WO2014129574A1 - 架橋用樹脂組成物および封止材 - Google Patents
架橋用樹脂組成物および封止材 Download PDFInfo
- Publication number
- WO2014129574A1 WO2014129574A1 PCT/JP2014/054127 JP2014054127W WO2014129574A1 WO 2014129574 A1 WO2014129574 A1 WO 2014129574A1 JP 2014054127 W JP2014054127 W JP 2014054127W WO 2014129574 A1 WO2014129574 A1 WO 2014129574A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- crosslinking
- meth
- acrylate
- resin composition
- ethylene copolymer
- Prior art date
Links
- 238000004132 cross linking Methods 0.000 title claims abstract description 45
- 239000011342 resin composition Substances 0.000 title claims abstract description 18
- 238000007789 sealing Methods 0.000 title description 4
- 229920001038 ethylene copolymer Polymers 0.000 claims abstract description 24
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920000193 polymethacrylate Polymers 0.000 claims abstract description 11
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 9
- 239000003566 sealing material Substances 0.000 claims description 8
- 230000005855 radiation Effects 0.000 claims description 5
- 238000009413 insulation Methods 0.000 abstract description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 25
- 150000001451 organic peroxides Chemical class 0.000 description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 6
- 239000005977 Ethylene Substances 0.000 description 6
- -1 methacryloyl groups Chemical group 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 4
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000005038 ethylene vinyl acetate Substances 0.000 description 3
- 239000012948 isocyanate Substances 0.000 description 3
- 150000002513 isocyanates Chemical class 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 3
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 2
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000005058 Isophorone diisocyanate Substances 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- FENNUTZYPOEXMW-UHFFFAOYSA-N bis(3,3,5,5-tetramethylpiperazin-1-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CN1OC(=O)CCCCCCCCC(=O)ON1CC(C)(C)NC(C)(C)C1 FENNUTZYPOEXMW-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- 239000012776 electronic material Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 2
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- CNHDIAIOKMXOLK-UHFFFAOYSA-N toluquinol Chemical compound CC1=CC(O)=CC=C1O CNHDIAIOKMXOLK-UHFFFAOYSA-N 0.000 description 2
- 229920001567 vinyl ester resin Polymers 0.000 description 2
- RIPYNJLMMFGZSX-UHFFFAOYSA-N (5-benzoylperoxy-2,5-dimethylhexan-2-yl) benzenecarboperoxoate Chemical compound C=1C=CC=CC=1C(=O)OOC(C)(C)CCC(C)(C)OOC(=O)C1=CC=CC=C1 RIPYNJLMMFGZSX-UHFFFAOYSA-N 0.000 description 1
- NALFRYPTRXKZPN-UHFFFAOYSA-N 1,1-bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane Chemical compound CC1CC(C)(C)CC(OOC(C)(C)C)(OOC(C)(C)C)C1 NALFRYPTRXKZPN-UHFFFAOYSA-N 0.000 description 1
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 1
- KCZQSKKNAGZQSZ-UHFFFAOYSA-N 1,3,5-tris(6-isocyanatohexyl)-1,3,5-triazin-2,4,6-trione Chemical compound O=C=NCCCCCCN1C(=O)N(CCCCCCN=C=O)C(=O)N(CCCCCCN=C=O)C1=O KCZQSKKNAGZQSZ-UHFFFAOYSA-N 0.000 description 1
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
- 229940008841 1,6-hexamethylene diisocyanate Drugs 0.000 description 1
- QWQNFXDYOCUEER-UHFFFAOYSA-N 2,3-ditert-butyl-4-methylphenol Chemical compound CC1=CC=C(O)C(C(C)(C)C)=C1C(C)(C)C QWQNFXDYOCUEER-UHFFFAOYSA-N 0.000 description 1
- ODBCKCWTWALFKM-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhex-3-yne Chemical compound CC(C)(C)OOC(C)(C)C#CC(C)(C)OOC(C)(C)C ODBCKCWTWALFKM-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- PTJWCLYPVFJWMP-UHFFFAOYSA-N 2-[[3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)COCC(CO)(CO)CO PTJWCLYPVFJWMP-UHFFFAOYSA-N 0.000 description 1
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 description 1
- VFTWMPNBHNNMAV-UHFFFAOYSA-N 2-tert-butylperoxy-1,4-di(propan-2-yl)benzene Chemical compound CC(C)C1=CC=C(C(C)C)C(OOC(C)(C)C)=C1 VFTWMPNBHNNMAV-UHFFFAOYSA-N 0.000 description 1
- BIISIZOQPWZPPS-UHFFFAOYSA-N 2-tert-butylperoxypropan-2-ylbenzene Chemical compound CC(C)(C)OOC(C)(C)C1=CC=CC=C1 BIISIZOQPWZPPS-UHFFFAOYSA-N 0.000 description 1
- OXYZDRAJMHGSMW-UHFFFAOYSA-N 3-chloropropyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)CCCCl OXYZDRAJMHGSMW-UHFFFAOYSA-N 0.000 description 1
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 1
- UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 description 1
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 239000004386 Erythritol Substances 0.000 description 1
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 description 1
