WO2008136343A1 - 結晶性ポリオキシアルキレンポリオールの製造方法およびこれを原料とした樹脂 - Google Patents

結晶性ポリオキシアルキレンポリオールの製造方法およびこれを原料とした樹脂 Download PDF

Info

Publication number
WO2008136343A1
WO2008136343A1 PCT/JP2008/057913 JP2008057913W WO2008136343A1 WO 2008136343 A1 WO2008136343 A1 WO 2008136343A1 JP 2008057913 W JP2008057913 W JP 2008057913W WO 2008136343 A1 WO2008136343 A1 WO 2008136343A1
Authority
WO
WIPO (PCT)
Prior art keywords
polyoxyalkylene polyol
crystalline polyoxyalkylene
raw material
same
resin obtained
Prior art date
Application number
PCT/JP2008/057913
Other languages
English (en)
French (fr)
Inventor
Hironobu Tokunaga
Ichiro Yamada
Yuko Tanaka
Original Assignee
Sanyo Chemical Industries, Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sanyo Chemical Industries, Ltd. filed Critical Sanyo Chemical Industries, Ltd.
Priority to US12/594,837 priority Critical patent/US8476381B2/en
Publication of WO2008136343A1 publication Critical patent/WO2008136343A1/ja

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66—Polyesters containing oxygen in the form of ether groups
    • C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/672—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C08G65/08—Saturated oxiranes
    • C08G65/10—Saturated oxiranes characterised by the catalysts used
    • C08G65/12—Saturated oxiranes characterised by the catalysts used containing organo-metallic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2654—Aluminium or boron; Compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/266—Metallic elements not covered by group C08G65/2648 - C08G65/2645, or compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Polyethers (AREA)

Abstract

本発明は、アイソタクティシティーが非常に高く、反応性が高い結晶性ポリオキシアルキレンポリオールを安価に製造し、シャープメルト性に優れたポリウレタン樹脂およびポリエステル樹脂を提供することを目的とする。本発明は、サレン錯体（Ｂ）の存在下で、アルキレンオキサイド（ａ）を開環重合させることを特徴とする数平均分子量が５００～２０，０００の結晶性ポリオキシアルキレンポリオール（Ａ）の製造方法、結晶性ポリオキシアルキレンポリオール（Ａ）、および結晶性ポリオキシアルキレンポリオール（Ａ）から得られるポリウレタン樹脂ならびにポリエステル樹脂に関する。
PCT/JP2008/057913 2007-04-26 2008-04-24 結晶性ポリオキシアルキレンポリオールの製造方法およびこれを原料とした樹脂 WO2008136343A1 (ja)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US12/594,837 US8476381B2 (en) 2007-04-26 2008-04-24 Method for producing crystalline polyoxyalkylene polyol, and resin obtained by using the same as raw material

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-117439 2007-04-26
JP2007117439 2007-04-26

Publications (1)

Publication Number Publication Date
WO2008136343A1 true WO2008136343A1 (ja) 2008-11-13

Family

ID=39943454

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/057913 WO2008136343A1 (ja) 2007-04-26 2008-04-24 結晶性ポリオキシアルキレンポリオールの製造方法およびこれを原料とした樹脂

Country Status (3)

Country Link
US (1) US8476381B2 (ja)
JP (1) JP5490372B2 (ja)
WO (1) WO2008136343A1 (ja)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011057966A (ja) * 2009-08-12 2011-03-24 Sumitomo Chemical Co Ltd 高分子量のアイソタクチックポリ（アルキレンオキシド）及びそれを製造する方法
JP5421034B2 (ja) * 2009-09-02 2014-02-19 帝人株式会社 植物由来成分を有するポリエステルの製造方法
WO2012166889A2 (en) 2011-05-31 2012-12-06 Cornell University Polyethers, methods of making same, and uses thereof
US9365661B2 (en) * 2012-08-03 2016-06-14 Exxonmobil Chemical Patents Inc. Polyalphaolefins prepared using modified salan catalyst compounds
BR112015026360A2 (pt) * 2013-04-17 2017-07-25 Reliance Industries Ltd pró-catalisador à base de metal de transição inovador e um processo para sua preparação
JP6365114B2 (ja) * 2014-08-25 2018-08-01 東ソー株式会社 アルキレンオキシド重合触媒およびそれを用いたポリアルキレンオキシドの製造方法
CN109715750B (zh) * 2016-09-22 2021-11-05 巴斯夫涂料有限公司 可通过缩合和/或加成反应固化的涂料组合物

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06248068A (ja) * 1993-02-26 1994-09-06 Asahi Glass Co Ltd ポリエーテル化合物および複合金属シアン化物錯体触媒の製造方法
JPH07278275A (ja) * 1993-12-23 1995-10-24 Arco Chem Technol Lp ポリウレタンフォームで支持された２金属シアン化物触媒およびその製造方法、ならびにエポキシドポリマーの製造方法
JP2001521957A (ja) * 1997-11-03 2001-11-13 バイエル・アクチエンゲゼルシヤフト 部分結晶性ポリエーテルポリオールの製造方法
JP2004315588A (ja) * 2003-04-11 2004-11-11 Sanyo Chem Ind Ltd ヘテロ環状化合物の開環重合用触媒

