WO2013073137A1 - 酸素燃焼ボイラの微粉燃料供給方法及び酸素燃焼ボイラシステム - Google Patents
酸素燃焼ボイラの微粉燃料供給方法及び酸素燃焼ボイラシステム Download PDFInfo
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- WO2013073137A1 WO2013073137A1 PCT/JP2012/007159 JP2012007159W WO2013073137A1 WO 2013073137 A1 WO2013073137 A1 WO 2013073137A1 JP 2012007159 W JP2012007159 W JP 2012007159W WO 2013073137 A1 WO2013073137 A1 WO 2013073137A1
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- Prior art keywords
- gas
- pulverized fuel
- fuel
- pulverized
- nitrogen gas
- Prior art date
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- 239000000446 fuel Substances 0.000 title claims abstract description 139
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 56
- 239000001301 oxygen Substances 0.000 title claims abstract description 56
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 52
- 238000002485 combustion reaction Methods 0.000 title claims abstract description 12
- 238000000034 method Methods 0.000 title claims description 10
- 239000007789 gas Substances 0.000 claims abstract description 128
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 69
- 229910001873 dinitrogen Inorganic materials 0.000 claims abstract description 59
- 238000010298 pulverizing process Methods 0.000 claims abstract description 38
- 239000012530 fluid Substances 0.000 claims abstract description 36
- 239000000843 powder Substances 0.000 claims abstract description 35
- 238000004519 manufacturing process Methods 0.000 claims abstract description 30
- 239000012159 carrier gas Substances 0.000 claims abstract description 29
- 238000000926 separation method Methods 0.000 claims abstract description 10
- 238000001035 drying Methods 0.000 claims abstract description 5
- 238000007789 sealing Methods 0.000 claims description 24
- 229910001882 dioxygen Inorganic materials 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- 239000002737 fuel gas Substances 0.000 claims description 2
- 239000000284 extract Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 24
- 239000003245 coal Substances 0.000 description 19
- 229910002092 carbon dioxide Inorganic materials 0.000 description 12
- 239000001569 carbon dioxide Substances 0.000 description 12
- 239000003077 lignite Substances 0.000 description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000000428 dust Substances 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 230000003134 recirculating effect Effects 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- 239000004449 solid propellant Substances 0.000 description 2
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- UBAZGMLMVVQSCD-UHFFFAOYSA-N carbon dioxide;molecular oxygen Chemical compound O=O.O=C=O UBAZGMLMVVQSCD-UHFFFAOYSA-N 0.000 description 1
- 238000009841 combustion method Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23N—REGULATING OR CONTROLLING COMBUSTION
- F23N1/00—Regulating fuel supply
- F23N1/04—Regulating fuel supply conjointly with air supply and with draught
- F23N1/042—Regulating fuel supply conjointly with air supply and with draught using electronic means
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23K—FEEDING FUEL TO COMBUSTION APPARATUS
- F23K3/00—Feeding or distributing of lump or pulverulent fuel to combustion apparatus
- F23K3/02—Pneumatic feeding arrangements, i.e. by air blast
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C9/00—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber
- F23C9/003—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber for pulverulent fuel
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C9/00—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber
- F23C9/08—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber for reducing temperature in combustion chamber, e.g. for protecting walls of combustion chamber
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23K—FEEDING FUEL TO COMBUSTION APPARATUS
- F23K1/00—Preparation of lump or pulverulent fuel in readiness for delivery to combustion apparatus
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L15/00—Heating of air supplied for combustion
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L7/00—Supplying non-combustible liquids or gases, other than air, to the fire, e.g. oxygen, steam
- F23L7/007—Supplying oxygen or oxygen-enriched air
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C2202/00—Fluegas recirculation
- F23C2202/20—Premixing fluegas with fuel
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23K—FEEDING FUEL TO COMBUSTION APPARATUS
- F23K2201/00—Pretreatment of solid fuel
- F23K2201/10—Pulverizing
- F23K2201/1003—Processes to make pulverulent fuels
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23K—FEEDING FUEL TO COMBUSTION APPARATUS
- F23K2201/00—Pretreatment of solid fuel
- F23K2201/20—Drying
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23K—FEEDING FUEL TO COMBUSTION APPARATUS
- F23K2201/00—Pretreatment of solid fuel
- F23K2201/30—Separating
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23K—FEEDING FUEL TO COMBUSTION APPARATUS
- F23K2201/00—Pretreatment of solid fuel
- F23K2201/50—Blending
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/32—Direct CO2 mitigation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/34—Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery
Definitions
- the present invention relates to a pulverized fuel supply method for an oxyfuel boiler and an oxyfuel boiler system.