- OKOBUGCCXMIKDM-UHFFFAOYSA-N Irganox 1098 Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NCCCCCCNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 OKOBUGCCXMIKDM-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- YPCHGLDQZXOZFW-UHFFFAOYSA-N [2-[[4-methyl-3-[[3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propoxy]carbonylamino]phenyl]carbamoyloxymethyl]-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound CC1=CC=C(NC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C)C=C1NC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C YPCHGLDQZXOZFW-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- BAPJBEWLBFYGME-UHFFFAOYSA-N acrylic acid methyl ester Natural products COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002313 adhesive film Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000001723 curing Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000011033 desalting Methods 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- KORSJDCBLAPZEQ-UHFFFAOYSA-N dicyclohexylmethane-4,4'-diisocyanate Chemical compound C1CC(N=C=O)CCC1CC1CCC(N=C=O)CC1 KORSJDCBLAPZEQ-UHFFFAOYSA-N 0.000 description 1
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 1
- 235000019414 erythritol Nutrition 0.000 description 1
- 229940009714 erythritol Drugs 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- WOXXJEVNDJOOLV-UHFFFAOYSA-N ethenyl-tris(2-methoxyethoxy)silane Chemical compound COCCO[Si](OCCOC)(OCCOC)C=C WOXXJEVNDJOOLV-UHFFFAOYSA-N 0.000 description 1
- SBRXLTRZCJVAPH-UHFFFAOYSA-N ethyl(trimethoxy)silane Chemical compound CC[Si](OC)(OC)OC SBRXLTRZCJVAPH-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 235000015203 fruit juice Nutrition 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000001631 haemodialysis Methods 0.000 description 1
- 230000000322 hemodialysis Effects 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 1
- 229940117841 methacrylic acid copolymer Drugs 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000012460 protein solution Substances 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- PNWOTXLVRDKNJA-UHFFFAOYSA-N tert-butylperoxybenzene Chemical compound CC(C)(C)OOC1=CC=CC=C1 PNWOTXLVRDKNJA-UHFFFAOYSA-N 0.000 description 1
- 238000001029 thermal curing Methods 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
- C08L31/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C08L31/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/10—Materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K3/1006—Materials in mouldable or extrudable form for sealing or packing joints or covers characterised by the chemical nature of one of its constituents
- C09K3/1021—Polyurethanes or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
- C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
- C08F299/06—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyurethanes
- C08F299/065—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyurethanes from polyurethanes with side or terminal unsaturations
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0025—Crosslinking or vulcanising agents; including accelerators
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/04—Homopolymers or copolymers of ethene
- C09J123/08—Copolymers of ethene
- C09J123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C09J123/0853—Vinylacetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/10—Materials in mouldable or extrudable form for sealing or packing joints or covers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
- H01L31/0481—Encapsulation of modules characterised by the composition of the encapsulation material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/204—Applications use in electrical or conductive gadgets use in solar cells
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2200/00—Chemical nature of materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K2200/06—Macromolecular organic compounds, e.g. prepolymers
- C09K2200/0615—Macromolecular organic compounds, e.g. prepolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09K2200/0617—Polyalkenes
- C09K2200/062—Polyethylene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2200/00—Chemical nature of materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K2200/06—Macromolecular organic compounds, e.g. prepolymers
- C09K2200/0615—Macromolecular organic compounds, e.g. prepolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09K2200/0622—Polyvinylalcohols, polyvinylacetates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Definitions
- the present invention relates to a cross-linking resin composition and a sealing material, and more specifically, to a cross-linking resin composition obtained by blending a specific cross-linking aid into an ethylene copolymer and a solar cell comprising the cross-linking resin composition. And so on.
