WO2014038203A1 - 固体電解コンデンサ - Google Patents
固体電解コンデンサ Download PDFInfo
- Publication number
- WO2014038203A1 WO2014038203A1 PCT/JP2013/005256 JP2013005256W WO2014038203A1 WO 2014038203 A1 WO2014038203 A1 WO 2014038203A1 JP 2013005256 W JP2013005256 W JP 2013005256W WO 2014038203 A1 WO2014038203 A1 WO 2014038203A1
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- WO
- WIPO (PCT)
- Prior art keywords
- cathode
- mounting
- solid electrolytic
- electrolytic capacitor
- storage
- Prior art date
Links
- 239000003990 capacitor Substances 0.000 title claims abstract description 65
- 239000007787 solid Substances 0.000 title claims abstract description 49
- 229920005989 resin Polymers 0.000 claims abstract description 52
- 239000011347 resin Substances 0.000 claims abstract description 52
- 239000000853 adhesive Substances 0.000 claims abstract description 47
- 230000001070 adhesive effect Effects 0.000 claims abstract description 47
- 238000003860 storage Methods 0.000 claims description 66
- 230000001154 acute effect Effects 0.000 claims description 6
- 230000004308 accommodation Effects 0.000 abstract 2
- 239000007784 solid electrolyte Substances 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 238000005452 bending Methods 0.000 description 3
- 229920001940 conductive polymer Polymers 0.000 description 3
- 239000003822 epoxy resin Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229920000647 polyepoxide Polymers 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000011231 conductive filler Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000009719 polyimide resin Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000128 polypyrrole Polymers 0.000 description 1
- 229920000123 polythiophene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 238000005476 soldering Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000001721 transfer moulding Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/15—Solid electrolytic capacitors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/008—Terminals
- H01G9/012—Terminals specially adapted for solid capacitors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/04—Electrodes or formation of dielectric layers thereon
- H01G9/048—Electrodes or formation of dielectric layers thereon characterised by their structure
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/08—Housing; Encapsulation
- H01G9/10—Sealing, e.g. of lead-in wires
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/14—Structural combinations or circuits for modifying, or compensating for, electric characteristics of electrolytic capacitors
Definitions
- the present invention relates to a solid electrolytic capacitor having a capacitor element and a pair of terminals connected to the capacitor element.
- FIG. 8 is a perspective view of a conventional solid electrolytic capacitor.
- the solid electrolytic capacitor includes a capacitor element (hereinafter referred to as element) 51, a cathode terminal 52, an anode terminal 53, and an exterior resin portion 54.
- the cathode terminal 52 is connected to the cathode portion of the element 51, and the anode terminal 53 is connected to the anode portion.
- the exterior resin portion 54 covers the elements 51 and part of the cathode terminal 52 and the anode terminal 53. A part of the cathode terminal 52 and the anode terminal 53 is exposed from the side surface of the exterior resin portion 54 and is bent from the side surface along the lower surface.
- the element 51 uses a conductive polymer having excellent conductivity as a solid electrolyte layer. Therefore, the ESR of the element 51 is small.
- the surface on which the dielectric oxide film is formed is etched. By increasing the surface area in this way, the element 51 has a large capacity.
- the anode terminal 53 is welded to the anode part of the element 51.
- the cathode terminal 52 is bent into an L shape inside the exterior resin portion 54 to form a mounting portion 55.
- the mounting portion 55 is joined to the lower surface of the cathode portion of the element 51 through a conductive adhesive portion (not shown) formed of a conductive paste.
- the cathode terminal 52 further has a holder portion 56.
- the holder portion 56 is fitted into a notch provided on the side surface of the element 51 on the end portion side of the cathode portion, and is joined to the side surface of the cathode portion via the conductive adhesive portion 57.
- the solid electrolytic capacitor of the present invention has a capacitor element, a cathode terminal, an anode terminal, and an exterior resin part covering the capacitor element.
