WO2012026682A2 - 무점착 송장 라벨과 이의 제조방법 - Google Patents
무점착 송장 라벨과 이의 제조방법 Download PDFInfo
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- WO2012026682A2 WO2012026682A2 PCT/KR2011/005556 KR2011005556W WO2012026682A2 WO 2012026682 A2 WO2012026682 A2 WO 2012026682A2 KR 2011005556 W KR2011005556 W KR 2011005556W WO 2012026682 A2 WO2012026682 A2 WO 2012026682A2
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
Definitions
- the present invention relates to a non-sticky invoice label and a method of manufacturing the same, to simplify the process and reduce the production cost, and to a non-sticky invoice label and its manufacturing method for minimizing the defective rate.
- another non-adhesive white ink is applied to the surface of the pressure-sensitive adhesive without using a non-adhesive composition to reduce the interfacial area between the intermediate paper and the battery to help peel the battery or to apply the white ink.
- the heat-resistant of the pressure-sensitive adhesive should be kept high when the white ink is dried, the battery to be separated is partially maintained by the white ink.
- the cut line should be additionally made by die cutting the separated part of the battery.
- it has the complexity of using a middle finger, and the surface of the intermediate paper from which the battery has been peeled off also retains the adhesiveness, thus failing to function as an adhesive-free invoice label.
- non-adhesive label invoice of Utility Model Registration No. 305874, filed with the Korean Intellectual Property Office, consists of Fuji peeled off, a battery constituting the invoice printing surface, and a middle finger coated with adhesive on the upper and lower surfaces between the Fuji and the battery. It laminated
- the non-stick polymer layer is a non-adhesive polymer layer, which serves to bond the battery to the stop, and is not configured to be contaminated by foreign matters because it does not exhibit adhesive strength once the battery is removed from the stop.
- the thin film is passed through a thin nonstick polymer layer, thereby allowing the battery to maintain adhesion to the adhesive of the middle finger.
- the thin thin nonstick polymer layer is a high temperature and high pressure laminating process to allow the adhesive on the middle portion of the medium to pass through the micropores of the polymer layer to temporarily maintain the adhesive force with the battery.
- it is made by treating the surface of the adhesive layer applied on the upper part of the middle part of the thin film that passes the adhesive finely. After removing the battery, it is not completely tack free, and stickiness remains due to the adhesive passed through the pores.
- the middle finger and the battery as the adhesive maintains the adhesive force, so it requires some excessive force, which causes the middle and upper limbs to be damaged.
- related coating materials such as pressure-sensitive adhesives also need to be prepared as a special material that withstands high heat, resulting in an increase in manufacturing cost.
- the present invention is to solve the problems with the conventional non-adhesive invoice label as described above, to avoid the use of intermediate paper, and to complete the non-adhesive invoice label only by coating the first and second coating liquid, thereby We want to achieve cost savings through simplification and elimination of intermediate papers.
- the adhesive-free invoice label is formed by applying a first coating liquid emulsified with a thermal paper and a polyolefin resin having a molecular weight of 800 ⁇ 1,300 with an emulsifier on the lower surface of the thermal paper
- a second coating layer formed by applying a first coating layer and latex containing 35 to 45% by weight of n-butylacrylate with respect to the total weight on the lower surface of the first coating layer as a second coating liquid, and the second coating layer It characterized in that it comprises a pressure-sensitive adhesive layer formed on the lower surface of the, and a release paper attached to the lower surface of the pressure-sensitive adhesive layer.
- the first coating layer may include an emulsifier for emulsifying the polyolefin resin in the first coating solution, wherein the emulsifier is 3 to 8% by weight of polyoxyethylene stearyl ether based on the total weight of the first coating solution. It is characterized by that.
- the first coating layer may include a stabilizer for emulsion stability of the polyolefin resin in the first coating solution, wherein the stabilizer is 3 to 8% by weight of cetyl alcohol based on the total weight of the first coating solution. do.
- the first coating layer is characterized in that the first coating solution contains 1 to 3% by weight of a water-soluble thickener based on the total weight of the first coating solution.
- the latex is emulsion polymerization of at least one acrylic monomer having a glass transition temperature range of -50 ⁇ -60 °C or at least one vinyl monomer having a glass transition temperature range of 95 ⁇ 105 °C with a sulfate-based emulsifier And a water-soluble thickener is mixed with the emulsion-polymerized product.
- the sulfate-based emulsifier is characterized in that 0.5 to 2.0% by weight relative to the total weight of the latex.
