WO2012063632A1 - フィルム露光方法 - Google Patents
フィルム露光方法 Download PDFInfo
- Publication number
- WO2012063632A1 WO2012063632A1 PCT/JP2011/074455 JP2011074455W WO2012063632A1 WO 2012063632 A1 WO2012063632 A1 WO 2012063632A1 JP 2011074455 W JP2011074455 W JP 2011074455W WO 2012063632 A1 WO2012063632 A1 WO 2012063632A1
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- WIPO (PCT)
- Prior art keywords
- film
- exposure
- mask
- alignment mark
- alignment
- Prior art date
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/20—Exposure; Apparatus therefor
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03B—APPARATUS OR ARRANGEMENTS FOR TAKING PHOTOGRAPHS OR FOR PROJECTING OR VIEWING THEM; APPARATUS OR ARRANGEMENTS EMPLOYING ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ACCESSORIES THEREFOR
- G03B27/00—Photographic printing apparatus
- G03B27/02—Exposure apparatus for contact printing
- G03B27/10—Copying apparatus with a relative movement between the original and the light source during exposure
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/70—Microphotolithographic exposure; Apparatus therefor
- G03F7/70691—Handling of masks or workpieces
- G03F7/70791—Large workpieces, e.g. glass substrates for flat panel displays or solar panels
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F9/00—Registration or positioning of originals, masks, frames, photographic sheets or textured or patterned surfaces, e.g. automatically
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/146—Laser beam
Definitions
- the present invention relates to a film exposure method, and in particular, when a film having an exposure material film formed on an exposure pattern forming region on a film substrate is continuously exposed, the meandering of the film is accurately corrected and stably performed.
- the present invention relates to a film exposure method capable of exposure.
- a substrate with a predetermined marking on the surface is used, and this marking is used for exposure.
- the position of a mask to be determined is determined (for example, Patent Documents 1 to 3), or positioning pins are installed on a pallet on which a substrate is placed (for example, Patent Document 4).
- the object to be exposed is a film as in the roll-to-roll method, and this film is continuously supplied into the exposure apparatus, the alignment technique in the exposure of the flat plate member as described above is applied. It is difficult. That is, in the roll-to-roll film production line, the film to be exposed is supplied into the exposure apparatus 1 in a process as shown in FIG. 9, for example, to expose a flat substrate or the like. In contrast, the film 1 being conveyed is easily wavy due to its flexibility.
- processing using the flexibility of the film is performed in every processing step. That is, the film 2 is unwound from the supply reel 80 and supplied to the line, and pretreatment such as dry cleaning and surface modification is performed in the pretreatment section 3, and a predetermined exposure material is applied to the surface by the slit coater 4. Is applied, the applied exposure material is dried by the drying device 5. Then, the film 2 having the exposure material film formed on the surface is supplied to the exposure apparatus 1, and the exposure material film is exposed by the exposure apparatus 1. At this time, the film 2 is supported by, for example, the rollers 9 between the apparatuses and is conveyed by the rotation. Therefore, it is difficult to apply the techniques disclosed in Patent Documents 1 to 4 to the exposure of the roll-to-roll film 2.
- Patent Document 5 discloses a mask alignment technique with respect to a film. That is, in the technique of Patent Document 5, in the case where exposure is performed twice on a single film, after the first exposure is performed on the film to form a pattern, The position of the mask is adjusted by detecting the pattern formed by the second exposure with the line CCD. In addition, as FIG. 2 of this patent document 5 shows, the both-sides edge part of the width direction of a film is not an exposure area
- FIG. 10 shows, as an example, a conventional exposure apparatus of a type in which exposure light sources 11 that emit exposure light are arranged to face each other corresponding to one mask 12 and irradiate exposure light from different directions.
- FIG. 10 Such a type of exposure apparatus is used for exposure of an alignment material film when a colorless and transparent alignment film is formed on a glass substrate such as a liquid crystal display or a film substrate such as a polarizing film. That is, when forming an alignment film by exposure by this exposure apparatus, an exposure target member having a colorless and transparent alignment material film formed on the surface is supplied into the exposure apparatus, and exposure light is directed in different directions for each predetermined region. To form an alignment film oriented in different directions.
- an area corresponding to one picture element of the film is divided and exposed in the width direction, or the film is divided and exposed in the width direction for each area corresponding to the pixel.
- An alignment film having a different alignment direction can be formed for each divided region. Due to the characteristics of the alignment direction of the alignment film, the operation at the time of voltage application of the liquid crystal molecules sandwiched between the glass substrates can be varied according to the alignment direction of the alignment film, thereby widening the viewing angle of the display device,
- the produced film can be used as a polarizing film such as a 3D (Three Dimensional) display. Recently, the exposure technology of such a film has been attracting attention.
- the film When the film is exposed by such an exposure apparatus, the film is likely to be wavy during conveyance, thereby causing a problem of deviation of the exposure position.
- the plurality of masks 12 are used, and the masks 12 are arranged in a staggered pattern so as to be aligned in the moving direction of the exposure target member and the width direction perpendicular thereto. Is provided for each mask to perform exposure. Then, the exposure light from the exposure light source 11 is transmitted through each of the masks 121 to 124, and as shown in FIG.
- the film is formed by the masks 121 and 122 that are spaced apart from each other on the upstream side where the film is supplied. 2 is exposed in the exposure areas A and C, the area B between the exposure areas A and C is exposed with the mask 123 on the downstream side, and the area D adjacent to the exposure area C is exposed with the mask 124. ing. Thereby, the pattern which carried out orientation division
- Patent Document 5 requires that the exposure operation be performed twice on a single film, and the productivity is poor.
- the housing portion of the exposure light source 11 has a length of about 2 m in the moving direction of the film for each light source, for example, exposure regions A and C and exposure regions B and D as shown in FIG.
- the distance between is at least as long as 4 m. Therefore, there is a problem in that the film easily undulates during conveyance from the upstream exposure areas A and C to the downstream exposure areas B and D and easily shifts in the width direction perpendicular to the moving direction. Therefore, in the exposure area downstream of the moving direction of the film, there is a problem that an already exposed area is exposed due to a positional deviation in the width direction of the film, and an unexposed area is also generated. .
