WO2012098765A1 - Produit cosmétique de maquillage - Google Patents

Produit cosmétique de maquillage Download PDF

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Publication number
WO2012098765A1
WO2012098765A1 PCT/JP2011/077030 JP2011077030W WO2012098765A1 WO 2012098765 A1 WO2012098765 A1 WO 2012098765A1 JP 2011077030 W JP2011077030 W JP 2011077030W WO 2012098765 A1 WO2012098765 A1 WO 2012098765A1
Authority
WO
WIPO (PCT)
Prior art keywords
titanium oxide
treated
fine particle
makeup
color
Prior art date
Application number
PCT/JP2011/077030
Other languages
English (en)
Japanese (ja)
Inventor
しほ花 大橋
克彦 八木
祥二 田島
Original Assignee
株式会社 資生堂
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 株式会社 資生堂 filed Critical 株式会社 資生堂
Publication of WO2012098765A1 publication Critical patent/WO2012098765A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0241—Containing particulates characterized by their shape and/or structure
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/29—Titanium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
    • A61Q1/06—Lipsticks
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/60—Particulates further characterized by their structure or composition
    • A61K2800/61—Surface treated
    • A61K2800/62—Coated
    • A61K2800/622—Coated by organic compounds

Definitions

  • the present invention relates to a makeup cosmetic containing a hydrophobized color material and metal soap-treated fine particle titanium oxide. More specifically, the present invention relates to a makeup cosmetic that is wet-molded and has excellent color development and long lasting makeup.
  • Makeup cosmetics are made by dispersing pigments (organic, inorganic, pearl pigments, etc.) in various bases, and products in various forms are on the market.
  • point makeup cosmetics such as eye shadows, lipsticks, and blushers are cosmetics that impart aesthetic effects by applying color to the skin, and their color development is one of the important characteristics.
  • the properties of the powder components that are often incorporated in these makeup cosmetics affect not only the color development of the cosmetics but also the usability such as familiarity with the skin and smoothness.
  • various contrivances have been made.
  • Patent Document 1 describes a colored composite powder in which metal colloidal fine particles are encapsulated in a metal oxide and a cosmetic containing the same.
  • the colored composite powder particularly vividly develops a blue or green color and exhibits a beautiful color. It is said that the cosmetics which have are obtained.
  • Patent Document 2 describes a stick makeup cosmetic containing a specific spherical resin powder, a polar oil, a solid oil, and preferably a fluorescent dye at a predetermined ratio, and a vivid and dull color is obtained. It is supposed to be done.
  • Patent Document 3 when a cationic surfactant-treated powder obtained by treating a specific powder with a cationic surfactant, and a hydrophobic treatment color material surface-treated with a silicone compound or a fluorine compound, it is described that a powder cosmetic that is excellent in usability such as familiarity with the skin and smoothness and has little color dullness over time can be obtained.
  • the color of the cosmetic itself is often different from the color when applied to the skin, and the beautiful color obtained when applied to the skin changes over time. There was also a problem.
  • an object of the present invention is to provide a makeup cosmetic that has a good color development and is applied with an as-looked color and that has a good color residue over time and has a long makeup.
  • the present invention provides a makeup cosmetic produced by wet molding, comprising (A) a hydrophobized colorant and (B) metal soap-treated fine particle titanium oxide.
  • the makeup cosmetic of the present invention is excellent in color development, can reproduce the color as it is seen on the skin, and is excellent in makeup, and maintains the color when applied for a long time without discoloration over time. The effect that it is done.
