WO2014069049A1 - 成膜マスク - Google Patents
成膜マスク Download PDFInfo
- Publication number
- WO2014069049A1 WO2014069049A1 PCT/JP2013/069461 JP2013069461W WO2014069049A1 WO 2014069049 A1 WO2014069049 A1 WO 2014069049A1 JP 2013069461 W JP2013069461 W JP 2013069461W WO 2014069049 A1 WO2014069049 A1 WO 2014069049A1
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- WIPO (PCT)
- Prior art keywords
- film
- pattern
- metal member
- magnetic metal
- thin film
- Prior art date
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B12/00—Arrangements for controlling delivery; Arrangements for controlling the spray area
- B05B12/16—Arrangements for controlling delivery; Arrangements for controlling the spray area for controlling the spray area
- B05B12/20—Masking elements, i.e. elements defining uncoated areas on an object to be coated
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/04—Coating on selected surface areas, e.g. using masks
- C23C14/042—Coating on selected surface areas, e.g. using masks using masks
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C21/00—Accessories or implements for use in connection with applying liquids or other fluent materials to surfaces, not provided for in groups B05C1/00 - B05C19/00
- B05C21/005—Masking devices
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/027—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
- H01L21/033—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers
- H01L21/0332—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers characterised by their composition, e.g. multilayer masks, materials
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/10—Deposition of organic active material
- H10K71/16—Deposition of organic active material using physical vapour deposition [PVD], e.g. vacuum deposition or sputtering
- H10K71/164—Deposition of organic active material using physical vapour deposition [PVD], e.g. vacuum deposition or sputtering using vacuum deposition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/32—Processes for applying liquids or other fluent materials using means for protecting parts of a surface not to be coated, e.g. using stencils, resists
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/04—Coating on selected surface areas, e.g. using masks
- C23C16/042—Coating on selected surface areas, e.g. using masks using masks
Definitions
- the present invention relates to a film formation mask, and more particularly, to a film formation mask that enables the deposition of a thin film pattern having a uniform thickness by eliminating the influence of the deposition shadow caused by the edge of the opening through which the deposition material passes on the film formation. It is concerned.
- a conventional film formation mask is formed of three metal layers including a thin opening pattern forming layer, a relatively thick support layer, and a bonding layer for bonding the opening pattern forming layer and the support layer.
- the support layer and the bonding layer were etched to form through openings that penetrate each of these layers (see, for example, Patent Document 1).
- the opening pattern forming layer and the support layer are etched using separate resist patterns, the opening pattern forming layer is provided with an opening pattern having a minimum width, and the supporting layer has a larger width than the opening pattern. A hole was provided.
- the opening pattern is a through-hole without considering the influence on the film formation of the shadow of vapor deposition determined by the thickness of the support layer and the maximum incident angle of the vapor deposition material on the mask surface. Therefore, when the alignment of each resist pattern that forms the opening pattern and the through hole is shifted, a part of the opening pattern is covered with the shadow portion of the deposition, and the film thickness is uniform on the substrate. There was a possibility that a thin film pattern could not be formed.
- An object of the present invention is to provide a film formation mask.
- a film formation mask is a film formation mask for forming a thin film pattern by depositing a vapor deposition material on a substrate, and is formed at a position corresponding to the thin film pattern.
- a thin plate-like magnetic metal member provided with a through-hole having a larger dimension than the thin-film pattern, and a close contact with one surface of the magnetic metal member, the position corresponding to the thin-film pattern in the through-hole
- the film-forming mask according to the second invention is a film-forming mask for forming a plurality of thin-film patterns by depositing a deposition material on a substrate and arranging them at a constant arrangement pitch, and the same arrangement as the thin-film pattern.
- a thin plate-like magnetic metal member provided with a through hole having a larger dimension than the thin film pattern arranged in a pitch, and provided in close contact with one surface of the magnetic metal member, corresponding to the thin film pattern in the through hole
- the width of the opening pattern formation region in the same direction as the arrangement direction of the through holes is at least the width of the opening pattern in the same direction as the arrangement direction of the through holes. It is desirable to be equal to a value obtained by adding a double value of the positional deviation allowable value.