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5426081A (en) * 1993-12-23 1995-06-20 Arco Chemical Technology, L.P. Polyurethane foam-supported double metal cyanide catalysts for polyol synthesis
JP3105474B2 (ja) 1997-06-26 2000-10-30 三井化学株式会社 アルキレンオキサイドの重合方法
US8207365B2 (en) * 2005-03-14 2012-06-26 Georgia Tech Research Corporation Polymeric salen compounds and methods thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06248068A (ja) * 1993-02-26 1994-09-06 Asahi Glass Co Ltd ポリエーテル化合物および複合金属シアン化物錯体触媒の製造方法
JPH07278275A (ja) * 1993-12-23 1995-10-24 Arco Chem Technol Lp ポリウレタンフォームで支持された２金属シアン化物触媒およびその製造方法、ならびにエポキシドポリマーの製造方法
JP2001521957A (ja) * 1997-11-03 2001-11-13 バイエル・アクチエンゲゼルシヤフト 部分結晶性ポリエーテルポリオールの製造方法
JP2004315588A (ja) * 2003-04-11 2004-11-11 Sanyo Chem Ind Ltd ヘテロ環状化合物の開環重合用触媒

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
PERETTI K.L. ET AL.: "A Highly Active, Isospecific Cobalt Catalyst for Propylene Oxide Polymerization", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 127, no. 33, 26 July 2005 (2005-07-26), pages 11566 - 11567 *
SCHOEN E. ET AL.: "Gas-Phase and Solution-Phase Polymerization of Epoxides by Cr(salen) Complexes: Evidence for a Dinuclear Cationic Mechanism", INORGANIC CHEMISTRY, vol. 43, no. 23, 26 October 2004 (2004-10-26), pages 7278 - 7280, XP002581175 *
TOKUNAGA M. ET AL.: "Asymmetric Catalysis with Water: Efficient Kinetic Resolution of Terminal Epoxides by Means of Catalytic Hydrolysis", SCIENCE, vol. 277, 15 August 1997 (1997-08-15), pages 936 - 938, XP002122950, DOI: doi:10.1126/science.277.5328.936 *

Also Published As

Publication number Publication date
JP2008291241A (ja) 2008-12-04
US8476381B2 (en) 2013-07-02
JP5490372B2 (ja) 2014-05-14
US20100120996A1 (en) 2010-05-13

Similar Documents

Publication Publication Date Title
WO2008136343A1 (ja) 結晶性ポリオキシアルキレンポリオールの製造方法およびこれを原料とした樹脂
WO2014060348A3 (de) Herstellung und verwendung neuer thermoplastischer polyurethan-elastomere auf basis von polyethercarbonatpolyolen
KR102539511B1 (ko) 블록 공중합체 제조 방법
EP2603546B1 (en) Polysiloxane-polylactide block copolymer and preparation method thereof
WO2014060300A3 (de) Herstellung und verwendung neuer thermoplastischer polyurethan-elastomere auf basis von polyethercarbonatpolyolen
WO2009001783A1 (ja) ポリマー分散ポリオールおよび軟質ポリウレタンフォームの製造方法
DK2091990T3 (da) Fremgangsmåde til fremstilling af polyurethan-blødskumstoffer
MX344353B (es) Polimero de polietilen tereftalato bio-basado y metodo de elaboracion del mismo.
MX2014000638A (es) Procedimiento para producir polioletercarbonatos.
WO2013053555A3 (en) Hybrid polyester-polyether polyols for improved demold expansion in polyurethane rigid foams
EP1359188A3 (en) Polyester compositions
WO2007089779A3 (en) Processes for making copolymers using macrocyclic oligoesters, and copolymers therefrom
Ali et al. Synthesis of biodegradable and flexible, polylactic acid based, thermoplastic polyurethane with high gas barrier properties
MX2012010780A (es) Fibras bicomponentes.
WO2011133208A3 (en) Polyols suitable for hot molded foam production with high renewable resource content
WO2008133262A1 (ja) ポリエステルエラストマー組成物及びその製造方法
EP1932864A3 (en) Method for preparing polymer polyol stabilizer using maleic anhydride, and polymer polyol stabilizer prepared thereby
WO2008124035A3 (en) Ring-opening polymerization of cyclic esters, polyesters formed thereby, and articles comprising the polyesters
WO2014005863A3 (de) Herstellung von schaumstoffen mit verbesserten eigenschaften
WO2008123323A1 (ja) ポリオールの製造方法および該ポリオール
MX2013010623A (es) Metodo para producir polioles de o-ftalato poliester con bajo contenido de ester ciclico.
SE0602588L (sv) Förfarande för att uppnå ökad molekylvikt hos en polymer, en polymer erhållen med förfarandet och användning av nämnd polymer
EP1867677A4 (en) POLYHYDROXYALKANOATE RESIN FOAM PARTICLES
WO2008139905A1 (ja) 硬質発泡合成樹脂の製造方法
WO2010033161A3 (en) Polyester melt-phase compositions having improved thermo-oxidative stability, and methods of making and using them

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 08752012

Country of ref document: EP

Kind code of ref document: A1

WWE Wipo information: entry into national phase

Ref document number: 12594837

Country of ref document: US

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 12594837

Country of ref document: US

122 Ep: pct application non-entry in european phase

Ref document number: 08752012

Country of ref document: EP

Kind code of ref document: A1