WO2014014021A1 - Dispositif de génération de gaz hydrogène de bureau - Google Patents

Dispositif de génération de gaz hydrogène de bureau Download PDF

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Publication number
WO2014014021A1
WO2014014021A1 PCT/JP2013/069395 JP2013069395W WO2014014021A1 WO 2014014021 A1 WO2014014021 A1 WO 2014014021A1 JP 2013069395 W JP2013069395 W JP 2013069395W WO 2014014021 A1 WO2014014021 A1 WO 2014014021A1
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WIPO (PCT)
Prior art keywords
hydrogen gas
tank
generation tank
gas generation
desktop
Prior art date
Application number
PCT/JP2013/069395
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English (en)
Japanese (ja)
Inventor
藤原　昭信
Original Assignee
株式会社健康支援センター
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 株式会社健康支援センター filed Critical 株式会社健康支援センター
Priority to KR1020167020501A priority Critical patent/KR101732117B1/ko
Priority to KR1020157004384A priority patent/KR101718110B1/ko
Publication of WO2014014021A1 publication Critical patent/WO2014014021A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/02—Process control or regulation
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • C25B9/23—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms comprising ion-exchange membranes in or on which electrode material is embedded
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70—Assemblies comprising two or more cells
    • C25B9/73—Assemblies comprising two or more cells of the filter-press type
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Definitions

  • the present invention relates to a desktop hydrogen gas generator, and in particular, does not require a circulation pump that can be suitably used when electrolyzing pure water by an electrolysis plate in which both surfaces of an ion exchange membrane are sandwiched between a pair of electrode plates.
  • the present invention relates to a small desktop hydrogen gas generator.
  • An electrolysis system as an example of a conventional gas generator includes an electrolysis plate composed of an ion exchange membrane and a pair of electrode plates in close contact with both surfaces of the ion exchange membrane, and hydrogen separated by the electrolysis plate.
  • An electrolysis tank having a gas generation tank and an oxygen gas generation tank, a feed water pump for supplying pure water to the electrolysis tank and circulating and discharging hydrogen gas and oxygen gas generated from the electrolysis plate, a hydrogen gas generation tank, and And a water intake tank for receiving pure water overflowing from the oxygen gas generation tank (see paragraph 0020 of FIG. 1 and FIG. 1).
  • the conventional electrolysis system has a problem in that pure water overflows from the hydrogen gas generation tank due to electrophoresis generated during electrolysis of pure water.
  • the conventional electrolysis system has a problem that it is difficult to reduce the size and to carry it because it is necessary to provide a water supply pump and a water intake tank for generating and circulating hydrogen gas.
  • the present invention has been made in view of these points, and it is an object of the present invention to provide a novel desktop hydrogen gas generator that has improved various problems in the prior art such as downsizing and portability.
  • the purpose is.
  • the desktop hydrogen gas generator of the present invention includes an ion exchange membrane that does not have liquid and gas passage holes, and a pair of electrode plates that are in close contact with both surfaces of the ion exchange membrane.
  • An electrolysis plate having a fixing portion for bringing a pair of electrode plates into close contact with both surfaces of the ion exchange membrane, and an electrolysis plate as a partition plate and partitioned into an electrolysis plate and pure water to be electrolyzed Hydrogen gas generated from the hydrogen gas generation tank at a pressure that suppresses the water level of pure water stored in the hydrogen gas generation tank and the electrolytic cell having the hydrogen gas generation tank to be stored and the oxygen gas generation tank from rising above a predetermined level. And a hydrogen gas pressurizing part that is taken out while being pressurized.
  • the electrolysis plate serves as a partition plate for the electrolytic cell that spatially separates the hydrogen gas generation tank and the oxygen gas generation tank, the hydrogen gas and the oxygen gas are not mixed when the electrolysis plate is energized. , They can be generated separately.
  • the hydrogen gas pressurizing unit pressurizes the hydrogen gas generated from the hydrogen gas generation tank.
  • the desktop hydrogen gas generator of the present invention further includes a surge tank that stores pure water and is connected to each lower portion of the hydrogen gas generation tank and the oxygen gas generation tank. .
  • the surge tank is connected to each lower part of the hydrogen gas generation tank and the oxygen gas generation tank, so that the surge tank supplies pure water to the hydrogen gas generation tank and the oxygen gas generation tank, Pure water biased to one of the gas generation tank or the oxygen gas generation tank can be moved to the other.
  • the surge tank since the surge tank is connected to each lower part of the hydrogen gas generation tank and the oxygen gas generation tank, the electrolytic tank water level and the pressure difference between hydrogen gas and oxygen gas can be buffered by the surge tank. it can.
  • the desktop hydrogen gas generator of the present invention adds oxygen gas generated from the oxygen gas generation tank at a pressure that prevents the water level of pure water stored in the oxygen gas generation tank from rising above a predetermined level. It is preferable to further include an oxygen gas pressurizing valve that discharges while pressing.
  • the oxygen gas pressurization valve when the oxygen gas pressurization valve is closed, the pure water in the oxygen gas generation tank is pressed at the atmospheric pressure or higher, so that the hydrogen gas generated from the hydrogen gas generation tank is pressurized with hydrogen gas. It is possible to prevent the pure water from overflowing from the oxygen gas outlet by the reaction pressurized by the section. Further, since the oxygen gas is discharged when the pressure exceeds a predetermined pressure, it is possible to prevent the oxygen gas generation tank from becoming excessively pressurized and damaging the oxygen gas generation tank and the electrolysis plate.
  • the hydrogen gas pressurizing unit includes a hydrogen gas storage unit for storing water at a predetermined water level, and a hydrogen gas discharge port provided at an upper portion of the hydrogen gas generation tank. And a hydrogen gas relay part that relays between the hydrogen gas storage part and the lower part of the hydrogen gas storage part, and a hydrogen gas extraction part that extracts hydrogen gas from the upper part of the hydrogen gas storage part, and is stored in the hydrogen gas storage part It is preferable to pressurize the hydrogen gas with a predetermined water pressure generated by pure water.
  • the pressurization structure and pressurization adjustment can be facilitated.
  • hydrogen gas passes in the water of a hydrogen gas storage part, generation
  • the hydrogen gas storage part is interposed between the hydrogen gas relay part and the hydrogen gas extraction part, even if the hydrogen gas taken out from the hydrogen gas extraction part ignites, it is stored in the hydrogen gas storage part. Water can extinguish the ignition and prevent the hydrogen gas generated from the hydrogen gas generation tank from being ignited.
  • the pair of electrode plates preferably each have a plurality of through holes having apex angles of 45 degrees or less inside.
  • the electrolysis efficiency of the electrolysis plate can be improved by about 10 to 15% as compared with a passage hole having an apex angle of 45 degrees or more and a passage hole having a semicircular or semi-elliptical upper portion.
  • hydrogen gas can be taken out from a hydrogen gas generation tank, without attaching a circulation pump to an electrolytic cell.
  • the ion exchange membrane is provided on the same axis as the passage holes of the pair of electrode plates, and has a plurality of rivet holes smaller than the passage holes.
  • a rivet shaft that is evenly provided on the contact surface of the plate, the fixing portion has an outer diameter smaller than an inner diameter of the passage hole and larger than an inner diameter of the rivet hole, and is inserted into the passage hole and the rivet hole;
  • a pair of electrode plates is formed at both ends of the shaft and at least one of which is inserted into the passage hole and the rivet hole through the rivet shaft and then melted and cooled by pressing an ultrasonic wave or a heating mold to form an ion exchange membrane.
  • the rivet is made of a thermoplastic plastic that has two rivet heads that are in close contact with both sides of the glass and that expands when liquid is absorbed. There.
