WO2012098765A1 - Makeup cosmetic - Google Patents
Makeup cosmetic Download PDFInfo
- Publication number
- WO2012098765A1 WO2012098765A1 PCT/JP2011/077030 JP2011077030W WO2012098765A1 WO 2012098765 A1 WO2012098765 A1 WO 2012098765A1 JP 2011077030 W JP2011077030 W JP 2011077030W WO 2012098765 A1 WO2012098765 A1 WO 2012098765A1
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- WIPO (PCT)
- Prior art keywords
- titanium oxide
- treated
- fine particle
- makeup
- color
- Prior art date
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
- A61Q1/06—Lipsticks
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/60—Particulates further characterized by their structure or composition
- A61K2800/61—Surface treated
- A61K2800/62—Coated
- A61K2800/622—Coated by organic compounds
Definitions
- the present invention relates to a makeup cosmetic containing a hydrophobized color material and metal soap-treated fine particle titanium oxide. More specifically, the present invention relates to a makeup cosmetic that is wet-molded and has excellent color development and long lasting makeup.
- Makeup cosmetics are made by dispersing pigments (organic, inorganic, pearl pigments, etc.) in various bases, and products in various forms are on the market.
- point makeup cosmetics such as eye shadows, lipsticks, and blushers are cosmetics that impart aesthetic effects by applying color to the skin, and their color development is one of the important characteristics.
- the properties of the powder components that are often incorporated in these makeup cosmetics affect not only the color development of the cosmetics but also the usability such as familiarity with the skin and smoothness.
- various contrivances have been made.
- Patent Document 1 describes a colored composite powder in which metal colloidal fine particles are encapsulated in a metal oxide and a cosmetic containing the same.
- the colored composite powder particularly vividly develops a blue or green color and exhibits a beautiful color. It is said that the cosmetics which have are obtained.
- Patent Document 2 describes a stick makeup cosmetic containing a specific spherical resin powder, a polar oil, a solid oil, and preferably a fluorescent dye at a predetermined ratio, and a vivid and dull color is obtained. It is supposed to be done.
- Patent Document 3 when a cationic surfactant-treated powder obtained by treating a specific powder with a cationic surfactant, and a hydrophobic treatment color material surface-treated with a silicone compound or a fluorine compound, it is described that a powder cosmetic that is excellent in usability such as familiarity with the skin and smoothness and has little color dullness over time can be obtained.
- the color of the cosmetic itself is often different from the color when applied to the skin, and the beautiful color obtained when applied to the skin changes over time. There was also a problem.
- an object of the present invention is to provide a makeup cosmetic that has a good color development and is applied with an as-looked color and that has a good color residue over time and has a long makeup.
- the present invention provides a makeup cosmetic produced by wet molding, comprising (A) a hydrophobized colorant and (B) metal soap-treated fine particle titanium oxide.
- the makeup cosmetic of the present invention is excellent in color development, can reproduce the color as it is seen on the skin, and is excellent in makeup, and maintains the color when applied for a long time without discoloration over time. The effect that it is done.
- the makeup cosmetic of the present invention is excellent in removal from the container and fit to the skin.
- the makeup cosmetic of the present invention contains a hydrophobized color material (component A).
- the hydrophobized color material in the present invention means a color material whose surface has been hydrophobized.
- the surface treatment agent for hydrophobizing the surface is not particularly limited, but it is preferable to use a silicone compound or a fluorine compound. Examples of the silicone compound include dimethicone, methicone, silane coupling agent, alkyl-modified silicone, and silicone resin.
- fluorine compound examples include a fluorine-modified alkyl compound and a fluorine-modified silicone compound, and examples thereof include perfluoroalkyl phosphate esters and salts thereof, perfluoroalkylsilane, Teflon (registered trademark), and perfluoroalkylcarboxylic acid.
- fluorine compound examples include a fluorine-modified alkyl compound and a fluorine-modified silicone compound, and examples thereof include perfluoroalkyl phosphate esters and salts thereof, perfluoroalkylsilane, Teflon (registered trademark), and perfluoroalkylcarboxylic acid.
- Coloring materials to be hydrophobized include white pigments such as titanium oxide, zinc oxide, and cerium oxide, and colored pigments such as yellow iron oxide, red iron oxide, black iron oxide, chromium oxide, carbon black, ultramarine, and bitumen Is mentioned.
- the blending amount of the hydrophobic treatment color material in the makeup cosmetic of the present invention is usually 0.01 to 40% by mass, preferably 0.05 to 35% by mass. If the blending amount is less than 0.01% by weight, coloration as a coloring material may not be observed. If the blending amount exceeds 40% by weight, the product can be removed with a chip or the like and used for elongation to the skin. Tend to get worse.
- the makeup cosmetic of the present invention further contains metal soap-treated fine particle titanium oxide (component B).
- component B metal soap-treated fine particle titanium oxide
- the metal soap-treated fine particle titanium oxide in the present invention is obtained by treating the surface of fine particle titanium oxide with a metal soap.
- the fine particle titanium oxide constituting the metal soap-treated fine particle titanium oxide of the present invention is not particularly limited as long as it is called fine particle titanium oxide.
- fine particle titanium oxide having an average primary particle size of 0.1 ⁇ m or less is used.
- the lower limit of the average particle diameter of the fine particle titanium oxide is not particularly limited, but is usually about 30 nm.
- the fine particle titanium oxide can be produced, for example, by a conventional method such as a sulfuric acid method or a chlorine method, and a commercially available product can also be used.
- Examples of commercially available fine particle titanium oxide include SIV series, TTO-55 series, TTO-S series (above, manufactured by Ishihara Sangyo Co., Ltd.), MT-100TV, MT-500V, MT-01 (above, manufactured by Teika), etc. Is mentioned.
- fine particle titanium oxide whose surface is treated with a metal soap is used as an essential component.
- the metal soap used for the surface treatment is a polyvalent metal salt of a fatty acid, and in particular, a fatty acid having 12 to 18 carbon atoms is preferable, and examples of such salts include calcium, magnesium, zinc, aluminum and the like.
- aluminum salts are preferred.
- Preferable specific examples include aluminum stearate, aluminum distearate, aluminum oleate, aluminum palmitate, aluminum laurate, aluminum myristate, and aluminum dimylate.
- the method of treating the surface of the fine particle titanium oxide with a metal soap is not particularly limited.
- the metal soap is dissolved in a volatile solvent such as isoparaffin or isopropyl alcohol, mixed with the fine particle titanium oxide, and then the volatile solvent is volatilized. Can be prepared. Further, it is also possible to simply mix fine particle titanium oxide and metal soap.
- the compounding amount of the metal soap-treated fine particle titanium oxide in the makeup cosmetic of the present invention is usually 0.1 to 5% by mass, preferably 0.2 to 3% by mass. If the blending amount is less than 0.1% by mass, the effect of improving the color development tends to be lost. If the blending amount exceeds 5% by mass, a tingling sensation caused by fine particles is observed when applied to the skin. Tend to get worse.
- the makeup cosmetic of the present invention is characterized by being manufactured by wet molding.
- Wet molding means adding a solvent to a cosmetic base containing a powder component containing the hydrophobic treatment color material (component A) and metal soap-treated fine particle titanium oxide (component B) and an oil component containing oil and the like. Then, after the slurry is filled in the container, the solvent is removed (see, for example, Japanese Patent Publication Nos. 57-60004 and 61-54766).
- volatile solvent used for wet molding examples include cyclic silicone, volatile linear silicone, light liquid isoparaffin, methylene chloride, fluorocarbon, hexane, cyclohexane, ether, toluene, xylene, acetone, benzene, terpenes, water 1,3 butanediol, ethanol, methanol, propanol, isopropanol, butanol, and the like, and can be appropriately selected depending on the type of compounding component.
