WO2011122233A1 - 機械構造用鋼の切削方法 - Google Patents
機械構造用鋼の切削方法 Download PDFInfo
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- WO2011122233A1 WO2011122233A1 PCT/JP2011/054932 JP2011054932W WO2011122233A1 WO 2011122233 A1 WO2011122233 A1 WO 2011122233A1 JP 2011054932 W JP2011054932 W JP 2011054932W WO 2011122233 A1 WO2011122233 A1 WO 2011122233A1
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 153
- 239000010959 steel Substances 0.000 title claims abstract description 153
- 238000005520 cutting process Methods 0.000 title claims abstract description 106
- 238000000034 method Methods 0.000 title claims abstract description 45
- 239000003595 mist Substances 0.000 claims abstract description 75
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 41
- 239000001301 oxygen Substances 0.000 claims abstract description 41
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 41
- 239000007789 gas Substances 0.000 claims abstract description 35
- 230000001590 oxidative effect Effects 0.000 claims abstract description 23
- 239000012535 impurity Substances 0.000 claims abstract description 5
- 239000002173 cutting fluid Substances 0.000 claims description 55
- 229910000746 Structural steel Inorganic materials 0.000 claims description 32
- 238000005507 spraying Methods 0.000 claims description 9
- 238000007599 discharging Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 abstract description 5
- 239000010730 cutting oil Substances 0.000 abstract description 4
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 4
- 229910052782 aluminium Inorganic materials 0.000 abstract description 3
- 229910052748 manganese Inorganic materials 0.000 abstract description 2
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 2
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 86
- 239000000463 material Substances 0.000 description 74
- 230000000694 effects Effects 0.000 description 69
- 239000012159 carrier gas Substances 0.000 description 39
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 34
- 230000001965 increasing effect Effects 0.000 description 20
- 239000003921 oil Substances 0.000 description 16
- 235000019198 oils Nutrition 0.000 description 16
- 229920006395 saturated elastomer Polymers 0.000 description 16
- 239000006104 solid solution Substances 0.000 description 15
- 238000002844 melting Methods 0.000 description 12
- 230000008018 melting Effects 0.000 description 12
- 230000001681 protective effect Effects 0.000 description 12
- 238000001816 cooling Methods 0.000 description 10
- 239000002245 particle Substances 0.000 description 10
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 8
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 8
- 230000001050 lubricating effect Effects 0.000 description 8
- 229910000859 α-Fe Inorganic materials 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
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- 229910052751 metal Inorganic materials 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 238000005461 lubrication Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 229910001566 austenite Inorganic materials 0.000 description 4
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- 238000003801 milling Methods 0.000 description 4
- 238000004881 precipitation hardening Methods 0.000 description 4
- 230000001629 suppression Effects 0.000 description 4
- 229910052720 vanadium Inorganic materials 0.000 description 4
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 3
- 238000005242 forging Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910052758 niobium Inorganic materials 0.000 description 3
- 238000005096 rolling process Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 238000007514 turning Methods 0.000 description 3
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910052797 bismuth Inorganic materials 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000000112 cooling gas Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
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- 230000007613 environmental effect Effects 0.000 description 2
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- 229910052735 hafnium Inorganic materials 0.000 description 2
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- 230000020169 heat generation Effects 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 239000010687 lubricating oil Substances 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 102200082816 rs34868397 Human genes 0.000 description 2
- 238000010079 rubber tapping Methods 0.000 description 2
- 229910052711 selenium Inorganic materials 0.000 description 2
- 230000003746 surface roughness Effects 0.000 description 2
- 229910052715 tantalum Inorganic materials 0.000 description 2
- 229910052714 tellurium Inorganic materials 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- 229910017231 MnTe Inorganic materials 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
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- 239000002826 coolant Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- -1 etc. is specified Inorganic materials 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 229910001562 pearlite Inorganic materials 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
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- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23Q—DETAILS, COMPONENTS, OR ACCESSORIES FOR MACHINE TOOLS, e.g. ARRANGEMENTS FOR COPYING OR CONTROLLING; MACHINE TOOLS IN GENERAL CHARACTERISED BY THE CONSTRUCTION OF PARTICULAR DETAILS OR COMPONENTS; COMBINATIONS OR ASSOCIATIONS OF METAL-WORKING MACHINES, NOT DIRECTED TO A PARTICULAR RESULT
- B23Q11/00—Accessories fitted to machine tools for keeping tools or parts of the machine in good working condition or for cooling work; Safety devices specially combined with or arranged in, or specially adapted for use in connection with, machine tools
- B23Q11/10—Arrangements for cooling or lubricating tools or work
- B23Q11/1038—Arrangements for cooling or lubricating tools or work using cutting liquids with special characteristics, e.g. flow rate, quality
- B23Q11/1046—Arrangements for cooling or lubricating tools or work using cutting liquids with special characteristics, e.g. flow rate, quality using a minimal quantity of lubricant
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23B—TURNING; BORING
- B23B35/00—Methods for boring or drilling, or for working essentially requiring the use of boring or drilling machines; Use of auxiliary equipment in connection with such methods
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/74—Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material
- C21D1/76—Adjusting the composition of the atmosphere
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/60—Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23B—TURNING; BORING
- B23B2222/00—Materials of tools or workpieces composed of metals, alloys or metal matrices
- B23B2222/84—Steel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23B—TURNING; BORING
- B23B2250/00—Compensating adverse effects during turning, boring or drilling
- B23B2250/12—Cooling and lubrication
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23C—MILLING
- B23C2250/00—Compensating adverse effects during milling
- B23C2250/12—Cooling and lubrication
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/62—Quenching devices
- C21D1/667—Quenching devices for spray quenching
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2261/00—Machining or cutting being involved
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/10—Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T408/00—Cutting by use of rotating axially moving tool
- Y10T408/03—Processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T408/00—Cutting by use of rotating axially moving tool
- Y10T408/44—Cutting by use of rotating axially moving tool with means to apply transient, fluent medium to work or product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T408/00—Cutting by use of rotating axially moving tool
- Y10T408/44—Cutting by use of rotating axially moving tool with means to apply transient, fluent medium to work or product
- Y10T408/45—Cutting by use of rotating axially moving tool with means to apply transient, fluent medium to work or product including Tool with duct
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T83/00—Cutting
- Y10T83/04—Processes
- Y10T83/0405—With preparatory or simultaneous ancillary treatment of work
- Y10T83/0443—By fluid application
Definitions
- the present invention relates to a method for cutting machine structural steel.
- This application claims priority based on Japanese Patent Application No. 2010-78231 filed in Japan on March 30, 2010, the contents of which are incorporated herein by reference.
- Cutting oil plays a role of lubrication between the tool and the work material, cooling during cutting, eliminating chips, and dramatically improves cutting efficiency.
- Cutting has been performed in large quantities.
- aiming at improving the production environment and minimizing waste there is a need for a cutting technique that can achieve high efficiency even if the cutting fluid is reduced as much as possible.
- Non-Patent Document 1 discusses a technique called MQL (Minimal Quantities Lubricants) cutting in which the use of a cutting fluid is reduced as much as possible.
- MQL cutting is a method in which an extremely small amount of cutting fluid is made into a mist with a large amount of carrier gas, and cutting is performed while spraying the mist-like cutting fluid on the cutting edge of a tool or the surface of a work material. With this technique, the amount of cutting fluid used can be significantly reduced.
- Patent Document 1 discloses a steel for machine structure in which the addition amount of Al and other nitride-forming elements and the addition amount of N are adjusted and an appropriate heat treatment is performed.
- the solid solution N which is harmful to the machinability is kept low
- the solid solution Al which improves the machinability by the high temperature embrittlement and the crystal structure of the high temperature embrittlement and the cleaving property provides the machinability
- An appropriate amount of AlN to be improved is secured. Therefore, this machine structural steel has excellent machinability in a wide cutting speed range from low speed to high speed, and has both a high impact value and a yield ratio.
- Patent Document 2 discloses a steel material for cutting using a small amount of lubricating oil, that is, a steel material for MQL cutting.
- a steel material for MQL cutting in order to reduce the strength around 200-400 ° C, which correlates with the cutting resistance during MQL cutting, the amount of elements such as N, Ti, V, Mo, etc. is specified, and ferrite with a pearlite structure By specifying the rate, the tool life is improved.
- MQL cutting and steel material components are being studied as environmentally-friendly technologies in cutting, and both MQL cutting methods and steel material components should be considered when considering environmentally-friendly technologies in the future. It is necessary to consider.
- Non-Patent Document 1 describes a method of MQL cutting and a working mechanism of an oil agent, but the steel material (work material) used is only JIS S45C steel, and no detailed study on the work material has been made. In particular, MQL is not applicable in all cutting conditions (cutting fluid, tool, work material, machine tool, processing method).
- Patent Document 1 does not describe MQL cutting, and the steel for machine structure is cut using a conventional cutting method such as drilling or turning.
- Patent Document 2 discloses a steel material for MQL, but does not disclose in detail the conditions at the time of MQL cutting. Therefore, the technique disclosed in Patent Document 2 is not always applicable in a wide range of cutting conditions.
- the present invention has been developed in view of the above-mentioned problems, and its purpose is to make MQL cutting, that is, to make a very small amount of cutting fluid into a mist with a carrier gas, on the tool edge and the surface of the work material.
