WO2015076066A1 - 光学フィルム用粘着剤組成物、粘着型光学フィルムおよび積層体 - Google Patents
光学フィルム用粘着剤組成物、粘着型光学フィルムおよび積層体 Download PDFInfo
- Publication number
- WO2015076066A1 WO2015076066A1 PCT/JP2014/078491 JP2014078491W WO2015076066A1 WO 2015076066 A1 WO2015076066 A1 WO 2015076066A1 JP 2014078491 W JP2014078491 W JP 2014078491W WO 2015076066 A1 WO2015076066 A1 WO 2015076066A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- pressure
- sensitive adhesive
- component
- mass
- optical film
- Prior art date
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
- C09J2203/318—Applications of adhesives in processes or use of adhesives in the form of films or foils for the production of liquid crystal displays
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2433/00—Presence of (meth)acrylic polymer
Definitions
- the present invention relates to an optical film adhesive composition, an adhesive optical film, and a laminate.
- the liquid crystal cell constituting the liquid crystal display device is becoming thinner.
- the bonding between the liquid crystal cell and the polarizing plate is not successful, and when the polarizing plate is peeled off from the liquid crystal cell, If the adhesive strength is too strong, the liquid crystal cell may be damaged.
- an adhesive such as silicone oil is blended in the adhesive to lower the adhesive strength of the adhesive.
- an additive may be mix
- the additive component may be deposited on the surface of the pressure-sensitive adhesive layer.
- the additive may be separated in the pressure-sensitive adhesive.
- An object of the present invention is to provide a pressure-sensitive adhesive composition for an optical film capable of obtaining a pressure-sensitive adhesive layer excellent in reworkability and durability, and a pressure-sensitive adhesive optical film and a laminate using the same.
- the present inventors have an adhesive composition containing an acrylic polymer obtained by using a predetermined component, which is excellent in reworkability (in particular, reworkability after heating) and durability. It has been found that an adhesive layer can be obtained.
- the pressure-sensitive adhesive composition for an optical film according to one aspect of the present invention, (A) a (meth) acrylic polymer having a weight average molecular weight of 1,000,000 or more; (B) a crosslinking agent; (C) a silane coupling agent,
- the (A) (meth) acrylic polymer is (A1) component: 1% by mass or more and 30% by mass or less of an acrylic acid alkyl ester monomer having a linear alkyl group having 12 to 18 carbon atoms; (A2) component: 0.1% by mass to 10% by mass of a monomer having a hydroxyl group, Component (a3): a monomer other than the component (a1) and the component (a2), and a non-crosslinkable (meth) acrylic acid ester monomer of 60% by mass or more and 98.9% by mass or less. It is a copolymer of the monomer mixture containing.
- the content of the carboxyl group-containing monomer in the monomer mixture may be 1% by mass or less.
- the (B) crosslinking agent may be contained in an amount of 0.01 to 5 parts by mass with respect to 100 parts by mass of the (A) acrylic polymer. it can.
- the gel fraction may be 40% or more and 93% or less.
- the pressure-sensitive adhesive composition for an optical film described in any one of 1 to 5 can further contain (D) an ionic compound.
- the optical film pressure-sensitive adhesive composition according to any one of 1 to 6 above is a 20 ⁇ m-thick pressure-sensitive adhesive layer obtained using the optical film pressure-sensitive adhesive composition according to any one of 1 to 6 above. , Placed on the surface of the glass treated with alkali, treated in an autoclave at 50 ° C. and 5 atm for 20 minutes, heated at 60 ° C. for 2 hours, and then in a 23 ° C./50% RH atmosphere The adhesive strength when peeling the pressure-sensitive adhesive layer from the surface after standing for 2 hours can be 700 gf / 25 mm or less.
- the pressure-sensitive adhesive optical film according to one embodiment of the present invention is provided with a pressure-sensitive adhesive layer obtained by using the pressure-sensitive adhesive composition for optical films according to any one of 1 to 7 above on one side or both sides of the optical film. .
- the adhesive optical film described in 8 above can be an optical film selected from the group consisting of a polarizing film, a retardation film, an elliptically polarizing film, an antireflection film, a brightness enhancement film, and a light diffusion film.
- the laminated body which concerns on 1 aspect of this invention is the adhesive for optical films of any one of said 1 thru
- a pressure-sensitive adhesive layer obtained by forming the adhesive composition into a film and heating it.
- the (A) (meth) acrylic copolymer which is a copolymer of a monomer mixture containing the component (a1), the component (a2) and the component (a3).
- the polymer By including the polymer, a pressure-sensitive adhesive layer excellent in reworkability (in particular, reworkability after heating) and durability can be obtained using the composition.
- repairability refers to the property of the pressure-sensitive adhesive layer that allows the pressure-sensitive adhesive layer to be once attached to the adherend and easily peeled off from the adherend.
- the pressure-sensitive adhesive optical film is provided with the pressure-sensitive adhesive layer obtained by using the pressure-sensitive adhesive composition for optical films on one side or both sides of the optical film, reworkability (especially, reworkability after heating) ) And durability.
- the laminate includes a pressure-sensitive adhesive layer obtained by heating the pressure-sensitive adhesive composition for an optical film, which is provided between the glass substrate and the polarizing plate, and is heated. Excellent durability.
- Drawing 1 is a sectional view showing typically an example of a layered product containing an adhesive layer obtained using an adhesive composition for optical films concerning one embodiment of the present invention.
- parts means “parts by mass” and “%” means “mass%” unless otherwise specified.
- optical film pressure-sensitive adhesive composition is a (meth) acrylic polymer (A (Hereinafter sometimes simply referred to as “component (A)”), (B) a crosslinking agent (hereinafter sometimes simply referred to as “component (B)”), and (C) silane.
- component (C) a coupling agent
- a component is a (A) (meth) acrylic-type polymer whose weight average molecular weight is 1 million or more.
- the component (A) includes (a1) component: 1% by mass to 30% by mass of an acrylic acid alkyl ester monomer having a linear alkyl group having 12 to 18 carbon atoms, and (a2) component: a hydroxyl group.
- Monomer having 0.1 mass% to 10 mass% and component (a3): a monomer other than the component (a1) and the component (a2), which is a non-crosslinkable (meth) acrylate A monomer mixture copolymer containing 60% by mass or more and 98.9% by mass or less of monomers.
- the “(meth) acrylic polymer” refers to at least one selected from acrylic acid, acrylate, acrylate, methacrylic acid, methacrylate, and methacrylate in the structural unit.
- Weight average molecular weight The weight average molecular weight of (A) component is 1 million or more and 2 million or less normally, and it is more preferable that it is 1.1 million or more at the point which can improve durability more.
- the weight average molecular weight of the component (A) is obtained by using GPC (gel permeation chromatography) and calculating the weight average molecular weight (Mw) in terms of standard polystyrene under the following conditions.
- Measuring device HLC-8120GPC (manufactured by Tosoh Corporation)
- GPC column configuration The following five columns (all manufactured by Tosoh Corporation) (1) TSK-GEL HXL-H (guard column) (2) TSK-GEL G7000HXL (3) TSK-GEL GMHXL (4) TSK-GEL GMHXL (5) TSK-GEL G2500HXL Diluted with tetrahydrofuran so that the sample concentration is 1.0 mg / cm 3
- Mobile phase solvent Tetrahydrofuran Flow rate: 1.0 cm 3 / min (min) Column temperature: 40 ° C
- the (A) component preferably has a Tg of the (A) (meth) acrylic polymer of 0 ° C. or less, preferably ⁇ 20 ° C. or less, from the viewpoint that durability and reworkability can be further improved. More preferred (usually -80 ° C or higher).
- Tg of the component (A) is a value calculated by the following formula (1) (FOX formula).
- Tg A represents the glass transition temperature (K) of the component (A)
- Tg a1 , Tg a2 , Tg a3 , Tg a4 , and Tg a5 are the component (a1), component (a2), ( a3) shows the glass transition temperature (Tg (K)) of the homopolymer prepared from the component, (a4) component and (a5) component
- W a1 , W a2 , W a3 , W a4 and W a5 are (A) Indicates the weight fraction of the components (a1), (a2), (a3), (a4), and (a5) contained in the component.
- K glass transition temperature
- the glass transition temperatures of homopolymers prepared from typical monomers are shown in Table 1 below. More specifically, for example, Polymer Handbook 4th Edition (Polymer Handbook Fourth Edition, Wiley-Interscience, 2003) Or on the manufacturer's website or pamphlet.
- (A) Content of component Content of (A) component in the adhesive composition which concerns on this embodiment is 80 mass parts or more and 99.9 mass parts with respect to 100 mass parts of adhesive composition which concerns on this embodiment. It is preferable that it is 90 mass part or more and 99.9 mass part or less.
- the optical pressure-sensitive adhesive composition according to the present embodiment is preferably 40% or more and 93% or less, more preferably 40% or more, further preferably 50% or more, and more preferably 85% or less, 80% More preferably, it is as follows.
- the gel fraction is, for example, (a1) component, (a2) component, (a3) component, (a4) component, (a5) in the monomer mixture. It can adjust with the kind and usage-amount of a component, and the kind and usage-amount of the crosslinking agent which are (B) components.
- the adhesive strength when peeling the adhesive layer is 700 gf / 25 mm or less.