- Patent Documents 1 and 2 show a technique for increasing the carbon dioxide concentration by using an oxyfuel boiler using coal as fuel, and oxygen and nitrogen-based gas (hereinafter referred to as nitrogen gas) by an oxygen production apparatus.
- the obtained oxygen is supplied to the boiler body.
- Patent Document 2 a part of the recirculated gas taken out from the exhaust gas downstream of the boiler body is supplied as a primary recirculating gas to the pulverizer to dry and pulverize the coal, and the finely pulverized fuel and the primary recirculating gas are obtained. Is supplied to the burner of the boiler body.
- the other part of the recirculation gas is supplied as a secondary recirculation gas to a boiler body (for example, a wind box), and the concentration of oxygen supplied from the oxygen production apparatus by adjusting the secondary recirculation gas To stabilize oxyfuel combustion of fine fuel. Therefore, the main components of the gas supplied to the boiler body for the combustion of pulverized fuel are oxygen, carbon dioxide, and water vapor, and the nitrogen in the combustion exhaust gas is suppressed and almost becomes carbon dioxide. Compared with a conventional boiler system containing a large amount of nitrogen, the concentration of carbon dioxide in the exhaust gas can be significantly increased.
- the primary recirculation gas As described above, when supplying the primary recirculation gas as the carrier gas to the pulverizer to dry and pulverize the coal, since the primary recirculation gas contains moisture, the pulverized fuel is moistened. There are concerns that hinder the transportation of fine fuel. That is, for example, it is conceivable that the fluidity of the pulverized fuel is remarkably deteriorated due to the hardening of the pulverized powder due to moisture.
- acidic gas accompanying the primary recirculation gas for example, sulfur oxide (SO X ) such as sulfur dioxide (SO 2 ) or sulfur trioxide (SO 3 ) reacts with moisture to become sulfuric acid, and pulverizer, piping, etc. There is a concern of corroding the equipment. Furthermore, there is a concern that the combustibility of the pulverized fuel deteriorates due to the wetness of the pulverized fuel.
- SO X sulfur oxide
- SO 2 sulfur dioxide
- SO 3 sulfur trioxid
- the primary recirculation gas must be a dry gas. For this reason, after the primary recirculation gas is once cooled to remove moisture, the primary recirculation gas is generally dried by heating again.
- the sulfur oxide (SO X ) that coexists in the primary recirculation gas reacts with the condensed water to generate acidic drain (sulfuric acid). Since piping and the like are corroded, it is necessary to construct the equipment and piping with a corrosion-resistant material, and there is a problem that the equipment becomes expensive.
- lignite which is considered to be low grade among coal, is often used as a fuel due to fuel conditions and the like.
- especially lignite has a property of being easily ignited when dried. Therefore, when brown coal is supplied to the pulverizer and preheated primary recirculation gas is supplied and dried and pulverized, oxygen is contained in the primary recirculation gas, so that there is a problem that ignition tends to occur.
- a method for obtaining a pulverized fuel by supplying pulverized wood scrap and waste together with the coal to the pulverizer, or a pulverized fuel provided with a dedicated pulverizer for supplying and pulverizing wood, etc. Although a method of obtaining the above has been proposed, these woods and the like may also ignite when pulverized.
- Patent Document 2 coal is supplied to a coal mill that supplies carrier air heated by an air superheater, and pulverized coal obtained by pulverization is sent to the solid-gas separator by the carrier air.
- the pulverized coal from which the carrier air has been removed is supplied to the hopper.
- the pulverized coal of a hopper is supplied so that it may mix with the oxygen from an oxygen production apparatus with a pulverized coal meter, and the boiler made to guide to a combustion apparatus is described.
- Patent Document 2 since the boiler of Patent Document 2 supplies heated carrier air to a coal mill and pulverizes the coal, there is a concern that ignition may occur when lignite or the like is used as fuel. Further, when heating by the air superheater is stopped in order to prevent ignition, there is a problem that it becomes difficult to transport and quantitatively supply pulverized coal because it cannot be dried in the case of wet fuel.