  • the rivet holes are evenly arranged and the two rivet heads bring the pair of electrode plates into close contact with both surfaces of the ion exchange membrane, the pair of electrode plates and the ion exchange membrane are It can be adhered evenly over the entire surface. Further, since the outer diameter of the rivet shaft is larger than the inner diameter of the rivet hole, the pure water of the electrolytic cell and the gas generated from the electrolysis plate are connected to the hydrogen gas generation tank and the oxygen gas generation tank through the rivet hole. Can be prevented.
  • the oxygen gas pressurizing valve includes a cylinder portion extending above an oxygen gas discharge port provided in an upper portion of the oxygen gas generation tank, and an inner tube. And a metal ball that closes the oxygen gas outlet with a predetermined pressure.
  • the pressure for closing the oxygen gas discharge port can be easily changed by changing the weight and number of the metal balls, so that the exhaust pressure of the oxygen gas can be easily and finely controlled.
  • the electrolytic cell is composed of two divided cases obtained by dividing a closed container in the vertical direction, and an ion exchange larger than the pair of electrode plates. It is preferable to have a fastening portion that fastens the two split cases together with the peripheral edge of the membrane sandwiched by the peripheral edges of the two split cases.
  • the structure of the electrolytic cell can be simplified. Further, the sealing performance of the electrolytic cell can be ensured without using a soft gasket at the peripheral portions of the two divided cases.
  • the desktop hydrogen gas generator of the present invention includes a backflow prevention valve that opens the hydrogen gas generation tank to the atmosphere using the negative pressure generated in the hydrogen gas generation tank when electrolysis is stopped by the electrolysis plate; Is preferably further provided.
  • the backflow prevention valve opens the hydrogen gas generation tank to the atmosphere when the electrolysis is stopped, the water stored in the hydrogen gas storage section is prevented from flowing back to the hydrogen gas generation tank through the hydrogen gas relay section. can do.
  • the backflow prevention valve has an atmosphere opening and a metal ball that closes the atmosphere opening with a predetermined pressure, and a hydrogen gas discharge port or a hydrogen gas relay. It is preferable that it is attached to the part.
  • the open negative pressure can be easily and finely adjusted as compared with the spring-type check valve.
  • the electrolysis plate has a maximum hydrogen gas generation amount of 10 ml / min during electrolysis of pure water, and hydrogen gas generated from the electrolysis plate.
  • the hydrogen gas pressurizing unit pressurizes hydrogen gas generated from the hydrogen gas generating tank at 100 to 400 Pa, and the oxygen gas pressurizing valve generates oxygen gas. It is preferable that the oxygen gas generated from the tank is pressurized at 50 to 150 Pa, and the backflow prevention valve opens the hydrogen gas generation tank to the atmosphere when the negative pressure of the hydrogen gas generation tank is ⁇ 100 to 200 Pa.
  • the pressure inside the electrolytic cell rises rapidly, and hydrogen gas and oxygen gas pass through the rivet hole of the ion exchange membrane. This can be prevented.
  • the surge tank supplies water to the electrolytic cell while controlling each pressure in detail, so that the water level of the electrolytic cell is maintained at ⁇ 5 mm, and pure water overflows from the hydrogen gas generating unit and the oxygen gas generating unit. This can be prevented and the generation efficiency of hydrogen gas and oxygen gas can be maintained.
  • the open negative pressure is close to 0 Pa, backflow can be prevented while maintaining the pressure relationship between the water level of the electrolytic cell and the generated gas.
  • each of the upper part of the hydrogen gas generation tank and the oxygen gas generation tank or a member connected to each upper part is configured to supply the hydrogen gas generation tank and the oxygen when water is supplied to the surge tank. It is preferable to have a gas venting part for venting the gas sealed in each upper part of the gas generation tank.
  • the gas in the electrolytic cell escapes from the gas vent part by the amount of water supply, so that the pressure relationship of the electrolytic cell can be maintained.
  • the desktop hydrogen gas generator of the present invention further includes a protective housing that covers the desktop hydrogen gas generator, and the protective housing is hydrogen that passes through the pure water in the hydrogen gas pressurizing unit. It is preferable to have a confirmation window for visually recognizing gas bubbles.
  • the generation of invisible hydrogen gas can be visually confirmed by visually confirming the bubbles of hydrogen gas from the confirmation window.
  • the desktop hydrogen gas generator of the present invention further includes a hydrogen gas generation amount meter that displays the amount of hydrogen gas generation according to the current value applied to the electrolysis plate.
  • the amount of hydrogen gas generated can be controlled while checking the hydrogen gas generation amount meter.
  • the desktop hydrogen gas generator of the present invention there is an effect that it is possible to provide a new desktop hydrogen gas generator in which various problems in the prior art such as downsizing and portability are improved.
  • FIG. 1 is a perspective view showing a desktop hydrogen gas generator of this embodiment.
  • FIG. 2 is a block diagram showing the desktop hydrogen gas generator of this embodiment.
  • FIG. 3 is a cross-sectional view of the electrolytic cell of this embodiment as viewed from the front.
  • FIG. 4 is a partial cross-sectional view of the electrolytic cell of the present embodiment as viewed from the hydrogen gas generation cell side.
  • FIG. 5 is a conceptual diagram showing a hydrogen gas generation state when the through hole formed in the electrode plate of the present embodiment is circular.
  • FIG. 6 is a conceptual diagram showing a hydrogen gas generation state when the apex angle of the through hole formed in the electrode plate of the present embodiment is about 120 degrees.
  • FIG. 1 is a perspective view showing a desktop hydrogen gas generator of this embodiment.
  • FIG. 2 is a block diagram showing the desktop hydrogen gas generator of this embodiment.
  • FIG. 3 is a cross-sectional view of the electrolytic cell of this embodiment as viewed from the front.
  • FIG. 4 is a partial
  • FIG. 7 is a conceptual diagram showing a hydrogen gas generation state when the apex angle of the through hole formed in the electrode plate of the present embodiment is about 30 degrees.
  • FIG. 8 is a graph showing the relationship between the apex angle of the passage hole and the amount of hydrogen gas generated.
  • FIG. 9 is a conceptual diagram showing a rivet insertion occurrence state in the case where one head portion of the rivet as the fixing portion of the present embodiment has not yet been formed.
  • FIG. 10 is a conceptual diagram showing a rivet insertion occurrence state when one head portion of the rivet as the fixing portion of the present embodiment is formed.
  • the desktop hydrogen gas generator of this embodiment is a small amount (up to about 10 ml / min for the purpose of aspiration, physicochemical experiment, clinical experiment, etc. for active oxygen removal and adult disease prevention in general homes and the like. ) And high purity (about 99%) hydrogen gas for a long time (for example, about 50 hours) and low pressure (maximum of about 500 Pa (converted to 1 mm water column ⁇ 10 Pa)). Therefore, the desktop hydrogen gas generator of this embodiment can be used easily and safely by patients who inhale hydrogen gas regardless of location or time, such as small size, light weight, portability, ease of operation, and low price. Is required.
  • the desktop hydrogen gas generator of this embodiment generates hydrogen gas by electrolyzing pure water.
  • pure water obtained after purification after ion exchange resin does not have electrical conductivity. Therefore, in order to electrolyze pure water, (A) acid such as sulfuric acid or sodium hydroxide is generally used.
  • a method in which an electrolytic solution in which an alkali such as potassium hydroxide is added to pure water is electrolyzed through a diaphragm, or (B) an electrolytic plate in which an anode and a cathode conductive electrode are in close contact with an ion exchange membrane A method of performing electrolysis while injecting pure water with a circulation pump is often adopted.
  • the desktop hydrogen gas generator of this embodiment directly electrolyzes pure water without adding an additive to pure water, using the electrolysis plate in the electrolysis method of (B) above.
