WO2013057725A2 - Empaque con válvula respirable para productos perecederos - Google Patents
Empaque con válvula respirable para productos perecederos Download PDFInfo
- Publication number
- WO2013057725A2 WO2013057725A2 PCT/IB2012/055765 IB2012055765W WO2013057725A2 WO 2013057725 A2 WO2013057725 A2 WO 2013057725A2 IB 2012055765 W IB2012055765 W IB 2012055765W WO 2013057725 A2 WO2013057725 A2 WO 2013057725A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- breathable
- ring
- flexible container
- valve
- cap
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D1/00—Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
- B65D1/40—Details of walls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/24—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
- B65D81/26—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators
- B65D81/263—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators for ventilating the contents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D51/00—Closures not otherwise provided for
- B65D51/16—Closures not otherwise provided for with means for venting air or gas
- B65D51/1605—Closures not otherwise provided for with means for venting air or gas whereby the interior of the container is maintained in permanent gaseous communication with the exterior
- B65D51/1611—Closures not otherwise provided for with means for venting air or gas whereby the interior of the container is maintained in permanent gaseous communication with the exterior by means of an orifice, capillary or labyrinth passage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D85/00—Containers, packaging elements or packages, specially adapted for particular articles or materials
- B65D85/30—Containers, packaging elements or packages, specially adapted for particular articles or materials for articles particularly sensitive to damage by shock or pressure
- B65D85/34—Containers, packaging elements or packages, specially adapted for particular articles or materials for articles particularly sensitive to damage by shock or pressure for fruit, e.g. apples, oranges or tomatoes
- B65D85/345—Containers, packaging elements or packages, specially adapted for particular articles or materials for articles particularly sensitive to damage by shock or pressure for fruit, e.g. apples, oranges or tomatoes having a meshed or apertured closure to allow contents to breathe
Definitions
- a package with a breathable valve to prolong the green life of perishable products is disclosed.
- the packaging consists of a flexible container (1) and a breathable valve assembly (2) that allows the concentration of oxygen, carbon dioxide, water vapor and ethylene in the interior atmosphere to be controlled, at a desired value depending on the weight and The product's breathing speed.
- the breathable valve assembly (2) comprises a ring (3) and a breathable cap (4) that is assembled to close the flexible container (1).
- the package disclosed has the advantage of being able to be assembled without the need of a heat sealing technique and of increasing the green life of perishable products, such as vegetables and fruits.
- the present invention relates to the packaging of perishable products, such as vegetables and fruits, in particular with the means for controlling the composition of gases in the interior atmosphere and facilitating closure, for example manual packaging, without using techniques. automatic such as heat sealing.
- Some perishable products such as vegetables and fruits, continue their ripening and aging process after harvest.
- the product During ripening and aging, the product exhibits a breathing process characterized by the absorption of oxygen and the release of carbon dioxide and ethylene. Additionally, the product exhibits moisture perspiration, reducing its weight.
- the reduction of respiration and perspiration in the packaging is crucial to extend the green life of perishable products.
- Other associated problem With uncontrolled respiration it is to reach a high concentration of carbon dioxide in the interior atmosphere of the packaging, which affects the organoleptic properties of the perishable product.
- Breathable packaging technologies include several possibilities, among which are: high permeability films; macro and microperforated films; permeable patches and windows; the valves and ventilation channels.
- Macro and micro perforated films have been disclosed in several patents (US5130152, US2005180664, DE202005011737, GB1 106265, GB1 134667, GB2141688, and JP6199385).
- This alternative has some disadvantages, such as: the need to seal the mouth of the package, the product may block some of the perforations and the need for additional manufacturing operations of the film or bag.
- Permeable patches and windows have been disclosed in the state of the art (US4842875, US4943440, US5045331, GB 1071586, FR2686577 and CN1036539).
- the main disadvantages of this technology are: the need to seal the mouth of the packaging and the need for additional film or bag manufacturing operations.
- the ventilation channels have been disclosed in the state of the art (US2004131731, US2007257040, US20081 16098, WO2007008459, WO2010141467 and JP2002308293).
- the main disadvantages of this technology are: the need to seal the mouth of the packaging and the need for additional operations of manufacturing the bag.
- the packaging of the present invention discloses a combination of flexible container and a breathable valve, in turn composed of a ring and a breathable cap to prolong the green life of perishable products, such as vegetables and fruits.