- wet disperser used for wet molding examples include, for example, a medium agitating mill using a medium such as zirconia beads, glass beads, and stainless beads from a normal wet disperser such as a disper mixer or a homogenizer. It is not limited.
- the makeup cosmetic of the present invention may contain other optional components conventionally used in makeup cosmetics in addition to the essential components A and B as long as the effects of the present invention are not impaired.
- specific examples include powder components (excluding metal soap-treated fine particle titanium oxide and hydrophobized color material), oil, wax, humectant, surfactant, thickener, dye, and preservative.
- Powder components other than the essential component A (hydrophobized color material) and component B (metal soap-treated fine particle titanium oxide) include extender pigments, colorants, pearl agents, lame agents, and the like. It may be used.
- extender pigments include, for example, pulverized products of viscous minerals such as mica, sericite, talc, and kaolin, silicic anhydride, cerium oxide, silica, zinc stearate, fluorinated phlogopite, synthetic talc, barium sulfate, boron nitride, Examples thereof include bismuth oxychloride, alumina, and magnesium carbonate.
- the colorant (color pigment) include bengara, yellow iron oxide, black iron oxide, ultramarine blue, titanium oxide, zinc oxide, and salmon.
- titanium dioxide-coated mica titanium dioxide-coated mica
- iron oxide-coated mica titanium carmine-coated mica titanium, carmine / conjugate-coated mica titanium, iron oxide / carmine-treated mica titanium, conger-treated mica titanium, iron oxide / conjugate treatment
- Mica titanium, chromium oxide treated mica titanium, black titanium oxide coated mica titanium, acrylic resin coated aluminum powder, titanium oxide coated mica, titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored titanium oxide coated mica, titanium oxide coated synthetic mica
- Typical examples include titanium oxide-coated silica, titanium oxide-coated alumina, titanium oxide-coated glass powder, polyethylene terephthalate / potimethyl methacrylate laminated film powder, bismuth oxychloride, fish scale foil, and the like.
- oils such as squalane, liquid paraffin and petrolatum, higher fatty acids such as myristic acid, palmitic acid, stearic acid, 12-hydroxystearic acid and behenic acid, cetyl alcohol, stearyl alcohol, oleyl alcohol, batyl alcohol Higher alcohols such as cetyl-2-ethylhexanoate, 2-ethylhexyl palmitate, 2-octyldodecyl myristate, neopentyl glycol-2-ethylhexanoate, glyceryl trioctanoate, pentaerythritol tetraoctanoate, triisostearic acid Ester oil such as glyceryl, glyceryl diisostearate, isopropyl myristate, myristyl myristate, glyceryl trioleate, olive oil
- wax examples include carnauba wax, candelilla wax, bees wax, mole, ceresin wax, microcrystalline wax, and solid paraffin wax.
- humectant examples include polyhydric alcohol humectants such as glycerin, propylene glycol, and 1,3 butylene glycol.
- the makeup cosmetic of the present invention is particularly excellent in color developability and good color durability. Therefore, the cosmetic of the present invention is suitable for use as an eye shadow in point makeup cosmetics such as eye shadow, blusher and lipstick.
- Example 1 A sample (eye shadow) having the composition listed in Table 1 below was prepared by a wet molding method. Ethanol was used as a volatile solvent in wet molding. Each of the obtained samples was evaluated according to the following evaluation methods and standards for good removal from the container, good color development when applied, and fit to the skin. The results are also shown in Table 1.
- Evaluation methods Each sample was used by a panelist (10 persons) and subjected to sensory evaluation (score) in five stages. Based on the average score, the following evaluation criteria were used. (Score) 5: Very good 4: Excellent 3: Normal 2: Inferior 1: Very inferior (Evaluation criteria) ⁇ : Evaluation value (average value) 4.0 or more and 5.0 points or less ⁇ : Evaluation value (average value) 3.0 or more and less than 4.0 points ⁇ : Evaluation value (average value) 2.0 or more and 3.0 points Less than x: Evaluation value (average value) 1.0 or more and less than 2.0 points
- Example 1 in which metal soap-treated fine particle titanium oxide was blended was superior to Comparative Examples 1 to 7 in which other powder components were blended, and was excellent in all items of color development and fit.
- Formulation Example 1 (Eye Shadow): Compounding ingredients Compounding amount (% by mass) Vaseline 2 Dimethylpolysiloxane 2 Methylphenyl polysiloxane 2 Glycerin 0.1 Trioctanoin 1 Plant-based squalane 0.5 Sorbitan sesquiisostearate 1 Boron nitride 2 Mica titanium 4 Phlogopite 4 Synthetic phlogopite 0.1 Sericite 25 Talc Residual Mica 7 Zinc myristate 1 Aluminum stearate 0.01 Silicic anhydride 4 Phytosterol 0.01 DL- ⁇ -tocopherol acetate 0.02 D- ⁇ -Tocopherol 0.02 Acetylated sodium hyaluronate 0.02 P-Hydroxybenzoate ester 0.2 Alkylsilane-treated iron oxide 9 Aluminum stearate treated fine particle titanium oxide 3 Synthetic sodium silicate / magnesium 0.1 Perfume proper amount diisostearyl mal
- Formulation Example 2 Compounding ingredients Compounding amount (% by mass) Liquid paraffin 3 Dimethylpolysiloxane 3 Mica 20 Talc Residual aluminum stearate treated fine particles Titanium oxide 2 ⁇ -tocopherol appropriate amount paraoxybenzoate 0.2 Cobalt titanate 4 Silicone-treated iron oxide 4 Aluminum magnesium silicate 1.5 Fragrance Appropriate Sericite 20 Sorbitan sesquiisostearate 2 Zinc myristate 5
- Formulation example 3 (blusher): Compounding ingredients Compounding amount (% by mass) Bengala coated mica titanium 30 Talc Residual Mica 15 ⁇ -tocopherol 0.02 Paraoxybenzoic acid ester Appropriate amount of dye Appropriate amount of alkyl-modified silicone-treated iron oxide Aluminum stearate treated fine particle titanium oxide 0.5 Aluminum magnesium silicate 3 Perfume proper amount cross-linked silicone powder 5 Polyalkyl acrylate 10 Metal soap treated talc 15: Compounding ingredients Compounding amount (% by mass) Bengala coated mica titanium 30 Talc Residual Mica 15 ⁇ -tocopherol 0.02 Paraoxybenzoic acid ester Appropriate amount of dye Appropriate amount of alkyl-modified silicone-treated iron oxide Aluminum stearate treated fine particle titanium oxide 0.5 Aluminum magnesium silicate 3 Perfume proper amount cross-linked silicone powder 5 Polyalkyl acrylate 10 Metal soap treated talc 15
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Abstract
Provided is a makeup cosmetic with which coloration is good, the color that is first seen when applied is well retained over time, and makeup durability is good. The makeup cosmetic is produced by mixing (A) a hydrophobization coloring material and (B) metallic soap-treated titanium oxide microparticles. The hydrophobization coloring material is preferably a coloring material that has been treated by a silicone compound or a fluorine compound, and the metallic soap-treated titanium oxide microparticles are preferably titanium oxide microparticles that have been treated by a calcium, magnesium, zinc, or aluminum salt of a C12-18 fatty acid.
Description
本発明は、疎水化処理色材及び金属石鹸処理微粒子酸化チタンを配合したメーキャップ化粧料に関する。より詳細には、湿式成型されたメーキャップ化粧料であって、発色性及び化粧持ちに優れたメーキャップ化粧料に関する。
The present invention relates to a makeup cosmetic containing a hydrophobized color material and metal soap-treated fine particle titanium oxide. More specifically, the present invention relates to a makeup cosmetic that is wet-molded and has excellent color development and long lasting makeup.
