WO2011055817A2 - Procédé d'impression de matières fibreuses et de cuir par papier transfert - Google Patents

Procédé d'impression de matières fibreuses et de cuir par papier transfert Download PDF

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Publication number
WO2011055817A2
WO2011055817A2 PCT/JP2010/069811 JP2010069811W WO2011055817A2 WO 2011055817 A2 WO2011055817 A2 WO 2011055817A2 JP 2010069811 W JP2010069811 W JP 2010069811W WO 2011055817 A2 WO2011055817 A2 WO 2011055817A2
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WO
WIPO (PCT)
Prior art keywords
paper
printing
water
printing method
printed
Prior art date
Application number
PCT/JP2010/069811
Other languages
English (en)
Japanese (ja)
Other versions
WO2011055817A3 (fr
Inventor
眩士 山本
山田　英二
久繁 寺尾
Original Assignee
Yamamoto Genshi
Yamada Eiji
Terao Hisashige
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yamamoto Genshi, Yamada Eiji, Terao Hisashige filed Critical Yamamoto Genshi
Priority to JP2011505049A priority Critical patent/JP4778124B2/ja
Priority to CN201080050257.8A priority patent/CN102597364B/zh
Priority to EP10828375.5A priority patent/EP2500464A4/fr
Publication of WO2011055817A2 publication Critical patent/WO2011055817A2/fr
Publication of WO2011055817A3 publication Critical patent/WO2011055817A3/fr

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/003—Transfer printing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/0041—Digital printing on surfaces other than ordinary paper
    • B41M5/0076—Digital printing on surfaces other than ordinary paper on wooden surfaces, leather, linoleum, skin, or flowers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/003—Transfer printing
    • D06P5/004—Transfer printing using subliming dyes
    • D06P5/005—Transfer printing using subliming dyes on resin-treated fibres
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/36—Polyalkenyalcohols; Polyalkenylethers; Polyalkenylesters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/12—Coatings without pigments applied as a solution using water as the only solvent, e.g. in the presence of acid or alkaline compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16—Sizing or water-repelling agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/0041—Digital printing on surfaces other than ordinary paper
    • B41M5/0047—Digital printing on surfaces other than ordinary paper by ink-jet printing

Definitions

  • the present invention relates to a textile material or leather material printing method using printed paper.
  • the present invention relates to a printing paper obtained by printing a dye ink on a printing paper using a printing paper obtained by applying a mixed paste comprising a water-soluble synthetic binder, a natural glue and an auxiliary agent to a base paper.
  • the present invention relates to a textile material or leather material printing method, characterized in that a dye fixing process (steaming or the like) is performed in a state where paper is attached to a fiber material or leather material.
  • This textile printing method is a novel processing method characterized by performing a steaming process or the like in a state in which textile paper is attached to a fiber material or leather material, and is named “paper textile printing method”.
  • the “printing base paper” used in the present specification and claims refers to the base paper used for the production of the printing paper, and the “printing paper” refers to the printing base paper to which the mixed glue has been applied.
  • Paper means textile paper to which dye ink is applied.
  • a paper having a release agent layer using a water-soluble varnish or a solvent-type varnish is applied, and a water-soluble paste is applied onto the release agent layer and dried.
  • a method is proposed in which a paste layer is formed, and dye ink is printed on the paste layer by ink-jet printing so that the dye is uniformly held in the paste layer to produce transfer paper, and transfer printing is performed using the transfer paper.
  • a method of using a special multilayer paper as the transfer paper is also known.
  • polyester fiber sublimation transfer method (dispersion transfer printing method) using disperse dyes that sublimate with heat, and wet fabrics made of cellulosic or protein fibers with water, and then strongly bonded together with transfer paper.
  • a wet transfer method (disclosed in Japanese Patent No. 2925562, Japanese Patent Application Laid-Open No. 06-287870, etc.) for transferring and printing a dye.
  • the application of the sublimation transfer method is limited to polyester fibers and has a low fastness.
  • the wet transfer method tends to have a problem that the pattern is not delicate and reproducible.
  • an ink receiving layer is formed by applying and drying a mixed glue liquid made of glue and resin on a release agent layer of a release paper, and then drying the ink receiving layer.
  • a method is disclosed in which dye ink is printed on a receiving layer, then dry-transferred onto a fabric, the release paper is peeled off, and then the dye transferred onto the fabric is fixed by steaming or the like.
  • the release paper used in this method requires a release agent coating process, which is expensive in its production, and the production cost is several times (5 to 10 times) that of general base paper.
  • the ink receiving layer may be transferred 100% and only the release paper may not be removed cleanly. In such a case, defective products are generated, and it is difficult to recycle paper. Further, in order to cope with a small quantity and a variety of production, the transfer paper is cut into small pieces, so that it is practically difficult to use the paper by recycling it.
  • the melting point of the release agent is generally low, the drying temperature after applying the mixed paste cannot be raised. As a result, the drying time becomes longer and the production efficiency becomes very poor. For example, since the melting point of the polyethylene laminate release agent is about 110 ° C., the drying temperature cannot be increased to 110 ° C. or higher, and it is difficult to increase the production capacity (speed).
  • this method has the following problems.
  • A An expensive release paper is required. Therefore, the cost is increased.
  • B There is a difficulty in releasability (reproducibility of paper peeling) in the process of transferring the ink receiving layer to the fabric, and the ink receiving layer may not be transferred to the 100% fabric (peeling instability). If the ink receiving layer partially remains on the transfer paper, the portion becomes mottled and defective products are generated.
