WO2012102449A1 - Solar cell and method for manufacturing the same - Google Patents

Solar cell and method for manufacturing the same Download PDF

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Publication number
WO2012102449A1
WO2012102449A1 PCT/KR2011/007394 KR2011007394W WO2012102449A1 WO 2012102449 A1 WO2012102449 A1 WO 2012102449A1 KR 2011007394 W KR2011007394 W KR 2011007394W WO 2012102449 A1 WO2012102449 A1 WO 2012102449A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
solar cell
buffer layer
light absorbing
back electrode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2011/007394
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English (en)
French (fr)
Inventor
Chin Woo Lim
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LG Innotek Co Ltd
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LG Innotek Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LG Innotek Co Ltd filed Critical LG Innotek Co Ltd
Priority to CN201180056408.5A priority Critical patent/CN103222068B/zh
Priority to JP2013550370A priority patent/JP2014503125A/ja
Priority to US13/981,781 priority patent/US9818902B2/en
Priority to EP11856640.5A priority patent/EP2619800B1/en
Publication of WO2012102449A1 publication Critical patent/WO2012102449A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F10/00—Individual photovoltaic cells, e.g. solar cells
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F10/00—Individual photovoltaic cells, e.g. solar cells
    • H10F10/10—Individual photovoltaic cells, e.g. solar cells having potential barriers
    • H10F10/16—Photovoltaic cells having only PN heterojunction potential barriers
    • H10F10/161—Photovoltaic cells having only PN heterojunction potential barriers comprising multiple PN heterojunctions, e.g. tandem cells
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F10/00—Individual photovoltaic cells, e.g. solar cells
    • H10F10/10—Individual photovoltaic cells, e.g. solar cells having potential barriers
    • H10F10/16—Photovoltaic cells having only PN heterojunction potential barriers
    • H10F10/167—Photovoltaic cells having only PN heterojunction potential barriers comprising Group I-III-VI materials, e.g. CdS/CuInSe2 [CIS] heterojunction photovoltaic cells
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F71/00—Manufacture or treatment of devices covered by this subclass
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F77/00—Constructional details of devices covered by this subclass
    • H10F77/10—Semiconductor bodies
    • H10F77/16—Material structures, e.g. crystalline structures, film structures or crystal plane orientations
    • H10F77/169—Thin semiconductor films on metallic or insulating substrates
    • H10F77/1694—Thin semiconductor films on metallic or insulating substrates the films including Group I-III-VI materials, e.g. CIS or CIGS
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/541—CuInSe2 material PV cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Definitions

