WO2014153942A1 - 制备源漏准soi多栅结构器件的方法 - Google Patents
制备源漏准soi多栅结构器件的方法 Download PDFInfo
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- WO2014153942A1 WO2014153942A1 PCT/CN2013/084743 CN2013084743W WO2014153942A1 WO 2014153942 A1 WO2014153942 A1 WO 2014153942A1 CN 2013084743 W CN2013084743 W CN 2013084743W WO 2014153942 A1 WO2014153942 A1 WO 2014153942A1
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- Prior art keywords
- silicon oxide
- source
- layer
- silicon
- drain
- Prior art date
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- 238000000034 method Methods 0.000 title claims abstract description 24
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 24
- 239000010703 silicon Substances 0.000 claims abstract description 24
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims abstract description 21
- 229920005591 polysilicon Polymers 0.000 claims abstract description 21
- 229910052751 metal Inorganic materials 0.000 claims abstract description 15
- 239000002184 metal Substances 0.000 claims abstract description 15
- 230000003647 oxidation Effects 0.000 claims abstract description 4
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 65
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 65
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 26
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 26
- 239000000463 material Substances 0.000 claims description 22
- 238000001312 dry etching Methods 0.000 claims description 19
- 238000001039 wet etching Methods 0.000 claims description 13
- 238000000231 atomic layer deposition Methods 0.000 claims description 8
- 238000000151 deposition Methods 0.000 claims description 8
- 238000002955 isolation Methods 0.000 claims description 8
- 238000005530 etching Methods 0.000 claims description 7
- 238000002513 implantation Methods 0.000 claims description 7
- 239000000758 substrate Substances 0.000 claims description 7
- 238000000137 annealing Methods 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 229910021421 monocrystalline silicon Inorganic materials 0.000 claims description 5
- 238000011065 in-situ storage Methods 0.000 claims description 4
- 230000003071 parasitic effect Effects 0.000 claims description 4
- 238000000206 photolithography Methods 0.000 claims description 4
- 230000001629 suppression Effects 0.000 claims description 4
- 238000009279 wet oxidation reaction Methods 0.000 claims description 4
- 229910045601 alloy Inorganic materials 0.000 claims description 3
- 239000000956 alloy Substances 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 239000007943 implant Substances 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 229920002120 photoresistant polymer Polymers 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- 238000005240 physical vapour deposition Methods 0.000 claims description 2
- 230000007704 transition Effects 0.000 claims description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
- 238000005260 corrosion Methods 0.000 claims 1
- 230000007797 corrosion Effects 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 238000002347 injection Methods 0.000 description 23
- 239000007924 injection Substances 0.000 description 23
- 239000010410 layer Substances 0.000 description 22
- 238000004518 low pressure chemical vapour deposition Methods 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 238000005498 polishing Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- -1 Note B Substances 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 230000004913 activation Effects 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 238000005224 laser annealing Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000004065 semiconductor Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 230000005669 field effect Effects 0.000 description 2
- 238000004151 rapid thermal annealing Methods 0.000 description 2
- 125000006850 spacer group Chemical group 0.000 description 2
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 2
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000001459 lithography Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
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- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/66007—Multistep manufacturing processes
- H01L29/66075—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
- H01L29/66227—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
- H01L29/66409—Unipolar field-effect transistors
- H01L29/66477—Unipolar field-effect transistors with an insulated gate, i.e. MISFET
- H01L29/66787—Unipolar field-effect transistors with an insulated gate, i.e. MISFET with a gate at the side of the channel
- H01L29/66795—Unipolar field-effect transistors with an insulated gate, i.e. MISFET with a gate at the side of the channel with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET
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- H01L29/43—Electrodes ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
- H01L29/49—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET
- H01L29/51—Insulating materials associated therewith
- H01L29/511—Insulating materials associated therewith with a compositional variation, e.g. multilayer structures
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- H01L29/66409—Unipolar field-effect transistors
- H01L29/66477—Unipolar field-effect transistors with an insulated gate, i.e. MISFET
- H01L29/66545—Unipolar field-effect transistors with an insulated gate, i.e. MISFET using a dummy, i.e. replacement gate in a process wherein at least a part of the final gate is self aligned to the dummy gate
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- H01L29/66409—Unipolar field-effect transistors
- H01L29/66477—Unipolar field-effect transistors with an insulated gate, i.e. MISFET
- H01L29/66568—Lateral single gate silicon transistors
- H01L29/66575—Lateral single gate silicon transistors where the source and drain or source and drain extensions are self-aligned to the sides of the gate
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- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
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- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/785—Field effect transistors with field effect produced by an insulated gate having a channel with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET
- H01L29/7851—Field effect transistors with field effect produced by an insulated gate having a channel with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET with the body tied to the substrate
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- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
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- H01L29/49—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET
- H01L29/4966—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET the conductor material next to the insulator being a composite material, e.g. organic material, TiN, MoSi2
Definitions
- the invention relates to a method for preparing a source-drained quasi-multi-gate structure device, and belongs to the technical field of ultra-large scale integrated circuit manufacturing. Background technique
- the object of the present invention is to provide a method for preparing a source-drained quasi-SOI multi-gate structure device in view of the difficulty of a multi-gate structure device still having a large leakage current at a short trench length.