- Patent Document 1 a resin composition in which an ethylene-based copolymer is used as a base material and an organic peroxide is blended as a crosslinking agent has been proposed.
- an adhesive sheet for solar cells comprising 100 parts by weight of an ethylene copolymer and 0.05 to 0.5 parts by weight of an organic peroxide, a total of four of either or both of acryloyl groups and methacryloyl groups
- the adhesive sheet for solar cells containing the polyfunctional monomer which has the above is proposed (patent document 2).
- the present invention has been made in view of the above circumstances, and its purpose is to mix an ethylene copolymer with a crosslinking aid, and the crosslinked product has excellent insulating properties (volume resistivity).
- the object is to provide a resin composition.
- the present invention has obtained the knowledge that the above object can be achieved by blending a specific crosslinking aid into the ethylene copolymer.
- the first gist of the present invention resides in a heat-crosslinking resin composition comprising an ethylene copolymer and urethane poly (meth) acrylate as a crosslinking aid together with a crosslinking agent.
- the gist of the present invention resides in a radiation cross-linking resin composition comprising a urethane poly (meth) acrylate blended with an ethylene copolymer as a cross-linking aid, and the third gist is the above-mentioned cross-linking resin composition. It exists in the sealing material characterized by consisting of a thing.
- the ethylene copolymer is a copolymer of ethylene as a main component and a monomer copolymerizable therewith.
- the monomer include vinyl esters, unsaturated carboxylic esters, unsaturated carboxylic acids and their metal salts, unsaturated salts. Examples include saturated silicon compounds and ⁇ -olefins.
- a polar monomer is preferable.
- the ethylene copolymer examples include an ethylene / vinyl ester copolymer such as an ethylene vinyl acetate copolymer, an ethylene / methyl acrylate copolymer, an ethylene / isobutyl acrylate / methacrylic acid copolymer, and the like.
- examples thereof include ethylene / unsaturated carboxylic acid ester copolymers and their ionomers.
- ethylene vinyl acetate copolymers are particularly preferred.
- the crosslinkable resin composition of the present invention is obtained by blending urethane poly (meth) acrylate as a crosslinking aid in an ethylene copolymer.
- Urethane poly (meth) acrylate can be synthesized from, for example, organic isocyanate and hydroxyl group-containing (meth) acrylate.
- urethane poly (meth) acrylates those having a high molecular weight are preferred.
- the average molecular weight is 1000 or more, preferably 1200 or more.
- the organic isocyanate is a compound having two or more isocyanate groups in one molecule, and the organic group includes a heterocyclic ring such as a linear, branched, or cyclic aliphatic hydrocarbon group, aromatic hydrocarbon group, or isocyanurate. Groups. Specific examples of the organic isocyanate include 1,6-hexamethylene diisocyanate, isophorone diisocyanate, toluidine diisocyanate, MDI (diphenylmethane diisocyanate), hydrogenated MDI, xylylene diisocyanate, 1,6-hexamethylene diisocyanate trimer, isophorone diisocyanate 3 Examples include a polymer.
- Hydroxyl group-containing (meth) acrylate is (meth) acrylate having one or more hydroxyl groups in one molecule.
- a polyhydric alcohol (meth) acrylate and specific examples thereof include trimethylolpropane di (meth) acrylate, pentaerythritol tri (meth) acrylate, dipentaerythritol tetra (meth) acrylate, tripentaerythritol ( Examples include hydroxyl group-containing (meth) acrylates such as (meth) acrylate, polyalkyldiol (meth) acrylate, polyethylene glycol (meth) acrylate, polyalkylene glycol (meth) acrylate, glycerin di (meth) acrylate, and polyol (meth) acrylate.
- the hydroxyl group-containing (meth) acrylate may be a single acrylate or a mixture thereof.
- Examples of commercially available products of urethane poly (meth) acrylate include “UA-306H”, “UA-306T”, “UA-306I”, “UA-510H” manufactured by Kyoeisha Chemical Co., Ltd., and “KRM7864” manufactured by Daicel Cytec. ”,“ KRM8452 ”,“ EB1290 ”,“ EB1290K ”,“ EB5129 ”,“ U-6HA ”,“ U-6LPA ”,“ UA-33H ”,“ U-15HA ”,“ UA ”manufactured by Shin-Nakamura Chemical Co., Ltd. -122P "," UV7600B “,” UV7605B “,” UV7610B “,” UV7620EA "manufactured by Nihon Gosei Co., Ltd., and the like.