  • C Since the ink receiving layer is transferred to the fabric (preferably 100%), the used glue and resin flow out to the drainage in the washing process of the fabric after the dye fixing process, and excess dye ink also flows into the drainage. , Contaminate the drainage.
  • Japanese Patent No. 2925562 JP 06-287870 A Japanese Patent No. 4058470 Japanese Patent Laid-Open No. 06-270596
  • the present invention is a textile material or leather material printing method, which exhibits excellent printing performance excellent in texture, fineness, fastness, color development and the like, and has the problems (A) to (1) described above.
  • the inventor has conducted extensive research on textile and leather printing methods using the inkjet printing method, Water-soluble synthetic binder that has film-forming properties and produces strong adhesive force by heating and pressurization, while the adhesive strength is easily reduced by applying dye fixing treatment by steaming, etc., and this water-soluble synthetic binder
  • a natural paste that has a good compatibility with the dye and has an excellent property of absorbing and holding dye ink uniformly, and a mixed paste consisting of an auxiliary agent is applied to commercially available general paper (base paper), dried and printed Get the paper,
  • base paper general paper
  • the textile paper with dye ink printed on this textile paper is affixed to a cloth or the like and subjected to a dye fixing process such as steaming to fix and color the dye, and at the same time provide an adhesive force between the textile paper and the textile.
  • the present invention A process of obtaining dyed paper by printing a dye ink on a printing paper obtained by applying a mixed paste composed of a water-soluble synthetic binder, a natural glue and an auxiliary agent to a base paper, and drying; A step of adhering the printed paper to a fiber material or leather material, and applying the pressure and heat to the fiber material or leather material, and a dye fixing process in a state in which the printed paper is applied to the fiber material or leather material, and then printing Removing the paper, It is a paper printing method of a fiber material or leather material characterized by having (Claim 1).
  • the paper printing method of the present invention having the above-described configuration is a novel printing method that solves the problems of the known methods, for example, the problems (A) to (E) described above.
  • a commercially available inexpensive paper instead of an expensive release paper, to solve the problem of defective products caused by peeling instability in the known transfer printing method, and to further increase the drainage load. It can be reduced, it can be applied at high temperature while maintaining the texture, and high-density dyeing is possible, and it does not use a release agent (low melting point).
  • the drying temperature after coating can be increased to 150 to 180 ° C., and the coating speed can be increased three times or more).
  • it is possible to print cellulosic fibers, protein fibers, leather or synthetic fibers by utilizing a roller type or flat plate type pressurization / heating facility which is currently widely used in the dyeing industry. it can.
  • the water-soluble synthetic binder constituting the mixed paste is water-soluble, polymerized by heating to have a high molecular weight, and has a film-forming property.
  • the coating formed on or in the base paper it produces an adhesive force that bonds the fiber or leather to the base paper, while the dye fixing process (steaming, humidification, Or, it has a property that the adhesive strength is reduced by dry heat treatment at high temperature.
  • water-soluble synthetic binder examples include those synthesized mainly by petrochemicals. Further, a binder that does not inhibit dyeing is desired. Specifically, water-soluble polyvinyl alcohol binder, water-soluble acrylic binder, water-soluble urethane binder, water-soluble urethane-modified ether binder, water-soluble polyethylene oxide binder, water-soluble polyamide binder, water-soluble phenol binder Water-soluble vinyl acetate binders, water-soluble styrene acrylic acid binders, water soluble styrene maleic acid binders, water soluble styrene acrylic maleic acid binders, water soluble polyester binders, water soluble polyvinyl acetal binders, water soluble polyesters Examples thereof include urethane binders, water-soluble polyether / urethane binders, water-soluble hot melt adhesives, and the like, and one or a mixture of two or more selected from these can be preferably used.
  • the water-soluble synthetic binder includes a water-soluble polyvinyl alcohol binder, a water-soluble acrylic binder, a water-soluble polyester binder, a water-soluble polyether / urethane binder, and a water-soluble hot melt adhesive.
  • the natural paste constituting the mixed paste is obtained by processing the raw material of the paste produced in nature as it is or physically or chemically. Natural glues show adhesive strength, but even when heated, the polymerization does not proceed and the adhesive strength does not increase like water-soluble synthetic binders. On the other hand, it can be removed by steaming or dry heat treatment, and therefore it is preferably hydrophilic. Moreover, the compatibility with dye ink is high, and the property which absorbs and retains dye ink uniformly is calculated
  • animal pastes are classified into animal pastes, plant pastes, and mineral pastes.
  • animal paste include gelatin extracted from collagen contained in animal skin and bone.
  • plant pastes include carboxymethyl cellulose that is processed using starch and cellulose as starting materials.
  • mineral paste include clay collected from clay minerals.
  • natural gum paste etherified tamarind gum, etherified locust bean gum, etherified guar gum, acacia arabic gum, etc.
  • fiber-derived paste carboxymethylcellulose, hydroxyethylcellulose, etc.
  • Polysaccharides starch, glycogen, dextrin, amylose, hyaluronic acid, kudzu, konjac, potato starch, etherified starch, esterified starch, etc.
  • seaweed sodium alginate, agar, etc.
  • mineral paste bentonite, porcelain clay, silicic acid
  • Aluminium and its derivatives silica, diatomaceous earth, clay, kaolin, acid clay, etc.
  • animal glue casein, gelatin, egg protein, etc.
  • natural gum paste carboxymethylcellulose, etc., cellulose derivatives, starch derivatives such as etherified starch, seaweeds such as sodium alginate, mineral pastes such as silicon oxide, aluminum silicate, clay, animal pastes, etc.
  • the natural paste is one or more selected from the group consisting of natural gum paste, cellulose derivatives, starch derivatives, seaweeds, mineral glues and animal glues.