- the latex contains an initiator used in the polymerization, the initiator is characterized in that the persulfate of 0.3 to 1.0% by weight relative to the total weight of the latex.
- the step of forming a first coating layer by applying a first coating liquid emulsified polyolefin resin having an molecular weight of 800 ⁇ 1,300 with an emulsifier on the surface of the thermal paper; And applying a latex having 35% to 45% by weight of n-butyl acrylate to the surface of the first coating layer as a second coating liquid to form a second coating layer, and adhering to the surface of the second coating layer. Forming a layer.
- the forming of the first coating layer may include melting the polyolefin resin and polyoxyethylene stearyl ether which is 3 to 8% by weight based on the total weight of the first coating liquid in the melt of the polyolefin resin. Melting and blending, distilled water is added dropwise to the product of melting and blending by the polyoxyethylene stearyl ether, stirred and cooled to room temperature, and cooling to the room temperature. Adding 3-8 wt% of cetyl alcohol to the total weight of the first coating solution and mixing the mixture; and adding 1-3 wt% of a water-soluble thickener with respect to the total weight of the first coating solution to the mixture of cetyl alcohol. Characterized in that it comprises a step of stirring.
- the forming of the second coating layer may include: sulphating one or more acrylic monomers having a glass transition temperature range of -50 to -60 ° C or one or more vinyl monomers having a glass transition temperature range of 95 to 105 ° C.
- Emulsion polymerization with a system-based emulsifier, and the step of mixing the water-soluble thickener to the emulsion-polymerized product may include: sulphating one or more acrylic monomers having a glass transition temperature range of -50 to -60 ° C or one or more vinyl monomers having a glass transition temperature range of 95 to 105 ° C.
- the step of emulsion polymerization characterized in that the persulfate-based initiator is 0.3 to 1.0% by weight relative to the total weight of the latex.
- the sulfate-based emulsifier is characterized in that 0.5 to 2.0% by weight relative to the total weight of the latex.
- a non-adhesive invoice label and a method of manufacturing the same can reduce production costs due to the simplification of the process and elimination of intermediate papers, and can reduce resource waste caused by the use of the intermediate papers.
- FIG. 1 is a cross-sectional view showing a tacky invoice label in accordance with the present invention
- Figure 2 is a perspective view of a tack free invoice label according to the present invention.
- FIG. 1 is a cross-sectional view showing a tack free invoice label according to the present invention.
- the non-adhesive invoice label 10 is an invoice label which directly coats the first and second coating liquids on the thermal paper 11 so as to omit the intermediate paper, the thermal paper 11,
- the first coating layer 12, the second coating layer 13, the adhesive layer 14, and the release paper 15 are sequentially formed on the bottom surface of the thermal paper 11.
- the thermal paper 11 is colored when a chemical substance is applied and heat, and the name, address and telephone number of the consignee and the consignee are printed on the upper surface thereof.
- the first coating layer 12 is formed by applying a first coating solution obtained by emulsifying a polyolefin resin having a molecular weight of 800 to 1,300 with an emulsifier on the surface of the thermal paper 11, that is, the lower surface thereof.
- a first coating solution obtained by emulsifying a polyolefin resin having a molecular weight of 800 to 1,300 with an emulsifier on the surface of the thermal paper 11, that is, the lower surface thereof.
- the molecular weight of the polyolefin resin is less than 800, it is impregnated into the thermal paper 11 in the oil phase after drying, the secondary coating solution is not settled, the printability of the thermal paper 11 is not shown.
- the molecular weight exceeds 1,300, the polyolefin resin is too hot to be emulsified during the emulsification process.
- the first coating layer 12 contains an emulsifier for the emulsification of the polyolefin resin in the first coating solution, the emulsifier is 3 to 8% by weight of polyoxyethylene stearyl ether (to the total weight of the first coating solution) Is preferred.
- polyoxyethylene stearyl is less than 3% with respect to the total weight of the first coating liquid, the emulsification power is weak to make a large particle, the quality of the coated surface is reduced, while the total weight of the first coating liquid When it exceeds 8%, due to the influence of the excess emulsifier, a time-dependent change in the peel strength at the time of peeling the thermal paper 11 is brought.
- the first coating layer 12 includes a stabilizer for emulsion stability of the polyolefin resin in the first coating liquid, it is preferred that the stabilizer is 3 to 8% by weight of cetyl alcohol relative to the total weight of the first coating liquid.
- the stabilizer is 3 to 8% by weight of cetyl alcohol relative to the total weight of the first coating liquid.