メーキャップ化粧料は顔料（有機、無機、パール顔料など）を種々の基剤中に分散させたものであり、様々な形態の製品が上市されている。特に、アイシャドー、口紅、頬紅などのポイントメーキャップ化粧料は、肌に塗布することにより色彩を付与し美的効果を得る化粧料であって、その発色性は重要な特性の一つである。
Makeup cosmetics are made by dispersing pigments (organic, inorganic, pearl pigments, etc.) in various bases, and products in various forms are on the market. In particular, point makeup cosmetics such as eye shadows, lipsticks, and blushers are cosmetics that impart aesthetic effects by applying color to the skin, and their color development is one of the important characteristics.
これらのメーキャップ化粧料に多く配合される粉末成分の性質は当該化粧料の発色性のみならず、肌へのなじみ、滑らかさ等の使用性に影響を与えるため、用途に応じて適切な粉末成分を選択して配合することが必要であり、表面処理等によって所望の性質を持った粉末を得るための様々な工夫がなされている。
The properties of the powder components that are often incorporated in these makeup cosmetics affect not only the color development of the cosmetics but also the usability such as familiarity with the skin and smoothness. In order to obtain a powder having desired properties by surface treatment or the like, various contrivances have been made.
例えば、特許文献１には、金属コロイド微粒子を金属酸化物に内包した着色複合粉末及びそれを配合した化粧料が記載され、当該着色複合粉末は特に青色又は緑色に鮮やかに発色し、美しい色彩を有する化粧料が得られるとされている。
また、特許文献２には、特定の球状樹脂粉末、極性油分、固形油分、及び好ましくは蛍光を発する染料を所定比率で配合したスティック状メーキャップ化粧料が記載され、鮮やかでくすみのない発色が得られるとされている。 For example, Patent Document 1 describes a colored composite powder in which metal colloidal fine particles are encapsulated in a metal oxide and a cosmetic containing the same. The colored composite powder particularly vividly develops a blue or green color and exhibits a beautiful color. It is said that the cosmetics which have are obtained.
Patent Document 2 describes a stick makeup cosmetic containing a specific spherical resin powder, a polar oil, a solid oil, and preferably a fluorescent dye at a predetermined ratio, and a vivid and dull color is obtained. It is supposed to be done.
また、特許文献２には、特定の球状樹脂粉末、極性油分、固形油分、及び好ましくは蛍光を発する染料を所定比率で配合したスティック状メーキャップ化粧料が記載され、鮮やかでくすみのない発色が得られるとされている。 For example, Patent Document 1 describes a colored composite powder in which metal colloidal fine particles are encapsulated in a metal oxide and a cosmetic containing the same. The colored composite powder particularly vividly develops a blue or green color and exhibits a beautiful color. It is said that the cosmetics which have are obtained.
Patent Document 2 describes a stick makeup cosmetic containing a specific spherical resin powder, a polar oil, a solid oil, and preferably a fluorescent dye at a predetermined ratio, and a vivid and dull color is obtained. It is supposed to be done.
一方、特許文献３には、特定の粉体をカチオン性界面活性剤で処理したカチオン性界面活性剤処理粉体と、シリコーン化合物又はフッ素化合物で表面処理した疎水化処理色材とを配合した場合、肌へのなじみ、滑らかさ等の使用性に優れ、経時での色ぐすみが少ない粉末化粧料が得られると記載されている。
しかしながら、一般のメーキャップ化粧料においては、化粧料自体の色彩と肌に塗布したときの色彩とが異なる場合が多く、さらには肌に塗布した際に得られた美しい色彩が経時で変化してしまうという問題もあった。 On the other hand, in Patent Document 3, when a cationic surfactant-treated powder obtained by treating a specific powder with a cationic surfactant, and a hydrophobic treatment color material surface-treated with a silicone compound or a fluorine compound In addition, it is described that a powder cosmetic that is excellent in usability such as familiarity with the skin and smoothness and has little color dullness over time can be obtained.
However, in general makeup cosmetics, the color of the cosmetic itself is often different from the color when applied to the skin, and the beautiful color obtained when applied to the skin changes over time. There was also a problem.
しかしながら、一般のメーキャップ化粧料においては、化粧料自体の色彩と肌に塗布したときの色彩とが異なる場合が多く、さらには肌に塗布した際に得られた美しい色彩が経時で変化してしまうという問題もあった。 On the other hand, in Patent Document 3, when a cationic surfactant-treated powder obtained by treating a specific powder with a cationic surfactant, and a hydrophobic treatment color material surface-treated with a silicone compound or a fluorine compound In addition, it is described that a powder cosmetic that is excellent in usability such as familiarity with the skin and smoothness and has little color dullness over time can be obtained.
However, in general makeup cosmetics, the color of the cosmetic itself is often different from the color when applied to the skin, and the beautiful color obtained when applied to the skin changes over time. There was also a problem.
よって本発明における課題は、発色が良好で見たままの色が塗布され、なおかつ経時での色残りが良好で化粧持ちに優れたメーキャップ化粧料を提供することにある。
Therefore, an object of the present invention is to provide a makeup cosmetic that has a good color development and is applied with an as-looked color and that has a good color residue over time and has a long makeup.
かかる課題を解決するために本発明者等は鋭意検討を重ねた結果、湿式成型で製造されるメーキャップ化粧料において、（Ａ）疎水化処理色材及び（Ｂ）金属石鹸処理微粒子酸化チタンを配合することにより、発色に優れ、経時での色残りも良好な化粧料が得られることを見出し、本発明を完成するに至った。
In order to solve this problem, the present inventors have made extensive studies and, as a result, formulated with (A) a hydrophobized colorant and (B) a metal soap-treated fine particle titanium oxide in a makeup cosmetic produced by wet molding. As a result, it was found that a cosmetic with excellent color development and good color residue over time was obtained, and the present invention was completed.
即ち本発明は、（Ａ）疎水化処理色材と、（Ｂ）金属石鹸処理微粒子酸化チタンとを配合し、湿式成型により製造されるメーキャップ化粧料を提供する。
That is, the present invention provides a makeup cosmetic produced by wet molding, comprising (A) a hydrophobized colorant and (B) metal soap-treated fine particle titanium oxide.
本発明のメーキャップ化粧料は、発色に優れ、見たままの色を肌上に再現することができ、なおかつ化粧持ちに優れ、経時での変色がなく塗布時の色が長時間に渡って維持されるという効果を奏する。また、本発明のメーキャップ化粧料は容器からのとれ及び肌へのフィット感にも優れたものである。
The makeup cosmetic of the present invention is excellent in color development, can reproduce the color as it is seen on the skin, and is excellent in makeup, and maintains the color when applied for a long time without discoloration over time. The effect that it is done. In addition, the makeup cosmetic of the present invention is excellent in removal from the container and fit to the skin.
本発明のメーキャップ化粧料は、疎水化処理色材（成分Ａ）を含有する。本発明における疎水化処理色材とは、表面を疎水化処理された色材を意味する。
表面を疎水化する表面処理剤としては、特に限定されないが、シリコーン化合物またはフッ素化合物を用いるのが好ましい。
シリコーン化合物としては、ジメチコン、メチコン、シランカップリング剤、アルキル変性シリコーン、シリコーンレジンなどが挙げられる。
フッ素化合物としては、フッ素変性アルキル化合物およびフッ素変性シリコーン化合物が挙げられ、例えばパーフルオロアルキルリン酸エステルとその塩、パーフルオロアルキルシラン、テフロン（登録商標）、パーフルオロアルキルカルボン酸などがを含む。またフッ素化合物とともにアクリル酸アルキルや（アクリル酸アルキル／ジメチコン）コポリマーなどと併用した疎水化処理を施してもよい。 The makeup cosmetic of the present invention contains a hydrophobized color material (component A). The hydrophobized color material in the present invention means a color material whose surface has been hydrophobized.