- the present invention has been made in view of the above-described conventional problems, and it is possible to stably pulverize a fuel that is easily ignited during pulverization, and to supply fine pulverized fuel to a boiler. It is to propose a fuel supply method and an oxyfuel boiler system.
- the pulverized fuel supply method for an oxyfuel boiler includes a pulverizer for drying and pulverizing a fuel with a carrier gas to send a mixed fluid of the carrier gas and the pulverized fuel, and introducing air into the oxygen and nitrogen gas to separate them.
- An oxygen production apparatus a boiler main body for supplying the finely pulverized fuel pulverized by the pulverization apparatus to the burner and supplying oxygen from the oxygen production apparatus for combustion, and extracting a part of the exhaust gas downstream of the boiler main body
- a method for supplying fine fuel to an oxyfuel boiler having a recirculation gas passage for supplying a part of the exhaust gas as a primary recirculation gas to the burner and a recirculation gas passage for supplying the other part as a secondary recirculation gas to the boiler body.
- Nitrogen gas separated by the oxygen production apparatus is supplied as a carrier gas to a pulverizer to dry and pulverize the fuel, and a mixed fluid of nitrogen gas and pulverized fuel derived from the pulverizer is supplied to the fine powder separator.
- the pulverized fuel is separated, and the separated pulverized fuel is mixed with the primary recirculation gas and guided to a burner.
- An oxyfuel boiler system includes a pulverizer for drying and pulverizing fuel with a carrier gas to send a mixed fluid of finely pulverized fuel and carrier gas, and an oxygen production device for introducing air into oxygen and nitrogen gas.
- An oxyfuel boiler system having a recirculation gas flow path for supplying a part to the burner as a primary recirculation gas and supplying another part as a secondary recirculation gas to the boiler body,
- a pulverizing apparatus that introduces nitrogen gas separated by the oxygen production apparatus as a carrier gas, performs dry pulverization of the fuel, and sends a mixed fluid of nitrogen gas and pulverized fuel;
- a pulverized fuel supply device comprising a pulverized fuel separation device for separating the pulverized fuel in the mixed fluid delivered from the pulverizing device, and a pulverized fuel flow auxiliary system for mixing the pulverized fuel separated by the fine powder separator with the primary recirculation gas; , It is provided with.
- the fine powder separation device may include at least one of a cyclone and a bag filter.
- the pulverized fuel supply device has a sealing means for preventing the nitrogen gas of the mixed fluid from being mixed with the primary recirculation gas.
- the oxyfuel boiler system preferably includes a carrier gas preheater that heats nitrogen gas separated by the oxygen production apparatus and guided to the pulverization apparatus.
- the nitrogen gas separated by the oxygen production apparatus is introduced as a carrier gas into the pulverizer to dry and pulverize the fuel, so that the inside of the pulverizer can be maintained in an inert atmosphere with nitrogen gas. Therefore, stable pulverization can be performed even with a fuel that is easily ignited, and since the nitrogen gas does not contain moisture, an excellent effect of obtaining a dry finely pulverized fuel can be obtained.
- FIG. 1 It is a whole lineblock diagram showing the outline of one example of the oxyfuel boiler system of the present invention. It is a side view which shows a detailed example of the pulverized fuel supply apparatus in FIG. It is a side view which shows the other detailed example of the pulverized fuel supply apparatus of FIG. It is a side view which shows another detailed example of the pulverized fuel supply apparatus of FIG. It is a whole block diagram which shows the outline of the other Example of the oxyfuel boiler system of FIG.
- FIG. 1 schematically shows an embodiment of an oxyfuel boiler system according to the present invention.
- reference numeral 1 denotes an oxygen production apparatus that takes in air 2 and separates it into oxygen 3 and nitrogen gas 4 (nitrogen-based gas).
- Reference numeral 5 denotes a pulverizing apparatus for introducing a solid fuel 6 such as coal to perform pulverization.
- Reference numeral 7 denotes a boiler body provided with a burner 8 and a wind box 9.
- Reference numeral 10 denotes a flue for guiding the exhaust gas 11 of the boiler body 7 downstream.
- the flue 10 is provided with a denitration device 12, a carrier gas preheater 13a, a primary air heater 13b, a secondary air heater 13c, and a dust remover 14.
- the flue 10 at the outlet of the dust remover 14 is provided with a recirculation passage 15 for branching out a part of the exhaust gas 11 as a recirculation gas 11 ′, and a part of the branched recirculation gas 11 ′ is primary.