  • natural glue 95: 5 to 20:80 (weight ratio) in terms of solid content.
  • the auxiliary agent constituting the mixed paste is added for the purpose of improving various physical properties of the mixed paste liquid, promoting dyeing properties, and the like.
  • auxiliary agents include surfactants, thickeners, moisturizers, pH adjusters, alkali agents, thickening agents, preservatives, antifungal agents, deaerators, antifoaming agents, and reducing agents.
  • the auxiliary agent is one or two or more selected from the auxiliary agents exemplified herein.
  • the paper printing method described in 1. is provided.
  • the mixed paste used in the paper printing method of the present invention is a hydrophilic mixture in which a water-soluble synthetic binder, a natural paste and an auxiliary are blended.
  • the mixed paste (hydrophilic mixture) or a solution thereof (mixed paste solution) is applied to a base paper and dried to obtain a printing paper used in the present invention.
  • This layer is a multi-component glue layer containing a mixture of a water-soluble synthetic binder and a natural glue and further mixed with various auxiliaries.
  • This layer functions as an ink receiving layer for holding the dye ink printed on the printing paper.
  • the printing paper is brought into close contact with a fabric or the like and heated and pressed, it is temporarily (printing). It is also an adhesive layer that strongly bonds printed paper (consisting of paper and a multi-component glue layer) to fibers such as fabric.
  • the dye ink is printed on the printed paper manufactured as described above based on the pattern of printing, and then dried to produce a printed paper.
  • the mixed paste is applied to one surface side of the printing paper, the dye ink is printed on the surface side.
  • the dye ink used herein include inks that use reactive dyes, acid dyes, metal complex dyes, direct dyes, disperse dyes, cationic dyes, and the like as dyes.
  • the dye ink is obtained by dissolving or dispersing these dyes in a dye dissolving agent such as water.
  • the dye included in the dye ink is one or more selected from the group consisting of reactive dyes, acid dyes, metal complex dyes, direct dyes, disperse dyes and cationic dyes.
  • the paper printing method according to any one of claims 1 to 5, wherein the paper printing method is provided.
  • the water-based dye ink is an ink in which a dye is dissolved or dispersed with water or a solvent that dissolves in water as a main component.
  • the transfer paper produced as described above is brought into close contact with a fiber material or leather material, heated and pressurized, and a dye fixing process is performed in the close contact state.
  • the heating and pressurizing conditions can be the same as those in the case of ordinary transfer printing, but it is preferable to set the pressure slightly higher. By this heating and pressurization, the transfer paper is bonded to the fiber material or leather material.
  • Examples of the dye fixing treatment include heating by steam, which is usually performed in printing using a reactive dye or the like, and heating in a state where humidification or moisture is applied.
  • a method of drying and heating can also be employed.
  • the transfer paper can be peeled off by heating with this steam or heating in a state where humidification or moisture is applied.
  • the transfer paper may be peeled by a method of drying and heating, but can be more easily peeled off by applying moisture after drying and heating (fixing).
  • the dye fixing treatment may be performed after heating and pressurization, or may be performed simultaneously with the heating and pressurization.
  • heating / pressurizing and dye fixing treatment most of the dye in the dye ink printed on the printing paper is absorbed and dyed on the fiber material or leather material.
  • the dye fixing process fixes the dye dyed on the fiber material or leather material, and decreases the adhesive force between the printed paper and the fiber material or leather material.
  • the mixed glue layer formed on or in the base paper as described above functions as an adhesive layer by the heating and pressurization described above.
  • the transfer paper can be easily peeled off from the fabric or the like.
  • the adhesive strength is reduced by the dye fixing process by steaming or the like. That is, it is desirable that the layer of the mixed paste has a property of easily reducing the adhesive force when moisture is applied in the dye fixing process by steaming or the like, or in the process of peeling the printed paper.
  • the dyeing and fixing of the dye to the fiber material or leather material is performed by a treatment process such as steaming, and after the transfer paper is peeled, a washing process such as water washing or soaping is usually performed.
  • the mixed paste preferably has a property that can be easily washed and removed in this washing step.
  • the mixed paste has a function as an ink receiving layer, a function as a temporary adhesive layer, and a property that the adhesive strength is reduced and easily removed at the final stage of the dye fixing process by steaming or the like. Is required. Specifically, the following conditions are required to be satisfied. 1. Good compatibility with dye ink and does not interfere with dyeing on the fiber. That is, it is a mixed paste that gives excellent reproducibility of density and hue after dyeing. 2. By heat and pressure treatment, the fiber (fiber material, leather material) -paper can be temporarily strongly bonded. That is, in a dry state after applying pressure and applying heat, the fiber-paper has an adhesive force that strongly bonds temporarily (until the final stage of the fixing process). 3.
  • the ink absorbency is good, the apparent ink drying property is good, and the fineness of the color pattern is also excellent. That is, the ink receptivity is large. 4).
  • Adhesive strength is easily reduced by a dye fixing process such as steaming. That is, it is a mixed paste that easily loses adhesive strength when moisture or moisture is applied, and can easily peel the transfer paper from the fabric or leather. 5. It can be removed from the coloring material by washing with water after washing the dye, soaping, or the like. That is, it is a mixed paste having a high water solubility even after heating.
  • the object of the present invention can be achieved by using a mixed paste of a water-soluble synthetic binder and a natural paste that satisfies these conditions.