- the reworkability after heating means having reworkability even after the pressure-sensitive adhesive layer is heated.
- the pressure-sensitive adhesive composition usually improves wettability by heating and increases the adhesive strength.
- the optical pressure-sensitive adhesive composition according to the present embodiment has little variation in wettability due to heating and little variation in adhesive strength after heating, and thus the pressure-sensitive adhesive layer obtained using the composition Has reworkability not only before heating but also after heating.
- the adhesive strength of 700 gf / 25 mm or less means that the pressure-sensitive adhesive layer obtained from the optical pressure-sensitive adhesive composition according to this embodiment has reworkability even after heating.
- the post-heating adhesive force measured in the Example mentioned later is small means that the rework property after a heating is favorable.
- the pressure-sensitive adhesive layer obtained from the composition is exposed to heating conditions (for example, a polarizing plate and an adherend to which the pressure-sensitive adhesive layer is attached).
- the adhesive layer has a feature that it is excellent in reworkability not only before heating but also after heating, even when heating (further reduced pressure) is applied.
- the component (a1) contributes to improvement in durability and reworkability after heating.
- the component (a1) is preferably 1% by mass or more and 30% by mass or less, more preferably 2% by mass or more, and more preferably 3% by mass from the viewpoint that durability and reworkability after heating can be further improved. More preferably, it is preferably 28% by mass or less, more preferably 26% by mass or less, and further preferably 24% by mass or less.
- the component (a1) exceeds 30% by mass, the polymerization rate is decreased, and a large amount of unreacted residual monomer is contained in the copolymer. .
- Examples of the linear alkyl group having 12 to 18 carbon atoms contained in the component (a1) include lauryl group (dodecyl group), tridecyl group, myristyl group (tetradecyl group), pentadecyl group, palmityl group (hexadecyl group). , Heptadecyl group, stearyl group (octadecyl group).
- component (a1) examples include lauryl acrylate, tridecyl acrylate, myristyl acrylate, pentadecyl acrylate, palmityl acrylate, heptadecyl acrylate, and stearyl acrylate, and one of these may be used alone or in combination of two or more. Can be used. Of these, lauryl acrylate is preferable.
- the component (a1) has a linear alkyl group having 12 to 18 carbon atoms, and when the homopolymer is formed, the Tg is ⁇ 20 ° C. or more and 50 ° C. or less (preferably ⁇ 15 ° C. or more, More preferably, it is ⁇ 10 ° C. or higher), is smooth, has little variation in wettability with respect to the adherend, and has an appropriate hardness.
- the low wettability of the component (a1) to the adherend is presumed to be due to the low polarity of a linear alkyl group having 12 to 18 carbon atoms. Moreover, it is estimated that the moderate hardness of (a1) component originates in the favorable crystal orientation which the C12-C18 linear alkyl group has.
- the pressure-sensitive adhesive composition according to this embodiment contains the component (A1) that is a copolymer of a monomer mixture containing 1% by mass to 30% by mass of the component (a1).
- the (a1) component By using the (a1) component, a pressure-sensitive adhesive layer excellent in reworkability and durability can be obtained.
- the (a2) component can contribute to crosslinking with the (B) component. More specifically, a hydroxyl group (hydroxyl group) contained in the component (a2) reacts with an isocyanate group in the component (B) to form a crosslinked structure.
- the pressure-sensitive adhesive composition according to the present embodiment contains the component (a2), even when a component with low polarity such as the component (a1) is used when preparing the component (A). Because of the high polarity of the component (a2) due to the hydroxyl group, it has the effect of increasing the adhesion to an adherend (for example, triacetylcellulose or a material described later) having a surface with a relatively high polarity. .
- an adherend for example, triacetylcellulose or a material described later
- an adherend having a surface having a relatively high polarity for example, an adherend having a hydrogen-bonding functional group such as a hydroxyl group (hydroxyl group), a carboxyl group, or an amino group on the surface can be mentioned.
- adherends include TAC (triacetyl cellulose), polycarbonate, and acrylic resin used for polarizing plates.
- the component (a2) is preferably 0.1% by mass or more and 10% by mass or less, more preferably 0.3% by mass or more, and 0.5% by mass in that the crosslinkability can be further improved. More preferably, it is the above. On the other hand, it is preferably 8% by mass or less, more preferably 7% by mass or less, and further preferably 6% by mass or less.
- Examples of the component (a2) include 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate, 2-hydroxypropyl acrylate, 2-hydroxypropyl methacrylate, 4-hydroxybutyl acrylate, 4-hydroxybutyl methacrylate, 2-hydroxy-3 -Hydroxyl group-containing (meth) acrylic acid ester, such as chloropropyl acrylate, 2-hydroxy-3-chloropropyl methacrylate, 2-hydroxy-3-phenoxypropyl acrylate, 2-hydroxy-3-phenoxypropyl methacrylate A body is mentioned, Among these, it can be used combining 1 type (s) or 2 or more types.
- the monomer mixture is a monomer other than the (a1) component and the (a2) component, and is a non-crosslinkable (meth) acrylate monomer (hereinafter simply referred to as “(a3) component”).
- “non-crosslinkable” means having no functional group capable of crosslinking by reacting with the (B) crosslinking agent.
- the non-crosslinkable (meth) acrylate monomer is, for example, a (meth) acrylate monomer that does not contain a functional group that can be crosslinked by reacting with the (B) crosslinking agent.
- the component (a3) is 60% by mass or more and 98.9% by mass or less, and preferably 64% by mass or more, in that the durability of the pressure-sensitive adhesive layer obtained using the composition can be further improved. 70% by mass or more, more preferably 97.7% by mass or less, and further preferably 96.5% by mass or less.
- the component (a3) may be, for example, a monomer represented by the following general formula (3).
- R 1 represents a hydrogen atom or a methyl group
- R 2 represents a linear alkyl group having 1 to 11 carbon atoms, a branched alkyl group, an alicyclic group, an aromatic ring-containing group, and a heterocyclic ring-containing group. Or represents an ether bond-containing group.
- Examples of the component (a3) include methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, n-propyl acrylate, n-propyl methacrylate, n-butyl acrylate, n-butyl methacrylate, n-hexadecyl acrylate, and n-hexa.
- the component (a3) is a (meth) acrylic acid alkyl ester monomer having a linear alkyl group having 1 to 11 carbon atoms, a (meth) acrylic acid alkyl ester monomer having a branched alkyl group, At least one selected from a (meth) acrylic acid ester monomer having an aromatic ring-containing group, a (meth) acrylic acid ester monomer having a heterocyclic ring-containing group, and a (meth) acrylate having an ether bond-containing group There may be.
- the component (a3) is a linear alkyl group having 1 to 11 carbon atoms in that the pressure-sensitive adhesive layer formed using the pressure-sensitive adhesive composition according to this embodiment is more excellent in durability. It is more preferable that they are (meth) acrylic-acid alkylester monomer which has these, and (meth) acrylic-acid alkylester which has an aromatic ring containing group, or any one.
- the (meth) acrylic acid alkyl ester monomer having a linear alkyl group having 1 to 11 carbon atoms is more preferably 1 to 9 carbon atoms in that durability can be further improved.
- n-butyl acrylate is preferable from the viewpoint of excellent balance of adhesive properties.
- content of the acrylic acid alkylester monomer which has a branched alkyl group is 4 mass% or less in the said monomer mixture, and 3 mass%. The following is more preferable.
- content of the acrylic acid alkyl ester monomer having a branched alkyl group exceeds 4% by mass in the monomer mixture, the increase in adhesive strength after heating may be large, and the reworkability may be reduced.
- the pressure-sensitive adhesive layer obtained using the pressure-sensitive adhesive composition according to this embodiment prevents light leakage.
- the content of the (meth) acrylic acid ester monomer having an aromatic ring-containing group in the monomer mixture is preferably 0% by mass or more and 25% by mass or less because it can be further reduced.
- the monomer mixture is a monomer other than the component (a1), the component (a2), and the component (a3), and one monomer in the molecule other than the acrylate monomer.
- a monomer having an olefinic double bond (hereinafter sometimes simply referred to as “component (a4)”) may further be included.
- the component (a4) is a monomer other than the components (a1), (a2) and (a3), and is a crosslinkable monomer having one olefinic double bond in the molecule. be able to.
- crosslinkable means that (B) includes a group capable of crosslinking by reacting with a crosslinking agent.
- a crosslinking agent examples include a hydroxyl group, an amino group, and a carboxyl group. , A carbonyl group, an aminocarbonyl group, and an epoxy group.
- Examples of the component (a4) include N, N-dimethylaminopropylacrylamide, N, N′-dimethylacrylamide, N, N′-diethylacrylamide, N, N′-dimethylaminoethylacrylamide, and N, N′-dimethyl.
- Amide monomers such as aminopropylacrylamide and N-isopropylacrylamide, nitrogen atom-containing acrylic monomers such as acryloylmorpholine, acrylamide, t-octyl (meth) acrylamide, diacetone acrylamide, acrylonitrile; acrylic acid, methacrylic acid
- Carboxyl group-containing (meth) acrylic acid ester monomers such as carboxyethyl acrylate: nitrogen-containing vinyl monomers such as vinylpyridine, N-vinylpyrrolidone, vinylcaprolactam, maleic acid, itaconic acid, etc.