- the cathode terminal and the anode terminal are respectively joined to the cathode part and the anode part of the capacitor element.
- the cathode terminal has a mounting portion, a protruding portion, and a storage portion.
- the mounting portion has a cathode portion and is joined to the lower surface of the cathode portion via a conductive adhesive portion.
- the protruding portion protrudes from the side of the mounting portion on the same surface as the mounting portion, and its width is gradually reduced in the protruding direction.
- the storage portion is provided adjacent to the side of the projecting portion that is gradually narrowed, and stores a part of the conductive adhesive portion.
- the storage portion By providing the storage portion in this way, the thickness of the conductive adhesive portion protruding from the cathode terminal can be reduced. As a result, since the conductive adhesive portion can be prevented from being exposed to the mounting surface, a solid electrolytic capacitor having a large capacity and a small ESR can be provided.
- FIG. 1 is a front sectional view of a solid electrolytic capacitor according to an embodiment of the present invention.
- 2 is a bottom view of the solid electrolytic capacitor shown in FIG.
- FIG. 3A is an enlarged plan view of a main part showing conductive adhesive portions housed in first and second housing portions provided on a cathode terminal of the solid electrolytic capacitor shown in FIG.
- FIG. 3B is an enlarged plan view of a main part showing conductive adhesive portions housed in first and second housing portions provided on other cathode terminals of the solid electrolytic capacitor shown in FIG. 1.
- 4 is a cross-sectional view taken along line 4-4 of the solid electrolytic capacitor shown in FIG.
- FIG. 5 is a cross-sectional view of the solid electrolytic capacitor shown in FIG. 1 taken along line 5-5.
- FIG. 6 is a cross-sectional view of the solid electrolytic capacitor shown in FIG. 1 taken along line 6-6.
- 7 is a cross-sectional view of the capacitor element of the solid electrolytic capacitor shown in FIG.
- FIG. 8 is a perspective view of a conventional solid electrolytic capacitor.
- the exterior resin portion 54 may be thinned to increase the storage efficiency of the element 51.
- the exterior resin portion 54 it is conceivable to provide a conductive resin portion so as to protrude from the cathode terminal 52.
- the exterior resin portion 54 is made thin, the conductive resin portion that protrudes from the cathode terminal 52 is exposed from the lower surface of the exterior resin portion 54, and the solid electrolytic capacitor may short-circuit the wiring of the circuit board.
- FIG. 1 and 2 are a front sectional view and a bottom view of a solid electrolytic capacitor according to an embodiment of the present invention.
- FIG. 3A is an enlarged plan view of a main part showing the first adhesive portion 35 and the conductive adhesive portion 25 accommodated in the second accommodating portion 36 provided in the cathode terminal 20 of the solid electrolytic capacitor shown in FIG. 4 is a cross-sectional view taken along line 4-4 of the solid electrolytic capacitor shown in FIG.
- FIG. 5 is a cross-sectional view taken along line 5-5 of the solid electrolytic capacitor shown in FIG. 6 is a cross-sectional view taken along line 6-6 of the solid electrolytic capacitor shown in FIG.
- FIG. 7 is a cross-sectional view of the capacitor element (hereinafter referred to as element) 10 of the solid electrolytic capacitor shown in FIG.
- the solid electrolytic capacitor according to the present embodiment includes a plurality of flat elements 10, a cathode terminal 20, an anode terminal 21, and an exterior resin portion 23.
- Each element 10 has a cathode portion 11 and an anode portion 12.
- the cathode terminal 20 is bonded to the stacked cathode portions 11.
- the anode terminal 21 is joined to the laminated anode portion 12.
- the exterior resin portion 23 covers a part of the cathode terminal 20 and the anode terminal 21 and the stacked element 10.
- One element 10 may be provided.