- the film base material to be marked is colorless and transparent, and laser light easily passes through the film in marking with a laser or the like. Therefore, for example, when ultraviolet light having a wavelength of 266 nm is used for the marking, there is a problem that it is difficult to form an alignment mark unless the irradiation energy of the laser light is extremely increased to, for example, about 8 J / cm 2 .
- the present invention has been made in view of such a problem, and when a film having an exposure material film formed on an exposure pattern formation region on a film substrate is continuously exposed, the alignment mark is formed and formed. It is an object of the present invention to provide a film exposure method that is easy to detect, can accurately correct the meandering of the film, and can be stably exposed.
- the exposure material is irradiated onto the exposure material film of the film in which the exposure material film is formed in the exposure pattern forming region on the film substrate through a mask.
- the film exposure method for exposing the pattern of the mask on the film at least one of both side edges in the width direction of the film base is coated with a colored baking material, a colored photocurable material, or a colored ink.
- a film on which a coating film is formed is supplied, the alignment mark is formed by irradiating the side coating film with a laser beam for alignment marks, and the alignment mark is used to detect film meandering, and the position of the mask It is characterized by adjusting.
- the exposure material film and / or the side coating film may be applied before the alignment mark laser light is irradiated while the film base material wound on the supply reel is moved from the supply reel to the take-up reel. , Formed on the film substrate.
- the mask is disposed on the upstream side and the downstream side in the movement direction of the film, and the exposure material film is provided on the upstream side and the downstream side in the movement direction of the film, respectively.
- Exposing the pattern of the upstream mask and the downstream mask, forming the alignment mark on the side coating film at a position corresponding to the position of the upstream mask in the moving direction of the film By detecting the alignment mark at a position corresponding to the position of the downstream mask in the movement direction, the film meanders until the film moves from the exposure area by the upstream mask to the exposure area by the downstream mask. And detecting the relative position of the downstream mask with respect to the film by meandering the film. Only correction amount that was.
- a film exposure method for exposing a film having an exposure material film formed in an exposure pattern forming region on a film substrate, using a mask pattern, at least one of both side edges in the width direction of the film substrate.
- This colored side coating film has a high laser beam absorptivity and facilitates the formation of alignment marks.
- the alignment mark is formed by removing the side coating film by irradiating the alignment mark laser light, the colored coating film remains around the alignment mark, so the alignment mark is detected clearly and accurately. can do. Therefore, according to the present invention, film meandering detection and mask position adjustment can be performed with high accuracy, and the film can be stably exposed.
- FIG. 1 is a view showing correction of displacement in the width direction of a film by an alignment mark in a film exposure apparatus according to an embodiment of the present invention
- FIG. 2 is a film conveyance in the film exposure apparatus according to the embodiment of the present invention
- FIG. 3 is a diagram showing the relative positional relationship between the pattern by the upstream mask and the pattern by the downstream mask in the film exposure apparatus according to the embodiment of the present invention.
- the exposure light source 11 that emits exposure light, the mask 12, and the exposure light emitted from the exposure light source 11, as in the conventional exposure apparatus shown in FIGS.
- the film 2 is irradiated with the exposure light emitted from the mask 12, and the exposure material film 21 formed on the film substrate 20 is exposed in the central region in the width direction of the film.
- the exposure apparatus 1 has an alignment laser marker 14 (alignment mark laser light source) for forming an alignment mark 2a on the side of the film 2, as shown in FIGS.
- the exposure apparatus 1 is supplied with a film 2 having a side coating film 22 formed by applying a colored baking material, a colored photocurable material or colored ink to at least one of both side edges.
- a film 2 having a side coating film 22 formed by applying a colored baking material, a colored photocurable material or colored ink to at least one of both side edges.
- an exposure material film 21 is formed in a region (an exposure pattern forming region in the present invention) on the film substrate 20 in the same manner as in the conventional case. ing.
- This exposure material film 21 is colorless and transparent, for example.
- a side coating film 22 is formed by applying a colored baking material, a colored photocurable material, or colored ink to the side portion of the film substrate 20 to which no exposure material is conventionally applied. ing. Then, laser light is irradiated from the alignment laser marker 14 onto the side coating film 22, and the alignment mark 2a is formed by heat from exposure or laser light irradiation.
- the exposure apparatus 1 includes, for example, a laser marker 13 (retraction mark forming unit) disposed in the vicinity of a film supply unit such as a transport roller and a mask 12 as illustrated in FIGS.
- a laser marker 13 retract mark forming unit
- the film supply unit has a line CCD 15 (film drawing position detection unit) arranged so as to extend in the width direction of the film 2 below.
- the drawing mark 2b serving as a reference for positioning the mask 12 by the laser marker 13, and the drawing mark 2b is detected by the line CCD 15, whereby the film 2
- the position of the mask 12 with respect to is adjustable.
- the film 2 to be exposed is unrolled from the roll-to-roll supply reel 80 and supplied to the slit coater 4, and the surface of the film 2 is predetermined by the slit coater 4.
- the material is applied in the form of a film.
- the slit coater 4 applies an exposure material to the center of the film substrate 20, for example, a colored baking material or a colored photocuring material on at least one of both side edges of the film substrate 20. It is comprised so that a property material can be apply
- the slit coater 4 applies, for example, a colorless and transparent exposure material that becomes an alignment material film (exposure material film 21) to the center of the film base 20 in the width direction, and forms an alignment mark on the side of the film base 20.
- a colored baking material or a photocurable material to be the side coating film 22 can be applied in a liquid or pasty state.
- the exposure material, the colored baking material, or the colored photocurable material may be applied by one slit coater 4 or by two slit coaters 4, respectively.
- the coloring material which can form a baking film on the film base material 20 by baking for example, red and green for optical color filters generally used
- a blue and / or black resist material can be preferably used.
- the side coating film in the present invention is used only for the formation of alignment marks for detecting film meandering, in the case of forming the side coating film with a resist material, the steps such as development are performed. Not particularly necessary.
- a photocurable material for example, a colored photocurable resin can be used.
- the slit coater 4 applies only the exposure material to the center of the film substrate 20. . Then, colored ink is applied to the side portion of the film substrate 20 by an application device provided upstream or downstream of the slit coater 4 in the moving direction of the film 2, that is, upstream of the drying device 5.