  • the embodiment relates to a solar cell and a method for manufacturing the same.
  • a CIGS-based solar cell has been extensively used, in which the CIGS-based solar cell is a PN hetero junction device having a substrate structure including a glass substrate, a metallic back electrode layer, a P type CIGS-based light absorbing layer, a high resistance buffer layer, and an N type electrode layer.
  • the embodiment provides a solar cell representing high productivity with improved efficiency.
  • a solar cell includes a substrate, a back electrode layer on the substrate, a light absorbing layer on the back electrode layer, a buffer layer on the light absorbing layer, and a window layer on the buffer layer.
  • the buffer layer is formed through a chemical equation of (A x Zn 1-x )O(0 ⁇ x ⁇ 1), in which the A represents a metallic element.
  • a method for manufacturing a solar cell includes forming a back electrode layer on a substrate, forming a light absorbing layer on the back electrode layer, forming a buffer layer having a chemical formula of (A x Zn 1-x )O(0 ⁇ x ⁇ 1) on the light absorbing layer, in which the A represents a metallic element, and forming a window layer on the buffer layer.
  • the embodiment can provide a solar cell capable of solving the problems related to environmental pollution due to the buffer layer without cadmium.
  • the embodiment can provide a solar cell capable of improving productivity by consecutively performing the manufacturing process because the buffer and window layers are formed through the same PVD process.
  • the embodiment can provide a solar cell capable of increasing short circuit current density by increasing the transmittance due to the buffer layer including zinc, so that the photoelectric conversion efficiency can be improved.
  • FIG. 1 is a sectional view showing a solar cell according to the embodiment.
  • FIGS. 2 to 5 are sectional views showing a method for manufacturing a solar cell panel according to the embodiment.
  • FIG. 1 is a sectional view showing a solar cell according to the embodiment.
  • a solar cell panel includes a support substrate 100, a back electrode layer 200, a light absorbing layer 300, a buffer layer 400, and a window layer 500.
  • the support substrate 100 has a plate shape and supports the back electrode layer 200, the light absorbing layer 300, the buffer layer 400, and the window layer 500.
  • the support substrate 100 may include an insulator.
  • the support substrate 100 may include glass, polymer, or metal.
  • the support substrate 100 may include a soda lime glass substrate.
  • the support substrate 100 includes soda lime glass
  • sodium (Na) contained in the soda lime glass may be diffused into the light absorbing layer 300 including CIGS when manufacturing the solar cell. Accordingly, the concentration of charges of the light absorbing layer 300 may be increased.
  • the photoelectric conversion efficiency of the solar cell may be increased.
  • the support substrate 100 may include a ceramic substrate including alumina, stainless steel, or polymer having flexibility. Therefore, the support substrate 100 may be transparent, rigid, or flexible.
  • the back electrode layer 200 is provided on the support substrate 100.
  • the back electrode layer 200 is a conductive layer.
  • the back electrode layer 200 moves charges generated from the light absorbing layer 300 of the solar cell so that current can flow to the outside of the solar cell.
  • the back electrode layer 200 must represent high electrical conductivity or low resistivity to perform the functions.
  • the back electrode layer 200 makes contact with a CIGS compound constituting the light absorbing layer 300, the back electrode layer 200 must make ohmic contact with the light absorbing layer 300, so that low contact resistance can be made.
  • the back electrode layer 200 must maintain stability under the high-temperature condition when the heat treatment process is performed under sulfur (S) or selenium (Se) atmosphere as the CIGS compound is formed.
  • the back electrode layer 200 must represent a superior adhesive property with respect to the support substrate 100 such that the back electrode layer 200 is not delaminated from the support substrate 100 due to the difference in the thermal expansion coefficient between the back electrode layer 200 and the support substrate 100.
  • the back electrode layer 200 may include one selected from the group consisting of molybdenum (Mo), gold (Au), aluminum (Al), chrome (Cr), tungsten (W), and copper (Cu).
  • Mo represents the low thermal expansion coefficient difference with respect to the support substrate 100 as compared with other elements. Accordingly, the Mo represents a superior adhesive property with respect to the support substrate 100 to prevent the back electrode layer 200 from being delaminated the support substrate 100.
  • the Mo satisfies the characteristics required with respect to the back electrode layer 200.
  • the back electrode layer 200 may include at least two layers.
  • the layers include the same metal, or different metals.
  • the light absorbing layer 300 may be formed on the back electrode layer 200.
  • the light absorbing layer 300 includes a P type semiconductor compound.
  • the light absorbing layer 300 includes group I-III-V compounds.
  • the light absorbing layer 300 may have a Cu-In-Ga-Se-based crystal structure (Cu(In,Ga)Se2;CIGS), a Cu-In-Se-based crystal structure, or a Cu-Ga-Se based crystal structure.
  • the energy band gap of the light absorbing layer 300 may be in the range of about 1.1eV to about 1.2eV.
  • the buffer layer 400 is provided on the light absorbing layer 300.
  • a PN junction is formed between a CIGS compound thin film including a P type semiconductor and the window layer 500 including an N type semiconductor.
  • a buffer layer having the intermediate band gap between the band gaps of the two materials is required in order to form a superior junction.
  • the buffer layer 400 includes CdS or ZnS, and the CdS represents superior generating efficiency of the solar cell.
  • a buffer layer including cadmium (Cd) causes environmental pollution.
  • the buffer layer 400 includes an organic metallic compound including zinc (Zn) instead of the CdS buffer layer.
  • the buffer layer 400 may include (A x Zn 1-x )O(0 ⁇ x ⁇ 1) materials, in which the A represents a group II element.
