201231071 六、發明說明： 【發明所屬之技術領域】 本發明係關於一種調配有疏水化處理有色材料及金屬皂 處理微粒子氧化鈦之彩链用化粧品。更詳細而·τ，本發明 係關於一種濕式成型所得，且顯色性及化粧持久性優異之 彩粧用化粧品。 【先前技術】 彩粧用化粧品係將顏料（有機、無機、珠光顏料等）分散 於各種基劑中而成者，市售有各種形態之產品。尤其是眼 影口紅、胭脂等重點部位彩粧用化粧品係藉由塗佈於肌 膚上而賦予色彩，獲得美感效果之化粧品，其顯色性為重 要之特性之一。 大量調配於該等彩粧用化牲品中的粉末成分之性質不僅 對該化粧品之顯色性，亦對親膚性、光滑度等使用性產生 影響’必需根據用途而選擇調配適當之粉末成分，為獲得 藉由表面處理等而具有所期望之性質的粉末，業界進行了 各種努力。 例如於專利文獻i中，記載有將金屬膠體微粒子内包 •:金屬*氧化物内而成之著色複合粉末及調配有其之化粧 . 11玄著色複合粉末尤其可鮮豔地顯現出藍色或綠色，認 為其可獲得具有美麗色彩之化粧品。 於專利文獻2中’記載有將特定之球狀樹脂粉末、 極性油分、、固體油分、及較佳為發出勞光之染料以特定比 率調而成之棒狀彩粧用化粧品，認為其可獲得鮮豔、不 160525.doc 201231071 暗淡之顯色。 另一方面，於專利文獻3中，記載有當調配有對特定之 粉體以陽離子性界面活性劑進行處理而得之陽離子性界面 活性劑處理粉體、與經利用聚⑪氧化合物或a化合物進行 表面處理之疏水化處理有色材料時，可獲得親膚性、光滑 度等使用性優異，且經時之顏色暗淡較少的粉末化粧品。 然而，通常之彩粧用化粧品於較多情形時化粧品本身之 色彩與塗佈於肌膚上時之色彩不同，並且亦存在塗佈於肌 膚上時所獲得之美麗色彩經時而發生變化的問題。 [先前技術文獻] [專利文獻] [專利文獻1]日本專利特開2008-24677號公報 [專利文獻2]曰本專利特開2008-247844號公報 [專利文獻1]曰本專利特開2006-199645號公報 【發明内容】 [發明所欲解決之問題] 因此，本發明之課題在於提供一種顯色良好、可塗佈所 呈現之顏色並且經時之顏色存留良好、化粧持久性優異之 彩粧用化粧品。_ [解決問題之技術手段] 為解決該課題，本發明者等反覆進行努力研究，結果發 現：藉由於以濕式成型所製造之彩粧用化粧品中，調配 (A)疏水化處理有色材料及（B)金屬皂處理微粒子氧化鈦， 可獲得顯色優異、經時之顏色存留亦良好之化粧品，從而 160525.doc201231071 VI. Description of the Invention: [Technical Field of the Invention] The present invention relates to a cosmetic for color chain which is prepared by disposing a hydrophobicized colored material and a metal soap to treat fine titanium oxide. More specifically, the present invention relates to a cosmetic for makeup which is obtained by wet molding and which is excellent in color developability and long-lasting makeup. [Prior Art] Cosmetics for cosmetics make it possible to disperse pigments (organic, inorganic, pearlescent pigments, etc.) in various bases, and various types of products are commercially available. In particular, cosmetic products such as eye shadow lipstick and rouge are one of the important characteristics of cosmetics that are applied to the skin to impart color and obtain an aesthetic effect. The nature of the powder component blended in these cosmetic products not only affects the color developability of the cosmetic, but also affects the usability of skin-friendliness, smoothness, etc. It is necessary to select an appropriate powder component depending on the use. In order to obtain a powder having desired properties by surface treatment or the like, various efforts have been made in the industry. For example, in Patent Document i, a colored composite powder in which metal colloidal particles are contained in a metal oxide is prepared and a makeup is prepared. The black colored composite powder is particularly brightly colored in blue or green. It is believed that it can obtain cosmetics with beautiful colors. Patent Document 2 describes a cosmetic product for a stick-shaped makeup which is obtained by adjusting a specific spherical resin powder, a polar oil component, a solid oil component, and a dye which is preferably a work-lighting dye at a specific ratio, and is considered to be available. Vivid, not 160525.doc 201231071 Dim color. On the other hand, Patent Document 3 describes a cationic surfactant-treated powder obtained by treating a specific powder with a cationic surfactant, and a compound using a polyoxyl compound or a compound. When