WO2012090580A1 - Composition désodorisante liquide pour produits textiles - Google Patents

Composition désodorisante liquide pour produits textiles Download PDF

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Publication number
WO2012090580A1
WO2012090580A1 PCT/JP2011/075052 JP2011075052W WO2012090580A1 WO 2012090580 A1 WO2012090580 A1 WO 2012090580A1 JP 2011075052 W JP2011075052 W JP 2011075052W WO 2012090580 A1 WO2012090580 A1 WO 2012090580A1
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group
liquid deodorant
deodorant composition
iii
composition
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PCT/JP2011/075052
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English (en)
Japanese (ja)
Inventor
洋子 浅沼
直行 江川
英史 小倉
昌平 藤村
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ライオン株式会社
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Priority to KR1020137019930A priority Critical patent/KR101922946B1/ko
Priority to MYPI2013002440A priority patent/MY161136A/en
Priority to PCT/JP2011/080171 priority patent/WO2012090989A1/fr
Priority to JP2012550964A priority patent/JP5735005B2/ja
Publication of WO2012090580A1 publication Critical patent/WO2012090580A1/fr

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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/005—Compositions containing perfumes; Compositions containing deodorants
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/01—Deodorant compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/14—Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D06M13/342—Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines

Definitions

  • the present invention relates to a liquid deodorant composition for fiber products and a liquid deodorant article for fiber products, which is excellent in deodorizing a composite odor such as tobacco odor, food odor and body odor attached to fibers.
  • Patent Documents 1 to 3 As a deodorizing technique, a technique using a metal complex of a metal ion and a chelating agent has been proposed.
  • the main purpose of this technology is to deodorize single or specific components, such as tobacco odor containing multiple malodorous components such as pyridine, nicotine and acetic acid, body odor containing oils and fatty acids such as sebum and sweat, It is not suitable for deodorizing complex odors such as excrement odors including hydrogen, methyl mercaptan and ammonia. Furthermore, since the deodorizing spray for home use has to consider damages such as discoloration and damage of fibers, it is difficult to use industrial techniques as they are (Patent Documents 4 and 5).
  • An object of the present invention is to provide a liquid deodorant composition for a textile product and a liquid deodorant article for a textile product, which are excellent in the effect of deodorizing the composite odor attached to the textile product.
  • a I represents an alkyl group, a sulfo group, an amino group, a hydroxyl group, a hydrogen atom or COOM I
  • M I may be the same as or different from each other, and each represents a hydrogen atom, an alkali metal, or an alkaline earth. 1 type selected from the group consisting of similar metals, cationic ammonium groups and alkanolamines, and m I and n I are each an integer of 0 to 2, provided that m I and n I are both 0 , A I is a methyl group.
  • X II-1 to X II-4 may be the same or different and are each independently a group consisting of a hydrogen atom, an alkali metal, an alkaline earth metal, a cationic ammonium group and an alkanolamine.
  • Q II represents a hydrogen atom or an alkyl group
  • R II represents a hydrogen atom or a hydroxyl group
  • n III represents an integer of 0 or 1.
  • R III is a linear or branched C8-C22 alkyl and alkenyl group
  • a III is H, a methyl group, or (CH 2 ) n III —COOX III
  • X III-1 is Each represents H, an alkali metal atom, an alkaline earth metal atom, an alkanolamine, or NH 4 .
  • n III represents any one of 1 to 3.
  • X IV represents a hydrogen atom, an alkali metal, or an alkaline earth metal.
  • n IV represents an integer of 1 or 2, and when n IV is 2, X IV may be the same or different.
  • the present invention also provides a liquid deodorizing article for textiles, which contains a liquid deodorant composition for textiles in a spray container.
  • the present invention it is possible to effectively deodorize complex odors such as tobacco odor, food odor and body odor adhering to the fiber. Even if the composition of the present invention is applied to a textile product, it does not cause discoloration such as a stain or cause fabric damage, and exhibits a high effect in a small amount. According to the present invention, a textile product can be easily deodorized even at home.