- crosslinking aids In this invention, unless the effect of this invention is impaired, you may use together other crosslinking adjuvants, such as a polyfunctional (meth) acrylate, for example.
- the polyfunctional (meth) acrylate has 2 or more, preferably 3 or more (meth) acryloyl groups in one molecule.
- trimethylolpropane tri (meth) acrylate dimethylolpropane tetra (meth) acrylate, pentaerythritol tri (meth) acrylate, pentaerythritol tetra (meth) acrylate, dipentaerythritol penta (meth) acrylate, dipenta Examples include erythritol hexa (meth) acrylate.
- a crosslinking agent In thermal crosslinking, a crosslinking agent is used together with a crosslinking aid. As such a crosslinking agent, an organic peroxide is generally used.
- the organic peroxide is not particularly limited as long as it is a known organic peroxide that generates a peroxy radical under vulcanization conditions.
- the amount of the crosslinking assistant urethane poly (meth) acrylate in the crosslinking resin composition of the present invention is usually 0.1 to 3.0 parts by weight, preferably 0.5 to 100 parts by weight with respect to 100 parts by weight of the ethylene copolymer. 2.0 parts by weight.
- the amount is usually 0.1 to 3.0 parts by weight, preferably 0.5 to 100 parts by weight of the ethylene copolymer. -2.0 parts by weight.
- the blending amount of the crosslinking agent varies depending on the type of the ethylene copolymer, but is usually 0.6 to 5 parts by weight, preferably 1 to 2 parts by weight with respect to 100 parts by weight of the ethylene copolymer. It should be noted that the organic peroxide is not always necessary when crosslinking is performed by irradiation with radiation.
- a reinforcing agent for example, a filler, a plasticizer, a processing aid, a lubricant, a pigment, an anti-aging agent, a coupling agent, an ultraviolet absorber, an acid acceptor, and the like are optionally added.
- Agents can be used.
- antioxidants include di-t-butyl-P-cresol, pentaerythrityl-tetraxy [3- (3,5-di-t-butyl-4-hydroxyphenyl) propionate], 2,2 ′ Methylenebis (2-methyl-6-tert-butylphenyl), bis (2,2,6,6-tetramethyl-4-piperazyl) sebacate, N, N′-hexane-1,6-diylbis [3- (3 , 5-di-tert-butyl-4-hydroxyphenyl) propionamide], bis (2,2,6,6-tetramethyl-4-piperazyl) sebacate, hydroquinone monomethyl ether, methyl hydroquinone and the like.
- the coupling agent examples include ⁇ -chloropropyltrimethoxysilane, vinyltriethoxysilane, vinyl-tris- ( ⁇ -methoxyethoxy) silane, ⁇ -methacryloxypropyltrimethoxysilane, ⁇ - (3,4- Ethoxycyclohexyl) ethyltrimethoxysilane, ⁇ -glycidoxypropyltrimethoxysilane, ⁇ -mercaptopropyltrimethoxysilane, ⁇ -aminopropyltrimethoxysilane, N- ⁇ - (aminoethyl) - ⁇ -aminopropyltrimethoxysilane , Etc.
- ultraviolet absorbers include 2-hydroxy-4-n-octyloxybenzophenone, 2,2-hydroxy 6-4,4-dimethoxybenzophenone, 2- (2′-hydroxy-5-methylphenyl) benzotriazole , Pt-butylphenyl succinate and the like.
- acid acceptor examples include magnesium hydroxide, calcium hydroxide, magnesium oxide, and zinc oxide.
- the amount of the above additive is usually 10 parts by weight or less, preferably 5 parts by weight or less with respect to 100 parts by weight of the ethylene copolymer.
- ⁇ Crosslinking of ethylene copolymer composition Accelerated electron beams, X-rays, ⁇ -rays, ⁇ -rays, ⁇ -rays, etc. can be used as radiation used for radiation crosslinking.
- the irradiation dose varies depending on the crosslinkable elastomer used, but is usually 0.1 to 500 kGy.
- thermal crosslinking for example, an injection molding machine or a pressure molding machine is used, and a molded body is obtained by heating at 150 ° C. to 200 ° C. for about 2 to 30 minutes. If necessary, secondary crosslinking may be performed by heating at 150 to 200 ° C. for 1 to 10 hours.
- the crosslinking of the above-mentioned ethylene copolymer composition is particularly preferably crosslinking with an organic peroxide.