the surface-treated hydrophobic treatment of the colored material is carried out, it is possible to obtain a powder cosmetic which is excellent in usability such as skin-friendliness and smoothness, and which has a dull color over time. However, in general, cosmetics for cosmetic use have a different color when applied to the skin in many cases, and there is also a problem that the beautiful color obtained when applied to the skin changes over time. [Prior Art Document] [Patent Document 1] Japanese Patent Laid-Open Publication No. 2008-24677 [Patent Document 2] Japanese Patent Laid-Open Publication No. 2008-247844 (Patent Document 1) SUMMARY OF THE INVENTION [Problems to be Solved by the Invention] Therefore, an object of the present invention is to provide a makeup which is excellent in color development, can be applied to a color which is exhibited, and has good color retention over time and excellent makeup durability. Use cosmetics. _ [Technical means for solving the problem] In order to solve this problem, the inventors of the present invention have conducted intensive studies and found that (A) the hydrophobized colored material and the (A) hydrophobized coloring material are prepared by the cosmetics for makeup made by wet molding. (B) Metal soap treatment of fine particle titanium oxide, which can obtain a cosmetic which is excellent in color development and has good color retention over time, thus 160525.doc
S 201231071 完成本發明。 亦即，本發明係提供一種調配（A)疏水化處理有色材 料、及（B)金屬皂處理微粒子氧化鈦，藉由濕式成型而製 造的彩粧用化粧品。 [發明之效果] 本發明之彩粧用化粧品可發揮如下效果：顯色優異，可 於肌膚上再現所呈現之顏色，並且化粧持久性優異，塗佈 時之顏色可歷經長時間而維持而無經時之變色。又，本發 明之彩粧用化粧品的自容器之蘸取性及對肌膚之伏貼感亦 優異。 【實施方式】 本發明之彩粧用化粧品含有疏水化處理有色材料（成分 A)。本發明中之所謂疏水化處理有色材料，意指表面經疏 水化處理之有色材料。 作為使表面疏水化之表面處理劑，並無特別限定，較佳 為使用聚矽氧化合物或氟化合物。 作為聚矽氧化合物，可列舉：二甲基聚矽氧烷 (dimethicone)、甲基聚石夕氧烧（methic〇ne)、石夕院偶合劑、 烷基改質聚矽氧、聚矽氧樹脂等。 作為氟化合物，可列舉氟改質烷基化合物及氟改質聚矽 氧化合物，例如包括：全氟烷基磷酸酯及其鹽、全氟烷基 矽烷、鐵氟龍（註冊商標）、全氟烷基羧酸等。另外，亦可 將丙烯酸焼基醋或（丙烯酸炫基醋/二f基聚石夕氧炫）共聚物 等與氟化合物一起使用而進行疏水化處理。 J60525.doc 201231071 作為進行疏水化處理之有色材料’可列舉：氧化鈦、氧 化鋅、氧化鈽等白色顏料，或氧化鐵黃、氧化鐵紅、氧化 鐵黑、氧化鉻、碳黑、群青、鐵藍等有色顏料。 本發明之彩粧用化粧品中的疏水化處理有色材料之調配 量通常為0.01〜40質量。/〇，較佳為〇.〇5〜35質量。/〇。若調配量 未達0.01質量％，則有時確認不到作為有色材料之顯色， 若調配超過40質量％，則有利用上粧棒（tip)等之產品之蘸 取性或於肌膚上之延伸性等使用性變差之傾向。 本發明之彩粧用化粧品進而含有金屬皂處理微粒子氧化 鈦（成分B) »本發明中之金屬皂處理微粒子氧化鈦係對微 粒子氧化鈦之表面以金屬皂加以處理而得者。 構成本發明之金屬矣處理微粒子氧化欽的微粒子氧化欽 只要為稱為微粒子氧化鈦者則無特別限定，一般而言，較 佳為使用平均一次粒徑為〇1 μπι以下之微粒子氧化鈦。微 粒子氧化鈦之平均粒徑之下限無特別限定，通常為3〇 nm 左右。微粒子氧化鈦例如可藉由硫酸法或氣法等常法進行 製U亦可使用市售品。作為市售之微粒子氧化鈦，例如 可列舉：SIV系列、ττο·55系列、TT〇s系列（以上係由石 原產業公司製造），MT_100TV、MT 500V、MT 01(以上係 由Tayca公司製造）等β 於本發明中，表面經金屬皂處理之微粒子氧化鈦係作為 必需成7?而使用。表面處理中所使用金屬皂為脂肪酸之多 仏金屬鹽’尤佳為脂肪酸之碳數為12〜18的多價金屬鹽， 又，作為該等鹽，例如可列舉鈣鹽、鎂鹽、鋅鹽、鋁鹽 160525.docS 201231071 The present invention has been completed. That is, the present invention provides a cosmetic for makeup which is prepared by wet molding by blending (A) a hydrophobized colored material and (B) a metal soap-treated fine titanium oxide. [Effects of the Invention] The cosmetic for makeup of the present invention exhibits an effect of excellent color development, reproducible color on the skin, and excellent cosmetic durability, and the color during coating can be maintained over a long period of time without Discoloration