  • Divalent water-soluble metal salt Component is a salt of the above specific metal, specifically, water-soluble zinc salts such as zinc sulfate and zinc chloride; water-soluble copper such as copper sulfate and copper chloride Salts; water-soluble iron salts such as iron sulfate; and water-soluble manganese salts such as manganese chloride.
  • the component (A) includes these hydrates. From the viewpoint of deodorizing performance, a water-soluble zinc salt or a water-soluble copper salt is preferable. As the water-soluble zinc salt, zinc sulfate and zinc chloride are preferable.
  • a component can be used individually by 1 type or in combination of 2 or more types as appropriate. When using 2 or more types together, it is preferable that a zinc salt is included.
  • the “water-soluble metal salt” means a metal salt that dissolves 10 g or more in 1 liter of water at 25 ° C.
  • the content of the component (A) in the composition of the present invention is preferably 0.01 to 10% by mass, and more preferably 0.05 to 5% by mass.
  • component (A) when the component (A) is a hydrate, it means the blending amount as an anhydride. If the proportion of component (A) is less than 0.01% by mass, the deodorizing effect will be insufficient. If it exceeds 10% by mass, the storage stability of the composition deteriorates, and there is a high possibility that defects such as blotting and discoloration will occur in the target fiber.
  • the component (B) in the present invention is a compound represented by the following formulas (I) to (IV).
  • a component can be used individually by 1 type or in combination of 2 or more types as appropriate.
  • a I represents a linear or branched alkyl group having 8 to 22 carbon atoms, a sulfo group, an amino group, a hydroxyl group, a hydrogen atom, or COOM I.
  • a I , CH 3 , OH, H, and COOM I are preferable, CH 3 and H are more preferable, and CH 3 is particularly preferable.
  • M I may be the same or different from each other, and each represents one selected from the group consisting of a hydrogen atom, an alkali metal, an alkaline earth metal, a cationic ammonium group, and an alkanolamine.
  • an alkali metal sodium and potassium are preferable.
  • alkanolamine monoethanolamine, diethanolamine, and triethanolamine are preferable.
  • M I an alkali metal is preferable, and sodium is particularly preferable.
  • m I and n I are each an integer of 0-2.
  • m I is preferably 0 or 1.
  • n I is preferably 0 or 1. When both m I and n I are 0, A I is CH 3 .
  • MGDA methylglycine diacetate
  • ASDA aspartate diacetate
  • ISDA isoserine diacetate
  • ADAA ⁇ -alanine diacetate
  • SDA acetic acid
  • GLDA glutamic acid diacetate
  • salts thereof are preferable.
  • X II-1 to X II-4 may be the same or different and are each selected from the group consisting of a hydrogen atom, an alkali metal, an alkaline earth metal, a cationic ammonium group, and an alkanolamine.
  • an alkali metal sodium and potassium are preferable.
  • As the alkanolamine monoethanolamine, diethanolamine, and triethanolamine are preferable.
  • the M II, alkali metals are preferred, sodium being particularly preferred.
  • Q II represents a hydrogen atom or a linear or branched alkyl group having 8 to 22 carbon atoms.
  • R II represents a hydrogen atom or a hydroxyl group.
  • n II represents 0 or 1.
  • Preferred examples of the compound represented by the formula (II) include iminodisuccinic acid (IDS), hydroxyiminodisuccinic acid (HIDS), and salts thereof. Among them, IDS or a salt thereof is more preferable. preferable.
  • R III represents a linear or branched alkyl or alkenyl group having 8 to 22 carbon atoms, preferably 12 to 18 carbon atoms.
  • a III represents H, a methyl group or (CH 2 ) m III -COOX III .
  • a III is preferably (CH 2 ) m III -COOX III .
  • m III represents any number of 1 to 3.
  • X III represents H, an alkali metal, an alkaline earth metal, an alkanolamine or NH 4 .
  • sodium and potassium are preferable.
  • As the alkanolamine monoethanolamine, diethanolamine, and triethanolamine are preferable.
  • n III represents any one of 1 to 3.