- An object of the present invention is to provide a method for cutting steel for machine structural use having an excellent tool life when cutting while spraying this mist-like cutting fluid.
- the present inventors have conducted intensive research to solve the above problems.
- a literature survey and experiments were conducted focusing on the lubrication mechanism at the interface between the tool and the work material, which is considered to have a large effect on the tool life.
- Non-Patent Document 1 describes that the following phenomenon occurs at the interface between the tool and the work material during MQL cutting.
- Fe is an element that has a larger free energy of formation of oxide than Al
- the binding energy when alumina is formed on the new surface of the steel material is higher than the binding energy when alumina is generated on the new surface of the aluminum alloy. Small. Therefore, even if alumina is generated on the new surface of the steel material, shear is easily generated from the interface between the steel material and alumina, and the alumina does not act as a frictional resistance.
- alumina Since alumina is hard, the oxide mainly composed of alumina produced on the tool works as a tool protective film, imparts wear resistance to the tool, and improves the tool life.
- D In order to stably generate alumina on the tool and improve the tool life, the amount of cutting fluid, the ratio of the flow rate of carrier gas to the amount of cutting fluid, the mist discharge cross-sectional area and the supply of carrier gas It is necessary to optimize the ratio to the pressure, the number of mist discharges per second, and the temperature of the carrier gas.
- the method for cutting steel for machine structure according to the present invention is as follows.
- a cutting fluid supplied at a supply rate of 0.01 to 200 ml / hour and oxygen of 21% or more and 50% or less by volume%.
- the oxidant gas is mixed to produce a mist, and while the mist is sprayed on the tool edge surface and the machine structural steel surface, the mechanical structural steel is cut, and the mechanical structural steel is mass%.
- the mechanical structural steel further contains Ca: 0.0001 to 0.02%, Ti: 0.0005 to 0% by mass. 0.5%, Nb: 0.0005 to 0.5%, W: 0.0005 to 1.0%, V: 0.0005 to 1.0%, Ta: 0.0001 to 0.2%, Hf: 0.0001-0.2%, Mg: 0.0001-0.02%, Zr: 0.0001-0.02%, Rem: 0.0001-0.02%, Sb: 0.0001-0.
- the flow rate of the oxidizing gas is Q (l / min), and the supply speed of the cutting fluid is q (ml / hour). In this case, the q / Q ratio may satisfy 0.001 to 1.
- the sectional area of the outlet for discharging the mist is S (mm 2 ), and the supply pressure of the oxidizing gas is P (MPa). ), The S / P ratio may satisfy 0.2 to 40.
- the cutting method for machine structural steel according to the above (1) or (2) even if the number of discharges per second of the discharge pump for supplying the cutting fluid is 0.05 to 16 times Good.
- the temperature of the oxidizing gas may be -80 ° C or higher and 40 ° C or lower.
- the oxygen concentration of the oxidizing gas may be 25% or more and 50% or less.
- the MQL cutting according to this embodiment is characterized in that an oxidizing gas is used as a carrier gas.
- the oxidizing gas in the present embodiment is a gas having an oxygen concentration of 21% or more in the gas, and air is also included in the oxidizing gas.
- an oxide mainly composed of alumina can be generated on the tool.
- Tool life can be improved by forming a protective film.
- the oxygen concentration in the gas can be measured with an oxygen concentration meter.
- a gas having an oxygen concentration higher than 21% can be obtained by mixing oxygen with air or using an oxygen concentrator.
- the oxygen concentration is preferably 25% or more, and more preferably 30% or more. However, from the viewpoint of safety, the oxygen concentration is preferably 50% or less.
- the oxygen concentration in this carrier gas is volume%.
- the amount of cutting fluid in the mist exceeds 200 ml / hour, the mist adhering to the tool hinders the formation of oxides mainly composed of alumina on the tool, so that it is difficult to improve the tool life.
- the amount of the cutting fluid is less than 0.01 ml / hour, it is difficult to obtain a lubricating action by the cutting fluid. Therefore, the amount of cutting fluid (supply rate) needs to be 0.01 to 200 ml / hour. From the viewpoint of tool life and cutting efficiency, the amount of the cutting fluid is preferably 0.1 to 150 ml / hour, and more preferably 1 to 100 ml / hour.
- the particle diameter of the mist supplied to the tool blade edge is too large, the cutting fluid adheres to the tool too much and prevents the generation of oxide mainly composed of alumina on the tool.
- the particle size of the mist is too small, the mist hardly adheres to the tool, and it is difficult to obtain a lubricating effect by the cutting fluid. Therefore, it is desirable to optimize the mist particle size.
- the particle diameter of the mist changes depending on the cross-sectional area of the outlet (oil hole opening end) from which the mist is finally discharged and the flow velocity of the carrier gas. The smaller the cross-sectional area and the larger the flow velocity, the larger the mist particle size. Prone.
- the flow rate of the carrier gas (oxidizing gas) increases as the gas supply pressure increases. Therefore, the smaller the value S / P (mm 2 / MPa) obtained by dividing the cross-sectional area S (mm 2 ) by the supply pressure P (MPa), the larger the particle size of the mist.
- S / P is 0.2 to 40, the particle diameter of mist can be controlled within a suitable range, and the tool life is further improved. Therefore, when the sectional area of the outlet for discharging mist is defined as S (mm 2 ) and the supply pressure of the oxidizing gas is defined as P (MPa), S / P obtained by dividing S by P is 0.2 to 40. It is preferably 0.25 to 25, more preferably 0.3 to 10.
- the cross-sectional area of the outlet for discharging mist is the cross-sectional area of the oil hole when axially refueling from an oil hole of a tool such as a drill, and the cross-sectional area of the nozzle hole when refueling from a nozzle.
- this cross-sectional area is the total value of the cross-sectional areas of those holes.
- Cutting fluid is supplied by a discharge pump. If the pump shot frequency by the discharge pump (the number of discharges per second) is too high, the mist adhering to the tool hinders the formation of oxides mainly composed of alumina on the tool, so it is difficult to improve the tool life. . On the other hand, if the pump shot frequency is too low, it is difficult to obtain a lubricating action by the cutting fluid. Therefore, the pump shot frequency N is preferably 0.05 to 16 Hz (times), more preferably 0.1 to 8 Hz, and further preferably 0.5 to 4 Hz.
- the cooling effect by cutting fluid is generally small, heat generation is large, thermal cracks occur, and tool wear tends to occur. Therefore, the tool life can be further increased by enhancing the cooling effect and preventing thermal cracking. Therefore, it is desirable to enhance the cooling effect with a low temperature carrier gas.
- the temperature of the carrier gas is 40 ° C. or lower, the tool life can be further improved. Therefore, the temperature of the carrier gas (oxidizing gas) is preferably 40 ° C. or less, more preferably 20 ° C. or less, and further preferably 0 ° C. or less. Considering the handling of the cooling gas and the manufacturing cost, it is better that the temperature is not too low, so the temperature of the carrier gas may be ⁇ 80 ° C. or higher.
- the cooling gas can be obtained by an air cooling device.
- Mist is generated by supplying cutting fluid and oxidizing gas to a mist generator.
- the mist is axially lubricated from the oil hole of a small-diameter tool, the pressure loss increases inside the tool, and thus the supply pressure of the oxidizing gas may be increased.
- the component of the cutting fluid is not particularly limited.
- the cutting fluid is a biodegradable lubricating oil.
- highly biodegradable synthetic ester oil or vegetable oil can be used as the cutting oil.
- a coolant such as water may be supplied in a mist form in addition to the oxidizing gas and the cutting fluid.
- the mist supply method includes a method of injecting mist from an external nozzle to the cutting part, a method of providing a tool holder of a machine tool with an MQL mist supply function, and a tool through a pipe line provided at the center of the rotating spindle.
- the MQL cutting of the present embodiment can be applied to any of continuous cutting such as drilling, turning, and tapping, and intermittent cutting such as milling, end milling, and hobbing.
- continuous cutting such as drilling, turning, and tapping
- intermittent cutting such as milling, end milling, and hobbing.
- content of each component of steel for machine structure (work material) in MQL cutting of this embodiment will be described.
- this machine structural steel (work material) has chemical components composed of Fe and inevitable impurities, with the remainder of each component described below. In the following description, mass% in chemical composition is simply described as%.
- C 0.01 to 1.2% C is an element that greatly affects the basic strength of steel. However, when the C content is less than 0.01%, sufficient strength cannot be obtained. On the other hand, if the C content exceeds 1.2%, a large amount of hard carbide precipitates, and the machinability is significantly reduced. Therefore, in order to obtain sufficient strength and machinability, the C content in the work material is 0.01 to 1.2%, preferably 0.05 to 0.8%, more preferably 0. 10 to 0.70%.
- Si 0.005 to 3.0%
- Si is generally added to steel as a deoxidizing element and provides ferrite strengthening and temper softening resistance.
- the Si content is less than 0.005%, a sufficient deoxidation effect cannot be obtained.
- the Si content exceeds 3.0%, the toughness and ductility are lowered, and at the same time, the hardness of the work material is increased, so that the machinability is also deteriorated. Therefore, the Si content in the work material is 0.005 to 3.0%, preferably 0.01 to 2.5%, more preferably 0.05 to 2.0%.