- the packaging of the present invention provides the possibility of performing a mechanical assembly, either manual or automatic, without the need for heat sealing technologies; of not requiring additional operations in the manufacture of the bags; of being able to open and reopen in the ripening chambers; of being recyclable and low cost. Additionally, by prolonging the green life of the product, it is possible to increase the growth time of the fruit or vegetable in the plant.
- the present invention provides a gasket with a breathable valve to prolong the green life of perishable products that exhibit respiration after harvest, such as vegetables and fruits.
- the package comprises a flexible container and a valve assembly that is assembled at the mouth of the flexible package to create a controlled gaseous atmosphere inside the package.
- the valve assembly comprises a ring located outside the flexible container and a breathable cap located inside the flexible container; these two components are They can be mechanically assembled without the need for heat sealing technologies to close the mouth of the flexible container.
- the breathable cap has fixing means for joining both parts with the flexible container in the middle, which can be assembled by interference and pressure adjustments.
- the breathable cap may be a plastic cap with a plurality of microperforations or nanoperforations, or an annular section that allows the installation of a permeable membrane interspersed between the ring, the flexible container and the breathable cap.
- the permeable membrane can be a cavitated, microperforated or nanoperforated film.
- the concentration of oxygen, water vapor, carbon dioxide and ethylene, is controlled by the permeation of the breathable cap, the weight and respiration rate of the perishable product contained.
- the permeation of the breathable cap is controlled with the number and size of micro and nanoperforations, in the case of the plastic cap and the micro and nano perforated film; and with gas permeability in the case of cavitated film. 5. DESCRIPTION OF THE FIGURES
- FIG. 1 illustrates a breathable valve (2) assembled and installed in the mouth of the flexible container (1).
- the figure also shows an interference assembly as a fixing means and a micro or nanoperforated plastic cover as a breathable cap (4).
- the breathable cap (4) has a circular cavity for a good assembly by interference with the ring (3).
- FIG. 2 illustrates a breathable valve (2) assembled and installed in the mouth of the flexible container (1).
- the figure also illustrates an interference assembly as a fixing means and a micro or nanoperforated plastic cap as a breathable cap (4).
- FIG. 3 illustrates an assembled breathable valve (2), a pressure adjustment (6) as a fixing means and a micro or nanoperforated plastic cap as a breathable cap (4).
- FIG. 4 illustrates an assembled breathable valve (2), a pressure adjustment (6) as a fixing means and a micro or nanoperforated plastic cap as a breathable cap (4).
- the figure also illustrates a rectangular channel (7) to facilitate the demolding without moving elements of the pieces to be assembled by pressure (6).
- FIG. 5 illustrates an assembled breathable valve (2), an interference assembly (8) in the ring (3) as a fixing means and a micro or nanoperforated plastic cap as a breathable cap (4).
- FIG. 6 illustrates another embodiment of the invention using a square-shaped breathable valve (2), an interference assembly as a fixing means and a micro or nanoperforated plastic cap as a breathable cap (4).
- FIG. 7 illustrates another embodiment of the invention using a triangular shaped breathable valve (2), an interference assembly as a fixing means and a micro or nanoperforated plastic cap as a breathable cap (4).
- FIG. 8 illustrates another embodiment of the invention where the breathable plug of the valve assembly is of annular section which allows the installation of a permeable membrane (10) sandwiched between the ring (3), the flexible container (1) and the plug breathable (9).
- FIG. 9 illustrates the evolution of the concentration of oxygen and carbon dioxide over time for two prototypes manufactured in accordance with the present invention. Two microperforated plastic caps with 1 1 and 18 microperforations between 250 and 300 microns in diameter are evaluated.
- the present invention provides a package provided with a breathable valve to prolong the green life of perishable products that exhibit breathing after harvesting, such as vegetables and fruits.
- the package comprises a flexible container (1) characterized by the presence of at least one mouth, and at least one valve assembly (2) composed of two parts: a ring ( 3), which is located on the periphery and outer surface of the mouth of the flexible container (1), and a breathable cap (4), which mechanically engages with the interior of the indigo (3) such that the material of The mouth of the flexible container (1) is fixed between the breathable cap (4) and the ring (3).
- the flexible container (1) is a flexible film, produced for example by emptying, blow extrusion, flat film extrusion, coextrusion or lamination.
- the Polymeric film is produced with a polymer preferably selected from the group comprising Polyethylene, Polypropylene, Polyethylene terephthalate, Polyamide, Copolymers of Polystyrene, Cellophane, Polylactic acid, cellulose acetate, thermoplastic starch and its derivatives, and mixtures of them.