  • the compound represented by the formula (III) include alkyl and alkenyl amino acetates such as sodium octylaminoacetate, sodium laurylaminoacetate, sodium myristylaminoacetate, sodium palmitylaminoacetate, sodium oleylaminoacetate; Alkyl and alkenyl aminopropionates such as sodium octylaminopropionate, sodium decylaminopropionate, sodium laurylaminopropionate, sodium myristylaminopropionate, sodium palmitylaminopropionate, sodium oleylaminopropionate; N-alkyl and alkenyl glycine salts such as sodium N-octylglycine, sodium N-decylglycine, sodium N-laurylglycine, sodium N-myristylglycine, sodium N-palmitylglycine, sodium N-oleylglycine, etc .; N-octy
  • alkyl and alkenylamino diacetates are preferable, among which decylaminodiacetic acid, laurylaminodiacetic acid, myristylaminodiacetic acid, palmitylaminodiacetic acid or salts thereof are preferable, and lauryl is particularly preferable. More preferred is aminodiacetic acid, myristylaminodiacetic acid, palmitylaminodiacetic acid or a salt thereof.
  • X IV represents a hydrogen atom, an alkali metal or an alkaline earth metal.
  • n IV represents 1 or 2, and when n IV is 2, X IV may be the same or different.
  • the substitution position of the (COOX IV ) n IV group is not particularly limited, but the ⁇ position is preferred.
  • a compound represented by the formula (I) and a compound represented by the formula (II) are particularly preferable, and MDGA, IDS and salts thereof are particularly preferable. MDGA and its salts are most preferred.
  • the amount of component (B) in the composition of the present invention exceeds 0% by mass, preferably 15% by mass or less, more preferably 10% by mass or less, and particularly preferably 5% by mass or less. , Preferably 0.05% by mass or more, more preferably 0.1% by mass or more.
  • the composition of the present invention has an odor that seems to be derived from the component (B). From the viewpoint of storage stability of odor, the pH (25 ° C.) of the composition is preferably 6.5 or less.
  • the amount of component (B) is preferably 3% or less, more preferably 1% or less, and still more preferably 0.5% or less.
  • the more the amount of component (B) increases the worse the odor of the composition over time.
  • the composition of the present invention can obtain a deodorizing effect superior to that of a conventional deodorant composition by using the component (A) and the component (B) in combination.
  • the blending molar ratio of the component (A) to the component (B) is expressed by (A) / (B), it is necessary from the aspect of deodorizing effect to be 0.01 to 6.
  • the ratio is preferably 0.05 to 2.5, more preferably 0.3 to 1, a further deodorizing effect can be obtained.
  • Water-soluble solvent As the water-soluble solvent used in the present invention, those generally used in liquid deodorant compositions for textiles can be used.
  • the “water-soluble solvent” as used herein refers to a solvent that is mixed with water at an arbitrary ratio and mixed transparently. Specifically, primary alcohols having 2 to 3 carbon atoms such as ethanol and isopropanol; glycols having 2 to 6 carbon atoms such as ethylene glycol, propylene glycol and dipropylene glycol; and carbon numbers such as glycerin and diethylene glycol monobutyl ether Examples thereof include 3 to 8 polyhydric alcohols.
  • Ethanol, glycerin, and diethylene glycol monobutyl ether are preferable from the viewpoint of the influence on the aroma of the liquid deodorant composition for textiles and the price.
  • the content of the water-soluble solvent is preferably 5 to 30% by mass and more preferably 10 to 20% by mass in the composition of the present invention. If the amount is less than this, it may take time to dry. If it is more than this, there is a possibility that the user will be exposed.
  • the liquid deodorant composition for textiles according to the present invention can be blended with the following optional components blended in a general liquid deodorant composition for textiles within a range not impairing the effects of the present invention.
  • a compound represented by the following formula (V) can be used as the quaternary ammonium compound.
  • Rs may be the same as or different from each other, and each of them may be H or having 1 to 14 carbon atoms, and may contain O or a benzene ring therebetween. Preferably, it represents a hydrocarbon group having 8 to 12 carbon atoms, preferably a linear or branched alkyl group or an alkenyl group.
  • X represents Cl, Br, CH 3 SO 4 or C 2 H 5 SO 4 . Examples of the compound represented by the formula (V) include didecyldimethylammonium chloride, stearyltrimethylammonium chloride, benzalkonium chloride, benzethonium chloride, and the like.