over time. Further, the cosmetics for makeup of the present invention are excellent in self-containedness and smear to the skin. [Embodiment] The cosmetic for makeup of the present invention contains a hydrophobized colored material (ingredient A). The term "hydrophobic treatment of colored material" in the present invention means a colored material whose surface is hydrophobized. The surface treatment agent for hydrophobizing the surface is not particularly limited, and a polyfluorene oxide compound or a fluorine compound is preferably used. Examples of the polyoxymethylene compound include dimethicone, methylmethoxime, shixiyuan coupling agent, alkyl modified polyoxo, polyoxane. Resin, etc. Examples of the fluorine compound include a fluorine-modified alkyl compound and a fluorine-modified polyoxyl compound, and include, for example, a perfluoroalkyl phosphate and a salt thereof, a perfluoroalkyl decane, a Teflon (registered trademark), and a perfluoro group. Alkyl carboxylic acid and the like. Further, a hydroquinone treatment may be carried out by using a fluorenyl ruthenium acrylate or a (acrylic acid vinegar/dif-based polyfluorene) copolymer or the like together with a fluorine compound. J60525.doc 201231071 As a colored material for hydrophobization, a white pigment such as titanium oxide, zinc oxide or cerium oxide, or iron oxide yellow, iron oxide red, iron oxide black, chromium oxide, carbon black, ultramarine blue or iron may be mentioned. Colored pigments such as blue. The amount of the hydrophobized colored material in the cosmetic for makeup of the present invention is usually 0.01 to 40% by mass. /〇, preferably 〇.〇5~35 mass. /〇. When the blending amount is less than 0.01% by mass, color development as a colored material may not be confirmed, and if it is blended in an amount of more than 40% by mass, the product of a tip or the like may be used for picking property or on the skin. The tendency to deteriorate in usability such as extensibility. The cosmetic for makeup of the present invention further contains a metal soap-treated fine particle titanium oxide (component B). The metal soap-treated fine particle titanium oxide of the present invention is obtained by treating the surface of the fine particle titanium oxide with a metal soap. The fine particle oxidation of the metal ruthenium-treated fine particles of the present invention is not particularly limited as long as it is called fine particle titanium oxide. In general, it is preferred to use fine particle titanium oxide having an average primary particle diameter of 〇1 μm or less. The lower limit of the average particle diameter of the fine particle titanium oxide is not particularly limited, and is usually about 3 〇 nm. The fine particle titanium oxide can be produced, for example, by a usual method such as a sulfuric acid method or a gas method, or a commercially available product can be used. Examples of the commercially available fine particle titanium oxide include SIV series, ττο·55 series, TT〇s series (the above are manufactured by Ishihara Sangyo Co., Ltd.), MT_100TV, MT 500V, and MT 01 (the above are manufactured by Tayca Co., Ltd.). β In the present invention, the fine particle titanium oxide having a surface treated with a metal soap is used as a necessity. The metal soap used for the surface treatment is a polyvalent metal salt of a fatty acid, and particularly preferably a polyvalent metal salt having a carbon number of 12 to 18, and examples of the salt include a calcium salt, a magnesium salt, and a zinc salt. Aluminum salt 160525.doc