- the valve assembly (2) comprises two parts: the ring (3) and the breathable cap (4), which can be mechanically assembled without the need to use heat sealing technologies to close the mouth of the flexible container (1), nor does it require additional operations in the manufacture of the bag.
- the breathable cap (4) has fixing means for joining both of its parts to the flexible container (1) such that the film that forms the mouth of the container is fixed between the two parts of the valve.
- a pressure adjustment (6) is used in the embodiment illustrated in Figures 3 and 4 .
- Figures 3 and 4 also show a rectangular channel (7) in the breathable cap (4) for the demolding without moving elements of the pieces to be assembled by pressure (6).
- the fixing means for joining both parts of the valve assembly (2) with the flexible container (1) is by interference of the ring (3 ) and the breathable cap (4).
- the breathable cap (4) has conical side walls to facilitate assembly with the ring (3).
- interference assembly is produced between an extension (8) of the breathable cap (4) and the corresponding cavity in the ring (3).
- the preferred embodiment is a ring (3) and a breathable cap (4) of circular shape, other shapes are also possible, for example polygonal or triangular shapes.
- the ring (3) and breathable cap (4) of the valve assembly (2) can be produced by injection molding or by pressing molding, using a polymer preferably from the group comprising thermoplastic polyurethane, vulcanized thermoplastics, thermoplastic elastomers , Polyethylene, Polypropylene, Polyethylene terephthalate, Polyamide, Copolymers of Polystyrene, Polylactic acid, acetate Cellulose, thermoplastic starch and its derivatives, and mixtures thereof.
- the ring (3) and breathable cap (4) of the valve assembly (2) are made of a material whose hardness must be less than that produced by a mark on the fruit or vegetable.
- the hardness should be less than 80 Shore A in the case of bananas, preferably less than 60 Shore A, to ensure that the banana is not damaged, nor is it carved with the valve. For the same reason it is advantageous that the contours are rounded.
- the breathable cap (4) can be a plastic cap characterized by a plurality of micro or nano perforations (5).
- FIG. 8 another embodiment of the present invention uses an annular section (9) that allows the installation of a permeable membrane (10) sandwiched between the ring (3), the flexible container (1) and the annular section ( 9).
- the permeable membrane (10) can be a cavitated film, a micro or nano perforated film. Cavitated film can be produced using a cavitant charge, such as calcium carbonate.
- the microperforated film can be produced using for example a mechanical, laser or electrostatic technology.
- the present invention can use any embodiment of the breathable cap (4) even with the permeable membrane (10) sandwiched between the ring (3) and the flexible container (1).
- the annular section (9) of this mode is mechanically coupled to the ring (3) and the mouth of the flexible container (1) to tension the permeable membrane (10).
- the concentration of oxygen, water vapor, carbon dioxide and ethylene can be controlled by the permeation of the breathable cap (4), the weight and the respiration rate of the perishable product contained.
- the permeation of the breathable cap (4) is controlled with the number and size of the micro and nano perforations in the case of the plastic cap and the micro and nano perforated film, and with the gas permeability in the case of the film cavitated
- the flexible container is a bag made of a 30 micron thick Polyethylene film with dimensions of 300 by 380 mm, an assembly of 32 mm inner diameter valve with a plastic lid with 1 1 microperforations between 250 and 300 microns.
- About 1.2 kg of bananas were packed and green life was evaluated at room temperature and refrigerated at 13 ° C.
- the disclosed packaging prototype is compared with the following technologies available in the state of the art: a microperforated bag 30 microns thick with 50 microperforations 200 microns in diameter and a macroperforated bag 30 microns thick and 12 12.5 mm holes diameter.
- Breathable valve packaging increases green life, decreases weight loss and reduces the conversion of starch into carbohydrates (measured as brix degrees).
- the flexible container is a bag made of a 30 micron thick Polyethylene film with dimensions of 300mm by 380mm, a 32mm inner diameter valve assembly with an annular section and a mechanically microperforated film. About 1.2 kg of bananas were packed and green life was evaluated at 13 ° C.
- the prototype of the package disclosed is compared with the technologies existing in the state of the art of example 1.
- the breathable valve package increases green life, decreases weight loss and reduces the conversion of starch into carbohydrates (measured as brix degrees).
- breathable valve material An important feature of the breathable valve material is its hardness and its contours, so that it does not cause damage to the perishable product that is being packed.
- the effect of hardness and the contour of the packing material with breathable valve on bananas is evaluated.
- the effect of 3.5 kg (approximately three green banana plantains) applied on the breathable valve and on the banana peel is evaluated.