- an application device provided upstream or downstream of the slit coater 4 in the moving direction of the film 2, that is, upstream of the drying device 5.
- the colored ink liquid or paste-like ink in general containing pigments and / or dyes can be used, and ink that can form a colored film by volatilizing the solvent component with the drying device 5, for example, oily Ink can be preferably used.
- ink is permeated into a coating portion formed of a material having moderate flexibility, for example, a felt-like fiber, and exposure of the side portion of the film substrate 20 fed to the coating portion is performed.
- a structure in which ink is applied in a film form by using a region where no material is applied is used.
- the film 2 coated with a predetermined material only by the slit coater 4 or by the slit coater 4 and the coating device is supplied to the drying device 5. Then, the exposure material applied to the center of the film and the material that becomes the coating film on the side of the film are baked (baked), dried (volatilization of solvent components), and / or photocured according to the characteristics of each material. Thus, an exposure material film 21 and a side coating film 22 are formed on the film substrate 20, respectively.
- the film 2 is supplied into the exposure apparatus 1 by a transport device such as a transport roller.
- the film 2 supplied into the exposure apparatus 1 is formed with an alignment film oriented in a predetermined direction by photo-aligning the exposure material film 21 at the center in the film width direction, as in the prior art.
- the side coating film 22 of the film 2 is irradiated with laser light from the alignment laser marker 14, and the alignment mark 2 a is formed by exposure or heat generated by laser light irradiation.
- the area where the side coating film 22 is formed is, for example, an area of, for example, 25 mm or less, for example, 10 mm from the edge of the film. It is.
- the alignment mark 2 a formed on the side coating film 22 is used to detect the meandering of the film 2 and adjust the position of the mask 12.
- a case will be described in which a colored oil-based ink is applied as the material of the side coating film 22 and the solvent component disappears by drying (volatilization), thereby forming a film of ink. .
- the exposure light source 11 is a light source that emits ultraviolet light in, for example, an alignment division type exposure apparatus, and is a mercury lamp, a xenon lamp, an excimer lamp, an ultraviolet LED, or the like, and emits continuous light or pulsed laser light.
- a light source is used.
- an optical system such as a collimator lens and / or a reflecting mirror is disposed on the optical path of the exposure light emitted from the exposure light source 11, and is formed in a pattern formation region on the film 2, for example.
- the alignment material film (exposure material film 21) is irradiated with exposure light with a predetermined amount of light.
- the exposure light source 11 can adjust the emission direction of the exposure light by, for example, a control device (not shown), and can thereby adjust the incident angle of the exposure light with respect to the film 2.
- a control device not shown
- two exposure light sources 11 are arranged so as to face each other in a moving direction of the film 2 with respect to one exposure region.
- the alignment material film is irradiated to the alignment material film (exposure material film 21) through the mask 12 with two exposure light beams emitted from the respective exposure light sources 11 and having different pretilt angles, and the alignment material film is perpendicular to the moving direction.
- the alignment films are exposed to each other, and different alignment films are formed on the film substrate 20 in the divided regions where the alignment directions are adjacent to each other.
- the orientation of liquid crystal molecules at the time of voltage application Is two directions within one picture element according to the alignment direction of the alignment film, and can widen the viewing angle of a liquid crystal display or the like.
- a film in which an alignment film having a different alignment direction is formed for each region serving as a pixel adjacent in the width direction can be used as a polarizing film such as a 3D (Three Dimensional) display.
- the number of exposure light sources 11 is not limited to two for one exposure region, and three or more exposure light sources 11 may be provided.
- alignment film materials may be aligned in three or more directions by exposure light from different directions.
- one exposure light source 11 is provided for one exposure area, the exposure light emitted from the exposure light source 11 is divided into two or more by a polarizing plate or the like, and the divided exposure light is irradiated from different directions.
- You may comprise as follows. For example, by using a polarizing plate, exposure light can be divided into P-polarized linearly-polarized exposure light and S-polarized linearly-polarized exposure light and irradiated from different directions.
- a plurality of masks 12 are arranged separately from each other on the upstream side and the downstream side in the moving direction of the film 2. For example, as shown in FIG. 2 and FIG. 121, 122) and two on the downstream side (masks 123, 124).
- the plurality of masks 12 are arranged in a staggered manner so that the exposure areas formed by the upstream masks 121 and 122 and the exposure areas formed by the downstream masks 123 and 124 are adjacent along the moving direction of the film.
- the pair of exposure light sources 11 is provided. Then, as shown in FIG.
- the exposure light from the exposure light source 11 is transmitted through the masks 121 and 122 upstream in the moving direction of the film 2 to expose the alignment film material on the film 2 in the exposure areas A and C. To do. Further, the exposure light from the exposure light source 11 is transmitted through the masks 123 and 124 on the downstream side, and the alignment film material on the film 2 is exposed in the exposure regions B and D.
- the mask 12 includes, for example, a frame body 120 and a pattern forming portion 125 at the center thereof.
- the pattern forming portion 125 includes a pattern 125 a of a predetermined light transmission region. Is formed. That is, in the pattern forming portion 125, an opening that transmits exposure light is formed corresponding to the pattern shape formed on the film 2, or a light transmissive member is installed.
- the alignment material film on the surface of the film 2 disposed on the stage 10 is exposed by the transmitted light of the pattern forming unit 121.
- a pair of exposure light sources 11 is arranged for each mask 12 and emits exposure light having different incident angles.
- the pattern 125a has a plurality of rectangular opening patterns so as to be arranged in two rows on the upstream side and the downstream side in the moving direction of the film corresponding to two exposure lights having different incident angles.
- the book is provided.
- the upstream and downstream light transmission region groups are formed apart from each other so that the irradiation regions of the exposure light do not overlap each other.
- the upstream pattern and the downstream pattern are formed in a zigzag pattern along the width direction so that the exposure areas of the upstream pattern and the downstream pattern are adjacent to each other.
- the mask 12 has a width of about 300 ⁇ m and a length so as to extend in the width direction perpendicular to the moving direction of the film 2 on the upstream side (upper side in FIG. 4) of the pattern 125a.