  • a circulation pump, a pressure sensor, a water level sensor, an electromagnetic valve, etc. that are generally essential for conventional electrolysis systems.
  • the desktop hydrogen gas generator of the present embodiment needs to completely separate the generated hydrogen gas and oxygen gas and prevent other impurities from being mixed. . For this reason, a structure is required in which the hydrogen gas generation source and the oxygen gas generation source are completely spatially separated and no additives other than pure water are mixed inside the desktop hydrogen gas generation apparatus.
  • FIG. 1 is a perspective view showing a desktop hydrogen gas generator 1 according to this embodiment.
  • FIG. 2 is a block diagram which shows the desktop type hydrogen gas generator 1 of this embodiment. In FIG. 2, only a part of the electrolysis plate 3 is shown.
  • the desktop hydrogen gas generator 1 of the present embodiment has a width of 120 mm, a height of 200 mm, a depth of 280 mm, and a weight of about 1200 g in order to enable desktop use and portable use by reducing the size and weight. Is set.
  • the desktop hydrogen gas generator 1 includes a constant current control circuit 3, a hydrogen gas generation amount meter 4, an electrolysis plate 5, an electrolytic cell 6, A hydrogen gas pressurizing unit 7, a surge tank 8, an oxygen gas pressurizing valve 9, a backflow prevention valve 10 and a gas venting unit 11 are provided.
  • the protective housing 2 is a metal box that covers the desktop hydrogen gas generator 1.
  • the protective housing 2 is formed in a substantially rectangular parallelepiped shape as a whole, and includes a main body support unit 200 including a lower panel 201, a front panel 202, and a rear panel 203, a left side panel 211, a right side panel 212, and an upper panel 213.
  • the cover part 210 which consists of.
  • the main body support portion 200 and the cover portion 210 are formed so as to be separable according to the attachment and detachment of the screw 220 during internal maintenance of the desktop hydrogen gas generator 1 or water supply of the pure water 13.
  • the protective housing 2 has a confirmation window 230 near the lower left of the front panel 202.
  • the confirmation window 230 is a substantially rectangular cutout extending in a vertical direction with a predetermined width, and the hydrogen gas bubbles 15 passing through the water 14 stored in the hydrogen gas pressurizing unit 7 can be visually recognized. .
  • the protective housing 2 has a handle 240 near the center of the top panel 213.
  • the handle 240 is used when the desktop hydrogen gas generator 1 is transported.
  • the protective housing 2 has a vent 250 near the upper left of the left side panel 211 and above the rear panel 203.
  • the vent 250 allows oxygen gas exhausted from the electrolytic cell 6 and heat exhausted from the internal heat source of the desktop hydrogen gas generator 1 to pass from the inside of the desktop hydrogen gas generator 1 to the outside. It is preferable that a cooling fan is attached to the inside of the vent 250 as necessary.
  • the constant current control circuit 3 is a circuit that controls the electric power obtained from the power supply 301 to a predetermined constant current and supplies the predetermined constant current to the electrolysis plate 5.
  • the power supply voltage is set to DC 6 to 9V, and the current consumption is set to 0 to 2A.
  • Examples of the power supply 301 include an AC adapter connected to an outlet, a dry battery such as an alkaline battery, and a secondary battery such as a lithium ion battery.
  • a dry battery such as an alkaline battery
  • a secondary battery such as a lithium ion battery.
  • a power input terminal for connecting the AC adapter is installed below the back panel 203.
  • a battery such as a dry battery or a secondary battery is used as the power source 301, the battery is built in the protective housing 2.
  • the predetermined constant current described above is the maximum value of the discharge amount (eg, about 10 ml / min at maximum) and the exhaust pressure (150 to 500 Pa) at which the hydrogen gas discharged from the desktop hydrogen gas generator 1 does not explode. Is set as a standard.
  • the predetermined constant current value can be controlled by a setting volume 302 connected to the constant current control circuit 3 as shown in FIG.
  • the setting volume 302 is disposed near the center of the front panel 202 as shown in FIG. Further, the power switch 303 of the constant current control circuit 3 is arranged at the lower right of the front panel 202 as shown in FIG. Further, a confirmation lamp 304 for confirming whether the constant current control circuit 3 is turned on or off is disposed at the lower right of the front panel 202 and above the power switch 303 as shown in FIG.
  • the hydrogen gas generation amount meter 4 is disposed above the front panel 202. This hydrogen gas generation amount meter 4 displays the generation amount of hydrogen gas according to the current value supplied to the electrolysis plate 5.
  • the desktop hydrogen gas generator 1 is used for inhalation therapy to human bodies, physics and chemistry experiments, etc., it is indispensable to install the hydrogen gas generation amount meter 4 in order to use the desktop hydrogen gas generator 1 safely.
  • the hydrogen gas generation amount meter 4 may be an ammeter remodeling meter in which the scale of the ammeter is made to correspond to the hydrogen gas generation amount (ml / min) in order to eliminate a complicated and expensive hydrogen amount measuring device. preferable.
  • the amount of hydrogen gas generated by the electrolysis of the pure water 13 is proportional to the value of current flowing through the electrolysis plate 5.
  • the hydrogen gas generation amount meter 4 is an ammeter remodeling meter
  • the hydrogen gas generation amount meter 4 is connected between the constant current control circuit 3 and the electrolysis plate 5 as shown in FIG.
  • FIG. 3 is a cross-sectional view of the electrolytic cell 6 of the present embodiment as viewed from the front.
  • FIG. 4 is a partial cross-sectional view of the electrolytic cell 6 of the present embodiment as viewed from the hydrogen gas generation tank 602 side.
  • the electrolysis plate 5 has a pair of electrode plates 500, an ion exchange membrane 510, and a fixing portion 520, as shown in FIGS.
  • the pair of electrode plates 500 are arranged on both surfaces of the ion exchange membrane 510.
  • the fixing portion 520 brings the pair of electrode plates 500 and the ion exchange membrane 510 into close contact with each other.
  • the pair of electrode plates 500 includes an anode plate 501 and a cathode plate 502.
  • oxygen gas (O 2 ) is generated from the anode plate 501 side
  • hydrogen gas (2H 2 ) is generated from the cathode plate 502 side.
  • anode plate 501 it is preferable to use an expanded metal made of titanium plated with iridium (Ir) or platinum (Pt). Further, as the cathode plate 5022, it is preferable to use an expanded metal made of titanium plated with platinum (Pt).
  • the expanded metal used as the anode plate 501 and the cathode plate 502 is preferably subjected to a smoothing treatment in order to improve the adhesion with the ion exchange membrane 510. Moreover, in order to improve the fixability by the fixing
  • the expanded metal in the present embodiment is set to a height of 80 mm ⁇ width of 40 mm ⁇ thickness of 0.3 to 0.5 mm. Moreover, the opening part surface area of said mesh in this embodiment is set to 2 mm ⁇ 2 >.
  • FIG. 5 is a conceptual diagram showing a hydrogen gas generation state when the passage hole 503 formed in the electrode plate 500 of the present embodiment is circular.
  • FIG. 6 is a conceptual diagram showing a hydrogen gas generation state when the apex angle 504 of the passage hole 503 formed in the electrode plate 500 of the present embodiment is about 120 degrees.
  • FIG. 7 is a conceptual diagram showing a hydrogen gas generation state when the apex angle 504 of the through hole 503 formed in the electrode plate 500 of the present embodiment is about 30 degrees.
  • the pair of electrode plates 500 preferably have a plurality of passage holes 503 as shown in FIG.
  • the passage hole 503 has various shapes such as a circular shape shown in FIG. 5, a horizontally long rhombus shape having an apex angle 504 of about 120 degrees shown in FIG. 6, and a vertically long rhombus shape having an apex angle 504 of about 30 degrees shown in FIG. Can be adopted.