- the ethylene copolymer composition includes various packaging materials such as foods, pharmaceuticals, industrial chemicals, agriculture, various adhesive films, sealing films for various electrical materials such as solar cells, liquid crystals, light emitting diodes, and organic ELs. It is useful in fields such as hemodialysis, plasma component separation, protein solution desalting, fractionation, concentration, fruit juice concentration, wastewater treatment and the like. In particular, it is useful as a sealing material used for assembling various electronic material modules. By the way, in the case of a sealing agent used in a mode having a considerable thickness like a sealing material for solar cells, curing with ultraviolet rays or an electron beam cannot be performed, and thus thermal curing is applied.
- Examples 1-2 and Comparative Example 1 Each component shown in Table 1 below was kneaded with an open roll. EVA (ethylene vinyl acetate copolymer) having a vinyl acetate content of 32% by weight was used. As the crosslinking aid, the compounds shown in Table 2 were used in various examples. The obtained composition was subjected to hot press crosslinking (primary crosslinking) at 150 ° C. to obtain a sheet having a thickness of 1 mm. The volume resistivity value of the sheet was measured by the method shown in Table 3. The results are shown in Table 4.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Materials Engineering (AREA)
- Electromagnetism (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Physics & Mathematics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Sealing Material Composition (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
Description
エチレン共重合体は、エチレンを主成分とし、これと共重合可能なモノマーとの共重合体であり、モノマーとしては、ビニルエステル、不飽和カルボン酸エステル、不飽和カルボン酸及びその金属塩、不飽和珪素化合物、α-オレフィンなどが例示される。共重合可能なモノマーとしては、極性モノマーが好ましい。エチレン共重合体の具体例としては、エチレン酢酸ビニル共重合体のようなエチレン・ビニルエステル共重合体、エチレン・アクリル酸メチル共重合体・エチレン・アクリル酸イソブチル・メタクリル酸共重合体のようなエチレン・不飽和カルボン酸エステル共重合体及びそのアイオノマーが例示される、これらの中ではエチレン酢酸ビニル共重合体が特に好ましい。
本発明の架橋用樹脂組成物は、エチレン共重合体に架橋助剤としてウレタンポリ(メタ)アクリレートを配合して成る。ウレタンポリ(メタ)アクリレートは、例えば有機イソシアネートと水酸基含有(メタ)アクリレートから合成することができる。ウレタンポリ(メタ)アクリレートの中では分子量が高いものが好ましい。平均分子量としては、1000以上、好ましくは1200以上である。
本発明においては、本発明の効果を損なわない限り、例えば多官能(メタ)アクリレート等の他の架橋助剤を併用してもよい。多官能(メタ)アクリレートは、1分子中に(メタ)アクリロイル基を2個以上、好ましくは3個以上有するものである。具体的には、トリメチロールプロパントリ(メタ)アクリレート、ジメチロールプロパンテトラ(メタ)アクリレート、ペンタエリスリトールトリ(メタ)アクリレート、ペンタエリスリトールテトラ(メタ)アクリレート、ジペンタエリスリトールペンタ(メタ)アクリレート、ジペンタエリスリトールヘキサ(メタ)アクリレート等が挙げられる。
熱架橋においては架橋助剤と共に架橋剤が使用される。斯かる架橋剤としては一般に有機過酸化物が使用される。有機過酸化物としては、加硫条件でパーオキシラジカルを発生する公知の有機過酸化物であれば特に限定されない。例えば、ジ-t-ブチルパーオキサイド、ジクミルパーオキサイド、2,5-ジメチル-2,5-ジ(ベンゾイルパーオキシ)ヘキサン、2,5-ジメチル-2,5-ジ(t-ブチルパーオキシ)ヘキサン、t-ブチルパーオキシ-2-エチルヘキシル-モノカーボネート、1,1-ビス(t-ブチルパーオキシ)-3,5,5-トリメチルシクロヘキサン、2,5-ジメチルヘキサン-2,5-ジヒドロキシパーオキシド、t-ブチルクミルパーオキシド、α,α’-ビス(t-ブチルパーオキシ)-p-ジイソプロピルベンゼン、2,5-ジメチル-2,5-ジ(t-ブチルパーオキシ)ヘキシン-3、ベンゾイルパーオキシド、t-ブチルパーオキシベンゼン等が挙げられる。