S -6 201231071 等，尤佳為紹鹽。 作為較佳之具體例，可列舉：硬酯酸鋁、二硬酯酸鋁、 油鲛鋁、棕搁酸鋁、月桂酸鋁、肉豆蔻酸鋁、二肉豆蔻酸 鋁等。 對微粒子氧化鈦之表面進行金屬皂處理之方法並無特別 限定’例如可藉由將金屬皂溶解於異烷烴、異丙醇等揮發 性心劑中，將其與微粒子氧化鈦混合之後，使揮發性溶劑 揮發而製備。又’亦可僅將微粒子氧化鈦與金屬皂混合。 本發明之彩粧用化粧品中的金屬皂處理微粒子氧化鈦之 調配量通常為0.1〜5質量％，較佳為〇·2〜3質量％。若調配量 未達0.1質量。/。，則有觀察不到顯色之提昇效果之傾向，若 調配超過5質量。/。，則有塗佈於肌膚上時可觀察到因微粒 子而引起之粗糙感等使用性變差之傾向。 進而，本發明之彩粧用化粧品之特徵在於係藉由濕式成 型而製造。所謂濕式成型係如下所述之成型方法：於含有 包含上述疏水化處理有色材料（成分Α)及金屬皂處理微粒 子氧化鈦（成分Β)之粉末成分、與包含油分等之油劑成分 的化粧品基劑十添加溶劑而製成漿料，繼而將該漿料填2 於容器内後’去除上述溶劑（例如’參照日本專利特公昭 57-60004號公報、日本專利特公昭61_54766號公報卜a 作為濕式成型中所使用之揮發性溶劑，例如可列舉： 狀聚矽氧、揮發性直鏈狀聚矽氧、輕質液體異烷烴、二環 曱燒、氟碳、己烧、環己燒、越、曱笨、_ 氣 ^ 甲本、丙鲷、 本、萜烯類、水、1,3-丁二醇、乙醇、甲醇、丙 鮮、異丙 160525.doc 201231071 醇、丁醇等，可根據調配成分之種類等而適當選擇。 又，作為濕式成型中所使用之濕式分散機，例如可列舉 分散混合器或均質機等通常之濕式分散機至使用氧化鍅 珠、玻璃珠、不鏽鋼珠等介質之介質攪拌研磨機，並無特 別限定^ 本發明之彩粧用化粧品除上述之必需成分A及B以外， 亦可於不妨礙本發明之效果之範圍内，調配先前以來用於 彩粧用化粧品中的其他任意成分。具體而言，可列舉：粉 末成分（除金屬皂處理微粒子氧化鈦及疏水化處理有色材 料以外）、油分、蠟、保濕劑、界面活性劑、增黏劑、色 素、防腐劑等。 上述必需成分A(疏水化處理有色材料）及成分B(金屬皂 處理微粒子氧化鈦）以外之粉末成分包括體質顏料、色 料、珠光劑、亮粉劑（lame agent)等，只要為先前以來用於 彩粧用化粧品等中者即可。 作為體質顏料，例如可列舉：雲母、絹雲母 嶺土等黏土礦物之粉碎品、矽酸酐、氧化鈽、二氧化矽 硬脂酸辞、含氟金雲母'合成滑石、硫酸鋇'氮化棚、 氣化祕、氧化銘、碳酸鎂等。 作為色料（著色顏料），例可列舉：鐵丹、氧 化鐵黑、群青、氧域、氧料、鐵藍等。 作為珠光劑，可列舉下述者作為代表例： 雲母（雲母欽）' 氧化鐵被覆帝魏b 礼化鈦被 胭脂紅-鐵藍被覆雲母鈦、氧 覆衣母鈦 氧化鐵-胭脂紅處理雲母鈦、 藍處理雲母林、氧化鐵__^ 鐵藍處理m氧化鉻處理 160525.doc 201231071 母鈦、氧化鈦黑被覆雲母鈦、丙烯酸系樹脂被覆鋁粉末、 氧化欽被覆雲母、氧化欽被覆氧氣化叙、氧化欽被覆滑 石、著色氧化鈦被覆雲母、氧化鈦被覆合成雲母、氧化妖 被覆二氧化矽、氧化鈦被覆氧化鋁'氧化鈦被覆破璃粉 末、聚對苯二子酸乙二酯·聚甲基丙烯酸甲酯積層膜粉 末、氧氣化叙、魚鱗羯等。 作為油分，可列舉：烴油、酯油、聚矽氧油等。具體而 言，包括：角鯊烷、液態石蠟、凡士林等烴油；肉豆籍 酸、棕櫚酸、硬脂酸、12_羥基硬脂酸、山籥酸等高級脂 肪酸，鯨堰醇、硬脂醇、油醇、鯊肝醇等高級醇；2_乙基 己酸鯨蠟酯、棕櫚酸-2-乙基己酯、肉豆蔻酸2_辛基十二二 基酯、新戊二醇-2-乙基己酸酯、三辛酸甘油酯、四辛酸季 戊四醇酯、三異硬脂酸甘油酯、二異硬脂酸甘油酯、肉豆 蔻酸異丙酉旨、肉豆蔻酸肉豆蔻酯 '三油酸甘油酯等酯油；S -6 201231071, etc., especially for Shao salt. Preferred examples of the resin include aluminum stearate, aluminum distearate, aluminum lanthanum, aluminum aluminosilicate, aluminum laurate, aluminum myristate, and aluminum dimyristate. The method of subjecting the surface of the fine particle titanium oxide to metal soap treatment is not particularly limited. For example, the metal soap can be dissolved in a volatile heart agent such as isoparaffin or isopropyl alcohol, and then mixed with the fine particle titanium oxide to be volatilized. The solvent is prepared by evaporation. Further, it is also possible to mix only the fine particle titanium oxide with the metal soap. The amount of the metal soap-treated fine particle titanium oxide in the cosmetic for makeup of the present invention is usually 0.1 to 5% by mass, preferably 2 to 3% by mass. If the amount is less than 0.1 mass. /. , there is a tendency to observe the improvement effect of color development, if the blending exceeds 5 mass. /. In addition, when applied to the skin, the usability due to the fineness caused by the fine particles is observed to be deteriorated. Further, the