- a viewing window 12a for a line CCD of about 250 mm is provided, and a line-shaped light shielding pattern 12b having a width of, for example, about 15 ⁇ m is provided in the middle of the viewing window 12a in the longitudinal direction. Then, the position of the light shielding pattern 12 b is detected by a line CCD 15 to be described later and used for positioning the mask 12.
- the positions and shapes of the viewing window 12a and the light shielding pattern 12b in the present embodiment are merely examples, and the present invention is not limited to these positions and shapes as long as the mask 12 can be accurately positioned. Absent.
- the positions of the viewing window 12a and the light shielding pattern 12b may be provided in a region between the patterns 125a formed so as to be arranged in two rows.
- each other for example, N-type
- a plurality of intersecting slits may be provided instead of the light shielding pattern 12b.
- Each of the masks 12 is configured such that, for example, a portion of the frame 120 is supported by the mask stage 17, and the entire mask 12 is movable by the movement of the mask stage 17.
- the mask stage 17 is connected to a mask position control unit 30 as shown in FIG. 5, for example, and the position thereof is controlled, for example, in the horizontal direction (film width direction or film width direction) under the control of the mask position control unit 30. And the longitudinal direction of the film). Thereby, the exposure position of the film 2 by the mask 12 can be adjusted to a horizontal direction.
- the mask stage 17 can be moved in the vertical direction, for example, and can be adjusted so that, for example, the alignment film material on the film 2 is exposed to a predetermined size.
- the film transport unit is, for example, a transport roller 9 provided outside the exposure apparatus 1 and inside the exposure apparatus 1, and is driven by a motor or the like.
- the film 2 unrolled from the supply reel 80 is rotated to rotate the exposure apparatus 1.
- the film 2 exposed in the exposure apparatus 1 is moved to the take-up reel 81.
- the alignment laser marker 14 is a laser light source that irradiates and exposes the side coating film 22 with exposure light, or a laser that marks the side coating film 22 by heat generated by the laser light irradiation.
- a light source for example, a Nd: YAG laser or a laser light source that emits ultraviolet light or the like, for example, a xenon flash lamp or the like.
- the alignment laser marker 14 is a pulse light source
- the colored side coating film 22 formed on the side of the film 2 is irradiated with exposure light and subjected to marking by heat from exposure or laser light irradiation,
- the marking is formed to extend linearly by the movement of the film 2, and the width is 10 to 50 ⁇ m and the length is 150 ⁇ m to 50 mm on the side coating film 22 (particularly, the width is about 20 ⁇ m and the length is 300 ⁇ m).
- the alignment mark 2a is preferably formed at regular intervals.
- the alignment laser marker 14 is a light source that emits continuous light
- the alignment mark 2 a is continuously formed on the side coating film 22 so as to extend in the moving direction of the film 1.
- the alignment laser marker 14 is provided, for example, so as to be aligned in the film width direction with respect to the masks 121 and 122 on the upstream side in the movement direction of the film 2, and the upstream mask in the movement direction of the film 2.
- An alignment mark 2a is formed on the side coating film 22 at a position corresponding to the viewing window 121a (and the light shielding pattern 12b) of 121, 122.
- the region where the alignment mark 2a is formed is, for example, a region within 25 mm from the edge of the film, and is a portion where the film substrate 20 is exposed without forming a material film or the like conventionally. .
- the alignment mark 2a By forming the alignment mark 2a on the edge of the film corresponding to the position of the viewing window 12a of the upstream masks 121 and 122, the pattern and film formed in the region A and the region C on the upstream side in the moving direction of the film 2, respectively.
- the distance between the edge 2 and the alignment mark 2a is always constant.
- the alignment mark 2 a formed on the side coating film 22 of the film at a position corresponding to the position of the upstream masks 121 and 122 in the moving direction of the film 2 is used for detecting the meandering of the film 2. That is, the alignment mark detection unit 16 is arranged at the position corresponding to the position of the downstream masks 123 and 124 in the moving direction of the film 2 so as to be aligned with the downstream masks 123 and 124 in the width direction of the film 2. It is arranged above or below, and is configured to detect the position of the alignment mark 16a at a position corresponding to the position of the downstream masks 123 and 124.
- the alignment mark detection unit 16 is, for example, a CCD camera. As shown in FIGS.
- the position of the alignment mark 2a in the film width direction at a position corresponding to the viewing window 12a of the downstream masks 123 and 124. Is detected.
- the alignment mark 2a is also shifted in the width direction of the film 2 by the same meandering amount. The position of the alignment mark 2a deviated to is detected.
- the alignment mark detection unit 16 is connected to a mask position control unit 30 as shown in FIG. Then, the detected position in the film width direction of the alignment mark 2 a is transmitted to the mask position control unit 30.
- the mask position control unit 30 is configured to adjust the positions of the masks 123 and 124 on the downstream side in the moving direction of the film based on the position of the alignment mark 2 a transmitted from the alignment mark detection unit 16. That is, the exposure apparatus 1 according to the present embodiment forms the alignment mark 2a and uses it for detecting the meandering of the film 2, thereby adjusting the positions of the downstream masks 123 and 124 according to the detected meandering amount. Can do.
- FIG. 5 is a diagram showing the configuration of the mask position control unit 30 as an example.
- the mask position control unit 30 is connected to, for example, a control unit of a motor provided in the mask stage driving unit, the exposure light source 11 and the film take-up reel 81 (see FIG. 9).
- the mask position control unit 30 includes an image processing unit 31, a calculation unit 32, a memory 33, a motor drive control unit 34, a light source drive unit 35, a mask stage drive control unit 36, And a control unit 37.
- the image processing unit 31 performs image processing of the alignment mark 2a imaged by the alignment mark detection unit 16 (CCD camera), and detects, for example, the center position of the alignment mark 2a in the film width direction.
- the calculating unit 32 calculates, for example, a shift in the film width direction between the center position of the alignment mark 2a to be set and the actual center position of the alignment mark 2a. Further, the calculation unit 32 determines the position of the mask 12 to be set at the start of exposure based on the distance between the position of the film drawing mark 2b detected by the line CCD 15 described later and the position of the light shielding pattern 12b on the mask 12. The deviation in the film width direction from the actual mask 12 position is also calculated.
- the memory 33 stores, for example, the center position of the alignment mark 2a detected by the image processing unit 31 and the shift amount calculated by the calculation unit 32.