- the width in the alignment direction of the through holes is the width of the area of the shadow of vapor deposition in the same direction as the alignment direction of the through holes to the width of the opening pattern formation region in the same direction as the alignment direction of the through holes. It is desirable to be equal to a value obtained by adding a double value of.
- the magnetic metal member may be nickel, nickel alloy, invar, or invar alloy.
- the film may be polyimide.
- one end face of a frame-like frame provided with an opening having a size including the through hole is joined to a peripheral area of one face of the magnetic metal member.
- the present invention it is possible to deposit a thin film pattern having a uniform thickness by eliminating the influence of the deposition shadow caused by the edge of the through hole of the magnetic metal member on the film formation. Therefore, for example, when the organic EL layer of the organic EL display panel is formed by vapor deposition, the organic EL layer having a uniform film thickness can be formed, and uniform light emission characteristics can be obtained over the entire display panel.
- FIG. 2 is a view as seen from an arrow A in which a partial cross section of FIG. It is process drawing explaining manufacture of the film-forming mask by this invention, and is sectional drawing which shows the process before opening pattern formation. It is sectional drawing explaining the formation process of the said opening pattern, and shows the case where there is no misalignment with the reference
- FIG. 1 is a perspective view showing an embodiment of a film-forming mask according to the present invention
- FIG. 2 is an enlarged view of a part of FIG.
- This film formation mask is for depositing a vapor deposition material on a substrate and arranging it at a constant arrangement pitch to form a plurality of thin film patterns, and includes a magnetic metal member 1, a film 2, and a frame 3. It is configured.
- the magnetic metal member 1 is in the form of a thin plate (sheet) made of a magnetic metal material such as nickel, nickel alloy, invar or invar alloy having a thickness of about 30 ⁇ m to 50 ⁇ m, and is arranged at the same arrangement pitch as the thin film pattern.
- a through hole 4 having a larger shape than the pattern is provided.
- a film 2 is provided in close contact with one surface of the magnetic metal member 1.
- This film 2 is a resin film that transmits visible light such as polyimide or polyethylene terephthalate (PET) having a thickness of about 10 ⁇ m to 30 ⁇ m, and corresponds to a thin film pattern in the through hole 4 of the magnetic metal member 1.
- An opening pattern 5 having the same shape and dimension as the thin film pattern is formed at the position.
- the opening pattern 5 is a shadow region of vapor deposition determined by the thickness t of the magnetic metal member 1 and the maximum incident angle ⁇ of the vapor deposition material on the surface of the film 2 in the through hole 4.
- 6 is formed in the opening pattern forming region 7 surrounded by (t ⁇ tan ⁇ ).
- the width W1 of the opening pattern forming region 7 in the same direction as the arrangement direction of the through holes 4 is at least the same as the arrangement direction of the through holes 4 (X direction). It is desirable to be equal to the value (W2 + 2 ⁇ ) obtained by adding the double value of the positional deviation allowable value ⁇ of the opening pattern 5 in the same direction to the width W2 of the opening pattern 5 in the direction. That is, it is desirable that W1 ⁇ (W2 + 2 ⁇ ).
- the width W1 in the X direction of the opening pattern formation region 7 is a value obtained by adding a double value of the positional deviation allowable value ⁇ of the opening pattern 5 in the same direction to at least the width W2 of the opening pattern 5 in the X direction ( In order to make the width equal to W2 + 2 ⁇ ), at least one of the thickness t of the magnetic metal member 1 and the width W3 in the adjacent direction (X direction) of the portion between the adjacent through holes 4 of the magnetic metal member 1 Adjust one.
- the thickness t of the magnetic metal member 1 is set to a thickness that can secure sufficient rigidity, and is then surrounded by the shadowing shadow region 6.
- the width W3 in the X direction of the portion between the adjacent through holes 4 of the magnetic metal member 1 is preferably determined so that the width W1 in the X direction of the opening pattern forming region 7 is equal to (W2 + 2 ⁇ ).