- Mn 0.05% to 3.0%
- Mn is an element necessary for improving the quenchability by solid solution in the matrix and ensuring the strength after quenching. Further, Mn has an effect of improving machinability by combining with S in the steel material to generate MnS-based sulfide. However, if the Mn content is less than 0.05%, S in the steel material combines with Fe to produce FeS, and the steel becomes brittle. On the other hand, when the Mn content increases, specifically, when the Mn content exceeds 3.0%, the hardness of the work material increases and the workability and machinability deteriorate. Therefore, the Mn content in the work material is 0.05 to 3.0%, preferably 0.2 to 2.5%, more preferably 0.35 to 2.0%.
- P 0.001 to 0.2%
- P has an effect of improving machinability.
- the P content is less than 0.001%, the effect cannot be obtained.
- the P content increases, specifically, when the P content exceeds 0.2%, the toughness is greatly reduced, the hardness of the work material in steel is increased, and only cold workability is achieved.
- hot workability and casting properties are also reduced. Therefore, the P content in the work material is 0.001 to 0.2%, preferably 0.005 to 0.1%, and more preferably 0.01 to 0.05%.
- S 0.001 to 0.35%
- MnS has the effect of improving machinability.
- the S content needs to be 0.001% or more.
- the S content in the work material is 0.001 to 0.35%, preferably 0.005 to 0.15%, and more preferably 0.01 to 0.07%.
- N 0.002 to 0.035%
- N combines with Al, Ti, V, Nb, or the like to generate nitrides or carbonitrides, and has an effect of suppressing coarsening of crystal grains.
- the N content is less than 0.002%, the effect is insufficient.
- the N content exceeds 0.035%, the effect will be saturated and hot ductility will deteriorate remarkably, and manufacture of a rolled steel material will become very difficult. Therefore, the N content in the work material is 0.002 to 0.035%, preferably 0.003 to 0.02%, and more preferably 0.0035 to 0.016%.
- O more than 0% and 0.003% or less O is an impurity inevitably contained. If the O content is excessive, a large amount of coarse oxide inclusions are generated in the steel, and the tool wear during cutting increases due to abrasive wear. In this case, the amount of solute Al described later may decrease. Therefore, it is desirable to reduce the O content as much as possible. Therefore, the O content needs to be limited to 0.003% or less, and is preferably limited to 0.0015% or less.
- Al 0.05 to 1.0%
- Solid solution Al 0.05-1.0%
- Al is the most important element in the present invention. Al improves the internal quality of steel as a deoxidizing element.
- Al is an indispensable element for improving the tool life when cutting a work material while spraying a mist containing an oxidizing gas and a cutting fluid on the cutting edge of the tool and the surface of the work material. That is, when the solid solution Al in the steel material and oxygen in the mist react chemically, an oxide protective film mainly composed of alumina is formed on the tool, and the tool life is improved.
- an Al content of 0.05% or more is necessary.
- the Al content is 0.05 to 1.0%, preferably 0.08 to 0.5%, more preferably more than 0.1% and 0.26% or less.
- the amount of solute Al needs to be 0.05% or more.
- the amount of solute Al is required to be 0.05% or more, if N is present in a predetermined amount (for example, 0.002% or more), it is necessary to add Al to the steel in consideration of the N amount. There is. Therefore, the Al content [Al%] and the N content [N%] must be mass% and satisfy the following formula (1), and preferably satisfy the following formula (2). [Al%]-(27/14) ⁇ [N%] ⁇ 0.05 (1) [Al%] ⁇ (27/14) ⁇ [N%]> 0.1 (2) In addition, the upper limit of the amount of solute Al is 1.0%.
- this mechanical structural steel may contain Ca in order to improve machinability.
- Ca 0.0001 to 0.02%
- Ca is a deoxidizing element, and lowers the melting point of a hard oxide such as Al 2 O 3 to soften the hard oxide, thereby improving the machinability of the work piece and suppressing tool wear.
- the Ca content is less than 0.0001%, this machinability improving effect cannot be obtained.
- the Ca content exceeds 0.02%, CaS is generated in the steel, and the machinability is lowered. Therefore, when Ca is added to the steel, the Ca content is 0.0001 to 0.02%, preferably 0.0003 to 0.005%, more preferably 0.0004 to 0.0020%. is there.
- this mechanical structural steel has Ti: 0.0005 to 0.5%, Nb: 0.0005 in addition to the above components.
- One or more elements selected from the group consisting of ⁇ 0.5%, W: 0.0005 ⁇ 1.0%, and V: 0.0005 ⁇ 1.0% may be contained.
- Ti 0.0005 to 0.5%
- Ti is an element that forms carbonitrides and contributes to suppression of austenite grain growth and strengthening of steel. Therefore, Ti is used as an element for preventing coarse grains and adjusting the grain size of the structure in steels that require high strength and steels that require low strain.
- Ti is also a deoxidizing element and has the effect of improving machinability by forming a soft oxide.
- the Ti content is less than 0.0005%, the effect is not recognized.
- the Ti content exceeds 0.5%, undissolved coarse carbonitrides that cause hot cracking precipitate, and the mechanical properties are impaired. Therefore, when Ti is added to the steel, the Ti content is 0.0005 to 0.5%, preferably 0.01 to 0.3%.
- Nb 0.0005 to 0.5%
- Nb is also an element that forms carbonitrides and contributes to the strengthening of steel by secondary precipitation hardening and the suppression of the growth of austenite grains. Therefore, steel that requires high strength and steel that requires low strain is used as an element that prevents coarse grains and regulates the grain size of the structure.
- the Nb content is less than 0.0005%, the effect of increasing the strength cannot be obtained.
- the Nb content exceeds 0.5%, undissolved coarse carbonitrides that cause hot cracking precipitate, and the mechanical properties are impaired. Therefore, when Nb is added to the steel, the Nb content is 0.0005 to 0.5%, preferably 0.005 to 0.2%.
- W 0.0005 to 1.0%
- W is also an element that forms carbonitride and can strengthen steel by secondary precipitation hardening.
- the W content is less than 0.0005%, the effect of increasing the strength cannot be obtained.
- the W content exceeds 1.0%, undissolved coarse carbonitrides that cause hot cracking precipitate, and the mechanical properties are impaired. Therefore, when W is added to the steel, the W content is 0.0005 to 1.0%, preferably 0.01 to 0.8%.
- V 0.0005 to 1.0%
- V is an element that forms carbonitride and can strengthen the steel by secondary precipitation hardening, and is appropriately added to steel that requires high strength.
- the V content is less than 0.0005%, the effect of increasing the strength cannot be obtained.
- V content exceeds 1.0%, undissolved coarse carbonitrides that cause hot cracking are precipitated, and mechanical properties are impaired. Therefore, when V is added to the steel, the V content is 0.0005 to 1.0%, preferably 0.01 to 0.8%.
- this mechanical structural steel is a group consisting of Ta: 0.0001 to 0.2%, Hf: 0.0001 to 0.2% in addition to the above components.
- One or more elements selected from may be contained.
- Ta 0.0001 to 0.2%
- Ta is an element that contributes to the strengthening of steel by secondary precipitation hardening and the suppression of the growth of austenite grains. Therefore, Ta is used as an element that prevents coarse grains and regulates the crystal grains of the structure in steels that require high strength and steels that require low strain.
- the Ta content is less than 0.0001%, the effect of increasing the strength cannot be obtained.
- the Ta content exceeds 0.2%, the mechanical properties are impaired by the undissolved coarse precipitates that cause hot cracking. Therefore, when Ta is added to the steel, the Ta content is 0.0001 to 0.2%, preferably 0.001 to 0.1%.
- Hf 0.0001 to 0.2% Hf, like Ti, is an element that contributes to the suppression of austenite grain growth and the strengthening of steel. Therefore, Hf is used as an element that prevents coarse grains and regulates the crystal grains of the structure in steels that require high strength and steels that require low strain. However, when the Hf content is less than 0.0001%, the effect of increasing the strength cannot be obtained. On the other hand, when Hf is added to the steel and the Hf content exceeds 0.2%, mechanical properties are impaired due to undissolved coarse precipitates that cause hot cracking. Therefore, when Hf is added to the steel, the Hf content is 0.0001 to 0.2%, preferably 0.001 to 0.1%.
- this steel for mechanical structure includes Mg: 0.0001 to 0.02%, Zr: 0.0001 to 0 in addition to the above components.
- One or more elements selected from the group consisting of 0.02% and Rem: 0.0001 to 0.02% may be contained.
- Mg 0.0001 to 0.02%
- Mg is a deoxidizing element and generates an oxide in steel.
- Al 2 O 3 harmful to machinability is modified into MgO or Al 2 O 3 .MgO that is relatively soft and finely dispersed.
- the oxide tends to be a nucleus of MnS and has an effect of finely dispersing MnS.
- Mg content is less than 0.0001%, these effects are not recognized.
- Mg forms a composite sulfide with MnS and spheroidizes MnS, but when Mg is added excessively in the steel and the Mg content exceeds 0.02%, single MgS generation is generated. Promotes and degrades machinability. Therefore, when adding Mg to the steel, the Mg content is 0.0001 to 0.02%, preferably 0.0003 to 0.0040%, more preferably 0.0005 to 0.0030%. is there.