- the use of a Shore A hardness of less than 80 and a valve with a rounded contour is essential to prevent the banana peel from being carved. Table 3
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Food Science & Technology (AREA)
- Ceramic Engineering (AREA)
- Packging For Living Organisms, Food Or Medicinal Products That Are Sensitive To Environmental Conditiond (AREA)
- Packages (AREA)
- Storage Of Fruits Or Vegetables (AREA)
- Bag Frames (AREA)
- Closures For Containers (AREA)
Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MX2014004816A MX2014004816A (es) | 2011-10-19 | 2012-10-19 | Empaque con valvula respirable para productos perecederos. |
US14/352,728 US20140251858A1 (en) | 2011-10-19 | 2012-10-19 | Packaging comprising a breathable valve for perishable products |
JP2014536401A JP2014534128A (ja) | 2011-10-19 | 2012-10-19 | 生鮮物のための通気可能バルブを備える包装材 |
EP12841504.9A EP2769932A4 (en) | 2011-10-19 | 2012-10-19 | PACKAGING WITH ATATING VALVE FOR DENRÉES |
CN201280062726.7A CN104066658A (zh) | 2011-10-19 | 2012-10-19 | 用于易腐产品的包含透气阀的包装 |
HK15102015.0A HK1201503A1 (en) | 2011-10-19 | 2015-02-27 | Packaging comprising a breathable valve for perishable products |
HK15103012.1A HK1202507A1 (en) | 2011-10-19 | 2015-03-24 | Packaging comprising a breathable valve for perishable products |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CO11140033 | 2011-10-19 | ||
CO11140033A CO6660073A1 (es) | 2011-10-19 | 2011-10-19 | Empaque con válvula respirable para productos perecederos |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2013057725A2 true WO2013057725A2 (es) | 2013-04-25 |
WO2013057725A3 WO2013057725A3 (es) | 2013-06-13 |
Family
ID=48141500
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IB2012/055765 WO2013057725A2 (es) | 2011-10-19 | 2012-10-19 | Empaque con válvula respirable para productos perecederos |
Country Status (11)
Country | Link |
---|---|
US (1) | US20140251858A1 (es) |
EP (1) | EP2769932A4 (es) |
JP (1) | JP2014534128A (es) |
CN (1) | CN104066658A (es) |
CO (1) | CO6660073A1 (es) |
CR (1) | CR20140174A (es) |
DO (1) | DOP2014000080A (es) |
EC (1) | ECSP14001706A (es) |
HK (2) | HK1201503A1 (es) |
MX (1) | MX2014004816A (es) |
WO (1) | WO2013057725A2 (es) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE202012103612U1 (de) * | 2012-09-20 | 2013-01-09 | Markus Scheidt | Archivkarton |
US9936729B2 (en) | 2014-10-16 | 2018-04-10 | R.J. Reynolds Tobacco Company | Package for a tobacco-containing material and related packaging method |
US9968130B2 (en) | 2014-10-16 | 2018-05-15 | R.J. Reynolds Tobacco Company | Package for a tobacco-containing material with a valve assembly and related packaging method |
DE102015220759A1 (de) | 2015-10-23 | 2017-04-27 | Mahle International Gmbh | Wärmeübertrager, insbesondere thermoelektrische Wärmepumpe, zum Temperieren einer Batterie |
CN107600672A (zh) * | 2017-10-13 | 2018-01-19 | 孙斐 | 一种可拆装气调袋的调气窗 |
KR102469140B1 (ko) | 2017-12-27 | 2022-11-22 | 후지필름 가부시키가이샤 | 농산(農産) 용기 |
MX2022013891A (es) * | 2021-03-11 | 2023-04-05 | Varillas Sergio Fernando Grijalva | Empaque para frutas y verduras con barrera antipatogena y proceso de fabricacion. |
TWI787100B (zh) * | 2022-03-16 | 2022-12-11 | 王賢明 | 冷熱透氣蓋 |
Citations (28)
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GB1071586A (en) | 1965-02-23 | 1967-06-07 | United Fruit Co | Controlled atmosphere storage of green bananas |
GB1106265A (en) | 1966-01-10 | 1968-03-13 | United Fruit Co | Storage of produce |
GB1134667A (en) | 1966-01-10 | 1968-11-27 | United Fruit Co | Storage of produce |
US3937396A (en) | 1974-01-18 | 1976-02-10 | Schneider William S | Valve for vented package |