cosmetic for makeup of the present invention is characterized in that it is produced by wet molding. The wet molding is a molding method including a powder component containing the hydrophobized colored material (component Α) and a metal soap-treated fine particle titanium oxide (component Β), and a cosmetic component containing an oil component such as an oil component. The base is added with a solvent to prepare a slurry, and then the slurry is filled in a container, and then the solvent is removed (for example, see Japanese Patent Publication No. Sho 57-60004, Japanese Patent Publication No. SHO 61-54766, A. Examples of the volatile solvent used in the wet molding include polyfluorene oxide, volatile linear polyfluorene oxide, light liquid isoparaffin, bicyclic fluorene, fluorocarbon, hexane, and cyclohexane. More, stupid, _ gas ^ A, B, 本, terpene, water, 1,3-butanediol, ethanol, methanol, propylene, isopropyl 160525.doc 201231071 alcohol, butanol, etc. The wet disperser used in the wet molding is, for example, a usual wet disperser such as a disperser mixer or a homogenizer to use cerium oxide beads or glass beads, and the like. Stainless steel beads, etc. The medium-sized agitating and polishing machine is not particularly limited. In addition to the above-mentioned essential components A and B, the cosmetic for makeup of the present invention can also be used for color cosmetics in the range which does not impair the effects of the present invention. Other optional components in the cosmetic, specifically, a powder component (except for metal soap-treated fine particle titanium oxide and hydrophobicized colored material), an oil component, a wax, a moisturizer, a surfactant, a tackifier, a pigment, Preservatives, etc. The powder components other than the above-mentioned essential component A (hydrophobicized colored material) and component B (metal soap-treated fine particle titanium oxide) include extender pigments, colorants, pearlizing agents, lame agents, etc., as long as In the past, it may be used for makeup cosmetics, etc. Examples of the body pigments include pulverized products of clay minerals such as mica and sericin clay, phthalic anhydride, cerium oxide, cerium oxide stearic acid, and Fluorphine mica 'synthetic talc, barium sulfate 'nitriding shed, gasification secret, oxidation, magnesium carbonate, etc. As a coloring material (coloring pigment), for example, iron oxide, Iron oxide black, ultramarine blue, oxygen field, oxygen material, iron blue, etc. As a pearling agent, the following may be mentioned as a representative example: Mica (mica Chin)' Iron oxide coated emperor Wei b Lihua titanium carmine red-iron blue Coated mica titanium, oxygen coating mother titanium iron oxide-carmine treatment mica titanium, blue treated mica forest, iron oxide __^ iron blue treatment m chromium oxide treatment 160525.doc 201231071 mother titanium, titanium oxide black coated mica titanium, acrylic Resin-coated aluminum powder, oxidized-coated mica, oxidized-coated oxygenated oxidized, oxidized-coated talc, colored titanium oxide-coated mica, titanium oxide-coated synthetic mica, oxidized dew coated