  • the passage hole 503 is preferably formed in a shape having an apex angle 504 having an inner angle of 45 degrees or less above it.
  • the pair of electrode plates 500 in the present embodiment is the above-described expanded metal. Therefore, in this embodiment, each mesh of expanded metal is employed as the plurality of passage holes 503.
  • the shape of the passage hole 503 is preferably a shape having an apex angle 504 with an inner angle of 45 degrees or less above it as shown in FIG.
  • each bubble diameter of hydrogen gas and oxygen gas is nano level near the contact surface thereof.
  • the bubbles 15 of that size grow to a micro-level bubble diameter when moved from the contact surface side to the outside of each electrode plate 500 in the passage hole 503 of the electrode plate 500.
  • the large size ( ⁇ mill level bubble size) bubble 15 is generated. It stays in the passage hole 503 of the plate 500, and the large-sized bubble 15 enters between the electrode plate 500 and the ion exchange membrane 510. Since the bubbles 15 are insulative, the electrolytic current generated between the electrode plate 500 and the ion exchange membrane 510 is disturbed when the large bubbles 15 enter the contact surface, causing a voltage increase and a temperature increase. This causes the electrolytic efficiency to decrease.
  • the desktop hydrogen gas generator 1 of the present embodiment forces the bubbles 15 generated in the passage hole 503, such as a water supply pump that supplies the pure water 13 or a circulation pump that circulates the pure water 13 in the electrolytic cell 6 There is no means for circulating automatically. Therefore, the passage hole 503 for preventing the bubbles 15 from growing to a bubble size of millimeter level is extremely important.
  • a circular passage hole 503 as shown in FIG. 6 is a comparative experiment with a passage hole 503 having a different top shape, such as a passage hole 503 having an apex angle 504 of about 120 degrees as shown in FIG. 6 and a passage hole 503 having an apex angle 504 of about 30 degrees as shown in FIG.
  • a passage hole 503 having an apex angle 504 of about 120 degrees as shown in FIG. 6 and a passage hole 503 having an apex angle 504 of about 30 degrees as shown in FIG.
  • Table 2 shows the experimental results.
  • the amount of hydrogen gas generated in Table 2 is converted based on an actual measurement value at which 7.0 ml / min of hydrogen gas is generated when the current 1A is supplied to the electrolysis plate 5.
  • FIG. 8 is a graph showing the relationship between the apex angle 504 of the passage hole 503 obtained from Table 2 and the amount of hydrogen gas generated. As shown in Table 2 and FIG. 8, it is apparent that the amount of hydrogen gas generated increases rapidly in the process in which the apex angle 504 of the passage hole 503 changes from 60 degrees to 45 degrees. This is considered to be because when the apex angle 504 of the passage hole 503 is 45 degrees or less, the bubbles 15 in the passage hole 503 hardly stay in the upper part of the passage hole 503 and the bubbles 15 are detached from the passage hole 503. It is done.
  • the passage hole 503 as shown in FIGS. 5 and 6 is circular or the apex angle 504 of the passage hole 503 is 45.
  • the electrolysis efficiency of the electrolysis plate 5 at or above the degree was about 65 to 70%.
  • the electrolysis efficiency of the electrolysis plate 5 in which the apex angle 504 of the passage hole 503 is 45 degrees or less as shown in FIG. 7 was about 80%, which is 10 to 15 points higher than the electrolysis efficiency.
  • the shape of the passage hole 503 is preferably a shape having an apex angle 504 having an inner angle of 45 degrees or less above, as shown in FIG.
  • the thickness of the electrode plate 500 of this embodiment is set to 0.3 to 0.5 mm.
  • the ion exchange membrane 510 is a smooth elastic membrane that expands due to absorption of the pure water 13.
  • Various commercially available products can be used as the ion exchange membrane 510.
  • the ion exchange membrane 510 of this embodiment is an ion exchange membrane “Nafion N-117CS” manufactured by DuPont. In this case, the ion exchange membrane 510 expands by about 12 to 15% due to absorption of the pure water 13.
  • the ion exchange membrane 510 of the present embodiment is slightly larger than the pair of electrode plates 500, and is set to 110 mm high ⁇ 70 mm wide ⁇ 0.17 mm thick.
  • the ion exchange membrane 510 preferably has eight rivet holes 511 as shown in FIG.
  • the eight rivet holes 511 are provided on the same axis as the passage holes 503 (mesh) of the pair of electrode plates 500 (expanded metal), and a plurality of rivet holes 511 smaller than the passage holes 503 are provided on the electrode plate. It is equally formed on 500 contact surfaces.
  • the inner diameter of the rivet hole 511 of this embodiment is set to 1.8 to 1.9 mm.
  • the ion exchange membrane 510 does not have a liquid or gas passage hole.
  • the eight rivet holes 511 are not included in the liquid and gas passage holes because the eight rivet holes 511 do not allow liquid and gas to pass therethrough.
  • the fixing portion 520 causes the pair of electrode plates 500 to be in close contact with both surfaces of the ion exchange membrane 510. If the pair of electrode plates 500 and the ion exchange membrane 510 are not in close contact with each other, the energization resistance between the pair of electrode plates 500 and the ion exchange membrane 510 is increased, and the electrolysis efficiency of the electrolysis plate 5 is reduced. The adhesion performance by the part 520 becomes important.
  • the ion exchange membrane 510 is sandwiched between thick electrode plates 500 that are difficult to be bent, as in the conventional case, and the total of four locations around the electrode plate 500 and one center.
  • a method of bolting at five locations is also conceivable.
  • hydrogen gas or oxygen gas bubbles 15 generated from the electrode plate 500 are adsorbed on the projections, thereby preventing the bubbles 15 from rising.
  • capacitance of the pure water 13 stored in the electrolytic cell 6 reduces, so that the volume of a protrusion becomes large. As a result, the amount of hydrogen gas generated decreases.
  • the desktop hydrogen gas generator 1 of this embodiment does not include a circulation pump in consideration of downsizing, portability improvement, and low cost.
  • the fixing portion 520 of the present embodiment is a small rivet as shown in FIGS.
  • rivets as the fixing portion 520 of the present embodiment are arranged in a rectangular shape along the periphery of the electrode plate 500 as shown in FIG. 4 are arranged in a vertically long rhombus shape.
  • the rivet as the fixing portion 520 is preferably expanded when the liquid is absorbed in order to improve adhesion.
  • These rivets are made of thermoplastic plastic, and are composed of a rivet shaft 521 and two rivet heads 522 as shown in FIG.
  • thermoplastics have water resistance and heat resistance that can withstand temperatures of several tens of degrees.
  • thermoplastic plastics include heat-resistant vinyl chloride (PVC), polycarbonate cage (PC), and polypropylene (PP).
  • the rivet shaft 521 is inserted into the passage hole 503 and the rivet hole 511 of the electrode plate 500.
  • the rivet shaft 521 is set to have an outer diameter smaller than the inner diameter of the passage hole 503 and larger than the inner diameter of the rivet hole 511.
  • the outer diameter of the rivet shaft 521 of this embodiment is set to 2 mm, which is about 10% larger than the rivet hole 511 of the ion exchange membrane 510.
  • FIG. 9 is a conceptual diagram showing a rivet insertion occurrence state when one rivet head 522 in the rivet as the fixing portion 520 of the present embodiment is not yet formed.
  • FIG. 10 is a conceptual diagram showing a rivet insertion occurrence state when one rivet head 522 is formed in the rivet as the fixing portion 520 of the present embodiment.