- the recirculation gas 16 is supplied to the burner 8 through the primary air heater 13b by the primary recirculation gas passage 16a.
- the other part of the branched recirculation gas 11 ′ is supplied as secondary recirculation gas 17 to the boiler body 7 through the secondary air heater 13c through the secondary recirculation gas flow path 17a.
- the boiler body 7 for supplying the secondary recirculation gas 17 includes the wind box 9 and an OAP (over air port) (not shown) provided on the upper portion of the wind box 9.
- the oxygen 3 separated by the oxygen production apparatus 1 is mixed with the secondary recirculation gas 17 in the secondary recirculation gas flow path 17a through the oxygen supply pipe 18.
- a part of the oxygen 3 may be branched by the branch pipe 19 and supplied to the burner 8.
- the nitrogen gas 4 separated by the oxygen production apparatus 1 is supplied to the pulverization apparatus 5 as a carrier gas through the carrier gas preheater 13a through a nitrogen gas supply pipe 20. Therefore, the pulverizing apparatus 5 performs the pulverization as the solid fuel 6 is dried by supplying the nitrogen gas 4, and the mixed fuel 22 of the pulverized fuel 21 and the nitrogen gas 4 generated by the pulverization is sent out from the mixed fluid pipe 23.
- reference numerals 27, 28 and 29 denote pushing fans.
- the mixed fluid 22 delivered from the mixed fluid pipe 23 is guided to the pulverized fuel supply device 26.
- the pulverized fuel supply device 26 introduces the mixed fluid 22 and separates the pulverized fuel 21.
- the pulverized fuel supply device 26 separates the pulverized fuel 21, and the pulverized fuel 21 separated by the pulverized fuel separator 24 is connected to the burner 8.
- a fine powder flow auxiliary system 25 mixed with the primary recirculation gas 16 of the gas flow path 16a.
- FIG. 2 shows a detailed example of the pulverized fuel supply device 26 in FIG. 1 and shows a case where the mixed fluid 22 from the pulverizing device 5 is supplied to a cyclone 30 which is a fine powder separating device 24. .
- a cyclone 30 which is a fine powder separating device 24.
- the mixed fluid pipes 23 from the pulverizing apparatus 5 are branched into a plurality of parts, and each of the branched mixed fluid pipes 23 is associated with each corresponding cyclone. Connect to 30.
- the mixed fluid 22 from the mixed fluid pipe 23 is introduced from the tangential direction into the large-diameter portion 31 at the upper part of the cyclone 30, and the mixed fluid 22 introduced into the cyclone 30 is reduced in the diameter-reduced portion 32 that is reduced in diameter downward.
- the pulverized fuel 21 is separated by centrifugal force, and the separated pulverized fuel 21 falls into the cylindrical portion 33 below the reduced diameter portion 32. Further, the separated nitrogen gas 4 is taken out from the upper center of the cyclone 30.
- Another diameter-reduced portion 34 having a diameter reduced downward is formed at the lower portion of the cylindrical portion 33, and the pulverized fuel 21 that has passed through the diameter-reduced portion 34 is supplied to the primary recirculation gas channel 16a. Are mixed with the primary recirculation gas 16 and supplied to the burner 8.
- a pulverized flow auxiliary system 25 is provided in order to prevent this clogging problem and stably supply the pulverized fuel 21 to the primary recirculation gas passage 16a.
- the fine powder flow auxiliary system 25 branches a part of the primary recirculation gas 16 from the primary recirculation gas flow path 16a and pressurizes it with a pressurized fan 35, and the compressed primary recirculation gas 16 is reduced in diameter.
- a nozzle 36 that blows into the portion 34 is provided.
- the primary recirculation gas 16 blown from the nozzle 36 prevents the fine fuel 21 inside the reduced diameter portion 34 from flowing and prevents the fine fuel 21 from being clogged. Is stably supplied to the primary recirculation gas passage 16a.
- the sealing means 37 has a detector 38 that detects a pressure difference between the pressure of the primary recirculation gas 16 in the primary recirculation gas flow path 16a and the pressure inside the cyclone 30, and the detector 38
- the opening degree of the flow rate regulator 39 (damper) provided at the nitrogen gas 4 outlet of the cyclone 30 is adjusted so that the pressure inside the cyclone 30 is lower than the pressure of the primary recirculation gas 16 by a predetermined pressure. I have to.