- the anode portion 12 of the element 10 is provided at the first end of a foil anode body 13 made of an aluminum valve metal, and the cathode portion 11 is an insulating separation portion 17 provided in a strip shape. Are provided at the second end of the anode body 13 divided by.
- valve action metal tantalum, niobium, titanium or the like can be used in addition to aluminum.
- the part which has formed the cathode part 11 in the anode body 13 may be a porous sintered body formed of valve action metal powder.
- the cathode portion 11 has a dielectric oxide film 14 formed on the surface of the anode body 13, a solid electrolyte layer 15, and a cathode layer 16.
- the solid electrolyte layer 15 is composed of a conductive polymer formed on the dielectric oxide film 14.
- the cathode layer 16 is formed by laminating a silver paste layer on a carbon layer. The solid electrolyte layer 15 and the cathode layer 16 are formed on the dielectric oxide film 14 in this order.
- polypyrrole, polythiophene, polyaniline, or the like can be used as the conductive polymer of the solid electrolyte layer 15. These polymers have high conductivity and excellent ESR characteristics. Note that manganese oxide such as manganese dioxide can also be used for the solid electrolyte layer 15.
- the exterior resin part 23 is composed of a heat-resistant insulating resin such as an epoxy resin.
- the cathode terminal 20 and the anode terminal 21 are composed of a lead frame made of a metal such as copper, iron or nickel, or an alloy thereof.
- the cathode terminal 20 and the anode terminal 21 respectively have lower steps 30 and 40 as shown in FIGS.
- the lower steps 30 and 40 are exposed on the mounting surface 24 of the solid electrolytic capacitor. More specifically, the lower surfaces of the lower steps 30 and 40 are flush with the lower surface of the exterior resin portion 23.
- an exterior resin portion 23 is provided on the upper surface of the lower step portions 30 and 40, and among the stacked elements 10, the cathode portion 11 of the lowest element 10 ⁇ / b> A and the lower step portion 30.
- the exterior resin part 23 is provided between the two.
- an exterior resin portion 23 is provided between the anode portion 12 and the lower step portion 40 of the element 10A.
- the lower step portions 30 and 40 are preferably substantially rectangular and have the same mounting area.
- the direction connecting the anode portion 12 and the cathode portion 11 is referred to as the length direction
- the side close to the anode portion 12 in the length direction is referred to as the anode side
- the side close to the cathode portion 11 is referred to as the cathode side.
- a direction perpendicular to the length direction is referred to as a width direction.
- the lower step portion 30 extends in the length direction from the cathode side end portion toward the anode side on the mounting surface 24, and the lower step portion 40 extends in the length direction from the anode side end portion of the mounting surface 24 toward the cathode side. It extends to.
- the tip portions exposed from the exterior resin portion 23 of the cathode terminal 20 and the anode terminal 21 extend from the end portions of the lower step portions 30 and 40 along the end surface of the solid electrolytic capacitor constituted by the exterior resin portion 23. And bent upward.
- a plating layer for soldering to the circuit board is provided at the lower stage portions 30 and 40 and the tip portions of the anode terminal 21 and the cathode terminal 20 bent along the end surface.
- the cathode terminal 20 further includes a mounting portion 31 that is bonded to the lower surface of the cathode portion 11 of the element 10 ⁇ / b> A via the conductive adhesive portion 22.
- the mounting portion 31 is connected to the anode-side end portion of the lower step portion 30 via a cathode connection portion (hereinafter, connection portion) 32. That is, the mounting portion 31 is connected to the end portion of the lower step portion 30 close to the anode terminal 21.
- the mounting portion 31 and the connection portion 32 are provided with the same width as the lower step portion 30.
- the conductive adhesive portion 22 includes a conductive filler such as silver or copper as a main component, a thermosetting resin such as an epoxy resin, a urethane resin, a silicone resin, an acrylic resin, or a polyimide resin, or a binder of a thermoplastic resin. ing.
- the conductive adhesive portion 22 is formed using a conductive paste in which a conductive filler, a binder, and a solvent are mixed.