  • the present invention provides a printing paper and a printing paper used in this method. That is, A printing paper used in the paper printing method according to any one of claims 1 to 7, wherein a mixed paste comprising a water-soluble synthetic binder, a natural glue and an auxiliary agent is applied to the base paper. A printing paper used for the paper printing method according to any one of claims 1 to 7, wherein the printing paper is obtained by drying, and is a water-soluble printing paper. Printing obtained by printing a dye ink on a printing paper obtained by applying a mixed paste comprising a natural synthetic binder, a natural glue and an auxiliary agent to a base paper and drying it It is paper (claim 9).
  • the present invention further provides a fiber material or leather material printed by the paper printing method described above. That is, a fiber material or leather material printed by the paper printing method according to any one of claims 1 to 7 (claim 10).
  • the feature of the paper printing method of the present invention is that it is composed of a mixed paste in which various auxiliary agents are blended with a multi-component mixed system of a water-soluble synthetic binder and a natural paste that do not inhibit dyeing.
  • a printing paper having an ink receiving layer and an adhesive layer whose adhesive strength is lowered by a dye fixing process (application of moisture, heating in some cases) by steaming or the like.
  • a dyed paper is printed on the textile paper to produce a textile paper, and the textile paper is peeled off by applying a dye fixing process by steaming or the like while the textile paper is attached to a fabric or leather.
  • the paper printing method of the present invention You can use inexpensive paper that is generally available on the market instead of expensive release paper. Can solve the problem of defective products caused by peeling instability in the known transfer printing method, The drainage load can be further reduced. High-temperature pasting and high-density dyeing are possible while maintaining the texture. Since no release agent is used, excellent effects such as increasing the drying temperature of the mixed paste and improving the coating efficiency can be obtained. As a result, it is possible to provide a finely printed pattern with good reproducibility based on excellent economy and ecology.
  • the base paper used in the paper printing method of the present invention is not particularly limited as long as it is a paper that can be provided with the mixed paste and has strength, flexibility, and the like that can be used as a printing paper. Therefore, since generally used paper or commercially available ordinary paper can be used as it is as a base paper, it is inexpensive. Although processed paper such as coated paper may be used, it is not necessary to use expensive release paper having a release layer. Therefore, the manufacturing cost can be greatly reduced.
  • a generally used inexpensive paper preferably a pulp such as kraft pulp or grind pulp or recycled paper having a basis weight of 10 to 100 g / m 2 , more preferably 20 to 80 g / m 2 Pulp paper made from paper, recycled paper, and the like are used as raw materials.
  • a paper having a thickness of about 0.01 to 0.5 mm is preferable.
  • Specific examples include pure white, bleached or unbleached kraft paper manufactured by Nippon Paper Industries Co., Ltd., brands manufactured by Nippon Daishowa Paperboard Co., Ltd., silver bamboo, silver candy, white silver, etc. Glassine paper, bleached kraft paper, unbleached kraft paper, and various coated papers manufactured by Mishima Paper Co., Ltd., are just examples.
  • water-soluble synthetic binder constituting the mixed paste applied to the base paper those exemplified above (listed in claim 2) can be preferably used.
  • water-soluble hot melt adhesive can include alkaline water-soluble hot melt adhesives of maleic acid alternating copolymers, water sensitive hot melt adhesives, polyvinyl alcohol hot melt adhesives, and the like.
  • the content in the mixed paste liquid is 0.2 to 5% by weight in the case of an anionic surfactant added as a surface tension reducing agent or a penetrating agent.
  • a moisturizing agent added to improve adhesion and dyeing power to, for example, polyhydric alcohols such as polyethylene glycol, glycerin, thiodiglycol, diethylene glycol, urea, thiourea, dicyandiamide, etc.
  • acrylic synthetic paste which is a thickening agent for increasing the viscosity of the mixed paste solution and facilitating application to the base paper, preservatives, antifungal agents, 0.1 to 5% by weight for defoaming agents, degassing agents and anti-reducing agents, 1 to 5 for alkaline agents such as soda ash, sodium bicarbonate, sodium oxalate and sodium acetate added when reactive dyes are used 15% by weight Disperse dyes and 0.1 to 3 wt% in the case of PH adjusting agents such as ammonium sulfate or phosphate monobasic sodium applied in the case of using an acid dye, preferable results when blending is obtained.
  • PH adjusting agents such as ammonium sulfate or phosphate monobasic sodium applied in the case of using an acid dye
  • a printing paper used in the present invention is obtained by applying a mixed paste (hydrophilic mixture) or a solution thereof (mixed paste liquid) comprising a water-soluble synthetic binder, a natural paste, and an auxiliary agent to a base paper and drying it. can get.
  • the method of applying to the base paper is not particularly limited, but a method of applying, spraying, or base paper a mixed paste liquid obtained by dissolving the above-mentioned components constituting the mixed paste in a solvent such as water. The method etc. which are immersed in a mixed paste liquid and made to absorb can be mentioned.
  • the mixed paste solution After applying the mixed paste solution to the base paper, it is dried to dry the layer (ink) on the base paper (if the application is applied) or inside the base paper (if the application is absorbed) A receiving layer / adhesive layer) is formed, and a printed paper is obtained.
  • the amount of the mixed paste applied to the base paper is preferably 10 to 100 g / m 2 in terms of dry.
  • the application amount of the mixed glue is related to the cost of printing paper and the strength and color developability when the binders adhere to the fabric. Therefore, when this application is performed by application using a coating machine, it is important to manage the amount of adhesion, such as adjusting the coater clearance and winding speed.
  • the type of surface tension reducing agent anionic, nonionic surfactants, alcohols, etc.
  • the application device for the mixed paste liquid include a comma coater, a gravure coater, a reverse coater, an air knife coater, a jet coater, and an impregnation device, but these are only examples.
