Classifications

• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K3/00—Use of inorganic substances as compounding ingredients
  • C08K3/38—Boron-containing compounds
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K3/00—Use of inorganic substances as compounding ingredients
  • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
  • C08K3/24—Acids; Salts thereof
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K9/00—Use of pretreated ingredients
  • C08K9/02—Ingredients treated with inorganic substances

Definitions

• Halogenated polymers are frequently used in the construction of almost all types of buildings, homes, and offices.
• One reason for using halogenated polymers, rather than other polymers, is that halogenated polymers are comparatively less flammable. Although these polymers are less flammable, they tend to produce a lot of smoke during combustion, particularly when they contain plasticizers. Consequently, governments and municipalities have set limits on smoke development during polymer combustion that can be difficult to meet with ordinary chlorinated polymers.
• the disclosed smoke suppressants are useful in thermoplastic polymer compositions and in other polymer compositions.
• the smoke suppressants comprise from about 75% to about 95% by weight of a borate core material; and from about 5% to about 25% by weight of zinc molybdate.
• the smoke suppressants can also be defined as the reaction product of a borate core material, a zinc compound, and a molybdate compound. Additionally, the smoke suppressants can comprise a borate core and zinc molybdate, which is precipitated on the borate core.
• the smoke suppressants can be prepared by reacting an aqueous slurry comprising a borate core material and zinc oxide with an aqueous molybdenum trioxide mixture to produce a product slurry, filtering the product slurry, and drying the product slurry to produce a dried mass.
• Thermoplastic polymer compositions can comprise the smoke suppressants along with a chlorine-containing polymer, for example.
• Smoke suppressant characteristics of a variety of polymer compositions can be improved by compounding a disclosed smoke suppressant with a polymer composition.
• Fig. 1 is a bar plot obtained from a four minute NBS smoke density for Control (no smoke suppressant), KG911C (commercial smoke suppressant), zinc borate core smoke suppressant of the present invention, and a physical blend of zinc borate and zinc molybdate.
• Fig. 2 is a bar plot showing maximum smoke density for Control (no smoke suppressant), KG911C (commercial smoke suppressant), zinc borate core smoke suppressant of the present invention, and a physical blend of zinc borate and zinc molybdate.
• Inorganic molybdates are the industry standard for smoke suppression because of their ability to promote char formation.
• a core material such as zinc borate or calcium borate
• smoke suppression capability increases. It is believed from observing the present invention, though not certain, that increasing the surface area of smoke suppressant particles by precipitating a molybdate on the core material results in smoke suppression improvements.
• the smoke suppressants can be prepared by precipitating zinc molybdate onto a smoke-suppressing borate core, such as zinc borate or calcium borate.
• a smoke-suppressing borate core such as zinc borate or calcium borate.
• the zinc molybdate on the surface of the borate core significantly increases smoke suppression performance.
• Smoke suppression performance of the inventive suppressants is even improved relative to a physical mixture of zinc molybdate and a borate core.
• Precipitation of zinc molybdate can be accomplished through a reaction between zinc oxide and a molybdenum source, such as molybdenum trioxide, ammonium
• dimolybdate, or ammonium octomolybdate in the presence of a core material, capable of acting as a smoke suppressant, such as zinc borate or calcium borate.
• surface treatment of the core can include the following steps: a) preparing a slurry of core material and zinc oxide in water; b) heating the slurry to between about 75 and 80 °C; c) adding molybdenum trioxide (M0O 3 ) in a stoichiometric ratio of 2:3 (2 molar parts molybdenum trioxide, 3 molar parts zinc oxide) to form ⁇ 3 ⁇ 2 ⁇ 9 ; d) stirring the slurry for about 2 hours; and e) filtering, drying, and optionally grinding the resulting product.
• M0O 3 molybdenum trioxide
• Zinc borate or calcium borate are preferred core materials.
• the core materials can have a particle size of about 1 to about 45 microns.
• the dried product can be milled using a lave grinder or another useful device.
• the zinc molybdate content in the smoke suppressant can be in the range of about 5% to about 25% by weight, and the core material can be in the range of about 75% to about 95% by weight, based on the total weight of the smoke suppressant.
• the smoke suppressant has a greater total surface area than any of the individual components or mixtures of any of the individual components.
• the smoke suppressant performs better in an NBS Smoke test than a physical mixture of zinc borate and zinc molybdate.
• the smoke suppressants can be incorporated into thermoplastic polymer or other polymer compositions to enhance smoke suppressing capacity of these compositions.
• These compositions generally comprise a polymer, preferably a chlorine or other halogen- containing polymer, together with a disclosed smoke suppressant.
• Smoke suppression capacity of polymers can be improved by compounding the polymer with the smoke suppressant.
• polyvinyl chloride such as a flexible polyvinylchloride (PVC).
• PVC polyvinylchloride
• the polymer compositions can comprise a plasticizer, a flame retardant, or a thermal stabilizer.
• Useful plasticizers include dioctyl phthalate plasticizers.
• Useful flame retardants include antimony trioxide.
• the polymer composition can also include aluminum hydroxide.
• PVC containing the borate core smoke suppressant can be made by blending about 30 phr to about 60 phr (parts by weight per hundred parts of resin) of aluminum trihydrate, and about 5 phr to about 15 phr of the borate core smoke suppressant with the blend of the base formula for flexible PVC resin listed in Table 1.
• the components of the formulation are mixed in a Waring blender mixing vessel.
• the flexible PVC specimens are fused using a 75 -mL Brabender Plasticarder Digisystem equipped with Type 6 roller blades (3:2 speed ratio).
• the fusion process parameters include a mixing temperature of 165 °C and a mixing time of about 5 min.
• the fused samples are
• ASTM E662 NBS Smoke Chamber The release of smoke generated by the combustion of plastic materials can be determined using the National Bureau of Standards (NBS) smoke chamber method, standardized in the U.S. as ASTM E662. This test was originally developed to determine the smoke generating characteristics of plastic materials used in aircraft construction. The NBS smoke chamber measures smoke density
• PVC plaques were made by adding to the PVC composition of Table 1 varying amounts of: 1) a commercial smoke suppressant, KG911C from The Sherwin-Williams Company, 2) a physical mixture of zinc borate and zinc molybdate, and 3) the inventive borate core smoke suppressant prepared according to Example 1 using zinc borate.
• the samples had total smoke suppressant content levels of 5 phr, 10 phr, and 15 phr (parts per hundred PVC resin).
• the control sample (no smoke suppressant) contains 50 phr aluminum trihydrate (ATH). Samples having 15 phr of smoke suppressant contain 35 phr ATH;
• Figs. 1 and 2 show results from a four minute NBS smoke density test for Control (no smoke suppressant), KG911C (commercial smoke suppressant), zinc borate core smoke suppressant of the present invention, and a physical blend of zinc borate and zinc molybdate.
• Fig. 2 shows maximum smoke density for Control (no smoke suppressant), KG911C (commercial smoke suppressant), zinc borate core smoke suppressant of the present invention, and a physical blend of zinc borate and zinc molybdate.

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• Chemical & Material Sciences (AREA)
• Health & Medical Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Medicinal Chemistry (AREA)
• Polymers & Plastics (AREA)
• Organic Chemistry (AREA)
• Compositions Of Macromolecular Compounds (AREA)

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• 2011
  • 2011-04-15 US US13/087,432 patent/US8277703B2/en active Active
  • 2011-04-20 WO PCT/US2011/033167 patent/WO2011133621A1/en not_active Ceased
  • 2011-04-20 JP JP2013506258A patent/JP5710744B2/ja active Active

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