1 中心軸
S11~S20 ステップ
Claims (18)
- 基板を処理する基板処理装置であって、
水平状態で基板を保持する基板保持部と、
下部開口を有し、前記下部開口の上方に蓋内部空間を形成するチャンバ蓋部と、
前記下部開口と上下方向に対向する上部開口を有し、本体内部空間を形成するチャンバ本体と、
前記チャンバ蓋部を前記チャンバ本体に対して前記上下方向に相対的に移動し、前記上部開口を前記チャンバ蓋部により覆うことにより、前記基板保持部を内部に収容するチャンバを形成するチャンバ開閉機構と、
前記基板の上面に処理液を供給する処理液供給部と、
前記蓋内部空間に配置されて前記基板の前記上面に対向し、前記下部開口を閉塞可能な遮蔽板と、
前記遮蔽板を前記蓋内部空間において前記チャンバ蓋部に対して前記上下方向に相対的に移動する遮蔽板移動機構と、
前記遮蔽板が前記チャンバ蓋部の前記下部開口に重ねられた状態で前記蓋内部空間にガスを供給するガス供給部と、
を備える。 - 請求項1に記載の基板処理装置であって、
前記基板を前記基板保持部と共に前記チャンバに対して前記上下方向に相対的に移動する基板移動機構をさらに備え、
前記遮蔽板が前記チャンバ蓋部の前記下部開口から離間している状態で、前記基板が、前記基板移動機構により前記チャンバ内において前記蓋内部空間と前記本体内部空間との間を前記下部開口および前記上部開口を介して相対的に移動する。 - 請求項1または2に記載の基板処理装置であって、
前記チャンバ蓋部が、
上下を反転したカップ状の蓋本体部と、
前記蓋本体部の下端部から径方向内方に拡がるとともに中央部に前記下部開口が設けられた環状の蓋底面部と、
を備え、
前記下部開口に重ねられた前記遮蔽板の下面が、前記下部開口の周囲の全周に亘って前記蓋底面部の上面に接することにより前記下部開口を閉塞する。 - 請求項3に記載の基板処理装置であって、
前記蓋底面部の前記上面が、前記径方向外方へと向かうに従って下方に向かい、
前記チャンバ蓋部の前記蓋底面部と前記蓋本体部との接続部に、前記蓋内部空間内の液体を排出する排出ポートが設けられる。 - 請求項1ないし4のいずれかに記載の基板処理装置であって、
前記遮蔽板の下面の中央部にガス噴出口が設けられ、
前記ガス供給部により、前記ガス噴出口を介して前記遮蔽板の前記下面と前記基板の前記上面との間の空間に前記ガスが供給される。 - 請求項1ないし5のいずれかに記載の基板処理装置であって、
前記上下方向を向く中心軸を中心として前記基板を前記基板保持部と共に回転する基板回転機構をさらに備え、
前記チャンバ本体が、
前記チャンバ蓋部の下方にて前記基板保持部の径方向外側に全周に亘って位置し、回転する前記基板から飛散する処理液を受けるカップ部を備える。 - 請求項6に記載の基板処理装置であって、
前記チャンバ本体が、
前記カップ部の前記径方向外側に全周に亘って位置し、前記チャンバ蓋部と接することにより前記チャンバを形成する外筒部と、
前記外筒部の上端部と前記カップ部との間の間隙を閉塞する外筒接続部と、
をさらに備える。 - 請求項2ないし5のいずれかに記載の基板処理装置であって、
前記上下方向を向く中心軸を中心として前記基板を前記基板保持部と共に回転する基板回転機構をさらに備え、
前記蓋内部空間において前記基板が前記基板回転機構により回転する際に、前記遮蔽板が前記基板に近接した位置にて前記中心軸を中心として回転する。 - 水平状態で基板を保持する基板保持部と、下部開口を有し、前記下部開口の上方に蓋内部空間を形成するチャンバ蓋部と、前記下部開口と上下方向に対向する上部開口を有し、本体内部空間を形成するチャンバ本体と、前記蓋内部空間に配置されて前記基板の上面に対向し、前記下部開口を閉塞可能な遮蔽板とを備える基板処理装置において、前記基板を処理する基板処理方法であって、
a)前記遮蔽板が前記チャンバ蓋部の前記下部開口に重ねられた状態で、前記蓋内部空間にガスを供給する工程と、
b)前記チャンバ蓋部が前記チャンバ本体から離間した状態で前記基板を前記基板保持部により保持する工程と、