- Carboxyl group-containing vinyl monomers, glycidyl (meth) acrylate is an epoxy group-containing monomer such as these, it is also possible to use these in combination of one or more kinds.
- the content of the component (a4) in the monomer mixture is preferably 0% by mass or more and 9% by mass or less, and more preferably 0% by mass or more and 8% by mass or less.
- the content of the monomer containing a carboxyl group in the monomer mixture is 1% by mass from the viewpoint that corrosion of the adherend can be prevented. The following is preferable.
- Component (a5) The monomer mixture is a monomer other than the components (a1), (a2), (a3), and (a4), and is a crosslinkable monomer (hereinafter simply referred to as “ (A5) may also be described as “component”).
- the component (a5) examples include styrene monomers such as styrene, ⁇ -methylstyrene, o-methylstyrene, p-methylstyrene, vinyl esters such as vinyl acetate, vinyl (meth) acryloyl group-containing macromonomers, and the like. Of these, one or a combination of two or more may be used.
- the content of the component (a5) in the monomer mixture is preferably 0% by mass or more and 5% by mass or less from the viewpoint that the reworkability is not impaired.
- the carboxyl group-containing monomer in the monomer mixture can be prevented from corroding a member (for example, an ITO layer) constituting an apparatus including the pressure-sensitive adhesive layer obtained from the pressure-sensitive adhesive composition according to this embodiment.
- the content is preferably 1% by mass or less.
- the total amount of component (a1), component (a2) and component (a3) can be 90% by mass or more and 100% by mass or less, and more preferably 95% by mass or more and 100% by mass or less.
- the content of the carboxyl group-containing monomer in the monomer mixture is preferably 1% by mass or less.
- the polymerization method of component (A) is not particularly limited and can be polymerized by known methods such as solution polymerization, emulsion polymerization, suspension polymerization, etc. In producing the pressure-sensitive adhesive composition of the present invention using a mixture of coalesces, it is preferable to perform polymerization by solution polymerization from the viewpoint that the treatment process is relatively simple and can be performed in a short time.
- solution polymerization generally, a predetermined organic solvent, each monomer, a polymerization initiator, and a chain transfer agent used as necessary are charged in a polymerization tank, under a nitrogen stream or a reflux temperature of the organic solvent, The reaction is carried out by heating for several hours with stirring.
- the organic solvent include aromatic hydrocarbons such as benzene, toluene, ethylbenzene, n-propylbenzene, t-butylbenzene, o-xylene, m-xylene, p-xylene, tetralin, decalin, aromatic naphtha;
- aromatic hydrocarbons such as benzene, toluene, ethylbenzene, n-propylbenzene, t-butylbenzene, o-xylene, m-xylene, p-xylene, tetralin, decalin, aromatic naphtha
- aliphatic or alicyclic hydrocarbons such as n-hexane, n-heptane, n-octane, i-octane, n-decane, dipentene, petroleum spirit, petroleum naphtha, turpentine oil
- Esters such as
- Ketones for example, ethylene glycol monomer And the like; ethers, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, glycol ethers such as diethylene glycol monobutyl ether.
- organic solvents can be used alone or in admixture of two or more.
- component (A) in the polymerization of component (A), it is preferable to use, for example, esters and ketones.
- esters and ketones In particular, from the viewpoints of solubility of component (A), ease of polymerization reaction, etc.
- Use of ethyl acetate, methyl ethyl ketone, acetone or the like is preferable.
- organic peroxides and azo compounds that can be used in ordinary solution polymerization.
- organic peroxides include t-butyl hydroperoxide, cumene hydroperoxide, dicumyl peroxide, benzoyl peroxide, lauroyl peroxide, caproyl peroxide, and di-i-propyl peroxide.
- polymerization initiators that do not cause a graft reaction during the polymerization reaction of component (A) are preferable, and azo-based compounds are particularly preferable.
- the amount used is usually 0.01 parts by mass or more and 2 parts by mass or less, and preferably 0.1 parts by mass or more and 1.0 parts by mass or less with respect to 100 parts by mass in total of the monomer mixture.
- the component (A) contained in the pressure-sensitive adhesive composition according to this embodiment it is normal not to use a chain transfer agent, but as long as the purpose and effect of the present invention are not impaired. It is possible to use it accordingly.
- chain transfer agents examples include cyanoacetic acid; alkyl esters having 1 to 8 carbon atoms of cyanoacetic acid; bromoacetic acid; alkyl esters having 1 to 8 carbon atoms of bromoacetic acid; anthracene, phenanthrene, and fluorene.
- Aromatic compounds such as 9-phenylfluorene; aromatic nitro compounds such as p-nitroaniline, nitrobenzene, dinitrobenzene, p-nitrobenzoic acid, p-nitrophenol and p-nitrotoluene; benzoquinone, 2,3, Benzoquinone derivatives such as 5,6-tetramethyl-p-benzoquinone; borane derivatives such as tributylborane; carbon tetrabromide, carbon tetrachloride, 1,1,2,2-tetrabromoethane, tribromoethylene, trichloroethylene, Bromotrichloromethane, tribromomethane, 3- Halogenated hydrocarbons such as lolo-1-propene; Aldehydes such as chloral and furaldehyde: Alkyl mercaptans having 1 to 18 carbon atoms; Aromatic mercaptans such as thiophenol and toluene mercaptan; Mercapto
- the polymerization temperature of the component (A) is generally about 30 ° C. or higher and 180 ° C. or lower, preferably 40 ° C. or higher and 150 ° C. or lower, more preferably 50 ° C. or higher and 90 ° C. or lower.
- an unreacted monomer is contained in a polymer obtained by a solution polymerization method or the like, it can be purified by a reprecipitation method using methanol or the like in order to remove the monomer.
- crosslinking agent as the component (B) is not particularly limited as long as the crosslinking agent as the component (B) is a crosslinking agent capable of crosslinking with the component (A) at room temperature or under heating.
- examples thereof include an isocyanate-based crosslinking agent, an epoxy-based crosslinking agent, and a metal chelate-crosslinking agent, and among these, an isocyanate-based crosslinking agent is preferable.
- isocyanate-based crosslinking agent examples include xylylene diisocyanate, tolylene diisocyanate, chlorophenylene diisocyanate, hexamethylene diisocyanate, tetramethylene diisocyanate, isophorone diisocyanate, diphenylmethane diisocyanate, hydrogenated diphenylmethane diisocyanate, and the like, Illustrative are isocyanate compounds and isocyanurates obtained by subjecting these to addition reaction with bivalent or higher alcohol compounds such as trimethylolpropane.
- Specific examples of the epoxy-based crosslinking agent include N, N ′-[1,3-phenylenebis (methylene)] bis [bis (oxiran-2-ylmethyl) amine].
- urethane prepolymer type isocyanates obtained by addition reaction of isocyanate compounds with known polyether polyols, polyester polyols, acrylic polyols, polybutadiene polyols, polyisoprene polyols, and the like can be mentioned. Of these, xylylene diisocyanate and its derivatives are preferably used.
- an isocyanate type crosslinking agent and an epoxy crosslinking agent can also be used together.
- the content of the component (B) in the pressure-sensitive adhesive composition according to this embodiment is that 100 parts by mass of the pressure-sensitive adhesive composition according to this embodiment is capable of imparting appropriate pressure-sensitive adhesive strength and enhancing durability. Is preferably 0.01 part by mass or more and 5 parts by mass or less, and more preferably 0.02 part by mass or more and 0.5 part by mass or less.
- the pressure-sensitive adhesive composition for an optical film according to this embodiment includes (C) a silane coupling agent (hereinafter sometimes simply referred to as “component (C)”).
- component (C) a silane coupling agent
- a hydroxyl group (hydroxyl group) contained in the component (A) and a functional group (for example, hydroxyl group (hydroxyl group)) in the component (C) are hydroxyl groups present on the glass surface.
- a bond can be formed with (hydroxyl group) to enhance durability.
- Component (C) is, for example, a polymerizable unsaturated group-containing silicon compound such as vinyltrimethoxysilane, vinyltriethoxysilane, and methacryloxypropyltrimethoxysilane; 3-glycidoxypropyltrimethoxysilane, 3-glycidoxypropyl Silicon compounds having an epoxy structure such as methyldimethoxysilane and 2- (3,4-epoxycyclohexyl) ethyltrimethoxysilane; 3-aminopropyltrimethoxysilane, N- (2-aminoethyl) 3-aminopropyltrimethoxysilane And amino group-containing silicon compounds such as N- (2-aminoethyl) -3-aminopropylmethyldimethoxysilane; and 3-chloropropyltrimethoxysilane; oligomer-type silane coupling agents, etc. Meta) acrylic Silane coupling agents having a functional group reactive
- the content of the component (C) in the optical film pressure-sensitive adhesive composition according to the present embodiment is 0. 0 parts by mass with respect to 100 parts by mass of the component (A) from the viewpoint of maintaining good adhesion to the adherend. It can be from 05 parts by mass to 0.5 parts by mass, and preferably from 0.08 parts by mass to 0.3 parts by mass.
- the adhesive composition for optical films which concerns on this embodiment can further contain components other than (A) component, (B) component, and (C) component as needed.