ceria, titanium oxide coated alumina 'titanium oxide It is coated with glass powder, polyethylene terephthalate, polymethyl methacrylate laminated film powder, oxygenated sputum, and ichthyosis. Examples of the oil component include a hydrocarbon oil, an ester oil, and a polyoxygenated oil. Specifically, it includes: hydrocarbon oils such as squalane, liquid paraffin, and petrolatum; higher fatty acids such as myristic acid, palmitic acid, stearic acid, 12-hydroxystearic acid, and behenic acid, whale sterol, and stearin. Higher alcohols such as alcohol, oleyl alcohol, and shark liver alcohol; 2-ethylhexanoate cetyl ester, palmitic acid 2-ethylhexyl ester, myristate 2-octyl dodecyl ester, neopentyl glycol- 2-ethylhexanoate, tricaprylin, pentaerythritol tetraoctanoate, glyceryl triisostearate, glyceryl diisostearate, isopropyl myristate, myristyl myristate An ester oil such as oleic acid glyceride;
橄欖油、酪梨油（avocado 〇u)、荷荷芭油、葵花籽油、紅 化子油1茶油、澳洲胡桃油、紹油、羊毛脂、液狀羊毛 脂、醋酸羊毛脂、缝麻油等油脂；二甲基聚矽氧烷、甲基 笨基聚碎氧院、高聚合度之膠狀二甲基㈣氧院、聚趟改 質聚石夕氧、胺基改質㈣氧等聚料系油分；纽質二甲 基聚石夕氧烧、氟改質甲基苯基聚石夕氧院 碳等氟系油分等。 I 西棕橺壤、堪地里拉蠛、蜂 固體石蠟等。 :甘油、丙二醇、1，3·丁二醇 作為蝶，例如可列舉：巴 蠟、漆樹蠟、地蠟、微晶蠟、 作為保濕劑，例如可列舉 等多元醇系保濕劑。 160525.doc 201231071 該等任意成分係於濕式成型令之化粧品基劑之階段混合 於基劑中。 如上所述，本發明之彩粧用化粧品尤其是顯色性優異、 顏色持久性良好。因此，本發明之化粧品適合用於眼影、 胭脂、口紅等重點部位彩粧用化粧品中，尤其是適合用於 眼影。 、 [實施例] 一以下列舉具體例更詳細地說明本發明，但本發明並不限 定於以下之實施例。又，以下之實施例等中之調配量只要 無特別說明均表示質量％。 (實施例及比較例） 藉由濕式成型法製備具有下述表i中揭示之組成之試樣 (眼影）。使用乙醇作為濕式成型中之揮發性溶劑。關於所 獲得之各試樣，針對自容器之Μ取性之良好程度、塗佈時 色之良好程度、對肌膚之伏貼感，依據以下之評價方 法及基準進行評價。將其等之結果一併示於表i中。 (評價方法） 他檢查員（10名）使用各試樣，並進行5個階段之官 平仏（”平刀）。依據該評分之平均值，按照 評價基 進行判定。 (評分） 5 :非常優異 4 :優異 3 :普通 2 :差 160525.doc 201231071 1 :非常差 (評價基準） ◎:評價值（平均值）為4.0以上且5.0分以下 〇：評價值（平均值）為3.0以上且未達4.0分 △:評價值（平均值）為2.0以上且未達3.0分 X :評價值（平均值）為1.0以上且未達2.0分 [表1] 實施 例1 比較 例1 比較 例2 比較 例3 比較 例4 比較 例5 比較 例6 比較 例7 聚矽氧處理滑石 16 16 16 16 16 16 16 16 合成雲母 10 10 10 10 10 10 10 10 硬脂酸鋁處理微粒子 氧化鈦 5 - - _ - - - - 氮化硼 - 5 - - - - - - 聚胺基甲酸酯樹脂 - - 5 - - - - - (二甲基聚矽氧烷/乙 烯基二曱基聚矽氧/曱 基聚矽氧院） 交聯聚合物 - - - 5 - - - - 矽酸酐 - - 5 - - - 尼龍粉末 - - - - - 5 - 聚乙烯粉末 - - - - - - 5 _ 交聯型聚甲基丙烯酸 甲酯 _ - - _ - - 5 烷基改質聚矽氧處理 氧化鐵 12.5 12.5 12.5 12.5 12.5 12.5 12.5 12.5 群青 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 氣苯甘醚 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 雲母鈦 30 30 30 30 30 30 30 30 曱基苯基聚矽氧烷 3 3 3 3 3 3 3 2 蘋果酸二異硬脂基酯 4 4 4 4 4 4 4 6 2-乙基己酸三甘油酯 3 3 3 3 3 3 3 2 辛氧基甘油 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 部分交聯型聚醚改質 有機聚矽氧烷 4 4 4 4 4 4 4 4 二甲基聚矽氧烷 11 11 11 11 11 11 11 11 合計 100 100 100 100 100 100 100 100 蘸取性 〇 Δ Δ Δ Δ Δ Δ Δ 顯色 ◎ Δ Δ Δ Δ Δ Δ Δ 伏貼感 ◎ Δ Δ Δ Δ Δ 〇 〇 I60525.doc -11 - 201231071 調配金屬皂處理微粒子氧化鈦之實施例1與調配其他粉 末成分之比較例1〜7相比較，蘸取性、顯色及伏貼感等所 有項目均優異。 以下’列舉本發明之彩粧用化粧品之其他配方例。利用 該等配方例之化粧品亦可獲得與上述實施例丨同樣^好 顯色、伏貼感及使用性。 