  • the makeup cosmetic of the present invention is excellent in removal from the container and fit to the skin.
  • the makeup cosmetic of the present invention contains a hydrophobized color material (component A).
  • the hydrophobized color material in the present invention means a color material whose surface has been hydrophobized.
  • the surface treatment agent for hydrophobizing the surface is not particularly limited, but it is preferable to use a silicone compound or a fluorine compound. Examples of the silicone compound include dimethicone, methicone, silane coupling agent, alkyl-modified silicone, and silicone resin.
  • fluorine compound examples include a fluorine-modified alkyl compound and a fluorine-modified silicone compound, and examples thereof include perfluoroalkyl phosphate esters and salts thereof, perfluoroalkylsilane, Teflon (registered trademark), and perfluoroalkylcarboxylic acid.
  • fluorine compound examples include a fluorine-modified alkyl compound and a fluorine-modified silicone compound, and examples thereof include perfluoroalkyl phosphate esters and salts thereof, perfluoroalkylsilane, Teflon (registered trademark), and perfluoroalkylcarboxylic acid.
  • Coloring materials to be hydrophobized include white pigments such as titanium oxide, zinc oxide, and cerium oxide, and colored pigments such as yellow iron oxide, red iron oxide, black iron oxide, chromium oxide, carbon black, ultramarine, and bitumen Is mentioned.
  • the blending amount of the hydrophobic treatment color material in the makeup cosmetic of the present invention is usually 0.01 to 40% by mass, preferably 0.05 to 35% by mass. If the blending amount is less than 0.01% by weight, coloration as a coloring material may not be observed. If the blending amount exceeds 40% by weight, the product can be removed with a chip or the like and used for elongation to the skin. Tend to get worse.
  • the makeup cosmetic of the present invention further contains metal soap-treated fine particle titanium oxide (component B).
  • component B metal soap-treated fine particle titanium oxide
  • the metal soap-treated fine particle titanium oxide in the present invention is obtained by treating the surface of fine particle titanium oxide with a metal soap.
  • the fine particle titanium oxide constituting the metal soap-treated fine particle titanium oxide of the present invention is not particularly limited as long as it is called fine particle titanium oxide.
  • fine particle titanium oxide having an average primary particle size of 0.1 ⁇ m or less is used.
  • the lower limit of the average particle diameter of the fine particle titanium oxide is not particularly limited, but is usually about 30 nm.
  • the fine particle titanium oxide can be produced, for example, by a conventional method such as a sulfuric acid method or a chlorine method, and a commercially available product can also be used.
  • Examples of commercially available fine particle titanium oxide include SIV series, TTO-55 series, TTO-S series (above, manufactured by Ishihara Sangyo Co., Ltd.), MT-100TV, MT-500V, MT-01 (above, manufactured by Teika), etc. Is mentioned.
  • fine particle titanium oxide whose surface is treated with a metal soap is used as an essential component.
  • the metal soap used for the surface treatment is a polyvalent metal salt of a fatty acid, and in particular, a fatty acid having 12 to 18 carbon atoms is preferable, and examples of such salts include calcium, magnesium, zinc, aluminum and the like.
  • aluminum salts are preferred.
  • Preferable specific examples include aluminum stearate, aluminum distearate, aluminum oleate, aluminum palmitate, aluminum laurate, aluminum myristate, and aluminum dimylate.
  • the method of treating the surface of the fine particle titanium oxide with a metal soap is not particularly limited.
