WO2012089300A3 - Hydroxylgruppen und estergruppen tragende polymere und verfahren zu ihrer herstellung - Google Patents

Hydroxylgruppen und estergruppen tragende polymere und verfahren zu ihrer herstellung Download PDF

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Publication number
WO2012089300A3
WO2012089300A3 PCT/EP2011/006176 EP2011006176W WO2012089300A3 WO 2012089300 A3 WO2012089300 A3 WO 2012089300A3 EP 2011006176 W EP2011006176 W EP 2011006176W WO 2012089300 A3 WO2012089300 A3 WO 2012089300A3
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WO
WIPO (PCT)
Prior art keywords
group
polymers
formula
atoms
hydroxyl groups
Prior art date
Application number
PCT/EP2011/006176
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English (en)
French (fr)
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WO2012089300A2 (de
Inventor
Matthias Krull
Roman MORSCHHÄUSER
Hans Jürgen SCHOLZ
Jochen Stock
Original Assignee
Clariant International Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BR112013016864A priority Critical patent/BR112013016864A2/pt
Application filed by Clariant International Ltd filed Critical Clariant International Ltd
Priority to KR1020137016863A priority patent/KR20140009272A/ko
Priority to EP11794410.8A priority patent/EP2658880A2/de
Priority to JP2013546601A priority patent/JP2014504656A/ja
Priority to CN201180059243.7A priority patent/CN103492427A/zh
Priority to US13/977,468 priority patent/US20130289206A1/en
Publication of WO2012089300A2 publication Critical patent/WO2012089300A2/de
Publication of WO2012089300A3 publication Critical patent/WO2012089300A3/de

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02Esters of monocarboxylic acids
    • C08F218/04Vinyl esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F16/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F16/02Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an alcohol radical
    • C08F16/04Acyclic compounds
    • C08F16/08Allyl alcohol
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/12Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F18/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F18/02Esters of monocarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/14Esterification
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G81/00Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
    • C08G81/02Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G81/00Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
    • C08G81/02Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C08G81/024Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G
    • C08G81/025Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G containing polyether sequences
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B6/00Heating by electric, magnetic or electromagnetic fields
    • H05B6/64Heating using microwaves
    • H05B6/80Apparatus for specific applications

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Manufacturing & Machinery (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyethers (AREA)

Abstract

Gegenstand der Erfindung sind Ester Hydroxylgruppen tragender Polymere, enthaltend repetitierende Struktureinheiten der Formeln (I) und (II) in blockweiser, alternierender oder statistischer Abfolge (I), (II) worin D für eine direkte Bindung zwischen Polymerrückgrat und Hydroxylgruppe, eine C-1-bis C6-Alkylengruppe, eine C5- bis C12-Arylengruppe, eine Oxyalkylengruppe der Formel -O-R2-, eine Estergruppe der Formel -C(O)-O-R2- oder eine Amidgruppe der Formel -C(O)-N(R3)R2-, E für einen Kohlenwasserstoffrest mit 1 bis 10 C-Atomen R1 für Wasserstoff, einen Kohlenwasserstoffrest mit 1 bis 50 C-Atomen oder einen Acylrest der Formel -C(O)-R4 R2 für einen C2- bis C10-Alkylenrest, R3 für Wasserstoff oder einen C1- bis C10-Alkylrest, der Substituenten tragen kann, R4 für einen Kohlenwasserstoffrest mit 1 bis 50 C-Atomen, A für einen C2- bis C10-Alkylenrest, k für eine Zahl zwischen 1 und 100, n für eine Zahl von 0 bis 4999, m für eine Zahl von 1 bis 5000, n+m für eine Zahl von 10 bis 5000 stehen, mit der Maßgabe, dass a) der molare Anteil der Struktureinheiten (I) am Polymer zwischen 0 und 99,9 mol-%, und b) der molare Anteil der Struktureinheiten (II) am Polymer zwischen 0,1 und 100 mol-% der repetitierenden Einheiten beträgt, und ein Verfahren zu Ihrer Herstellung durch Bestrahlung einer Reaktionsmischung aus Hydroxylgruppen enthaltenden Polymeren und Ethercarbonsäuren mit Mikrowellen.
PCT/EP2011/006176 2010-12-30 2011-12-08 Hydroxylgruppen und estergruppen tragende polymere und verfahren zu ihrer herstellung WO2012089300A2 (de)

Priority Applications (6)

Application Number Priority Date Filing Date Title
BR112013016864A BR112013016864A2 (pt) 2010-12-30 2011-11-08 polímeros portadores de grupos hidroxila e grupos éster e processo para a sua produção
KR1020137016863A KR20140009272A (ko) 2010-12-30 2011-12-08 하이드록실 그룹 및 에스테르 그룹을 포함하는 중합체 및 이의 제조 방법
EP11794410.8A EP2658880A2 (de) 2010-12-30 2011-12-08 Hydroxylgruppen und estergruppen tragende polymere und verfahren zu ihrer herstellung
JP2013546601A JP2014504656A (ja) 2010-12-30 2011-12-08 ヒドロキシル基およびエステル基担持ポリマー、ならびにその製造方法
CN201180059243.7A CN103492427A (zh) 2010-12-30 2011-12-08 带有羟基和酯基团的聚合物及其制备方法
US13/977,468 US20130289206A1 (en) 2010-12-30 2011-12-08 Polymers Comprising Hydroxyl Groups And Ester Groups And Method For The Production Thereof