- the motor drive control unit 34 controls the rotation speed when the motor of the film take-up reel 81 is driven or stopped, or is driven, for example.
- the light source drive unit 35 controls the turning on / off of the exposure light source 11, the output, or the oscillation frequency.
- the mask stage drive control unit 36 controls the drive of the mask stage 17 and controls, for example, the movement direction and the movement amount of the mask stage 17.
- the control unit 37 controls driving of the image processing unit 31, the calculation unit 32, the memory 33, the motor drive control unit 34, the light source drive unit 35, and the mask stage drive control unit 36.
- the film exposure apparatus 1 adjusts the position of the mask 12, for example, switches on / off the exposure light irradiation by the exposure light source 11, or the rotational speed of the motor provided on the take-up reel 81 for the film 2 Etc. can be controlled.
- the mask position control unit 30 calculates the amount of the shift.
- the positions of the downstream masks 123 and 124 are moved outward in the width direction of the film by an amount by which the alignment mark 2a is displaced.
- the mask position control unit 30 calculates the shift amount, and the position of the alignment marks 2a is shifted from the positions of the downstream masks 123 and 124. Only move inward in the width direction of the film.
- the laser marker 13 includes a gantry stage 13a, a transport unit 13b, and a marking unit 13c.
- the gantry stage 13a is located above the portion where the film is supplied with respect to the moving direction of the film. Are arranged so as to extend in the vertical film width direction.
- the transport unit 13b is supported by the gantry stage 13a and is configured to be able to move along the longitudinal direction on the gantry stage 13a. Further, the position of the transport unit 13b is controlled by a control device (not shown), and thereby the position of the marking unit 13c can be adjusted.
- the marking unit 13c emits laser light from a laser light source such as an Nd: YAG laser, for example, and has a predetermined shape, for example, a cross shape, at the leading end of the film 2 supplied from the film supply unit as shown in FIG.
- the pull-in mark 2b is formed.
- the marking unit 13c is fixed to the conveyance unit 13b, and is configured to be able to adjust the formation position of the drawing mark 2b on the film 2 by controlling the position of the conveyance unit 13b by a control device.
- the marking portion 13 c has four lead-in marks 2 b at the front end portion of the film 2 so as to correspond to each of the four masks 12, for example, at regular intervals. It is configured to form.
- the line CCD 15 (film drawing position detection unit) is arranged to extend in the width direction of the film 2 below the viewing window 12a and the light shielding pattern 12b provided in each mask 12.
- the line CCD 15 detects a light shielding pattern 12 b provided in the middle of the viewing window 12 a of the mask 12 as an actual position of the mask 12.
- the line CCD 15 is connected to the mask position control unit 30 and is configured to transmit the detected positions of the pull-in mark 2 b and the light shielding pattern 12 b to the mask position control unit 30.
- the mask position control unit 30 is a mask used when the film is first exposed based on the distance between the drawing mark 2b transmitted from the line CCD 15 and the plane parallel to the film surface calculated from the position of the light shielding pattern 12b.
- the position of 12 is also adjusted. That is, the mask position control unit 30 stores in advance the position data of the mask (light shielding pattern 12b) to be set with reference to the position of the pull-in mark 2b. As shown in FIG.
- the unit 30 moves the position of the mask stage 17 using the position of the pull-in mark 2b detected by the line CCD 15 as a reference position until the mask position determined by the detected position of the light shielding pattern 12b reaches a predetermined position.
- the position of the mask 12 can be adjusted with reference to the position of the pull-in mark 2b formed on the film 2 in advance with high accuracy even when the exposure is started.
- the position to be exposed can be determined with high accuracy.
- the film 2 supplied to the exposure apparatus 1 has a side coating film 22 formed on the side where the film substrate 20 is exposed without a material film or the like conventionally formed.
- the side coating film 22 is formed by applying colored oil-based ink by a coating device and then removing the solvent component by volatilization in the drying device 5 or the like.
- the side coating film 22 formed of colored ink or a color filter resist material has a laser beam absorptivity of 90 to 98% when irradiated with a laser beam having a wavelength of 532 nm, for example.
- the alignment film material Compared to the material and the alignment film material (both the film base material and the alignment film material have an absorption rate of laser light of approximately 0%), it is easily exposed or laser-exposed by laser light irradiation from the alignment laser marker 14. Marked by processing. Therefore, compared with the case where marking is performed by irradiating a colorless and transparent film substrate with laser light, marking with the laser light is easy, and the alignment mark 2a can be easily formed. For example, in the case where marking is performed on the film substrate 20, for example, when the laser beam to be used is ultraviolet light having a wavelength of 266 nm, the alignment mark 2a must be set to an extremely large irradiation energy of the laser beam, for example, 8 J / cm 2. The formation of is difficult.
- the irradiation energy of the laser beam can be reduced as compared with the case of using only the film substrate 20, but the alignment material film around the alignment mark 2a is also colorless and transparent. Therefore, for example, it is necessary to use an expensive and large-sized detection apparatus such as SEM, and there is a problem that the cost of the exposure apparatus is increased and the size is increased.
- the side coating film 22 is formed of colored ink as in the present embodiment, for example, when the laser light to be used is ultraviolet light having a wavelength of 532 nm, the irradiation energy of the laser light is 0.6 J / It can be reduced to about cm 2 .
- the laser beam irradiation energy can be reduced to about 1.0 J / cm 2 . Therefore, by forming the side coating film 22 with a colored material as described above, marking with a laser beam is easy, and a colored coating film remains around the formed alignment mark 2a. Even when an inexpensive and small detection device such as a CCD camera is used, the formed alignment mark 2a can be detected easily and accurately. Therefore, since the alignment mark 2a formed with high accuracy can detect the meandering of the film 2 and adjust the position of the mask 12 with high accuracy, the film can be stably exposed.
- the exposure area is divided into the upstream side and the downstream side by forming a drawing mark 2b at the leading end of the film 2 and adjusting the position of the mask 12 according to the position of the drawing mark 2b.
- the exposed areas are not overlapped or unexposed areas are not generated due to the undulation of the film 2 and the shift in the width direction. Since the initial position of the mask 12 is determined with reference to the pull-in mark 2b formed at the leading end of the film 2, the downstream pattern can be accurately formed in addition to the upstream pattern. Thereby, a film can be exposed stably.