  • the metal soap is dissolved in a volatile solvent such as isoparaffin or isopropyl alcohol, mixed with the fine particle titanium oxide, and then the volatile solvent is volatilized. Can be prepared. Further, it is also possible to simply mix fine particle titanium oxide and metal soap.
  • the compounding amount of the metal soap-treated fine particle titanium oxide in the makeup cosmetic of the present invention is usually 0.1 to 5% by mass, preferably 0.2 to 3% by mass. If the blending amount is less than 0.1% by mass, the effect of improving the color development tends to be lost. If the blending amount exceeds 5% by mass, a tingling sensation caused by fine particles is observed when applied to the skin. Tend to get worse.
  • the makeup cosmetic of the present invention is characterized by being manufactured by wet molding.
  • Wet molding means adding a solvent to a cosmetic base containing a powder component containing the hydrophobic treatment color material (component A) and metal soap-treated fine particle titanium oxide (component B) and an oil component containing oil and the like. Then, after the slurry is filled in the container, the solvent is removed (see, for example, Japanese Patent Publication Nos. 57-60004 and 61-54766).
  • volatile solvent used for wet molding examples include cyclic silicone, volatile linear silicone, light liquid isoparaffin, methylene chloride, fluorocarbon, hexane, cyclohexane, ether, toluene, xylene, acetone, benzene, terpenes, water 1,3 butanediol, ethanol, methanol, propanol, isopropanol, butanol, and the like, and can be appropriately selected depending on the type of compounding component.
  • wet disperser used for wet molding examples include, for example, a medium agitating mill using a medium such as zirconia beads, glass beads, and stainless beads from a normal wet disperser such as a disper mixer or a homogenizer. It is not limited.
  • the makeup cosmetic of the present invention may contain other optional components conventionally used in makeup cosmetics in addition to the essential components A and B as long as the effects of the present invention are not impaired.
  • specific examples include powder components (excluding metal soap-treated fine particle titanium oxide and hydrophobized color material), oil, wax, humectant, surfactant, thickener, dye, and preservative.
  • Powder components other than the essential component A (hydrophobized color material) and component B (metal soap-treated fine particle titanium oxide) include extender pigments, colorants, pearl agents, lame agents, and the like. It may be used.
  • extender pigments include, for example, pulverized products of viscous minerals such as mica, sericite, talc, and kaolin, silicic anhydride, cerium oxide, silica, zinc stearate, fluorinated phlogopite, synthetic talc, barium sulfate, boron nitride, Examples thereof include bismuth oxychloride, alumina, and magnesium carbonate.
  • the colorant (color pigment) include bengara, yellow iron oxide, black iron oxide, ultramarine blue, titanium oxide, zinc oxide, and salmon.
  • titanium dioxide-coated mica titanium dioxide-coated mica
  • iron oxide-coated mica titanium carmine-coated mica titanium, carmine / conjugate-coated mica titanium, iron oxide / carmine-treated mica titanium, conger-treated mica titanium, iron oxide / conjugate treatment
  • Mica titanium, chromium oxide treated mica titanium, black titanium oxide coated mica titanium, acrylic resin coated aluminum powder, titanium oxide coated mica, titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored titanium oxide coated mica, titanium oxide coated synthetic mica
  • Typical examples include titanium oxide-coated silica, titanium oxide-coated alumina, titanium oxide-coated glass powder, polyethylene terephthalate / potimethyl methacrylate laminated film powder, bismuth oxychloride, fish scale foil, and the like.
  • oils such as squalane, liquid paraffin and petrolatum, higher fatty acids such as myristic acid, palmitic acid, stearic acid, 12-hydroxystearic acid and behenic acid, cetyl alcohol, stearyl alcohol, oleyl alcohol, batyl alcohol Higher alcohols such as cetyl-2-ethylhexanoate, 2-ethylhexyl palmitate, 2-octyldodecyl myristate, neopentyl glycol-2-ethylhexanoate, glyceryl trioctanoate, pentaerythritol tetraoctanoate, triisostearic acid Ester oil such as glyceryl, glyceryl diisostearate, isopropyl myristate, myristyl myristate, glyceryl trioleate, olive oil