  • the buffer layer 400 may include MgZnO, the buffer layer 400 may include a compound containing Zn, and an element such as Ca or Sr may be used instead of Mg.
  • the x has a value in the range of about 0.1 to about 0.5.
  • the buffer layer 400 may have energy band gap in the range of about 3.3eV to about 3.6eV, and have a thickness in the range of about 10nm to about 100nm.
  • a zinc diffusion layer 350 may be formed at the contact region between the light absorbing layer 300 and the buffer layer 400.
  • the zinc diffusion layer 350 is formed by the diffusion of Zn, which is contained in the buffer layer 400 when the buffer layer 400 is formed, into the light absorbing layer 300.
  • the zinc diffusion layer 350 may represent as a chemical formula of CIGS:Zn.
  • the zinc diffusion layer 350 may have a thickness of about 10nm to about 100nm. Since the zinc diffusion layer 350 includes an N type semiconductor. Since the buffer layer 400 including the N type semiconductor and the zinc diffusion layer 350 form homo-junction, the recombination of carriers can be reduced at the boundary surface between the light absorbing layer 300 and the buffer layer 400, so that the electrical characteristic of the solar cell can be improved.
  • the energy band gap of the zinc diffusion layer 350 may be in the range of about 2.4eV to about 2.8eV.
  • the window layer 500 is formed on the buffer layer 400.
  • the window layer 500 is a transparent conductive layer.
  • the resistance of the window layer 500 is higher than that of the back electrode layer 200.
  • the window layer 500 includes an oxide.
  • the window layer 500 may include zinc oxide, indium tin oxide (ITO), or indium zinc oxide (IZO).
  • the window layer 500 may include Ga doped zinc oxide (ZnO:Ga).
  • the mass ratio of Ga in the ZnO:Ga may be in the range of about 0.1% to about 3%.
  • the mass ratio having the range is required to form the window layer 500 having energy band gap higher than that of the buffer layer 400, and the energy band gap of the window layer 500 may be in the range of about 3.6eV to about 3.8eV.
  • the oxide may include conductive impurities such as aluminum (Al), alumina (Al 2 O 3 ), magnesium (Mg), or gallium (Ga).
  • the window layer 500 may include Al doped zinc oxide (AZO) or Ga doped zinc oxide (GZO).
  • the buffer layer 400 without Cd is formed, so that the problems related to the environmental pollution can be solved.
  • the buffer layer 400 includes Zn transmittance can be increased, so that short circuit current density J sc can be increased.
  • the buffer layer 400 and the window layer 500 are formed through the same PVD (Physical Vapor Deposition) process, the manufacturing process can be consecutively performed, so that productivity can be improved.
  • PVD Physical Vapor Deposition
  • FIGS. 2 to 5 are sectional views showing the method for manufacturing the solar cell according to the embodiment.
  • the description about the method for manufacturing the solar cell will be made based on the above description about the solar cell.
  • the description about the solar cell may be basically linked with the description about the method for manufacturing the solar cell.
  • the back electrode layer 200 may be deposited by using Mo.
  • the back electrode layer 200 may be formed through the PVD scheme or a plating scheme.
  • an additional layer such as an anti-diffusion layer may be interposed between the support substrate 100 and the back electrode layer 200.
  • the light absorbing layer 300 is formed on the back electrode layer 200.
  • the light absorbing layer 300 may be formed through various schemes such as a scheme of forming a Cu(In,Ga)Se2 (CIGS) based-light absorbing layer 300 by simultaneously or separately evaporating Cu, In, Ga, and Se and a scheme of performing a selenization process after a metallic precursor film has been formed.
  • CIGS Cu(In,Ga)Se2
  • the metallic precursor layer is formed on the back contact electrode 200 through a sputtering process employing a Cu target, an In target, or a Ga target.
  • the metallic precursor layer is subject to the selenization process so that the Cu(In,Ga)Se2 (CIGS) based-light absorbing layer 300 is formed.
  • the sputtering process employing the Cu target, the In target, and the Ga target and the selenization process may be simultaneously performed.
  • a CIS or a CIG light absorbing layer 300 may be formed through a sputtering process employing only Cu and In targets or only Cu and Ga targets and the selenization process.
  • the buffer layer 400 is formed on the light absorbing layer 300.
  • the buffer layer 400 may include Zn.
  • the buffer layer 400 includes MgZnO, which is an organic metallic compound including Mg or O according to the present embodiment, the buffer layer 400 may include a group II element such as Ca or Sr other than Mg.
  • the buffer layer 400 may be formed through the PVD scheme, and may have a thickness of about 10nm to about 100nm.
  • the zinc diffusion layer 350 may be formed by the diffusion of Zn, which is contained in the buffer layer 400, into the light absorbing layer 300.
  • the zinc diffusion layer 350 may have an intermediate band gap between band gaps of the light absorbing layer 300 and the buffer layer 400.
  • the zinc diffusion layer 350 may have a band gap in the range of about 2.2eV to about 2.8eV.
  • the window layer 500 is formed on the buffer layer 400.
  • the window layer 500 is formed by depositing a transparent conductive material on the buffer layer 400.
  • the embodiment can provide a solar cell capable of solving problems related to environmental pollution by employing a buffer layer without cadmium.
  • the embodiment can provide a solar cell capable of improving productivity by consecutively performing the manufacturing process because the buffer and window layers are formed through the same vacuum process.
  • the embodiment can provide a solar cell capable of increasing short circuit current density by increasing the transmittance due to the buffer layer including Zn, so that the photoelectric conversion efficiency can be improved.
  • any reference in this specification to 'one embodiment', 'an embodiment', 'example embodiment', etc. means that a particular feature, structure, or characteristic described in connection with the embodiment is included in at least one embodiment of the invention.
  • the appearances of such phrases in various places in the specification are not necessarily all referring to the same embodiment.