- the opening pattern forming region It is preferable to determine the thickness t of the magnetic metal member 1 and adjust the width of the shadow region 6 of the vapor deposition so that the width W1 in the X direction 7 is equal to at least (W2 + 2 ⁇ ).
- a frame-like frame 3 provided with an opening 8 (see FIG. 3D) having a size including a plurality of through holes 4 is joined to the peripheral region of one surface of the magnetic metal member 1 by joining one end surface 3a. Is provided.
- the frame 3 supports the stretched magnetic metal member 1 and the film 2 and is made of invar or invar alloy having a thickness of several mm to several tens of mm and a small thermal expansion coefficient.
- Opening width of opening pattern 5 stripe pattern: W2 ⁇ Pitch of opening pattern 5: P -Tolerable value of positional deviation of the opening pattern 5: ⁇
- liquid polyimide is spray-coated on one surface of a magnetic metal member 1 made of a sheet-like invar having a thickness t, and then dried to form a polyimide film 2 having a uniform thickness (FIG. 3A). reference).
- the photoresist is exposed using, for example, a photomask having an opening in a portion where the through hole 4 is to be formed.
- development is performed to form a resist mask 10 having an opening 9 in a portion where the through hole 4 is to be formed (see FIG. 3B).
- the magnetic metal member 1 is etched using the resist mask 10.
- stripe-shaped through holes 4 having a width W4 reaching the surface of the film 2 are formed at the arrangement pitch P in the magnetic metal member 1 (see FIG. 3C).
- the etching solution to be used is appropriately selected according to the material of the magnetic metal member 1.
- the portion of the film 2 corresponding to the peripheral region of the magnetic metal member 1 is removed by laser processing to expose the peripheral region of the magnetic metal member 1, and then the magnetic metal member 1 with the film 2 is removed.
- the frame 3 is stretched over one end surface 3a of the frame-shaped frame 3, and the peripheral edge of the magnetic metal member 1 and one end surface 3a of the frame 3 are spot welded to join the frame 3 to the magnetic metal member 1 (FIG. 3D). reference).
- the magnetic metal member 1 with the film 2 provided with the through holes 4 is positioned and placed on a reference substrate 12 on which a reference pattern 11 to be a target for forming the opening pattern 5 is formed in advance.
- the film 2 is placed on the reference substrate 12 so as to be on the reference substrate 12 side (see FIG. 3E).
- the reference substrate 12 may be configured such that the surface 12a on which the reference pattern 11 is formed is on the lower side, and the film 2 is brought into close contact with the surface 12b opposite to the surface 12a.
- the film 2 corresponding to the reference pattern 11 is irradiated with the laser beam L using, for example, an excimer laser having a wavelength of 400 nm or less, for example, KrF248 nm, and the film 2 is laser processed.
- a stripe-shaped opening pattern 5 having a width W2 is formed on the film 2 (see FIGS. 4A and 4B).
- the reference pattern 11 is imaged in advance by an imaging camera, the position of the reference pattern 11 is detected, and the reference substrate 12 side and a laser processing apparatus (not shown) are relatively moved based on the detection result to move the laser beam. After positioning L on the reference pattern 11, laser processing of the film 2 is performed.
- FIGS. 4A and 4B show a case where there is no positional deviation in the alignment between the reference substrate 12 and the magnetic metal member 1.
- the opening pattern 5 is formed at the center of the through hole 4 of the magnetic metal member 1, and naturally, the influence of the shadow of the vapor deposition can be eliminated during the vapor deposition.
- the position of the opening pattern 5 formed by laser processing is the same.
- the magnetic metal member 1 is formed to be shifted from the center of the through hole 4 in the X direction by a maximum ⁇ .
- the width W4 of the through hole 4 of the magnetic metal member 1 is formed to be (W2 + 2 ⁇ + 2t ⁇ tan ⁇ )
- the opening pattern 5 is It is formed in the region surrounded by the shadow region 6 of the vapor deposition, and the influence of the vapor deposition shadow on the film formation during the vapor deposition can be eliminated.