- the cathode terminal 20 includes the lower step portion 30, the connection portion 32, and the mounting portion 31.
- the connection portion 32 is formed by being bent vertically or obliquely upward over the entire width of the end portion on the anode side of the lower step portion 30 and embedded in the exterior resin portion 23.
- the mounting portion 31 is provided at the upper end of the connection portion 32 bent upward.
- the shape which connected the lower stage part 30 and the mounting part 31 is step shape.
- the mounting portion 31 is provided on the anode side with respect to the lower step portion 30, and the exterior resin portion 23 is provided on the lower surface of the mounting portion 31. Furthermore, the upper surface of the mounting portion 31 is flat, and is parallel to the mounting surface 24 with a predetermined interval. In the length direction, the center of the mounting portion 31 is preferably provided closer to the cathode than the center of the cathode portion 11.
- the cathode terminal 20 further includes protrusions 34 provided in pairs along both sides of the mounting portion 31. As shown in FIG. The protruding portion 34 protrudes from the side along the length direction of the mounting portion 31 and extends in the same plane as the mounting portion 31 along the width direction. The width of the protrusion 34 is gradually reduced toward the protrusion direction. Further, the projecting portion 34 is provided with a storage portion 60 formed of a conductive paste that is formed of a conductive paste that protrudes from the cathode terminal 20 and has a vertex that intersects two sides. . That is, the storage portion 60 is provided adjacent to the side of the projecting portion 34 that is gradually narrowed. The storage unit 60 stores the conductive adhesive portion 25 that is a part of the conductive adhesive portion 22.
- the conductive adhesive portion 22 is provided between the upper surface of the mounting portion 31 and the lower surface of the cathode portion 11 of the element 10A, and joins the mounting portion 31 and the cathode portion 11 together. A part of the conductive adhesive portion 22 is also provided on the upper surface of the protruding portion 34.
- the holder portion 33 is joined to the cathode portion 11 via the conductive adhesive portion 22 provided between the side portion of the cathode portion 11 and the holder portion 33.
- the conductive adhesive portion 22 provided on the projecting portion 34 may be continuous with the conductive adhesive portion 22 provided on the holder portion 33 or may be separated.
- the storage unit 60 preferably includes at least a first storage unit 35 and a second storage unit 36.
- the first storage unit 35 includes a side 31A of the mounting unit 31 and a first side 61 of the protrusion 34 connected to the side 31A in plan view. That is, the first storage portion 35 is a boundary between the mounting portion 31 and the protruding portion 34.
- the second storage portion 36 includes a second side 62 and a third side 63 that are connected to each other in a plan view.
- the conductive paste for forming the conductive adhesive portion 22 protrudes from the mounting portion 31 or the protruding portion 34 and is stored in the storage portion 60.
- the cathode portion 11 and the cathode terminal 20 can be reliably bonded, and ESR can be reduced.
- the conductive paste is applied to the upper surface of the cathode terminal 20 or the lower surface of the cathode portion 11 from the mounting portion 31 to the protruding portion 34 substantially along the length direction. Subsequently, the element 10 stacked on the mounting portion 31 is pressurized at the substantially central portion of the cathode portion 11 from above. In this way, the element 10 is in close contact with the mounting portion 31. During this pressurization, the conductive paste is pushed out from the side of the protrusion 34.
- the amount of the conductive paste that is pushed out increases as it is closer to the mounting portion 31, and further increases in the vicinity of the apex where the side 31 ⁇ / b> A of the mounting portion 31 intersects the first side 61 of the protruding portion 34. Therefore, by providing the storage portion 60, it is possible to prevent the conductive adhesive portion 25 protruding from the cathode terminal 20 from being exposed from the exterior resin portion 23.
- the conductive adhesive portion 25 is formed thicker in the bent portion 35A of the first storage portion 35.