  • the amount of component (D) in the composition of the present invention is usually 0 to 20% by mass, preferably 0.01 to 20% by mass, more preferably 0.05 to 5% by mass. Even if it mixes more than this, an effect does not improve.
  • the mass ratio of (A) / (D) is usually 0 to 100, preferably 0.01 to 100, and more preferably 0.1 to 10. It is preferable to use both in such a ratio because the component (A) can efficiently penetrate into the fiber product.
  • Nonionic surfactant By including a nonionic surfactant, the dispersion stability of the deodorant composition for textiles of the present invention can be enhanced.
  • the nonionic surfactant that can be used in the present invention include polyoxyethylene alkyl ethers having an alkyl group or alkenyl group having 10 to 22 carbon atoms and an average addition mole number of oxyethylene groups of 10 to 100 moles, Polyoxyethylene fatty acid alkyl (C1-3) esters, polyoxyethylene alkylamines having an average addition mole number of oxyethylene groups of 10 to 100 moles, alkyl polyglucosides having an alkyl group or alkenyl group of 8 to 18 carbon atoms And hydrogenated castor oil having an average addition mole number of oxyethylene groups of 20 to 100 moles.
  • a polyoxyethylene alkyl ether having an alkyl group having 10 to 14 carbon atoms, an average addition mole number of oxyethylene groups of 5 to 20 moles, and an average addition mole number of oxyethylene groups of 30 to 50 moles Castor oil is preferred.
  • the blending amount of the nonionic surfactant in the liquid deodorant composition for textile products of the present invention is preferably 0.01 to 5% by mass, more preferably 0.1 to 3% by mass. Within this range, the dispersion stability of the liquid deodorant composition for textiles can be enhanced.
  • ingredients include chelating agents, anti-contamination agents, polymers, preservatives, antibacterial agents, antifungal agents, repellents, natural product extracts, dispersants, dyes, antioxidants, thickeners As long as it is highly safe and used for ordinary cleaning agents, such as a thickener and an ultraviolet absorber, any material may be used without any particular limitation.
  • the upper limit of the amount of the optional component in the present invention is preferably 5% by mass or less, more preferably 3% by mass or less.
  • Organic antibacterial and antifungal agents are used alone or in combination It can be used by mixing.
  • Organic fungicides and fungicides include alcohol, phenol, aldehyde, carboxylic acid, ester, ether, nitrile, peroxide / epoxy, halogen, pyridine / quinoline, triazine, Examples include isothiazolone, imidazole / thiazole, anilide, biguanide, disulfide, thiocarbamate, saccharide, tropolone, and organometallic.
  • the inorganic antibacterial and fungicides include metal oxides and silver.
  • an antibacterial agent or a disinfectant such as isopropylmethylphenol is preferably blended in the liquid deodorant composition in the range of 0.05 to 1% by mass.
  • a pH adjuster can be added to the deodorant composition.
  • the acid include inorganic acids such as hydrochloric acid and sulfuric acid, and carboxylic acids such as acetic acid and citric acid.
  • the alkali include alkali metal salts such as sodium hydroxide and alkanolamines such as triethanolamine.
  • a fragrance can be added to the liquid deodorant composition.
  • Any perfume normally used in the field of the present invention can be used, for example, a perfume composition containing a perfume component, a solvent, and a stabilizer as described in JP-A-2008-7872, and a liquid 0.005 to 5% by mass can be added to the deodorant composition. From the viewpoint of scenting effect and economy, it is preferable to blend 0.01 to 1% by mass.
  • a silicone compound can be blended in the liquid deodorant composition to obtain a “wrinkle removing deodorant composition” that reduces the deodorizing effect and wrinkles such as suits.
  • Silicone compounds include dimethyl silicone, polyether modified silicone, methylphenyl silicone, alkyl modified silicone, higher fatty acid modified silicone, methyl hydrogen silicone, fluorine modified silicone, epoxy modified silicone, carboxy modified silicone, carbinol modified silicone and amino modified. Examples include silicone.
  • a polyether-modified silicone is preferable as the silicone compound used, and among them, a polyether-modified silicone having an HLB of 13 or less, preferably 10 or less, more preferably 7 or less is preferable from the viewpoint of reducing wearing wrinkles. .