、之 配方例1 (眼影）： 調配量（質量〇/〇) 2 2 2 0.1 1 0.5 1 2 4 4 0.1 25 剩餘 7 1 0.01 4 0.01 0.02 調配成分 凡士林 二甲基聚矽氧烷 甲基苯基聚矽氧烷 甘油 三辛酸甘油酯 植物性角鯊烷 山梨糖醇酐倍半異硬脂酸酯 氮化硼 雲母鈦 金雲母 合成金雲母 絹雲母 滑石 雲母 肉豆蔻酸鋅 硬脂酸鋁 矽酸酐 植物固醇 DL-α-生育醇醋酸酯 160525.doc 201231071 D-δ-生育酚 0.02 乙醢化玻尿酸鈉 0.02 對羥基苯甲酸酯 0.2 烷基矽烷處理氧化鐵 9 硬脂酸鋁處理微粒子氧化鈦 3 合成矽酸鈉/鎂 0.1 香料 適量 蘋果酸二異硬脂基酯 5 三異硬脂精 2 配方例2(眼影）： 調配成分 調配量（質量 液態石蠍 3 二曱基聚矽氧烷 3 雲母 20 滑石 剩餘 硬脂酸鋁處理微粒子氧化鈦 2 δ-生育酚 適量 對羥基苯曱酸酯 0.2 鈦酸銘 4 聚矽氧處理氧化鐵 4 石夕酸鎮銘 1.5 香料 適量 絹雲母 20 山梨糖醇酐倍半異硬脂酸酯 2 肉豆蔻酸辞 5 配方例3(胭脂）： 調配成分 調配量（質量 鐵丹被覆雲母鈦 30 160525.doc 13 201231071 滑石 剩餘 雲母 15 δ-生育酚 0.02 對羥基苯曱酸酯 適量 色素 適量 烷基改質聚矽氧處理氧化鐵 1 硬脂酸鋁處理微粒子氧化鈦 0.5 石夕酸錢铭 3 香料 適量 交聯型聚矽氧粉末 5 聚丙烯酸烷基酯 10 金屬皂處理滑石 15 14 160525.docOlive oil, avocado oil (avocado 〇u), jojoba oil, sunflower oil, red pepper oil 1 tea oil, Australian walnut oil, Shao oil, lanolin, liquid lanolin, lanolin acetate, sesame oil Such as oil; dimethyl polyoxyalkylene, methyl stupid polyoxycholate, high polymerization degree of colloidal dimethyl (tetra) oxygen institute, polyfluorene modified polysulfide, amine modified (four) oxygen and other poly The oil content of the system is fluorocarbon oil such as dimethyl chlorite, fluoro-modified methyl phenyl poly-stone, and carbon-based oil. I West brown soil, candidum, bees, solid paraffin, etc. Glycerin, propylene glycol, and 1,3-butanediol As the butterfly, for example, wax, lacquer wax, ozokerite, microcrystalline wax, and a humectant, for example, a polyhydric alcohol-based humectant can be mentioned. 160525.doc 201231071 These optional ingredients are mixed in the base at the stage of the cosmetic base of the wet forming order. As described above, the cosmetic for makeup of the present invention is excellent in color developability and good in color durability. Therefore, the cosmetic of the present invention is suitable for use in makeup cosmetics for key parts such as eye shadow, blush, and lipstick, and is particularly suitable for use in eye shadow. [Embodiment] The present invention will be described in more detail with reference to specific examples, but the present invention is not limited to the following examples. In addition, the blending amount in the following examples and the like indicates the mass % unless otherwise specified. (Examples and Comparative Examples) A sample (eye shadow) having the composition disclosed in the following Table i was prepared by a wet molding method. Ethanol is used as a volatile solvent in wet forming. Regarding each of the obtained samples, the degree of goodness of the self-containedness of the container, the degree of goodness of the application, and the feeling of smear on the skin were evaluated according to the following evaluation methods and criteria. The results of these and the like are shown together in Table i. (Evaluation method) The inspector (10) used each sample and performed a five-stage official flat ("flat knife"). Based on the average of the scores, the judgment was made according to the evaluation basis. (Score) 5: Very Excellent 4: Excellent 3: Normal 2: Difference 160525.doc 201231071 1 : Very poor (evaluation standard) ◎: Evaluation value (average value) is 4.0 or more and 5.0 or less 〇: Evaluation value (average value) is 3.0 or more and is not 4.0 points Δ: The evaluation value (average value) was 2.0 or more and less than 3.0 minutes X: The evaluation value (average value) was 1.0 or more and less than 2.0 points [Table 1] Example 1 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Comparative Example 6 Comparative Example 7 Polyoxane-treated talc 16 16 16 16 16 16 16 16 Synthetic mica 10 10 10 10 10 10 10 10 Aluminum stearate treated fine particle