- Zr 0.0001 to 0.02%
- Zr is a deoxidizing element and generates an oxide in steel.
- the oxide is considered to be ZrO 2 , but since this oxide acts as MnS precipitation nuclei, there is an effect of increasing MnS precipitation sites and uniformly dispersing MnS.
- Zr also has a function of forming a complex sulfide by dissolving in MnS, reducing the deformability of MnS, and suppressing the elongation of the MnS shape during rolling and hot forging.
- Zr is an effective element for reducing anisotropy.
- the Zr content is less than 0.0001%, a remarkable effect cannot be obtained for these.
- the Zr content is 0.0001 to 0.02%, preferably 0.0003 to 0.01%, more preferably 0.0005 to 0.005%. is there.
- Rem 0.0001 to 0.02%
- Rem is a deoxidizing element, generates a low melting point oxide, and suppresses nozzle clogging during casting. Furthermore, Rem has a function of suppressing the elongation of the MnS shape during rolling and hot forging by dissolving or bonding to MnS and reducing the deformability of MnS. Thus, Rem is an element effective for reducing anisotropy.
- the Rem content is less than 0.0001% in total, the effect is not remarkable.
- Rem content is added to the steel and the Rem content exceeds 0.02%, a large amount of Rem sulfide is generated and the machinability deteriorates. Therefore, when Rem is added to the steel, the Rem content is 0.0001 to 0.02%, preferably 0.0003 to 0.015%, more preferably 0.0005 to 0.01%. is there.
- this steel for machine structural use includes Sb: 0.0001 to 0.015%, Sn: 0.0005 to 2.0%, Zn: 0.0005 to 0.5%, B: 0.0001 to 0.015%, Te: 0.0003 to 0.2%, Se: 0.0003 to 0.2%, Bi: 0.001 to One or more elements selected from the group consisting of 0.5% and Pb: 0.001 to 0.5% may be contained.
- Sb 0.0001 to 0.015%
- Sb moderately embrittles ferrite and improves machinability. The effect is not observed when the Sb content is less than 0.0001%. Further, when the Sb content increases, specifically, when the Sb content exceeds 0.015%, excessive macrosegregation of Sb occurs, and the impact value greatly decreases. Therefore, when Sb is added to the steel, the Sb content is 0.0001 to 0.015%, preferably 0.0005 to 0.012%, more preferably 0.001 to 0.01%. is there.
- Sn 0.0005 to 2.0%
- Sn has the effect of making the ferrite brittle and extending the tool life and improving the surface roughness. However, the effect is not recognized when Sn content is less than 0.0005%. Moreover, when Sn is added to steel and Sn content exceeds 2.0%, the effect will be saturated. Therefore, when Sn is added to the steel, the Sn content is 0.0005 to 2.0%, preferably 0.001 to 1.0%, more preferably 0.01 to 0.2%. is there.
- Zn 0.0005 to 0.5%
- Zn has the effect of making the ferrite brittle and extending the tool life and improving the surface roughness.
- the Zn content is less than 0.0005%, the effect is not recognized.
- the Zn content exceeds 0.5%, the effect is saturated. Therefore, when Zn is added to the steel, the Zn content is 0.0005 to 0.5%, preferably 0.001 to 0.3%, more preferably 0.01 to 0.1%. is there.
- B 0.0001 to 0.015%
- B is effective in grain boundary strengthening and hardenability when dissolved in steel, and is effective in improving machinability when precipitated as BN. These effects are not significant when the B content is less than 0.0001%.
- the B content is 0.0001 to 0.015%, preferably 0.0005 to 0.01%, more preferably 0.001 to 0.003%. is there.
- Te 0.0003 to 0.2% Te is an element that improves machinability. Te also has the function of generating MnTe or coexisting with MnS to reduce the deformability of MnS and suppress the extension of the MnS shape. Thus, Te is an element effective for reducing anisotropy. However, when the Te content is less than 0.0003%, these effects are not recognized. On the other hand, when the Te content exceeds 0.2%, not only the effect is saturated, but also the hot ductility is reduced and soot tends to be generated. Therefore, when Te is added to the steel, the Te content is 0.0003 to 0.2%, preferably 0.0005 to 0.1%, more preferably 0.001 to 0.01%. is there.
- Se 0.0003 to 0.2%
- Se is an element that improves machinability. Se also has the function of generating MnSe or coexisting with MnS to reduce the deformability of MnS and suppress the extension of the MnS shape. Thus, Se is an element effective for reducing anisotropy.
- Se content is less than 0.0003%, these effects are not recognized. If the Se content exceeds 0.2%, the effect is saturated. Therefore, when Se is added to the steel, the Se content is 0.0003 to 0.2%, preferably 0.0005 to 0.1%, more preferably 0.001 to 0.01%. is there.
- Bi 0.001 to 0.5%
- Bi is an element that improves machinability.
- the Bi content is less than 0.001%, the effect cannot be obtained.
- the Bi content exceeds 0.5%, not only the effect of improving the machinability is saturated but also the hot ductility is lowered and flaws are easily generated. Therefore, when Bi is added to the steel, the Bi content is 0.001 to 0.5%, preferably 0.01 to 0.3%, more preferably 0.04 to 0.25%. is there.
- Pb 0.001 to 0.5%
- Pb is an element that improves machinability.
- the Pb content is less than 0.001%, the effect is not recognized.
- the Pb content exceeds 0.5%, not only the effect of improving the machinability is saturated, but also the hot ductility is lowered and flaws are easily generated. Therefore, when Pb is added to the steel, the Pb content is 0.001 to 0.5%, preferably 0.01 to 0.3%, more preferably 0.04 to 0.25%. is there.
- this steel for mechanical structure contains Cr: 0.001 to 3.0%, Mo: 0
- One or more elements selected from the group consisting of 0.001 to 1.0% may be contained.
- Cr 0.001 to 3.0% Cr is an element that improves hardenability and imparts temper softening resistance to steel, and is added to steel that requires high strength. However, when the Cr content is less than 0.001%, these effects cannot be obtained. In addition, when a large amount of Cr is added to the steel, specifically, if the Cr content exceeds 3.0%, Cr carbide is generated and the steel becomes brittle. Therefore, when Cr is added to the steel, the Cr content is 0.001 to 3.0%, preferably 0.01 to 2.3%, more preferably 0.1 to 1.8%. is there.
- Mo 0.001 to 1.0%
- Mo is an element that imparts temper softening resistance to steel and improves hardenability, and is added to steel that requires high strength.
- Mo content is less than 0.001%, these effects cannot be obtained.
- Mo content will be saturated if Mo is added in steel and Mo content exceeds 1.0%. Therefore, when Mo is added to the steel, the Mo content is 0.001 to 1.0%, preferably 0.01 to 0.8%, more preferably 0.05 to 0.5%. is there.
- this mechanical structural steel is made of Ni: 0.001 to 5.0%, Cu: 0.001 to 5.0%. It may contain one or more selected elements.
- Ni 0.001 to 5.0%
- Ni is an element that strengthens ferrite, improves ductility, and improves hardenability and corrosion resistance.
- the Ni content is less than 0.001%, the effect is not recognized.
- the Ni content exceeds 5.0%, the effect is saturated in terms of mechanical properties, and the machinability is lowered. Therefore, when Ni is added to the steel, the Ni content is 0.001 to 5.0%, preferably 0.1 to 4.0%, more preferably 0.3 to 3.0%. is there.
- Cu 0.001 to 5.0%
- Cu is an element that strengthens ferrite and improves hardenability and corrosion resistance.
- the Cu content is less than 0.001%, the effect is not recognized.
- the Cu content exceeds 5.0%, the effect is saturated in terms of mechanical properties. Therefore, when Cu is added to the steel, the Cu content is 0.001 to 5.0%, preferably 0.01 to 4.0%, more preferably 0.1 to 3.0%. is there.
- Ni since Cu lowers hot ductility and tends to cause defects during rolling, in this case, it is preferable to add Ni at the same time.
- this machine structural steel is composed of Li: 0.00001 to 0.005%, Na: 0.00001 to 0.005%, K
- One or more elements selected from the group consisting of: 0.00001 to 0.005%, Ba: 0.00001 to 0.005%, and Sr: 0.00001 to 0.005% may be contained.
- Li 0.00001 to 0.005% Li suppresses tool wear by forming a low melting point oxide in steel. However, when the Li content is less than 0.00001%, the effect is not recognized. Moreover, when Li is added to steel and the Li content exceeds 0.005%, not only the effect is saturated, but also refractory erosion may be caused. Therefore, when Li is added to the steel, the Li content is 0.00001 to 0.005%, preferably 0.0001 to 0.0045%.
- Na 0.00001 to 0.005% Na, like Li, suppresses tool wear by forming a low melting point oxide in steel.
- the Na content is less than 0.00001%, the effect is not recognized.
- the Na content exceeds 0.005%, not only the effect is saturated but also refractory melting may occur. Therefore, when Na is added to the steel, the Na content is 0.00001 to 0.005%, preferably 0.0001 to 0.0045%.