  • silicone compounds such as SH3775C and SH3772C manufactured by Toray Dow Corning are suitable. These silicone compounds can be blended in an amount of 0.01 to 5% by mass in the liquid deodorant composition. From the viewpoint of wrinkle reduction effect and economic efficiency, it is preferable to add 0.1 to 1% by mass.
  • the liquid deodorant composition for textiles of the present invention can be produced by a conventional method.
  • (C) water-soluble solvent if necessary, add (D) optional components such as quaternary ammonium compounds, silicone compounds, nonionic surfactants, etc., add water to some extent, then add component (A) Add ingredients (B) and mix.
  • a pH adjuster such as sodium hydroxide, hydrochloric acid, sulfuric acid, etc., and adjust the pH while stirring the mixture with a stirrer with a pH meter (for example, model number MP230 manufactured by Mettler Toledo). It can manufacture by adding water.
  • the pH of the composition of the present invention is not particularly limited. However, in order to ensure the storage stability of the liquid deodorant composition and the target odor control effect, it is preferable to adjust the pH of the liquid deodorant composition to a certain range using the pH adjustor.
  • the lower limit is preferably 3 or more
  • the upper limit is preferably 8 or less, more preferably 6.5 or less.
  • the lower limit is preferably 4 or more, more preferably 5.5 or more
  • the upper limit is preferably 9 or less, it is possible to enhance the deodorizing effect of pillow cover odor, body odor and the like.
  • the pH of the composition is preferably 6.5 or less, and more preferably 5 or less.
  • the appearance of the composition may change due to storage, but the reason is not limited by any theory, but the A component / B component It is conceivable that the greater the molar ratio of 1, the greater the amount of the component A in the composition in the ionic state in the composition, and the formation of a water-insoluble compound over time. In addition, the odor may change due to storage, but the reason is not limited by any theory, but it is conceivable that the B component is altered by high pH.
  • the viscosity of the liquid deodorant composition for textiles of the present invention is preferably 10 mPa ⁇ s or less. When used in a spray container, it is more preferably 5 mPa ⁇ s or less.
  • the viscosity shown here is a numerical value when the stock solution is measured at 25 ° C. using a B-type viscometer (manufactured by Tokimec).
  • the method of using the liquid deodorant composition of the present invention for a textile product is not particularly limited.
  • the fiber product may be dipped in the composition and then air-dried, or the composition may be stored in a spray container and sprayed with the composition on the fiber product and then air-dried.
  • the composition is stored in a spray container, and the textile product.
  • the method of spraying and using is preferable.
  • Examples of spray containers include aerosol spray containers, trigger spray containers (direct pressure type or accumulator type), dispenser spray containers, and the like.
  • Examples of the aerosol spray container include those described in JP-A-9-3441 and JP-A-9-58765.
  • Examples of the propellant include LPG (liquefied propane gas), DME (dimethyl ether), carbon dioxide gas, nitrogen gas, and the like. These may be used alone or in combination of two or more.
  • Examples of the trigger spray container include those described in JP-A-9-268473, JP-A-9-256272, JP-A-10-76196, and the like.
  • Examples of the dispenser spray container include those described in JP-A-9-256272.
  • the amount of spray when the article of the present invention is used by spraying on the target textile product is not particularly limited because it depends on the strength of the attached odor, but the lower limit is preferable with respect to the mass of the textile product. Is 5% by mass or more, more preferably 10% by mass or more, further preferably 20% by mass or more, and the upper limit is preferably 100% by mass or less, more preferably 80% by mass or less, and further preferably 50% by mass or less. . It is preferable for the spray amount to be within this range since it is excellent in deodorizing effect and economy.
  • the liquid deodorant composition of the present invention can be stored in a plastic container.
  • the plastic container include a bottle container and a standing pouch for refilling.