- the amount of conductive paste flowing into the first storage portion 35 can be reduced as compared with the case where only the first storage portion 35 is provided. That is, the conductive adhesive portion 25 that cannot be accommodated in the first accommodating portion 35 can be accommodated in the second accommodating portion 36.
- the conductive adhesive portion 25 is also thick at the bent portion 36A of the second storage portion 36. It is formed.
- the first storage portion 35 and the second storage portion 36 are provided as a pair on both sides of the protrusion portion 34, and the protrusion portion 34 gradually decreases in width as it moves away from the mounting portion 31. ing. Furthermore, in the 1st accommodating part 35 and the 2nd accommodating part 36, the angle which a side intersects is a substantially right angle. Thus, it is preferable that the storage unit 60 is provided in a stepped manner by the first storage unit 35 and the second storage unit 36. By providing the storage portion 60 in a stepped shape, the conductive paste easily protrudes from the second storage portion 36, and the effect of preventing the conductive adhesive portion 25 from being exposed from the exterior resin portion 23 can be enhanced.
- the cathode terminal 20 is provided with the support portion 38 having the upper step portion 39 as will be described later, the conductive paste protruding from the first storage portion 35 spreads when the conductive adhesive portion 22 is formed on the mounting portion 31. It can be prevented that the upper stage 39 is reached.
- the curvature radius R inside the bent portion 35A of the first storage portion 35 is preferably larger than the curvature radius inside the bent portion 36A of the second storage portion 36. That is, in the first storage portion 35, the portion where the side 31A of the mounting portion 31 and the first side 61 are connected has a bent portion 35A that is a first curved portion. A portion where the side 62 and the third side 63 are connected has a bent portion 36A that is a second curved portion. In this case, it is preferable that the curvature radius of the first curved portion is larger than the curvature radius of the second curved portion.
- the second storage portion 361 may be formed so that the angle at which the second side 62 and the third side 63 intersect is an acute angle.
- FIG. 3B is an enlarged plan view of the main part showing the first adhesive part 35 and the conductive adhesive part 25 accommodated in the second accommodating part 361 provided on the other cathode terminal of the solid electrolytic capacitor shown in FIG.
- the angle at which the side 31A and the first side 61 intersect may be an acute angle.
- the internal angle of the first storage unit 35 and the second storage unit 36 (361) may be a right angle or an acute angle, and at least one of the internal angles may be an acute angle.
- the inner angle of the second storage part 36 (361) is preferably smaller than the inner angle of the first storage part 35. That is, the angle at which the second side edge 62 and the third side edge 63 intersect is preferably smaller than the angle at which the side edge 31A of the mounting portion 31 and the first side edge 61 intersect. The reason for this is the same as providing a magnitude relationship in the radius of curvature.
- the protruding conductive adhesive portion 25 is formed separately in the region of the first storage portion 35 and in the region of the second storage portion 36 or the second storage portion 361, respectively.
- the conductive adhesive portion 25 may be integrally formed so as to protrude from the apex where the first side 61 and the second side 62 intersect.
- a cathode holder part (hereinafter, a holder part) 33 at the tip of the protruding part 34.
- the holder portion 33 is formed by bending the tip portion of the mounting portion 31 upward substantially vertically. That is, the holder portion 33 extends from the protruding portion 34 in the stacking direction of the elements 10.
- the cathode portion 11 is preferably provided with a notch portion 18.
- the notches 18 are provided on both sides of the cathode portion 11 away from the end of the cathode portion 11.
- the holder part 33 fits into the notch part 18 of the cathode part 11, and is joined. In this way, the surface area of the element 10 can be increased at a portion other than the notch portion 18 by joining the holder portion 33 to the notch portion 18. As a result, the capacity of the solid electrolytic capacitor can be increased and ESR can be reduced.
- the cathode terminal 20 has a support portion 38 that abuts on the lower surface on the end portion side of the cathode portion 11 without using the conductive adhesive portion 22.