- K 0.00001 to 0.005% K also suppresses tool wear by forming a low-melting-point oxide in steel like Li. However, when the K content is less than 0.00001%, the effect is not recognized. Moreover, when K is added to steel and the K content exceeds 0.005%, not only the effect is saturated, but also refractory melting may occur. Therefore, when K is added to the steel, the K content is 0.00001 to 0.005%, preferably 0.0001 to 0.0045%.
- Ba 0.00001 to 0.005% Ba, like Li, suppresses tool wear by forming a low melting point oxide in steel.
- the Ba content is less than 0.00001%, the effect is not recognized.
- the Ba content exceeds 0.005%, not only the effect is saturated, but also refractory melting may occur. Therefore, when Ba is added to the steel, the Ba content is 0.00001 to 0.005%, preferably 0.0001 to 0.0045%.
- Sr 0.00001 to 0.005% Sr also suppresses tool wear by forming a low-melting-point oxide in steel as in Li. However, when the Sr content is less than 0.00001%, the effect is not recognized. Moreover, when Sr is added to the steel and exceeds 0.005%, not only the effect is saturated, but also the refractory may be melted. Therefore, when Sr is added to the steel, the Sr content is 0.00001 to 0.005%, preferably 0.0001 to 0.0045%.
- MQL cutting that is, a tiny amount of cutting fluid is made mist with a large amount of carrier gas, and the tool edge or the surface of the work material is obtained.
- the solid solution Al in the steel material and the oxygen in the mist react chemically to form an oxide protective film mainly composed of alumina on the tool. Excellent tool life can be obtained.
- FIG. 1A An outline of the tool life evaluation test is shown in FIG. 1A.
- a cemented carbide drill 1 provided with an oil hole is attached to the spindle of a horizontal machining center, and a mist 2 in which a carrier gas and a cutting fluid are mixed is sprayed from an oil hole of a drill (tool) 1.
- Drilling was performed at a drilling position 4 of a test piece (test piece) 3 for tool life evaluation fixed by a vise.
- the drill 1 is provided with an oil hole 5 in a tip blade portion where a flank 6 is formed.
- the direction of the bent arrow is the rotation direction
- the direction of the straight arrow is the feed direction of the drill.
- Tables 6 and 7 show various conditions during cutting in the tool life evaluation test.
- air was used as the gas having an oxygen concentration of 21%.
- a gas having an oxygen concentration higher than 21% was prepared by using an oxygen concentrator, and a gas having an oxygen concentration lower than 21% was prepared by mixing nitrogen with air.
- the oxygen concentration C O2 (%) was measured with an oxygen concentration meter.
- the amount q (ml / hour) of the cutting fluid was determined using the specific gravity of the cutting fluid from the change in weight per unit time obtained by applying mist to the nonwoven fabric.
- the flow rate Q (l / min) of the carrier gas and the supply pressure P (MPa) of the carrier gas were measured with a flow meter and a pressure meter attached to the mist generator, respectively.
- the pump shot frequency N was determined by measuring the number of times the air solenoid valve of the mist generator was opened and closed.
- the temperature T (° C.) of the carrier gas was measured with a thermometer.
- the gas below 0 ° C. was prepared by an air cooling device, and the gas above 40 ° C. was prepared by a gas heater. Gases in other temperature ranges were obtained by adjusting the temperature in the test chamber.
- the cross-sectional area of the discharge port of the mist S (mm 2), was calculated from the diameter of the oil hole drilled in the drill (opening diameter) d h. Since the drill used this time has two oil holes, the sum of the cross-sectional areas of the two oil holes was used.
- test no. In A1 to A8, B1 to B7, C1 to C8, D1 to D7, and E1 to E8, the tool wear was small and an excellent tool life was obtained. Even when elements for increasing the strength and controlling the morphology of the sulfide are added, sufficient machinability is obtained by sufficiently optimizing the chemical components and cutting conditions of the steel material.
- Test No. In A11, B8, B9, C9, D8 to 10, and E10, the Al content, the oxygen concentration of the carrier gas, and the amount of the cutting fluid in the carrier gas are appropriately controlled. Therefore, these test Nos. Then, tool wear was improved by forming an oxide protective film mainly composed of alumina on the tool. For example, test no.
- test No. 1 test No. Compared with A1, since the value S / P obtained by dividing the discharge port cross-sectional area S (mm 2 ) by the supply pressure P (MPa) is too small, the particle size of the mist greatly increased. Therefore, this test No. In A11, test no. Compared with A1, since the cutting fluid adhered to the tool too much and oxides mainly composed of alumina were hardly formed on the tool, tool wear progressed. Test No.
- Test No. In C9 test no. Compared with C3, the frequency of pump shots was too low, so that it was difficult to obtain a lubricating action, and tool wear progressed.
- Test No. In C10 since the C content is excessive, a large amount of hard carbide is precipitated in the work material. Compared with C4, machinability was reduced.
- Test No. In C11 since the Si content is excessive, the hardness of the work material is increased. Compared with C1, machinability decreased.
- Test No. In C12 since the Mn content is excessive, the hardness of the work material is increased. Compared with C6, machinability was reduced.
- Test No. In C13 since the Al content is excessive, a large amount of a high melting point and hard oxide is present in the work material. Tool wear increased compared to C9.
- Test No. In D8 test no. Compared with D2, the value q / Q obtained by dividing the amount q (ml / hour) of the cutting fluid by the flow rate Q (l / min) of the carrier gas is too large, so alumina is mainly formed on the tool by mist adhering to the tool. It became difficult to produce the oxide. Therefore, this test No. In D8, test no. Tool wear progressed compared to D2. Test No. In D9, test no. Compared with D1, the pump shot frequency was too high, and it became difficult for oxides mainly composed of alumina to be generated on the tool by the mist adhering to the tool. Therefore, this test No. In D9, test no. Tool wear progressed compared to D1. Test No.
- test No. In E9 since the amount of cutting fluid in the mist was too large, the mist adhering to the tool prevented the formation of an oxide protective film mainly composed of alumina on the tool. Therefore, this test No. In E9, test no. Tool wear progressed compared to E1.
- Test No. In E10 test no. Compared with E8, since the value S / P obtained by dividing the discharge port cross-sectional area S (mm 2 ) by the supply pressure P (MPa) was too large, the particle size of the mist became small. Therefore, this test No. In E10, test no. Compared with E8, mist did not adhere to the tool so much that it was difficult to obtain a lubricating effect, and tool wear progressed. Test No.
- MQL cutting that is, by cutting while spraying this mist-like cutting fluid on the cutting edge of the tool and the surface of the work material by misting the cutting fluid with carrier gas
- Tool life is improved.
- mist was supplied from an oil hole in the drilling using a drill was illustrated.
- the tool life can be improved with respect to any of continuous cutting such as turning and tapping, milling, end milling, and intermittent cutting such as hobbing.
- the tool life can be improved even if mist is supplied by various mist supply methods, such as a method in which mist is sprayed from the nozzle installed outside to the cutting part or a tool holder of the machine tool is provided with an MQL mist supply function.
- various mist supply methods such as a method in which mist is sprayed from the nozzle installed outside to the cutting part or a tool holder of the machine tool is provided with an MQL mist supply function.
- MQL cutting described in the examples is an example, and the gist of the present invention is not limited to these descriptions, and is widely interpreted based on the claims.
- Machine tool with excellent tool life when cutting machine structural steel while spraying this mist of cutting fluid into the mist of carrier blade and spraying this mist of cutting fluid onto the surface of the workpiece.
- a method for cutting structural steel is provided.