  • wax examples include carnauba wax, candelilla wax, bees wax, mole, ceresin wax, microcrystalline wax, and solid paraffin wax.
  • humectant examples include polyhydric alcohol humectants such as glycerin, propylene glycol, and 1,3 butylene glycol.
  • the makeup cosmetic of the present invention is particularly excellent in color developability and good color durability. Therefore, the cosmetic of the present invention is suitable for use as an eye shadow in point makeup cosmetics such as eye shadow, blusher and lipstick.
  • Example 1 A sample (eye shadow) having the composition listed in Table 1 below was prepared by a wet molding method. Ethanol was used as a volatile solvent in wet molding. Each of the obtained samples was evaluated according to the following evaluation methods and standards for good removal from the container, good color development when applied, and fit to the skin. The results are also shown in Table 1.
  • Evaluation methods Each sample was used by a panelist (10 persons) and subjected to sensory evaluation (score) in five stages. Based on the average score, the following evaluation criteria were used. (Score) 5: Very good 4: Excellent 3: Normal 2: Inferior 1: Very inferior (Evaluation criteria) ⁇ : Evaluation value (average value) 4.0 or more and 5.0 points or less ⁇ : Evaluation value (average value) 3.0 or more and less than 4.0 points ⁇ : Evaluation value (average value) 2.0 or more and 3.0 points Less than x: Evaluation value (average value) 1.0 or more and less than 2.0 points
  • Example 1 in which metal soap-treated fine particle titanium oxide was blended was superior to Comparative Examples 1 to 7 in which other powder components were blended, and was excellent in all items of color development and fit.
  • Formulation Example 1 (Eye Shadow): Compounding ingredients Compounding amount (% by mass) Vaseline 2 Dimethylpolysiloxane 2 Methylphenyl polysiloxane 2 Glycerin 0.1 Trioctanoin 1 Plant-based squalane 0.5 Sorbitan sesquiisostearate 1 Boron nitride 2 Mica titanium 4 Phlogopite 4 Synthetic phlogopite 0.1 Sericite 25 Talc Residual Mica 7 Zinc myristate 1 Aluminum stearate 0.01 Silicic anhydride 4 Phytosterol 0.01 DL- ⁇ -tocopherol acetate 0.02 D- ⁇ -Tocopherol 0.02 Acetylated sodium hyaluronate 0.02 P-Hydroxybenzoate ester 0.2 Alkylsilane-treated iron oxide 9 Aluminum stearate treated fine particle titanium oxide 3 Synthetic sodium silicate / magnesium 0.1 Perfume proper amount diisostearyl mal
  • Formulation Example 2 Compounding ingredients Compounding amount (% by mass) Liquid paraffin 3 Dimethylpolysiloxane 3 Mica 20 Talc Residual aluminum stearate treated fine particles Titanium oxide 2 ⁇ -tocopherol appropriate amount paraoxybenzoate 0.2 Cobalt titanate 4 Silicone-treated iron oxide 4 Aluminum magnesium silicate 1.5 Fragrance Appropriate Sericite 20 Sorbitan sesquiisostearate 2 Zinc myristate 5
  • Formulation example 3 (blusher): Compounding ingredients Compounding amount (% by mass) Bengala coated mica titanium 30 Talc Residual Mica 15 ⁇ -tocopherol 0.02 Paraoxybenzoic acid ester Appropriate amount of dye Appropriate amount of alkyl-modified silicone-treated iron oxide Aluminum stearate treated fine particle titanium oxide 0.5 Aluminum magnesium silicate 3 Perfume proper amount cross-linked silicone powder 5 Polyalkyl acrylate 10 Metal soap treated talc 15: Compounding ingredients Compounding amount (% by mass) Bengala coated mica titanium 30 Talc Residual Mica 15 ⁇ -tocopherol 0.02 Paraoxybenzoic acid ester Appropriate amount of dye Appropriate amount of alkyl-modified silicone-treated iron oxide Aluminum stearate treated fine particle titanium oxide 0.5 Aluminum magnesium silicate 3 Perfume proper amount cross-linked silicone powder 5 Polyalkyl acrylate 10 Metal soap treated talc 15