放射線架橋に使用される放射線としては、加速電子線、X線、α線、β線、γ線等が利用可能である。照射線量は使用する架橋性エラストマーなどによっても異なるが、通常0.1~500kGyである。熱架橋は、例えば射出成型機や加圧成型機などを使用し、150℃~200℃、約2~30分加熱することで成形体を得る。必要に応じて、その後、150℃~200℃で1~10時間加熱し二次架橋を行ってもよい。前述のエチレン共重合体組成物の架橋は、特に有機過酸化物による架橋が好ましい。
オープンロールにより、以下の表1に示す各成分を混練した。EVA(エチレン酢酸ビニル共重合体)としては酢酸ビニル含有量:32重量%のものを使用した。架橋助剤として表2示す化合物を各諸例ごとに変更して使用した。得られた組成物を150℃で熱プレス架橋(一次架橋)して厚さ1mmのシートを得た。シートの体積固有抵抗値を表3に示す方法で測定した。結果を表4に示した。
Claims (4)
- エチレン共重合体に架橋剤と共に架橋助剤としてウレタンポリ(メタ)アクリレートを配合して成ることを特徴とする熱架橋用樹脂組成物。
- エチレン共重合体に架橋助剤としてウレタンポリ(メタ)アクリレートを配合して成ることを特徴とする放射線架橋用樹脂組成物。
- 請求項1又は2に記載の架橋用樹脂組成物から成ることを特徴とする封止材。
- 太陽電池用である請求項3に記載の封止材。
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020157019611A KR20150119847A (ko) | 2013-02-21 | 2014-02-21 | 가교용 수지 조성물 및 봉지재 |
EP14754765.7A EP2960265B1 (en) | 2013-02-21 | 2014-02-21 | Crosslinking resin composition and sealing medium |
JP2015501513A JP6065098B2 (ja) | 2013-02-21 | 2014-02-21 | 架橋用樹脂組成物および封止材 |
US14/768,098 US9932471B2 (en) | 2013-02-21 | 2014-02-21 | Crosslinking resin composition and sealing material |
CN201480008919.3A CN105189590B (zh) | 2013-02-21 | 2014-02-21 | 交联用树脂组合物和封装材料 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2013-032283 | 2013-02-21 | ||
JP2013032283 | 2013-02-21 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2014129574A1 true WO2014129574A1 (ja) | 2014-08-28 |
Family
ID=51391355
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2014/054127 WO2014129574A1 (ja) | 2013-02-21 | 2014-02-21 | 架橋用樹脂組成物および封止材 |
Country Status (7)
Country | Link |
---|---|
US (1) | US9932471B2 (ja) |
EP (1) | EP2960265B1 (ja) |
JP (1) | JP6065098B2 (ja) |
KR (1) | KR20150119847A (ja) |
CN (1) | CN105189590B (ja) |
TW (1) | TWI640564B (ja) |
WO (1) | WO2014129574A1 (ja) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101981331B1 (ko) * | 2017-03-30 | 2019-05-22 | 에스케이씨에코솔루션즈(주) | 태양전지용 봉지재 및 이를 포함하는 태양전지 모듈 |
CN107057598B (zh) * | 2017-04-28 | 2021-02-02 | 西安泰力松新材料股份有限公司 | 用于无主栅太阳能电池组件的复合膜及其制备方法 |
CN107240861A (zh) * | 2017-07-18 | 2017-10-10 | 杭州大湛机电科技有限公司 | 基于制冷单元的纳米水离子发生装置及制冷单元制作方法 |
Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS56159207A (en) * | 1980-05-15 | 1981-12-08 | Hitachi Cable Ltd | Poly-alpha-olefin resin composition crosslinkable with radioactive ray |
JPS60226589A (ja) | 1984-04-24 | 1985-11-11 | Bridgestone Corp | 封止用組成物及び該組成物による封止方法 |
JPH04126711A (ja) * | 1990-09-19 | 1992-04-27 | Denki Kagaku Kogyo Kk | 高エネルギー線硬化性樹脂組成物 |
JPH0820620A (ja) * | 1994-07-06 | 1996-01-23 | Teijin Seiki Co Ltd | 光学的立体造形用樹脂組成物 |
JPH08259907A (ja) * | 1995-03-22 | 1996-10-08 | Nichiban Co Ltd | 熱硬化性接着シート |
JP2003051605A (ja) * | 2001-08-06 | 2003-02-21 | Haishiito Kogyo Kk | 太陽電池封止用シート |
JP2007123488A (ja) | 2005-10-27 | 2007-05-17 | Sekisui Chem Co Ltd | 太陽電池用接着シート |
JP2008024862A (ja) * | 2006-07-24 | 2008-02-07 | Denki Kagaku Kogyo Kk | 樹脂組成物および注型成形方法 |
JP2008144067A (ja) * | 2006-12-12 | 2008-06-26 | Nichiban Co Ltd | テープ状成形シーリング材 |