- cetyl alcohol is less than 3% of the total weight of the first coating solution, the emulsion stability is weak, so that the aggregation of particles decreases the storage stability.
- the content of the first coating solution exceeds 8%, the effect of the excess stabilizer This lowers the thermal performance of the thermal paper 11.
- the first coating layer 12 may include a water-soluble thickener of 1 to 3% by weight based on the total weight of the first coating liquid in the first coating liquid.
- the second coating layer 13 is formed by applying a latex containing 35 to 45% by weight of n-butyl acrylate relative to the total weight on the surface of the first coating layer 12, that is, the lower surface thereof as a second coating liquid.
- a latex containing 35 to 45% by weight of n-butyl acrylate relative to the total weight on the surface of the first coating layer 12, that is, the lower surface thereof as a second coating liquid if the n-butyl acrylate is less than 35% by weight relative to the total weight of the latex, there is a fear that the thermal paper 11 is detached during thermal printing, and if the n-butyl acrylate exceeds 45% by weight relative to the total weight of the latex, the adhesive force becomes stronger and the thermal paper ( 11) It requires more force than necessary for peeling.
- the latex is emulsified by emulsion polymerization of at least one acrylic monomer having a glass transition temperature range of -50 ⁇ -60 °C or at least one vinyl monomer having a glass transition temperature range of 95 ⁇ 105 °C with a sulfate-based emulsifier, emulsified
- a water soluble thickener may be mixed in the polymerized product.
- the sulfate-based emulsifier is preferably 0.5 to 2.0% by weight based on the total weight of the latex.
- the emulsion-based emulsifier is less than 0.5% by weight relative to the total weight of the latex, the stability of the particles is poor, and the polymerization is not performed smoothly. Poor polymerization stability due to viscosity increase.
- the latex contains an initiator used in the polymerization, it is preferred that the initiator is persulfate of 0.3 to 1.0% by weight based on the total weight of the latex.
- the persulfate-based initiator is less than 0.3% by weight relative to the total weight of the latex, the reaction conversion rate is lowered, resulting in deterioration of quality due to the unreacted monomer, and when it exceeds 1.0% by weight relative to the total weight of the latex, the molecular weight decreases, Will increase.
- the adhesive layer 14 is formed by applying an adhesive to the surface of the second coating layer 13, that is, the lower surface, and provides an adhesive force for attaching the thermal paper 11 to the object to be attached.
- the release paper 15 adheres to the surface of the adhesive layer 14, that is, the bottom surface, so that the release paper 15 is easily separated from the adhesive layer 14, thereby facilitating the process of attaching the thermal paper 11 to the object to be attached as the adhesive layer 14. .
- the adhesive layer 14 is attached to an attachment object such as a delivery box by removing the release paper 15 (shown in FIG. 1).
- the thermal paper 11 needs to be removed, when the thermal paper 11 is separated from the invoice label, the thermal paper 11 and the first coating layer 12 are separated from the second coating layer 13, and the separated surface has adhesive force. Doing so prevents foreign matter from sticking to the separation surface.
- Method for producing a non-adhesive invoice label comprises the steps of forming a first coating layer 12 by applying a first coating solution emulsified polyolefin resin having a molecular weight of 800 ⁇ 1,300 with an emulsifier on the surface of the thermal paper (11), Applying to the surface of the first coating layer 12 an acrylic latex having 35% to 45% by weight of n-butylacrylate as a second coating liquid to form a second coating layer 13, and a second coating layer And forming an adhesive layer 14 on the surface of (13).
- the step of forming the first coating layer may include melting the polyolefin resin to form the first coating liquid, and polyoxyethyl resteraryl which is 3 to 8% by weight based on the total weight of the first coating liquid in the melt of the polyolefin resin. Melting and blending the ether, dropping distilled water into the mixture of polyoxyethylesteraryl ether, stirring and cooling to room temperature, and cooling to room temperature before the first coating solution is transferred to the resultant. Adding 3 to 8% by weight of cetyl alcohol with respect to the weight, and mixing; and adding and mixing 1 to 3% by weight of a water-soluble thickener with respect to the total weight of the first coating solution in the mixture of cetyl alcohol. have.
- the polyolefin has a molecular weight of 800 ⁇ 1,300, if the molecular weight is less than 800 is impregnated in the thermal paper 11 in the oil after drying, the second coating solution is not settled, the printability of the thermal paper (11) does not appear, the molecular weight is If it exceeds 1,300, the hot melt viscosity during the emulsification process is too high to emulsify.