  • the standing pouch include those described in Japanese Patent Application Laid-Open No. 2000-72181.
  • the material is a double layer of 100 to 250 ⁇ m linear low density polyethylene for the inner layer and 15 to 30 ⁇ m stretched nylon for the outer layer. From the viewpoint of storage stability, a standing pouch having a structure or a three-layer structure in which 15 ⁇ m stretched nylon is an intermediate layer and 15 ⁇ m stretched nylon is an outer layer is preferable.
  • the material of the target textile product is not particularly limited.
  • natural fibers such as cotton, wool and hemp
  • synthetic fibers such as polyester, nylon and acrylic
  • semi-synthetic fibers such as acetate, rayon, tencel and polynosic.
  • blended products, blended fabrics, blended products of these various fibers, etc., and among them the effect of the composition of the present invention is remarkably exhibited in wool and its blended products that are difficult to maintain regularly. Is done.
  • A Component A-1: Zinc sulfate (II) (manufactured by Kanto Chemical Co., Inc.)
  • A-2 Copper sulfate pentahydrate (manufactured by Kanto Chemical Co., Inc.)
  • A-5 Aluminum sulfate (III)
  • B Component B-1: Trisodium methylglycine diacetate “MGDA” (manufactured by BASF)
  • B-2 2,2'-Iminodisuccinic acid tetrasodium salt (LANXESS)
  • B-4 2,3-pyridinedicarboxylic anhydride (ACR)
  • B-5 Ethylenediaminetetraacetic acid “EDTA” (manufactured by Kanto Chemical Co., Inc.)
  • B-6 Diethylenetriamine “DETA”: (manufactured by Tokyo Chemical Industry Co., Ltd.)
  • E Common component
  • E-1 Polyoxyethylene hydrogenated castor oil (HC40: Japanese emulsion): 0.5%
  • E-2 Polyether-modified silicone (same as used in E-1): 0.5%
  • F-1 Fragrance composition a-1-1 described in Examples of JP-A-2008-7872 F-2 to F-4: See Table 4
  • the intensity of tobacco odor was scored according to the evaluation standard A.
  • the evaluation was performed by sensory evaluation of the intensity of tobacco odor remaining on the cloth by 10 panelists according to the following criteria, and the average value was described in Examples or Comparative Examples according to Evaluation Criteria B.
  • ⁇ Method for evaluating discoloration of target clothing Put a wool top milled cloth (30cm x 30cm, gray) on a vertically standing acrylic board (40cm x 50cm) with clothespins, and dispense the dispenser pump spray (style guard wrinkle) The odor was sprayed 3 times on the same part using a clean spray (manufactured by Lion Co., Ltd.) at a distance of 20 cm from the test cloth. After drying for 2 hours as it was, the color change such as discoloration of the sprayed part and ring stain was judged visually.
  • ⁇ Evaluation criteria C> ⁇ : No change ⁇ : Slightly discolored ⁇ : Slightly discolored ⁇ : Fairly discolored ⁇ : Clearly discolored ⁇ , ⁇ , ⁇ pass.
  • ⁇ Pillow cover deodorant evaluation method> A cotton cloth (10 cm x 10 cm, Kanakin No. 3, manufactured by Japan Standards Association) was sewed on a pillow and used as a test cloth by men in their 30s and 40s for a week. 1 g of the composition described in the examples or comparative examples was sprayed uniformly onto the test cloth using a dispenser pump spray (style guard cleansing wrinkles and odors, manufactured by Lion Co., Ltd.). After standing for 10 minutes as it was, the strength of the odor of the pillow was scored according to the evaluation standard A. The evaluation was performed by sensory evaluation of the intensity of bad odor remaining on the cloth with 10 panelists according to the following criteria, and the average value was described in Examples or Comparative Examples according to Evaluation Criteria B.
  • ⁇ Toilet mat deodorant evaluation method 10 g of urine collected from 5 males in their 20s to 40s was evenly applied to a toilet mat (65cm x 65cm, good dry D Nature (white), manufactured by Oka Corporation) and left at room temperature for 3 days This was used as a test cloth. 1 g of the composition described in Examples or Comparative Examples was sprayed uniformly on the above-mentioned test cloth 10 cm ⁇ 10 cm using a dispenser pump spray (style guard wrinkle and odor clean spray, manufactured by Lion Co., Ltd.). After leaving for 10 minutes as it was, the odor strength of the toilet mat was scored according to Evaluation A. The evaluation was performed by sensory evaluation of the intensity of malodor remaining on the tray mat by 10 panelists according to the following criteria, and the average value was described in Examples or Comparative Examples according to Evaluation Criteria B.