- the support portion 38 is connected to a part of the side portion of the lower step portion 30, and the shape in which the lower step portion 30 and the support portion 38 are connected is stepped. . That is, the support portion 38 extends from the side portion of the lower step portion 30.
- the support portions 38 are bent in the exterior resin portion 23 vertically or obliquely upward from the side portion of the lower step portion 30, and are provided in pairs on both sides of the side portion of the lower step portion 30. Further, an upper stage 39 is provided at the upper end of the support portion 38.
- the upper surface of the upper step portion 39 of the support portion 38 is provided substantially parallel to the mounting surface 24 with a predetermined gap, and the outer resin portion 23 is provided on the lower surface of the upper step portion 39. It has been.
- the exterior resin portion 23 By providing the exterior resin portion 23 on the lower surface of the upper step portion 39, the deformation of the lower step portion 30 can be suppressed and the mountability can be ensured.
- the upper step portion 39 is bent outwardly with respect to the lower step portion 30 in the width direction and is formed outward from the side portion side of the lower step portion 30. Accordingly, the upper step portion 39 is provided outward from the cathode side end portion of the mounting portion 31 in the width direction, and the upper surface of the upper step portion 39 is provided further away from the upper surface of the mounting portion 31. Therefore, it is possible to prevent the conductive paste from spreading and reaching the upper step portion 39 when forming the conductive adhesive portion 22 on the mounting portion 31, and the upper step portion 39 can be surely brought into a non-fixed state.
- the cathode side edge part of the mounting part 31 mentioned above is a bending part by the side of the upper end part of the connection part 32, as shown in FIG. 1, FIG.
- the tip portion on the side portion side of the cathode portion 11 in the upper stage portion 39 is provided to protrude outward from the side portion of the cathode portion 11.
- the upper step portion 39 may be bent inward in the width direction and provided directly above the upper surface of the lower step portion 30.
- the upper surface of the upper step portion 39 abuts so as to include the end portion of the lower surface of the cathode portion 11 of the lowermost element 10A. Further, it is preferable that the upper surface of the upper stage portion 39 is provided on substantially the same plane as the upper surface of the mounting portion 31 and is smaller than the area of the upper surface of the mounting portion 31. More preferably, the upper surface of the upper stage portion 39 is provided higher than the upper surface of the mounting portion 31 by the thickness of the conductive adhesive portion 22 provided in the mounting portion 31.
- the upper step portion 39 and the cathode portion 11 can move relative to each other. That is, the upper stage portion 39 and the cathode portion 11 are not fixed.
- the support resin 38 and the cathode portion 11 are in a fixed state in which the exterior resin portion 23 cannot move relative to each other.
- the support portion 38 so as to be connected to the side portion of the lower step portion 30 and contact the lower surface of the end portion side of the cathode portion 11 without passing through the conductive adhesive portion 22.
- the end portion of the cathode portion 11 is not fixed to the cathode terminal 20. Therefore, physical stress on the cathode portion 11 due to thermal expansion of the cathode terminal 20 and processing variation of the lead frame can be reduced, and deterioration of leakage current can be suppressed.
- the anode terminal 21 has an anode connection part (hereinafter, connection part) 41.
- connection part 41 extends in the width direction from a part of the side portion of the lower step portion 40, and is bent vertically or obliquely upward in the exterior resin portion 23 from the side portion of the lower step portion 40. It is provided in pairs on both sides of the side portion of the portion 40.
- the mounting part 42 is provided in the connection part 41.
- the mounting portion 42 is provided outside the side portion of the lower step portion 40.
- the mounting portion 42 is provided in a flat shape so as to mount the lower surface of the anode portion 12.
- connection portion 41 is provided with an anode holder portion (hereinafter referred to as a holder portion) 43 extending from the placement portion 42 as shown in FIG.