The surface treatment agent for hydrophobizing the surface is not particularly limited, but it is preferable to use a silicone compound or a fluorine compound.
Examples of the silicone compound include dimethicone, methicone, silane coupling agent, alkyl-modified silicone, and silicone resin.
Examples of the fluorine compound include a fluorine-modified alkyl compound and a fluorine-modified silicone compound, and examples thereof include perfluoroalkyl phosphate esters and salts thereof, perfluoroalkylsilane, Teflon (registered trademark), and perfluoroalkylcarboxylic acid. Moreover, you may perform the hydrophobization process used together with an alkyl acrylate, an (alkyl acrylate / dimethicone) copolymer, etc. with a fluorine compound.
表面を疎水化する表面処理剤としては、特に限定されないが、シリコーン化合物またはフッ素化合物を用いるのが好ましい。
シリコーン化合物としては、ジメチコン、メチコン、シランカップリング剤、アルキル変性シリコーン、シリコーンレジンなどが挙げられる。
フッ素化合物としては、フッ素変性アルキル化合物およびフッ素変性シリコーン化合物が挙げられ、例えばパーフルオロアルキルリン酸エステルとその塩、パーフルオロアルキルシラン、テフロン（登録商標）、パーフルオロアルキルカルボン酸などがを含む。またフッ素化合物とともにアクリル酸アルキルや（アクリル酸アルキル／ジメチコン）コポリマーなどと併用した疎水化処理を施してもよい。 The makeup cosmetic of the present invention contains a hydrophobized color material (component A). The hydrophobized color material in the present invention means a color material whose surface has been hydrophobized.
The surface treatment agent for hydrophobizing the surface is not particularly limited, but it is preferable to use a silicone compound or a fluorine compound.
Examples of the silicone compound include dimethicone, methicone, silane coupling agent, alkyl-modified silicone, and silicone resin.
Examples of the fluorine compound include a fluorine-modified alkyl compound and a fluorine-modified silicone compound, and examples thereof include perfluoroalkyl phosphate esters and salts thereof, perfluoroalkylsilane, Teflon (registered trademark), and perfluoroalkylcarboxylic acid. Moreover, you may perform the hydrophobization process used together with an alkyl acrylate, an (alkyl acrylate / dimethicone) copolymer, etc. with a fluorine compound.
疎水化処理される色材としては、酸化チタン、酸化亜鉛、酸化セリウムなどの白色顔料や、黄酸化鉄、赤色酸化鉄、黒酸化鉄、酸化クロム、カーボンブラック、群青、紺青、などの有色顔料が挙げられる。
Coloring materials to be hydrophobized include white pigments such as titanium oxide, zinc oxide, and cerium oxide, and colored pigments such as yellow iron oxide, red iron oxide, black iron oxide, chromium oxide, carbon black, ultramarine, and bitumen Is mentioned.
本発明のメーキャップ化粧料における疎水化処理色材の配合量は、通常は０．０１～４０質量％、好ましくは０．０５～３５質量％である。配合量が０．０１質量％未満であると色材としての発色が認められない場合があり、４０質量％を越えて配合するとチップ等での製品の取れや肌への伸び等の使用性が悪くなる傾向がある。
The blending amount of the hydrophobic treatment color material in the makeup cosmetic of the present invention is usually 0.01 to 40% by mass, preferably 0.05 to 35% by mass. If the blending amount is less than 0.01% by weight, coloration as a coloring material may not be observed. If the blending amount exceeds 40% by weight, the product can be removed with a chip or the like and used for elongation to the skin. Tend to get worse.
本発明のメーキャップ化粧料は、さらに金属石鹸処理微粒子酸化チタン（成分Ｂ）を含有する。本発明における金属石鹸処理微粒子酸化チタンは、微粒子酸化チタンの表面を金属石鹸で処理したものである。
The makeup cosmetic of the present invention further contains metal soap-treated fine particle titanium oxide (component B). The metal soap-treated fine particle titanium oxide in the present invention is obtained by treating the surface of fine particle titanium oxide with a metal soap.
本発明の金属石鹸処理微粒子酸化チタンを構成する微粒子酸化チタンは、微粒子酸化チタンと呼ばれるものであれば特に限定されないが、一般的には、平均一次粒子径が０．１μｍ以下の微粒子酸化チタンが好ましく使用される。微粒子酸化チタンの平均粒子径の下限は特に限定されないが、通常は３０ｎｍ程度である。微粒子酸化チタンは、例えば、硫酸法や塩素法等の常法により製造することが可能であり、市販品を用いることも可能である。市販の微粒子酸化チタンとしては、例えば、ＳＩＶシリーズ、ＴＴＯ－５５シリーズ、ＴＴＯ－Ｓシリーズ（以上、石原産業社製）、ＭＴ－１００ＴＶ、ＭＴ－５００Ｖ、 ＭＴ－０１（以上、テイカ社製）などが挙げられる。
The fine particle titanium oxide constituting the metal soap-treated fine particle titanium oxide of the present invention is not particularly limited as long as it is called fine particle titanium oxide. Generally, fine particle titanium oxide having an average primary particle size of 0.1 μm or less is used. Preferably used. The lower limit of the average particle diameter of the fine particle titanium oxide is not particularly limited, but is usually about 30 nm. The fine particle titanium oxide can be produced, for example, by a conventional method such as a sulfuric acid method or a chlorine method, and a commercially available product can also be used. Examples of commercially available fine particle titanium oxide include SIV series, TTO-55 series, TTO-S series (above, manufactured by Ishihara Sangyo Co., Ltd.), MT-100TV, MT-500V, MT-01 (above, manufactured by Teika), etc. Is mentioned.
本発明においては、表面を金属石鹸処理された微粒子酸化チタンが必須成分として用いられる。表面処理に使用される金属石鹸は脂肪酸の多価金属塩であり、特に脂肪酸の炭素数が１２～１８のものが好ましく、またそれらの塩としては、例えばカルシウム、マグネシウム、亜鉛、アルミニウム等が挙げられ、特にアルミニウム塩が好ましい。
好ましい具体例として、ステアリン酸アルミニウム、ジステアリン酸アルミニウム、オレイン酸アルミニウム、パルミチン酸アルミニウム、ラウリン酸アルミニウム，ミリスチン酸アルミニウム，ジミリチン酸アルミニウム等が挙げられる。 In the present invention, fine particle titanium oxide whose surface is treated with a metal soap is used as an essential component. The metal soap used for the surface treatment is a polyvalent metal salt of a fatty acid, and in particular, a fatty acid having 12 to 18 carbon atoms is preferable, and examples of such salts include calcium, magnesium, zinc, aluminum and the like. In particular, aluminum salts are preferred.
Preferable specific examples include aluminum stearate, aluminum distearate, aluminum oleate, aluminum palmitate, aluminum laurate, aluminum myristate, and aluminum dimylate.
好ましい具体例として、ステアリン酸アルミニウム、ジステアリン酸アルミニウム、オレイン酸アルミニウム、パルミチン酸アルミニウム、ラウリン酸アルミニウム，ミリスチン酸アルミニウム，ジミリチン酸アルミニウム等が挙げられる。 In the present invention, fine particle titanium oxide whose surface is treated with a metal soap is used as an essential component. The metal soap used for the surface treatment is a polyvalent metal salt of a fatty acid, and in particular, a fatty acid having 12 to 18 carbon atoms is preferable, and examples of such salts include calcium, magnesium, zinc, aluminum and the like. In particular, aluminum salts are preferred.
Preferable specific examples include aluminum stearate, aluminum distearate, aluminum oleate, aluminum palmitate, aluminum laurate, aluminum myristate, and aluminum dimylate.