- the polyoxyethylene stearyl ether is preferably 3 to 8% of the total weight of the first coating liquid as an emulsifier, and the polyoxyethyl stearyl ether is 3 to the total weight of the first coating liquid. If it is less than%, the emulsifying power is weak to make huge particles, and the quality of the coated surface is lowered. On the other hand, if it exceeds 8% with respect to the total weight of the first coating liquid, when the thermal paper 11 is peeled off due to the effect of the excess emulsifier. This will cause a change in peel strength over time.
- cetyl alcohol is 3 to 8% by weight based on the total weight of the first coating solution for emulsification stability of the first coating solution.
- the stability is weak, the aggregates of particles impair the storage stability.
- the amount exceeds 8% with respect to the total weight of the first coating solution, the thermal performance of the thermal paper 11 is lowered due to the influence of the excess stabilizer.
- the first coating solution contains a water-soluble thickener to improve storage stability and coating processability.
- Example 1 30% by weight of polyolefin was taken into the reactor and completely melted while maintaining at 135 ° C, followed by 8% by weight of polyoxyethylene stearyl ether to be melt blended evenly. 15% by weight of distilled water was added dropwise thereto in 2 hours, and then 42% by weight of distilled water was added dropwise in 1 hour. Then, stirring was continued for 30 minutes, and then cooled to 10 ° C or more per minute. After cooling, the resultant product was cooled to room temperature, and then 3 wt% of cetyl alcohol was uniformly blended, 2 wt% of a water-soluble thickener was added thereto, and then stirred in a stable state to complete the first coating solution.
- Example 2 the same procedure as in Example 1 was carried out, but the first coating solution was completed by changing the molecular weight of the polyolefin and the addition amount of the emulsifier, stabilizer, water-soluble thickener and the like as shown in Table 1 below.
- Comparative Example 1 a heat curable silicone release agent used as a general release coating solution was used as the first coating solution.
- the forming of the second coating layer may include one or more acrylic monomers having a glass transition temperature range of -50 to -60 ° C or one or more glass transition temperature ranges of 95 to 105 ° C for the preparation of the second coating solution. It can be achieved by a latex production method using a styrene-butyl-acrylic copolymer comprising a step of emulsion polymerization of a vinyl monomer with a sulfate-based emulsifier, and a step of admixing a water-soluble thickener in the emulsion-polymerized product and a coating agent therefrom. .
- the second coating liquid of the present invention is n-butyl acrylate used for the purpose of giving the flexibility to withstand the bending or warping of the label when the thermal printing on the thermal paper 11 with respect to the total weight of the latex, for example acrylic latex It is preferable to contain 35 to 45% by weight, and if the content of n-butyl acrylate is less than 35% by weight relative to the total weight of the acrylic latex, there is a fear of detachment of the thermal paper 11 during thermal printing, and the total weight of the latex If it exceeds 45% by weight, the adhesive force becomes stronger, and more than necessary force is required during peeling of the thermal paper 11.
- the emulsifier used for emulsion stability during polymerization of the second coating liquid may be optionally used among one or two sulfate anionic emulsifiers, and preferably contains 0.5 to 2.0% by weight based on the total weight of the acrylic latex. Is less than 0.5% by weight with respect to the total weight of the acrylic latex, the stability of the particles is poor, and the polymerization is not performed smoothly; if it exceeds 2.0% by weight with respect to the total weight of the acrylic latex, the particle size is excessively reduced to increase the viscosity during polymerization. Poor polymerization stability.
- the initiator used in the polymerization of the second coating solution may use a persulfate system, and preferably contains 0.3 to 1.0% by weight based on the total weight of the acrylic latex, and if the initiator of the persulfate system is 0.3 to the total weight of the acrylic latex If the content is less than% by weight, the reaction conversion rate is lowered, resulting in deterioration due to the unreacted monomer. When the content is more than 1.0% by weight based on the total weight of the acrylic latex, the molecular weight decreases, thereby increasing adhesion.
- Example 1 39.024% by weight of distilled water and 0.5% by weight of ammonium persulfate initiator relative to the total weight of acryl latex are maintained in the reactor at 80 ° C.
- distilled water was added to 11.707% by weight relative to the total weight of the acrylic latex
- sodium lauryl sulfate emulsifier was 0.5% by weight relative to the n-butylacrylate monomer
- Example 2 the same procedure as in Example 1 described above was performed, but the addition amount of the styrene monomer, the n-butyl acrylate monomer and the emulsifier, and the initiator was changed as shown in Table 2 to complete the second coating solution. It was.