  • one of the rivet heads 522 exceeds one end of the rivet shaft 521 before inserting the rivet shaft 521 into the passage hole 503 and the rivet hole 511, as shown in FIG. It is formed into an umbrella shape by melting and cooling with a sonic wave or a heating mold. Then, after the rivet shaft 521 of an incomplete rivet in which only one rivet head 522 is formed is inserted into the rivet hole 511, the other end of the rivet shaft 521 is ultrasonically or heated as shown in FIG. The other rivet head 522 is formed into an umbrella shape by melting and cooling with a mold.
  • the completed rivet and ion exchange membrane 510 is expanded by the pure water 13 supplied to the electrolytic cell 6. By this expansion, there is no gap between the rivet hole 511 and the rivet shaft 521, and the rivet hole 511 is completely sealed. Thereby, there is no movement of liquid and gas from the rivet hole 511 of the ion exchange membrane 510 at all.
  • the electrolytic cell 6 of the present embodiment is partitioned into two chambers, a hydrogen gas generation tank 602 and an oxygen gas generation tank 601, with the electrolysis plate 5 as a partition plate.
  • the hydrogen gas generation tank 602 is a tank formed on the cathode plate 502 side where hydrogen gas is generated.
  • the oxygen gas generation tank 601 is a tank formed on the anode plate 501 side where oxygen gas is generated.
  • the electrolytic cell 6 of this embodiment is formed in a hollow rectangular parallelepiped shape that extends vertically, and the dimensions thereof are 110 mm in height, 70 mm in width, and 43 mm in depth as viewed from the front of the electrolytic cell 6 as shown in FIG. Is set to In this case, the capacity of the electrolytic cell 6 is about 192 ml.
  • the ideal water level in the electrolytic cell 6 of the present embodiment is set to about 70% (about 60 mm) in consideration of improvement in electrolysis efficiency by the electrolysis plate 5 and prevention of overflow of the pure water 13.
  • the capacity of the pure water 13 is about 144 ml.
  • the change of the water level (the water level of the hydrogen gas generation tank 602 and the water level of the oxygen gas generation tank 601) of the electrolytic cell 6 in this embodiment is set to a range of about ⁇ 5% (about ⁇ 5 mm).
  • the capacity of the pure water 13 corresponding to a water level difference of 10 mm between the upper limit water level and the lower limit water level is about 24 ml.
  • the desktop hydrogen gas generator 1 of the present embodiment can generate about 1200 ml of hydrogen gas from 131.0 ml of pure water. That is, even when there is no water supply to the electrolytic cell 6, the desktop hydrogen gas generator 1 of the present embodiment has a capacity of about 24 ml to 28800 ml of pure water 13 corresponding to a water level difference of 10 mm between the upper limit water level and the lower limit water level.
  • the hydrogen gas can be generated. This is because the desktop hydrogen gas generator 1 can continue to generate hydrogen gas for about 48 hours even when the hydrogen gas generation rate is 10 ml per minute.
  • the electrolytic cell 6 of the present embodiment is preferably composed of two divided cases 611 and fastening portions 612 as shown in FIGS.
  • the two divided cases 611 are formed in a shape obtained by dividing a vertically long hollow rectangular parallelepiped container in the vertical direction.
  • the split case 611 is made of transparent plastic such as acrylic resin, and generation of hydrogen gas and oxygen gas from the electrolysis plate 5 and the water level of the pure water 13 in the electrolytic cell 6 can be confirmed.
  • the fastening portion 612 is configured such that the peripheral portion of the ion exchange membrane 510 formed larger than the pair of electrode plates 500 is sandwiched between the peripheral portions of the two divided cases 611. As shown in FIG. 4, the two divided cases 611 are fastened together. As shown in FIGS. 4 and 3, the fastening portion 612 includes a plurality of penetrating through the two split cases 611 at the periphery of the split case 611 when the hydrogen gas generation tank 602 or the oxygen gas generation tank 601 is viewed from the front.
  • the dried ion exchange membrane 510 constituting the electrolysis plate 5 is sandwiched between two divided cases 611, and the two divided cases 611 are fastened by fastening portions 612.
  • pure water 13 was supplied to the electrolytic cell 6 and a leakage experiment of the electrolytic cell 6 was performed. Even after a long time (about 50 hours) had elapsed since the water supply to the electrolytic cell 6, leakage of the pure water 13 from the electrolytic cell 6 could not be confirmed. Therefore, it can be said that the peripheral portion of the ion exchange membrane 510 expanded by the supplied pure water 13 sufficiently plays the role of a soft gasket on the mating surfaces of the two divided cases 611.
  • the hydrogen gas pressurizing unit 7 is configured to take out hydrogen gas generated from the hydrogen gas generation tank 602 while pressurizing it at a predetermined pressure.
  • the predetermined pressure by the hydrogen gas pressurizing unit 7 is that the water level of the pure water 13 stored in the hydrogen gas generation tank 602 is higher than a predetermined level (reference water level 70% (about 60 mm) + 5% (about ⁇ 5 mm) range). It is the pressure that suppresses the rise.
  • the predetermined pressure by the hydrogen gas pressurizing unit 7 is set to 100 to 400 Pa.
  • the hydrogen gas pressurization unit 7 of the present embodiment includes a hydrogen gas storage unit 710, a hydrogen gas relay unit 720, and a hydrogen gas extraction unit 730.
  • the hydrogen gas storage unit 710 stores water 14 at a predetermined water level.
  • the hydrogen gas storage unit 710 of the present embodiment includes a transparent glass container 711 and a storage unit rubber stopper 712.
  • the container 711 is set to a height of about 50 mm.
  • the storage portion rubber plug 712 is a lid of the container 711 and has two passage holes through which the hydrogen gas relay portion 720 and the hydrogen gas extraction portion 730 pass.
  • the water 14 stored in the hydrogen gas storage unit 710 is not pure water 13 for electrolysis, but water 14 for visually confirming the generation of hydrogen gas and the hydrogen gas extracted from the hydrogen gas extraction unit ignited. Water 14 for use as fire extinguishing water at the time. Therefore, although the pure water 13 is preferable as the water 14 stored in the hydrogen gas storage unit 710, tap water may be used.
  • the water level of the hydrogen gas storage unit 710 is preferably set to about 30 to 40 mm. This is because the hydrogen gas generated from the hydrogen gas generation tank 602 is pressurized at a predetermined pressure, and the hydrogen gas relayed from the hydrogen gas generation tank 602 to the hydrogen gas storage section 710 via the hydrogen gas relay section 720. This is for visually recognizing as bubbles 15.
  • the hydrogen gas relay unit 720 relays from the hydrogen gas discharge port 622 provided in the upper part of the hydrogen gas generation tank 602 to the lower part of the hydrogen gas storage unit 710.
  • the hydrogen gas relay unit 720 of this embodiment is a relay connection pipe that connects the hydrogen gas discharge port 622 to the lower part of the container 711 of the hydrogen gas storage unit 710 through the storage unit rubber plug 712.
  • the hydrogen gas relay unit 720 relays the hydrogen gas from the hydrogen gas generation tank 602 to the lower part of the hydrogen gas storage unit 710. Further, the hydrogen gas relay unit 720 pressurizes the hydrogen gas generated from the hydrogen gas generation tank 602 by the water pressure of the water 14 at a predetermined water level stored in the hydrogen gas storage unit 710.
  • the hydrogen gas extraction unit 730 extracts hydrogen gas from the upper part of the hydrogen gas storage unit 710.
  • the hydrogen gas extraction portion 730 of the present embodiment is configured by an extraction connection pipe 731 and a hydrogen gas extraction port 732.
  • the connection pipe for extraction 731 connects from the upper part of the hydrogen gas storage part 710 to the hydrogen gas outlet 732 via the storage part rubber plug 712.
  • the hydrogen gas outlet 732 is disposed on the central left side of the front panel 202.
  • the hydrogen gas outlet 732 serves as a connection means with an external instrument such as a tracheal cannula or a laboratory tube.