- This solution can be implemented in a process compatible with traditional bulk silicon CMOS, can be easily integrated into the process flow, and can still maintain a small leakage current under a short channel length condition, thereby reducing the power consumption of the device. .
- the technical solution for preparing a source-drain quasi-SOI multi-gate structure device includes the following steps:
- a) Forming an active region in the shape of a Fin strip The main purpose of this step is to form a thin stripe (Fin strip shape) pattern structure on the hard mask by photolithography. i. depositing a layer of silicon oxide (200 A in thickness) and a layer of silicon nitride (50 ⁇ ⁇ ) on the surface of the silicon wafer. As a hard mask material.
- Ii. Define a thin strip of Fin strip structure by lithography. Iii. Transfer the pattern to the hard mask by dry etching.
- STI material i. Deposit a thick layer of silicon oxide (more than 1000 A above the height of the Fin strip) as the STI material.
- CMP Chemical Mechanical Polishing
- Iv. By dry etching, the silicon oxide in the STI region is etched back to form an STI. v. Perform well implant and well anneal. Vi. Perform substrate parasitic transistor suppression implant and annealing.
- Ii. Deposit a thicker polysilicon (more than 1000 A above the height of the Fin strip) as a gate material layer. Iii. Plan the polysilicon by CMP chemistry and stop at a certain height on top of the Fin strip. Iv. Deposit a layer of silicon oxide (thickness 30 ⁇ ) as a hard mask layer for the gate lines. v. Photolithographic etching to form hard mask lines and gate lines.
- Ii Perform the implantation of the source and drain extension regions and anneal.
- Iii. A further layer of ( ⁇ ) silicon oxide is deposited and dry etched back to form a silicon oxide sidewall.
- Ii Deposit a layer of (150A) silicon nitride and dry etch it back to form a silicon nitride sidewall.
- the sidewalls are only outside the sidewalls of the silicon oxide, and the silicon nitride in the recesses of the source and drain regions between the STIs must be completely removed.
- the anisotropic dry etching etches the silicon in the groove of the source and drain regions to a certain depth (20-30 nm).
- Wet oxidation forms silicon oxide in the grooves of the source and drain regions as a quasi-S0I isolation layer.
- High k means high dielectric constant material
- Metal gate structure The main purpose of this step is to form a high-k metal gate structure by dummy gate and dummy gate dielectric removal and backfilling of the corresponding high-k metal gate material.
- i. Deposit a layer of (4000A) silicon oxide as the dielectric layer.
- Ii. CMP silicon oxide and stop on the polysilicon surface to planarize the silicon oxide and polysilicon surfaces.
- Iii. Wet etching removes the polysilicon dummy gate material.
- Atomic layer deposition forms a silicon oxide transition layer and a high-k gate dielectric Hf0 2 .
- Vi. Atomic layer deposition forms a metal work function adjustment layer TiN.
- the invention has the following technical effects:
- the solution can be implemented in a process compatible with traditional bulk silicon CMOS, can be easily integrated into the process flow, and can still maintain a small leakage current under a short channel length condition, thereby reducing the power consumption of the device. . DRAWINGS
- Figure 1 is a schematic view showing the structure of a device after forming a Fin strip.
- Fig. 2 is a schematic view showing the structure of a device after isolation of silicon oxide by CMP.
- FIG. 3 is a schematic view showing the structure of the device after forming the isolation region and the active region.
- FIG. 4 is a schematic view showing the structure of a device after forming a dummy gate.
- Figure 5 is a schematic diagram of the structure of the device after forming the Offset and the sidewall spacers.
- Fig. 6 is a schematic view showing the structure of the device after the grooves are formed between the source and drain regions STI.
- Figure 7 is a schematic view showing the structure of the device after forming a silicon nitride sidewall.
- Figure 8 is a cross-sectional view in the AA direction of Figure 7.
- Figure 9 is a cross-sectional view taken along the line BB in Figure 7.
- Figure 10 is a schematic view showing the structure of the device after another anisotropic dry etching.
- Figure 11 is a cross-sectional view in the AA direction of Figure 10.
- Figure 12 is a cross-sectional view taken along line BB of Figure 1.
- Figure 13 is a schematic view showing the structure of the device after wet oxidation has formed a quasi-SOI in the source and drain regions.