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  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Epidemiology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

La présente invention concerne une composition désodorisante liquide pour produits textiles, ladite composition incluant : (A) du sulfate de zinc ou du sulfate de cuivre ; (B) de la méthylglycine-acide diacétique, de l'acide iminobissuccinique ou l'un de leurs sels ; et (C) un solvant hydrosoluble ; où (A)/(B) = 0,01-6 (rapport molaire). La composition désodorisante liquide pour produits textiles présente un excellent effet désodorisant vis-à-vis des odeurs complexes imprégnées dans les produits textiles.
PCT/JP2011/075052 2010-12-27 2011-10-31 Composition désodorisante liquide pour produits textiles WO2012090580A1 (fr)

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KR1020137019930A KR101922946B1 (ko) 2010-12-27 2011-12-27 섬유 제품용 액체 소취제 조성물
MYPI2013002440A MY161136A (en) 2010-12-27 2011-12-27 Liquid deodorant composition for textile products
PCT/JP2011/080171 WO2012090989A1 (fr) 2010-12-27 2011-12-27 Composition désodorisante liquide pour produits textiles
JP2012550964A JP5735005B2 (ja) 2010-12-27 2011-12-27 繊維製品用液体消臭剤組成物

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022065409A1 (fr) * 2020-09-26 2022-03-31 株式会社日本抗菌総合研究所 Réducteur de composé soufré volatil, liquide réducteur et procédé de réduction d'un composé soufré volatil
WO2022230617A1 (fr) 2021-04-27 2022-11-03 ダイキン工業株式会社 Dispersion
WO2023068308A1 (fr) 2021-10-20 2023-04-27 ダイキン工業株式会社 Composition hydrofuge
WO2024101396A1 (fr) 2022-11-09 2024-05-16 ダイキン工業株式会社 Agent répulsif

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20140076745A (ko) * 2012-12-13 2014-06-23 씨제이라이온 주식회사 액체세제 조성물
JP6183998B2 (ja) * 2013-07-09 2017-08-23 ライオン株式会社 液体消臭剤
JP6251911B2 (ja) * 2013-11-25 2017-12-27 ライオン株式会社 消臭剤組成物
JP6519080B2 (ja) * 2015-06-22 2019-05-29 ライオン株式会社 繊維製品用抗ウイルス組成物
JP2017197884A (ja) * 2016-04-28 2017-11-02 住江織物株式会社 優れた消臭抗菌性能を有する衛生用品用繊維布帛
JP6885679B2 (ja) * 2016-05-30 2021-06-16 ライオン株式会社 繊維処理剤組成物
JP2019033866A (ja) * 2017-08-14 2019-03-07 株式会社バイオシールドサイエンス 二価鉄系消臭抗菌剤
JP2021107591A (ja) 2019-12-27 2021-07-29 ライオン株式会社 液体柔軟剤組成物

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001302415A (ja) * 2000-04-28 2001-10-31 Mitsubishi Rayon Co Ltd 抗菌剤組成物
JP2006325669A (ja) * 2005-05-23 2006-12-07 Kao Corp 液体消臭剤組成物
WO2009078459A1 (fr) * 2007-12-19 2009-06-25 Lion Corporation Catalyseur d'oxydation pour le blanchiment et composition de blanchiment le contenant
JP2009155292A (ja) * 2007-12-27 2009-07-16 Lion Corp 殺菌・除菌用組成物

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3449533B2 (ja) * 1998-12-18 2003-09-22 花王株式会社 消臭剤組成物
JP2003096667A (ja) * 2001-09-27 2003-04-03 Lion Corp 繊維用消臭抗菌シワ除去剤組成物
US8318806B2 (en) * 2007-10-03 2012-11-27 Zorbx Inc. Deodorizing composition and method of forming thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001302415A (ja) * 2000-04-28 2001-10-31 Mitsubishi Rayon Co Ltd 抗菌剤組成物
JP2006325669A (ja) * 2005-05-23 2006-12-07 Kao Corp 液体消臭剤組成物
WO2009078459A1 (fr) * 2007-12-19 2009-06-25 Lion Corporation Catalyseur d'oxydation pour le blanchiment et composition de blanchiment le contenant
JP2009155292A (ja) * 2007-12-27 2009-07-16 Lion Corp 殺菌・除菌用組成物

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022065409A1 (fr) * 2020-09-26 2022-03-31 株式会社日本抗菌総合研究所 Réducteur de composé soufré volatil, liquide réducteur et procédé de réduction d'un composé soufré volatil
WO2022230617A1 (fr) 2021-04-27 2022-11-03 ダイキン工業株式会社 Dispersion
WO2023068308A1 (fr) 2021-10-20 2023-04-27 ダイキン工業株式会社 Composition hydrofuge
WO2024101396A1 (fr) 2022-11-09 2024-05-16 ダイキン工業株式会社 Agent répulsif

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KR20140022373A (ko) 2014-02-24
WO2012090989A1 (fr) 2012-07-05
MY161136A (en) 2017-04-14
JP5735005B2 (ja) 2015-06-17
JPWO2012090989A1 (ja) 2014-06-05
KR101922946B1 (ko) 2018-11-28

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