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Abstract
Description
증류수 | 폴리올레핀 수지 | 유화제 | 안정제 | 수성증점제 | 감열성능 | 도포물성 | 박리강도(gf) | 라벨 이탈 | 저장안정성 | |
실시예 1 | 57 | 30 | 8 | 3 | 2 | 양호 | ◎ | 90 | 없음 | 양호 |
실시예 2 | 62 | 30 | 3 | 3 | 2 | 양호 | ○ | 130 | 없음 | 양호 |
실시예 3 | 60 | 30 | 4 | 4 | 2 | 양호 | ○ | 120 | 없음 | 양호 |
실시예 4 | 61 | 30 | 5 | 4 | 2 | 양호 | ◎ | 120 | 없음 | 양호 |
실시예 5 | 59 | 30 | 6 | 5 | 2 | 양호 | ◎ | 120 | 없음 | 양호 |
실시예 6 | 58 | 30 | 7 | 5 | 2 | 양호 | ◎ | 100 | 없음 | 양호 |
실시예 7 | 56 | 30 | 8 | 6 | 2 | 양호 | ◎ | 100 | 없음 | 양호 |
실시예 8 | 61 | 30 | 3 | 6 | 2 | 양호 | ○ | 120 | 없음 | 양호 |
실시예 9 | 59 | 30 | 4 | 7 | 2 | 양호 | △ | 120 | 없음 | 양호 |
실시예 10 | 57 | 30 | 5 | 8 | 2 | 양호 | ◎ | 110 | 없음 | 양호 |
비교예 1 | - | - | - | - | - | 불량 | × | 20 | 있음 | - |
비교예 2 | - | - | - | - | - | 양호 | × | 20 | 있음 | - |
n-부틸아크릴레이트 단량체 | 스틸렌 단량체 | 개시제 | 유화제 | 유리전이온도(℃) | 분자량(Mw) | 박리강도(gf) | 라벨이탈 | |
실시예 1 | 39.6 | 59.4 | 0.5 | 0.5 | 18.1℃ | 420,000 | 100 | 없음 |
실시예 2 | 35.0 | 63.7 | 0.3 | 1.0 | 25.5℃ | 480,000 | 110 | 없음 |
실시예 3 | 37.0 | 60.5 | 0.5 | 2.0 | 21.4℃ | 380,000 | 85 | 없음 |
실시예 4 | 42.0 | 56.7 | 0.8 | 0.5 | 14.1℃ | 340,000 | 80 | 없음 |
실시예 5 | 45.0 | 53.0 | 1.0 | 1.0 | 10.0℃ | 330,000 | 130 | 없음 |
Claims (12)
- 무점착 송장 라벨(10)에 있어서,감열지(11)와,상기 감열지의 하면에 분자량 800~1,300을 가지는 폴리올레핀 수지를 유화제로 유화시킨 제 1 코팅액을 도포하여 형성되는 제 1 코팅층(12)과,상기 제 1 코팅층의 하면에 전 중량에 대하여 35~45중량%의 n-부틸아크릴레이트가 함유한 라텍스를 제 2 코팅액으로 하여 도포하여 형성되는 제 2 코팅층(13)과,상기 제 2 코팅층의 하면에 형성되는 점착층(14)과,상기 점착층의 하면에 부착되는 이형지(15)를 포함하는 무점착 송장 라벨.
- 제 1 항에 있어서, 제 1 코팅층은,상기 제 1 코팅액에 상기 폴리올레핀 수지의 유화를 위하여 유화제가 포함되되, 상기 유화제가 상기 제 1 코팅액의 전 중량에 대하여 3~8중량%의 폴리옥시에틸렌스테아릴이써인 것을 특징으로 하는 무점착 송장 라벨.
- 제 1 항 또는 제 2 항에 있어서, 상기 제 1 코팅층은,상기 제 1 코팅액에 상기 폴리올레핀 수지의 유화 안정을 위한 안정제가 포함되되, 상기 안정제가 상기 제 1 코팅액의 전 중량에 대하여 3~8중량%의 세틸알콜인 것을 특징으로 하는 무점착 송장 라벨.
- 제 1 항 또는 제 2 항에 있어서, 상기 제 1 코팅층은,상기 제 1 코팅액에 상기 제 1 코팅액의 전 중량에 대하여 1~3중량%의 수용성 증점제가 포함되는 것을 특징으로 하는 무점착 송장 라벨.