JP2009135200A (ja) | 2007-11-29 | 2009-06-18 | Bridgestone Corp | 太陽電池用封止膜及びこれを用いた太陽電池 |
JP2010073720A (ja) * | 2008-09-16 | 2010-04-02 | Konica Minolta Holdings Inc | 太陽電池モジュール |
JP2013112787A (ja) * | 2011-11-30 | 2013-06-10 | Mitsui Chemicals Tohcello Inc | 太陽電池封止用樹脂シートの製造方法 |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE69219465T2 (de) * | 1991-05-08 | 1997-10-09 | Minnesota Mining And Mfg. Co., Saint Paul, Minn. | Waschbare retroreflektierende applikationsarbeit |
US5679722A (en) | 1993-07-15 | 1997-10-21 | Teijin Seiki Co., Ltd. | Resin composition for production of a three-dimensional object by curing |
JP3173333B2 (ja) * | 1995-07-24 | 2001-06-04 | 松下電工株式会社 | プリプレグの製造方法 |
US5754338A (en) * | 1996-04-01 | 1998-05-19 | Minnesota Mining And Manufacturing Company | Structured retroreflective sheeting having a rivet-like connection |
JP2001348464A (ja) * | 2000-06-07 | 2001-12-18 | Shin Etsu Polymer Co Ltd | 高分子系マトリックス、およびその製造方法 |
WO2010055507A2 (en) * | 2008-11-12 | 2010-05-20 | Pythagoras Solar Inc. | Concentrating photovoltaic module |
CN102460724B (zh) * | 2009-06-05 | 2014-06-25 | 株式会社普利司通 | 太阳能电池用密封膜及使用了该密封膜的太阳能电池 |
JPWO2010143614A1 (ja) * | 2009-06-10 | 2012-11-22 | 旭硝子株式会社 | 太陽電池モジュールの製造方法 |
US20120309878A1 (en) | 2010-02-18 | 2012-12-06 | Bridgestone Corporation | Solar cell sealing film and solar cell using the sealing film |
JP2011210891A (ja) * | 2010-03-29 | 2011-10-20 | Hitachi Chem Co Ltd | 波長変換型太陽電池封止シート、及び太陽電池モジュール |
EP2557137A4 (en) * | 2010-04-09 | 2014-12-03 | Hitachi Chemical Co Ltd | BALL PHOSPHORUS, SEALING MATERIAL FOR A WAVELENGTH-CONVERTING SOLAR BATTERY, SOLAR BATTERY MODULE AND MANUFACTURING METHOD THEREFOR |
EP2579329A1 (en) * | 2010-05-26 | 2013-04-10 | Hitachi Chemical Company, Ltd. | Wavelength conversion-type solar cell sealing material, and solar cell module |
JP5859193B2 (ja) * | 2010-07-14 | 2016-02-10 | デンカ株式会社 | 多層粘着シート及び電子部品の製造方法 |
KR101279975B1 (ko) * | 2010-10-05 | 2013-07-05 | 제일모직주식회사 | 도체간 전기적 접속 재료 |
WO2014129573A1 (ja) * | 2013-02-21 | 2014-08-28 | 日本化成株式会社 | 架橋助剤およびその応用 |
-
2014
- 2014-02-21 JP JP2015501513A patent/JP6065098B2/ja active Active
- 2014-02-21 EP EP14754765.7A patent/EP2960265B1/en active Active
- 2014-02-21 TW TW103105846A patent/TWI640564B/zh active
- 2014-02-21 CN CN201480008919.3A patent/CN105189590B/zh active Active
- 2014-02-21 US US14/768,098 patent/US9932471B2/en active Active
- 2014-02-21 KR KR1020157019611A patent/KR20150119847A/ko not_active Application Discontinuation
- 2014-02-21 WO PCT/JP2014/054127 patent/WO2014129574A1/ja active Application Filing
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS56159207A (en) * | 1980-05-15 | 1981-12-08 | Hitachi Cable Ltd | Poly-alpha-olefin resin composition crosslinkable with radioactive ray |
JPS60226589A (ja) | 1984-04-24 | 1985-11-11 | Bridgestone Corp | 封止用組成物及び該組成物による封止方法 |