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Abstract
Description
本願は、2010年3月30日に、日本に出願された特願2010-78231号に基づき優先権を主張し、その内容をここに援用する。
(d)工具上にアルミナを安定的に生成させて工具寿命を向上させるためには、切削油剤の量、キャリアガスの流量と切削油剤の量との比、ミスト吐出断面積とキャリアガスの供給圧力との比、1秒あたりのミスト吐出回数、キャリアガスの温度を最適化することが必要である。
すなわち、本発明に係る機械構造用鋼の切削方法は、次の通りである。
(3)上記(1)または(2)に記載の機械構造用鋼の切削方法では、前記酸化性ガスの流量をQ(l/分)、前記切削油剤の供給速度をq(ml/時)と定義した場合に、q/Qの比が、0.001~1を満たしてもよい。
(4)上記(1)または(2)に記載の機械構造用鋼の切削方法では、前記ミストを吐出する出口の断面積をS(mm2)、前記酸化性ガスの供給圧力をP(MPa)と定義した場合に、S/Pの比が、0.2~40を満たしてもよい。
(5)上記(1)または(2)に記載の機械構造用鋼の切削方法では、前記切削油剤を供給する吐出ポンプの1秒当たりの吐出回数が、0.05~16回であってもよい。
(6)上記(1)または(2)に記載の機械構造用鋼の切削方法では、前記酸化性ガスの温度が、-80℃以上かつ40℃以下であってもよい。
(7)上記(1)または(2)に記載の機械構造用鋼の切削方法では、前記酸化性ガスの酸素濃度が、25%以上かつ50%以下であってもよい。
まず、本発明の一実施形態に係るMQL切削に関して説明する。
ミストの供給方法には、外部に設置したノズルから切削部にミストを噴射する方式、工作機械の工具ホルダにMQLミストの供給機能を持たせる方式、回転主軸の中心部に設けた管路を通じて工具刃先の油穴からミストを供給する方式など複数の方式がある。これらのどの方式においても、工具寿命を高めることができる。
次に、本実施形態のMQL切削における機械構造用鋼(被削材)の各成分の含有量について説明する。ここで、この機械構造用鋼(被削材)は、以下に説明する各成分の残部がFeおよび不可避的不純物からなる化学成分を有している。なお、以下の説明においては、化学組成における質量%を、単に%と記載する。
Cは、鋼材の基本強度に大きな影響を及ぼす元素である。しかしながら、C含有量が0.01%未満である場合、十分な強度が得られない。一方、C含有量が1.2%を超えると、硬質の炭化物が多く析出するため、被削性が著しく低下する。よって、十分な強度と被削性とを得るため、被削材中のC含有量は、0.01~1.2%であり、好ましくは0.05~0.8%、さらに好ましくは0.10~0.70%である。
Siは、一般に脱酸元素として鋼中に添加され、フェライトの強化及び焼戻し軟化抵抗を付与する。しかしながら、Si含有量が0.005%未満である場合、十分な脱酸効果が得られない。一方、Si含有量が3.0%を超えると、靭性及び延性が低くなると同時に、被削材の硬さが大きくなるため被削性も劣化する。よって、被削材中のSi含有量は、0.005~3.0%であり、好ましくは0.01~2.5%、さらに好ましくは0.05~2.0%である。
Mnは、マトリックスに固溶して焼入れ性を向上させ、焼入れ後の強度を確保するために必要な元素である。さらに、Mnには、鋼材中のSと結合してMnS系硫化物を生成し、被削性を改善させる効果がある。しかしながら、Mn含有量が0.05%未満であると、鋼材中のSがFeと結合してFeSを生成し、鋼が脆くなる。一方、Mn含有量が増えると、具体的には、Mn含有量が3.0%を超えると、被削材の硬さが大きくなり加工性及び被削性が低下する。よって、被削材中のMn含有量は、0.05~3.0%であり、好ましくは0.2~2.5%、さらに好ましくは0.35~2.0%である。
Pは、被削性を良好にする効果がある。しかしながら、P含有量が0.001%未満である場合、その効果が得られない。また、P含有量が増えると、具体的には、P含有量が0.2%を超えると、靭性が大きく低化し、鋼中において被削材の硬さが大きくなり、冷間加工性だけでなく、熱間加工性及び鋳造特性も低下する。よって、被削材中のP含有量は、0.001~0.2%であり、好ましくは0.005~0.1%、さらに好ましくは0.01~0.05%である。
Sは、Mnと結合し、MnS系硫化物として鋼中に存在する。MnSには、被削性を向上させる効果がある。その効果を顕著に得るためには、S含有量が0.001%以上である必要がある。一方、S含有量が0.35%を超えると、靭性及び疲労強度の低下を著しく促進する。よって、被削材中のS含有量は、0.001~0.35%であり、好ましくは0.005~0.15%、さらに好ましくは0.01~0.07%である。
Nは、Al、Ti、VまたはNb等と結合して窒化物または炭窒化物を生成し、結晶粒の粗大化を抑制する効果がある。ただし、N含有量が0.002%未満では、その効果が不十分である。また、N含有量が0.035%を超えると、その効果が飽和するとともに熱間延性が著しく劣化し、圧延鋼材の製造が極めて困難になる。よって、被削材中のN含有量は、0.002~0.035%であり、好ましくは0.003~0.02%、さらに好ましくは0.0035~0.016%である。
Oは、不可避的に含まれる不純物である。O含有量が過剰であると、粗大な酸化物系介在物が鋼材中に多量に生成し、アブレシブ摩耗により切削時の工具摩耗が増大する。また、この場合には、後述の固溶Al量が低下する場合がある。したがって、出来るだけO含有量を低減することが望ましい。そのため、O含有量を0.003%以下に制限する必要があり、0.0015%以下に制限することが好ましい。
固溶Al:0.05~1.0%
Alは、本発明で最も重要な元素である。Alは、脱酸元素として鋼材の内部品質を向上させる。また、Alは、酸化性ガスと切削油剤とを含むミストを工具の刃先及び被削材の表面に吹き付けながら被削材を切削する場合に、工具寿命を向上させるために不可欠な元素である。すなわち、鋼材中の固溶Alとミスト中の酸素とが化学反応すると、工具上にアルミナを主体とする酸化物の保護膜が形成し、工具寿命が向上する。この工具寿命の向上に有効な固溶Alを十分に生成させるためには、0.05%以上のAl含有量が必要である。しかしながら、Al含有量が1.0%を超えると、高融点で硬質な酸化物が鋼材中に多量に生成し、硬質介在物としてアブレシブ摩耗を起こすため切削時の工具摩耗を増大させる。よって、Al含有量は、0.05~1.0%であり、好ましくは0.08~0.5%、さらに好ましくは0.1%超かつ0.26%以下である。
上述の理由から、固溶Alの量は、0.05%以上必要である。鋼中にNが存在すると、AlNが生成するため、Alが含まれる場合であっても、固溶Alが減少してしまう。すなわち、Nの原子量が14、Alの原子量が27であることを考慮すると、例えば、鋼中にNが0.01%添加された場合、N含有量の約2倍(27/14倍)である0.02%の固溶Alが減少してしまうため、工具寿命が十分に向上しないことがある。固溶Alの量は、0.05%以上必要であるので、Nが、所定量(例えば、0.002%以上)存在すれば、そのN量を考慮して鋼中にAlを添加する必要がある。したがって、Al含有量[Al%]とN含有量[N%]とが、質量%で、下記(1)式を満たす必要があり、下記(2)式を満たすことが好ましい。
[Al%]-(27/14)×[N%]≧0.05 ・・・(1)
[Al%]-(27/14)×[N%]>0.1 ・・・(2)
なお、固溶Alの量の上限は、1.0%である。
Caは、脱酸元素であり、Al2O3などの硬質酸化物の融点を低下させて硬質酸化物を軟質化することにより、被削物の被削性を向上させ、工具摩耗を抑制する。しかしながら、Ca含有量が0.0001%未満である場合、この被削性の向上効果が得られない。また、Ca含有量が0.02%を超えると、鋼中にCaSが生成し、却って被削性が低下する。よって、鋼中にCaを添加する場合、Ca含有量は、0.0001~0.02%であり、好ましくは0.0003~0.005%、さらに好ましくは0.0004~0.0020%である。
Tiは、炭窒化物を形成し、オーステナイト粒の成長の抑制及び鋼の強化に寄与する元素である。そのため、Tiは、高強度が必要な鋼、及び低歪を要求される鋼には、粗大粒を防止して組織の結晶粒を整粒する元素として使用される。また、Tiは、脱酸元素でもあり、軟質酸化物を形成させることにより、被削性を向上させる効果もある。しかしながら、Ti含有量が0.0005%未満である場合、その効果が認められない。また、Ti含有量が0.5%を超えると、熱間割れの原因になる未固溶の粗大な炭窒化物が析出し、却って機械的性質が損なわれる。よって、鋼中にTiを添加する場合、Ti含有量は、0.0005~0.5%であり、好ましくは0.01~0.3%である。
Nbも、炭窒化物を形成し、二次析出硬化による鋼の強化及びオーステナイト粒の成長の抑制に寄与する元素である。そのため、高強度が必要な鋼及び低歪を要求される鋼には、粗大粒を防止して組織の結晶粒を整粒する元素として使用される。しかしながら、Nb含有量が0.0005%未満である場合、強度を高める効果が得られない。また、鋼中にNbを添加してNb含有量が0.5%を超えると、熱間割れの原因になる未固溶の粗大な炭窒化物が析出し、却って機械的性質が損なわれる。よって、鋼中にNbを添加する場合、Nb含有量は、0.0005~0.5%であり、好ましくは0.005~0.2%である。
Wも、炭窒化物を形成し、二次析出硬化により鋼を強化することができる元素である。しかしながら、W含有量が0.0005%未満である場合、強度を高める効果が得られない。また、鋼中にWを添加してW含有量が1.0%を超えると、熱間割れの原因になる未固溶の粗大な炭窒化物が析出し、却って機械的性質が損なわれる。よって、鋼中にWを添加する場合、W含有量は、0.0005~1.0%であり、好ましくは0.01~0.8%である。