  • the dyed ink is printed on the printed paper thus obtained, and dried to produce a printed paper.
  • inkjet printing is preferable, but other methods such as gravure printing and screen printing can also be used, and printing can be performed by the same methods and conditions as in known transfer textile printing.
  • the dye ink used for ink jet printing a dye dissolved or dispersed with a dye dissolving agent or a dispersing agent is used.
  • the dye solubilizer include water, thiodiglycol, polyethylene glycol, glycerin, ethylene glycol, and ⁇ -caprolactam.
  • drying ink, surface tension adjuster, viscosity adjuster, pH adjuster, preservative, antifungal agent, sequestering agent, antifoaming agent, deaerator, etc. are added to dye ink as necessary Is done.
  • a dye ink is used in which these components are mixed and a minute amount of insoluble matter is filtered and degassed with a membrane filter of 1 micron or less.
  • the type of dye is selected from reactive dyes, direct dyes, acid dyes, metal complex salt dyes, disperse dyes, cationic dyes, etc., depending on the type of fibers constituting the fabric. In this case, it is desirable to atomize the average particle size of the dye to about 0.1 ⁇ m using 0.1 to 0.3 mm zirconium beads.
  • the printed paper produced as described above is brought into close contact with the fabric to be printed, and is pressed and heated. Then, the dye fixing process is performed by steaming or the like in a state where the printed paper and the fabric are bonded. By this treatment, dyeing (coloring or fixing of the dye) to the fabric or leather is performed, and the adhesive force of the ink receiving layer / adhesive layer is reduced, so that the printed paper can be easily peeled and removed.
  • the fabric and the like are washed (washing, soaping, washing with water) to wash away and remove the water-soluble synthetic binder and the natural paste adhering to the fabric with a small amount.
  • a fine printed fabric or printed product having a good texture is obtained.
  • the washing step can be omitted.
  • the present invention can be said to be an ecological processing method.
  • the paper textile printing method of the present invention is applied to textile textiles and leather materials.
  • the fiber material to which the present invention is applied includes both natural fiber materials and synthetic fiber materials.
  • natural fiber materials include cellulosic fiber materials such as cotton, hemp, lyocell, rayon and acetate, and protein fiber materials such as silk, wool and animal hair.
  • synthetic fiber material include fibers called polyamide fiber (nylon), vinylon, polyester, polyacryl and the like.
  • Examples of the leather material to which the present invention is applied include animal leather, for example, natural leather such as cow, buffalo, pig, horse, sheep, goat, kangaroo, deer, rabbit, rabbit, rabbit, camel, etc. The thing dried through the process can be mentioned.
  • the paper printing method of the present invention is applied to single, blended, blended or interwoven products of these fiber materials such as woven fabrics, knitted fabrics, nonwoven fabrics, and leathers. Furthermore, a composite fiber may be used.
  • the fabric or the like may be pretreated with a chemical agent that affects dyeing or an agent that is effective in promoting dyeing, and then used for paper printing.
  • a chemical agent that affects dyeing or an agent that is effective in promoting dyeing for example, when reactive dyes are printed, 3-15% by weight of sodium carbonate, potassium carbonate, sodium bicarbonate, sodium silicate, sodium acetate, sodium sesquicarbonate, sodium trichloroacetate, etc. as an alkaline agent is used to prevent yellowing during transfer.
  • a pad containing a mixed solution containing 3 to 25% by weight of urea and 0.05 to 1% by weight of a hydrophilic thickening substance such as sodium alginate as a migration inhibitor is dried. Also good.
  • an acid ammonium salt such as ammonium sulfate or ammonium tartrate is used in an amount of 0.5 to 5% by weight as a dyeing accelerator, and an acid-resistant natural gum 0.05 to 0.00% as a migration inhibitor. You may pad and dry the liquid mixture containing 5 weight%. However, it is a feature of the present invention that usually no pretreatment of these doughs is necessary.
  • the conditions for the dye fixing process by steaming, etc. performed by bringing the printed paper into close contact with the cloth, etc. can be used as they are, the same conditions as the dye fixing process employed in the normal direct printing method.
  • the dye is a reactive dye
  • steaming is performed by a one-phase steam fixing method at 100 to 105 ° C. for 5 to 20 minutes, and when the ink receiving layer does not contain an alkali, a two-phase method (for example, a cold fix method)
  • a steaming treatment can be performed at 100 to 105 ° C. for 10 to 30 minutes.
  • the paper When peeling the paper from the dough, it is easy to peel off the paper in a state where moisture and moisture after steaming are applied.
  • the dye is a disperse dye
  • HT steaming or dry heat treatment is performed at 160 to 220 ° C. for 1 to 15 minutes.
  • the paper can be peeled off by the dry heat treatment, but the paper can be easily peeled off by applying a small amount of moisture or moisture after the dry heat treatment.
  • the dye fixing process by steaming, etc., it can be washed by washing (water washing, soaping, water washing, water washing, reduction washing, water washing in the case of disperse dyes) under the same conditions as in the conventional transfer printing method. It is possible to obtain a fine, dense and dense printed matter. In the case of disperse dyes, even if washing is omitted, it is possible to obtain a fine, dense print with a good texture.
  • % means% by weight.
  • Example 1 As an ink receiving layer / adhesive layer, 134 g of POVAL AP-17 (15% water-soluble polyvinyl alcohol binder aqueous solution: manufactured by NIPPON BI POVAL), hydran AP-20 (45% aqueous polyester / urethane binder: DIC Corporation) 100 g, urea 20 g, dicyandiamide 10 g, soda ash 30 g, FD Algin BL (Furukawa Chemical Industries, Ltd .: sodium alginate low-viscosity product powder) 10 g, water 86 g, thickener F (acrylic synthetic paste paste: Sano) 10 g, a total of 400 g of the mixture was thoroughly stirred with a high-speed desper type stirrer (about 5,000 rpm) to make a high-viscosity paste.