微粒子酸化チタンの表面を金属石鹸処理する方法は特に限定されず、例えば、金属石鹸をイソパラフィン，イソプロピルアルコールなどの揮発性溶媒に溶解し、それを微粒子酸化チタンと混合した後、揮発性溶媒を揮散させることによって調製することができる。また単に微粒子酸化チタンと金属石鹸とを混合するだけでもよい。
The method of treating the surface of the fine particle titanium oxide with a metal soap is not particularly limited. For example, the metal soap is dissolved in a volatile solvent such as isoparaffin or isopropyl alcohol, mixed with the fine particle titanium oxide, and then the volatile solvent is volatilized. Can be prepared. Further, it is also possible to simply mix fine particle titanium oxide and metal soap.
本発明のメーキャップ化粧料における金属石鹸処理微粒子酸化チタンの配合量は、通常は０．１～５質量％、好ましくは０．２～３質量％である。配合量が０．１質量％未満であると発色の向上効果が見られなくなる傾向があり、５質量％を越えて配合すると肌へ塗布した際に微粒子に起因するキシミ感が見られるなど使用性が悪くなる傾向がある。
The compounding amount of the metal soap-treated fine particle titanium oxide in the makeup cosmetic of the present invention is usually 0.1 to 5% by mass, preferably 0.2 to 3% by mass. If the blending amount is less than 0.1% by mass, the effect of improving the color development tends to be lost. If the blending amount exceeds 5% by mass, a tingling sensation caused by fine particles is observed when applied to the skin. Tend to get worse.
さらに本発明のメーキャップ化粧料は、湿式成型によって製造されることを特徴としている。湿式成型とは、前記疎水化処理色材（成分Ａ）及び金属石鹸処理微粒子酸化チタン（成分Ｂ）を含む粉末成分と油分等を含む油剤成分とを含有する化粧料基剤に溶媒を添加してスラリーとし、次いで該スラリーを容器内に充填した後、前記溶剤を除去する成型方法である（例えば、特公昭５７－６０００４号公報、特公昭６１－５４７６６号公報を参照）。
Furthermore, the makeup cosmetic of the present invention is characterized by being manufactured by wet molding. Wet molding means adding a solvent to a cosmetic base containing a powder component containing the hydrophobic treatment color material (component A) and metal soap-treated fine particle titanium oxide (component B) and an oil component containing oil and the like. Then, after the slurry is filled in the container, the solvent is removed (see, for example, Japanese Patent Publication Nos. 57-60004 and 61-54766).
湿式成型に用いられる揮発性溶媒としては、例えば、環状シリコーン、揮発性直鎖状シリコーン、軽質流動イソパラフィン、塩化メチレン、フルオロカーボン、ヘキサン、シクロヘキサン、エーテル、トルエン、キシレン、アセトン、ベンゼン、テルペン類、水、１，３ブタンジオール、エタノール、メタノール、プロパノール、イソプロパノール、ブタノールなどが挙げられ、配合成分の種類等に応じて適宜選択することができる。
Examples of the volatile solvent used for wet molding include cyclic silicone, volatile linear silicone, light liquid isoparaffin, methylene chloride, fluorocarbon, hexane, cyclohexane, ether, toluene, xylene, acetone, benzene, terpenes, water 1,3 butanediol, ethanol, methanol, propanol, isopropanol, butanol, and the like, and can be appropriately selected depending on the type of compounding component.
また、湿式成型に用いられる湿式分散機としては、例えば、ディスパーミキサーやホモジナイザーなどの通常の湿式分散機から、ジルコニアビーズ、ガラスビーズ、ステンレスビーズなどのメディアを用いた媒体攪拌ミルが挙げられ、特に限定されるものではない。
Examples of the wet disperser used for wet molding include, for example, a medium agitating mill using a medium such as zirconia beads, glass beads, and stainless beads from a normal wet disperser such as a disper mixer or a homogenizer. It is not limited.
本発明のメーキャップ化粧料は、上記の必須成分Ａ及びＢに加えて、従来からメーキャップ化粧品に使用されている他の任意成分を、本発明の効果を阻害しない範囲で配合していてもよい。具体的には、粉末成分（金属石鹸処理微粒子酸化チタン及び疎水化処理色材を除く）、油分、ワックス、保湿剤、界面活性剤、増粘剤、色素、防腐剤などが挙げられる。
The makeup cosmetic of the present invention may contain other optional components conventionally used in makeup cosmetics in addition to the essential components A and B as long as the effects of the present invention are not impaired. Specific examples include powder components (excluding metal soap-treated fine particle titanium oxide and hydrophobized color material), oil, wax, humectant, surfactant, thickener, dye, and preservative.
前記必須成分Ａ（疎水化処理色材）及び成分Ｂ（金属石鹸処理微粒子酸化チタン）以外の粉末成分は、体質顔料、色剤、パール剤、ラメ剤などを含み、従来からメーキャップ化粧料等に使用されているものでよい。
Powder components other than the essential component A (hydrophobized color material) and component B (metal soap-treated fine particle titanium oxide) include extender pigments, colorants, pearl agents, lame agents, and the like. It may be used.
体質顔料としては、例えば、マイカ、セリサイト、タルク、カオリンなどの粘度鉱物の粉砕品、無水ケイ酸、酸化セリウム、シリカ、ステアリン酸亜鉛、含フッ素金雲母、合成タルク、硫酸バリウム、窒化ホウ素、オキシ塩化ビスマス、アルミナ、炭酸マグネシウムなどを挙げることができる。
色剤（着色顔料）としては、例えば、ベンガラ、黄酸化鉄、黒酸化鉄、群青、酸化チタン、酸化亜鉛、コンジョウなどを挙げることができる。 Examples of extender pigments include, for example, pulverized products of viscous minerals such as mica, sericite, talc, and kaolin, silicic anhydride, cerium oxide, silica, zinc stearate, fluorinated phlogopite, synthetic talc, barium sulfate, boron nitride, Examples thereof include bismuth oxychloride, alumina, and magnesium carbonate.
Examples of the colorant (color pigment) include bengara, yellow iron oxide, black iron oxide, ultramarine blue, titanium oxide, zinc oxide, and salmon.
色剤（着色顔料）としては、例えば、ベンガラ、黄酸化鉄、黒酸化鉄、群青、酸化チタン、酸化亜鉛、コンジョウなどを挙げることができる。 Examples of extender pigments include, for example, pulverized products of viscous minerals such as mica, sericite, talc, and kaolin, silicic anhydride, cerium oxide, silica, zinc stearate, fluorinated phlogopite, synthetic talc, barium sulfate, boron nitride, Examples thereof include bismuth oxychloride, alumina, and magnesium carbonate.
Examples of the colorant (color pigment) include bengara, yellow iron oxide, black iron oxide, ultramarine blue, titanium oxide, zinc oxide, and salmon.
パール剤としては、二酸化チタン被覆雲母（雲母チタン）、酸化鉄被覆雲母チタン、カルミン被覆雲母チタン、カルミン・コンジョウ被覆雲母チタン、酸化鉄・カルミン処理雲母チタン、コンジョウ処理雲母チタン、酸化鉄・コンジョウ処理雲母チタン、酸化クロム処理雲母チタン、黒酸化チタン被覆雲母チタン、アクリル樹脂被覆アルミニウム末、酸化チタン被覆マイカ、酸化チタン被覆オキシ塩化ビスマス、酸化チタン被覆タルク、着色酸化チタン被覆マイカ、酸化チタン被覆合成マイカ、酸化チタン被覆シリカ、酸化チタン被覆アルミナ、酸化チタン被覆ガラス粉、ポリエチレンテレフタレート・ポチメチルメタクリレート積層フィルム末、オキシ塩化ビスマス、魚鱗箔等が代表例として挙げられる。
As the pearl agent, titanium dioxide-coated mica (titanium mica), iron oxide-coated mica titanium, carmine-coated mica titanium, carmine / conjugate-coated mica titanium, iron oxide / carmine-treated mica titanium, conger-treated mica titanium, iron oxide / conjugate treatment Mica titanium, chromium oxide treated mica titanium, black titanium oxide coated mica titanium, acrylic resin coated aluminum powder, titanium oxide coated mica, titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored titanium oxide coated mica, titanium oxide coated synthetic mica Typical examples include titanium oxide-coated silica, titanium oxide-coated alumina, titanium oxide-coated glass powder, polyethylene terephthalate / potimethyl methacrylate laminated film powder, bismuth oxychloride, fish scale foil, and the like.