- the pulverized fuel 21 is accumulated in the cyclone 30 with a required layer thickness.
- a fine fuel layer 21 ′ is formed, and this fine fuel layer 21 ′ exhibits a sealing function, so that the nitrogen gas 4 in the cyclone 30 leaks into the primary recirculation gas flow path 16a and the primary recirculation gas. 16 can be prevented.
- a bag filter 40 is provided in which nitrogen gas 4 separated by the cyclone 30 is introduced to separate fine powder.
- the fine powder separated by the bag filter 40 is supplied to the primary recirculation gas channel 16a by a screw feeder 41 having sealing properties.
- the nitrogen gas 4 from which fine powder has been separated by the bag filter 40 is guided to the chimney 42.
- the fine powder separated by the bag filter 40 may be discarded.
- an exhaust gas purification device 43 is provided downstream of the branch position of the recirculation flow path 15 in the flue 10 shown in FIG. 1, and further, a carbon dioxide recovery device 44 is provided downstream of the exhaust gas purification device 43.
- the liquefied carbon dioxide 45 is generated and taken out.
- the non-condensable off gas 46 separated when the liquefied carbon dioxide 45 is taken out by the carbon dioxide recovery device 44 is guided to the chimney 42.
- the exhaust gas 11 at the outlet of the dust remover 14 in the flue 10 of the boiler body 7 is branched by a recirculation passage 15, and a part of the branched recirculation gas 11 ′ is used as a primary recirculation gas 16. It passes through 16a and is preheated by the primary air heater 13b and supplied to the burner 8. The other part of the branched recirculation gas 11 ′ passes through the secondary recirculation gas passage 17 a as the secondary recirculation gas 17, is preheated by the secondary air heater 13 c, and is supplied to the wind box 9 of the boiler body 7. .
- the oxygen 3 separated from the air 2 in the oxygen production apparatus 1 is mixed with the secondary recirculation gas 17 in the secondary recirculation gas channel 17a by the oxygen supply pipe 18. At this time, a part of the oxygen 3 may be branched by the branch pipe 19 and supplied to the burner 8.
- the nitrogen gas 4 separated from the air 2 in the oxygen production apparatus 1 is preheated by the carrier gas preheater 13a through the nitrogen gas supply pipe 20 and supplied to the grinding device 5 as a carrier gas.
- the fuel 6 is dried and pulverized by supplying the nitrogen gas 4, and the mixed fluid 22 of the pulverized fine fuel 21 and the nitrogen gas 4 is mixed fluid pipe 23. Is sent from.
- the nitrogen gas 4 from the oxygen production apparatus 1 does not contain moisture, and the nitrogen gas 4 is heated by the carrier gas preheater 13a, the fuel 6 is suitably dried and pulverized. Is done. Further, since the nitrogen gas 4 from the oxygen production apparatus 1 does not contain oxygen, the inside of the pulverization apparatus 5 is maintained in an inert atmosphere by the nitrogen gas 4, and therefore, it easily ignites, such as lignite. Even if the fuel 6 is pulverized, the problem that the pulverized fuel 21 ignites can be reliably prevented. Further, since the nitrogen gas 4 is heated by the carrier gas preheater 13a as described above, even if the humid fuel 6 is supplied to the pulverizer 5, it can be dried and pulverized.
- the mixed fluid 22 delivered from the pulverizing device 5 through the mixed fluid pipe 23 is introduced into a cyclone 30 that is a fine powder separation device 24 of the fine powder fuel supply device 26 and separated into the fine fuel 21 and the nitrogen gas 4.
- the pulverized fuel 21 falls down inside the cyclone 30.
- a detector 38 for detecting a pressure difference between the pressure of the primary recirculation gas 16 in the primary recirculation gas flow path 16a and the pressure inside the cyclone 30 is provided, and the primary recirculation gas 16 is detected by the detector 38.
- the primary recirculation gas 16 branched from a portion of the primary recirculation gas 16 of the primary recirculation gas flow path 16 a and pressurized by the pressurized fan 35 is supplied to the nozzle. Since the pulverized fuel flow auxiliary system 25 that is blown by 36 is provided, the pulverized fuel 21 in the pulverized fuel layer 21 ′ is stably cut out and mixed with the primary recirculation gas 16.