- the pressure-sensitive adhesive composition according to the present embodiment includes (D) an ionic compound (hereinafter sometimes simply referred to as “component (D)”), oxidation within a range that does not impair the effects of the present invention.
- component (D) an ionic compound
- An inhibitor, an ultraviolet absorber, a tackifier, a plasticizer, and the like may be blended.
- the pressure-sensitive adhesive composition according to the present embodiment contains the component (D)
- the pressure-sensitive adhesive layer is formed on the surface of the adherend using the pressure-sensitive adhesive composition according to the present embodiment, charging of the adherend is performed. Can be effectively prevented.
- an ionic compound that is liquid or solid at 25 ° C. composed of an anion and a cation can be mentioned.
- an alkali metal salt, an onium salt, a surfactant, etc. can be mentioned.
- alkali metal salt examples include compounds comprising an alkali metal cation such as lithium, sodium and potassium and an anion.
- Examples of the cation constituting the onium salt include organic oniums in which onium ions are formed by substitution with an organic group or the like.
- Examples of the organic group in the organic onium include an alkyl group, an alkoxyl group, and an alkenyl group. Among these, in order to suppress the polarizer deterioration, those having no unsaturated bond are preferable.
- the number of carbon atoms of the alkyl group can be selected from 1 to 12, for example.
- the alkyl group can be linear or branched, but is preferably linear.
- the organic onium has a cyclic structure, the onium preferably has a 5-membered or 6-membered ring, and the other substituent is preferably an alkyl group having 1 to 12 carbon atoms.
- the onium is not particularly limited, and examples thereof include nitrogen-containing onium, sulfur-containing onium, and phosphorus-containing onium. Of these, nitrogen-containing onium and sulfur-containing onium are preferred.
- Nitrogen-containing onium includes pyridinium cation, piperidinium cation, pyrrolidinium cation, cation having pyrroline skeleton, cation having pyrrole skeleton, imidazolium cation, tetrahydropyrimidinium cation, dihydropyrimidinium cation, pyrazolium Cations, pyrazolinium cations, tetraalkylammonium cations and the like can be mentioned.
- a tetraalkylammonium cation and an alkylpyridinium cation are preferable from the viewpoint of compatibility with the component (A).
- sulfur-containing onium examples include a sulfonium cation.
- phosphorus-containing phosphonium examples include phosphonium cations.
- the onium salt a compound comprising a combination of the onium component and the anion component is appropriately selected and used, and at least one selected from a nitrogen-containing onium salt, a sulfur-containing onium salt and a phosphorus-containing onium salt is used. Preferably used. Furthermore, at least one selected from ammonium salts and pyridinium salts is preferably used.
- 2-methyl-1-pyrroline tetrafluoroborate 1-ethyl-2-phenylindole tetrafluoroborate, 1,2-dimethylindole tetrafluoroborate, 1-ethylcarbazole tetrafluoroborate, 1-ethyl- 3-methylimidazolium tetrafluoroborate, 1-ethyl-3-methylimidazolium acetate, 1-ethyl-3-methylimidazolium trifluoroacetate, 1-ethyl-3-methylimidazolium heptafluorobutyrate, 1-ethyl -3-Methylimidazolium trifluoromethanesulfonate, 1-ethyl-3-methylimidazolium perfluorobutanesulfonate, 1-ethyl-3-methylimidazolium dicyanamide, 1-ethyl-3-methylimidazolium Bis (trifluoromethanesulfon
- any of nonionic surfactants, cationic surfactants, anionic surfactants and amphoteric surfactants can be used.
- nonionic surfactant examples include polyoxyethylene alkyl ethers such as polyoxyethylene lauryl ether and polyoxyethylene stearyl ether, polyoxyethylene alkylphenyls such as polyoxyethylene octylphenyl ether and polyoxyethylene nonielphenyl ether.
- Sorbitan higher fatty acid esters such as ethers, sorbitan monolaurate, sorbitan monostearate, sorbitan trioleate, polyoxyethylene sorbitan higher fatty acid esters such as polyoxyethylene sorbitan monolaurate, polyoxyethylene monolaurate, poly Polyoxyethylene higher fatty acid esters such as oxyethylene monostearate; for example, oleic acid monoglyceride, stearic acid monoglyceride Glycerine higher fatty acid esters such as id, polyoxyethylene, polyoxypropylene, polyoxyalkylenes and their block copolymers such as polyoxyethylene butylene.
- cationic surfactant examples include alkyltrimethylammonium chloride, dialkyldimethylammonium chloride, benzalkonium chloride, alkyldimethylammonium ethosulphate and the like.
- anionic surfactant examples include sodium laurate, sodium oleate, N-acyl-N-methylglycine sodium salt, sodium carboxylate such as sodium polyoxyethylene lauryl ether carboxylate, sodium dodecylbenzenesulfonate, dialkylsulfosuccinate.
- amphoteric surfactant examples include carboxybetaine surfactants, aminocarboxylates, imidazolinium petines, lecithins, and alkylamine oxides.
- conductive polymers, conductive carbon, ammonium chloride, aluminum chloride, copper chloride, iron chloride, ammonium sulfate, and the like can be used.
- Content of (D) component in the adhesive composition for optical films which concerns on this embodiment is 0.1 to 5 mass parts with respect to 100 mass parts of (A) component which concerns on this embodiment. It is preferable that it is 0.5 mass part or more and 3 mass parts or less.
- the pressure-sensitive adhesive composition for an optical film can ensure appropriate pressure-sensitive adhesive strength, durability, and storage stability, can prevent the separation of components in the composition, and can be used to prepare the composition.
- the silicone oil content is 0.1% by mass or less, preferably 0.08% by mass or less, and more preferably 0.05% by mass or less in that it becomes easier.
- the pressure-sensitive adhesive composition according to the present embodiment usually comprises the component (A), the component (B) and the component (C), and optional components at the same time or in any order. Prepared by mixing. In mixing the component (A) and the component (B), when the component (A) is prepared by solution polymerization, the solution containing the component (A) after completion of the polymerization is added to the component (B), (C) Components and optional components may be added. When the component (A) is prepared by bulk polymerization, uniform mixing becomes difficult after completion of the polymerization. Therefore, during the polymerization, the components (B) and (C) It is preferable to add and mix arbitrary components.
- the (A) (meth) acrylic polymer which is a copolymer of a monomer mixture containing the component (a1) and the component (a2). And (B) a crosslinking agent and (C) a silane coupling agent, thereby imparting excellent durability and reworkability to the pressure-sensitive adhesive layer obtained by using the pressure-sensitive adhesive composition. .
- the polarity of the (A) (meth) acrylic polymer is reduced due to the linear alkyl group having 12 to 18 carbon atoms constituting the component (a1). Therefore, for example, since the wettability with an adherend having a relatively high surface polarity (for example, TAC, polycarbonate, acrylic resin, etc. used in a polarizing plate) can be reduced, the rework of the pressure-sensitive adhesive layer can be performed. Can increase the sex.
- a relatively high surface polarity for example, TAC, polycarbonate, acrylic resin, etc. used in a polarizing plate
- the molecular weight of the (A) (meth) acrylic polymer is 1,000,000 or more. Therefore, durability of the adhesive layer obtained using this adhesive composition can be improved.
- the pressure-sensitive adhesive composition according to this embodiment can be suitably used as an adhesive for optical films (details will be described later).
- the image display device includes a retardation film
- the pressure-sensitive adhesive composition according to this embodiment is provided between the retardation film and the polarizing film.
- a pressure-sensitive adhesive layer using can be provided.
- the pressure-sensitive adhesive composition according to this embodiment when used for bonding an adherend such as a liquid crystal cell and an optical film such as a polarizing film, excellent reworkability and high durability can be realized. Therefore, high image quality of the image display device can be achieved.
- the adherend including the thinned liquid crystal cell and the optical film are bonded together via the pressure-sensitive adhesive layer obtained using the pressure-sensitive adhesive composition according to the present embodiment, foreign matters and bubbles are present at the interface. Even if the bonding fails due to mixing, the optical film can be easily peeled off from the adherend without damaging the adherend.
- the glass constituting the liquid crystal cell when the glass constituting the liquid crystal cell is thinned (for example, a glass substrate having a film thickness of 500 ⁇ m or less (for example, 100 ⁇ m or more and 500 ⁇ m or less)), it was obtained using the pressure-sensitive adhesive composition according to this embodiment. Since the pressure-sensitive adhesive layer is excellent in reworkability, the pressure-sensitive adhesive layer can be easily peeled off without damaging the adherend.
- the pressure-sensitive adhesive composition according to the present embodiment can be used as an adhesive having a VA mode polarizing film, a TN mode polarizing film, or an IPS mode polarizing film as an adherend.
- Adhesive Optical Film An adhesive optical film according to an embodiment of the present invention is provided with an adhesive layer obtained by using the optical film adhesive composition according to the above embodiment on one or both surfaces of the optical film. .
- the pressure-sensitive adhesive layer is formed by applying the pressure-sensitive adhesive composition on the optical film with a gravure coater, Mayer bar coater, air knife coater, roll coater, or the like. It may be formed by drying and crosslinking the pressure-sensitive adhesive composition applied thereon at room temperature or by heating, or by forming a pressure-sensitive adhesive layer on a release film and transferring it to the optical film. Good.