油分としては、炭化水素油、エステル油、シリコーン油などが挙げられる。具体的には、スクワラン、流動パラフィン、ワセリン等の炭化水素油、ミリスチン酸、パルミチン酸、ステアリン酸、１２－ヒドロキシステアリン酸、ベヘニン酸等の高級脂肪酸、セチルアルコール、ステアリルアルコール、オレイルアルコール、バチルアルコール等の高級アルコール、セチルー２－エチルヘキサノエート、２－エチルヘキシルパルミテート、２－オクチルドデシルミリステート、ネオペンチルグリコール－２－エチルヘキサノエート、トリオクタン酸グリセリル、テトラオクタン酸ペンタエリスリトール、トリイソステアリン酸グリセリル、ジイソステアリン酸グリセリル、イソプロピルミリステート、ミリスチルミリステート、トリオレイン酸グリセリル等のエステル油、オリーブ油、アボカド油、ホホバ油、ヒマワリ油、サフラワー油、椿油、マカデミアナッツ油、ミンク油、ラノリン、液状ラノリン、酢酸ラノリン、ヒマシ油等の油脂、ジメチルポリシロキサン、メチルフェニルポリシロキサン、高重合度のガム状ジメチルポリシロキサン、ポリエーテル変性シリコーン、アミノ変性シリコーン等のシリコーン系油分、フッ素変性ジメチルポリシロキサン、フッ素変性メチルフェニルポリシロキサン、パーフロロポリエーテル、パーフロロカーボン等のフッ素系油分等が含まれる。
Examples of the oil include hydrocarbon oil, ester oil, and silicone oil. Specifically, hydrocarbon oils such as squalane, liquid paraffin and petrolatum, higher fatty acids such as myristic acid, palmitic acid, stearic acid, 12-hydroxystearic acid and behenic acid, cetyl alcohol, stearyl alcohol, oleyl alcohol, batyl alcohol Higher alcohols such as cetyl-2-ethylhexanoate, 2-ethylhexyl palmitate, 2-octyldodecyl myristate, neopentyl glycol-2-ethylhexanoate, glyceryl trioctanoate, pentaerythritol tetraoctanoate, triisostearic acid Ester oil such as glyceryl, glyceryl diisostearate, isopropyl myristate, myristyl myristate, glyceryl trioleate, olive oil, avocado oil, jojoba oil, sunflower Oils such as safflower oil, coconut oil, macadamia nut oil, mink oil, lanolin, liquid lanolin, lanolin acetate, castor oil, dimethylpolysiloxane, methylphenylpolysiloxane, highly polymerized gum dimethylpolysiloxane, polyether-modified silicone , A silicone oil such as amino-modified silicone, and a fluorine oil such as fluorine-modified dimethylpolysiloxane, fluorine-modified methylphenylpolysiloxane, perfluoropolyether, and perfluorocarbon.
ワックスとしては、例えば、カルナバロウ、キャンデリラロウ、ビースワックス、モクロウ、セレシンワックス、マイクロクリスタリンワックス、固形パラフィンワックス等が挙げられる。
保湿剤としては、例えば、グリセリン、プロピレングリコール、１,３ブチレングリコール等の多価アルコール系保湿剤が挙げられる。
これらの任意成分は、湿式成型における化粧料基剤の段階で基剤に混合される。 Examples of the wax include carnauba wax, candelilla wax, bees wax, mole, ceresin wax, microcrystalline wax, and solid paraffin wax.
Examples of the humectant include polyhydric alcohol humectants such as glycerin, propylene glycol, and 1,3 butylene glycol.
These optional components are mixed with the base at the stage of the cosmetic base in wet molding.
保湿剤としては、例えば、グリセリン、プロピレングリコール、１,３ブチレングリコール等の多価アルコール系保湿剤が挙げられる。
これらの任意成分は、湿式成型における化粧料基剤の段階で基剤に混合される。 Examples of the wax include carnauba wax, candelilla wax, bees wax, mole, ceresin wax, microcrystalline wax, and solid paraffin wax.
Examples of the humectant include polyhydric alcohol humectants such as glycerin, propylene glycol, and 1,3 butylene glycol.
These optional components are mixed with the base at the stage of the cosmetic base in wet molding.
上記したように、本発明のメーキャップ化粧料は特に発色性に優れ色持ちが良好である。従って、本発明の化粧料は、アイシャドー、頬紅、口紅などのポイントメーキャップ化粧料において、中でもアイシャドーとして使用するのに適している。
As described above, the makeup cosmetic of the present invention is particularly excellent in color developability and good color durability. Therefore, the cosmetic of the present invention is suitable for use as an eye shadow in point makeup cosmetics such as eye shadow, blusher and lipstick.
以下に具体例を挙げて本発明を更に詳細に説明するが、本発明は以下の実施例に限定されるものではない。また、以下の実施例等における配合量は特に断らない限り質量％を示す。
Hereinafter, the present invention will be described in more detail with specific examples, but the present invention is not limited to the following examples. Moreover, the compounding quantity in a following example etc. shows the mass% unless there is particular notice.
（実施例及び比較例）
下記の表１に掲げた組成を有する試料（アイシャドー）を湿式成型法で調製した。湿式成型における揮発性溶媒としてエタノールを使用した。得られた各試料について、容器からのとれの良さ、塗布した際の発色の良さ、肌へのフィット感について、以下の評価方法及び基準に従って評価した。それらの結果を表１に併せて示す。 (Examples and Comparative Examples)
A sample (eye shadow) having the composition listed in Table 1 below was prepared by a wet molding method. Ethanol was used as a volatile solvent in wet molding. Each of the obtained samples was evaluated according to the following evaluation methods and standards for good removal from the container, good color development when applied, and fit to the skin. The results are also shown in Table 1.
下記の表１に掲げた組成を有する試料（アイシャドー）を湿式成型法で調製した。湿式成型における揮発性溶媒としてエタノールを使用した。得られた各試料について、容器からのとれの良さ、塗布した際の発色の良さ、肌へのフィット感について、以下の評価方法及び基準に従って評価した。それらの結果を表１に併せて示す。 (Examples and Comparative Examples)
A sample (eye shadow) having the composition listed in Table 1 below was prepared by a wet molding method. Ethanol was used as a volatile solvent in wet molding. Each of the obtained samples was evaluated according to the following evaluation methods and standards for good removal from the container, good color development when applied, and fit to the skin. The results are also shown in Table 1.
（評価方法）
各試料をパネリスト（１０名）に使用してもらい、５段階の官能評価（スコア）した。そのスコア平均値により、下記評価基準で判定した。
（スコア）
５：非常に優れている
４：優れている
３：普通
２：劣る
１：非常に劣る
（評価基準）
◎：評価値（平均値）４．０以上５．０点以下
○：評価値（平均値）３．０以上４．０点未満
△：評価値（平均値）２．０以上３．０点未満
×：評価値（平均値）１．０以上２．０点未満 (Evaluation methods)
Each sample was used by a panelist (10 persons) and subjected to sensory evaluation (score) in five stages. Based on the average score, the following evaluation criteria were used.