- the film forming mask for forming the thin film patterns by arranging them at a constant arrangement pitch has been described.
- the present invention is not limited to this, and the arrangement of the thin film patterns may be irregular.
- the opening pattern 5 of the film formation mask is surrounded by the deposition shadow region 6 determined by the thickness of the magnetic metal member 1 and the maximum incident angle ⁇ of the deposition material on the surface of the film 2 in the through hole 4. If it is provided in the opening pattern formation region 7, it is possible to eliminate the influence of the shadow of the vapor deposition on the film formation during vapor deposition, and a thin film pattern having a uniform thickness can be formed.
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Abstract
Description
また、前記フィルムは、ポリイミドであるとよい。
(成膜マスクの仕様)
・開口パターン5(ストライプパターン)の開口幅:W2
・開口パターン5の配列ピッチ:P
・開口パターン5の位置ずれの許容値:α
先ず、厚みがtのシート状のインバーからなる磁性金属部材1の一面に例えば液状のポリイミドをスプレー塗布した後、乾燥させて、均一な厚みのポリイミドのフィルム2を形成する(図3(a)参照)。
W4=W1+2t×tanθ
=W2+2α+2t×tanθ
となる。したがって、レジストマスク10の開口9は、幅がW4のストライプパターンである。
W3=P-W4
=P-W2-2(α+t×tanθ)
となる。
2…フィルム
3…フレーム
4…貫通孔
5…開口パターン
6…蒸着の影の領域
7…開口パターン形成領域
8…フレームの開口
Claims (7)
- 基板上に蒸着材料を被着させて薄膜パターンを形成するための成膜マスクであって、
前記薄膜パターンに対応した位置に該薄膜パターンよりも形状寸法の大きい貫通孔を設けた薄板状の磁性金属部材と、
前記磁性金属部材の一面に密接して設けられ、前記貫通孔内にて前記薄膜パターンに対応した位置に該薄膜パターンと形状寸法の同じ開口パターンを形成した可視光を透過する樹脂製のフィルムと、
を備え、
前記開口パターンは、前記貫通孔内にて前記磁性金属部材の厚みと前記蒸着材料の前記フィルム面への最大入射角度とにより決まる蒸着の影の領域によって囲まれた開口パターン形成領域内に設けられていることを特徴とする成膜マスク。 - 基板上に蒸着材料を被着させて一定の配列ピッチで並べて複数の薄膜パターンを形成するための成膜マスクであって、
前記薄膜パターンと同じ配列ピッチで並べて該薄膜パターンよりも形状寸法の大きい貫通孔を設けた薄板状の磁性金属部材と、
前記磁性金属部材の一面に密接して設けられ、前記貫通孔内にて前記薄膜パターンに対応した位置に該薄膜パターンと形状寸法の同じ開口パターンを形成した可視光を透過する樹脂製のフィルムと、
を備え、
前記開口パターンは、前記貫通孔内にて前記磁性金属部材の厚みと前記蒸着材料の前記フィルム面への最大入射角度とにより決まる蒸着の影の領域によって囲まれた開口パターン形成領域内に設けられていることを特徴とする成膜マスク。 - 前記開口パターン形成領域の前記貫通孔の並び方向と同方向の幅は、少なくとも前記貫通孔の並び方向と同方向の前記開口パターンの幅に、同方向の前記開口パターンの位置ずれ許容値の2倍値を加算した値に等しいことを特徴とする請求項2記載の成膜マスク。
- 前記貫通孔の並び方向の幅は、前記貫通孔の並び方向と同方向の前記開口パターン形成領域の幅に前記貫通孔の並び方向と同方向の前記蒸着の影の領域の幅の2倍値を加算した値に等しいことを特徴とする請求項3記載の成膜マスク。
- 前記磁性金属部材は、ニッケル、ニッケル合金、インバー又はインバー合金であることを特徴とする請求項1~4のいずれか1項に記載の成膜マスク。
- 前記フィルムは、ポリイミドであることを特徴とする請求項1~4のいずれか1項に記載の成膜マスク。
- 前記貫通孔を内包する大きさの開口を設けた枠状のフレームの一端面を前記磁性金属部材の一面の周縁領域に接合して備えたことを特徴とする請求項1~4のいずれか1項に記載の成膜マスク。
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
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CN201380057122.8A CN104755648B (zh) | 2012-10-30 | 2013-07-18 | 成膜掩膜 |
KR1020157014244A KR102155258B1 (ko) | 2012-10-30 | 2013-07-18 | 성막 마스크 |