titanium oxide 5 - - _ - - - - Boron Nitride - 5 - - - - - - Polyurethane Resin - - 5 - - - - - (Dimethyl polyoxyalkylene / vinyl dimercapto polyoxyl / ruthenium polyfluorene Oxygen Institute) Crosslinked Polymer - - - 5 - - - - Phthalic Anhydride - - 5 - - - Nylon Powder - - - - - 5 - Polyethylene Powder - - - - - - 5 _ Crosslinked polymethyl methacrylate _ - - _ - - 5 alkyl modified polyoxo treated iron oxide 12.5 12.5 12.5 12.5 12.5 12.5 12.5 12.5 Ultramarine 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 Gas Benzene Ether 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 mica titanium 30 30 30 30 30 30 30 30 nonylphenyl polyoxane 3 3 3 3 3 3 3 2 diisostearyl malate 4 4 4 4 4 4 4 6 2-Ethylhexanoic acid triglyceride 3 3 3 3 3 3 3 2 Octyloxyglycerol 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Partially crosslinked polyether modified organic polyoxane 4 4 4 4 4 4 4 4 Dimethyl polyoxane 11 11 11 11 11 11 11 11 Total 100 100 100 100 100 100 100 100 蘸 〇 Δ Δ Δ Δ Δ Δ □ Δ Δ Δ Δ Δ Δ Δ Δ Δ Δ Δ Δ Δ Δ Δ 〇〇I60525.doc -11 - 201231071 Example 1 of formulating metal soap-treated fine particle titanium oxide Compared with Comparative Examples 1 to 7 in which other powder components were blended, all items such as pick-up property, color development, and volt-stick feeling were compared. Both are excellent. The following is a list of other formulation examples of the cosmetic for makeup of the present invention. The cosmetics of the above-mentioned formulas can also be obtained in the same manner as the above-mentioned examples, in terms of color development, smear feeling, and usability. Formulation Example 1 (eye shadow): Preparation amount (mass 〇 / 〇) 2 2 2 0.1 1 0.5 1 2 4 4 0.1 25 Remaining 7 1 0.01 4 0.01 0.02 Formulation of Vaseline dimethyl polyoxyalkylene methyl phenyl Polyoxyalkylene glyceryl tricaprylin plant squalane sorbitan sesquiisostearate boron nitride mica titanium phlogopite synthetic phlogopite sericite talc mica myristate zinc stearate aluminum phthalate plant Sterol DL-α-tocopherol acetate 160525.doc 201231071 D-δ-tocopherol 0.02 acetonitrile sodium hyaluronate 0.02 p-hydroxybenzoate 0.2 alkyl decane treated iron oxide 9 aluminum stearate treated microparticle titanium oxide 3 Synthetic sodium citrate/magnesium 0.1 Perfume amount of diisostearyl malate 5 Triisostearyl 2 Formulation 2 (eye shadow): Formulation of ingredients (mass liquid sarcophagus 3 dimercapto polyoxaxane 3 mica 20 talc residual aluminum stearate treatment of titanium oxide 2 δ-tocopherol amount of para-hydroxybenzoate 0.2 Titanic acid Ming 4 Polyoxane treatment of iron oxide 4 Shi Xi acid Zhen Ming 1.5 Spice amount of sericite 20 Sorbitol Half Isostearate 2 Myristic acid 5 Formulation Example 3 (Rouge): Formulation of ingredients (Quality of iron oxide coated mica titanium 30 160525.doc 13 201231071 Talc residual mica 15 δ-tocopherol 0.02 p-hydroxybenzoate Appropriate amount of pigment, modified alkyl, polyfluorene, iron oxide, aluminum stearate, microparticulate, titanium oxide, 0.5, Shiyan acid, Qianming 3, flavor, cross-linked polyoxynium powder, 5 polyalkyl acrylate, 10 metal soap, talc, 15 14 160525.doc