- the exposure light source 11 that emits the exposure light and the laser marker 14 that forms the alignment mark 2a can also simplify the configuration of the exposure apparatus by using the same laser light.
- the initial position of the mask 12 at the start of exposure is adjusted by forming the pull-in mark 2b at the leading end of the film and detecting it by the line CCD 15, but the present invention adjusts the initial position of the mask 12.
- these configurations may not be provided.
- an exposure material to be an alignment film (exposure material film 21) is applied to the center of the film substrate 20 by the slit coater 4 shown in FIG. 9.
- the coating device provided on the upstream side or the downstream side of the slit coater 4 in the moving direction of the film (the upstream side of the drying device 5) can be used for both side edges (regions from the edge to 25 mm) of the film substrate 20. Colored ink is applied to at least one of them.
- the ink When the ink is applied, for example, the ink is applied to the surface of the film substrate 20 by bringing the ink infiltrated into an application portion formed of felt fiber or the like into contact with the surface of the film substrate 20. Apply in film form. Thereby, a liquid or paste-like exposure material and colored ink are applied to the surface of the film substrate 20 in a film form.
- the film 2 is conveyed to a drying device 5 where the surface liquid or paste-like exposure material and the colored coating film material (ink) are dried (volatilization of the solvent component) and photocured according to the characteristics of each material. And / or baked (baked).
- an exposure material film 21 (alignment material film) and a side coating film 22 are formed on the surface of the film substrate 20. That is, a predetermined alignment material film is formed at the center of the film substrate 20 in the width direction, but a side coating film for forming an alignment mark is formed on the side of the film substrate 20 from the edge to 25 mm.
- a film made of ink in which the solvent component is volatilized is formed.
- the film 2 on which these two types of films are formed is supplied into the exposure apparatus 1 from the front end portion thereof by, for example, the transport roller 9.
- the film 2 supplied into the exposure apparatus 1 is supplied from the front end portion to below the laser marker 13 by a film supply unit such as a transport roller.
- the supply of the film 2 by a conveying device such as a conveying roller is temporarily stopped.
- the marking part 13c is conveyed to a predetermined position by moving the conveyance part 13b of the laser marker 13 on the gantry stage 13a by control by a control apparatus.
- the marking part 13c is arrange
- a laser beam is emitted from the marking portion 13c to form, for example, a cross-shaped pull-in mark 2b at the leading end of the film 2.
- the control device moves the marking unit 13c, for example, by moving the transport unit 13b on the gantry stage 13a.
- a pull-in mark 2b is formed at the leading end of the film.
- the film 2 reaches below the mask 12 (masks 121 and 122) arranged corresponding to the exposure areas A and C, as shown in FIG.
- a line CCD 15 is arranged at a position corresponding to the viewing window 12a (and the light shielding pattern 12b) below each mask 12 so as to extend in the width direction of the film 2.
- the line CCD 15 has a pull-in mark 2b and a line CCD 15 The position of the pull-in mark 2b is detected when the sheet is conveyed until it is positioned above. Further, the line CCD 15 detects the position of the light shielding pattern 12 b provided in the middle of the viewing window 12 a of the mask 12.
- the line CCD 15 transmits a signal indicating the distance between the detected pull-in mark 2 b and the light shielding pattern 12 b to the mask position control unit 30. For example, the conveyance of the film 2 is stopped until the adjustment of the mask position is completed after the detection process by the line CCD 15.
- the mask position control unit 30 When the signal of the distance between the pull-in mark 2b and the light shielding pattern 12b is input from the line CCD 15, the mask position control unit 30 first stores the distance between the two in a plane parallel to the film surface (the pull-in). Compared with the data of the initial position to be set on the mask 12 with the position of the mark 2b as a reference). Then, the mask stage 17 is moved until the mask position determined by the position of the light shielding pattern 12b reaches a predetermined initial position. Thereby, before the start of exposure in the exposure areas A and C, the initial position of the mask 12 (masks 121 and 122) is accurately determined with reference to the film 2.
- the side coating film 22 formed on the side portion of the film 2 is started to be irradiated with the laser beam by the alignment laser marker 14 and irradiated with the laser beam.
- the formed area is marked by exposure, or marked by heat by laser light irradiation.
- the side coating film 22 may have the ink removed in the region irradiated with the laser light, and the film substrate 20 may be exposed in the marking region.
- the laser beam irradiation energy is small, and the film substrate itself is not affected by alteration or the like.
- the colorless and transparent film substrate 20 is slightly scratched, but the region where the side coating film 22 is formed is not included in the image display region of the display device. Since this is an unused area, there is no problem.
- the side coating film made of colored ink formed on the side of the film has an extremely high laser light absorptance compared to the light absorptivity of the film base material and the alignment film material. Therefore, even when the irradiation energy of the laser beam irradiated from the alignment laser marker 14 is as small as about 0.6 J / cm 2 , the ink in the irradiation region is easily marked by the heat generated by the laser beam irradiation. Therefore, the alignment mark 2a can be easily formed and the coating film remaining around it is colored compared to the case where marking is performed by irradiating a laser beam onto a colorless and transparent film substrate. And it can form with sufficient precision.
- the position of the alignment laser marker 14 is a position corresponding to the viewing window 12a (and the light shielding pattern 12b) of the upstream mask 12 (masks 121 and 122) in the moving direction of the film 2. Therefore, the alignment mark 2a is formed on the side coating film 22 so that the relative distance to the upstream masks 121 and 122 in the moving direction of the film 2 is constant.
- the film 2 is transported by a transport roller or the like without starting the exposure. Then, as shown in FIG. 2, the film 2 is transported so that the leading end reaches below the mask 12 (masks 123 and 124) arranged corresponding to the downstream exposure regions B and D.
- a line CCD 15 is arranged at a position corresponding to the viewing window 12a (and the light shielding pattern 12b) below each mask 12 so as to extend in the width direction of the film 2, as in the upstream case.