  • the surge tank 8 stores the pure water 13 and is connected to the lower portions of the hydrogen gas generation tank 602 and the oxygen gas generation tank 601, respectively.
  • the surge tank 8 of the present embodiment includes a tank body 801 made of transparent plastic or transparent glass, a tank rubber stopper 802, a drain cock 803, and two tank connection tubes 804.
  • the tank body 801 is a container for storing the pure water 13 supplied to the electrolytic cell 6 and is set to a height of about 100 mm.
  • the tank rubber plug 802 is a lid of the tank body 801 and is opened and closed when the pure water 13 is supplied to the tank body 801.
  • the drain cock 803 is used when the pure water 13 is drained from the surge tank 8.
  • the two tank connection tubes 804 connect the lower part of the tank body 801 and the lower part of the hydrogen gas generation tank 602 and the lower part of the tank body 801 and the lower part of the oxygen gas generation tank 601, respectively. .
  • the reason why the hydrogen gas generation tank 602 and the oxygen gas generation tank 601 are connected to each lower portion is that hydrogen gas and oxygen gas are not moved from the hydrogen gas generation tank 602 and the oxygen gas generation tank 601 to the surge tank 8.
  • the oxygen gas pressurizing valve 9 discharges the oxygen gas generated from the oxygen gas generating tank 601 while pressurizing it at a predetermined pressure.
  • the predetermined pressure by the oxygen gas pressurizing valve 9 is a pressure that suppresses a rise in the water level of the pure water 13 stored in the oxygen gas generation tank 601 beyond a predetermined level.
  • the predetermined pressure by the oxygen gas pressurizing valve 9 of this embodiment is 50 to 150 Pa.
  • the oxygen gas pressurizing valve 9 is preferably constituted by an oxygen gas pressurizing cylinder portion 901, an oxygen gas pressurizing metal ball 902, and a perforated rubber cap 903.
  • the cylinder portion 901 for pressurizing oxygen gas extends above an oxygen gas discharge port 621 having an inner diameter of 2 to 3 mm provided in the upper part of the oxygen gas generation tank 601.
  • the inner diameter of the oxygen gas pressurizing cylinder 901 is set to 1.2 to 1.8 times the diameter of the oxygen gas pressurization metal ball 902.
  • the oxygen gas pressurizing cylinder 901 may be formed integrally with the oxygen gas discharge port 621 or may be formed separately.
  • the oxygen gas pressurizing metal ball 902 is contained in the oxygen gas pressurizing cylinder 901 and closes the oxygen gas discharge port 621 with a predetermined pressure.
  • the diameter of the oxygen gas pressurizing metal ball 902 is set to be larger than the inner diameter of the oxygen gas discharge port 621 and smaller than the inner diameter of the oxygen gas pressurizing cylinder 901.
  • the weight of the oxygen gas pressurizing metal ball 902 is set so as to satisfy a predetermined pressure by the oxygen gas pressurizing valve 9 described above.
  • the oxygen gas pressurizing metal balls 902 of the present embodiment are two stainless steel balls having a diameter of 4 to 5 mm, and are stacked up and down inside the oxygen gas pressurizing cylinder 901.
  • the perforated rubber cap 903 covers the upper end of the oxygen gas pressurizing cylinder 901 so that dust does not enter the oxygen gas pressurizing cylinder 901, and the oxygen gas pressurizing metal ball 902 is pushed up above a predetermined pressure.
  • oxygen gas is discharged from the oxygen gas discharge port 621, the oxygen gas is released to the atmosphere.
  • the backflow prevention valve 10 generates hydrogen gas by utilizing the negative pressure generated in the hydrogen gas generation tank 602 when the power switch 303 of the constant current control circuit 3 is turned off to stop the electrolysis by the electrolysis plate 5.
  • the tank 602 is opened to the atmosphere.
  • the open negative pressure by the check valve 10 of this embodiment is set to ⁇ 100 to 200 Pa.
  • the backflow prevention valve 10 is provided in either the hydrogen gas discharge port 622 or the hydrogen gas relay unit 720.
  • the backflow prevention valve 10 of the present embodiment is connected to the hydrogen gas discharge port 622 on the side of the hydrogen gas discharge port 622 in order to increase sensitivity.
  • the backflow prevention valve 10 preferably has a backflow prevention valve cylinder 101 and a backflow prevention valve metal ball 102.
  • the cylinder portion 101 for the backflow prevention valve has an air opening 103 below it.
  • the inner diameter of the air opening 103 is set to be smaller than the diameter of the backflow prevention valve metal ball 102.
  • the backflow prevention valve metal ball 102 is included in the backflow prevention valve cylinder 101 and closes the atmosphere opening 103 with a predetermined pressure.
  • the diameter of the backflow prevention valve metal ball 102 is set to be larger than the inner diameter of the atmosphere opening 103 and smaller than the inner diameter of the backflow prevention valve cylinder 101.
  • the weight of the metal ball for backflow prevention valve 102 is such that the metal ball for backflow prevention valve 102 is lifted away from the atmosphere opening 103 by the above open negative pressure, and the hydrogen gas generation tank 602 is lifted from the negative pressure to the positive pressure (> 0 Pa). ) Is set so that the backflow prevention valve metal ball 102 quickly closes the atmosphere opening 103.
  • the backflow prevention valve metal balls 102 of the present embodiment are two stainless steel balls having a diameter of 2 to 3 mm, and are stacked up and down inside the backflow prevention valve cylinder 101.
  • the degassing unit 11 evacuates the gas enclosed in each upper part of the hydrogen gas generation tank 602 and the oxygen gas generation tank 601 when water is supplied to the surge tank 8.
  • This degassing part 11 is arrange
  • the gas venting part 11 of this embodiment includes a gas venting rubber stopper 111 and a gas venting rubber cap 112.
  • the gas vent rubber plug 111 is provided for venting the hydrogen gas generation tank 602 and covers the upper opening of the hydrogen gas discharge port 622.
  • the gas vent rubber cap 112 is provided for venting the oxygen gas generation tank 601 and covers the upper opening of the gas vent cylinder extending upward from the upper part of the oxygen gas generation tank 601.
  • the current supplied from the constant current control circuit 3 is supplied to the anode plate 501 and the cathode plate 502 of the electrolysis plate 5 respectively.
  • the pair of electrode plates 500 including the anode plate 501 and the cathode plate 502 are in close contact with both surfaces of the ion exchange membrane 510 by the fixing portion 520. Therefore, the pure water 13 is electrolyzed without adding an electrolysis promoter such as acid or alkali to the pure water 13 supplied to the electrolytic cell 6.
  • an electrolysis promoter such as acid or alkali
  • the pair of electrode plates 500 are made of expanded metal having a plurality of passage holes (mesh) 503 having apex angles 504504 set to 45 degrees or less, hydrogen gas having a nanometer bubble diameter at the initial generation stage.
  • the oxygen gas bubbles 15 are detached from the pair of electrode plates 500 in the state of the bubbles 15 having a bubble diameter of micro level before growing into the bubbles 15 having a bubble diameter of millimeter level.
  • the hydrogen gas discharged from the hydrogen gas discharge port 622 of the hydrogen gas generation tank 602 reaches the lower part of the hydrogen gas storage unit 710 via the hydrogen gas relay unit 720. Since the hydrogen gas storage unit 710 stores water 14 at a predetermined water level, the hydrogen gas exhaust pressure (150 to 500 Pa) is required for the hydrogen gas to move from the hydrogen gas relay unit 720 to the hydrogen gas storage unit 710. It must be higher than the water pressure (about 100 to 250 Pa) received from the hydrogen gas reservoir 710 during movement. This water pressure becomes a predetermined pressure for pressurizing the hydrogen gas generated from the hydrogen gas generation tank 602.