  • POVAL AP-17 15% water-soluble polyvinyl alcohol binder aqueous solution: manufactured by NIPPON BI POVAL
  • This mixed glue solution which becomes the ink receiving layer and adhesive layer is applied to paper (manufactured by Nippon Paper Industries Co., Ltd., unbleached kraft paper, 70 g / m 2 , thickness 0.15 mm) using a coating machine (manufactured by Yokoyama Seisakusho). Applied and dried.
  • the coating amount (dry weight) of the mixed paste was 38 g / m 2 . In this way, a printing paper for reactive dyes was obtained.
  • a reactive dye ink solution (CI Reactive Red 226 10%, polyethylene glycol 5%, glycerin 5%, ⁇ caprolactam 5%, ion-exchanged water 75%) is applied onto the above-mentioned printing paper (HYPERCO: Muto).
  • a printed paper was obtained by printing with an on-demand type piezo ink jet printer) and drying.
  • this reactive dye printed paper and cotton broad cloth were brought into close contact, and heated and pressurized (155 ° C., 0.4 Mpa, 3 m / min. Roller type), and the printed paper was attached to the cotton broad cloth.
  • the cotton broad cloth was subjected to HT steam treatment at 105 ° C. for 10 minutes with the printed paper adhered. Thereafter, the printed paper was peeled off, but could be easily peeled off. After removing the printed paper, it was washed with water, soaped, washed with water and dried by a conventional method.
  • the printed fabric thus obtained has a delicate design and is dyed with fineness, robustness, and richness.
  • Example 2 Instead of 10 g of FD algin BL in Example 1, 65 g of FD algin BL is used, the thickener F is omitted, the amount of water used is increased to 300 g, the viscosity is adjusted, and the sticking temperature of the printed paper is 140. As a result of processing in the same manner except that the temperature was changed to 0 ° C., a printed fabric showing a soft texture in which a delicate design was dyed finely, firmly and densely as in Example 1 was obtained.
  • Example 3 As an ink receiving layer and adhesive layer, 85 g of NK binder M-302HN (water-soluble acrylic binder 46% aqueous solution: Shin-Nakamura Chemical Co., Ltd.), POVAL AP-17 (water-soluble polyvinyl alcohol binder 15% aqueous solution: Nippon Vinegar) (Poval Corporation) 134 g, urea 30 g, dicyandiamide 10 g, soda ash 35 g, FD Algin BL (Furukawa Chemical Co., Ltd .: sodium alginate), and water 96 g were mixed at 5,000 r. p. m.
  • NK binder M-302HN water-soluble acrylic binder 46% aqueous solution: Shin-Nakamura Chemical Co., Ltd.
  • POVAL AP-17 water-soluble polyvinyl alcohol binder 15% aqueous solution: Nippon Vinegar
  • urea 30 g urea 30 g
  • a high-viscosity despar-type stirrer was used to stir well to make a high-viscosity paste.
  • This mixed paste solution for ink-receiving layer / adhesive layer was applied and dried on inorganic coated paper (manufactured by Mishima Paper Co., Ltd., 50 g / m 2 ) using a coating machine.
  • the coating amount (dry weight) of the mixed paste was 40 g / m 2 . In this way, a printing paper for reactive dyes was obtained.
  • a reactive dye ink solution (CI Reactive Yellow95 15%, polyethylene glycol 5%, glycerin 5%, ⁇ -caprolactam 5%, ion-exchanged water 70%) is applied to the above-mentioned printing paper (HYPERCO: Muto Kogyo Co., Ltd.). (Printed on-demand type piezo ink jet printer), the design was printed and dried to obtain printed paper.
  • the reactive dye printed paper and the lyocell (Cortles registered trademark: Tencel) fiber satin fabric are brought into intimate contact, and heated and pressurized (150 ° C., 0.4 Mpa, 2.5 m / min. Roller type) to form the lyocell fabric.
  • Printed paper was affixed to.
  • the fabric with the printed paper applied was subjected to HT steam treatment at 105 ° C. for 8 minutes, and then the printed paper was peeled off, but it could be peeled off easily. After removing the printed paper, it was washed with water, soaped, washed with water and dried by a conventional method.
  • the lyocell printed fabric thus obtained had a delicate design, the fiber texture was flexible, and various fastnesses such as light resistance, washing, and sweat were grade 4 or higher.
  • Example 4 As the ink receiving layer and adhesive layer, 200 g of POVAL AP-17 (water-soluble polyvinyl alcohol-based binder 15% aqueous solution: manufactured by NIPPON BI POVAL), Hydran AP-20 (45% aqueous polyester-urethane binder: DIC) A mixture of 100 g, 20 g of urea, 10 g of dicyandiamide, 2 g of ammonium sulfate, 15 g of FD Algin BL (manufactured by Furukawa Chemical Co., Ltd .: sodium alginate), and 53 g of water. p. m was stirred well with a high-speed desper type stirrer to make a high-viscosity paste.
  • POVAL AP-17 water-soluble polyvinyl alcohol-based binder 15% aqueous solution: manufactured by NIPPON BI POVAL
  • Hydran AP-20 45% aqueous polyester-urethane binder: DIC
  • This ink receiving agent and adhesive paste were applied and dried on paper (Nihon Daishowa Paperboard Co., Ltd., silver bamboo, 50 g / m 2 ) using a coating machine.