US14/439,309 US10035162B2 (en) | 2012-10-30 | 2013-07-18 | Deposition mask for forming thin-film patterns |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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JP2012238956A JP2014088594A (ja) | 2012-10-30 | 2012-10-30 | 蒸着マスク |
JP2012-238956 | 2012-10-30 |
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WO2014069049A1 true WO2014069049A1 (ja) | 2014-05-08 |
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PCT/JP2013/069461 WO2014069049A1 (ja) | 2012-10-30 | 2013-07-18 | 成膜マスク |
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US (1) | US10035162B2 (ja) |
JP (1) | JP2014088594A (ja) |
KR (1) | KR102155258B1 (ja) |
CN (1) | CN104755648B (ja) |
TW (1) | TWI588277B (ja) |
WO (1) | WO2014069049A1 (ja) |
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JP6035548B2 (ja) * | 2013-04-11 | 2016-11-30 | 株式会社ブイ・テクノロジー | 蒸着マスク |
US10892415B2 (en) * | 2016-03-10 | 2021-01-12 | Hon Hai Precision Industry Co., Ltd. | Deposition mask, vapor deposition apparatus, vapor deposition method, and method for manufacturing organic EL display apparatus |
CN110144547B (zh) * | 2016-04-14 | 2021-06-01 | 凸版印刷株式会社 | 蒸镀掩模用基材、蒸镀掩模用基材的制造方法及蒸镀掩模的制造方法 |
TWI678824B (zh) * | 2016-07-29 | 2019-12-01 | 鴻海精密工業股份有限公司 | 掩膜及其製備方法 |
CN109643057A (zh) * | 2017-07-21 | 2019-04-16 | 深圳市柔宇科技有限公司 | 掩膜板的制造方法和掩膜板 |
JP6319505B1 (ja) | 2017-09-08 | 2018-05-09 | 凸版印刷株式会社 | 蒸着マスク用基材、蒸着マスク用基材の製造方法、蒸着マスクの製造方法および表示装置の製造方法 |
CN107641786B (zh) * | 2017-09-27 | 2020-04-14 | 京东方科技集团股份有限公司 | 掩模板及掩模板制作方法 |
JP6299921B1 (ja) | 2017-10-13 | 2018-03-28 | 凸版印刷株式会社 | 蒸着マスク用基材、蒸着マスク用基材の製造方法、蒸着マスクの製造方法、および、表示装置の製造方法 |
US10886452B2 (en) * | 2018-01-25 | 2021-01-05 | United States Of America As Represented By The Administrator Of Nasa | Selective and direct deposition technique for streamlined CMOS processing |
CN108441817B (zh) * | 2018-06-22 | 2020-03-31 | 京东方科技集团股份有限公司 | 掩模板 |
KR20210091382A (ko) * | 2020-01-13 | 2021-07-22 | 삼성디스플레이 주식회사 | 마스크, 이의 제조 방법, 및 표시 패널 제조 방법 |
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- 2013-07-18 CN CN201380057122.8A patent/CN104755648B/zh active Active
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TW201422829A (zh) | 2014-06-16 |
CN104755648B (zh) | 2018-04-03 |
KR102155258B1 (ko) | 2020-09-11 |
US10035162B2 (en) | 2018-07-31 |
KR20150079908A (ko) | 2015-07-08 |
US20150290667A1 (en) | 2015-10-15 |
JP2014088594A (ja) | 2014-05-15 |
CN104755648A (zh) | 2015-07-01 |
TWI588277B (zh) | 2017-06-21 |
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