- Figure 14 is a cross-sectional view taken along line AA of Figure 13;
- Figure 15 is a cross-sectional view taken along the line BB in Figure 13 .
- Figure 16 is a schematic view showing the structure of the device after wet etching to remove the silicon nitride sidewall.
- Figure 17 is a cross-sectional view taken along line AA of Figure 16.
- FIG. 18 is a cross-sectional view taken along line BB of Figure 16.
- FIG. 19 is a schematic view showing the structure of a device after epitaxial single crystal silicon forms an elevated source and drain.
- FIG. 20 is a schematic view showing the structure of a device after the dielectric layer silicon oxide is subjected to CMP.
- 21 is a schematic view showing the structure of a device after forming a high-k metal gate.
- Figure 22 is a description of the materials used. detailed description
- An n-type tri-gate field effect transistor having a Fin strip width of about 10 nm, a height of 30 nm, and a channel length of about 25 nm was prepared according to the following procedure:
- Optical lithography defines a Fin strip with a Fin strip width of 20 nm
- CMP chemical mechanical polishing planarizes the polysilicon and stops on the silicon nitride hard mask layer, as shown in Figure 2;
- RTP rapid thermal annealing
- Substrate parasitic transistor suppression injection Note B, implantation energy is 8keV, injection inclination is 0 degree, injection dose is lel3cm- 2
- Parasitic transistor suppression injection activation laser annealing, 1100 degrees, 1 nanosecond; 18. HF solution for silicon surface treatment;
- Optical lithography defines a gate line having a gate line width of 25 nm, that is, a physical gate length of 25 nm;
- Source-drain extension region injection Note As, injection energy is 5keV, injection inclination angle is 20 degrees, injection dose is lel5cm" 2 , divided into two injections;
- FIG. 7 Anisotropic dry etching 250A silicon nitride, forming sidewalls, and exposing silicon in the source and drain regions, as shown in FIG. 7, the cross-sectional view in the AA direction in FIG. 7 is as shown in FIG. The cross-sectional view in the BB direction of 7 is shown in Fig. 9;
- the anisotropic dry etching 100 A silicon as shown in FIG. 10, the cross-sectional view in the AA direction in FIG. 10 is as shown in FIG. 11, and the cross-sectional view in the BB direction in FIG. 10 is as shown in FIG. ;
- FIG. 35 Wet oxidation forms 200 A of silicon oxide inside the groove of the source and drain regions, as shown in Fig. 13, a cross-sectional view in the direction of AA in Fig. 13 is shown in Fig. 14, and a cross-sectional view in the direction of BB in Fig. 13 As shown in FIG. 15; 36. Isotropic wet etching of 150A silicon nitride by hot phosphoric acid solution, as shown in FIG. 16, a cross-sectional view in the AA direction of FIG. 16 is shown in FIG. 17, and FIG. 16 is in the BB direction. The cross-sectional view is shown in Figure 18; 37.
- the in-situ doped epitaxial single-crystal silicon forming a highly doped source and drain lifting, epitaxial thickness 50 ⁇ , doping concentration le20cm_ 3.
- the shape of the epitaxial single crystal silicon lifted source and drain is related to the crystal plane of the silicon wafer and the crystal orientation of the channel.
- Source and drain region injection Note As, the implantation energy is 10keV, the injection inclination angle is 0 degree, and the implantation dose is 2el5cm" 2 ;
- the doping dose is lel5cm_ 2 ;
- Atomic layer deposition 100 A silicon oxide
- Atomic layer deposition 20 A yttrium oxide
- the source and drain forms a contact hole and a metal contact
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Abstract
Description
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US20160064529A1 (en) * | 2013-03-28 | 2016-03-03 | Peking University | Method for fabricating multi-gate structure device with source and drain having quasi-soi structure |
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CN103700593B (zh) * | 2013-12-18 | 2016-02-17 | 北京大学 | 制备准soi源漏多栅器件的方法 |
CN103681355B (zh) | 2013-12-18 | 2016-04-06 | 北京大学 | 制备准soi源漏场效应晶体管器件的方法 |
CN109841525B (zh) * | 2017-11-27 | 2021-12-14 | 中芯国际集成电路制造(上海)有限公司 | 半导体结构及其形成方法 |
CN110473916B (zh) * | 2019-09-18 | 2024-04-02 | 深圳爱仕特科技有限公司 | 一种具有p+区域自对准工艺的碳化硅MOSFET器件的制备方法 |
US11211470B2 (en) * | 2019-10-18 | 2021-12-28 | Taiwan Semiconductor Manufacturing Company, Ltd. | Semiconductor device and method |
WO2024081473A1 (en) * | 2022-10-12 | 2024-04-18 | Lam Research Corporation | Inhibited oxide deposition for refilling shallow trench isolation |
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US20160064529A1 (en) | 2016-03-03 |
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