- the line CCD 15 detects the light shielding pattern 12b provided in the middle of the observation window 12a of the mask 12 as the actual position of the mask 12, and thereby the pull-in mark 2b and the mask 12 The distance from the light shielding pattern 12b is measured. Then, a signal of the distance between the detected pull-in mark 2b and the light shielding pattern 12b is transmitted to the mask position control unit 30. For example, the conveyance of the film 2 is stopped from the detection process by the line CCD 15 provided corresponding to the position of the downstream mask 12 until the adjustment of the downstream mask position is completed. At this time, the formation of the alignment mark 2a may be temporarily stopped.
- the mask position control unit 30 determines the distance between the two in a plane parallel to the film surface. Is compared with data stored in advance (data of the initial position to be set on the mask 12 with reference to the position of the pull-in mark 2b). Then, the position of the downstream mask 12 (123, 124) is adjusted by moving the mask stage 17 until the mask position determined by the position of the light shielding pattern 12b reaches a predetermined initial position. Thereby, before the start of exposure in the exposure regions B and D, the initial position of the downstream mask 12 (masks 123 and 124) is accurately determined with reference to the film 2.
- the conveyance of the film 2 by the conveyance roller or the like is resumed. Then, the film 2 is transported until the exposure target portion is positioned in the irradiation region of the exposure light transmitted through each mask 12, the exposure light from the exposure light source 11 is transmitted through the mask 12, and the exposure of the film 2 is started. Thereby, the alignment film material (exposure material film 21) on the film 2 is aligned in a predetermined direction according to the irradiation angle of the exposure light.
- each pattern 2 c is formed in a band shape along the conveyance direction of the film 2.
- the position of each mask 12 at the start of exposure is adjusted by a pull-in mark 2 b formed at a fixed position with respect to the film 2.
- the positions of the two upstream masks 121 and 122 and the two downstream masks 123 and 124 are accurately set relative to the film.
- a pattern formed by the upstream masks 121 and 122 is used.
- Each mask position is set so that 2c and the pattern 2c formed by the downstream masks 123 and 124 do not overlap each other and are adjacent to each other without forming a gap therebetween.
- the pattern 2c formed in the exposure areas A and C eventually approaches a position corresponding to the downstream masks 123 and 124.
- the position of the mask 12 (123, 124) on the downstream side in the moving direction of the film is separated from the position of the mask 12 (121, 122) on the upstream side by about 4 m in the moving direction of the film.
- the film 2 is displaced in the width direction with respect to the mask 12 due to the meandering of the film 2 on the downstream side in the moving direction of the film. Therefore, the pattern 2 c formed by the upstream masks 121 and 122 is also shifted in the meandering direction of the film 2 and supplied to the exposure areas B and D by the downstream masks 123 and 124.
- an alignment mark detection unit such as a CCD camera is located at a position corresponding to the viewing window 12a (and the light shielding pattern 12b) of the downstream mask 12 (masks 123 and 124) in the moving direction of the film 2.
- a film made of colored ink is formed as a side coating film 22 in a predetermined region from the edge of the film 2, and the alignment mark 2a is clear on the side coating film 22. It is formed with high accuracy.
- the alignment mark 2a is formed so that the relative position in the width direction perpendicular to the moving direction of the film is constant with respect to the upstream masks 121 and 122.
- the alignment mark 2a is detected at a position corresponding to the downstream masks 123 and 124, and the distance between the alignment mark 2a and the downstream masks 123 and 124 is a constant interval on the downstream side in the moving direction of the film 2.
- the positions of the downstream masks 123 and 124 are adjusted. That is, as shown in FIG. 1, for example, when the position of the alignment mark 2a is shifted to the outside in the width direction of the film, the mask position control unit 30 shifts the positions of the downstream masks 123 and 124 with respect to the alignment mark 2a. Move the film outward in the width direction by the amount.
- the mask position control unit 30 shifts the positions of the downstream masks 123 and 124 by the amount by which the alignment mark 2a is shifted. Move inward direction.
- the exposure area by the downstream mask can be accurately compared to the pattern 2c formed by the upstream mask. Can be adjusted well.
- a coating film of colored ink is formed around the alignment mark 2a used for adjusting the mask position. Even when an inexpensive and small detection device such as a CCD camera is used, alignment is performed. The mark 2a can be detected clearly and accurately. Therefore, in this embodiment, meandering of the film 2 can be detected with high accuracy without using an expensive and large-sized detection device for detecting the alignment mark 2a. Therefore, in the present embodiment, during continuous exposure, as shown in FIG. 1, even when the film 2 is displaced in the width direction, the mask 12 (123, 124) on the downstream side in the moving direction of the film 2 is used. By correcting the position, stable exposure can be performed without shifting the exposure position on the film 2.
- the exposure area D is so formed that the pattern formed between the exposure areas A and C is filled in the film 2 with the pattern exposed by the exposure area B and is adjacent to the pattern formed by the exposure area C.
- a pattern is formed.
- the pattern already formed by the exposure areas A and C and the pattern formed by the exposure areas B and D do not overlap or leave unexposed portions, and the pattern is accurately formed on the entire surface of the film. Can be formed.
- the exposure material film 21 and the side coating film 22 are formed on the surface of the film substrate 20.
- the film 2 on which two types of material films are formed is supplied to the exposure apparatus.
- the exposure material film 21 and the side coating film 22 are formed on a line different from the line of the exposure apparatus. May be.
- the exposure material film 21 and / or the side coating film 22 are formed on the surface of the film substrate 20 and are temporarily wound around a take-up reel.
- the other material film is formed on the same line as the exposure apparatus, or another roll. Performed on the Toroll line.
- the roll of the film 2 on which the material film is formed is attached to the supply reel 80 in the line of the exposure apparatus 1, and the film 2 on which the two kinds of material films are formed is supplied to the exposure apparatus 1.
- the alignment laser marker 14 for forming the alignment mark 2a is provided at a position corresponding to the upstream masks 121 and 122 in the film moving direction.
- the alignment laser marker 14 is, for example, It may be provided upstream of the upstream masks 121 and 122 in the film moving direction.
- a new alignment mark detection unit 16 is provided so as to be aligned in the width direction of the upstream masks 121 and 122 and the film 2 in correspondence with the positions of the upstream masks 121 and 122 in the moving direction of the film 2. Just do it.