- the thickness of the pressure-sensitive adhesive layer is usually 1 ⁇ m or more and 50 ⁇ m or less, and preferably about 5 ⁇ m or more and 30 ⁇ m or less.
- Examples of the pressure-sensitive adhesive optical film according to the present embodiment include those used in image display devices such as FPD, such as a polarizing film, a retardation film, an elliptically polarizing film, an antireflection film, a brightness enhancement film, and the like. It can be an optical film selected from the group consisting of light diffusing films. The thickness of the optical film can be appropriately selected according to the purpose of use, but is usually from 10 ⁇ m to 500 ⁇ m, and preferably from about 15 ⁇ m to 300 ⁇ m.
- the laminated body which concerns on one Embodiment of this invention is the adhesive composition for optical films which concerns on the said embodiment provided between the glass substrate, the polarizing plate, and the said glass substrate and the said polarizing plate. And a pressure-sensitive adhesive layer (pressure-sensitive adhesive sheet) obtained by molding into a film and heating.
- FIG. 1 is a cross-sectional view schematically showing an example (laminated body 100) of a laminated body according to an embodiment of the present invention.
- the laminated body 100 contains the glass substrate 10, the polarizing film 30, and the adhesive layer 20 provided between the glass substrate 10 and the polarizing film 30, as FIG. 1 shows.
- the laminate 100 includes a glass substrate 10, a pressure-sensitive adhesive layer 20 provided on the glass substrate 10, and a polarizing film 30 provided on the glass substrate 10 via the pressure-sensitive adhesive layer 20. Including. The glass substrate 10 and the polarizing film 30 are bonded via the pressure-sensitive adhesive layer 20.
- the pressure-sensitive adhesive layer 20 is formed on the surface of an adherend (glass substrate 10).
- an adherend glass substrate 10
- the transfer method which transfers the said coating film to the surface of a specific resin film can be mentioned.
- the laminate according to this embodiment is included in, for example, an image display device (particularly a liquid crystal display device).
- the glass substrate included in the laminate according to the present embodiment is a glass substrate for a liquid crystal display device.
- the glass substrate which comprises the laminated body which concerns on this embodiment can be a glass substrate used for image display apparatuses.
- the image display device can be, for example, a TFT (thin film transistor) liquid crystal display device used for liquid crystal televisions, computer monitors, mobile phones, tablets, and the like.
- the laminate according to the present embodiment is a glass substrate, a polarizing film, and the optical film pressure-sensitive adhesive composition according to the embodiment, which is provided between the glass substrate and the polarizing film. It is excellent in durability by including an adhesive layer obtained by molding, heating and drying appropriately.
- the adhesive processed polarizing plates for evaluation were evaluated by the following methods for the adhesive strength, post-heating adhesive strength, adherend contamination after peeling, heat resistance, and moist heat resistance shown in Tables 3 and 4 below. Moreover, the gel fraction was measured with the method described in the above-mentioned embodiment about the solution of the adhesive composition of Examples 1-20 and Comparative Examples 1-8.
- the evaluation-use pressure-sensitive adhesive polarizing plate produced in 4.2 is cut into a width of 25 mm and a length of 70 mm and bonded onto alkali-treated glass to obtain a test piece. After pressure bonding with a 2 kg roller, it is left to stand for 2 hours in an atmosphere of 23 ° C./50% RH. Next, the test piece is set in a tensile tester (manufactured by Shimadzu Corporation). The pressure-sensitive adhesive polarizing plate is peeled from the alkali-treated glass at a peeling angle of 90 ° and a peeling speed of 300 mm / min. The numerical value at this time is defined as adhesive strength.
- Adhesive strength after heating After sticking on alkali-treated glass to obtain a test piece, it was autoclaved at 50 ° C., 5 atm, 20 minutes, further heat-treated at 60 ° C. for 2 hours, and then allowed to stand in a 23 ° C./50% RH atmosphere for 2 hours. Other than the measurement after placing, the method is the same as the adhesive strength.
- AA acrylic acid
- BA n-butyl acrylate
- BzA benzyl acrylate
- 2-EHA 2-ethylhexyl acrylate
- 2-HEA 2-hydroxyethyl acrylate
- LA lauryl acrylate
- 4-HBA 4-hydroxybutyl acrylate
- INA isononyl acrylate ( Osaka Organic Chemical Industry Co., Ltd.)
- ISA Isostearyl acrylate SA: Stearyl acrylate (manufactured by Osaka Organic Chemical Industry Co., Ltd.)
- E-AX N, N ′-[1,3-phenylenebis (methylene)] bis [bis (oxiran-2-ylmethyl) amine] (epoxy crosslinking agent, manufactured by Soken Chemical Co., Ltd.)
- KBM-403 3-glycidoxypropyltrimethoxysilane (silane coupling agent, manufactured by Shin-Etsu Chemical Co.
- compositions of Examples 1 to 20 are copolymers of monomer mixtures containing the component (a1), the component (a2) and the component (a3).
- the (A) (meth) acrylic polymer By including the (A) (meth) acrylic polymer, it is possible to obtain a pressure-sensitive adhesive layer excellent in reworkability (in particular, reworkability after heating) and durability (heat resistance and heat-and-moisture resistance). Understandable.