GB2141688A (en) | 1983-05-19 | 1985-01-03 | Brayford Plastics Limited | Bag for fresh produce |
US4842875A (en) | 1986-10-06 | 1989-06-27 | Hercules Incorporated | Controlled atmosphere package |
CN1036539A (zh) | 1988-03-31 | 1989-10-25 | 赫尔克里斯有限公司 | 用玻璃纸和微孔膜制成的可透水分的可控气氛包装容器 |
JPH01279073A (ja) | 1988-04-26 | 1989-11-09 | Fujimori Kogyo Kk | ガス抜き可能な包装体 |
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FR2686577A1 (fr) | 1992-01-24 | 1993-07-30 | Bachmann Sa | Dispositif a membrane de permeabilite selective aux constituants de l'air. |
JPH06199385A (ja) | 1992-10-21 | 1994-07-19 | Sumitomo Bakelite Co Ltd | 青果物保存用袋 |
EP0700839A1 (fr) | 1994-09-07 | 1996-03-13 | Cif (S.A.) | Dispositif pour évacuer l'air contenu dans un sac de conditionnement |
JPH11301743A (ja) | 1998-04-21 | 1999-11-02 | Toppan Printing Co Ltd | 圧力調整弁および圧力調整弁付き包装体 |
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JP2002308293A (ja) | 2002-03-15 | 2002-10-23 | Mitsubishi Chemicals Corp | 青果物入り包装袋 |
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WO2004043191A2 (en) | 2002-11-08 | 2004-05-27 | Cook Leland B | Oneway concealed-valve vented storage bag |
US20040131731A1 (en) | 1998-11-06 | 2004-07-08 | Shepard William H. | Ventilated closure strips for use in packaging food products |
WO2004108557A2 (en) | 2003-05-30 | 2004-12-16 | Avery Dennison Corporation | Food bag release valve |
US20050180664A1 (en) | 2002-09-26 | 2005-08-18 | Ohki Yamada | Farm product protecting bag |
DE202005011737U1 (de) | 2005-07-27 | 2005-10-13 | Chen, Han-Lung, Tai Shan Hsiang | Kunststoffbeutel |
JP2006125559A (ja) | 2004-10-29 | 2006-05-18 | Power System:Kk | ガス抜き弁 |
WO2007008459A2 (en) | 2005-07-08 | 2007-01-18 | Chiquita Brands, Inc. | Device for controlling the gas medium inside a container |
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WO2010141467A1 (en) | 2009-06-01 | 2010-12-09 | Kraft Foods Global Brands Llc | Vented package |
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GB2264922A (en) * | 1992-01-22 | 1993-09-15 | Peter Ervin Kraus | Bag sealing device |
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-
2011
- 2011-10-19 CO CO11140033A patent/CO6660073A1/es unknown
-
2012
- 2012-10-19 EP EP12841504.9A patent/EP2769932A4/en not_active Withdrawn
- 2012-10-19 CN CN201280062726.7A patent/CN104066658A/zh active Pending
- 2012-10-19 US US14/352,728 patent/US20140251858A1/en not_active Abandoned
- 2012-10-19 MX MX2014004816A patent/MX2014004816A/es not_active Application Discontinuation
- 2012-10-19 WO PCT/IB2012/055765 patent/WO2013057725A2/es active Application Filing
- 2012-10-19 JP JP2014536401A patent/JP2014534128A/ja active Pending
-
2014
- 2014-04-21 CR CR20140174A patent/CR20140174A/es unknown
- 2014-04-21 DO DO2014000080A patent/DOP2014000080A/es unknown
- 2014-05-22 EC ECIEPI20141706A patent/ECSP14001706A/es unknown
-
2015
- 2015-02-27 HK HK15102015.0A patent/HK1201503A1/xx unknown
- 2015-03-24 HK HK15103012.1A patent/HK1202507A1/xx unknown
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Also Published As
Publication number | Publication date |
---|---|
US20140251858A1 (en) | 2014-09-11 |
HK1202507A1 (en) | 2015-10-02 |
CR20140174A (es) | 2014-09-09 |
HK1201503A1 (en) | 2015-09-04 |
MX2014004816A (es) | 2014-08-27 |
CO6660073A1 (es) | 2013-04-30 |
JP2014534128A (ja) | 2014-12-18 |
DOP2014000080A (es) | 2014-08-31 |
ECSP14001706A (es) | 2015-11-30 |
CN104066658A (zh) | 2014-09-24 |
EP2769932A4 (en) | 2015-07-01 |
WO2013057725A3 (es) | 2013-06-13 |
EP2769932A2 (en) | 2014-08-27 |
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