- the pulverized fuel 21 separated in the cyclone 30 is stabilized to the primary recirculation gas flow path 16a by the pulverized flow auxiliary system 25 in a state where the pulverized fuel layer 21 ′ having a predetermined thickness is always formed in the cyclone 30. Therefore, the finely divided fuel layer 21 'exhibits a sealing function, and the problem that the nitrogen gas 4 in the cyclone 30 leaks to the primary recirculation gas channel 16a is prevented. Therefore, the problem that the carbon dioxide concentration of the exhaust gas 11 is reduced by mixing (diluting) the leaked nitrogen gas 4 with the primary recirculation gas 16 is prevented.
- the fine powder flow auxiliary system 25 is basically used at all times, but can be stopped when the fine powder supply is smooth.
- FIG. 3 shows another detailed example of the pulverized fuel supply device 26 in the case where the pulverized powder separating device 24 composed of the cyclone 30 and the pulverized powder flow auxiliary system 25 are provided.
- a sealing device 47 called a J valve is provided to store the pulverized fuel 21 separated by the cyclone 30.
- a horizontal portion 47b is formed from the lower end of the vertical portion 47a provided at the lower portion of the cyclone 30
- a rising portion 47c is formed from the end portion of the horizontal portion 47b
- a horizontal portion is formed from the upper end of the rising portion 47c.
- An outlet 47d is formed.
- a nozzle in which the primary recirculation gas 16 branched from a portion of the primary recirculation gas 16 of the primary recirculation gas passage 16 a and pressurized by the pressure fan 35 is provided in the sealing device 47.
- 36 constitutes the fine powder flow auxiliary system 25 which is blown from the lower end of the vertical portion 47a toward the other end of the horizontal portion 47b.
- FIG. 3 also has a detector 38 for detecting the pressure difference between the pressure of the primary recirculation gas 16 and the pressure inside the cyclone 30 as in FIG.
- the opening degree of the flow rate regulator 39 (damper) at the nitrogen gas 4 outlet of the cyclone 30 is adjusted so that the pressure inside the cyclone 30 is lower than the pressure of the primary recirculation gas 16 by a predetermined pressure.
- Sealing means 37 is provided.
- the pulverized fuel 21 is always stored in the sealing device 47 with a required layer thickness, while a part of the primary recirculation gas 16 is stored in the sealing device 47. Since the primary recirculation gas 16 branched and pressurized by the pressure fan 35 is provided with the fine powder flow auxiliary system 25 that is blown by the nozzle 36, the fine fuel 21 stored in the sealing device 47 is stably supplied. It is cut out and mixed with the primary recirculation gas 16.
- the pulverized fuel 21 separated in the cyclone 30 is always cut into the primary recirculation gas flow path 16a while maintaining a state where the fine fuel 21 is stored in the sealing device 47 with a constant thickness.
- the pulverized fuel 21 stored in the sealing device 47 exhibits the function as the sealing means 37, and the problem that the nitrogen gas 4 in the cyclone 30 leaks to the primary recirculation gas flow path 16a can be prevented.
- FIG. 4 shows another detailed example of the pulverized fuel supply device 26 in the case where the pulverized powder separating device 24 comprising the cyclone 30 and the pulverized powder flow assisting system 25 are provided.
- the lower part of the cyclone 30 is shown.
- the rotary feeder 49 as 25 is provided.
- the detector 50 detects a pressure difference between the pressure of the primary recirculation gas 16 and the pressure in the upper portion of the hopper 48.
- the sealing means 37 is provided so as to control the rotational speed of the rotary feeder 49 so that the pressure of the rotary feeder 49 becomes lower by a predetermined pressure.
- the pulverized fuel layer 21 ′ having a required layer thickness is always formed in the hopper 48 by the action of the sealing means 37.
- the fuel layer 21 ′ exhibits a sealing function, and the problem that the nitrogen gas 4 in the cyclone 30 leaks to the primary recirculation gas channel 16 a can be prevented.
- FIG. 5 shows an outline of another embodiment of the oxyfuel boiler system of the present invention.
- a pulverized fuel supply device 26 shown in this embodiment is a mixed fluid 22 delivered from the pulverizing device 5 to the mixed fluid pipe 23.
- the bag filter 51 fine powder separation device 24
- the finely divided fuel 21 separated by the bag filter 51 is supplied to the primary recirculation gas passage 16a by a screw feeder 52 (fine powder flow auxiliary system 25) provided at the lower part.
- the screw feeder 52 is kept filled with the pulverized fuel 21.