- the pressure-sensitive adhesive layer obtained using the composition can be understood to be inferior in reworkability (in particular, reworkability after heating).
- composition of the comparative example 5 used a copolymer of a monomer mixture in which the proportion of the component (a1) exceeded 30% by mass, the polymerization rate was lowered, and the copolymer was unreacted. Therefore, it can be understood that the adherend after peeling is contaminated.
- Comparative Example 6 used a copolymer having a weight average molecular weight of less than 1,000,000, the cohesiveness was inferior, and the wettability between the adherend interface and the low molecular region in the copolymer was remarkably high. It rises and it can be understood that the adherend after peeling is contaminated.
- composition of Comparative Example 7 does not contain the component (C), it can be understood that the adhesion with the adherend becomes insufficient and the heat and humidity resistance is lowered.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Adhesive Tapes (AREA)
- Polarising Elements (AREA)
- Surface Treatment Of Optical Elements (AREA)
Abstract
Description
(A)重量平均分子量が100万以上である(メタ)アクリル系ポリマーと、
(B)架橋剤と、
(C)シランカップリング剤と、を含み、
前記(A)(メタ)アクリル系ポリマーは、
(a1)成分:炭素数12以上18以下の直鎖状アルキル基を有するアクリル酸アルキルエステル単量体1質量%以上30質量%以下と、
(a2)成分:ヒドロキシル基を有する単量体0.1質量%以上10質量%以下と、
(a3)成分:前記(a1)成分および前記(a2)成分以外の単量体であって、非架橋性(メタ)アクリル酸エステル単量体60質量%以上98.9質量%以下と、を含む単量体混合物の共重合体である。
本発明の一実施形態に係る光学フィルム用粘着剤組成物(以下、単に「粘着剤組成物」と記載する場合もある。)は、(メタ)アクリル系ポリマー(A)(以下、単に「(A)成分」と記載する場合もある。)と、(B)架橋剤(以下、単に「(B)成分」と記載する場合もある。)と、(C)シランカップリング剤(以下、単に「(C)成分」と記載する場合もある。)と、を含む。
(A)成分は、重量平均分子量が100万以上である(A)(メタ)アクリル系ポリマーである。(A)成分は、(a1)成分:炭素数12以上18以下の直鎖状アルキル基を有するアクリル酸アルキルエステル単量体1質量%以上30質量%以下と、(a2)成分:ヒドロキシル基を有する単量体0.1質量%以上10質量%以下と、(a3)成分:前記(a1)成分および前記(a2)成分以外の単量体であって、非架橋性(メタ)アクリル酸エステル単量体60質量%以上98.9質量%以下と、を含む単量体混合物の共重合体である。
耐久性をより高めることができる点で、(A)成分の重量平均分子量は通常100万以上200万以下であり、110万以上であることがより好ましい。ここで、(A)成分の重量平均分子量は、GPC(ゲルパーミエーションクロマトグラフィー)を用い、下記の条件で標準ポリスチレン換算による重量平均分子量(Mw)を求めたものである。
測定装置:HLC-8120GPC(東ソー社製)
GPCカラム構成:以下の5連カラム(すべて東ソー社製)
(1)TSK-GEL HXL-H (ガードカラム)
(2)TSK-GEL G7000HXL
(3)TSK-GEL GMHXL
(4)TSK-GEL GMHXL
(5)TSK-GEL G2500HXL
サンプル濃度:1.0mg/cm3となるように、テトラヒドロフランで希釈
移動相溶媒:テトラヒドロフラン
流量:1.0cm3/分(min)
カラム温度:40℃
耐久性およびリワーク性をより高めることができる点で、(A)成分は、前記(A)(メタ)アクリル系ポリマーのTgが0℃以下であることが好ましく、-20℃以下であることがより好ましい(通常、-80℃以上である)。本発明において、(A)成分のTgは、下記式(1)(FOXの式)により算出された値である。
(式中、TgAは、(A)成分のガラス転移温度(K)を示し、Tga1,Tga2,Tga3,Tga4,Tga5はそれぞれ、(a1)成分,(a2)成分,(a3)成分,(a4)成分および(a5)成分から調製されたホモポリマーのガラス転移温度(Tg(K))を示し、Wa1,Wa2,Wa3,Wa4,Wa5はそれぞれ、(A)成分中に含まれる、(a1)成分,(a2)成分,(a3)成分,(a4)成分,(a5)成分の重量分率を示す。)
なお、上記式(1)により、TgAは、絶対温度(K)として算出されるので、必要に応じて摂氏温度(℃)に換算される。
本実施形態に係る粘着剤組成物における(A)成分の含有量は、本実施形態に係る粘着剤組成物100質量部に対して80質量部以上99.9質量部以下であることができ、90質量部以上99.9質量部以下であることが好ましい。
本実施形態に係る光学用粘着剤組成物を用いて得られる粘着剤層の被着体との粘着力を高めることができる観点から、本実施形態に係る光学用粘着剤組成物のゲル分率が40%以上93%以下であることが好ましく、40%以上であることがより好ましく、50%以上であることがさらに好ましく、一方、85%以下であることがより好ましく、80%以下であることがさらに好ましい。
ゲル分率(%)=(乾燥重量2)/(乾燥重量1)×100 ・・・(2)
本実施形態に係る光学用粘着剤組成物を用いて、以下で規定される、加熱後のリワーク性を有する粘着剤層を得ることができる。加熱後のリワーク性が良好であることは、本実施形態に係る光学用粘着剤組成物の特徴のひとつである。
1.1.6-1.(a1)成分
(a1)成分は、耐久性および加熱後のリワーク性の向上に寄与する。耐久性および加熱後のリワーク性をより高めることができる点で、(a1)成分は1質量%以上30質量%以下であることが好ましく、2質量%以上であることがより好ましく、3質量%以上であることがさらに好ましく、一方、28質量%以下であることが好ましく、26質量%以下であることがより好ましく、24質量%以下であることがさらに好ましい。(a1)成分が30質量%を超えると、重合率が低下し、共重合体中に未反応の残留単量体が多く含まれることになり、被着体汚染性が不良となるため好ましくない。
(a2)成分は、(B)成分との架橋に寄与することができる。より具体的には、(a2)成分に含まれる水酸基(ヒドロキシル基)が(B)成分中のイソシアナート基と反応することにより、架橋構造を形成することができる。
前記単量体混合物は、(a1)成分および(a2)成分以外の単量体であって、非架橋性(メタ)アクリル酸エステル単量体(以下、単に「(a3)成分」と記載する場合もある。)をさらに含む。本発明において、「非架橋性」とは、(B)架橋剤と反応して架橋し得る官能基を有さないことをいう。したがって、非架橋性(メタ)アクリル酸エステル単量体は例えば、(B)架橋剤と反応して架橋し得る官能基を含まない(メタ)アクリル酸エステル単量体である。
t-ブチルアクリレート、t-ブチルメタクリレート、イソプロピルアクリレート、イソプロピルメタクリレート、イソブチルアクリレート、イソブチルメタクリレート、2-エチルヘキシルアクリレート、2-エチルヘキシルメタクリレート、イソノニルアクリレート、イソノニルメタクリレート、イソステアリルアクリレート、イソステアリルメタクリレート等の分岐状アルキル基を有する(メタ)アクリル酸アルキルエステル単量体;
シクロヘキシルアクリレート、シクロヘキシルメタクリレート、イソボルニルアクリレート、イソボルニルメタクリレート、ジシクロペンタニルアクリレート等の脂環基を有する(メタ)アクリル酸エステル単量体;
ベンジルアクリレート、ベンジルメタクリレート、2-ナフチルアクリレート、ペンタメチルピペリジンメタクリレート、2-フェノキシエチルアクリレート等の芳香環または複素環含有基を有する(メタ)アクリル酸エステル単量体;
メトキシエチル(メタ)アクリレート、エトキシメチル(メタ)アクリレート、ジシクロペンテニルオキシエチル(メタ)アクリレート、テトラヒドロフルフリルメタクリレート等のエーテル結合含有基を有する(メタ)アクリレートが挙げられ、このうち1種を単独でまたは2種以上を組み合わせて使用することができる。
前記単量体混合物は、(a1)成分、(a2)成分、および(a3)成分以外の単量体であって、アクリル酸エステル単量体以外の、分子内に1個のオレフィン性二重結合を有する単量体(以下、単に「(a4)成分」と記載する場合もある。)をさらに含むことができる。
前記単量体混合物は、(a1)成分、(a2)成分、(a3)成分、および(a4)成分以外の単量体であって、架橋性単量体(以下、単に「(a5)成分」と記載する場合もある。)をさらに含むことができる。
本実施形態に係る粘着剤組成物では、耐久性およびリワーク性を確保できる点で、前記単量体混合物中における前記(a1)成分、(a2)成分、および(a3)成分の合計量が90質量%以上100質量%以下であることができ、95質量%以上100質量%以下であることがより好ましい。
(A)成分の重合方法は、特に制限されるものではなく、溶液重合、乳化重合、懸濁重合などの公知の方法により重合できるが、重合により得られた共重合体の混合物を用いて、本発明の粘着剤組成物を製造するにあたり、処理工程が比較的簡単でかつ短時間で行える観点から、溶液重合により重合することが好ましい。
(B)成分である架橋剤としては、例えば、(B)成分である架橋剤は、常温又は加熱下で(A)成分と架橋し得る架橋剤であれば特に限定されないが、例えば、イソシアネート系架橋剤、エポキシ系架橋剤、金属キレ―ト架橋剤が挙げられ、このうち、イソシアネート系架橋剤が好ましい。
本実施形態に係る光学フィルム用粘着剤組成物が(C)シランカップリング剤(以下、単に「(C)成分」と記載することもある。)を含むことにより、本実施形態に係る光学フィルム用粘着剤組成物を用いて被着体の表面に粘着剤層を形成した場合、被着体との接着を良好に保つことができる。
本実施形態に係る光学フィルム用粘着剤組成物は、必要に応じて、(A)成分、(B)成分、および(C)成分以外の成分をさらに含むことができる。例えば、本実施形態に係る粘着剤組成物には、本発明の効果を損なわない範囲で、(D)イオン性化合物(以下、単に「(D)成分」と記載する場合もある。)、酸化防止剤、紫外線吸収剤、粘着付与剤、可塑剤等が配合されていても良い。
本実施形態に係る粘着剤組成物は、通常、前記(A)成分、(B)成分および(C)成分、ならびに必要に応じて任意成分を、同時にあるいは任意の順番で混合して調製される。また、(A)成分と(B)成分とを混合するにあたり、(A)成分を溶液重合により調製した場合は、重合完了後の(A)成分を含む溶液に(B)成分、(C)成分、任意成分を添加してもよく、(A)成分を塊状重合により調製する場合は、重合完了後では均一混合が困難になるため、この重合の途中で(B)成分、(C)成分、任意成分を添加して混合することが好ましい。