- 제 1 항에 있어서, 상기 라텍스는,유리전이 온도 범위가 -50~-60℃에 해당하는 하나 이상의 아크릴계 단량체 또는 유리전이 온도 범위가 95~105℃에 해당하는 하나 이상의 비닐계 단량체를 설페이트계 유화제로 유화 중합시키고, 유화 중합된 결과물에 수용성 증점제가 혼합되는 것을 특징으로 하는 무점착 송장 라벨.
- 제 5 항에 있어서, 상기 설페이트계 유화제는,상기 라텍스의 전 중량에 대하여 0.5~2.0중량%인 것을 특징으로 하는 무점착 송장 라벨.
- 제 5 항에 있어서, 상기 라텍스는 중합시 사용되는 개시제가 함유되며,상기 개시제는 상기 라텍스의 전 중량에 대하여 0.3 ~ 1.0중량%의 퍼설페이트계인 것을 특징으로 하는 무점착 송장 라벨.
- 무점착 송장 라벨을 제조하는 방법에 있어서,감열지의 표면에 분자량 800~1,300을 가지는 폴리올레핀 수지를 유화제로 유화시킨 제 1 코팅액을 도포하여 제 1 코팅층을 형성하는 단계와,상기 제 1 코팅층의 표면에 전 중량에 대하여 n-부틸아크릴레이트가 35~45중량%인 라텍스를 제 2 코팅액으로 하여 도포하여 제 2 코팅층을 형성시키는 단계와,상기 제 2 코팅층의 표면에 점착층을 형성시키는 단계를 포함하는 것을 특징으로 하는 무점착 송장 라벨의 제조방법.
- 제 8 항에 있어서, 상기 제 1 코팅층을 형성하는 단계는,폴리올레핀 수지를 용융시키는 단계와,상기 폴레올레핀 수지의 용융물에 상기 제 1 코팅액의 전 중량에 대하여 3~8중량%인 폴리옥시에틸렌스테아릴이써를 용융 및 블랜딩시키는 단계와,상기 폴리옥시에틸렌스테아릴이써에 의한 용융 및 블랜딩의 결과물에 증류수를 적하시키고 교반한 후 상온으로 냉각시키는 단계와,상기 상온으로 냉각시키는 단계에 의해 냉각된 결과물에 상기 제 1 코팅액의 전 중량에 대하여 3~8중량%인 세틸알콜을 투입하여 혼합하는 단계와,상기 세틸알콜의 혼합물에 상기 제 1 코팅액의 전 중량에 대하여 1~3중량%인 수용성 증점제를 투입하여 교반하는 단계를 포함하는 것을 특징으로 하는 무점착 송장 라벨의 제조방법.
- 제 8 항에 있어서, 상기 제 2 코팅층을 형성하는 단계는,유리전이 온도 범위가 -50 ~ -60℃에 해당하는 하나 이상의 아크릴계 단량체 또는 유리전이 온도 범위가 95 ~ 105℃에 해당하는 하나 이상의 비닐계 단량체를 설페이트계 유화제로 유화 중합시키는 단계와,상기 유화 중합된 결과물에 수용성 증점제를 혼합시키는 단계를 포함하는 것을 특징으로 하는 무점착 송장 라벨의 제조방법.
- 제 10 항에 있어서, 상기 유화 중합시키는 단계는,상기 라텍스의 전 중량에 대하여 0.3 ~ 1.0중량%인 퍼설페이트계 개시제를 혼합하는 것을 특징으로 하는 무점착 송장 라벨의 제조방법.
- 제 10 항에 있어서, 상기 설페이트계 유화제는,상기 라텍스의 전 중량에 대하여 0.5 ~ 2.0중량%인 것을 특징으로 하는 무점착 송장 라벨의 제조방법.
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CN103498390A (zh) * | 2013-09-28 | 2014-01-08 | 云梦县德邦实业有限责任公司 | 可分离热敏纸及其制备方法 |
JP2016175410A (ja) * | 2015-03-19 | 2016-10-06 | キム,ウンチョルKIM, Eun Chul | 無粘着性送り状ラベル及びその製造方法 |
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CN107254799B (zh) * | 2017-07-04 | 2019-02-22 | 吉林化工学院 | 一种环保型外贸物流运单标签的制备方法 |
KR102416872B1 (ko) | 2021-07-19 | 2022-07-05 | 주식회사 윈글로벌 | 개인정보 제거가 가능한 운송장 |
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WO2012026682A3 (ko) | 2012-05-31 |
KR101011974B1 (ko) | 2011-02-01 |
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