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne un produit cosmétique de maquillage avec lequel la coloration est bonne, la couleur qui est vue en premier lorsqu'il est appliqué est bien conservée au cours du temps et la durabilité du maquillage est bonne. Le produit cosmétique de maquillage est obtenu par mélange (A) d'une matière colorante d'hydrophobisation et (B) de microparticules d'oxyde de titane traitées par un savon métallique. La matière colorante d'hydrophobisation est, de préférence, une matière colorante qui a été traitée par un composé de silicone ou un composé du fluor et les microparticules d'oxyde de titane traitées par un savon métallique sont, de préférence, des microparticules d'oxyde de titane qui ont été traitées par un sel de calcium, de magnésium, de zinc ou d'aluminium et d'un acide gras en C12-18.
PCT/JP2011/077030 2011-01-19 2011-11-24 Produit cosmétique de maquillage WO2012098765A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2011-008569 2011-01-19
JP2011008569A JP2012149005A (ja) 2011-01-19 2011-01-19 メーキャップ化粧料

Publications (1)

Publication Number Publication Date
WO2012098765A1 true WO2012098765A1 (fr) 2012-07-26

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PCT/JP2011/077030 WO2012098765A1 (fr) 2011-01-19 2011-11-24 Produit cosmétique de maquillage

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JP (1) JP2012149005A (fr)
TW (1) TW201231071A (fr)
WO (1) WO2012098765A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115052576A (zh) * 2020-02-28 2022-09-13 株式会社资生堂 脂肪酸钙盐颗粒和化妆品

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2022071143A1 (fr) * 2020-09-30 2022-04-07

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56108703A (en) * 1980-01-29 1981-08-28 Shiseido Co Ltd Production of caked powder cosmetic in vessel
JP2001278743A (ja) * 2000-03-29 2001-10-10 Shiseido Co Ltd 化粧料
JP2002060329A (ja) * 2000-08-16 2002-02-26 Shiseido Co Ltd 日焼け止め化粧料
JP2003012461A (ja) * 2001-07-05 2003-01-15 Shiseido Co Ltd メーキャップ化粧料
JP2006199616A (ja) * 2005-01-20 2006-08-03 Shiseido Co Ltd 粉末化粧料の成型方法及び装置及び製品
JP2008184399A (ja) * 2007-01-29 2008-08-14 Shiseido Co Ltd 粉末化粧料
WO2009078486A1 (fr) * 2007-12-19 2009-06-25 Shiseido Company Ltd. Procédé de fabrication d'une préparation cosmétique pulvérulente
JP2009209139A (ja) * 2008-02-07 2009-09-17 Shiseido Co Ltd 固形粉末化粧料
WO2010119954A1 (fr) * 2009-04-16 2010-10-21 株式会社 資生堂 Cosmétique solide pulvérulent et procédés de fabrication pour celui-ci

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Publication number Priority date Publication date Assignee Title
JP5559990B2 (ja) * 2009-06-05 2014-07-23 花王株式会社 固形粉末化粧料の製造方法

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56108703A (en) * 1980-01-29 1981-08-28 Shiseido Co Ltd Production of caked powder cosmetic in vessel
JP2001278743A (ja) * 2000-03-29 2001-10-10 Shiseido Co Ltd 化粧料
JP2002060329A (ja) * 2000-08-16 2002-02-26 Shiseido Co Ltd 日焼け止め化粧料
JP2003012461A (ja) * 2001-07-05 2003-01-15 Shiseido Co Ltd メーキャップ化粧料
JP2006199616A (ja) * 2005-01-20 2006-08-03 Shiseido Co Ltd 粉末化粧料の成型方法及び装置及び製品
JP2008184399A (ja) * 2007-01-29 2008-08-14 Shiseido Co Ltd 粉末化粧料
WO2009078486A1 (fr) * 2007-12-19 2009-06-25 Shiseido Company Ltd. Procédé de fabrication d'une préparation cosmétique pulvérulente
JP2009209139A (ja) * 2008-02-07 2009-09-17 Shiseido Co Ltd 固形粉末化粧料
WO2010119954A1 (fr) * 2009-04-16 2010-10-21 株式会社 資生堂 Cosmétique solide pulvérulent et procédés de fabrication pour celui-ci

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Title
ATSUSHI MATSUSHITA: "Development of powder foundation by wet filling method", FRAGRANCE JOURNAL, vol. 34, no. 6, 15 June 2006 (2006-06-15), pages 34 - 39 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115052576A (zh) * 2020-02-28 2022-09-13 株式会社资生堂 脂肪酸钙盐颗粒和化妆品

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JP2012149005A (ja) 2012-08-09
TW201231071A (en) 2012-08-01

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