本実施形態に係る粘着剤組成物によれば、上記(a1)成分および上記(a2)成分を含む単量体混合物の共重合体である前記(A)(メタ)アクリル系ポリマーと、(B)架橋剤と、(C)シランカップリング剤とを含むことにより、該粘着剤組成物を用いて得られる粘着剤層に、優れた耐久性およびリワーク性を付与することができる。
本発明の一実施形態に係る粘着型光学フィルムは、上記実施形態に係る光学フィルム用粘着剤組成物を用いて得られた粘着剤層を、光学フィルムの片面または両面に設える。
本発明の一実施形態に係る積層体は、ガラス基板と、偏光板と、前記ガラス基板と前記偏光板との間に設けられた、上記実施形態に係る光学フィルム用粘着剤組成物を膜状に成形し、加熱して得られる粘着剤層(粘着シート)と、を含む。
図1は、本発明の一実施形態に係る積層体の一例(積層体100)を模式的に示す断面図である。積層体100は、図1に示されるように、ガラス基板10と、偏光フィルム30と、ガラス基板10と偏光フィルム30との間に設けられた粘着剤層20と、を含む。
本実施形態に係る積層体を構成するガラス基板は、画像表示装置用に用いられるガラス基板であることができる。画像表示装置としては、例えば、液晶テレビ、コンピュータのモニタ、携帯電話、タブレットなどに用いられるTFT(薄膜トランジスタ)液晶表示装置であることができる。
本実施形態に係る積層体は、ガラス基板と、偏光フィルムと、前記ガラス基板と前記偏光フィルムとの間に設けられた、上記実施形態に係る光学フィルム用粘着剤組成物を膜状に成形し、適宜加熱、乾燥して得られる粘着剤層と、を含むことにより、耐久性に優れている。
以下、本発明を下記実施例に基づいて説明するが、本発明は実施例に限定されない。
攪拌機、還流冷却器、温度計および窒素導入管を備えた反応装置に、下記表2に示す配合比率を有する単量体混合物を仕込み、次に、酢酸エチルをモノマー濃度が50質量%になる配合量にて仕込んだ。次に、アゾビスイソブチロニトリル0.1質量部を加え、反応容器内の空気を窒素ガスで置換しながら撹拌を行い60℃に昇温した後、4時間反応させた。反応終了後、酢酸エチルで希釈して、表2に示す(メタ)アクリル系ポリマーA~Pを得た。
上記4.1.で得られた(A)成分を用いて、下記表3および表4の配合(固形分配合)にて各成分を添加して、実施例1ないし20および比較例1ないし8の粘着剤組成物の溶液を得た。この粘着剤組成物の溶液を剥離処理したポリエステルフィルムの表面に塗布して乾燥させることにより、厚さ25μmの粘着剤層を有する粘着シートを得た。この粘着シートを偏光フィルムの片面に貼り付けた後、23℃/50%RHの条件で暗所にて7日間熟成させて、評価用粘着加工偏光板を得た。
4.3.1.粘着力(リワーク性)
上記4.2で作製された評価用粘着加工偏光板を、幅25mm×長さ70mmにカットし、アルカリ処理ガラス上に貼り合わせて試験片とする。2kgローラーにて圧着後、23℃/50%RH雰囲気下で2時間静置する。次に、前記試験片を、引っ張り試験機(島津製作所製)にセットする。剥離角度90°、剥離速度300mm/分にて、粘着加工偏光板をアルカリ処理ガラスより剥離する。このときの数値を粘着力とする。
アルカリ処理ガラス上に貼り合わせて試験片を得た後、50℃、5atm、20分オートクレーブ処理し、さらに60℃×2時間加熱処理をした後、23℃/50%RH雰囲気下で2時間静置した後に測定する他は、粘着力と同じ方法で行う。
加熱後粘着力測定後の被着体表面への汚染性を目視にて判断した。判断基準は以下の通りである。
(基準)
○:被着体への糊残り、曇りなし
△:被着体への糊残り、曇り 僅かに有り
×:被着体への糊残り、曇り有り
19インチサイズの無アルカリ処理ガラスに、上記4.2で作製された評価用粘着加工偏光板を貼り合わせて、80℃の環境下に500時間静置した後、剥がれ・発泡等の外観変化を目視で確認した。判断基準は以下の通りである。
(基準)
○:発泡、亀裂、剥がれ等の外観欠陥無し
△:実用上問題にならないサイズの発泡、亀裂、剥がれ等の外観欠陥有り
×:発泡、亀裂、剥がれ等の外観欠陥有り
19インチサイズの無アルカリ処理ガラスに、上記4.2で作製された評価用粘着加工偏光板を貼り合わせて、60℃/90%RHの環境下に500時間静置した後、剥がれ・発泡等の外観変化を目視で確認した。判断基準は以下の通りである。
(基準)
○:発泡、亀裂、剥がれ等の外観欠陥無し
△:実用上問題にならないサイズの発泡、亀裂、剥がれ等の外観欠陥有り
×:発泡、亀裂、剥がれ等の外観欠陥有り
AA:アクリル酸
BA:n-ブチルアクリレート
BzA:ベンジルアクリレート
2-EHA:2-エチルヘキシルアクリレート
2-HEA:2-ヒドロキシエチルアクリレート
LA:ラウリルアクリレート
4-HBA:4-ヒドロキシブチルアクリレート
INA:イソノニルアクリレート(大阪有機化学工業(株)製)
ISA:イソステアリルアクリレート
SA:ステアリルアクリレート(大阪有機化学工業(株)製)
E-AX:N,N’-[1,3-フェニレンビス(メチレン)]ビス[ビス(オキシラン-2-イルメチル)アミン](エポキシ系架橋剤、綜研化学株式会社製)
KBM-403:3-グリシドキシプロピルトリメトキシシラン(シランカップリング剤、信越化学工業株式会社製)
LiTFSI:リチウムビス(トリフルオロメタンスルホニル)イミド(イオン性化合物、3M社製)
AS-1:1-オクチル-4-メチルピリジニウムビス(トリフルオロメタンスルホニル)イミド(イオン性化合物)
AS-2:トリデシルメチルアンモニウムビス(フルオロスルホニル)イミド(イオン性化合物)
AS-3:テトラデシルアンモニウムビス(フルオロスルホニル)イミド(イオン性化合物)
AS-4:トリブチルメチルアンモニウムビス(トリフルオロメタンスルホニル)イミド(イオン性化合物)
TD-75:XDI系イソシアネート化合物(イソシアネート系架橋剤、三井武田薬品株式会社製)
20 粘着剤層
30 偏光板
100 積層体
Claims (10)
- (A)重量平均分子量が100万以上である(メタ)アクリル系ポリマーと、
(B)架橋剤と、
(C)シランカップリング剤と、を含み、
前記(A)(メタ)アクリル系ポリマーは、
(a1)成分:炭素数12以上18以下の直鎖状アルキル基を有するアクリル酸アルキルエステル単量体1質量%以上30質量%以下と、
(a2)成分:ヒドロキシル基を有する単量体0.1質量%以上10質量%以下と、
(a3)成分:前記(a1)成分および前記(a2)成分以外の単量体であって、非架橋性(メタ)アクリル酸エステル単量体60質量%以上98.9質量%以下と、を含む単量体混合物の共重合体である、光学フィルム用粘着剤組成物。 - 前記単量体混合物におけるカルボキシル基含有単量体の含有量が1質量%以下である、請求項1に記載の光学フィルム用粘着剤組成物。
- 前記(A)アクリル系ポリマー100質量部に対して、前記(B)架橋剤を0.01質量部以上5質量部以下含む、請求項1に記載の光学フィルム用粘着剤組成物。
- 前記(A)アクリル系ポリマー100質量部に対して、前記(C)シランカップリング剤を0.05質量部以上0.5質量部以下含む、請求項1に記載の光学フィルム用粘着剤組成物。
- ゲル分率が40%以上93%以下である、請求項1に記載の光学フィルム用粘着剤組成物。
- (D)イオン性化合物をさらに含む、請求項1に記載の光学フィルム用粘着剤組成物。
- 請求項1に記載の光学フィルム用粘着剤組成物を用いて得られた厚さ20μmの粘着剤層を、表面がアルカリで処理されたガラスの該表面上に貼り合わせ、50℃および5atmの条件にて20分間オートクレーブで処理した後、60℃で2時間加熱し、次いで、23℃/50%RH雰囲気下で2時間静置した後に、該粘着剤層を該表面から剥離するときの粘着力が700gf/25mm以下である、請求項1に記載の光学フィルム用粘着剤組成物。
- 請求項1ないし7のいずれか1項に記載の光学フィルム用粘着剤組成物を用いて得られた粘着剤層を、光学フィルムの片面または両面に設える、粘着型光学フィルム。
- 偏光フィルム、位相差フィルム、楕円偏光フィルム、反射防止フィルム、輝度向上フィルムおよび光拡散フィルムからなる群から選択される光学フィルムである、請求項8に記載の粘着型光学フィルム。
- ガラス基板と、
偏光板と、
前記ガラス基板と前記偏光板との間に設けられた、請求項1ないし7のいずれか1項に記載の光学フィルム用粘着剤組成物を膜状に成形し、加熱して得られる粘着剤層と、を含む、積層体。
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201480061895.8A CN105722935B (zh) | 2013-11-22 | 2014-10-27 | 光学膜用粘接剂组合物、粘接型光学膜和叠层体 |
KR1020167010063A KR101946695B1 (ko) | 2013-11-22 | 2014-10-27 | 광학 필름용 점착제 조성물, 점착형 광학 필름 및 적층체 |
JP2015549046A JP6517150B2 (ja) | 2013-11-22 | 2014-10-27 | 光学フィルム用粘着剤組成物、粘着型光学フィルムおよび積層体 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2013-241791 | 2013-11-22 | ||
JP2013241791 | 2013-11-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2015076066A1 true WO2015076066A1 (ja) | 2015-05-28 |
Family
ID=53179335
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2014/078491 WO2015076066A1 (ja) | 2013-11-22 | 2014-10-27 | 光学フィルム用粘着剤組成物、粘着型光学フィルムおよび積層体 |
Country Status (5)
Country | Link |
---|---|
JP (1) | JP6517150B2 (ja) |
KR (1) | KR101946695B1 (ja) |
CN (1) | CN105722935B (ja) |
TW (1) | TW201522550A (ja) |
WO (1) | WO2015076066A1 (ja) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106256865A (zh) * | 2015-06-19 | 2016-12-28 | 日东电工株式会社 | 表面保护薄膜 |
JP2017008173A (ja) * | 2015-06-19 | 2017-01-12 | 日東電工株式会社 | 表面保護フィルム |
KR101854507B1 (ko) * | 2015-10-29 | 2018-05-04 | 삼성에스디아이 주식회사 | 편광판 및 이를 포함하는 광학표시장치 |
KR101854498B1 (ko) * | 2015-04-23 | 2018-06-15 | 삼성에스디아이 주식회사 | 편광판 및 이를 포함하는 광학표시장치 |
JP2019189764A (ja) * | 2018-04-25 | 2019-10-31 | 藤森工業株式会社 | 粘着剤組成物及び粘着フィルム |
WO2019216094A1 (ja) * | 2018-05-11 | 2019-11-14 | 住友化学株式会社 | 偏光板および表示装置 |
JP2019200413A (ja) * | 2018-05-11 | 2019-11-21 | 住友化学株式会社 | 偏光板および表示装置 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101996835B1 (ko) * | 2017-03-31 | 2019-07-05 | 동우 화인켐 주식회사 | 편광판 및 이를 포함하는 화상 표시 장치 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63202682A (ja) * | 1987-02-18 | 1988-08-22 | Nitto Electric Ind Co Ltd | 感圧性接着剤 |