  • the surge tank 8 is simply connected to the hydrogen gas generation tank 602 and the oxygen gas generation tank 601, and temporarily removes the pure water 13 excessively flowing into the hydrogen gas generation tank 602 and the oxygen gas generation tank 601. Accumulate. Thereby, the increase and decrease of the rapid inflow amount in the hydrogen gas generation tank 602 and the oxygen gas generation tank 601 are alleviated, and the water level of the electrolytic cell 6 is leveled.
  • the oxygen gas pressurizing valve 9 discharges the oxygen gas generated from the oxygen gas generation tank 601 while pressurizing it.
  • fine adjustment of the predetermined pressure by the oxygen gas pressurizing valve 9 is performed, as shown in FIGS. 3 and 4, the perforated rubber cap 903 is removed, and the size and number of the metal balls 902 for the oxygen gas pressurizing valve are changed. Since it is only necessary to change and adjust the total weight of the metal ball 902 for the oxygen gas pressurizing valve and attach the perforated rubber cap 903 to the original position, the fine adjustment is easy compared with the conventional spring-type pressurizing valve. It is.
  • the hydrogen gas stored above the hydrogen gas storage unit 710 passes through an external instrument such as a tracheal cannula or an experimental tube connected to the hydrogen gas outlet 732 of the hydrogen gas extraction unit 730. Supplied for aspiration and experiment.
  • an external instrument such as a tracheal cannula or an experimental tube connected to the hydrogen gas outlet 732 of the hydrogen gas extraction unit 730. Supplied for aspiration and experiment.
  • the tank rubber plug 802, the gas vent rubber cap 112, and the gas vent rubber plug 111 are attached.
  • the gas vent rubber cap 112 and the gas vent rubber plug 111 the pressure relationship between the electrolytic cell 6 and the surge tank 8 is maintained, and the surge tank 8 is generated inside the electrolytic cell 6. Absorbs subtle pressure changes.
  • the desktop hydrogen gas generator 1 of this embodiment includes an ion exchange membrane 510 that does not have a liquid and gas passage hole 503, a pair of electrode plates 500 that are in close contact with both surfaces of the ion exchange membrane 510, and ions
  • the electrolysis plate 5 having a fixing portion 520 for bringing the pair of electrode plates 500 into close contact with both surfaces of the exchange membrane 510 and the electrolysis plate 5 as a partition plate are partitioned into the electrolysis plate 5 and subjected to electrolysis.
  • a hydrogen gas pressurizing unit 7 for taking out the hydrogen gas generated from the hydrogen gas generating tank 602 while pressurizing.
  • the electrolysis plate 5 serves as a partition plate for the electrolytic cell 6 that spatially separates the hydrogen gas generation tank 602 and the oxygen gas generation tank 601, hydrogen gas and oxygen are supplied when the electrolysis plate 5 is energized. They can be generated separately without mixing the gases. Further, even if pure water 13 moves from the oxygen gas generation tank 601 to the hydrogen gas generation tank 602 by electrophoresis during electrolysis, the hydrogen gas pressurizing unit 7 adds hydrogen gas generated from the hydrogen gas generation tank 602. Therefore, the pure water 13 moved to the hydrogen gas generation tank 602 by electrophoresis can be prevented from overflowing from the hydrogen gas generation tank 602.
  • the desktop hydrogen gas generator 1 of the present embodiment stores the pure water 13 and is connected to the lower portions of the hydrogen gas generation tank 602 and the oxygen gas generation tank 601 respectively, Is preferably further provided.
  • the surge tank 8 since the surge tank 8 is connected to the lower portions of the hydrogen gas generation tank 602 and the oxygen gas generation tank 601, the surge tank 8 is added to the hydrogen gas generation tank 602 and the oxygen gas generation tank 601, respectively. While supplying the water 13, the pure water 13 biased to one of the hydrogen gas generation tank 602 or the oxygen gas generation tank 601 can be moved to the other.
  • the surge tank 8 since the surge tank 8 is connected to each lower part of the hydrogen gas generation tank 602 and the oxygen gas generation tank 601, the surge tank 8 can be used to change the water level of the electrolytic tank 6 and the pressure difference between the hydrogen gas and the oxygen gas that change every moment. Can be buffered.
  • the desktop hydrogen gas generator 1 of the present embodiment is generated from the oxygen gas generation tank 601 at a pressure that suppresses the water level of the pure water 13 stored in the oxygen gas generation tank 601 from rising above a predetermined level. It is preferable to further include an oxygen gas pressurizing valve 9 that discharges the oxygen gas while pressurizing.
  • the hydrogen gas generated from the hydrogen gas generation tank 602 It is possible to prevent the pure water 13 from overflowing from the oxygen gas discharge port 621 due to the reaction that is pressurized by the hydrogen gas pressurizing unit 7. Further, since the oxygen gas is discharged when the pressure exceeds a predetermined pressure, it is possible to prevent the oxygen gas generation tank 601 from being overpressured and the oxygen gas generation tank 601 and the electrolysis plate 5 from being damaged.
  • the hydrogen gas pressurizing unit 7 is provided in the upper part of the hydrogen gas storage unit 710 that stores the water 14 at a predetermined water level and the hydrogen gas generation tank 602.
  • a hydrogen gas relay unit 720 that relays between the generated hydrogen gas discharge port 622 and the lower part of the hydrogen gas storage unit 710, and a hydrogen gas extraction unit 730 that extracts hydrogen gas from the upper part of the hydrogen gas storage unit 710.
  • the hydrogen gas is preferably pressurized by a predetermined water pressure generated by the pure water 13 stored in the hydrogen gas storage unit 710.
  • the pressurization structure and pressurization adjustment are facilitated. be able to. Further, since hydrogen gas passes through the water 14 of the hydrogen gas storage unit 710, generation of hydrogen gas can be confirmed as the bubbles 15.
  • the water 14 of the hydrogen gas storage unit 710 is interposed between the hydrogen gas relay unit 720 and the hydrogen gas extraction unit 730, even if the hydrogen gas extracted from the hydrogen gas extraction unit 730 ignites, It is possible to prevent the water 14 stored in the gas storage unit 710 from extinguishing the ignition and igniting the hydrogen gas generated from the hydrogen gas generation tank 602.
  • the pair of electrode plates 500 preferably each have a plurality of through holes 503 having apex angles 504504 having an inner angle of 45 degrees or less.
  • the electrolytic efficiency by the electrolysis plate 5 is improved by about 10 to 15% compared to the passage hole 503 having an apex angle 504504 of 45 degrees or more and the passage hole 503 having a semicircular or semi-elliptical upper shape.
  • hydrogen gas can be taken out from the hydrogen gas generation tank 602 without attaching a circulation pump to the electrolytic tank 6.
  • the ion exchange membrane 510 is provided coaxially with the passage holes 503 included in the pair of electrode plates 500 and is smaller than the passage holes 503.
  • a plurality of rivet holes 511 are equally provided on the contact surface of the electrode plate 500, and the fixing portion 520 has an outer diameter smaller than the inner diameter of the passage hole 503 and larger than the inner diameter of the rivet hole 511 and the passage hole 503.
  • a rivet head 522 is preferably a thermoplastic plastic rivets which expands upon absorbing liquid.
  • the rivet holes 511 are evenly arranged and the two rivet heads 522 make the pair of electrode plates 500 in close contact with both surfaces of the ion exchange membrane 510, the pair of electrode plates 500. And the ion exchange membrane 510 can be uniformly adhered over the entire surface. Further, since the outer diameter of the rivet shaft 521 is larger than the inner diameter of the rivet hole 511, the gas generated from the pure water 13 of the electrolytic cell 6 and the electrolysis plate 5 is passed through the rivet hole 511 and the hydrogen gas generation tank 602. And the oxygen gas generation tank 601 can be prevented from passing each other.