- the sealing function of the pulverized fuel 21 filled in the screw feeder 52 causes the bag filter 51 to This prevents the nitrogen gas 4 from leaking into the primary recirculation gas channel 16a.
- the pulverized fuel 21 taken out from the outlet of the screw feeder 52 can be supplied in a plurality of branches so as to correspond to the plurality of burners 8. Therefore, when a plurality of primary recirculation gas passages 16a are provided so as to supply the primary recirculation gas 16 corresponding to the plurality of burners 8, the screw feeder is provided for each primary recirculation gas passage 16a.
- the pulverized fuel 21 branched at the 52 outlet can be mixed.
- the nitrogen gas 4 separated in the oxygen production apparatus 1 is introduced into the pulverizer 5 as a carrier gas and dry pulverization of the fuel 6 is performed.
- the inside of the apparatus 5 can be maintained in an inert atmosphere by the nitrogen gas 4, and thus stable pulverization can be performed even in the fuel 6 such as lignite that is easily ignited, and the nitrogen gas 4 does not contain moisture. Therefore, a dry pulverized fuel 4 is obtained.
- the nitrogen gas 4 supplied as the carrier gas to the pulverizer 5 is originally unnecessary when the oxygen 3 is separated by the oxygen production apparatus 1, and the unnecessary nitrogen gas 4 is effectively used as the carrier gas. Economical.
- the fine fuel 21 can be separated and taken out from the mixed fluid 22 supplied from the separation device 5.
- the pulverized fuel supply device 26 is provided with the sealing means 37, it is possible to prevent the nitrogen gas 4 of the mixed fluid 22 from being mixed with the primary recirculation gas 16.
- oxyfuel boiler system of the present invention is not limited to the above-described embodiments, and various modifications can be made without departing from the scope of the present invention.
- the oxyfuel boiler system of the present invention can be applied to stably pulverizing fuel that is easily ignited during pulverization, and further supplying dry fine powder fuel to the boiler.
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Abstract
Description
前記酸素製造装置で分離した窒素ガスを搬送ガスとして粉砕装置に供給することにより燃料の乾燥粉砕を行い、前記粉砕装置から導出される窒素ガスと微粉燃料の混合流体を微粉分離装置に供給して微粉燃料を分離し、分離した微粉燃料を前記一次再循環ガスに混合してバーナに導くようにしたことを特徴とする。
前記酸素製造装置で分離した窒素ガスを搬送ガスとして導入し燃料の乾燥粉砕を行って窒素ガスと微粉燃料の混合流体を送出する粉砕装置と、
該粉砕装置から送出される混合流体中の微粉燃料を分離する微粉分離装置と該微粉分離装置で分離した微粉燃料を前記一次再循環ガスに混合する微粉流動補助系統とからなる微粉燃料供給装置と、
を備えたことを特徴とする。
2 空気
3 酸素
4 窒素ガス(搬送ガス)
5 粉砕装置
6 燃料
7 ボイラ本体
8 バーナ
11 排ガス
16 一次再循環ガス
17 二次再循環ガス
21 微粉燃料
22 混合流体
24 微粉分離装置
25 微粉流動補助系統
26 微粉燃料供給装置
30 サイクロン
37 シール手段
51 バグフィルタ
Claims (6)
- 搬送ガスにより燃料を乾燥粉砕して搬送ガスと微粉燃料の混合流体を送出する粉砕装置と、空気を導入して酸素と窒素ガスとに分離する酸素製造装置と、前記粉砕装置で粉砕した微粉燃料をバーナに供給すると共に前記酸素製造装置からの酸素を導入して燃焼を行うボイラ本体と、該ボイラ本体下流の排ガスの一部を抜き出し、抜き出した排ガスの一部を一次再循環ガスとして前記バーナに供給し、他部を二次再循環ガスとして前記ボイラ本体に供給する再循環ガス流路とを有する酸素燃焼ボイラの微粉燃料供給方法であって、