(Score)
5: Very good 4: Excellent 3: Normal 2: Inferior 1: Very inferior (Evaluation criteria)
◎: Evaluation value (average value) 4.0 or more and 5.0 points or less ○: Evaluation value (average value) 3.0 or more and less than 4.0 points △: Evaluation value (average value) 2.0 or more and 3.0 points Less than x: Evaluation value (average value) 1.0 or more and less than 2.0 points
各試料をパネリスト（１０名）に使用してもらい、５段階の官能評価（スコア）した。そのスコア平均値により、下記評価基準で判定した。
（スコア）
５：非常に優れている
４：優れている
３：普通
２：劣る
１：非常に劣る
（評価基準）
◎：評価値（平均値）４．０以上５．０点以下
○：評価値（平均値）３．０以上４．０点未満
△：評価値（平均値）２．０以上３．０点未満
×：評価値（平均値）１．０以上２．０点未満 (Evaluation methods)
Each sample was used by a panelist (10 persons) and subjected to sensory evaluation (score) in five stages. Based on the average score, the following evaluation criteria were used.
(Score)
5: Very good 4: Excellent 3: Normal 2: Inferior 1: Very inferior (Evaluation criteria)
◎: Evaluation value (average value) 4.0 or more and 5.0 points or less ○: Evaluation value (average value) 3.0 or more and less than 4.0 points △: Evaluation value (average value) 2.0 or more and 3.0 points Less than x: Evaluation value (average value) 1.0 or more and less than 2.0 points
金属石鹸処理微粒子酸化チタンを配合した実施例１は、その他の粉末成分を配合した比較例１～７に比較して、とれ、発色及びフィット感の全ての項目において優れていた。
Example 1 in which metal soap-treated fine particle titanium oxide was blended was superior to Comparative Examples 1 to 7 in which other powder components were blended, and was excellent in all items of color development and fit.
以下に、本発明に係るメーキャップ化粧料の他の処方例を挙げる。これらの処方例の化粧料によっても前記実施例１と同様に良好な発色、フィット感及び使用性が得られた。
Hereinafter, other prescription examples of makeup cosmetics according to the present invention will be given. Also with the cosmetics of these formulation examples, good color development, fit and usability were obtained as in Example 1.
処方例１（アイシャドー）：
配合成分 配合量（質量％）
ワセリン ２
ジメチルポリシロキサン ２
メチルフェニルポリシロキサン ２
グリセリン ０．１
トリオクタノイン １
植物性スクワラン ０．５
セスキイソステアリン酸ソルビタン １
窒化ホウ素 ２
雲母チタン ４
金雲母 ４
合成金雲母 ０．１
セリサイト ２５
タルク 残余
マイカ ７
ミリスチン酸亜鉛 １
ステアリン酸アルミニウム ０．０１
無水ケイ酸 ４
フィトステロール ０．０１
酢酸ＤＬ－α－トコフェロール ０．０２
Ｄ－δ－トコフェロール ０．０２
アセチル化ヒアルロン酸ナトリウム ０．０２
パラオキシ安息香酸エステル ０．２
アルキルシラン処理酸化鉄 ９
ステアリン酸アルミ処理微粒子酸化チタン ３
合成ケイ酸ナトリウム／マグネシウム ０．１
香料 適量
リンゴ酸ジイソステアリル ５
トリイソステアリン ２ Formulation Example 1 (Eye Shadow):
Compounding ingredients Compounding amount (% by mass)
Vaseline 2
Dimethylpolysiloxane 2
Methylphenyl polysiloxane 2
Glycerin 0.1
Trioctanoin 1
Plant-based squalane 0.5
Sorbitan sesquiisostearate 1
Boron nitride 2
Mica titanium 4
Phlogopite 4
Synthetic phlogopite 0.1
Sericite 25
Talc Residual Mica 7
Zinc myristate 1
Aluminum stearate 0.01
Silicic anhydride 4
Phytosterol 0.01
DL-α-tocopherol acetate 0.02
D-δ-Tocopherol 0.02
Acetylated sodium hyaluronate 0.02
P-Hydroxybenzoate ester 0.2
Alkylsilane-treated iron oxide 9
Aluminum stearate treated fine particle titanium oxide 3
Synthetic sodium silicate / magnesium 0.1
Perfume proper amount diisostearyl malate 5
Triisostearin 2
配合成分 配合量（質量％）
ワセリン ２
ジメチルポリシロキサン ２
メチルフェニルポリシロキサン ２
グリセリン ０．１
トリオクタノイン １
植物性スクワラン ０．５
セスキイソステアリン酸ソルビタン １
窒化ホウ素 ２
雲母チタン ４
金雲母 ４
合成金雲母 ０．１
セリサイト ２５
タルク 残余
マイカ ７
ミリスチン酸亜鉛 １
ステアリン酸アルミニウム ０．０１
無水ケイ酸 ４
フィトステロール ０．０１
酢酸ＤＬ－α－トコフェロール ０．０２
Ｄ－δ－トコフェロール ０．０２
アセチル化ヒアルロン酸ナトリウム ０．０２
パラオキシ安息香酸エステル ０．２
アルキルシラン処理酸化鉄 ９
ステアリン酸アルミ処理微粒子酸化チタン ３
合成ケイ酸ナトリウム／マグネシウム ０．１
香料 適量
リンゴ酸ジイソステアリル ５
トリイソステアリン ２ Formulation Example 1 (Eye Shadow):
Compounding ingredients Compounding amount (% by mass)
Vaseline 2
Dimethylpolysiloxane 2
Methylphenyl polysiloxane 2
Glycerin 0.1
Trioctanoin 1
Plant-based squalane 0.5
Sorbitan sesquiisostearate 1
Boron nitride 2
Mica titanium 4
Phlogopite 4
Synthetic phlogopite 0.1
Sericite 25
Talc Residual Mica 7
Zinc myristate 1
Aluminum stearate 0.01
Silicic anhydride 4
Phytosterol 0.01
DL-α-tocopherol acetate 0.02
D-δ-Tocopherol 0.02
Acetylated sodium hyaluronate 0.02
P-Hydroxybenzoate ester 0.2
Alkylsilane-treated iron oxide 9
Aluminum stearate treated fine particle titanium oxide 3
Synthetic sodium silicate / magnesium 0.1
Perfume proper amount diisostearyl malate 5
Triisostearin 2
処方例２（アイシャドー）：
配合成分 配合量（質量％）
流動パラフィン ３
ジメチルポリシロキサン ３
マイカ ２０
タルク 残余
ステアリン酸アルミ処理微粒子酸化チタン ２
δ－トコフェロール 適量
パラオキシ安息香酸エステル ０．２
チタン酸コバルト ４
シリコーン処理酸化鉄 ４
ケイ酸アルミニウムマグネシウム １．５
香料 適量
セリサイト ２０
セスキイソステアリン酸ソルビタン ２
ミリスチン酸亜鉛 ５ Formulation Example 2 (Eye Shadow):
Compounding ingredients Compounding amount (% by mass)
Liquid paraffin 3
Dimethylpolysiloxane 3
Mica 20
Talc Residual aluminum stearate treated fine particles Titanium oxide 2
δ-tocopherol appropriate amount paraoxybenzoate 0.2
Cobalt titanate 4
Silicone-treated iron oxide 4
Aluminum magnesium silicate 1.5
Fragrance Appropriate Sericite 20
Sorbitan sesquiisostearate 2
Zinc myristate 5
配合成分 配合量（質量％）
流動パラフィン ３
ジメチルポリシロキサン ３
マイカ ２０
タルク 残余
ステアリン酸アルミ処理微粒子酸化チタン ２
δ－トコフェロール 適量
パラオキシ安息香酸エステル ０．２
チタン酸コバルト ４
シリコーン処理酸化鉄 ４
ケイ酸アルミニウムマグネシウム １．５
香料 適量
セリサイト ２０
セスキイソステアリン酸ソルビタン ２
ミリスチン酸亜鉛 ５ Formulation Example 2 (Eye Shadow):
Compounding ingredients Compounding amount (% by mass)
Liquid paraffin 3
Dimethylpolysiloxane 3
Mica 20
Talc Residual aluminum stearate treated fine particles Titanium oxide 2
δ-tocopherol appropriate amount paraoxybenzoate 0.2
Cobalt titanate 4
Silicone-treated iron oxide 4
Aluminum magnesium silicate 1.5
Fragrance Appropriate Sericite 20
Sorbitan sesquiisostearate 2
Zinc myristate 5
処方例３（頬紅）：
配合成分 配合量（質量％）
ベンガラ被覆雲母チタン ３０
タルク 残余
マイカ １５
δ－トコフェロール ０．０２
パラオキシ安息香酸エステル 適量
色素 適量
アルキル変性シリコーン処理酸化鉄 １
ステアリン酸アルミ処理微粒子酸化チタン ０．５
ケイ酸アルミニウムマグネシウム ３
香料 適量
架橋型シリコーン末 ５
ポリアクリル酸アルキル １０