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102010056578.4 2010-12-30
DE102010056578A DE102010056578A1 (de) 2010-12-30 2010-12-30 Hydroxylgruppen und Estergruppen tragende Polymere und Verfahren zu ihrer Herstellung

Publications (2)

Publication Number Publication Date
WO2012089300A2 WO2012089300A2 (de) 2012-07-05
WO2012089300A3 true WO2012089300A3 (de) 2012-09-27

Family

ID=45319060

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2011/006176 WO2012089300A2 (de) 2010-12-30 2011-12-08 Hydroxylgruppen und estergruppen tragende polymere und verfahren zu ihrer herstellung

Country Status (8)

Country Link
US (1) US20130289206A1 (de)
EP (1) EP2658880A2 (de)
JP (1) JP2014504656A (de)
KR (1) KR20140009272A (de)
CN (1) CN103492427A (de)
BR (1) BR112013016864A2 (de)
DE (1) DE102010056578A1 (de)
WO (1) WO2012089300A2 (de)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102006047617B4 (de) * 2006-10-09 2008-11-27 Clariant International Limited Verfahren zur Herstellung basischer (Meth)acrylamide
DE102008017216B4 (de) * 2008-04-04 2013-08-14 Clariant International Ltd. Kontinuierliches Verfahren zur Herstellung von Fettsäureamiden
DE102009031059A1 (de) 2009-06-30 2011-01-05 Clariant International Ltd. Vorrichtung zur kontinuierlichen Durchführung chemischer Reaktionen bei hohen Temperaturen
DE102009042523B4 (de) 2009-09-22 2012-02-16 Clariant International Ltd. Vorrichtung und Verfahren zur kontinuierlichen Durchführung heterogen katalysierter chemischer Reaktionen bei hohen Temperaturen
DE102009042522A1 (de) 2009-09-22 2011-04-07 Clariant International Ltd. Kontinuierliches Umesterungsverfahren
DE102010056564A1 (de) 2010-12-30 2012-07-05 Clariant International Limited Hydroxylgruppen und Estergruppen tragende Polymere und Verfahren zu ihrer Herstellung
DE102010056565A1 (de) 2010-12-30 2012-07-05 Clariant International Ltd. Verfahren zur Modifizierung Hydroxylgruppen tragender Polymere
CN109642162B (zh) * 2016-09-05 2022-12-09 默克专利股份有限公司 基于官能化聚乙烯醇的uv可固化附着力促进剂

Citations (3)

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WO1998039370A1 (en) * 1997-03-07 1998-09-11 Playtex Products, Inc. Improved polyvinyl alcohol compound
US5830953A (en) * 1996-03-26 1998-11-03 Fuji Photo Film Co., Ltd. Process for producing ester-substituted polyvinyl alcohol and thin film using the same
WO2003090669A2 (fr) * 2002-04-25 2003-11-06 Aldivia S.A. Procedes de transesterification, esterification, interesterification, par chauffage dielectrique

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US2601561A (en) 1949-05-05 1952-06-24 Hercules Powder Co Ltd Synthetic drying oils from polyvinyl alcohol and method of production
JPH022848A (ja) * 1987-11-06 1990-01-08 Asahi Chem Ind Co Ltd 改良された再生セルロース膜及びその製造法
JP2543597B2 (ja) * 1989-08-31 1996-10-16 ユニ・チャーム株式会社 開孔を有する複合不織布の製造方法
JPH0545613A (ja) * 1991-08-15 1993-02-26 Asahi Chem Ind Co Ltd 耐汚染性の改良されたコンタクトレンズ及びその製造方法
US6175037B1 (en) * 1998-10-09 2001-01-16 Ucb, S.A. Process for the preparation of (meth)acrylate esters and polyester (meth)acrylates using microwave energy as a heating source
JP2000162601A (ja) * 1998-11-27 2000-06-16 Fuji Photo Film Co Ltd 配向膜形成材料層付き長尺可撓性シート
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JP5300014B2 (ja) * 2009-03-10 2013-09-25 独立行政法人産業技術総合研究所 流体へのマイクロ波連続照射方法及び装置

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5830953A (en) * 1996-03-26 1998-11-03 Fuji Photo Film Co., Ltd. Process for producing ester-substituted polyvinyl alcohol and thin film using the same
WO1998039370A1 (en) * 1997-03-07 1998-09-11 Playtex Products, Inc. Improved polyvinyl alcohol compound
WO2003090669A2 (fr) * 2002-04-25 2003-11-06 Aldivia S.A. Procedes de transesterification, esterification, interesterification, par chauffage dielectrique

Non-Patent Citations (1)

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Title
See also references of EP2658880A2 *

Also Published As

Publication number Publication date
CN103492427A (zh) 2014-01-01
US20130289206A1 (en) 2013-10-31
EP2658880A2 (de) 2013-11-06
JP2014504656A (ja) 2014-02-24
KR20140009272A (ko) 2014-01-22
DE102010056578A1 (de) 2012-07-05
BR112013016864A2 (pt) 2016-10-04
WO2012089300A2 (de) 2012-07-05

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