JPH04126711A (ja) * | 1990-09-19 | 1992-04-27 | Denki Kagaku Kogyo Kk | 高エネルギー線硬化性樹脂組成物 |
JPH0820620A (ja) * | 1994-07-06 | 1996-01-23 | Teijin Seiki Co Ltd | 光学的立体造形用樹脂組成物 |
JPH08259907A (ja) * | 1995-03-22 | 1996-10-08 | Nichiban Co Ltd | 熱硬化性接着シート |
JP2003051605A (ja) * | 2001-08-06 | 2003-02-21 | Haishiito Kogyo Kk | 太陽電池封止用シート |
JP2007123488A (ja) | 2005-10-27 | 2007-05-17 | Sekisui Chem Co Ltd | 太陽電池用接着シート |
JP2008024862A (ja) * | 2006-07-24 | 2008-02-07 | Denki Kagaku Kogyo Kk | 樹脂組成物および注型成形方法 |
JP2008144067A (ja) * | 2006-12-12 | 2008-06-26 | Nichiban Co Ltd | テープ状成形シーリング材 |
JP2009135200A (ja) | 2007-11-29 | 2009-06-18 | Bridgestone Corp | 太陽電池用封止膜及びこれを用いた太陽電池 |
JP2010073720A (ja) * | 2008-09-16 | 2010-04-02 | Konica Minolta Holdings Inc | 太陽電池モジュール |
JP2013112787A (ja) * | 2011-11-30 | 2013-06-10 | Mitsui Chemicals Tohcello Inc | 太陽電池封止用樹脂シートの製造方法 |
Non-Patent Citations (1)
Title |
---|
See also references of EP2960265A4 |
Also Published As
Publication number | Publication date |
---|---|
TWI640564B (zh) | 2018-11-11 |
US20150376389A1 (en) | 2015-12-31 |
CN105189590B (zh) | 2019-08-06 |
TW201504308A (zh) | 2015-02-01 |
US9932471B2 (en) | 2018-04-03 |
CN105189590A (zh) | 2015-12-23 |
JP6065098B2 (ja) | 2017-01-25 |
EP2960265B1 (en) | 2018-11-14 |
JPWO2014129574A1 (ja) | 2017-02-02 |
EP2960265A4 (en) | 2016-10-19 |
EP2960265A1 (en) | 2015-12-30 |
KR20150119847A (ko) | 2015-10-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5888466B2 (ja) | 架橋助剤およびその応用 | |
JP6065098B2 (ja) | 架橋用樹脂組成物および封止材 | |
EP2685508A1 (en) | Sealing film for solar cells and solar cell using same | |
JP2011190432A (ja) | 架橋性エラストマー用架橋剤およびその応用 | |
US9527983B2 (en) | Sealing material for solar cell and crosslinking aid | |
WO2011102231A1 (ja) | トリアジン誘導体およびその応用 | |
JP2011178993A (ja) | 架橋性エラストマー用架橋剤およびその応用 | |
WO2021079886A1 (ja) | 樹脂シート及びその製造方法 | |
JP2016216665A (ja) | 架橋用樹脂組成物の製造方法 | |
JP4343589B2 (ja) | 合わせガラスの製造方法 | |
JP2005001952A (ja) | 合わせガラス | |
JP2015083622A (ja) | オレフィン系樹脂組成物 | |
JP2015093946A (ja) | オレフィン系樹脂組成物 | |
JP2013112630A (ja) | トリメタリルイソシアヌレート誘導体オリゴマー及びその応用 | |
TW202411277A (zh) | 自由基聚合性組成物及其聚合物 | |
WO2014087772A1 (ja) | 架橋型樹脂組成物、硬化物およびその製造方法 | |
JP2017165887A (ja) | 絶縁膜形成用組成物およびそれを用いたゲート絶縁膜 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 201480008919.3 Country of ref document: CN |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 14754765 Country of ref document: EP Kind code of ref document: A1 |
|
ENP | Entry into the national phase |
Ref document number: 20157019611 Country of ref document: KR Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2014754765 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 14768098 Country of ref document: US |
|
ENP | Entry into the national phase |
Ref document number: 2015501513 Country of ref document: JP Kind code of ref document: A |
|
NENP | Non-entry into the national phase |
Ref country code: DE |