- the alignment mark detection unit 16 newly disposed may be configured to detect the position of the alignment mark 16a at a position corresponding to the position of the upstream masks 121 and 122.
- the exposure method by the exposure apparatus in which two masks are arranged on the upstream side and the downstream side respectively has been described.
- the present invention detects the meandering of the film by forming the alignment mark and the mask. The position is adjusted and is not limited by the number and arrangement of masks.
- the present invention at least one of both side edges in the width direction of the film base is coated with a colored baking material, a colored photocurable material or colored ink to enhance the laser light absorption rate. Since the film on which the film is formed is supplied and the alignment mark is formed by irradiating the side coating film with the laser beam, the alignment mark can be easily formed. Therefore, the present invention is particularly useful for correcting the meandering of the film in an exposure apparatus that continuously exposes the film.
- 1 exposure apparatus, 10: stage, 11: exposure light source, 12: mask, 12a: viewing window, 12b: light shielding pattern, 120: frame, 121: (first) mask, (122): second mask , 123: (third) mask, 124: (fourth) mask, 125: pattern forming unit, 125a: (mask) pattern, 13: laser marker, 13a: gantry stage, 13b: transport unit, 13c: marking unit , 14: laser marker for alignment, 15: film drawing position detection unit, 16: alignment mark detection unit, 17: mask stage, 2: film, 2a: alignment mark, 2b: drawing mark, 2c: pattern, 20: film base material , 21: exposure material film, 22: side coating film, 30: mask position control unit, 31: image processing unit, 32: calculation , 33: memory, 34: motor drive controller, 35: light source driving section, 36: a mask stage drive control unit, 37: control unit
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Abstract
Description
Claims (3)
- フィルム基材上の露光パターン形成用領域に露光材料膜が形成されたフィルムの前記露光材料膜に、マスクを介して露光光を照射することにより、前記露光材料膜に前記マスクのパターンを露光するフィルム露光方法において、前記フィルム基材の幅方向の両側縁部の少なくとも一方に、有色の焼成材料、有色の光硬化性材料又は有色のインクが塗布されて側部塗布膜が形成されたフィルムを供給し、この側部塗布膜にアライメントマーク用レーザ光を照射してアライメントマークを形成し、このアライメントマークを使用してフィルム蛇行を検出し、前記マスクの位置を調整することを特徴とするフィルム露光方法。
- 前記露光材料膜及び/又は前記側部塗布膜は、供給リールに巻回されたフィルム基材を、前記供給リールから巻取リールまで移動させる間における前記アライメントマーク用レーザ光の照射前に、前記フィルム基材上に形成されることを特徴とする請求項1に記載のフィルム露光方法。
- 前記マスクは、前記フィルムの移動方向の上流側及び下流側に夫々配置されており、前記フィルムの移動方向の上流側及び下流側で前記露光材料膜に夫々前記上流側マスクと下流側マスクのパターンを露光するものであり、
前記フィルムの移動方向における前記上流側マスクの位置に対応する位置で前記側部塗布膜に前記アライメントマークを形成し、前記フィルムの移動方向における前記下流側マスクの位置に対応する位置で前記アライメントマークを検出することにより、前記フィルムが前記上流側マスクによる露光領域から前記下流側マスクによる露光領域まで移動するまでに生じたフィルム蛇行を検出し、前記フィルムに対する下流側マスクの相対的位置を前記フィルム蛇行によりずれた量だけ補正することを特徴とする請求項1又は2に記載のフィルム露光方法。
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CN201180064668.7A CN103314328B (zh) | 2010-11-10 | 2011-10-24 | 膜曝光方法 |
KR1020137014751A KR101781245B1 (ko) | 2010-11-10 | 2011-10-24 | 필름 노광 방법 |
US13/884,192 US8883380B2 (en) | 2010-11-10 | 2011-10-24 | Film exposure method |
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JP2010252206A JP5685756B2 (ja) | 2010-11-10 | 2010-11-10 | フィルム露光方法 |
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JP (1) | JP5685756B2 (ja) |
KR (1) | KR101781245B1 (ja) |
CN (1) | CN103314328B (ja) |
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Cited By (1)
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WO2016114178A1 (ja) * | 2015-01-15 | 2016-07-21 | 株式会社村田製作所 | 露光装置 |
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TW201314374A (zh) * | 2011-09-30 | 2013-04-01 | Chimei Innolux Corp | 配向膜之光配向裝置及配向膜製造方法及液晶顯示裝置製造方法 |
FI124325B (fi) * | 2012-06-08 | 2014-06-30 | Tecnomar Oy | Laserprosessin kohdistuksen mittausmenetelmä |
JP5963194B2 (ja) * | 2012-07-17 | 2016-08-03 | 株式会社ブイ・テクノロジー | 露光装置 |
JP6729954B1 (ja) * | 2019-10-18 | 2020-07-29 | 株式会社 ベアック | 露光装置 |
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2011
- 2011-10-24 CN CN201180064668.7A patent/CN103314328B/zh not_active Expired - Fee Related
- 2011-10-24 KR KR1020137014751A patent/KR101781245B1/ko active IP Right Grant
- 2011-10-24 US US13/884,192 patent/US8883380B2/en not_active Expired - Fee Related
- 2011-10-24 WO PCT/JP2011/074455 patent/WO2012063632A1/ja active Application Filing
- 2011-11-04 TW TW100140367A patent/TWI515704B/zh not_active IP Right Cessation
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JP2006235533A (ja) * | 2005-02-28 | 2006-09-07 | Nikon Corp | 露光装置及びマイクロデバイスの製造方法 |
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JPWO2016114178A1 (ja) * | 2015-01-15 | 2017-06-22 | 株式会社村田製作所 | 露光装置 |
Also Published As
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JP5685756B2 (ja) | 2015-03-18 |
CN103314328A (zh) | 2013-09-18 |
KR101781245B1 (ko) | 2017-09-22 |
US20130230799A1 (en) | 2013-09-05 |
CN103314328B (zh) | 2015-08-26 |
TWI515704B (zh) | 2016-01-01 |
JP2012103500A (ja) | 2012-05-31 |
TW201227644A (en) | 2012-07-01 |
US8883380B2 (en) | 2014-11-11 |
KR20140006804A (ko) | 2014-01-16 |
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