- the holder portion 43 extends along the end portion of the laminated anode portion 12 and is bent at the upper surface of the anode portion 12 so as to enclose the laminated anode portion 12.
- stacked anode part 12 are joined by laser welding or resistance welding.
- the cathode terminal 20 having the first storage portion 35 and the second storage portion 36 is exposed from the mounting surface 24 of the exterior resin portion 23, and the end portion is bent upward along the exterior resin portion 23. ing.
- the shape of the cathode terminal 20 is not limited to this. If the lower step portion 30 is exposed from the mounting surface 24, it may not be bent upward along the exterior resin portion 23.
- the first storage portion 35 and the second storage portion are provided in the portion where the cathode portion of the capacitor element is mounted. 36 may be provided.
- the first storage portion 35 is configured by the side 31A of the mounting portion 31 and the first side 61 of the protrusion 34 in plan view
- the second storage 36 (361) is The second side 62 and the third side 63 are configured in plan view.
- a lead frame having a thickness of 0.1 mm to 0.2 mm in which the cathode terminal 20 and the anode terminal 21 are integrally formed is prepared, and the element 10A includes the upper stage portion 39, the mounting portion 31, and the anode terminal 21 of the cathode terminal 20. Is placed on the placement unit 42 of
- a conductive paste that becomes the conductive adhesive portion 22 is applied to the mounting portion 31 and the protruding portion 34 on which the cathode portion 11 is placed, and the cathode portion 11 of the element 10 is attached to the upper portion 39. And superimposing on the mounting portion 31.
- the conductive paste may be applied to the portion of the cathode portion 11 that is placed on the mounting portion 31 and the protruding portion 34, or the conductive paste may be applied to both.
- a conductive paste is applied to the other elements 10 and stacked on the elements 10A, and further, a conductive paste is applied to the other elements 10 and sequentially stacked. Then, by pressurizing the stacked elements 10, between the cathode part 11 and the mounting part 31, between the cathode part 11 and the protruding part 34, between the cathode part 11 and the cathode part 11, and between the cathode part 11 and A conductive paste is spread between the holder part 33 and sandwiched. By this pressurization, the conductive paste protrudes and is stored in the first storage portion 35 and the second storage portion 36. Thereafter, the conductive paste is cured at a high temperature of 110 ° C. to 200 ° C. to form the conductive adhesive portions 22 and 25.
- the end portion of the holder portion 43 is bent and brought into contact with the laminated anode portion 12. Then, the anode part 12, the anode terminal 21, and the laminated anode parts 12 are welded together by irradiating laser from the upper surface of the end part of the holder part 43.
- the element 10 joined to the cathode terminal 20 and the anode terminal 21, the mounting portion 31, the connection portion 32, the support portion 38, and the connection portion 41 are formed by transfer molding to heat-resistant insulating resin such as epoxy resin. Cover with.
- heat-resistant insulating resin such as epoxy resin. Cover with.
- the lower surfaces of the lower steps 30 and 40 are exposed to the mounting surface 24.
- the exterior resin portion 23 is formed.
- the cathode terminal 20 and the anode terminal 21 are cut from the lead frame so that the tip ends of the cathode terminal 20 and the anode terminal 21 protrude from the end of the exterior resin portion 23 on the same surface as the mounting surface 24.
- the tip portions of the cathode terminal 20 and the anode terminal 21 are bent along the end surface of the exterior resin portion 23.
- the solid electrolytic capacitor shown in FIGS. 1 and 2 is completed by the above procedure.
- the solid electrolytic capacitor of the present invention can prevent exposure of the conductive adhesive portion while having a large capacity. This configuration is useful for a solid electrolytic capacitor in which an external lead terminal is connected to a capacitor element.