金属石鹸処理タルク １５ Formulation example 3 (blusher):
Compounding ingredients Compounding amount (% by mass)
Bengala coated mica titanium 30
Talc Residual Mica 15
δ-tocopherol 0.02
Paraoxybenzoic acid ester Appropriate amount of dye Appropriate amount of alkyl-modified silicone-treated iron oxide
Aluminum stearate treated fine particle titanium oxide 0.5
Aluminum magnesium silicate 3
Perfume proper amount cross-linked silicone powder 5
Polyalkyl acrylate 10
Metal soap treated talc 15
配合成分 配合量（質量％）
ベンガラ被覆雲母チタン ３０
タルク 残余
マイカ １５
δ－トコフェロール ０．０２
パラオキシ安息香酸エステル 適量
色素 適量
アルキル変性シリコーン処理酸化鉄 １
ステアリン酸アルミ処理微粒子酸化チタン ０．５
ケイ酸アルミニウムマグネシウム ３
香料 適量
架橋型シリコーン末 ５
ポリアクリル酸アルキル １０
金属石鹸処理タルク １５ Formulation example 3 (blusher):
Compounding ingredients Compounding amount (% by mass)
Bengala coated mica titanium 30
Talc Residual Mica 15
δ-tocopherol 0.02
Paraoxybenzoic acid ester Appropriate amount of dye Appropriate amount of alkyl-modified silicone-treated iron oxide
Aluminum stearate treated fine particle titanium oxide 0.5
Aluminum magnesium silicate 3
Perfume proper amount cross-linked silicone powder 5
Polyalkyl acrylate 10
Metal soap treated talc 15
Claims (3)
- （Ａ）疎水化処理色材と、（Ｂ）金属石鹸処理微粒子酸化チタンとを配合し、湿式成型により製造されるメーキャップ化粧料。 A makeup cosmetic produced by wet molding, comprising (A) a hydrophobized colorant and (B) metal soap-treated fine particle titanium oxide.
- 前記（Ａ）疎水化処理色材が、シリコーン化合物又はフッ素化合物で処理された色材である、請求項１に記載の化粧料。 The cosmetic according to claim 1, wherein the (A) hydrophobic treatment color material is a color material treated with a silicone compound or a fluorine compound.
- 前記（Ｂ）金属石鹸処理微粒子酸化チタンが、炭素数が１２～１８の脂肪酸のカルシウム、マグネシウム、亜鉛、又はアルミニウム塩で処理した微粒子酸化チタンである、請求項１又は２に記載の化粧料。 The cosmetic according to claim 1 or 2, wherein the (B) metal soap-treated fine particle titanium oxide is a fine particle titanium oxide treated with a calcium, magnesium, zinc, or aluminum salt of a fatty acid having 12 to 18 carbon atoms.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011008569A JP2012149005A (en) | 2011-01-19 | 2011-01-19 | Makeup cosmetic |
| JP2011-008569 | 2011-01-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2012098765A1 true WO2012098765A1 (en) | 2012-07-26 |
Family
ID=46515402
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2011/077030 WO2012098765A1 (en) | 2011-01-19 | 2011-11-24 | Makeup cosmetic |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP2012149005A (en) |
| TW (1) | TW201231071A (en) |
| WO (1) | WO2012098765A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115052576A (en) * | 2020-02-28 | 2022-09-13 | 株式会社资生堂 | Fatty acid calcium salt particles and cosmetic |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPWO2022071143A1 (en) * | 2020-09-30 | 2022-04-07 |
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|---|---|---|---|---|
| JPS56108703A (en) * | 1980-01-29 | 1981-08-28 | Shiseido Co Ltd | Production of caked powder cosmetic in vessel |
| JP2001278743A (en) * | 2000-03-29 | 2001-10-10 | Shiseido Co Ltd | Cosmetics |
| JP2002060329A (en) * | 2000-08-16 | 2002-02-26 | Shiseido Co Ltd | Sunscreening cosmetic |
| JP2003012461A (en) * | 2001-07-05 | 2003-01-15 | Shiseido Co Ltd | Makeup cosmetic |
| JP2006199616A (en) * | 2005-01-20 | 2006-08-03 | Shiseido Co Ltd | Method and system for forming powder cosmetic and the resulting product |
| JP2008184399A (en) * | 2007-01-29 | 2008-08-14 | Shiseido Co Ltd | Powdery cosmetic |
| WO2009078486A1 (en) * | 2007-12-19 | 2009-06-25 | Shiseido Company Ltd. | Process for producing powdery cosmetic preparation |
| JP2009209139A (en) * | 2008-02-07 | 2009-09-17 | Shiseido Co Ltd | Solid powder cosmetic |
| WO2010119954A1 (en) * | 2009-04-16 | 2010-10-21 | 株式会社 資生堂 | Powdered solid cosmetic and manufacturing method therefor |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5559990B2 (en) * | 2009-06-05 | 2014-07-23 | 花王株式会社 | Method for producing solid powder cosmetic |
-
2011
- 2011-01-19 JP JP2011008569A patent/JP2012149005A/en active Pending
- 2011-11-24 WO PCT/JP2011/077030 patent/WO2012098765A1/en active Application Filing
- 2011-12-12 TW TW100145806A patent/TW201231071A/en unknown
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|---|---|---|---|---|
| JPS56108703A (en) * | 1980-01-29 | 1981-08-28 | Shiseido Co Ltd | Production of caked powder cosmetic in vessel |
| JP2001278743A (en) * | 2000-03-29 | 2001-10-10 | Shiseido Co Ltd | Cosmetics |
| JP2002060329A (en) * | 2000-08-16 | 2002-02-26 | Shiseido Co Ltd | Sunscreening cosmetic |
| JP2003012461A (en) * | 2001-07-05 | 2003-01-15 | Shiseido Co Ltd | Makeup cosmetic |
| JP2006199616A (en) * | 2005-01-20 | 2006-08-03 | Shiseido Co Ltd | Method and system for forming powder cosmetic and the resulting product |
| JP2008184399A (en) * | 2007-01-29 | 2008-08-14 | Shiseido Co Ltd | Powdery cosmetic |
| WO2009078486A1 (en) * | 2007-12-19 | 2009-06-25 | Shiseido Company Ltd. | Process for producing powdery cosmetic preparation |
| JP2009209139A (en) * | 2008-02-07 | 2009-09-17 | Shiseido Co Ltd | Solid powder cosmetic |
| WO2010119954A1 (en) * | 2009-04-16 | 2010-10-21 | 株式会社 資生堂 | Powdered solid cosmetic and manufacturing method therefor |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115052576A (en) * | 2020-02-28 | 2022-09-13 | 株式会社资生堂 | Fatty acid calcium salt particles and cosmetic |
Also Published As
| Publication number | Publication date |
|---|---|
| TW201231071A (en) | 2012-08-01 |
| JP2012149005A (en) | 2012-08-09 |
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