WO2012089298A3 - Hydroxylgruppen und estergruppen tragende polymere und verfahren zu ihrer herstellung - Google Patents

Hydroxylgruppen und estergruppen tragende polymere und verfahren zu ihrer herstellung Download PDF

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Publication number
WO2012089298A3
WO2012089298A3 PCT/EP2011/006174 EP2011006174W WO2012089298A3 WO 2012089298 A3 WO2012089298 A3 WO 2012089298A3 EP 2011006174 W EP2011006174 W EP 2011006174W WO 2012089298 A3 WO2012089298 A3 WO 2012089298A3
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WIPO (PCT)
Prior art keywords
group
production
formula
ester
structural units
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PCT/EP2011/006174
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English (en)
French (fr)
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WO2012089298A2 (de
Inventor
Matthias Krull
Roman MORSCHHÄUSER
Hans Jürgen SCHOLZ
Jochen Stock
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Clariant International Ltd
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Priority to JP2013546599A priority Critical patent/JP2014504654A/ja
Priority to US13/977,326 priority patent/US9221938B2/en
Priority to CN201180060563.4A priority patent/CN103443134B/zh
Priority to BR112013016852A priority patent/BR112013016852A2/pt
Priority to EP11796922.0A priority patent/EP2658881A2/de
Priority to KR1020137016843A priority patent/KR20140012040A/ko
Publication of WO2012089298A2 publication Critical patent/WO2012089298A2/de
Publication of WO2012089298A3 publication Critical patent/WO2012089298A3/de

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
    • B01J19/122—Incoherent waves
    • B01J19/126—Microwaves
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F216/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an alcohol radical
    • C08F216/04—Acyclic compounds
    • C08F216/06—Polyvinyl alcohol ; Vinyl alcohol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F16/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F16/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an alcohol radical
    • C08F16/04—Acyclic compounds
    • C08F16/06—Polyvinyl alcohol ; Vinyl alcohol
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/14—Esterification
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
    • C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B6/00—Heating by electric, magnetic or electromagnetic fields
    • H05B6/64—Heating using microwaves
    • H05B6/80—Apparatus for specific applications
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B6/00—Heating by electric, magnetic or electromagnetic fields
    • H05B6/64—Heating using microwaves
    • H05B6/80—Apparatus for specific applications
    • H05B6/806—Apparatus for specific applications for laboratory use
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0873—Materials to be treated
    • B01J2219/0881—Two or more materials
    • B01J2219/0884—Gas-liquid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0873—Materials to be treated
    • B01J2219/0881—Two or more materials
    • B01J2219/0888—Liquid-liquid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0873—Materials to be treated
    • B01J2219/0892—Materials to be treated involving catalytically active material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/12—Processes employing electromagnetic waves
    • B01J2219/1203—Incoherent waves
    • B01J2219/1206—Microwaves
    • B01J2219/1209—Features relating to the reactor or vessel
    • B01J2219/1212—Arrangements of the reactor or the reactors
    • B01J2219/1215—Single reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/12—Processes employing electromagnetic waves
    • B01J2219/1203—Incoherent waves
    • B01J2219/1206—Microwaves
    • B01J2219/1209—Features relating to the reactor or vessel
    • B01J2219/1221—Features relating to the reactor or vessel the reactor per se
    • B01J2219/1224—Form of the reactor
    • B01J2219/1227—Reactors comprising tubes with open ends
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/12—Processes employing electromagnetic waves
    • B01J2219/1203—Incoherent waves
    • B01J2219/1206—Microwaves
    • B01J2219/1287—Features relating to the microwave source
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/20—Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Electromagnetism (AREA)
  • Physics & Mathematics (AREA)
  • General Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Toxicology (AREA)
  • Clinical Laboratory Science (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