  • the amount of the paste applied to dryness was 35 g / m 2 . In this way, a printing paper for disperse dyes was obtained.
  • disperse dye ink solution (CI Disperse Blue 60 6%, ethylene glycol 5%, glycerin 15%, nonionic dispersant 5%, anionic dispersant 5%, ion-exchanged water 64%) on the above printing paper
  • Printing was performed with an ink jet printer (HYPERCO: manufactured by Muto Kogyo Co., Ltd .: on-demand type piezo ink jet printer) and dried to obtain a printed paper.
  • the disperse dye printed paper and the polyester satin fabric were brought into close contact with each other, and heated and pressurized (150 ° C., 0.4 Mpa, 3 m / min. Roller type) to attach the printed paper to the polyester fabric.
  • the polyester fabric was subjected to HT steam treatment at 180 ° C. for 8 minutes while the printed paper was stuck, and then the printed paper was peeled off, but could be easily peeled off. After removing the printed paper, it was washed with water, reduced, washed, and dried by a conventional method.
  • the polyester printed fabric thus obtained had a delicate design, the texture of the fiber was flexible, and various fastnesses were grade 4 or higher.
  • Example 5 Nylon taffeta fabric was used in place of the polyester fabric in Example 4, acid dye ink was used as the dye ink, and steaming was performed at 100 ° C. for 30 minutes. As a result, the nylon taffeta printed fabric was delicate. It had a design, the texture of the fiber was flexible, and the various fastnesses such as light resistance, washing and sweat were also good.
  • Example 6 As an ink receiving layer and adhesive layer, plus coat RZ-142 (water-soluble polyester resin-based binder 25% aqueous solution: manufactured by Kyoyo Chemical Co., Ltd.) 700 g, sorbitol C-5 (etherified starch: manufactured by AVEBE) 10 g, FD Algin BL (Sodium alginate low-viscosity powder: manufactured by Furukawa Chemical Co., Ltd.) 198 g, Embatex D-23 (silicate aluminum derivative: manufactured by Kyoei Chemical Co., Ltd.) 190 g, Microid ML389 (silicon oxide: manufactured by Toyo Chemical Co., Ltd.), 5 g, dicyandiamide A mixture of 70 g, soda ash 85 g, and water about 1000 g was mixed at 5,000 r.
  • RZ-142 water-soluble polyester resin-based binder 25% aqueous solution: manufactured by Kyoyo Chemical Co., Ltd.
  • sorbitol C-5 etherified starch
  • a high-viscosity despar-type stirrer was used to stir well to make a high-viscosity paste.
  • This mixed paste was applied and dried on paper (Nippon Paper Industries, bleached kraft paper, 70 g / m 2 , thickness 125 ⁇ m) using a coating machine (Yokoyama Seisakusho).
  • the amount of paste applied to this textile paper was 38 g / m 2 . In this way, a printing paper for reactive dyes was obtained.
  • a reactive dye ink solution (CI Reactive Blue 19, 15%, polyethylene glycol 5%, glycerin 5%, ⁇ caprolactam 5%, ion-exchanged water 70%) is applied onto the above-mentioned printing paper (HYPERCO: Muto Kogyo).
  • a printed paper was obtained by printing with an on-demand type piezo ink jet printer and drying.
  • the reactive dye printed paper and the cotton lawn cloth were brought into close contact, and heated and pressurized (150 ° C., 0.4 Mpa, 3 m / min. Roller type), and the printed paper was attached to the cotton broad cloth.
  • the cotton loan cloth was subjected to a steaming treatment at 100 ° C. for 10 minutes while the printed paper was stuck, and then the printed paper was peeled off, but could be easily peeled off. After removing the printed paper, it was washed with water, soaped, washed with water and dried by a conventional method.
  • the printed fabric thus obtained has a delicate design and is dyed with fineness, robustness, and richness.
  • Example 7 As an ink receiving layer / adhesive layer, 75 g of Poval JP-18 (water-soluble polyvinyl alcohol binder powder: manufactured by Nihon Vineyard-Poval), 56 g of sorbitol C-5 (etherified starch: manufactured by AVEBE), EX-100S ( Tamarind gum: 30 g manufactured by Tomoe Glue Co., Ltd., 5 g defoaming agent 104 (manufactured by Sano Co., Ltd.), 840 g water, 2 g neoprene LB (preservative: manufactured by Sumika Enviro Science Co., Ltd.), neosynthol TF-1 (antifungal agent: 2 g of a mixture of 5,000 r.
  • Poval JP-18 water-soluble polyvinyl alcohol binder powder: manufactured by Nihon Vineyard-Poval
  • sorbitol C-5 etherified starch: manufactured by AVEBE
  • EX-100S Tamarind gum: 30
  • disperse dye ink liquid (CI Disperse Red86 press cake 4%, ethylene glycol 5%, glycerin 15%, nonionic dispersant 5%, anionic dispersant 5%, ion exchange water 66%) with the above-mentioned printing paper
  • Printed paper was obtained by printing with an ink jet printer (HYPERCO: manufactured by Muto Kogyo Co., Ltd .: on-demand type piezo ink jet printer) and drying.
  • the disperse dyed printed paper and the polyester satin fabric were in close contact with each other, and the dyed paper was fixed at the same time as applying the printed paper to the polyester fabric by heating and pressing at 210 ° C., 0.5 MPa for 2 minutes using a flat plate press. .
  • the printed paper was peeled off while applying moisture by spraying steam on the pasted paper, but it could be peeled off easily.
  • the polyester printed fabric thus obtained had a fine pattern, the texture of the fiber was flexible, and various fastnesses were grade 4 or higher.