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- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
Abstract
Description
11 陰極部
12 陽極部
13 陽極体
14 誘電体酸化皮膜
15 固体電解質層
16 陰極層
17 分離部
18 切り欠き部
20 陰極端子
21 陽極端子
22,25 導電性接着部
23 外装樹脂部
24 実装面
30 下段部
31 搭載部
31A 側辺
32 陰極接続部(接続部)
33 陰極ホルダ部(ホルダ部)
34 突出部
35 第1収納部
35A,36A 屈曲部
36,361 第2収納部
38 支持部
39 上段部
40 下段部
41 陽極接続部(接続部)
42 載置部
43 陽極ホルダ部(ホルダ部)
60 収納部
61 第1側辺
62 第2側辺
63 第3側辺
Claims (9)
- 陰極部と陽極部とを有するコンデンサ素子と、
前記陰極部に接合された陰極端子と、
前記陽極部に接合された陽極端子と、
前記コンデンサ素子を被覆した外装樹脂部と、を備え、
前記陰極端子は、
前記陰極部を搭載し前記陰極部の下面に導電性接着部を介して接合する搭載部と、
前記搭載部の側辺から前記搭載部と同一面に突出するとともに、その突出方向に向かってその幅が段階的に狭くなっている突出部と、
前記突出部の段階的に狭くなっている箇所の側辺に隣接して設けられ、前記導電性接着部の一部を収容した収納部と、を有する、
固体電解コンデンサ。 - 前記収納部は、
平面視で、前記搭載部の前記側辺と、前記搭載部の前記側辺に繋がった前記突出部の第1側辺とにより構成された第1収納部と、
平面視で、前記突出部の互いに繋がった第2側辺と第3側辺とにより構成された第2収納部と、を含む、
請求項1記載の固体電解コンデンサ。 - 前記収納部は、前記第1収納部と前記第2収納部により階段状に設けられた、
請求項2記載の固体電解コンデンサ。 - 前記第1収納部において、前記搭載部の前記側辺と前記第1側辺とが繋がった部分は第1曲線部を有し、
前記第2収納部において、前記第2側辺と前記第3側辺とが繋がった部分は第2曲線部を有し、
前記第1曲線部の曲率半径は、前記第2曲線部の曲率半径より大きい、
請求項2記載の固体電解コンデンサ。 - 前記第1収納部において、前記搭載部の前記側辺と、前記第1側辺とが交わる角度が直角又は鋭角であり、
前記第2収納部において、前記第2側辺と前記第3側辺が交わる角度が直角又は鋭角である、
請求項2記載の固体電解コンデンサ。 - 前記第2側辺と前記第3側辺が交わる角度は、前記搭載部の前記側辺と、前記第1側辺とが交わる角度よりも小さい、
請求項5記載の固体電解コンデンサ。 - 前記陰極端子は、前記突出部から延出し、前記陰極部の側部に接続された陰極ホルダ部をさらに有する、
請求項1記載の固体電解コンデンサ。 - 前記陰極端子は、前記固体電解コンデンサの実装面に露出した下面と、前記外装樹脂部が設けられた上面とを有する下段部をさらに有し、
前記搭載部は、前記下段部における前記陽極端子に近い端部に繋がっている、
請求項1記載の固体電解コンデンサ。 - 前記陰極端子は、
前記固体電解コンデンサの実装面に露出した下面と、前記外装樹脂部が設けられた上面とを有する下段部と、
前記下段部の側部から延出し、前記導電性接着部を介さずに前記陰極部の端部の下面に当接した支持部と、をさらに有する、
請求項1記載の固体電解コンデンサ。
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JP2014534201A JP6232587B2 (ja) | 2012-09-10 | 2013-09-05 | 固体電解コンデンサ |
US14/416,276 US9640326B2 (en) | 2012-09-10 | 2013-09-05 | Solid electrolytic capacitor |
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CN110088862A (zh) * | 2016-12-28 | 2019-08-02 | 松下知识产权经营株式会社 | 固体电解电容器及其制造方法 |
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JPWO2014038203A1 (ja) | 2016-08-08 |
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