Vも、炭窒化物を形成し、二次析出硬化により鋼を強化することができる元素であり、高強度が必要な鋼には適宜添加される。しかしながら、V含有量が0.0005%未満である場合、強度を高める効果が得られない。また、鋼中にVを添加してV含有量が1.0%を超えると、熱間割れの原因になる未固溶の粗大な炭窒化物が析出し、却って機械的性質が損なわれる。よって、鋼中にVを添加する場合、V含有量は、0.0005~1.0%であり、好ましくは0.01~0.8%である。
Taも、Nbと同様に、二次析出硬化による鋼の強化及びオーステナイト粒の成長の抑制に寄与する元素である。そのため、Taは、高強度が必要な鋼及び低歪を要求される鋼には、粗大粒を防止して組織の結晶粒を整粒する元素として使用される。しかしながら、Ta含有量が0.0001%未満である場合、強度を高める効果が得られない。また、鋼中にTaを添加してTa含有量が0.2%を超えると、熱間割れの原因になる未固溶の粗大な析出物により、却って機械的性質が損なわれる。よって、鋼中にTaを添加する場合、Ta含有量は、0.0001~0.2%であり、好ましくは0.001~0.1%である。
Hfも、Tiと同様に、オーステナイト粒の成長の抑制及び鋼の強化に寄与する元素である。そのため、Hfは、高強度が必要な鋼、及び低歪を要求される鋼には、粗大粒を防止して組織の結晶粒を整粒する元素として使用される。しかしながら、Hf含有量が0.0001%未満である場合、強度を高める効果が得られない。また、鋼中にHfを添加してHf含有量が0.2%を超えると、熱間割れの原因になる未固溶の粗大な析出物により、却って機械的性質が損なわれる。よって、鋼中にHfを添加する場合、Hf含有量は、0.0001~0.2%であり、好ましくは0.001~0.1%である。
Mgは、脱酸元素であり、鋼中で酸化物を生成する。Alによる脱酸が前提である場合には、被削性に有害なAl2O3を、比較的軟質で微細に分散するMgO又はAl2O3・MgOに改質する。また、その酸化物は、MnSの核となりやすく、MnSを微細分散させる効果もある。しかしながら、Mg含有量が0.0001%未満では、これらの効果が認められない。また、Mgは、MnSとの複合硫化物を生成して、MnSを球状化するが、鋼中にMgを過剰に添加してMg含有量が0.02%を超えると、単独のMgS生成を促進して被削性を劣化させる。よって、鋼中にMgを添加する場合、Mg含有量は、0.0001~0.02%であり、好ましくは0.0003~0.0040%、さらに好ましくは0.0005~0.0030%である。
Zrは、脱酸元素であり、鋼中で酸化物を生成する。その酸化物は、ZrO2であると考えられているが、この酸化物がMnSの析出核として作用するため、MnSの析出サイトを増やし、MnSを均一に分散させる効果がある。また、Zrは、MnSに固溶して複合硫化物を生成し、MnSの変形能を低下させ、圧延及び熱間鍛造時にMnS形状の伸延を抑制する働きもある。このように、Zrは、異方性の低減に有効な元素である。しかしながら、Zr含有量が0.0001%未満である場合、これらについて顕著な効果は得られない。一方、鋼中にZrを添加してZr含有量が0.02%を超えると、歩留まりが極端に悪くなるばかりでなく、ZrO2およびZrS等の硬質な化合物が大量に生成し、却って被削性、衝撃値及び疲労特性等の機械的性質が低下する。よって、鋼中にZrを添加する場合、Zr含有量は、0.0001~0.02%であり、好ましくは0.0003~0.01%、さらに好ましくは0.0005~0.005%である。
Rem(希土類元素)は、脱酸元素であり、低融点酸化物を生成し、鋳造時のノズル詰りを抑制する。さらに、Remは、MnSに固溶又は結合し、MnSの変形能を低下させて、圧延及び熱間鍛造時にMnS形状の伸延を抑制する働きもある。このように、Remは、異方性の低減に有効な元素である。しかしながら、Rem含有量が総量で0.0001%未満である場合、その効果が顕著ではない。また、鋼中にRemを添加してRem含有量が0.02%を超えると、Remの硫化物が大量に生成し、被削性が悪化する。よって、鋼中にRemを添加する場合、Rem含有量は、0.0001~0.02%であり、好ましくは0.0003~0.015%、さらに好ましくは0.0005~0.01%である。
Sbは、フェライトを適度に脆化し被削性を向上させる。その効果は、Sb含有量が0.0001%未満では認められない。また、Sb含有量が増えると、具体的にはSb含有量が0.015%を超えると、過剰なSbのマクロ偏析が生じて衝撃値が大きく低下する。よって、鋼中にSbを添加する場合、Sb含有量は、0.0001~0.015%であり、好ましくは0.0005~0.012%、さらに好ましくは0.001~0.01%である。
Snは、フェライトを脆化させて工具寿命を延ばすと共に、表面粗さを改善する効果がある。しかしながら、Sn含有量が0.0005%未満である場合、その効果が認められない。また、鋼中にSnを添加してSn含有量が2.0%を超えると、その効果は飽和する。よって、鋼中にSnを添加する場合、Sn含有量は、0.0005~2.0%であり、好ましくは0.001~1.0%、さらに好ましくは0.01~0.2%である。
Znは、フェライトを脆化させて工具寿命を延ばすと共に、表面粗さを改善する効果がある。しかしながら、Zn含有量が0.0005%未満である場合、その効果が認められない。また、鋼中にZnを添加してZn含有量が0.5%を超えると、その効果は飽和する。よって、鋼中にZnを添加する場合、Zn含有量は、0.0005~0.5%であり、好ましくは0.001~0.3%、さらに好ましくは0.01~0.1%である。
Bは、鋼中に固溶している場合、粒界強化及び焼入れ性に効果があり、BNとして析出している場合には、被削性の向上に効果がある。これらの効果は、B含有量が0.0001%未満では顕著ではない。一方、鋼中にBを添加してB含有量が0.015%を超えると、その効果が飽和すると共に、BNが析出しすぎるため、却って鋼の機械的性質が損なわれる。よって、鋼中にBを添加する場合、B含有量は、0.0001~0.015%であり、好ましくは0.0005~0.01%、さらに好ましくは0.001~0.003%である。
Teは、被削性を向上させる元素である。また、Teは、MnTeを生成したり、MnSと共存することでMnSの変形能を低下させ、MnS形状の伸延を抑制したりする働きがある。このように、Teは、異方性の低減に有効な元素である。しかしながら、Te含有量が0.0003%未満である場合、これらの効果が認められない。また、Te含有量が0.2%を超えると、その効果が飽和するだけでなく、熱間延性が低下して疵が発生しやすい。よって、鋼中にTeを添加する場合、Te含有量は、0.0003~0.2%であり、好ましくは0.0005~0.1%、さらに好ましくは0.001~0.01%である。
Seは、被削性を向上させる元素である。また、Seは、MnSeを生成したり、MnSと共存することでMnSの変形能を低下させ、MnS形状の伸延を抑制したりする働きがある。このように、Seは、異方性の低減に有効な元素である。しかしながら、Se含有量が0.0003%未満である場合、これらの効果が認められない。また、Se含有量が0.2%を超えると、その効果が飽和する。よって、鋼中にSeを添加する場合、Se含有量は、0.0003~0.2%であり、好ましくは0.0005~0.1%、さらに好ましくは0.001~0.01%である。
Biは、被削性を向上させる元素である。しかしながら、Bi含有量が0.001%未満である場合、その効果が得られない。また、鋼中にBiを添加してBi含有量が0.5%を超えると、被削性を向上させる効果が飽和するだけでなく、熱間延性が低下して疵が発生しやすい。よって、鋼中にBiを添加する場合、Bi含有量は、0.001~0.5%であり、好ましくは0.01~0.3%、さらに好ましくは0.04~0.25%である。
Pbは、被削性を向上させる元素である。しかしながら、Pb含有量が0.001%未満である場合、その効果が認められない。また、鋼中にPbを添加してPb含有量が0.5%を超えると、被削性を向上させる効果が飽和するだけでなく、熱間延性が低下して疵が発生しやすい。よって、鋼中にPbを添加する場合、Pb含有量は、0.001~0.5%であり、好ましくは0.01~0.3%、さらに好ましくは0.04~0.25%である。
Crは、焼入れ性を向上すると共に、鋼に焼戻し軟化抵抗を付与する元素であり、高強度が必要な鋼に添加される。しかしながら、Cr含有量が0.001%未満である場合、これらの効果が得られない。また、鋼中にCrを多量に添加すると、具体的には、Cr含有量が3.0%を超えると、Crの炭化物が生成して鋼が脆化する。よって、鋼中にCrを添加する場合、Cr含有量は、0.001~3.0%であり、好ましくは0.01~2.3%、さらに好ましくは0.1~1.8%である。
Moは、鋼に焼戻し軟化抵抗を付与すると共に、焼入れ性を向上させる元素であり、高強度が必要な鋼に添加される。しかしながら、Mo含有量が0.001%未満である場合、これらの効果が得られない。また、鋼中にMoを添加してMo含有量が1.0%を超えると、その効果は飽和する。よって、鋼中にMoを添加する場合、Mo含有量は、0.001~1.0%であり、好ましくは0.01~0.8%、さらに好ましくは0.05~0.5%である。
Niは、フェライトを強化し、延性を向上させると共に、焼入れ性及び耐食性を向上させる元素である。しかしながら、Ni含有量が0.001%未満である場合、その効果は認められない。また、鋼中にNiを添加してNi含有量が5.0%を超えると、機械的性質の点で効果が飽和し、被削性が低下する。よって、鋼中にNiを添加する場合、Ni含有量は、0.001~5.0%であり、好ましくは0.1~4.0%、さらに好ましくは0.3~3.0%である。