Gegenstand der Erfindung sind Ester Hydroxylgruppen tragender Polymere, enthaltend repetitierende Struktureinheiten der Formeln (I) und (II) in blockweiser, alternierender oder statistischer Abfolge D für eine direkte Bindung zwischen Polymerrückgrat und Hydroxylgruppe, eine C1-bis C6-Alkylengruppe, eine C5- bis C12-Arylengruppe, eine Oxyalkylengruppe der Formel -O-R2-, eine Estergruppe der Formel -C(O)-O-R2- oder eine Amidgruppe der Formel -C(O)-N(R3)R2-, E für einen Kohlenwasserstoffrest mit 1 bis 50 C-Atomen R2 für einen C2- bis C10-Alkylenrest, R3 für Wasserstoff oder einen C1- bis C10-Alkylrest, der Substituenten tragen kann, k für eine Zahl zwischen 1 und 1.000, n für eine Zahl von 0 bis 4999, m für eine Zahl von 1 bis 5000, n+m für eine Zahl von 10 bis 5000 stehen, mit der Maßgabe, dass a) der molare Anteil der Struktureinheiten (I) am Polymer zwischen 0 und 99,9 mol-%, und b) der molare Anteil der Struktureinheiten (II) am Polymer zwischen 0,1 und 100 mol-% der repetitierenden Einheiten beträgt, und ein Verfahren zu Ihrer Herstellung mittels Einsatz von Mikrowellen.
PCT/EP2011/006174 2010-12-30 2011-12-08 Hydroxylgruppen und estergruppen tragende polymere und verfahren zu ihrer herstellung WO2012089298A2 (de)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP2013546599A JP2014504654A (ja) 2010-12-30 2011-12-08 ヒドロキシル基およびエステル基担持ポリマー、ならびにその製造方法
US13/977,326 US9221938B2 (en) 2010-12-30 2011-12-08 Polymers carrying hydroxyl groups and ester groups and method for the production thereof
CN201180060563.4A CN103443134B (zh) 2010-12-30 2011-12-08 制备带有羟基和酯基团的聚合物的方法
BR112013016852A BR112013016852A2 (pt) 2010-12-30 2011-12-08 processo para a produção de polímeros carregando grupos hidroxila e grupos éster
EP11796922.0A EP2658881A2 (de) 2010-12-30 2011-12-08 Hydroxylgruppen und estergruppen tragende polymere und verfahren zu ihrer herstellung
KR1020137016843A KR20140012040A (ko) 2010-12-30 2011-12-08 하이드록실 그룹 및 에스테르 그룹을 갖는 중합체의 제조 방법

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102010056564A DE102010056564A1 (de) 2010-12-30 2010-12-30 Hydroxylgruppen und Estergruppen tragende Polymere und Verfahren zu ihrer Herstellung
DE102010056564.4 2010-12-30

Publications (2)

Publication Number Publication Date
WO2012089298A2 WO2012089298A2 (de) 2012-07-05
WO2012089298A3 true WO2012089298A3 (de) 2012-09-13

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Country Status (8)

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US (1) US9221938B2 (de)
EP (1) EP2658881A2 (de)
JP (1) JP2014504654A (de)
KR (1) KR20140012040A (de)
CN (1) CN103443134B (de)
BR (1) BR112013016852A2 (de)
DE (1) DE102010056564A1 (de)
WO (1) WO2012089298A2 (de)

Families Citing this family (9)

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Publication number Priority date Publication date Assignee Title
DE102006047617B4 (de) * 2006-10-09 2008-11-27 Clariant International Limited Verfahren zur Herstellung basischer (Meth)acrylamide
DE102009042523B4 (de) 2009-09-22 2012-02-16 Clariant International Ltd. Vorrichtung und Verfahren zur kontinuierlichen Durchführung heterogen katalysierter chemischer Reaktionen bei hohen Temperaturen
DE102009042522A1 (de) 2009-09-22 2011-04-07 Clariant International Ltd. Kontinuierliches Umesterungsverfahren
DE102010056565A1 (de) 2010-12-30 2012-07-05 Clariant International Ltd. Verfahren zur Modifizierung Hydroxylgruppen tragender Polymere
WO2016167323A1 (ja) * 2015-04-17 2016-10-20 Jsr株式会社 立体造形物の製造方法
KR101704563B1 (ko) * 2015-10-12 2017-02-08 한국화학연구원 락타이드 정제공정을 이용한 락타이드 제조방법 및 제조장치
EP3456747B1 (de) * 2016-05-09 2020-12-09 Tokushima University Verfahren zur herstellung eines vinylalkohol-vinylacetat-copolymers
CN113121815B (zh) * 2019-12-30 2022-06-14 江苏苏博特新材料股份有限公司 一种耐粘土型膦酸基超塑化剂及其制备方法
JPWO2023033142A1 (de) * 2021-09-06 2023-03-09

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WO2012089298A2 (de) 2012-07-05
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