  • this dough was subjected to reduction cleaning according to a conventional method, the cleaning liquid was colorless and transparent, the texture was not changed, and it was proved that reduction cleaning could be omitted.
  • Example 8 The leather obtained by the conventional one-bath method chrome tanning is combined with the printed paper obtained in Example 6 and set in a flat plate press HSP-2210 manufactured by Hashima, and then wetted with water to strongly The squeezed cotton fabric was applied and pressed and heated at 120 ° C. and 0.9 MPa for 2 minutes to perform pasting and fixing at the same time. Next, the printed paper was peeled off, but could be easily peeled off. Then, it washed with water and dried. As a result, a high-density cowhide with fine texture was obtained. The light fastness was 4-5, and the wet friction fastness was 3-4.
  • the paper printing method of the present invention targets all fiber materials and leather materials, and is a transfer printing method that can provide a finely printed pattern that has been regarded as difficult in the past with excellent reproducibility and economy. It is. According to the method of the present invention, it is possible to construct a production system capable of responding quickly and efficiently to small-lot, multi-product production and diversity needs. Therefore, the paper printing method of the present invention is a method that is excellent in environmental compatibility, economical efficiency, and quality effect, and is a novel printing method that greatly contributes to the enhancement of added value and the expansion of applications of printed fiber products and leather products.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Coloring (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)

Abstract

L'invention concerne un procédé d'impression de matières fibreuses et de cuir par papier transfert, caractérisé en ce qu'il comprend : une étape au cours de laquelle un papier d'impression est obtenu par application d'une pâte de mélange, comprenant un liant synthétique hydrosoluble, un adhésif naturel et un agent auxiliaire, sur un papier de base qui est ensuite séché pour obtenir un papier pour impression, sur lequel une encre à base de colorants est imprimée; une étape au cours de laquelle le papier d'impression est assemblé à une matière fibreuse ou de cuir et fixé par pression/chaleur; ainsi qu'une étape au cours de laquelle le papier d'impression est retiré à l'issue d'un processus de fixation des colorants, mis en oeuvre lorsque le papier d'impression est fixé sur la matière fibreuse ou de cuir. L'invention concerne en outre le papier pour impression et le papier d'impression utilisés dans le procédé d'impression par papier transfert, ainsi que les matières fibreuses et de cuir imprimées par le procédé d'impression par papier transfert.
PCT/JP2010/069811 2009-11-09 2010-11-08 Procédé d'impression de matières fibreuses et de cuir par papier transfert WO2011055817A2 (fr)

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JP2011505049A JP4778124B2 (ja) 2009-11-09 2010-11-08 繊維材料又は皮革材料のペーパー捺染法
CN201080050257.8A CN102597364B (zh) 2009-11-09 2010-11-08 纤维材料或皮革材料的纸印染法
EP10828375.5A EP2500464A4 (fr) 2009-11-09 2010-11-08 Procédé d'impression de matières fibreuses et de cuir par papier transfert

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WO2015093276A1 (fr) * 2013-12-18 2015-06-25 三菱製紙株式会社 Papier pour impression sur textile utilisé dans un procédé d'impression sur textile par papier
WO2015093277A1 (fr) * 2013-12-18 2015-06-25 三菱製紙株式会社 Papier pour impression sur textile utilisé dans un procédé d'impression sur textile par papier
JP2016102283A (ja) * 2014-11-27 2016-06-02 株式会社 Ｓｍｉ 繊維材料又は皮革材料のペーパー捺染法
JP2016104916A (ja) * 2014-12-01 2016-06-09 三菱製紙株式会社 ペーパー捺染法に用いる捺染用紙
JP2016104917A (ja) * 2014-12-01 2016-06-09 三菱製紙株式会社 ペーパー捺染法に用いる捺染用紙
JP5970588B1 (ja) * 2015-06-15 2016-08-17 株式会社 Ｓｍｉ 水性染料系印刷インキ、並びに、この水性染料系印刷インキを用いる印刷方法及び捺染法
WO2017111107A1 (fr) * 2015-12-25 2017-06-29 株式会社丸保 Procédé d'impression par transfert de matériaux fibreux à base de polyester
JP6173641B1 (ja) * 2015-12-25 2017-08-02 株式会社丸保 ポリエステル系繊維材料の転写捺染法
JP2017082383A (ja) * 2016-11-24 2017-05-18 株式会社 Ｓｍｉ 繊維材料又は皮革材料のペーパー捺染法及び捺染紙
WO2018139183A1 (fr) * 2017-01-25 2018-08-02 三菱製紙株式会社 Papier d'impression utilisé dans un procédé d'impression de papier
JP2018076635A (ja) * 2017-12-06 2018-05-17 日本製紙株式会社 捺染印刷用転写紙および捺染方法
JP6465325B1 (ja) * 2018-02-09 2019-02-06 眩士 山本 転写捺染法
WO2019156080A1 (fr) * 2018-02-09 2019-08-15 株式会社グローバルプリンティング＆ペーパー Procédé d'impression sur textile par transfert, composition de produit d'encollage pour impression sur textile par transfert, et papier pour impression sur textile
JP2019137943A (ja) * 2018-02-09 2019-08-22 眩士 山本 転写捺染法
WO2020195284A1 (fr) * 2019-03-26 2020-10-01 三菱製紙株式会社 Papier à report et procédé d'impression par report
JP2020165070A (ja) * 2019-03-26 2020-10-08 三菱製紙株式会社 転写用紙

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WO2011055817A3 (fr) 2011-08-04
EP2500464A4 (fr) 2015-01-14
JP4778124B2 (ja) 2011-09-21
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