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  • Photovoltaic Devices (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
PCT/KR2011/007394 2011-01-25 2011-10-06 Solar cell and method for manufacturing the same Ceased WO2012102449A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN201180056408.5A CN103222068B (zh) 2011-01-25 2011-10-06 太阳能电池及其制造方法
JP2013550370A JP2014503125A (ja) 2011-01-25 2011-10-06 太陽電池及びその製造方法
US13/981,781 US9818902B2 (en) 2011-01-25 2011-10-06 Solar cell and method for manufacturing the same
EP11856640.5A EP2619800B1 (en) 2011-01-25 2011-10-06 Solar cell

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020110007516A KR101219835B1 (ko) 2011-01-25 2011-01-25 태양전지 및 이의 제조방법
KR10-2011-0007516 2011-01-25

Publications (1)

Publication Number Publication Date
WO2012102449A1 true WO2012102449A1 (en) 2012-08-02

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PCT/KR2011/007394 Ceased WO2012102449A1 (en) 2011-01-25 2011-10-06 Solar cell and method for manufacturing the same

Country Status (6)

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US (1) US9818902B2 (enExample)
EP (1) EP2619800B1 (enExample)
JP (1) JP2014503125A (enExample)
KR (1) KR101219835B1 (enExample)
CN (1) CN103222068B (enExample)
WO (1) WO2012102449A1 (enExample)

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EP3419057A4 (en) * 2016-02-18 2019-12-11 Jun, Young-kwon SOLAR CELL AND METHOD FOR THE PRODUCTION THEREOF

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CN106531827A (zh) * 2015-09-15 2017-03-22 株式会社东芝 光电转换元件、太阳能电池、太阳能电池模块及太阳光发电系统
CN105514198B (zh) * 2015-12-29 2017-03-08 中国科学院深圳先进技术研究院 薄膜太阳能电池及其缓冲层的制备方法
CN106449875A (zh) * 2016-10-10 2017-02-22 北京四方创能光电科技有限公司 一种利用MgZnO薄膜制作CIGS薄膜太阳能电池的方法
CN108321216A (zh) * 2018-01-30 2018-07-24 北京铂阳顶荣光伏科技有限公司 一种可调光学带隙的氧锌镁材料、制备方法及太阳能电池

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3419057A4 (en) * 2016-02-18 2019-12-11 Jun, Young-kwon SOLAR CELL AND METHOD FOR THE PRODUCTION THEREOF

Also Published As

Publication number Publication date
EP2619800B1 (en) 2019-12-04
US20130327383A1 (en) 2013-12-12
CN103222068B (zh) 2016-08-17
CN103222068A (zh) 2013-07-24
US9818902B2 (en) 2017-11-14
EP2619800A4 (en) 2018-01-17
KR20120086205A (ko) 2012-08-02
JP2014503125A (ja) 2014-02-06
KR101219835B1 (ko) 2013-01-21
EP2619800A1 (en) 2013-07-31

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