  • the oxygen gas pressurizing valve 9 includes a cylindrical portion extending above the oxygen gas discharge port 621 provided in the upper part of the oxygen gas generation tank 601. And a metal ball enclosed in the cylindrical portion and closing the oxygen gas discharge port 621 with a predetermined pressure.
  • the pressure for closing the oxygen gas discharge port 621 can be easily changed by changing the weight or number of the metal balls, so that the oxygen gas exhaust pressure can be easily and finely controlled. it can.
  • the electrolytic cell 6 includes two divided cases 611 having a shape obtained by dividing a closed container in the vertical direction, and a pair of electrode plates 500. It is preferable to have a fastening portion 612 that integrally fastens the two split cases 611 in a state where the peripheral portion of the larger ion exchange membrane 510 is sandwiched between the peripheral portions of the two split cases 611.
  • the structure of the electrolytic cell 6 can be simplified. Further, the sealing performance of the electrolytic cell 6 can be ensured without using a soft gasket at the peripheral edge of the two divided cases 611.
  • the desktop hydrogen gas generator 1 of the present embodiment opens the hydrogen gas generation tank 602 to the atmosphere using the negative pressure generated in the hydrogen gas generation tank 602 when the electrolysis plate 5 stops electrolysis. It is preferable to further include a backflow prevention valve 10.
  • the backflow prevention valve 10 opens the hydrogen gas generation tank 602 to the atmosphere when the electrolysis is stopped, the water 14 stored in the hydrogen gas storage unit 710 passes through the hydrogen gas relay unit 720. Backflow to 602 can be prevented.
  • the backflow prevention valve 10 includes the atmosphere opening 103 and a metal ball that closes the atmosphere opening 103 with a predetermined pressure, It is preferably attached to the outlet 622 or the hydrogen gas relay part 720.
  • the open negative pressure can be easily and finely adjusted as compared with the spring-type check valve 10.
  • the electrolysis plate 5 has a maximum hydrogen gas generation amount of 10 ml / min during electrolysis of the pure water 13, and the electrolysis plate 5
  • the hydrogen gas generated from the hydrogen gas pressurizing unit 7 pressurizes the hydrogen gas generated from the hydrogen gas generating tank 602 at 100 to 400 Pa to generate oxygen gas.
  • the pressurizing valve 9 pressurizes the oxygen gas generated from the oxygen gas generating tank 601 at 50 to 150 Pa
  • the backflow prevention valve 10 is the hydrogen gas generating tank 602 when the negative pressure of the hydrogen gas generating tank 602 is ⁇ 100 to 200 Pa. Is preferably opened to the atmosphere.
  • the pressure inside the electrolytic cell 6 rises rapidly, and the hydrogen gas and oxygen gas are forced from the rivet hole 511 of the ion exchange membrane 510. It can be prevented from passing through.
  • the surge tank 8 supplies the pure water 13 to the electrolytic cell 6 while controlling each pressure in detail, the water level of the electrolytic cell 6 is maintained at ⁇ 5 mm, and from the hydrogen gas generating unit and the oxygen gas generating unit The pure water 13 can be prevented from overflowing, and the generation efficiency of hydrogen gas and oxygen gas can be maintained.
  • the open negative pressure is close to 0 Pa, backflow can be prevented while maintaining the pressure relationship between the water level of the electrolytic cell 6 and the generated gas.
  • the hydrogen gas generation tank 602 and the oxygen gas generation tank 601 are connected to each upper portion or a member connected to each upper portion when hydrogen is supplied to the surge tank 8. It is preferable to have the gas venting part 11 for venting the gas sealed in each upper part of the gas generating tank 602 and the oxygen gas generating tank 601.
  • the gas in the electrolytic cell 6 escapes from the gas vent 11 at the time of water supply to the surge tank 8, only the water supply escapes, so that the pressure relationship of the electrolytic cell 6 can be maintained.
  • the desktop hydrogen gas generator 1 of the present embodiment further includes a protective housing 2 that covers the desktop hydrogen gas generator 1, and the protective housing 2 is provided in the hydrogen gas pressurizing unit 7. It is preferable to have a confirmation window 230 for visually recognizing the bubbles 15 of hydrogen gas passing through the pure water 13.
  • the desktop hydrogen gas generator 1 of the present embodiment further includes a hydrogen gas generation amount meter 4 that displays the generation amount of hydrogen gas according to the current value applied to the electrolysis plate 5. It is preferable.
  • the amount of hydrogen gas generated can be controlled while checking the hydrogen gas generation amount meter 4.
  • the desktop hydrogen gas generator 1 of the present embodiment it is possible to provide a new desktop hydrogen gas generator 1 that has improved various problems in the prior art such as miniaturization and portability. There is an effect.
  • SYMBOLS 1 Desktop type hydrogen gas generator, 2 ... Protective housing, 3 ... Constant current control circuit, 4 ... Hydrogen gas generation amount meter, 5 ... Electrolysis board, 6 ... Electrolyzer, 7 ... Hydrogen gas pressurization part, 8 ... Surge tank, 9 ... Oxygen gas pressurization valve, 10 ... Backflow prevention valve, 11 ... Degassing part, 13 ... Pure Water, 14 ... Water, 15 ... Bubble, 101 ... Cylinder part for backflow prevention valve, 102 ... Metal ball for backflow prevention valve, 103 ... Air release port, 111 ... Air vent Rubber plug, 112 ... rubber cap for venting, 200 ... main body support part, 201 ...

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Abstract

L'invention fournit un nouveau dispositif de génération de gaz hydrogène de bureau qui améliore les dysfonctionnements relatifs à des techniques de l'art antérieur, tel que des problèmes de miniaturisation, de propriétés liées à son aspect portable, ou similaire. Le dispositif de génération de gaz hydrogène de bureau (1) de l'invention est équipé : d'une plaque d'électrolyse (5) constituée par mise en adhésion individuellement de plaques d'électrode formant une paire (500) sur les deux faces d'une membrane échangeuse d'ions (510); d'une cuve d'électrolyse (6) qui est divisée par la plaque d'électrolyse (5), et qui possède une cuve de génération de gaz hydrogène (602) ainsi qu'une cuve de gaz oxygène (601) stockant chacune une eau douce (13) faisant l'objet d'une électrolyse; et d'une partie de mise sous pression de gaz hydrogène (7) qui extrait tout en le mettant sous pression un gaz hydrogène généré par la cuve de génération de gaz hydrogène (602) sous une pression empêchant une élévation égale ou supérieure à un niveau prédéfini de l'eau douce (13) stockée dans la cuve de génération de gaz hydrogène (602).
PCT/JP2013/069395 2012-07-20 2013-07-17 Dispositif de génération de gaz hydrogène de bureau WO2014014021A1 (fr)

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KR1020167020501A KR101732117B1 (ko) 2012-07-20 2013-07-17 탁상형 수소가스 발생장치
KR1020157004384A KR101718110B1 (ko) 2012-07-20 2013-07-17 탁상형 수소가스 발생장치

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JP2012-162127 2012-07-20
JP2012162127A JP5196510B1 (ja) 2012-07-20 2012-07-20 卓上型水素ガス発生装置

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CN108677206A (zh) * 2018-05-24 2018-10-19 河北云悦生物科技有限公司 氢发生装置
EP4079937A3 (fr) * 2021-04-21 2022-11-02 Sungrow Power Supply Co., Ltd. Dispositif de production d'hydrogène par électrolyse d'eau
EP4109018A4 (fr) * 2020-03-24 2023-08-02 Hefei Midea Refrigerator Co., Ltd. Module d'élimination d'oxygène, dispositif de conservation au frais et réfrigérateur

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