c)前記チャンバ蓋部を前記チャンバ本体に対して前記上下方向に相対的に移動し、前記上部開口を前記チャンバ蓋部により覆うことにより、前記基板および前記基板保持部を内部に収容するチャンバを形成する工程と、
d)前記遮蔽板を前記チャンバ蓋部に対して相対的に上昇させて前記遮蔽板を前記下部開口から離間させる工程と、
e)前記チャンバ内に前記ガスを供給する工程と、
f)前記基板の前記上面に処理液を供給する工程と、
を備える。 - 請求項9に記載の基板処理方法であって、
前記b)工程において、前記基板が前記チャンバ本体の前記上部開口よりも上方にて前記基板保持部により保持され、
前記d)工程が前記c)工程と並行して行われ、前記チャンバが形成された状態で、前記基板が前記蓋内部空間に位置する。 - 請求項10に記載の基板処理方法であって、
前記e)工程において、前記遮蔽板の下面の中央部に設けられたガス噴出口を介して、前記遮蔽板の前記下面と前記基板の前記上面との間の空間に前記ガスが供給される。 - 請求項10または11に記載の基板処理方法であって、
g)前記f)工程よりも前に、前記基板を前記基板保持部と共に前記チャンバに対して相対的に下降させることにより、前記基板を前記蓋内部空間から前記下部開口および前記上部開口を介して前記本体内部空間へと移動する工程をさらに備える。 - 請求項12に記載の基板処理方法であって、
前記f)工程において、前記蓋内部空間の気圧が前記本体内部空間の気圧よりも高い。 - 請求項9ないし13のいずれかに記載の基板処理方法であって、
h)前記f)工程よりも後に、前記基板を前記基板保持部と共に前記チャンバに対して相対的に上昇させることにより、前記基板を前記本体内部空間から前記上部開口および前記下部開口を介して前記蓋内部空間へと移動する工程と、
i)前記上下方向を向く中心軸を中心として前記基板を前記基板保持部と共に回転することにより、前記基板上の処理液を除去する工程と、
をさらに備える。 - 請求項14に記載の基板処理方法であって、
前記チャンバ蓋部が、
上下を反転したカップ状の蓋本体部と、
前記蓋本体部の下端部から径方向内方に拡がるとともに中央部に前記下部開口が設けられた環状の蓋底面部と、
前記蓋底面部と前記蓋本体部との接続部に設けられ、前記i)工程において前記基板上から除去された処理液を排出する排出ポートと、
を備え、
前記蓋底面部の上面が、前記径方向外方へと向かうに従って下方に向かう。 - 請求項14または15に記載の基板処理方法であって、
前記i)工程において、前記遮蔽板が前記基板に近接した位置にて前記中心軸を中心として回転する。 - 請求項14ないし16のいずれかに記載の基板処理方法であって、
前記i)工程において、前記遮蔽板の下面の中央部に設けられたガス噴出口を介して、前記遮蔽板の前記下面と前記基板の前記上面との間の空間に前記ガスが供給される。 - 請求項9ないし17のいずれかに記載の基板処理方法であって、
前記基板は、表面に金属パターンが露出したものである。
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CN105981139A (zh) | 2016-09-28 |
US11282718B2 (en) | 2022-03-22 |
KR101831545B1 (ko) | 2018-02-22 |
KR20160106712A (ko) | 2016-09-12 |
TW201539621A (zh) | 2015-10-16 |
US20170069512A1 (en) | 2017-03-09 |
TWI545678B (zh) | 2016-08-11 |
CN109461685B (zh) | 2022-03-08 |
CN109461685A (zh) | 2019-03-12 |
US20200328097A1 (en) | 2020-10-15 |
CN105981139B (zh) | 2018-12-21 |
US10777432B2 (en) | 2020-09-15 |
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