JPH07502560A (ja) * | 1991-12-31 | 1995-03-16 | ミネソタ マイニング アンド マニュファクチャリング カンパニー | 再剥離型低溶融粘度アクリル系感圧接着剤 |
WO2008126849A1 (ja) * | 2007-04-09 | 2008-10-23 | Sony Chemical & Information Device Corporation | 粘着剤組成物、粘着シート、光学用粘着シート、及び電磁波シールド用粘着シート |
JP2008308633A (ja) * | 2007-06-18 | 2008-12-25 | Nitto Denko Corp | 光学部材用粘着剤組成物 |
WO2013048934A1 (en) * | 2011-09-26 | 2013-04-04 | 3M Innovative Properties Company | Pressure-sensitive adhesives with a (meth)acrylic-based elastomeric material |
JP2013107977A (ja) * | 2011-11-21 | 2013-06-06 | Fujimori Kogyo Co Ltd | 粘着剤組成物及び表面保護フィルム |
JP2013194170A (ja) * | 2012-03-21 | 2013-09-30 | Nitto Denko Corp | 粘着剤、粘着剤層、および粘着シート |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005232335A (ja) * | 2004-02-20 | 2005-09-02 | Toyo Ink Mfg Co Ltd | 水性エマルジョン型粘着剤及び該粘着剤を用いてなる粘着シート |
JP4498057B2 (ja) * | 2004-08-09 | 2010-07-07 | 日東電工株式会社 | 光重合性アクリル系粘着剤組成物および該組成物を用いた粘着シート又はテープ |
JP2007169329A (ja) | 2005-12-19 | 2007-07-05 | Saiden Chemical Industry Co Ltd | 光学用粘着剤組成物および粘着シート |
JP5038224B2 (ja) * | 2007-05-08 | 2012-10-03 | 日東電工株式会社 | 粘着型光学フィルムおよび画像表示装置 |
JP5616005B2 (ja) * | 2008-06-02 | 2014-10-29 | スリーエム イノベイティブ プロパティズ カンパニー | 粘着剤組成物及び粘着テープ |
JP5523052B2 (ja) * | 2008-10-29 | 2014-06-18 | 日本合成化学工業株式会社 | 粘着剤、それを用いてなる粘着シート、一時表面保護用粘着剤、それを用いてなる一時表面保護用粘着シート、およびその一時表面保護用粘着シートの使用方法。 |
CN101693820A (zh) * | 2009-10-30 | 2010-04-14 | 北京化工大学 | Lcd偏光片用丙烯酸酯压敏胶及其制备方法 |
JP5912833B2 (ja) * | 2011-05-26 | 2016-04-27 | 日東電工株式会社 | 光学フィルム用粘着剤組成物、光学フィルム用粘着剤層、粘着剤層付光学フィルムおよび画像表示装置 |
JP2013122035A (ja) * | 2011-11-10 | 2013-06-20 | Nitto Denko Corp | 粘着シート |
-
2014
- 2014-10-27 JP JP2015549046A patent/JP6517150B2/ja active Active
- 2014-10-27 CN CN201480061895.8A patent/CN105722935B/zh active Active
- 2014-10-27 KR KR1020167010063A patent/KR101946695B1/ko active IP Right Grant
- 2014-10-27 WO PCT/JP2014/078491 patent/WO2015076066A1/ja active Application Filing
- 2014-11-05 TW TW103138322A patent/TW201522550A/zh unknown
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63202682A (ja) * | 1987-02-18 | 1988-08-22 | Nitto Electric Ind Co Ltd | 感圧性接着剤 |
JPH07502560A (ja) * | 1991-12-31 | 1995-03-16 | ミネソタ マイニング アンド マニュファクチャリング カンパニー | 再剥離型低溶融粘度アクリル系感圧接着剤 |
JPH07502558A (ja) * | 1991-12-31 | 1995-03-16 | ミネソタ マイニング アンド マニュファクチャリング カンパニー | 再剥離型低溶融粘度アクリル系感圧接着剤 |
WO2008126849A1 (ja) * | 2007-04-09 | 2008-10-23 | Sony Chemical & Information Device Corporation | 粘着剤組成物、粘着シート、光学用粘着シート、及び電磁波シールド用粘着シート |
JP2008308633A (ja) * | 2007-06-18 | 2008-12-25 | Nitto Denko Corp | 光学部材用粘着剤組成物 |
WO2013048934A1 (en) * | 2011-09-26 | 2013-04-04 | 3M Innovative Properties Company | Pressure-sensitive adhesives with a (meth)acrylic-based elastomeric material |
JP2013107977A (ja) * | 2011-11-21 | 2013-06-06 | Fujimori Kogyo Co Ltd | 粘着剤組成物及び表面保護フィルム |
JP2013194170A (ja) * | 2012-03-21 | 2013-09-30 | Nitto Denko Corp | 粘着剤、粘着剤層、および粘着シート |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101854498B1 (ko) * | 2015-04-23 | 2018-06-15 | 삼성에스디아이 주식회사 | 편광판 및 이를 포함하는 광학표시장치 |
KR102518798B1 (ko) * | 2015-06-19 | 2023-04-07 | 닛토덴코 가부시키가이샤 | 표면 보호 필름 |
KR20160150023A (ko) * | 2015-06-19 | 2016-12-28 | 닛토덴코 가부시키가이샤 | 표면 보호 필름 |
JP2017008172A (ja) * | 2015-06-19 | 2017-01-12 | 日東電工株式会社 | 表面保護フィルム |
JP2017008173A (ja) * | 2015-06-19 | 2017-01-12 | 日東電工株式会社 | 表面保護フィルム |
CN106256865A (zh) * | 2015-06-19 | 2016-12-28 | 日东电工株式会社 | 表面保护薄膜 |
KR101854507B1 (ko) * | 2015-10-29 | 2018-05-04 | 삼성에스디아이 주식회사 | 편광판 및 이를 포함하는 광학표시장치 |
JP2019189764A (ja) * | 2018-04-25 | 2019-10-31 | 藤森工業株式会社 | 粘着剤組成物及び粘着フィルム |
KR20210040928A (ko) * | 2018-04-25 | 2021-04-14 | 후지모리 고교 가부시키가이샤 | 점착제 조성물 및 점착 필름 |
KR102383869B1 (ko) | 2018-04-25 | 2022-04-08 | 후지모리 고교 가부시키가이샤 | 점착제 조성물 및 점착 필름 |
JP7166783B2 (ja) | 2018-04-25 | 2022-11-08 | 藤森工業株式会社 | 粘着剤組成物溶液、粘着フィルムの製造方法、粘着剤層付き光学フィルムの製造方法、粘着剤層付き偏光板の製造方法 |
JP2019200413A (ja) * | 2018-05-11 | 2019-11-21 | 住友化学株式会社 | 偏光板および表示装置 |
WO2019216094A1 (ja) * | 2018-05-11 | 2019-11-14 | 住友化学株式会社 | 偏光板および表示装置 |
Also Published As
Publication number | Publication date |
---|---|
CN105722935A (zh) | 2016-06-29 |
CN105722935B (zh) | 2017-11-24 |
JPWO2015076066A1 (ja) | 2017-03-16 |
KR101946695B1 (ko) | 2019-02-11 |
TW201522550A (zh) | 2015-06-16 |
JP6517150B2 (ja) | 2019-05-22 |
KR20160089348A (ko) | 2016-07-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
TWI672347B (zh) | 光學薄膜用黏著劑組成物、光學薄膜用黏著劑層、附黏著劑層之光學薄膜以及影像顯示裝置 | |
WO2015076066A1 (ja) | 光学フィルム用粘着剤組成物、粘着型光学フィルムおよび積層体 | |
TWI608064B (zh) | 光學膜用黏著劑組成物及黏著型光學膜,以及積層體 | |
TWI609062B (zh) | 黏著劑層及黏著膜 | |
JP6283355B2 (ja) | 積層体 | |
CN115731778A (zh) | 透明树脂层 | |
JP2012131963A (ja) | 光学フィルム用粘着剤組成物および粘着型光学フィルム | |
KR102153560B1 (ko) | 점착제층, 점착제층 부착 편광판 및 적층체 | |
JP2015205974A (ja) | 偏光板用粘着剤組成物、粘着シート、粘着剤層付き偏光板および積層体 | |
KR102156462B1 (ko) | 광학 필름용 점착제 조성물 및 점착형 광학 필름 | |
WO2014163003A1 (ja) | 光学用粘着剤組成物、光学用粘着シートおよびその製造方法 | |
WO2016129353A1 (ja) | 偏光板用粘着剤組成物およびその用途 | |
TW201827542A (zh) | 黏著劑組成物、黏著劑層、附黏著劑層之偏光薄膜、液晶面板、及影像顯示裝置 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 14864008 Country of ref document: EP Kind code of ref document: A1 |
|
ENP | Entry into the national phase |
Ref document number: 2015549046 Country of ref document: JP Kind code of ref document: A |
|
ENP | Entry into the national phase |
Ref document number: 20167010063 Country of ref document: KR Kind code of ref document: A |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 14864008 Country of ref document: EP Kind code of ref document: A1 |