Cuは、フェライトを強化すると共に、焼入れ性及び耐食性を向上させる元素である。しかしながら、Cu含有量が0.001%未満である場合、その効果が認められない。また、鋼中にCuを添加してCu含有量が5.0%を超えると、機械的性質の点で効果が飽和する。よって、鋼中にCuを添加する場合、Cu含有量は、0.001~5.0%であり、好ましくは0.01~4.0%、さらに好ましくは0.1~3.0%である。なお、Cuは、特に熱間延性を低下させ、圧延時の疵の原因になりやすいため、この場合には、Niを同時に添加することが好ましい。
Liは、鋼中で低融点酸化物を形成することにより工具摩耗を抑制する。しかしながら、Li含有量が0.00001%未満である場合、その効果が認められない。また、鋼中にLiを添加してLi含有量が0.005%を超えると、その効果が飽和するばかりでなく、耐火物の溶損を引き起こすことがある。よって、鋼中にLiを添加する場合、Li含有量は、0.00001~0.005%であり、好ましくは0.0001~0.0045%である。
Naも、Liと同様に鋼中で低融点酸化物を形成することにより工具摩耗を抑制する。しかしながら、Na含有量が0.00001%未満である場合、その効果が認められない。また、鋼中にNaを添加してNa含有量が0.005%を超えると、その効果が飽和するばかりでなく、耐火物の溶損を引き起こすことがある。よって、鋼中にNaを添加する場合、Na含有量は、0.00001~0.005%であり、好ましくは0.0001~0.0045%である。
Kも、Liと同様に鋼中で低融点酸化物を形成することにより工具摩耗を抑制する。しかしながら、K含有量が0.00001%未満である場合、その効果が認められない。また、鋼中にKを添加してK含有量が0.005%を超えると、その効果が飽和するばかりでなく、耐火物の溶損を引き起こすことがある。よって、鋼中にKを添加する場合、K含有量は、0.00001~0.005%であり、好ましくは0.0001~0.0045%である。
Baも、Liと同様に鋼中で低融点酸化物を形成することにより工具摩耗を抑制する。しかしながら、Ba含有量が0.00001%未満である場合、その効果が認められない。また、鋼中にBaを添加してBa含有量が0.005%を超えると、その効果が飽和するばかりでなく、耐火物の溶損を引き起こすことがある。よって、鋼中にBaを添加する場合、Ba含有量は、0.00001~0.005%であり、好ましくは0.0001~0.0045%である。
Srも、Liと同様に鋼中で低融点酸化物を形成することにより工具摩耗を抑制する。しかしながら、Sr含有量が0.00001%未満である場合、その効果が認められない。また、鋼中にSrを添加して0.005%を超えると、その効果が飽和するばかりでなく、耐火物の溶損を引き起こすことがある。よって、鋼中にSrを添加する場合、Sr含有量は、0.00001~0.005%であり、好ましくは0.0001~0.0045%である。
本実施例においては、表1~表5に示す組成を有する鋼を150kg真空溶解炉で溶製後、得られた鋼を1250℃の温度条件下で熱間鍛造により直径が50mmの円柱状に鍛伸し、1300℃で2時間加熱後空冷する均質化処理を行い、その後に1200℃で1時間加熱後空冷する熱処理を行った。その後、得られた鋼材から直径が48mm、長さが105mmである工具寿命評価用試験片を切り出し、この試験片を試験(試験No.A1~E12)に供した。
また、試験No.A11、B8、B9、C9、D8~10、E10では、Al含有量と、キャリアガスの酸素濃度と、キャリアガス中の切削油材の量とが適切に制御されている。そのため、これらの試験No.では、工具上へのアルミナを主体とする酸化物の保護膜の形成によって、工具摩耗が改善した。例えば、試験No.A11では、Al含有量が0.05%以下である試験No.A13に比べて工具摩耗が改善した。試験No.B9では、キャリアガスの酸素濃度が21%よりも低い試験No.B13に比べて工具摩耗が改善した。試験No.C9では、Al含有量が1.0%以上である試験No.C13に比べて工具摩耗が改善した。試験No.D8では、切削油材の供給速度が200mlを超えている試験No.D13に比べて工具摩耗が改善した。
試験No.A9では、キャリアガスの酸素濃度が21%よりも低い、すなわちキャリアガスに酸化性ガスを用いていないので、被削材中の固溶Alとミスト中の酸素との化学反応が起こりにくかった。そのため、この試験No.A9では、工具上にアルミナを主体とする酸化物の保護膜を形成して工具寿命を向上するという効果が得られず、試験No.A2と比べて工具摩耗が進行した。試験No.A10では、ミスト中の切削油剤の量が少なすぎるため、潤滑作用が得られず、試験No.A3と比べて工具摩耗が進行した。試験No.A11では、試験No.A1と比べて、吐出口断面積S(mm2)を供給圧力P(MPa)で割った値S/Pが小さすぎるため、ミストの粒径が大きく増加した。そのため、この試験No.A11では、試験No.A1と比べて、切削油剤が工具に付着しすぎて、工具上にアルミナを主体とする酸化物が生成しにくいため、工具摩耗が進行した。試験No.A12では、Al含有量が不足しているため、被削材中の固溶Alとミスト中の酸素との化学反応が起こりにくかった。そのため、この試験No.A12では、工具上にアルミナを主体とする酸化物の保護膜を形成するという効果が得られず、試験No.A6と比べて工具摩耗が進行した。試験No.A13では、Al含有量が不足しているため、被削材中の固溶Alとミスト中の酸素との化学反応がほとんど起こらなかった。そのため、この試験No.A13では、試験No.A11と比べて工具摩耗が進行した。
2 ミスト
3 工具寿命評価用試験片(試験片)
4 穴あけ位置
5 油穴
6 逃げ面
Claims (7)
- 0.01~200ml/時の供給速度で供給される切削油剤と、体積%で21%以上かつ50%以下の酸素を含む酸化性ガスとを混ぜ合わせてミストを生成し、このミストを工具の刃先表面及び機械構造用鋼の表面に吹きかけながら、前記機械構造用鋼を切削し、
前記機械構造用鋼が、質量%で、
C:0.01~1.2%、
Si:0.005~3.0%、
Mn:0.05~3.0%、
P:0.001~0.2%、
S:0.001~0.35%、
N:0.002~0.035%、
Al:0.05~1.0%
を含有し、残部がFeおよび不可避的不純物からなり、
O:0.003%以下
に制限し、
かつAl含有量[Al%]と、N含有量[N%]とが、[Al%]-(27/14)×[N%]≧0.05を満足する
ことを特徴とする機械構造用鋼の切削方法。 - 前記機械構造用鋼が、さらに、質量%で、
Ca:0.0001~0.02%、
Ti:0.0005~0.5%、
Nb:0.0005~0.5%、
W:0.0005~1.0%、
V:0.0005~1.0%、
Ta:0.0001~0.2%、
Hf:0.0001~0.2%、
Mg:0.0001~0.02%、
Zr:0.0001~0.02%、
Rem:0.0001~0.02%、
Sb:0.0001~0.015%、
Sn:0.0005~2.0%、
Zn:0.0005~0.5%、
B:0.0001~0.015%、
Te:0.0003~0.2%、
Se:0.0003~0.2%、
Bi:0.001~0.5%、
Pb:0.001~0.5%、
Cr:0.001~3.0%、
Mo:0.001~1.0%、
Ni:0.001~5.0%、
Cu:0.001~5.0%、
Li:0.00001~0.005%、
Na:0.00001~0.005%、
K:0.00001~0.005%、
Ba:0.00001~0.005%、
Sr:0.00001~0.005%
の内の1種以上をさらに含有することを特徴とする請求項1に記載の機械構造用鋼の切削方法。 - 前記酸化性ガスの流量をQ(l/分)、前記切削油剤の供給速度をq(ml/時)と定義した場合に、q/Qの比が、0.001~1を満たすことを特徴とする請求項1または2に記載の機械構造用鋼の切削方法。
- 前記ミストを吐出する出口の断面積をS(mm2)、前記酸化性ガスの供給圧力をP(MPa)と定義した場合に、S/Pの比が、0.2~40を満たすことを特徴とする請求項1または2に記載の機械構造用鋼の切削方法。
- 前記切削油剤を供給する吐出ポンプの1秒当たりの吐出回数が、0.05~16回であることを特徴とする請求項1または2に記載の機械構造用鋼の切削方法。
- 前記酸化性ガスの温度が、-80℃以上かつ40℃以下であることを特徴とする請求項1または2に記載の機械構造用鋼の切削方法。
- 前記酸化性ガスの酸素濃度が、25%以上かつ50%以下であることを特徴とする請求項1または2に記載の機械構造用鋼の切削方法。
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Also Published As
Publication number | Publication date |
---|---|
KR20120024930A (ko) | 2012-03-14 |
CN102470502A (zh) | 2012-05-23 |
US20120085209A1 (en) | 2012-04-12 |
EP2554329A4 (en) | 2013-03-27 |
AU2011233202A1 (en) | 2012-01-12 |
JP5009438B2 (ja) | 2012-08-22 |
EP2554329B1 (en) | 2014-01-29 |
US8545137B2 (en) | 2013-10-01 |
KR101290880B1 (ko) | 2013-07-29 |
EP2554329A1 (en) | 2013-02-06 |
JPWO2011122233A1 (ja) | 2013-07-08 |
CN102470502B (zh) | 2014-11-19 |
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