前記酸素製造装置で分離した窒素ガスを搬送ガスとして粉砕装置に供給することにより燃料の乾燥粉砕を行い、前記粉砕装置から導出される窒素ガスと微粉燃料の混合流体を微粉分離装置に供給して微粉燃料を分離し、分離した微粉燃料を前記一次再循環ガスに混合してバーナに導く酸素燃焼ボイラの微粉燃料供給方法。 - 搬送ガスにより燃料を乾燥粉砕して微粉燃料と搬送ガスの混合流体を送出する粉砕装置と、空気を導入して酸素と窒素ガスとに分離する酸素製造装置と、前記粉砕装置で粉砕した微粉燃料をバーナに供給すると共に前記酸素製造装置からの酸素を供給して燃焼を行うボイラ本体と、該ボイラ本体下流の排ガスの一部を抜き出し、抜き出した排ガスの一部を一次再循環ガスとして前記バーナに供給し、他部を二次再循環ガスとして前記ボイラ本体に供給する再循環ガス流路とを有する酸素燃焼ボイラシステムであって、
前記酸素製造装置で分離した窒素ガスを搬送ガスとして導入し燃料の乾燥粉砕を行って窒素ガスと微粉燃料の混合流体を送出する粉砕装置と、
該粉砕装置から送出される混合流体中の微粉燃料を分離する微粉分離装置と該微粉分離装置で分離した微粉燃料を前記一次再循環ガスに混合する微粉流動補助系統とからなる微粉燃料供給装置と、
を備えた酸素燃焼ボイラシステム。 - 前記微粉分離装置は、サイクロンとバグフィルタの少なくとも一方を有する請求項2に記載の酸素燃焼ボイラシステム。
- 前記微粉燃料供給装置は、混合流体の窒素ガスが一次再循環ガスに混合するのを防止するためのシール手段を有する請求項2に記載の酸素燃焼ボイラシステム。
- 前記微粉燃料供給装置は、混合流体の窒素ガスが一次再循環ガスに混合するのを防止するためのシール手段を有する請求項3に記載の酸素燃焼ボイラシステム。
- 前記酸素製造装置で分離されて前記粉砕装置に導かれる窒素ガスを加熱する搬送ガス予熱器を有する請求項2~5のいずれか1つに記載の酸素燃焼ボイラシステム。
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EP12850226.7A EP2781837B1 (en) | 2011-11-16 | 2012-11-08 | Pulverized fuel supply method for oxyfuel combustion boiler, and oxyfuel combustion boiler system |
CA2855471A CA2855471C (en) | 2011-11-16 | 2012-11-08 | Pulverized fuel supply method for oxyfuel combustion boiler, and oxyfuel combustion boiler system |
AU2012338259A AU2012338259B2 (en) | 2011-11-16 | 2012-11-08 | Pulverized fuel supply method for oxygen combustion boiler, and oxygen combustion boiler system |
US14/271,095 US10024535B2 (en) | 2011-11-16 | 2014-05-06 | Pulverized fuel supply method for oxyfuel combustion boiler, and oxyfuel combustion boiler system |
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JP2011250503A JP6019565B2 (ja) | 2011-11-16 | 2011-11-16 | 酸素燃焼ボイラの微粉燃料供給方法及び酸素燃焼ボイラシステム |
JP2011-250503 | 2011-11-16 |
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US14/271,095 Continuation US10024535B2 (en) | 2011-11-16 | 2014-05-06 | Pulverized fuel supply method for oxyfuel combustion boiler, and oxyfuel combustion boiler system |
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CN103438473A (zh) * | 2013-08-07 | 2013-12-11 | 华电电力科学研究院 | 一种300mw炉底加热与微油点火结合无邻炉输粉机组启动方法 |
CN111750373A (zh) * | 2020-08-07 | 2020-10-09 | 西安热工研究院有限公司 | 一种防止中速磨煤机煤粉管道积粉自燃的烟气再循环系统 |
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WO2017164990A1 (en) * | 2016-03-21 | 2017-09-28 | Linde Aktiengesellschaft | Methods for coal drying and oxy-fuel combustion thereof |
US20170321896A1 (en) * | 2016-05-04 | 2017-11-09 | Elwha Llc | Managing emission produced by a combustion device |
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CN111750373A (zh) * | 2020-08-07 | 2020-10-09 | 西安热工研究院有限公司 | 一种防止中速磨煤机煤粉管道积粉自燃的烟气再循环系统 |
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US20140238281A1 (en) | 2014-08-28 |
EP2781837B1 (en) | 2018-04-04 |
JP2013104637A (ja) | 2013-05-30 |
CA2855471C (en) | 2016-08-16 |
EP2781837A1 (en) | 2014-09-24 |
AU2012338259A1 (en) | 2014-05-29 |
CA2855471A1 (en) | 2013-05-23 |
JP6019565B2 (ja) | 2016-11-02 |
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